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CN118896492A - A transmission device and a carbonization system - Google Patents

A transmission device and a carbonization system Download PDF

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Publication number
CN118896492A
CN118896492A CN202410935859.5A CN202410935859A CN118896492A CN 118896492 A CN118896492 A CN 118896492A CN 202410935859 A CN202410935859 A CN 202410935859A CN 118896492 A CN118896492 A CN 118896492A
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CN
China
Prior art keywords
guide rail
carbon paper
carbonization
working area
pressing plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202410935859.5A
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Chinese (zh)
Inventor
请求不公布姓名
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Guoke Lingxian New Materials Changzhou Co ltd
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Guoke Lingxian New Materials Changzhou Co ltd
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Application filed by Guoke Lingxian New Materials Changzhou Co ltd filed Critical Guoke Lingxian New Materials Changzhou Co ltd
Priority to CN202410935859.5A priority Critical patent/CN118896492A/en
Publication of CN118896492A publication Critical patent/CN118896492A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H18/00Winding webs
    • B65H18/08Web-winding mechanisms
    • B65H18/10Mechanisms in which power is applied to web-roll spindle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H23/00Registering, tensioning, smoothing or guiding webs
    • B65H23/04Registering, tensioning, smoothing or guiding webs longitudinally
    • B65H23/26Registering, tensioning, smoothing or guiding webs longitudinally by transverse stationary or adjustable bars or rollers
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/05Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/14Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment
    • F27B9/20Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a substantially straight path
    • F27B9/24Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a substantially straight path being carried by a conveyor
    • F27B9/2407Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a substantially straight path being carried by a conveyor the conveyor being constituted by rollers (roller hearth furnace)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/30Details, accessories or equipment specially adapted for furnaces of these types
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D2003/0034Means for moving, conveying, transporting the charge in the furnace or in the charging facilities
    • F27D2003/0067Means for moving, conveying, transporting the charge in the furnace or in the charging facilities comprising conveyors where the translation is communicated by friction from at least one rotating element, e.g. two opposed rotations combined

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The invention discloses a conveying device and a carbonization system, wherein the conveying device is used for conveying carbon paper to be carbonized through a carbonization furnace for carbonization and comprises the following components: the first guide rail and the second guide rail are oppositely arranged in the horizontal direction, and at least one section of the first guide rail and at least one section of the second guide rail are positioned in the carbonization furnace; a stretching structure including a sliding portion and a connecting portion; the first guide rail and the second guide rail are respectively connected with a stretching structure in sliding fit with the first guide rail and the second guide rail, wherein a plurality of sliding parts are respectively in sliding fit with the first guide rail and the second guide rail, and the connecting parts are used for being fixedly connected to two sides of the width of the carbon paper; in the width direction of the carbon paper in the carbonization process, the stretching structure provides tension for the carbon paper to inhibit the carbon paper from shrinking under heating. According to the carbonization residence time and the temperature interval, the interval between the guide rails at two sides is regulated and controlled to control the tension of the carbon paper material in the width direction, so that the shrinkage deformation of the material caused by the thermal effect in the high-temperature carbonization process is effectively reduced.

Description

一种传输装置和碳化系统A transmission device and a carbonization system

技术领域Technical Field

本发明涉及高温碳化技术领域,更具体地,涉及一种传输装置和碳化系统。The present invention relates to the technical field of high-temperature carbonization, and more specifically, to a transmission device and a carbonization system.

背景技术Background Art

碳纸是燃料电池膜电极的关键核心材料,而卷材碳纸在进行高温碳化的过程中,在碳纸幅宽方向上无法提供有效张力,如果任由碳纸自由收缩,其纸面可能会出现褶皱、变形、甚至开裂情况,很难完成连续碳化制备;碳纸中碳链结构断裂,进而会影响材料石墨化程度,最终会导致碳纸的导电性及力学强度下降。作为气体扩散层的基材,碳纸性能下降必然会影响膜电极的发电效率及寿命,甚至会使燃料电池电堆结构遭到不可逆的损坏。Carbon paper is the key core material of fuel cell membrane electrode. However, during the high-temperature carbonization process, the rolled carbon paper cannot provide effective tension in the width direction of the carbon paper. If the carbon paper is allowed to shrink freely, the paper surface may become wrinkled, deformed, or even cracked, making it difficult to complete continuous carbonization preparation. The carbon chain structure in the carbon paper is broken, which will affect the degree of graphitization of the material, and ultimately lead to a decrease in the conductivity and mechanical strength of the carbon paper. As the substrate of the gas diffusion layer, the performance degradation of carbon paper will inevitably affect the power generation efficiency and life of the membrane electrode, and may even cause irreversible damage to the fuel cell stack structure.

因此,如何提供一种能够有效控制碳纸材料在幅宽方向自由收缩的传输装置和碳化系统成为本领域亟需解决的技术难题。Therefore, how to provide a transmission device and a carbonization system that can effectively control the free shrinkage of carbon paper materials in the width direction has become a technical problem that urgently needs to be solved in this field.

发明内容Summary of the invention

本发明的目的是提供一种能够有效控制碳纸材料在幅宽方向自由收缩的传输装置和碳化系统。The object of the present invention is to provide a transmission device and a carbonization system which can effectively control the free shrinkage of carbon paper material in the width direction.

