Detailed Description
The technical solutions of the embodiments of the present application will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present application, and it is apparent that the described embodiments are only some embodiments of the present application, but not all embodiments, and all other embodiments obtained by those skilled in the art without making creative efforts based on the embodiments of the present application are included in the protection scope of the present application.
Currently, most of window glass is laminated glass. Ceramic ink is typically screen printed at the edges of the laminated glass to create a masking effect at the edges of the laminated glass. Since the screen-printed mold is usually flat, it is necessary to screen-print the edges of the individual glass plates when the individual glass plates are flat, so as to form a ceramic ink layer on the edges of the individual glass plates. Subsequently, the single glass sheet is subjected to a high-temperature heat treatment to bend the single glass sheet into a shape. And then bonding and connecting the plurality of single glass plates after bending and forming through the thermoplastic layer to form the laminated glass.
In the process of bending and forming a single glass plate, as the ceramic ink is positioned on the surface of the glass, the thermal conductivity of the ceramic ink is larger than that of the glass, the cooling speed of the ceramic ink is larger than that of the glass, and the ceramic ink usually reaches normal temperature in preference to the glass. When the ceramic ink reaches normal temperature and cures, the glass in contact with the ceramic ink remains above normal temperature. In the process of continuously cooling and forming the glass, the solidified ceramic ink can apply stress to the edge position of the single glass plate, so that stress concentration is generated at the edge position of the formed single glass plate, and the structural strength of the edge position of the single glass plate is reduced. The edge position of the single glass plate is easy to break when being impacted by external force. Thus, the edge position of the laminated glass assembled from the individual glass plates is easily broken when an external force is applied.
In view of this, the present application provides a window glass 100 that can ensure structural strength of the window glass 100, and that can improve safety performance of the vehicle 1000 by applying the window glass 100 of the present application to the vehicle 1000.
It should be noted that the vehicle 1000 according to the present application may be, but is not limited to, a vehicle such as an automobile, a train, or a rail transit. The window glass 100 may be, but is not limited to, a front windshield, a side windshield, a rear windshield, a sunroof glass, and the like of the vehicle 1000. The embodiment of the present application will be described by taking the vehicle 1000 as an automobile and the window glass 100 as a front windshield as an example.
Referring to fig. 1 and 2 in combination, a vehicle 1000 includes a vehicle body 200 and a window glass 100. The window glass 100 is connected to the vehicle body 200. The vehicle 1000 further includes an interior (not shown), a body sheet metal member of the vehicle 1000, and the like.
For convenience of description, the width direction of the window glass 100 in fig. 2 is defined as the X-direction, the height direction of the window glass 100 is defined as the Y-axis direction, and the thickness direction of the window glass 100 is defined as the Z-axis direction. The X-axis direction, the Y-axis direction and the Z-axis direction are perpendicular to each other. The terms "top", "bottom", and the like, in the present application, refer to the direction toward the positive Y-axis as "top", and the direction toward the negative Y-axis as "bottom", and similar descriptions will be understood hereinafter.
The window glass 100 has a shaded area S1 and a non-shaded area S2. The shielded region S1 and the non-shielded region S2 do not overlap. The shielding region S1 surrounds the non-shielding region S2. The shielding region S1 is connected to the edge of the non-shielding region S2. Wherein the shielding region S1 is for blocking visible light and ultraviolet rays outside the vehicle 1000 from entering the interior of the vehicle 1000. The non-shielded area S2 may be used for light transmission both indoors and outdoors, i.e., as a window of the vehicle 1000.
The shielding region S1 has a haze HS1. The haze HS1 of the shielding region S1 is more than or equal to 10 percent. Further, the haze HS1 of the shielding region S1 is not less than 50%, or HS1 is not less than 80%, or HS1 is not less than 90%. The shielding region S1 has a visible light transmittance TL1.TL1 is less than or equal to 80 percent. Further, TL1 is 10% or less, or TL1 is 5% or less, or TL1 is 1% or less. The shielding region S1 has an ultraviolet transmittance T1 UV,T1UV which is less than or equal to 1%. Further, T1 UV is less than or equal to 0.1 percent.
The non-shielded region S2 has a haze HS2. It is understood that the haze HS2 of the non-shielded region S2 and the haze HS1 of the shielded region S1 may be equal. In some embodiments, the haze HS2 of the non-masked region S2 is less than or equal to 10%. Further, the haze HS2 of the non-shielding region S2 is 5% or less, or HS2 is 2% or less. The non-shielding region S2 has a visible light transmittance TL2.TL2>70%, or TL2 < 30%, or TL2 < 10%. It is understood that when TL2>70%, the window glass 100 is suitable for a front windshield, and when TL2 is less than or equal to 70%, the window glass 100 is suitable for a rear door glass, a rear windshield, or a sunroof of the vehicle 1000. The non-shielding region S2 has an ultraviolet transmittance T2 UV,T2UV +.1%. Further, T2 UV is less than or equal to 0.1 percent.
Further, the ratio of the haze HS1 of the shielding region S1 to the haze HS2 of the non-shielding region S2 is in the range of 4.ltoreq.HS 1/HS 2.ltoreq.48. For example, the ratio of the haze HS1 of the shielding region S1 to the haze HS2 of the non-shielding region S2 is 4, or 8, or 16, or 20, or 24, or 28, or 32, or 36, or 40, or 44, or 48, etc.
