CN1191889A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
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- CN1191889A CN1191889A CN98104357A CN98104357A CN1191889A CN 1191889 A CN1191889 A CN 1191889A CN 98104357 A CN98104357 A CN 98104357A CN 98104357 A CN98104357 A CN 98104357A CN 1191889 A CN1191889 A CN 1191889A
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- composition
- acid
- salt
- multipolymer
- Prior art date
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- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 44
- 239000003599 detergent Substances 0.000 title claims abstract description 21
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 13
- 229910052816 inorganic phosphate Inorganic materials 0.000 claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 17
- 239000013543 active substance Substances 0.000 claims description 15
- -1 polyoxyethylene Polymers 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- 239000003513 alkali Substances 0.000 claims description 13
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 12
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 12
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 229910052728 basic metal Inorganic materials 0.000 claims description 5
- 150000003818 basic metals Chemical class 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 239000001226 triphosphate Substances 0.000 claims description 3
- 235000011178 triphosphate Nutrition 0.000 claims description 3
- 125000002264 triphosphate group Chemical group [H]OP(=O)(O[H])OP(=O)(O[H])OP(=O)(O[H])O* 0.000 claims description 2
- 238000005406 washing Methods 0.000 abstract description 13
- 239000007787 solid Substances 0.000 abstract description 5
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 230000001965 increasing effect Effects 0.000 abstract 1
- 239000010446 mirabilite Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 239000011734 sodium Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000011777 magnesium Substances 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 5
- 229940088598 enzyme Drugs 0.000 description 5
- 239000001488 sodium phosphate Substances 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 5
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 5
- 235000019801 trisodium phosphate Nutrition 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000007850 fluorescent dye Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000004584 polyacrylic acid Substances 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000003352 sequestering agent Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 2
- 108010065511 Amylases Proteins 0.000 description 2
- 102000013142 Amylases Human genes 0.000 description 2
- 108010059892 Cellulase Proteins 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- 102000004882 Lipase Human genes 0.000 description 2
- 108090001060 Lipase Proteins 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 102000035195 Peptidases Human genes 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 2
- 108010082455 Sebelipase alfa Proteins 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 235000019418 amylase Nutrition 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 238000003287 bathing Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229940106157 cellulase Drugs 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 229940041615 kanuma Drugs 0.000 description 2
- 235000019421 lipase Nutrition 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N pentadecanoic acid Chemical compound CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 229920013701 VORANOL™ Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- DCAYPVUWAIABOU-UHFFFAOYSA-N alpha-n-hexadecene Natural products CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- PMPJQLCPEQFEJW-GNTLFSRWSA-L disodium;2-[(z)-2-[4-[4-[(z)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C/C1=CC=C(C=2C=CC(\C=C/C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-GNTLFSRWSA-L 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Provided is a powdery cleanser composition which is capable of increasing properties for preventing a solid state dirt from reattaching without damaging cleansing properties and useful for washing clothes by formulating specific proportions of an inorganic phosphate, polyethylene glycol, a specified copolymer and mirabilite with a detergent.
Description
The present invention relates to the clothing powder detergent composition.
Clothing is composed of the following components with washing composition: tensio-active agent, and it can make the dirt solubilising on the fiber, therefore makes its dissolving or is dispersed in the washing lotion; Sequestrant is used to remove the material (as calcium and magnesium) of failure surface promoting agent performance; Alkali has the decomposition of promotion dirt and the effect of solubilising; The high-molecular weight compound is used to disperse dirt; And other detergent builder.
An effect of detergent builder is to prevent the redeposition removed from clothing.Example with builder of this usefulness comprises Tri sodium Phosphate, polyacrylic acid and polyoxyethylene glycol.An example as the prior art of using these builders, can be referring to " the Detergentcomposition having improved physical properties and solubility in cold water " that disclose in the U.S. Patent No. 4657693 (having improved physicals and energy dissolved detergent composition in cold water), said composition contains tensio-active agent, Tri sodium Phosphate, polyoxyethylene glycol and polyacrylic acid.Yet said composition is preventing that the performance aspect the solid soil redeposition is still abundant inadequately.