本发明第一方面提供了一种传输装置,用于将待碳化的碳纸输送通过碳化炉碳化,包括:A first aspect of the present invention provides a transmission device for conveying carbon paper to be carbonized through a carbonization furnace for carbonization, comprising:

在水平方向上相对设置的第一导轨和第二导轨,第一导轨和第二导轨的至少一段位于碳化炉内;A first guide rail and a second guide rail are arranged opposite to each other in a horizontal direction, and at least one section of the first guide rail and the second guide rail is located in the carbonization furnace;

拉伸结构,拉伸结构包括滑动部和连接部;第一导轨和第二导轨分别连接有与之滑动配合的拉伸结构,其中,多个滑动部分别与第一导轨和第二导轨滑动配合,连接部用于固定连接在碳纸的宽度两侧;The stretching structure includes a sliding part and a connecting part; the first guide rail and the second guide rail are respectively connected with the stretching structure slidably matched therewith, wherein the plurality of sliding parts are respectively slidably matched with the first guide rail and the second guide rail, and the connecting part is used to be fixedly connected to both sides of the width of the carbon paper;

碳化过程中在碳纸的宽度方向上,拉伸结构为碳纸提供张力以抑制碳纸受热收缩。During the carbonization process, the tensile structure provides tension to the carbon paper in the width direction of the carbon paper to inhibit the carbon paper from shrinking due to heat.

可选地,在传输方向上,第一导轨和第二导轨之间的间距以预设规则变化。Optionally, in the transport direction, the spacing between the first guide rail and the second guide rail changes according to a preset rule.

可选地,在传输方向上至少包括依次设置的第一作业区、第二作业区、第三作业区和第四作业区;Optionally, in the transmission direction, at least a first operation area, a second operation area, a third operation area and a fourth operation area are sequentially arranged;

在第一作业区的入口,第一导轨和第二导轨之间的间距为D1;At the entrance of the first working area, the distance between the first guide rail and the second guide rail is D1;

在第二作业区的入口,第一导轨和第二导轨之间的间距为D2;At the entrance of the second working area, the distance between the first guide rail and the second guide rail is D2;

在第三作业区的入口,第一导轨和第二导轨之间的间距为D3;At the entrance of the third working area, the distance between the first guide rail and the second guide rail is D3;

在第四作业区的入口,第一导轨和第二导轨之间的间距为D4;At the entrance of the fourth operating area, the distance between the first guide rail and the second guide rail is D4;

在第四作业区的出口,第一导轨和第二导轨之间的间距为D5;At the exit of the fourth operating area, the distance between the first guide rail and the second guide rail is D5;

其中,D1=D2、D2>D3、D3=D4、D4≤D5;和/或D1:D2:D3:D4:Wherein, D1=D2, D2>D3, D3=D4, D4≤D5; and/or D1:D2:D3:D4:

D5=1:1:0.95~0.99:0.95~0.99:0.95~0.99。D5=1: 1: 0.95~0.99: 0.95~0.99: 0.95~0.99.

可选地,第一作业区的长度:第二作业区的长度:第三作业区的长度:第四作业区长度=1:3:2.5:1.5;Optionally, the length of the first working area: the length of the second working area: the length of the third working area: the length of the fourth working area = 1:3:2.5:1.5;

和/或,第一作业区的工作温度为200℃~260℃;第二作业区的工作温度为450℃~720℃;第三作业区的工作温度为900℃~1600℃;第四作业区的工作温度为室温。And/or, the working temperature of the first working area is 200°C to 260°C; the working temperature of the second working area is 450°C to 720°C; the working temperature of the third working area is 900°C to 1600°C; and the working temperature of the fourth working area is room temperature.

可选地,在输送方向上,多个拉伸结构分别在第一导轨和第二导轨上交错设置。Optionally, in the conveying direction, a plurality of stretching structures are staggeredly arranged on the first guide rail and the second guide rail, respectively.

可选地,设置在第一导轨上的多个拉伸结构等间距分布;Optionally, the plurality of tensile structures disposed on the first guide rail are distributed at equal intervals;

和/或设置在第二导轨上的多个拉伸结构等间距分布。And/or the multiple tensile structures arranged on the second guide rail are distributed at equal intervals.

可选地,第一导轨和第二导轨相对的一侧分别设置有沿其延伸方向设置的滑槽,两道滑槽的截面为圆形,且两道滑槽的开口相对;Optionally, one side of the first guide rail and the other side of the second guide rail are respectively provided with a slide groove arranged along the extension direction thereof, the cross-sections of the two slide grooves are circular, and the openings of the two slide grooves are opposite to each other;

滑动部为球头,球头滑动安装于滑槽内,第一导轨和第二导轨在朝向二者中心处的方向限位阻挡球头。The sliding part is a ball head, which is slidably installed in the slide groove, and the first guide rail and the second guide rail limit and block the ball head in the direction toward the center of the first guide rail and the second guide rail.