In the present embodiment, the front projection of the interior (not shown) and the sheet metal part of the vehicle body 1000 on the window glass 100 is located at least partially in the shielding region S1 along the thickness direction (Z-axis direction) of the window glass 100. The shielding region S1 can shield the junction of the window glass 100 and the vehicle 1000, so that the junction structure between the window glass 100 and the vehicle 1000 cannot be seen from the outside of the vehicle by a viewer, thereby achieving an aesthetic effect.
Referring to fig. 3, the present application provides a first embodiment of a window glass 100. In the present embodiment, the window glass 100 includes the laminated glass 10. By having high haze in part of the laminated glass 10, high haze in the shielded region S1 is achieved.
The laminated glass 10 includes a first glass plate 11, a second glass plate 12, and an interlayer 13, the interlayer 13 being interposed between the first glass plate 11 and the second glass plate 12. The first glass plate 11 comprises a first surface 111 and a second surface 112 arranged facing away from each other. The second surface 112 faces the intermediate layer 13. The second glass sheet 12 includes third and fourth surfaces 121 and 122 disposed opposite thereto. The third surface 121 faces the intermediate layer 13. The intermediate layer 13 connects the second surface 112 and the third surface 121. It is understood that the first glass pane 11 may be closer to the exterior of the vehicle 1000 than the second glass pane 12, and that the first glass pane 11 may also be closer to the interior of the vehicle 1000 than the second glass pane 12. The embodiment of the present application will be described only by taking an example in which the first glass plate 11 can be located closer to the outside of the vehicle 1000 than the second glass plate 12.
For example, the laminated glass 10 may have a specific structure in which the first glass plate 11 is an outer glass plate (a glass plate located outside the vehicle 1000) of the laminated glass 10, and the second glass plate 12 is an inner glass plate (a glass plate located inside the vehicle 1000) of the laminated glass 10. In addition, the laminated glass 10 may be structured such that, when the laminated glass 10 further includes an outer glass plate and an additional one intermediate layer 13, the outer glass plate is bonded to the first surface 111 of the first glass plate 11 through the additional one intermediate layer 13 in the thickness direction of the laminated glass 10, and at this time, the first glass plate 11 and the second glass plate 12 are both inner glass plates (glass plates located inside the vehicle 1000), or when the laminated glass 10 further includes an inner glass plate and an additional one intermediate layer 13, the inner glass plate is bonded to the fourth surface 122 of the second glass plate 12 through the additional one intermediate layer 13 in the thickness direction of the laminated glass 10, and at this time, the first glass plate 11 is an outer glass plate (glass plate located outside the vehicle 1000), and the second glass plate 12 is an inner glass plate (glass plate located inside the vehicle 1000). The embodiment of the present application will be described by taking the first glass plate 11 as an outer glass plate and the second glass plate 12 as an inner glass plate of the laminated glass 10 as examples.
Wherein the outer glass plate is transparent glass or colored glass. The thickness of the outer glass plate is 1.6mm to 6.0mm (inclusive). For example, the thickness of the outer glass sheet may be, but is not limited to, 1.6mm, or 3.2mm, or 4.8mm, or 6.0mm, etc. The visible light transmittance of the outer glass plate is 1% -99% (inclusive). For example, the visible light transmittance of the outer glass sheet may be, but is not limited to, 1%, 2%, or 10%, or 20%, or 30%, or 40%, or 50%, or 60%, or 70%, or 80%, or 90%, or 99%, etc. The outer glass plate may be inorganic glass or organic glass. The material of the outer glass plate may be, but is not limited to, soda lime glass, borosilicate glass, aluminosilicate glass, polymethacrylate, polycarbonate, and the like. Further, the outer glass plate is made of soda lime glass.
The inner glass plate is transparent glass or colored glass. The thickness of the inner glass plate is 0.7 mm-6.0 mm (inclusive). For example, the thickness of the inner glass sheet may be, but is not limited to, 0.7mm, or 1.4mm, or 2.1mm, or 2.8mm, or 3.5mm, or 4.2mm, or 4.9mm, or 5.6mm, or 6.0mm, etc. The visible light transmittance of the inner glass plate is 1% -99% (inclusive). For example, the visible light transmittance of the inner glass sheet may be, but is not limited to, 1%, 2%, or 10%, or 20%, or 30%, or 40%, or 50%, or 60%, or 70%, or 80%, or 90%, or 99%, etc. The inner glass plate can be inorganic glass or organic glass. The material of the inner glass plate may be, but is not limited to, soda lime glass, borosilicate glass, aluminosilicate glass, polymethacrylate, polycarbonate, etc. Further, the inner glass plate is made of soda lime glass.
