Background
The waste steel is used as an energy-carrying resource, and the increase of the use amount of the waste steel is beneficial to reducing the production pressure of high-energy-consumption procedures such as coking, sintering, iron making and the like. The method can save a large amount of coke and raw coal, is also beneficial to reducing carbon emission and wastewater emission in the steel production process, and promotes the steel industry to develop into low carbon and green. In order to reduce the cost and increase the efficiency and increase the profit of ton steel, steel enterprises generally adopt a method for increasing the scrap ratio. With the continuous improvement of the steel scrap ratio, the heat quantity in the furnace is insufficient, the original heat balance is broken, sludge and terminal peroxidation are easy to occur, problems are brought to production and quality, and the ton steel cost is indirectly improved.
To solve these problems, various iron and steel enterprises have proposed many methods. For example, patent CN112981039a discloses a scrap steel preheating system and a working method, in which the scrap steel preheating method is adopted, scrap steel needs to be preheated in a ladle, field equipment needs to be modified, the used combustible gas is CO, carbon monoxide poisoning or explosion accidents easily occur, and life health of workers is threatened. For another example, patent CN114196798a discloses a single-channel secondary combustion oxygen lance and a method for using the same, which can increase the combustion rate of CO and supply heat to the furnace. However, the oxygen lance needs to be modified, the service life of the modified oxygen lance is low, secondary combustion is performed above a molten pool, heat is easy to be pumped away, the heat efficiency is low, the gas value of a converter is influenced, adverse effects are brought to a lime kiln, the blowing time can be prolonged due to the fact that a heating agent is added into the converter, siO 2 is formed after the main heating element Si is oxidized, the slag alkalinity is reduced, the slag alkalinity is increased due to the fact that lime is additionally added, and the slag quantity is increased.
Disclosure of Invention
Aiming at the problem of high residue content caused by the improvement of the scrap steel ratio in the prior art, the invention provides a low-iron-consumption low-silicon duplex slag-free smelting method for solving the problem. The method of the invention improves dephosphorization efficiency of the converter while reducing smelting slag amount, and reduces the steps of waiting for component detection after finishing blowing and smelting period, wherein w P in chemical components of molten steel at the end point of the converter is less than or equal to 0.015 percent.
The technical scheme of the invention is as follows:
a smelting method of low iron loss and low silicon duplex slag reduction comprises the following steps:
the method comprises the steps of (1) feeding, (2) converting, (3) end point control, (4) tapping and (5) slag splashing;
The step (1) is to put molten iron and scrap steel into a converter, wherein the molten iron accounts for 70% -73%, the rest is scrap steel, the converter is adopted for smelting, and w P is less than or equal to 0.18% and w Si is less than or equal to 0.40% in the molten iron.
Further, in the step (1), the molten iron charged into the furnace is less than 185 tons.
In the step (2), during the blowing process, slag-making materials such as lime, raw dolomite, magnesium balls, sinter and the like and cold materials are added, the reaction condition in the furnace is judged through flame, gun position and flow rate are controlled, and decarburization and dephosphorization reactions are carried out.
Further, in the step (3), a sublance is used for measuring the blowing process, the end temperature and the components, lime or sinter is added into a furnace according to the process temperature to reduce the temperature of molten steel P to avoid the runaway caused by the high process temperature, the cooling effect of the lime is 10-12 ℃ per ton, the cooling effect of the sinter is 15-20 ℃ per ton, w [ C ] in the molten steel at the end of converter blowing is 0.04-0.10%, the end temperature is 1600-1640 ℃, and tapping is started after the blowing is finished.
In the step (4), an end slag sample is taken and detected during tapping, and the alkalinity is 2.6-3.3.
In the step (5), a proper amount of magnesium balls or raw dolomite (CaCO 3 and MgCO 3 are used as main components) is added according to the final slag condition to adjust the alkalinity and fluidity of slag, and the slag splashing operation time is 3-5 min.
Further, the slag components after slag splashing comprise 12-16% of SiO 2, 35-43% of CaO, 3-7% of MgO and 13-20% of TFe.
And (3) after the step (5) is finished, carrying out slag retention according to the tapping molten iron condition and the steel grade, wherein the slag retention amount in the furnace after the slag pouring is finished is 1-2 tons.
The invention has the beneficial effects that:
(1) The invention increases the heat in the converter by reducing the addition amount of slag-making materials and the total slag amount, increases the steel scrap addition amount and improves the steel scrap ratio. By reducing the total slag amount, the iron content in the slag is reduced, and the consumption of steel materials is reduced.
(2) The invention accelerates the dephosphorization reaction rate of the steel slag interface by utilizing the characteristics of good final slag alkalinity and high iron oxide fluidity. The dephosphorization efficiency of the converter in the desilication period is improved by reducing the adding amount of slag to accelerate the early-stage deslagging, the adding amount of slag is less in the process, the deslagging is ensured to be thoroughly melted, the dephosphorization efficiency of the converting process is improved, the endpoint wP of the converter is less than or equal to 0.015%, the dynamic dephosphorization and the late-stage back-phosphorus pressure are reduced, and the loss caused by the high phosphorus content of molten steel is avoided.
(3) The invention can pour slag once after slag splashing in the whole blowing process, and the slag is directly tapped without detecting endpoint components after carbon drawing is finished, thereby shortening the smelting period, improving the converter rhythm and reducing the smelting cost.