可选地,连接部包括第一压板和第二压板,第一压板靠近滑槽的一侧连接有球头,两个球头沿滑槽的延伸方向依次设置;第一压板和第二压板相对设置以形成夹持位,碳纸的边缘被第一压板和第二压板夹持。Optionally, the connecting part includes a first pressing plate and a second pressing plate, a ball head is connected to the side of the first pressing plate close to the slide groove, and the two ball heads are arranged in sequence along the extension direction of the slide groove; the first pressing plate and the second pressing plate are arranged relative to each other to form a clamping position, and the edge of the carbon paper is clamped by the first pressing plate and the second pressing plate.

可选地,碳化炉前后两侧分别设置有前传动机构和后传动机构;Optionally, a front transmission mechanism and a rear transmission mechanism are respectively provided on the front and rear sides of the carbonization furnace;

前传动机构和后传动机构各自包括相对设置的两个驱动辊,碳纸从相对设置的两个驱动辊之间狭缝穿过,碳纸被相对设置的两个驱动辊夹持,驱动辊转动时,摩擦力作用下碳纸沿输送方向前行。本发明第二方面提供了一种碳化系统,包括碳化炉和本发明第一方面中任一项的传输装置,传输装置用于将碳纸输送通过碳化炉碳化。The front transmission mechanism and the rear transmission mechanism each include two drive rollers arranged opposite to each other, the carbon paper passes through the slit between the two drive rollers arranged opposite to each other, the carbon paper is clamped by the two drive rollers arranged opposite to each other, and when the drive rollers rotate, the carbon paper moves forward along the conveying direction under the action of friction. The second aspect of the present invention provides a carbonization system, including a carbonization furnace and a transmission device according to any one of the first aspects of the present invention, the transmission device being used to convey the carbon paper through the carbonization furnace for carbonization.

根据本发明公开的技术内容,具有如下有益效果:According to the technical content disclosed in the present invention, the following beneficial effects are achieved:

使用本发明提供的传输装置进行碳化时,将连接部固定连接在碳纸的宽度两侧,碳纸随拉伸结构进入碳化炉内碳化时,碳纸受热产生在幅宽方向上的热收缩,此时由于拉伸结构的另一端连接在第一导轨和第二导轨上,使拉伸结构在碳纸的幅宽两侧拉紧碳纸,确保碳化过程中在碳纸的宽度方向上,拉伸结构为碳纸提供张力以抑制多少碳纸受热收缩。When the transmission device provided by the present invention is used for carbonization, the connecting parts are fixedly connected to both sides of the width of the carbon paper. When the carbon paper enters the carbonization furnace for carbonization along with the stretching structure, the carbon paper is heated and produces thermal contraction in the width direction. At this time, since the other end of the stretching structure is connected to the first guide rail and the second guide rail, the stretching structure tightens the carbon paper on both sides of the width of the carbon paper, ensuring that the stretching structure provides tension for the carbon paper in the width direction of the carbon paper during the carbonization process to suppress the thermal contraction of the carbon paper.

通过以下参照附图对本发明的示例性实施例的详细描述,本发明的其它特征及其优点将会变得清楚。Further features and advantages of the present invention will become apparent from the following detailed description of exemplary embodiments of the present invention with reference to the attached drawings.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

被结合在说明书中并构成说明书的一部分的附图示出了本发明的实施例,并且连同其说明一起用于解释本发明的原理。The accompanying drawings, which are incorporated in and constitute a part of the specification, illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.

图1为本发明的碳化系统结构示意图。FIG1 is a schematic structural diagram of a carbonization system of the present invention.

图2为本发明的传输装置结构示意图。FIG. 2 is a schematic diagram of the structure of the transmission device of the present invention.

图3为本发明的拉伸结构结构示意图。FIG. 3 is a schematic diagram of the tensile structure of the present invention.

图4为本发明的拉伸结构结构截面示意图。FIG. 4 is a schematic cross-sectional view of the tensile structure of the present invention.

图5为本发明的拉伸结构安装示意图。FIG. 5 is a schematic diagram of the installation of the tensile structure of the present invention.

图6为本发明的导轨结构示意图。FIG. 6 is a schematic diagram of the guide rail structure of the present invention.

附图标记说明:11、预热区;12、整型区;13、碳化区;14、冷却区;101、第一导轨;102、第二导轨;2、拉伸结构;201、第二压板;202、球头;203、螺栓;204、柔性毡;205、润滑粉;206、第一压板;3、碳纸;4、放卷机构;51、前传动机构;52、后传动机构;6、收卷机构;7、碳化炉;71、前气封装置;72、后气封装置;73、前进气口;74、后进气口;75、排气口。Explanation of the reference numerals: 11. preheating zone; 12. shaping zone; 13. carbonization zone; 14. cooling zone; 101. first guide rail; 102. second guide rail; 2. stretching structure; 201. second pressure plate; 202. ball head; 203. bolt; 204. flexible felt; 205. lubricating powder; 206. first pressure plate; 3. carbon paper; 4. unwinding mechanism; 51. front transmission mechanism; 52. rear transmission mechanism; 6. winding mechanism; 7. carbonization furnace; 71. front air sealing device; 72. rear air sealing device; 73. front air inlet; 74. rear air inlet; 75. exhaust port.