In this embodiment, the intermediate layer 13 includes at least one adhesive layer 133. The adhesive layer 133 is a transparent thermoplastic polymer film or a colored thermoplastic polymer film. The thickness of the adhesive layer 133 is 0.38mm to 1.52mm (inclusive). For example, the thickness of the adhesive layer 133 may be, but is not limited to, 0.38mm, or 0.76mm, or 1.14mm, or 1.52mm, etc. Further, the thickness of the adhesive layer 133 was 0.76mm. Further, the thickness of the adhesive layer 133 was 0.80mm. The material of the thermoplastic polymer film may be at least one selected from polyvinyl butyral (Polyvinyl Butyral, PVB), polyurethane (PU), ethylene-vinyl acetate Copolymer (EVA), polycarbonate (PC), polymethyl methacrylate (Polymethyl Methacrylate, PMMA), and ionic polymer (SentryGlasPlus, SGP). The adhesive layer 133 can prevent ultraviolet rays from transmitting. The adhesive layer 133 has an ultraviolet transmittance T0 UV,T0UV.ltoreq.1%. For example, T0 UV may be, but is not limited to, 1%, or 0.8%, or 0.6%, or 0.4%, or 0.2%, etc. Further, or T UV is less than or equal to 0.1 percent.
The adhesive layer 133 includes a first portion and a second portion. The first portion of the adhesive layer 133 is disposed circumferentially around the second portion. The first portion is located outside the second portion, and the second portion is located within the first portion. The first portion is disposed around the periphery of the second portion, the first portion completely surrounds the second portion, and the shape of the first portion matches the shape of the laminated glass 10. The first portion is in the shape of an annular frame and surrounds the second portion.
In one possible embodiment, as shown in fig. 3, the intermediate layer 13 has a single-layer structure. The intermediate layer 13 comprises an adhesive layer 133. A first portion of the adhesive layer 133, i.e. the first portion 13a of the intermediate layer 13, and a second portion of the adhesive layer 133, i.e. the second portion 13b of the intermediate layer 13. It will be appreciated that the intermediate layer 13 comprises a first portion 13a and a second portion 13b, the first portion 13a surrounding the second portion 13b, the first portion 13a being connected to an edge of the second portion 13b.
In another possible embodiment, the intermediate layer 13 is a multilayer structure. The intermediate layer 13 includes a plurality of adhesive layers 133. The plurality of adhesive layers 133 are laminated in this order along the thickness direction (Z-axis direction) of the window glass 100. Specifically, the first portions of the plurality of adhesive layers 133 overlap each other, and the first portions of the plurality of adhesive layers 133 are stacked to form the first portion 13a of the intermediate layer 13. The second portions overlap each other, and the second portions of the plurality of adhesive layers 133 are laminated to form the second portion 13b of the intermediate layer 13. It will be appreciated that the intermediate layer 13 comprises a first portion 13a and a second portion 13b, the first portion 13a surrounding the second portion 13b, the first portion 13a being connected to an edge of the second portion 13b.
It should be noted that, the first portion 13a and the second portion 13b of the intermediate layer 13 are only used to divide the entire intermediate layer 13 into regions, and it is not mandatory to define that the first portion 13a and the second portion 13b are relatively independent two units, that is, the first portion 13a and the second portion 13b may be formed integrally or formed by splicing in other manners, which is not limited in the present application.
With continued reference to fig. 3, in this embodiment, the first glass plate 11 includes a third portion 11a and a fourth portion 11b. The third portion 11a is disposed circumferentially around the fourth portion 11b. The third portion 11a is located outside the fourth portion 11b, and the fourth portion 11b is located within the third portion 11 a. The third portion 11a is disposed around the fourth portion 11b, and the third portion 11a completely surrounds the fourth portion 11b. The shape of the third portion 11a matches the shape of the laminated glass 10. The third portion 11a is in the shape of an annular frame, and the third portion 11a surrounds the peripheral side of the fourth portion 11b. The third portion 11a and the fourth portion 11b of the first glass plate 11 are only used for dividing the whole first glass plate 11, but not necessarily limited to the fact that the third portion 11a and the fourth portion 11b need to be relatively independent two units, that is, the third portion 11a and the fourth portion 11b may be integrally formed structures or structures formed by splicing in other manners, which is not limited in the application.
In this embodiment, the second glass sheet 12 includes a fifth portion 12a and a sixth portion 12b. The fifth portion 12a is disposed circumferentially around the sixth portion 12b. The fifth portion 12a is located outside the sixth portion 12b, and the sixth portion 12b is located within the fifth portion 12 a. The fifth portion 12a is disposed around the periphery of the sixth portion 12b, and the fifth portion 12a completely surrounds the sixth portion 12b. The shape of the fifth portion 12a matches the shape of the laminated glass 10. The fifth portion 12a is in the shape of an annular frame, and the fifth portion 12a surrounds the peripheral side of the sixth portion 12b. The fifth portion 12a and the sixth portion 12b of the second glass sheet 12 are only used to divide the whole second glass sheet 12, but it is not mandatory to define that the fifth portion 12a and the sixth portion 12b are two relatively independent units, that is, the fifth portion 12a and the sixth portion 12b may be integrally formed structures or structures formed by splicing in other manners, which is not limited in the present application.