The present inventor has carried out extensive studies to address the above problem.Found that the problems referred to above can be resolved by following method: the multipolymer and the saltcake of inorganic phosphate, polyoxyethylene glycol, vinylformic acid and toxilic acid are mixed with specific ratio, and then to wherein adding tensio-active agent and alkali.
Therefore, powder detergent composition provided by the present invention contains 15-30% (weight) inorganic phosphate, the multipolymer of 0.05-2.0% (weight) vinylformic acid and toxilic acid, 0.05-2.0% (weight) polyoxyethylene glycol, 15-40% (weight) saltcake, tensio-active agent and alkali.
In other words, powder detergent composition of the present invention contains tensio-active agent and alkali, it is characterized in that also containing 15-30% (weight) inorganic phosphate, the multipolymer of 0.05-2.0% (weight) vinylformic acid and toxilic acid, 0.05-2.0% (weight) polyoxyethylene glycol, and 15-40% (weight) saltcake or sodium sulfate.
Preferable detergent composition of the present invention also contains 0.1-5% (weight) crystalline silicate (crystallinesilicate), when its consumption with 0.1% (weight) is scattered in 20 ℃ the deionized water, the pH value of given maximum is 11 or higher, and the HCl aqueous solution that such basicity needs 5ml 0.1N at least is reduced to 10 with the pH value of above-mentioned aqueous dispersions by 11.
Detergent composition of the present invention contains 10-40% (weight) tensio-active agent and 10-30% (weight) alkali preferably.
Inorganic phosphate is triphosphate, orthophosphoric acid salt or pyrophosphate salt preferably, and the counter ion of these salt are basic metal.
The concrete example of used vinylformic acid and maleic acid comprises vinylformic acid/maleic acid, vinylformic acid/copolymer-maleic anhydride and part salt thereof (partial salt).
According to the present invention, in the phosphorus-containing detergent that contains tensio-active agent, alkali, inorganic phosphate and saltcake, the multipolymer and the polyoxyethylene glycol that add vinylformic acid and toxilic acid improve performance.
The example preferably that is used for inorganic phosphate of the present invention also has orthophosphoric acid salt and pyrophosphate salt except triphosphate.More suitable is, the content of Tri sodium Phosphate is at least 80% (weight) in whole phosphoric acid salt, and the content range of ortho-phosphoric acid and tetra-sodium is respectively 1-5% (weight) and 2-5% (weight), and these content are all in dry substance.Basic metal is counter ion preferably, is more preferably sodium and/or potassium.The content of inorganic phosphate in detergent composition is 15-30% (weight), is 17-25% (weight) preferably, and these content are all in dry substance.
The multipolymer that is used for vinylformic acid of the present invention and toxilic acid except sequestering action is arranged, also has the solid dirt particles on the clothing is distributed to effect in the bathing, and its another effect is to prevent that these particles from depositing (staiing) again to clothing again.Sneak into molecular weight for from the multipolymer of hundreds of to ten ten thousand in order to reach this purpose, to be preferably, it is represented by following formula (I).In general, this multipolymer prepares by random polymerization.
-(Z
1)
m-(Z
2)
n-·(m+2n)M????(I)
In following formula, Z
1Expression derives from acrylic acid monomeric unit; Z
2Expression derives from the another kind of monomeric unit of toxilic acid or maleic anhydride; M and n are the numbers that molecular weight (m+n) can be provided, and this molecular weight is from hundreds of to ten ten thousand, and the ratio of m: n is 8: 2 to 5: 5; M is Na, K, NH
4Or H.This multipolymer can be the form of part salt.M can be Na, K or NH in a molecule
4With combining of H.
In detergent composition, the content of the multipolymer of formula (I) is 0.05-2% (weight), and the molecular weight of this polymkeric substance is preferably in 200 to 100,000 scope.
Being used for polyoxyethylene glycol of the present invention, to be preferably molecular-weight average be 5,000 to 15,000 polyoxyethylene glycol.In composition, its content is 0.05-2.0% (weight), is 0.1-1.0% (weight) preferably.