具体实施方式DETAILED DESCRIPTION

现在将参照附图来详细描述本发明的各种示例性实施例。应注意到:除非另外具体说明,否则在这些实施例中阐述的部件和步骤的相对布置、数字表达式和数值不限制本发明的范围。Various exemplary embodiments of the present invention will now be described in detail with reference to the accompanying drawings. It should be noted that the relative arrangement of components and steps, numerical expressions and numerical values set forth in these embodiments do not limit the scope of the present invention unless otherwise specifically stated.

以下对至少一个示例性实施例的描述实际上仅仅是说明性的,决不作为对本发明及其应用或使用的任何限制。The following description of at least one exemplary embodiment is merely illustrative in nature and is in no way intended to limit the invention, its application, or uses.

对于相关领域普通技术人员已知的技术、方法和设备可能不作详细讨论,但在适当情况下,技术、方法和设备应当被视为说明书的一部分。Technologies, methods, and equipment known to ordinary technicians in the relevant art may not be discussed in detail, but where appropriate, the technologies, methods, and equipment should be considered part of the specification.

在这里示出和讨论的所有例子中,任何具体值应被解释为仅仅是示例性的,而不是作为限制。因此,示例性实施例的其它例子可以具有不同的值。In all examples shown and discussed herein, any specific values should be interpreted as merely exemplary and not limiting. Therefore, other examples of the exemplary embodiments may have different values.

应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步讨论。It should be noted that like reference numerals and letters refer to similar items in the following figures, and therefore, once an item is defined in one figure, it need not be further discussed in subsequent figures.

参见图1,本发明公开了一种碳化系统,包括碳化炉7和制作材料均为高密度石墨的传输装置,传输装置用于将碳纸3输送通过碳化炉7碳化。Referring to FIG. 1 , the present invention discloses a carbonization system, including a carbonization furnace 7 and a transmission device made of high-density graphite. The transmission device is used to transport the carbon paper 3 through the carbonization furnace 7 for carbonization.

结合图1和图2,传输装置包括第一导轨101、第二导轨102、拉伸结构2、放卷机构4、前传动机构51、后传动机构52和收卷机构6。其中,第一导轨101和第二导轨102在水平方向上相对设置,第一导轨101和第二导轨102的至少一段位于碳化炉内;在本实施例中,整个传输装置固定于碳化炉7的炉体内,即第一导轨101和第二导轨102分别在碳化炉的炉腔内部两侧固定并保持水平。1 and 2, the transmission device includes a first guide rail 101, a second guide rail 102, a stretching structure 2, an unwinding mechanism 4, a front transmission mechanism 51, a rear transmission mechanism 52 and a rewinding mechanism 6. The first guide rail 101 and the second guide rail 102 are arranged opposite to each other in the horizontal direction, and at least one section of the first guide rail 101 and the second guide rail 102 is located in the carbonization furnace; in this embodiment, the entire transmission device is fixed in the furnace body of the carbonization furnace 7, that is, the first guide rail 101 and the second guide rail 102 are respectively fixed on both sides of the furnace chamber of the carbonization furnace and kept horizontal.

再结合图3至图6,拉伸结构2包括滑动部和连接部;第一导轨101和第二导轨102分别连接有与之滑动配合的拉伸结构2,其中,多个滑动部分别与第一导轨101和第二导轨102滑动配合,连接部用于固定连接在碳纸的宽度两侧以固定碳纸,使碳纸3可随拉伸结构2同步向前滑行通过碳化炉7的炉体进行高温碳化,碳化过程中在碳纸3的宽度方向上,拉伸结构2为碳纸3提供自由收缩方向的相反方向的张力以抑制碳纸3受热收缩。设置在第一导轨101上的多个拉伸结构2等间距分布以及设置在第二导轨102上的多个拉伸结构2等间距分布,使滑动过程中碳纸3受力更加均匀。进一步地,再结合图6,在输送方向上,多个拉伸结构2分别在第一导轨101和第二导轨102上交错设置,这样设置有利于碳纸3边缘连接处应力释放,保证碳纸3在热分解过程中张力稳定。In conjunction with Figures 3 to 6, the stretching structure 2 includes a sliding portion and a connecting portion; the first guide rail 101 and the second guide rail 102 are respectively connected with the stretching structure 2 that slides therewith, wherein the plurality of sliding portions slides with the first guide rail 101 and the second guide rail 102, respectively, and the connecting portion is used to be fixedly connected to both sides of the width of the carbon paper to fix the carbon paper, so that the carbon paper 3 can slide forward synchronously with the stretching structure 2 through the furnace body of the carbonization furnace 7 for high-temperature carbonization. During the carbonization process, in the width direction of the carbon paper 3, the stretching structure 2 provides the carbon paper 3 with tension in the opposite direction of the free shrinkage direction to inhibit the carbon paper 3 from shrinking due to heat. The plurality of stretching structures 2 arranged on the first guide rail 101 are evenly spaced and the plurality of stretching structures 2 arranged on the second guide rail 102 are evenly spaced, so that the force on the carbon paper 3 during the sliding process is more uniform. Further, in conjunction with Figure 6, in the conveying direction, the plurality of stretching structures 2 are staggeredly arranged on the first guide rail 101 and the second guide rail 102, respectively, so that the arrangement is conducive to the stress release at the edge connection of the carbon paper 3 and ensures the stability of the tension of the carbon paper 3 during the thermal decomposition process.