In this embodiment, the first glass plate 11 and the second glass plate 12 are adhesively connected by the interlayer 13. In the thickness direction (Z-axis direction) of the window glass 100, the first portion 13a of the intermediate layer 13, the third portion 11a of the first glass plate 11 and the fifth portion 12a of the second glass plate 12 are completely overlapped, and the second portion 13b of the intermediate layer 13, the fourth portion 11b of the first glass plate 11 and the sixth portion 12b of the second glass plate 12 are completely overlapped. In the thickness direction (Z-axis direction) of the window glass 100, the shielded region S1 is completely overlapped with the first portion 13a of the intermediate layer 13, and the non-shielded region S2 is completely overlapped with the second portion 13b of the intermediate layer 13.
The broken line in fig. 3 is used only for dividing the first portion 13a and the second portion 13b of the intermediate layer 13, dividing the third portion 11a and the fourth portion 11b of the first glass plate 11, and dividing the fifth portion 12a and the sixth portion 12b of the second glass plate 12, and does not limit the specific structure of the laminated glass 10.
With continued reference to fig. 3, in the present embodiment, by providing high haze to a part of the laminated glass 10, it is achieved that the shaded area S1 of the window glass 100 has high haze. The haze of at least one of the first portion 13a of the intermediate layer 13 and the third portion 11a of the first glass plate 11 is greater than or equal to 10%.
In a first possible embodiment, the haze of the first portion 13a of the intermediate layer 13 is greater than or equal to 10%. When the intermediate layer 13 has a single-layer structure, the haze of the first portion of the single adhesive layer 133 is 10% or more. When the intermediate layer 13 has a multilayer structure, the haze of the first portion of the at least one adhesive layer 133 is 10% or more.
In a second possible embodiment, the haze of the third portion 11a of the first glass plate 11 is greater than or equal to 10%.
In a third possible embodiment, the haze of the first portion 13a of the intermediate layer 13 and the third portion 11a of the first glass plate 11 are simultaneously greater than or equal to 10%.
In other embodiments, the haze of the fifth portion 12a of the second glass sheet 12 may also be greater than or equal to 10%.
It will be appreciated that when the haze HS1 of the masked region S1 is greater than the haze HS2 of the non-masked region S2, the haze of the first portion 13a of the intermediate layer 13 is greater than the haze of the second portion 13b and/or the haze of the third portion 11a of the first glass sheet 11 is greater than the haze of the fourth portion 11 b. Illustratively, the ratio of the haze H1 of the third portion 11a to the haze H2 of the fourth portion 11b of the first glass sheet 11 ranges from 25.ltoreq.H2.ltoreq.80. For example, the ratio of the haze H1 of the third portion 11a to the haze H2 of the fourth portion 11b is 25, or 50, or 75, or 80, etc.
The first portion of the adhesive layer 133 may be added with colorant particles, and the first portion of the adhesive layer 133 may be increased in haze by increasing scattering of light by the colorant particles. Illustratively, the first portion of the bond layer 133 includes a matrix and colorant particles uniformly distributed throughout the matrix. Wherein the matrix is PVB, EVA, PU, PC, PMMA or SGP, and the colorant particles are CaCO 3、CaSO4、MgSO4、MgO、ZnSO4 or ZnO.
The third portion 11a of the first glass sheet 11 may be subjected to a surface process treatment to form the third portion 11a of the first glass sheet 11 into frosted glass, thereby increasing the haze of the third portion 11a of the first glass sheet 11. Frosted glass is a glass product that is treated specifically to make the surface of the glass appear hazy, frosted or milky. The surface treatment process comprises an acid etching process, a frosting process, a sand blasting process, a film forming process and the like. The acid etching process is to immerse glass in an acid solution to make the surface of the glass have frosted effect through the corrosion of acid. The polishing process is to mechanically polish the surface of the glass by using a polishing tool (such as a grinding wheel and a grinding wheel) so as to blur the surface of the glass. The sand blasting process is to blast sand particles onto the glass surface using a high pressure air stream, thereby sanding the glass surface. The film forming process is to coat a special semitransparent film or frosted film on the surface of glass to make the glass show frosted glass effect. It will be appreciated that to increase the haze of the fifth portion 12a of the second glass sheet 12, reference may also be made to the surface treatment of the third portion 11a of the first glass sheet 11 described above.
It is to be understood that in the present embodiment, by making the haze of at least one of the first portion 13a of the intermediate layer 13 and the third portion 11a of the first glass plate 11 be 10% or more, the first portion 13a of the intermediate layer 13 and the third portion 11a of the first glass plate 11 fully overlap the shielding region S1, and the second portion 13b of the intermediate layer 13 and the fourth portion 11b of the first glass plate 11 fully overlap the non-shielding region S2, it is possible to make the shielding region S1 of the window glass 100 have a high haze, that is, the haze HS1 of the shielding region S1 is 10% or more. The first glass plate 11 and the second glass plate 12 are bonded by the interlayer 13 after the first glass plate 11 and the second glass plate 12 are subjected to the bending molding process, so that the interlayer 13 does not need to be subjected to high-temperature heat treatment, the optical performance of the interlayer 13 is more stable, and the optical performance of the window glass 100 is more stable.