Be used for the generic name that saltcake of the present invention is a sodium sulfate, its effect is the salt intensity that strengthens bathing, and is formed at the skeleton (this and other alkali similar) of the detergent particles after dry.The content of saltcake in composition is preferably 15-40% (weight), is more preferably 18-35% (weight), and content is in dry substance.
In the present invention, the detersive power of composition can further improve by adding crystalline silicate.Be used for crystalline silicate of the present invention when the consumption with 0.1% (weight) is scattered in 20 ℃ deionized water, the pH value of given maximum is 11 or higher, and the HCl aqueous solution that big like this basicity needs 5ml 0.1N at least is reduced to 10 with the pH value of above-mentioned aqueous dispersions by 11.This kind crystalline silicate is different from crystal aluminosilicate.
The good especially example of crystalline silicate is the crystalline silicate with following composition:
x(M
2O)·y(SiO
2)·z(Me
mO
n)·w(H
2O)??????(II)
Wherein, the element of Ia family in the M indication cycle table, that good especially is K and/or Na; Me represents to be selected from one or more elements of IIa in the periodictable, IIb, IIIa, IVa and VIII family, is preferably Mg and/or Ca; Y/x is 0.5 to 2.6; Z/x is 0.01 to 0.9; W is 0 to 20; N/m is 0.5 to 2.0.
Crystalline silicate by general formula (II) expression can be prepared with reference to JP-A 7-89712.
In addition, the crystalline silicate with following composition also is suitable for:
M
2O·x′(SiO
2)·y′(H
2O)????(III)
Wherein M represents basic metal, and that good especially is K and/or Na; X ' is 1.5 to 2.6; Y ' is 0 to 20, and good especially is to be essentially 0.
The crystalline silicate of general formula (III) is recorded in JP-A 60-227895, Phys.Chem.Glasses.7, and 127-138 (1966), Z.Kristallogr., 129, p.396-p.404 in the documents such as (1969).In addition, " the Na-SKS-6 of also available HoechstAG. company
TM" (δ-Na
2Si
2O
5) powdery or partical.The consumption of crystalline silicate is preferably 0-5% (weight) in the present composition, better is 0.1-5% (weight).
A kind of anion surfactant that contains is a tensio-active agent used among the present invention as the tensio-active agent of main ingredient.Among the present invention good especially being to use in alkyl chain, have 12 to 14 carbon atoms line style alkylbenzene sulfonate or have the alkyl-sulphate of 12 to 18 carbon atoms.Basic metal is counter ion preferably, is more preferably sodium and/or potassium.In addition, tensio-active agent can also contain a spot of soap that derives from butter and coconut.
In the present invention, the content of anion surfactant is in the scope of 10-40% (weight), preferably in the scope of 15-30% (weight).
As the used alkali of the present invention, except above-mentioned crystalline silicate and inorganic phosphate, be preferably the alkali known to adding usually.These alkali for example comprise alkaline carbonate, as yellow soda ash (being commonly called as heavy soda ash or light soda ash ash), and unbodied alkalimetal silicate, as JIS No.1, No.2 and No.3.The effect of these mineral alkalis is to form the particulate skeleton in the step of dry washing composition, thereby guarantees to provide harder, mobile well washing composition.The content of alkali in composition in the scope of 10-30% (weight), better is 15-25% (weight) preferably.
Except said components, detergent composition of the present invention can also contain the component that some people are familiar with, and its consumption also is used usually.For example, tensio-active agent is as non-ionic tensio-active agent (as Voranol EP 2001), cationic tensio-active agent and amphoterics; Sequestrant, as be called the crystal aluminosilicate of zeolite and the crystalline silicate described in JP-A 7-89712 and the JP-A 60-227895; Organic sequestering agent is as ethylenediamine tetraacetic acid (EDTA) (EDTA) and Citrate trianion; Dispersion agent or color transfer inhibitor are as carboxymethyl cellulose (CMC), polyvinylpyrrolidone (PVP) and polyvinyl alcohol (PVA); SYNTHETIC OPTICAL WHITNER is as SPC-D; Bleach-activating agent, organic peracid precursor described in JP-A 6-316700 and tetraacetyl ethylene diamine (TAED); Enzyme is as proteolytic enzyme, cellulase, amylase and lipase; Enzyme stabilizers is as boron compound and S-WAT; The fluorescence dye of biphenyl or Stilbene type; The defoamer of siloxanes/silica-type etc.; Oxidation inhibitor; Bluing agent; And spices.Particularly, some materials described in the JP-A 8-218093 can be used as above-mentioned additive.