在碳化炉7前侧配备放卷机构4、前传动机构51,在碳化炉7的后侧配备后传动机构52和收卷机构6。传输装置的输送方向为从放卷机构4至收卷机构6的方向,碳纸3的长度两侧分别卷绕在放卷机构4和收卷机构6的外周,前传动机构51和后传动机构52之间的碳纸3在其长度方向上处于涨紧状态,在前传动机构51和后传动机构52的驱动作用下,碳纸3输送方向前进,放卷机构4同步放卷、收卷机构6同步收卷。前传动机构51和后传动机构52均包括设置在碳纸3上下两侧的驱动辊,相对设置在碳纸3上下两侧的驱动辊夹持碳纸3,碳纸3从相对设置的两个驱动辊之间狭缝穿过,驱动辊转动时,摩擦力作用下碳纸3沿输送方向前行。The unwinding mechanism 4 and the front transmission mechanism 51 are provided at the front side of the carbonization furnace 7, and the rear transmission mechanism 52 and the winding mechanism 6 are provided at the rear side of the carbonization furnace 7. The conveying direction of the transmission device is from the unwinding mechanism 4 to the winding mechanism 6. The two sides of the length of the carbon paper 3 are respectively wound on the outer periphery of the unwinding mechanism 4 and the winding mechanism 6. The carbon paper 3 between the front transmission mechanism 51 and the rear transmission mechanism 52 is in a tensioned state in the length direction. Under the driving action of the front transmission mechanism 51 and the rear transmission mechanism 52, the carbon paper 3 moves forward in the conveying direction, and the unwinding mechanism 4 unwinds synchronously, and the winding mechanism 6 winds synchronously. The front transmission mechanism 51 and the rear transmission mechanism 52 both include driving rollers arranged on the upper and lower sides of the carbon paper 3. The driving rollers arranged on the upper and lower sides of the carbon paper 3 clamp the carbon paper 3. The carbon paper 3 passes through the slit between the two driving rollers arranged oppositely. When the driving rollers rotate, the carbon paper 3 moves forward along the conveying direction under the action of friction.

碳化炉7的炉腔前、后端分别配备有前气封装置71和后气封装置72,前气封装置71的底部设置有前进气口73,后气封装置72的底部设置有后进气口74,通过前进气口73和后进气口74向炉腔内持续通入氮气,并保持腔体内微正压,有效减少高温下氧气对碳纸3的氧化分解。The front and rear ends of the furnace chamber of the carbonization furnace 7 are respectively equipped with a front air sealing device 71 and a rear air sealing device 72. A front air inlet 73 is provided at the bottom of the front air sealing device 71, and a rear air inlet 74 is provided at the bottom of the rear air sealing device 72. Nitrogen is continuously introduced into the furnace chamber through the front air inlet 73 and the rear air inlet 74, and a slight positive pressure is maintained in the chamber, thereby effectively reducing the oxidation and decomposition of the carbon paper 3 by oxygen at high temperature.

碳化炉7的炉腔内包括从入口至出口依次排列的第一作业区、第二作业区、第三作业区和第四作业区;其中,第一作业区为预热区11,第二作业区为整型区12,第三作业区为碳化区13,第四作业区为冷却区14。其中各段区域长度符合如下关系,预热区11长度:整型区12长度:碳化区13长度:冷却区14长度=1:3:2.5:1.5。由于碳纸在个区间内匀速运行,所以各区域长度也对应碳纸在各自温区的停留时间。其中每段区域应设置温度范围如下:预热区11温度:200℃~260℃;整型区12温度:450℃~720℃;碳化区13:900℃~1600℃;冷却区14无加热,自然冷却降温。碳纸连续通过各段区域,在不同的温区停留时间有所差异。预热区11温度为200℃~260℃,此过程碳纸无明显变化,可适当缩短其停留时间。整型区12温度为450℃~720℃,此过程中树脂热解过程剧烈,碳纸收缩明显,应有效延长停留时间,可以使热解反应过程更加充分,有利于碳纸表面平整,减少褶皱。而碳化区13温度为900℃~1600℃,此过程主要完成树脂炭的形成,类石墨结构逐步形成,停留时间不宜过短。而冷却区14主要完成高温至常温的降温过程,停留时间可以相应缩短。需要说明的是,炉腔(整型区)上端配有排气口75。排气口75可以有效排出H2O,CO,CO2,CH4等高温热分解产物气体。The furnace chamber of the carbonization furnace 7 includes the first operating area, the second operating area, the third operating area and the fourth operating area arranged in sequence from the entrance to the exit; wherein the first operating area is the preheating area 11, the second operating area is the shaping area 12, the third operating area is the carbonization area 13, and the fourth operating area is the cooling area 14. The length of each section area conforms to the following relationship: the length of the preheating area 11: the length of the shaping area 12: the length of the carbonization area 13: the length of the cooling area 14 = 1:3:2.5:1.5. Since the carbon paper runs at a uniform speed in each interval, the length of each area also corresponds to the residence time of the carbon paper in each temperature zone. The temperature range of each section area should be set as follows: the temperature of the preheating area 11: 200℃~260℃; the temperature of the shaping area 12: 450℃~720℃; the carbonization area 13: 900℃~1600℃; the cooling area 14 is not heated and is cooled naturally. The carbon paper passes through each section area continuously, and the residence time in different temperature zones is different. The temperature of the preheating zone 11 is 200℃~260℃. There is no obvious change in the carbon paper during this process, and its residence time can be appropriately shortened. The temperature of the shaping zone 12 is 450℃~720℃. During this process, the resin pyrolysis process is intense and the carbon paper shrinks significantly. The residence time should be effectively extended to make the pyrolysis reaction process more complete, which is conducive to the flat surface of the carbon paper and reduce wrinkles. The temperature of the carbonization zone 13 is 900℃~1600℃. During this process, the resin carbon is mainly formed, and the graphite-like structure is gradually formed. The residence time should not be too short. The cooling zone 14 mainly completes the cooling process from high temperature to room temperature, and the residence time can be shortened accordingly. It should be noted that the upper end of the furnace chamber (shaping zone) is equipped with an exhaust port 75. The exhaust port 75 can effectively discharge high-temperature thermal decomposition product gases such as H2O , CO, CO2 , and CH4 .