By making the haze of the third portion 11a of the first glass plate 11 greater than or equal to 10% on the basis of the haze of the first portion 13a of the intermediate layer 13 being greater than or equal to 10%, the haze of the shielding region S1 of the window glass 100 is further increased, and the shielding effect of the shielding region S1 of the window glass 100 is achieved. Therefore, ceramic ink does not need to be printed on the shielding area S1 of the window glass 100 to form a shielding effect, stress applied to the edge position of the window glass 100 in the curing process by the ceramic ink is avoided, the structural strength of the window glass 100 is ensured, the edge position of the window glass 100 is prevented from being easily broken when being impacted by external force, and the safety performance of the window glass 100 is ensured.
In the present application, the haze of at least one of the first portion 13a of the intermediate layer 13 and the third portion 11a of the first glass plate 11 is greater than or equal to 10%, so that the shielding region S1 of the window glass 100 has high haze, and the shielding effect of the shielding region S1 is further achieved, thereby replacing the scheme of providing ceramic ink in the shielding region S1, and ensuring the structural strength of the window glass 100. The shielding region S1 may be provided with no ink layer or may be provided with an ink layer. The proportion of the ink layer in the shielding region S1 to the range of the shielding region S1 is less than or equal to 10%. For example, an ink layer may be provided in the masking zone S1 to mark the window glass 100.
In this embodiment, the window glass 100 may further include the heat insulating layer 20 and the low-emissivity layer 30. The insulating layer 20 is used to adjust the insulating properties of the window glass 100. The low-emissivity layer 30 is used to adjust the emissivity of the glazing 100. The insulating layer 20 and the low-emissivity layer 30 may be provided on the first surface 111, the second surface 112, the third surface 121, or the fourth surface 122 of the laminated glass 10. The heat insulating layer 20 and the low-emissivity layer 30 are respectively located on different surfaces of the laminated glass 10. Illustratively, as in FIG. 3, the insulating layer 20 is laminated to the second surface 112 of the first glass sheet 11. The low emissivity layer 30 is laminated to the fourth surface 122 of the second glass sheet 12. The insulating layer 20 completely covers the non-shielding region S2 in the thickness direction (Z-axis direction) of the window glass 100. The low-emissivity layer 30 completely covers the non-shielding region S2 in the thickness direction (Z-axis direction) of the window glass 100.
In other embodiments, the window glass 100 may not be provided with the insulating layer 20 or the low-emissivity layer 30.
The insulating layer 20 includes a functional metal layer and a plurality of dielectric layers. Along the thickness direction of the heat insulating layer 20, dielectric layers are laminated on opposite sides of the functional metal layer. The number of functional metal layers may be one or more. Both the functional metal layer and the dielectric layer may be deposited by chemical vapor deposition (Chemical Vapor Deposition, CVD) or physical vapor deposition (Physical Vapor Deposition, PVD). Illustratively, the functional metal layer and the dielectric layer are both deposited by magnetron sputtering.
The functional metal layer may be a metal layer or an alloy layer. Illustratively, the material of the functional metal layer may be a metal or a metal alloy of at least one element selected from Ag, au, cu, al, pt. The material of the dielectric layer may be at least one selected from nitrides, oxides and oxynitrides of metals such as Zn, sn, ti, si, al, ni, cr, nb, mg, zr, ga, Y, in, sb, V, ta and alloys thereof.
The emissivity E of the low emissivity layer 30 is less than or equal to 0.3. The low emissivity layer 30 includes at least one dielectric layer. The dielectric layer may be deposited by chemical vapor deposition (Chemical Vapor Deposition, CVD) or physical vapor deposition (Physical Vapor Deposition, PVD) methods. Illustratively, the dielectric layer is deposited by magnetron sputtering.
The material of the dielectric layer may be at least one selected from nitrides, oxides and oxynitrides of metals such as Zn, sn, ti, si, al, ni, cr, nb, mg, zr, ga, Y, in, sb, V, ta and alloys thereof.
Referring to fig. 4, the present application provides a second embodiment of a window glass 100. The distinguishing feature of this embodiment from the first embodiment described above is that the window glass 100 further includes a haze layer. By the haze layer having high haze, high haze of the shielding region S1 is achieved.
In this embodiment, the haze layer is a light modulation film 40. The haze of the light modulation film 40 can be greater than or equal to 10%. Types of dimming films 40 include, but are not limited to, polymer dispersed liquid crystals (Polymer Dispersed Liquid Crystal, PDLC), polymer network liquid crystals (Polymer Network Liquid Crystal, PNLC), guest-host liquid crystals (Guest/Host Liquid Crystal, GHLC), electrochromic (Electrochromic, EC), and the like. The haze of the dimming film 40 has a minimum value and a maximum value. By adjusting the energization voltage of the light modulation film 40, the haze of the light modulation film 40 can be changed. The haze of the light modulation film 40 increases from a minimum value when the light modulation film 40 is energized, the haze of the light modulation film 40 increases with an increase in voltage, the haze of the light modulation film 40 reaches a maximum value when the voltage increases to a critical value, the haze of the light modulation film 40 decreases to a minimum value when the light modulation film 40 is deenergized, or the haze of the light modulation film 40 decreases from a maximum value when the light modulation film 40 is energized, the haze of the light modulation film 40 decreases with an increase in voltage, the haze of the light modulation film 40 reaches a minimum value when the voltage increases to a critical value, and the haze of the light modulation film 40 increases to a maximum value when the light modulation film 40 is deenergized.