Detergent composition can prepare by known method.Those skilled in the art can be not difficult to select suitable preparation condition according to its composition.
Composition of the present invention has very big detersive power, and it is also very superior at the aspect of performance that prevents the solid soil redeposition.
Embodiment 1 and 2 and comparing embodiment 1 to 4
Earlier by 20kg LAS, 0.5kg AA-MA multipolymer, it is 60% water slurry that 0.5kg polyoxyethylene glycol, 20kg Tri sodium Phosphate, 10kg water glass JIS No.2,14.9g SODA ASH LIGHT 99.2,20kg saltcake and 0.3kg fluorescence dye have prepared solids content.With the water slurry spraying drying, the powder that obtains is thus added in the vertical mixing tank, again to wherein adding 3kg zeolite, 1.5kg crystalline silicate and 1kg enzyme, follow blend mixture, obtain powder detergent composition (tap density: 0.35g/ml, the median size: 400 μ m) of the embodiment 1 shown in the table 1.The composition for preparing embodiment 2 and comparing embodiment 1 to 4 by identical method.
For the every kind of composition that obtains, all carry out detersive power test and antiredeposition test in order to following method.Table 1 has been summed up the result.
＜detersive power test 〉
The preparation of the artificial dress material that stains
Use the following artificial contamination solution of forming earlier dress material manually to be stain.Being to use tankage is 58cm
3/ m
2The grooved roll coating machine, with the application rate of 1.0m/min, will manually stain solution and print on the dress material and stain.Then, following dry 1 minute at 100 ℃.Use shirt to use cotton 2003 (Tanigashira Shoten production) as dress material.
The artificial composition that stains solution
Lauric acid 0.44% (weight)
Tetradecanoic acid 3.09% (weight)
Pentadecylic acid 2.31% (weight)
Palmitinic acid 6.18% (weight)
Margaric acid 0.44% (weight)
Stearic acid 1.57% (weight)
Oleic acid 7.75% (weight)
Three oleic acid 13.06% (weight)
Palmitinic acid hexadecane ester 2.18% (weight)
Squalene 6.53% (weight)
Lecithin, liquid crystal shape 1.94% (weight)
Red soil (Kanuma) 8.11% (weight)
Carbon black 0.01% (weight)
The tap water surplus
Wash conditions and testing method
(10cm * 10cm) puts into the aqueous solution of the 1 liter of washing composition that will test and tests, and under the following conditions, washs with the speed of per minute 100 commentaries on classics (100rpm) with Terg-O-Tometer with the artificial cloth that stains of 5 warps.
Wash conditions:
Washing time 10 minutes
Detergent concentration 0.133%
5 ° of DH of water hardness
25 ℃ of the temperature of water
Tap water rinsing 5 minutes are used in rinsing
The following test of detersive power: with monochromatic colorimeter (selfcolorimeter) (Shimadzu Corporation productions) measure before initial cloth and the cloth washing through staiing and wash after at the reflectivity at 550nm place, according to following formula calculating detersive power (%).The detersive power data are represented with the mean value of 5 cloth gained data.
The test of＜antiredeposition 〉
Use shirt to use cotton 2003 (Tanigashira Shoten production) as dress material.With after commercially available washing composition AttackTM (the Kao Corporation production) washing, this cloth is cut into bulk (10cm * 10cm).Add 2.5g red soil (Kanuma) in the aqueous solution of the 1 liter of washing composition that will test, these red soils sieve through super-dry with 150 purposes sieve in advance.Then 5 blocks of above-mentioned clothes are put into, washed with the rotating speed of Terg-O-Tometer under the following conditions with 100rpm.