在传输方向上,第一导轨101和第二导轨102之间的间距以预设规则变化。在预热区11的入口,第一导轨和第二导轨之间的间距为D1;在整型区的入口(也是预热区11的出口),第一导轨和第二导轨之间的间距为D2;在碳化区13的入口(也是整型区12的出口),第一导轨和第二导轨之间的间距为D3;在冷却区14的入口(也是碳化区13的出口),第一导轨和第二导轨之间的间距为D4;在冷却区14的出口,第一导轨和第二导轨之间的间距为D5;其中,D1=D2、D2>D3、D3=D4、D4≤D5,D1:D2:D3:D4:D5=1:1:0.95~0.99:0.95~0.99:0.95~0.99。In the transmission direction, the spacing between the first guide rail 101 and the second guide rail 102 changes according to a preset rule. At the entrance of the preheating zone 11, the spacing between the first guide rail and the second guide rail is D1; at the entrance of the shaping zone (also the exit of the preheating zone 11), the spacing between the first guide rail and the second guide rail is D2; at the entrance of the carbonization zone 13 (also the exit of the shaping zone 12), the spacing between the first guide rail and the second guide rail is D3; at the entrance of the cooling zone 14 (also the exit of the carbonization zone 13), the spacing between the first guide rail and the second guide rail is D4; at the exit of the cooling zone 14, the spacing between the first guide rail and the second guide rail is D5; wherein, D1=D2, D2>D3, D3=D4, D4≤D5, D1:D2:D3:D4:D5=1:1:0.95~0.99:0.95~0.99:0.95~0.99.

采用可调导轨间距的设计目的为:预热区11温度较低纸页无明显收缩,导轨间距始终不变;整型区12中树脂热分解碳纸3有明显收缩,导轨间距适当减小,既保证持续提供张力又防止张力过大导致碳纸3断裂;碳化区13主要完成碳纸类石墨结构成型,碳纸3基本无明显收缩,可维持导轨间距不变;而冷却区14由于材料快速降温,应力需快速释放,可以适当增大导轨间距,防止碳纸3纸面变形弯曲。The design purpose of using adjustable guide rail spacing is as follows: the temperature in the preheating zone 11 is low and the paper sheet has no obvious shrinkage, and the guide rail spacing remains unchanged; the resin thermal decomposition carbon paper 3 in the shaping zone 12 has obvious shrinkage, and the guide rail spacing is appropriately reduced to ensure continuous provision of tension and prevent excessive tension from causing the carbon paper 3 to break; the carbonization zone 13 mainly completes the molding of the carbon paper-like graphite structure, and the carbon paper 3 has basically no obvious shrinkage, and the guide rail spacing can be maintained unchanged; and in the cooling zone 14, due to the rapid cooling of the material, the stress needs to be released quickly, and the guide rail spacing can be appropriately increased to prevent the carbon paper 3 from deforming and bending.

可选地,第一导轨101和第二导轨102相对的一侧分别设置有沿其延伸方向设置的滑槽,两道滑槽的截面为圆形,且两道滑槽的开口相对,滑槽的设置既方便拉伸结构2固定于导轨上,又能使拉伸结构2在导轨上连续滑动运行。具体地,第一导轨101和第二导轨102的内侧(两个导轨相对的一侧)开设有贯通其延伸方向的圆柱形长通孔结构,该通孔朝向连接碳纸3的一侧开一条开口通槽,开口通槽和圆柱形长通孔构成本发明的滑槽。Optionally, the first guide rail 101 and the second guide rail 102 are respectively provided with a slide groove arranged along the extension direction thereof on the opposite side thereof, the cross-section of the two slide grooves is circular, and the openings of the two slide grooves are opposite to each other, and the arrangement of the slide grooves is convenient for fixing the tensile structure 2 on the guide rails, and enables the tensile structure 2 to slide and run continuously on the guide rails. Specifically, the inner side of the first guide rail 101 and the second guide rail 102 (the opposite side of the two guide rails) is provided with a cylindrical long through hole structure that runs through the extension direction thereof, and the through hole opens an open through groove toward the side connected to the carbon paper 3, and the open through groove and the cylindrical long through hole constitute the slide groove of the present invention.