It should be noted that the number of the dimming films 40 may be one or more. The embodiment of the present application will be described with reference to only one of the light modulation films 40.
In this embodiment, the intermediate layer 13 has a multilayer structure. The intermediate layer 13 includes a plurality of adhesive layers 133 laminated in order. The thickness, material and structure of the adhesive layer 133 can be described with reference to the adhesive layer 133 in the first embodiment. And will not be described in detail herein.
In this embodiment, a plurality of adhesive layers 133 are laminated in this order along the thickness direction (Z-axis direction) of the window glass 100. The light control film 40 is sandwiched between any two adhesive layers 133 in the thickness direction of the window glass 100. The dimming film 40 completely covers the shielding region S1. It will be appreciated that the dimming film 40 may also cover at least part of the non-shielded region S2.
The number of adhesive layers 133 and the position of the light control film 40 shown in fig. 4 are only for illustration of the structure of the plurality of adhesive layers 133 and the light control film 40, but the number of adhesive layers 133 may be other, and the light control film 40 may be sandwiched between any two other adhesive layers 133, and the number of adhesive layers 133 and the position of the light control film 40 are not limited. In fig. 4, only the light modulation film 40 is illustrated as a case where the shielding region S1 and the non-shielding region S2 are completely covered, and a specific limitation of the coverage of the light modulation film 40 is not formed.
It is to be understood that in the present embodiment, by sandwiching the light control film 40 between any two of the adhesive layers 133 of the intermediate layer 13 and making the light control film 40 entirely cover the shielded region S1, by adjusting the voltage applied to the light control film 40, the haze of the light control film 40 can be adjusted so that the haze of the light control film 40 is 10% or more, and further the shielded region S1 of the window glass 100 can be made to have high haze, that is, the haze HS1 of the shielded region S1 is 10% or more. Therefore, ceramic ink does not need to be printed on the shielding area S1 of the window glass 100 to form a shielding effect, stress applied to the edge position of the window glass 100 in the curing process by the ceramic ink is avoided, the structural strength of the window glass 100 is ensured, the edge position of the window glass 100 is prevented from being easily broken when being impacted by external force, and the safety performance of the window glass 100 is ensured.
In addition, the dimming film 40 covers at least part of the non-shielding region S2, and by adjusting the haze of the dimming film 40, the haze of the non-shielding region S2 of the window glass 100 can also be adjusted, so that the window glass 100 can be suitable for different application scenarios.
The light modulation film 40 is sandwiched between the two adhesive layers 133 after the first glass plate 11 and the second glass plate 12 are subjected to the bending molding process, and thus, the light modulation film 40 does not need to be subjected to a high-temperature heat treatment, and the optical performance of the light modulation film 40 is more stable.
In the present application, the haze layer may be used alone, or the high haze may be provided in the masking region S1 of the window glass 100 by providing the haze layer together with the high haze in a part of the laminated glass 10.
Referring to fig. 5, the present application provides a third embodiment of a window glass 100. The distinguishing feature of this embodiment from the first embodiment described above is that the window glass 100 further includes a haze layer. By the haze layer having high haze, high haze of the shielding region S1 is achieved.
In this embodiment, the haze layer is a functional layer 50. The haze of the functional layer 50 is constant. The haze of the functional layer 50 is greater than or equal to 10%. The functional layer 50 may be a film layer having a function of heat insulation, low radiation, or the like, or may be a film layer having no function of heat insulation, low radiation, or the like. Illustratively, the functional layer 50 is a film layer having a heat insulating or low-emissivity function, and the functional layer 50 achieves a haze of more than or 10% and a heat insulating effect or low-emissivity effect by a film system structure.
The functional layer 50 may be deposited by chemical vapor deposition (Chemical Vapor Deposition, CVD) or physical vapor deposition (Physical Vapor Deposition, PVD).
In the present embodiment, at least one of the first surface 111, the second surface 112, the third surface 121, or the fourth surface 122 of the laminated glass 10 is provided with the functional layer 50. The functional layer 50 completely covers the shielding region S1. It will be appreciated that the functional layer 50 may also cover at least part of the non-shielded region S2.
In fig. 5, only the case where one functional layer 50 is provided on the fourth surface 122 of the laminated glass 10 and the functional layer 50 completely covers the shielded region S1 and the non-shielded region S2 is illustrated, and the position and coverage of the functional layer 50 are not particularly limited.
It is to be understood that in the present embodiment, by providing the functional layer 50 with the functional layer 50 entirely covering the shielded region S1, the haze of the functional layer 50 is 10% or more, the shielded region S1 of the window glass 100 can be made to have high haze, that is, the haze HS1 of the shielded region S1 is 10% or more. Therefore, ceramic ink does not need to be printed on the shielding area S1 of the window glass 100 to form a shielding effect, stress applied to the edge position of the window glass 100 in the curing process by the ceramic ink is avoided, the structural strength of the window glass 100 is ensured, the edge position of the window glass 100 is prevented from being easily broken when being impacted by external force, and the safety performance of the window glass 100 is ensured.