Wash conditions:
Washing time 10 minutes
Detergent concentration 0.133%
5 ° of DH of water hardness
25 ℃ of the temperature of water
Tap water rinsing 5 minutes are used in rinsing
The following test of antiredeposition rate: with the reflectivity at the 550nm place of initial cloth before monochromatic colorimeter (Shimadzu Corporation production) the measurement contamination and the cloth after the washing, according to following formula calculating antiredeposition rate (%).Antiredeposition rate data are represented with the mean value of 5 cloth gained data.
Table 1
| Component (%) | Embodiment | Comparing embodiment | ||||||||
| ???1 | ???2 | ???3 | ???4 | ???5 | ???6 | ???1 | ???2 | ???3 | ???4 | |
| LAS | ???20 | ???18 | ???20 | ???20 | ???27 | ???20 | ???25 | ???20 | ???20 | ???20 |
| The AA-MA multipolymer | ???0.5 | ???0.5 | ???0.5 | ???0.5 | ???0.07 | ???1.9 | ???0.5 | ???- | ???0.5 | ???- |
| Polyacrylic acid | ???- | ???- | ???- | ???- | ???- | ???- | ???- | ???- | ???- | ???0.5 |
| Polyoxyethylene glycol | ???0.5 | ???0.5 | ???0.5 | ???0.5 | ???0.07 | ???1.9 | ???0.5 | ???0.5 | ???- | ???0.5 |
| STPP | ???20 | ???20 | ???29 | ???16 | ???20 | ???20 | ???10 | ???20 | ???20 | ???20 |
| SODA ASH LIGHT 99.2 | ???14.9 | ???14.9 | ???9.9 | ???1.9 | ???8.76 | ???12.1 | ???14.9 | ???14.9 | ???14.9 | ???14.9 |
| Water glass | ???10 | ???10 | ???10 | ???10 | ???10 | ???10 | ???10 | ???10 | ???10 | ???10 |
| Crystalline silicate | ???1.5 | ???1.5 | ???1.5 | ???1.5 | ???1.5 | ???1.5 | ???1.5 | ???1.5 | ???1.5 | ???1.5 |
| Zeolite | ???3 | ???3 | ???3 | ???3 | ???3 | ???3 | ???18 | ???3.5 | ???3.5 | ???3 |
| Saltcake | ???20 | ???22 | ???16 | ???37 | ???20 | ???20 | ???10 | ???20 | ???20 | ???20 |
| Enzyme | ???1 | ???1 | ???1 | ???1 | ???1 | ???1 | ???1 | ???1 | ???1 | ???1 |
| Fluorescence dye | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 |
| Spices | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 | ???0.3 |
| Water | ???8 | ???8 | ???8 | ???8 | ???8 | ???8 | ???8 | ???8 | ???8 | ???8 |
| Detersive power (%) | ???70 | ???68 | ???70 | ???66 | ???68 | ???70 | ???72 | ???71 | ???71 | ???70 |
| Antiredeposition rate (%) | ???80 | ???78 | ???80 | ???78 | ???75 | ???82 | ???68 | ???67 | ???69 | ???69 |
Annotate:
LAS: linear alkyl (C
12) benzene sulfonic acid sodium salt
The AA-MA multipolymer: mol ratio is the sodium salt of vinylformic acid/maleic acid of 7/3, and molecular-weight average is 70,000.
Polyacrylic acid: sodium polyacrylate, molecular-weight average are 6,000.
Polyoxyethylene glycol: molecular-weight average is 7,000.
STPP: Tri sodium Phosphate
Water glass: water glass JIS No.2
Crystalline silicate: form M
2O1.8SiO
20.02M ' O (M:Na, K, K/Na=0.03, M '=Ca, Mg, Mg/Ca=0.01).Ion-exchange capacity: 290 CaCO
3Mg/g, median size: the represented crystalline silicate of 30 μ m[general formulas (II)].
Zeolite: form M
2OAl
2O
32SiO
22H
2O, median size: 4 μ m, ion-exchange capacity: 290 CaCO
3Mg/g.