滑动部为球头202,球头202滑动安装于滑槽内,第一导轨101和第二导轨102在朝向二者中心处的方向限位阻挡球头202,防止球头202从滑槽内脱出,优选在球头202与滑槽的间隙之间可以添加润滑粉205,如石墨粉,保证球头202在滑槽中滑行顺畅。连接部包括第一压板206和第二压板201,第一压板206靠近滑槽的一侧连接有沿滑槽的延伸方向设置的球头202,第一压板206和第二压板201相对设置以形成夹持位,碳纸3的边缘被第一压板206和第二压板201夹持,第一压板206和第二压板201之间通过螺栓203紧固。第一压板206和第二压板201相对的一侧各自设置有一张柔性垫片,柔性垫片选自柔性毡204,柔性毡204包括石墨纸、碳毡等,碳纸3边缘夹持于两张所述柔性毡204之间,保证碳纸3与连接部固定紧密,贴合平整。The sliding part is a ball head 202, which is slidably installed in the slide groove. The first guide rail 101 and the second guide rail 102 limit and block the ball head 202 in the direction toward the center of the two to prevent the ball head 202 from falling out of the slide groove. Preferably, lubricating powder 205, such as graphite powder, can be added between the gap between the ball head 202 and the slide groove to ensure that the ball head 202 slides smoothly in the slide groove. The connecting part includes a first pressing plate 206 and a second pressing plate 201. The first pressing plate 206 is connected to a side close to the slide groove with a ball head 202 arranged along the extension direction of the slide groove. The first pressing plate 206 and the second pressing plate 201 are arranged relative to each other to form a clamping position. The edge of the carbon paper 3 is clamped by the first pressing plate 206 and the second pressing plate 201. The first pressing plate 206 and the second pressing plate 201 are fastened by bolts 203. A flexible gasket is provided on each side opposite to the first pressing plate 206 and the second pressing plate 201. The flexible gasket is selected from flexible felt 204. The flexible felt 204 includes graphite paper, carbon felt, etc. The edge of the carbon paper 3 is clamped between the two flexible felts 204 to ensure that the carbon paper 3 is tightly fixed to the connection part and fits flatly.

传输装置的组装的方法包括:首先按照相应位置用两个螺栓将第二压板201固定在第一压板206上;将多个的两个球头202分别依次放入第一导轨101或第二导轨102的滑槽内;将待处理碳纸一侧边缘固定于第一压板206和第二压板201,并用螺栓压合紧密,压合强度0.5~2MPa。拉伸结构2固定在碳纸3一侧后,依次进行碳纸3另一侧的拉伸结构2安装。具体安装规则如下:参见图5,第一导轨101中的滑动部上朝向输送方向的球头202与第二导轨102的滑动部上背离输送方向的球头202平行对应;第一导轨101中的滑动部上背离输送方向的球头202与第二导轨102的滑动部上朝向输送方向的球头202平行对应;即两侧滑动部的位置形成依次交替对应的关系。The method for assembling the transmission device includes: firstly, fixing the second pressing plate 201 on the first pressing plate 206 with two bolts according to the corresponding position; placing two ball heads 202 in the slide groove of the first guide rail 101 or the second guide rail 102 in turn; fixing the edge of one side of the carbon paper to be processed on the first pressing plate 206 and the second pressing plate 201, and pressing them tightly with bolts, with a pressing strength of 0.5 to 2 MPa. After the tensile structure 2 is fixed on one side of the carbon paper 3, the tensile structure 2 on the other side of the carbon paper 3 is installed in turn. The specific installation rules are as follows: Referring to FIG. 5, the ball head 202 on the sliding part of the first guide rail 101 facing the conveying direction corresponds in parallel to the ball head 202 on the sliding part of the second guide rail 102 away from the conveying direction; the ball head 202 on the sliding part of the first guide rail 101 away from the conveying direction corresponds in parallel to the ball head 202 on the sliding part of the second guide rail 102 facing the conveying direction; that is, the positions of the sliding parts on both sides form a sequentially alternating corresponding relationship.

具体实施过程如下:The specific implementation process is as follows:

1、将待处理碳纸3从放卷机构4牵引经过前传动机构51带入碳化炉7进口处。1. The carbon paper 3 to be processed is pulled from the unwinding mechanism 4 through the front transmission mechanism 51 and brought into the entrance of the carbonization furnace 7.

2、调整第一导轨101和第二导轨102的间距,使其满足条件D1:D2:D3:D4:D5=1:1:0.98:0.98:0.99。2. Adjust the distance between the first guide rail 101 and the second guide rail 102 to satisfy the condition D1:D2:D3:D4:D5=1:1:0.98:0.98:0.99.

3、设置碳化炉7各区域温度为:预热区260℃,整型区560℃,碳化区1350℃,冷却区不控温,并升温至设定温度。3. Set the temperature of each area of the carbonization furnace 7 as follows: 260°C for the preheating zone, 560°C for the shaping zone, 1350°C for the carbonization zone, and no temperature control for the cooling zone, and heat it up to the set temperature.

4、将碳纸3利用拉伸结构2一侧固定于一侧导轨上,依据球头202交替对应的关系,将碳纸3另一侧固定于另一侧导轨。4. Fix one side of the carbon paper 3 on one side of the guide rail by using the stretching structure 2, and fix the other side of the carbon paper 3 on the other side of the guide rail according to the alternating correspondence of the ball heads 202.