In addition, the functional layer 50 can also have a heat insulating or low-radiation effect, and can also realize a heat insulating or low-radiation effect of the shielding region S1 while realizing a high haze of the shielding region S1 of the window glass 100. Particularly when the functional layer 50 covers at least part of the non-shielded region S2, a thermal insulation or low radiation effect of the non-shielded region S2 can also be achieved.
Even if the functional layer 50 is thin, and the functional layer 50 is attached to the first glass plate 11 or the second glass plate 12 and is processed by a bending process along with the glass plates, the functional layer 50 is insufficient to apply stress to the edge positions of the glass plates, so that the structural strength of the edge positions of the glass plates is reduced.
In the present application, the haze layer may be used alone, or the high haze may be provided in the masking region S1 of the window glass 100 by providing the haze layer together with the high haze in a part of the laminated glass 10.
The following describes specific examples of the window glass 100 of different structures.
Example 1:
the first glass plate 11 and the second glass plate 12 are each green glass having a thickness of 2.1 mm. The third portion 11a and the fourth portion 11b of the first glass plate 11 have equal haze. The haze of the fifth portion 12a and the sixth portion 12b of the second glass sheet 12 are equal. The intermediate layer 13 has a single-layer structure. The haze of the first portion 13a of the intermediate layer 13 is greater than 10%. The visible light transmittance of the second portion 13b of the intermediate layer 13 is 90%.
Example 2:
The window glass 100 of example 2 differs from the window glass 100 of example 1 in that the first glass plate 11 and the second glass plate 12 are each a dark glass having a thickness of 2.1 mm.
Example 3:
The window glass 100 of example 3 differs from the window glass 100 of example 1 in that the first glass plate 11 and the second glass plate 12 are each transparent glass having a thickness of 2.1 mm. The second surface 112 of the first glass pane 11 is provided with a thermal insulation layer 20.
Example 4:
the window glass 100 of example 4 differs from the window glass 100 of example 3 in that the fourth surface 122 of the second glass pane 12 is provided with the low-emissivity layer 30. The visible light transmittance of the second portion 13b of the intermediate layer 13 was 8%.
Example 5:
The window glass 100 of example 5 differs from the window glass 100 of example 4 in that the visible light transmittance of the second portion 13b of the intermediate layer 13 is 6%.
Example 6:
The window glass 100 of example 6 differs from the window glass 100 of example 5 in that the visible light transmittance of the second portion 13b of the intermediate layer 13 is 2%.
Example 7:
The window glass 100 of example 7 is identical in structure to the window glass 100 of example 1, except that the surface of the third portion 11a of the first glass plate 11 is subjected to a frosting process. The haze of the third portion 11a of the first glass plate 11 is greater than 10%. The haze of the first portion 13a of the intermediate layer 13 is equal to the haze of the second portion 13 b.
Example 8:
the window glass 100 of example 8 is identical in structure to the window glass 100 of example 2, except that the surface of the third portion 11a of the first glass plate 11 is subjected to a frosting process. The haze of the third portion 11a of the first glass plate 11 is greater than 10%. The haze of the first portion 13a of the intermediate layer 13 is equal to the haze of the second portion 13 b.
Example 9:
The window glass 100 of example 9 is identical in structure to the window glass 100 of example 3, except that the surface of the third portion 11a of the first glass plate 11 is subjected to a frosting process. The haze of the third portion 11a of the first glass plate 11 is greater than 10%. The haze of the first portion 13a of the intermediate layer 13 is equal to the haze of the second portion 13 b.
Example 10:
The window glass 100 of example 10 is identical in structure to the window glass 100 of example 4, except that the surface of the third portion 11a of the first glass plate 11 is subjected to a frosting process. The haze of the third portion 11a of the first glass plate 11 is greater than 10%. The haze of the first portion 13a of the intermediate layer 13 is equal to the haze of the second portion 13 b.
Example 11:
The window glass 100 of example 11 is identical in structure to the window glass 100 of example 5, except that the surface of the third portion 11a of the first glass plate 11 is subjected to a frosting process. The haze of the third portion 11a of the first glass plate 11 is greater than 10%. The haze of the first portion 13a of the intermediate layer 13 is equal to the haze of the second portion 13 b.
Example 12:
the window glass 100 of example 12 is identical in structure to the window glass 100 of example 6, except that the surface of the third portion 11a of the first glass plate 11 is subjected to a frosting process. The haze of the third portion 11a of the first glass plate 11 is greater than 10%. The haze of the first portion 13a of the intermediate layer 13 is equal to the haze of the second portion 13 b.
Example 13:
The window glass 100 of example 13 is identical in structure to the window glass 100 of example 1. The only difference is that the intermediate layer 13 has a multi-layer structure. Wherein the light modulation film 40 is sandwiched between two adhesive layers 133. The light modulation film 40 is in the power-off state, and the haze of the light modulation film 40 is greater than 10%.
In this example, haze of the intermediate layer 13 was measured in accordance with JIS R3212 using a spectrophotometer (company: PERKINELMER, model: LAMBDA 950). Haze of the first glass plate 11 and the second glass plate 12 was measured according to standard GB/T2410 using a spectrophotometer (company: PERKINELMER, model: LAMBDA 950). The haze and visible light transmittance of the masked region S1 and the haze and visible light transmittance of the non-masked region S2 of the window glass 100 were measured using a spectrophotometer (company: PERKINELMER, model: LAMBDA 950) according to the standard GB/T2410.