Enzyme: with 2: 1: 1: 1 weight ratio blended proteolytic enzyme (Savinase 12.0TW, Novo Nordisk production), lipase (Lipolase 100T, Novo Nordis production), cellulase (Celluzyme 0.1T, originate from Novo Nordisk) and amylase (Termamyl 60T, Novo Nordisk produces).
Fluorescence dye: weight ratio blended Tinopal CBS (Ciba-Geigy the production)/Whitex SA with 1/1 (Sumitomo Chemical Co., Ltd. produces).
Claims (5)
1. powder detergent composition, comprise tensio-active agent and alkali, it is characterized in that said composition also comprises the multipolymer of 15-30% (weight) inorganic phosphate, 0.05-2.0% (weight) vinylformic acid and toxilic acid, 0.05-2.0% (weight) polyoxyethylene glycol and 15-40% (weight) saltcake or sodium sulfate.
2. composition as claimed in claim 1, it is characterized in that said composition also contains 0.1-5% (weight) crystalline silicate, when its consumption with 0.1% (weight) is scattered in 20 ℃ the deionized water, the pH value of given maximum is 11 or higher, and the HCl aqueous solution that such basicity needs 5ml 0.1N at least is reduced to 10 with the pH value of above-mentioned aqueous dispersions by 11.
3. composition as claimed in claim 1 is characterized in that said composition contains the described tensio-active agent of 10-40% (weight) and the described alkali of 10-30% (weight).
4. composition as claimed in claim 1 is characterized in that described inorganic phosphate is triphosphate, orthophosphoric acid salt or pyrophosphate salt, and the counter ion of these salt are basic metal.
5. composition as claimed in claim 1, the multipolymer that it is characterized in that described vinylformic acid and toxilic acid are vinylformic acid/maleic acid, vinylformic acid/copolymer-maleic anhydride or its part salt.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP012744/1997 | 1997-01-27 | ||
| JP1274497A JPH10204490A (en) | 1997-01-27 | 1997-01-27 | Cleanser composition |
| JP012744/97 | 1997-01-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1191889A true CN1191889A (en) | 1998-09-02 |
| CN1195831C CN1195831C (en) | 2005-04-06 |
Family
ID=11813939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB981043577A Expired - Fee Related CN1195831C (en) | 1997-01-27 | 1998-01-26 | Detergent composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPH10204490A (en) |
| CN (1) | CN1195831C (en) |
| ID (1) | ID19765A (en) |
| SG (1) | SG64469A1 (en) |
| TW (1) | TW402634B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014387B (en) * | 2004-08-19 | 2011-02-02 | 欧莱雅 | Cosmetic use of polysaccharide compounds containing non-polymer siloxane graft(s) |
| CN104674553A (en) * | 2015-03-06 | 2015-06-03 | 苏州爱立方服饰有限公司 | Stain-removal finishing agent for fabric and preparation method of stain-removal finishing agent |
-
1997
- 1997-01-27 JP JP1274497A patent/JPH10204490A/en active Pending
-
1998
- 1998-01-09 TW TW87100210A patent/TW402634B/en not_active IP Right Cessation
- 1998-01-13 SG SG1998000089A patent/SG64469A1/en unknown
- 1998-01-26 ID IDP980102A patent/ID19765A/en unknown
- 1998-01-26 CN CNB981043577A patent/CN1195831C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014387B (en) * | 2004-08-19 | 2011-02-02 | 欧莱雅 | Cosmetic use of polysaccharide compounds containing non-polymer siloxane graft(s) |
| CN104674553A (en) * | 2015-03-06 | 2015-06-03 | 苏州爱立方服饰有限公司 | Stain-removal finishing agent for fabric and preparation method of stain-removal finishing agent |
| CN104674553B (en) * | 2015-03-06 | 2016-11-09 | 苏州爱立方服饰有限公司 | A kind of fabric decontamination inorganic agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| SG64469A1 (en) | 1999-04-27 |
| ID19765A (en) | 1998-07-30 |
| CN1195831C (en) | 2005-04-06 |
| TW402634B (en) | 2000-08-21 |
| JPH10204490A (en) | 1998-08-04 |
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