Detailed Description
In order to better understand the technical solutions of the present invention, the following description will clearly and completely describe the technical solutions of the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the present invention without making any inventive effort, shall fall within the scope of the present invention.
Examples 1 to 3 were prepared by smelting AH36 steel using a 210 ton top-bottom combined blown converter.
Example 1
A smelting method of low iron loss and low silicon duplex slag reduction comprises the following steps:
(1) Feeding material
181 Tons of molten iron and 66 tons of scrap steel are put into a converter, wherein w P is 0.12% and Si is 0.15%.
(2) Converting by blowing
During blowing, adding 7134kg of lime, 632kg of magnesium balls, 299kg of ferrosilicon, 2600mm of a blowing gun position, 28500m 3/h of flow, 2300mm of a process gun position, 48500m 3/h of flow, properly adjusting the gun position according to the reaction in the furnace after the slag in the furnace is gasified, and carrying out decarburization and dephosphorization reaction by pulling the carbon gun position 2000mm and 51800m 3/h of flow.
(3) Endpoint control
The end point temperature and composition are measured by using sublance, w < C > is 0.063%, end point temperature is 1615 deg.C, and w < P > is 0.011% in the end point molten steel of converter blowing.
(4) Tapping steel
And after blowing, tapping is started, and a terminal slag sample is taken and detected during tapping, wherein the alkalinity is 2.9.
(5) Slag splashing
And adding 1033kg of raw dolomite according to the final slag condition to adjust the alkalinity and fluidity of slag, wherein the slag splashing operation time is 3-5 min. The slag components after slag splashing comprise SiO 2 14.7.7%, caO 43.8%, mgO 7.4% and TFe 17.2%.
(6) After the slag splashing is finished, slag is reserved according to the molten iron condition and the steel grade of the lower furnace, and the slag amount reserved in the furnace after the slag splashing is finished is 1.5 tons.
Example 2
A smelting method of low iron loss and low silicon duplex slag reduction comprises the following steps:
(1) Feeding material
179 Tons of molten iron and 66 tons of scrap steel are put into a converter, wherein w P is 0.106% and Si is 0.2%.
(2) Converting by blowing
During blowing, 6999kg of lime, 625kg of magnesium balls, 308kg of ferrosilicon, 2600mm of open blowing gun position, 28500m 3/h of flow, 2300mm of process gun position, 48500m 3/h of flow, proper adjustment of gun position according to furnace reaction after slag in the furnace is gasified, 2000mm of carbon pulling gun position, 51800m 3/h of flow, and decarburization and dephosphorization reaction are carried out.
(3) Endpoint control
The end point temperature and the components are measured by using a sublance, wherein w < C > is 0.045% and the end point temperature is 1629 ℃ in the end point molten steel of converter blowing, and w < P > is 0.012%.
(4) Tapping steel
And after blowing, tapping is started, and a terminal slag sample is taken and detected during tapping, wherein the alkalinity is 2.76.
(5) Slag splashing
Adding 1003kg of raw dolomite according to the final slag condition to adjust the alkalinity and fluidity of slag, wherein the slag splashing operation time is 3-5 min. The slag components after slag splashing comprise SiO 2 15.4.4%, caO 45.5%, mgO 5.59% and TFE14.7%.
(6) After the slag splashing is finished, slag is reserved according to the molten iron condition and the steel grade of the lower furnace, and the slag amount reserved in the furnace after the slag splashing is finished is 1.8 tons.
Example 3
A smelting method of low iron loss and low silicon duplex slag reduction comprises the following steps:
(1) Feeding material
181 Tons of molten iron and 67 tons of scrap steel are put into a converter, wherein w P is 0.126 percent and Si is 0.24 percent in the molten iron.
(2) Converting by blowing
During blowing, 7386kg of lime, 623kg of magnesium balls, 227kg of ferrosilicon and 678kg of raw dolomite are added, a blowing gun position is 2600mm, the flow is 28500m 3/h, a process gun position is 2300mm, the flow is 48500m 3/h, the gun position is properly adjusted according to the reaction in the furnace after slag in the furnace is completely melted, a carbon pulling gun position is 2000mm, and the flow is 51800m 3/h for decarburization and dephosphorization reaction.
(3) Endpoint control
The end point temperature and the components are measured by using a sublance, wherein w < C > is 0.065%, the end point temperature is 1630 ℃ and w < P > is 0.009% in the end point molten steel of converter blowing.
(4) Tapping steel
And after blowing, tapping is started, and a terminal slag sample is taken and detected during tapping, wherein the alkalinity is 3.0.
(5) Slag splashing
And adding 665kg of raw dolomite according to the final slag condition to adjust the alkalinity and fluidity of slag, wherein the slag splashing operation time is 3-5 min. The slag components after slag splashing comprise SiO 2 14.6.6%, caO 45.3%, mgO 4.8% and TFe 13.2%.
(6) After the slag splashing is finished, slag is reserved according to the molten iron condition and the steel grade of the lower furnace, and the slag amount reserved in the furnace after the slag splashing is finished is 1.3 tons.
Although the present invention has been described in detail by way of preferred embodiments, the present invention is not limited thereto. Various equivalent modifications and substitutions may be made in the embodiments of the present invention by those skilled in the art without departing from the spirit and scope of the present invention, and it is intended that all such modifications and substitutions be within the scope of the present invention/be within the scope of the present invention as defined by the appended claims.