TABLE 1 parameters of the masked and unmasked regions S1 and S2 of the window glass 100 of examples 1-13
Example |
HS1 |
HS2 |
TL1 |
TL2 |
Example 1 |
80.2% |
1.5% |
5.0% |
78.5% |
Example 2 |
81.5% |
1.8% |
3.6% |
16.5% |
Example 3 |
83.0% |
2.0% |
5.7% |
77.2% |
Example 4 |
85.2% |
5.3% |
4.4% |
7.3% |
Example 5 |
86.1% |
5.5% |
2.3% |
4.5% |
Example 6 |
87.2% |
5.5% |
0.5% |
1.6% |
Example 7 |
80.2% |
1.5% |
4.8% |
78.5% |
Example 8 |
91.3% |
1.8% |
3.5% |
16.5% |
Example 9 |
65.2% |
2.0% |
5.5% |
77.2% |
Example 10 |
70.0% |
5.3% |
4.6% |
7.3% |
Example 11 |
71.2% |
5.5% |
2.5% |
4.5% |
Example 12 |
72.3% |
5.5% |
0.5% |
1.6% |
Example 13 |
85.0% |
1.2% |
62.0% |
73.5% |
As can be seen from table 1, the haze HS1 of the masked areas S1 of the window glasses 100 of examples 1 to 6 is all greater than 80%, and the visible light transmittance TL1 of the masked areas S1 is all less than 6%. Thus, the shielding region S1 of the window glass 100 of examples 1 to 6 can each have a good effect of blocking the transmission of visible light. Wherein, haze HS2 of non-shielded region S2 of window glass 100 of examples 1 and 3 is less than 2%, and visible light transmittance TL2 of non-shielded region S2 is greater than 77%. Thus, the non-shielded region S2 of the window glass 100 of examples 1 and 3 can be used as a window, and the window glass 100 of examples 1 and 3 is suitable for a windshield of the vehicle 1000. The haze HS2 of the non-shielded region S2 of the window glass 100 of examples 2 and examples 4 to 6 is less than 6%, and the visible light transmittance TL2 of the non-shielded region S2 is less than 17%. Thus, the non-shielded region S2 of examples 2 and examples 4 to 6 can function as a barrier to the line of sight, and the window glass 100 of examples 2 and examples 4 to 6 is suitable for a backlight or sunroof glass of the vehicle 1000. By making the haze of the first portion 13a of the intermediate layer 13 larger than 10%, the shielded region S1 of the window glass 100 can be made to have high haze. The shielding region S1 of the window glass 100 has a good shielding effect.
Further, the haze HS1 of the shielding regions S1 of the window glasses 100 of examples 7 to 12 is larger than 65%, and the visible light transmittance TL1 of the shielding regions S1 is smaller than 6%. Thus, the shielding region S1 of the window glass 100 of examples 7 to 12 can each exert a good effect of blocking the transmission of visible light. Wherein, haze HS2 of non-shielded regions S2 of window glass 100 of examples 7 and 9 is less than 2%, and visible light transmittance TL2 of non-shielded regions S2 is greater than 77%. Thus, the non-shielded region S2 of the window glass 100 of examples 7 and 9 can be used as a window, and the window glass 100 of examples 7 and 9 is suitable for a windshield of the vehicle 1000. The haze HS2 of the non-shielded regions S2 of the window glasses 100 of examples 8 and examples 10 to 12 is less than 6%, and the visible light transmittance TL2 of the non-shielded regions S2 is less than 17%. Thus, the non-shielded region S2 of examples 8 and examples 10 to 12 can function as a barrier to the line of sight, and the window glass 100 of examples 8 and examples 10 to 12 is suitable for a backlight or sunroof glass of the vehicle 1000. By making the haze of the first portion 11a of the first glass plate 11 larger than 10%, the shielded region S1 of the window glass 100 can be made to have high haze. The shielding region S1 of the window glass 100 has a good shielding effect.
Since the haze HS1 of the shielding region S1 of the window glass 100 of example 13 is 85% and the visible light transmittance TL1 of the shielding region S1 is 62%, the shielding region S1 of the window glass 100 of example 13 has high haze on the basis of ensuring a constant visible light transmittance, and can provide a good shielding effect. The haze HS2 of the non-shielded region S2 of the window glass 100 of example 13 is 1.2%, and the visible light transmittance TL2 of the non-shielded region S2 is 73.5%, and thus the non-shielded region S2 of the window glass 100 of example 13 can be used as a window, and the window glass 100 of example 13 is suitable for a windshield of the vehicle 1000.
The foregoing has outlined rather broadly the more detailed description of embodiments of the application, wherein the principles and embodiments of the application are explained in detail using specific examples, the above examples being provided solely to facilitate the understanding of the method and core concepts of the application; meanwhile, as those skilled in the art will have variations in the specific embodiments and application scope in accordance with the ideas of the present application, the present description should not be construed as limiting the present application in view of the above.