5、重复步骤4方法,依据两侧拉伸结构2的对应方法,将待处理碳纸3持续带入碳化炉7,并使碳纸3能连续稳定运行。5. Repeat the method in step 4, and according to the corresponding method of the stretching structure 2 on both sides, continuously bring the carbon paper 3 to be processed into the carbonization furnace 7, and make the carbon paper 3 run continuously and stably.

6、待碳纸3通过碳化炉7后,取下碳纸3的拉伸结构2,备后续循环使用。6. After the carbon paper 3 passes through the carbonization furnace 7, the stretching structure 2 of the carbon paper 3 is removed for subsequent recycling.

7、将碳纸3经后传动机构52牵引带入收卷机构6,将碳化后的卷材碳纸3进行收卷。7. The carbon paper 3 is pulled into the winding mechanism 6 by the rear transmission mechanism 52, and the carbonized coiled carbon paper 3 is wound up.

综上,本发明的技术方案主要是将薄层状的碳纸(也包括碳布、碳毡等)材料两侧分别固定于拉伸结构2上,拉伸结构2放置于已固定位置的导轨中,一方面可以使碳纸材料在碳化炉7炉体内稳定匀速滑动运行;另一方面根据碳化停留时间和温度区间,调控两侧导轨之间的间距以控制碳纸材料在幅宽方向的张力,有效减少高温碳化过程中由于热效应造成的材料收缩变形。In summary, the technical solution of the present invention is mainly to fix the two sides of the thin layer of carbon paper (also including carbon cloth, carbon felt, etc.) material on the tensile structure 2 respectively, and the tensile structure 2 is placed in the guide rail at a fixed position. On the one hand, the carbon paper material can slide stably and uniformly in the furnace body of the carbonization furnace 7; on the other hand, according to the carbonization residence time and temperature range, the spacing between the guide rails on both sides is adjusted to control the tension of the carbon paper material in the width direction, thereby effectively reducing the shrinkage and deformation of the material caused by the thermal effect during the high-temperature carbonization process.

本发明提供的传输装置,可以有效控制碳纸材料在幅宽方向的张力,避免碳纸中树脂热分解过程中幅宽方向的热收缩,使碳纸页面展平,提高碳纸平整度,防止褶皱。采用此传输装置,使碳纸在碳化过程中持续提供稳定张力,有效提高碳纸力学性能,提高其石墨化结晶取向。采用此传输装置的幅宽变化方案,碳化结束后可调整幅宽方向张力,有利于降温的过程中释放应力,可有效减少碳纸卷曲程度。The transmission device provided by the present invention can effectively control the tension of the carbon paper material in the width direction, avoid thermal shrinkage in the width direction during the thermal decomposition of the resin in the carbon paper, flatten the carbon paper pages, improve the flatness of the carbon paper, and prevent wrinkles. By adopting this transmission device, the carbon paper can continuously provide stable tension during the carbonization process, effectively improve the mechanical properties of the carbon paper, and improve its graphitized crystal orientation. By adopting the width variation scheme of this transmission device, the tension in the width direction can be adjusted after the carbonization is completed, which is conducive to releasing stress during the cooling process and can effectively reduce the curling degree of the carbon paper.

虽然已经通过例子对本发明的一些特定实施例进行了详细说明,但是本领域的技术人员应该理解,以上例子仅是为了进行说明,而不是为了限制本发明的范围。本领域的技术人员应该理解,可在不脱离本发明的范围和精神的情况下,对以上实施例进行修改。本发明的范围由所附权利要求来限定。Although some specific embodiments of the present invention have been described in detail by way of example, it will be appreciated by those skilled in the art that the above examples are for illustration only and are not intended to limit the scope of the present invention. It will be appreciated by those skilled in the art that the above embodiments may be modified without departing from the scope and spirit of the present invention. The scope of the present invention is defined by the appended claims.

Claims (10)

1. A transfer device for conveying carbon paper to be carbonized through a carbonization furnace for carbonization, comprising:
A first guide rail and a second guide rail which are oppositely arranged in the horizontal direction, wherein at least one section of the first guide rail and at least one section of the second guide rail are positioned in the carbonization furnace;
A tensile structure including a sliding portion and a connecting portion; the first guide rail and the second guide rail are respectively connected with the stretching structure in sliding fit with the first guide rail and the second guide rail, a plurality of sliding parts are respectively in sliding fit with the first guide rail and the second guide rail, and the connecting parts are used for being fixedly connected to two sides of the width of the carbon paper;
the stretching structure provides tension to the carbon paper in the width direction of the carbon paper during carbonization so as to inhibit the carbon paper from shrinking under heating.
2. The transmission device according to claim 1, wherein:
in the conveying direction, the distance between the first guide rail and the second guide rail is changed in a preset rule.
3. The transmission device according to claim 2, wherein:
the device at least comprises a first operation area, a second operation area, a third operation area and a fourth operation area which are sequentially arranged in the transmission direction;
at the entrance of the first working area, the distance between the first guide rail and the second guide rail is D1;
at the entrance of the second working area, the distance between the first guide rail and the second guide rail is D2;
At the entrance of the third working area, the distance between the first guide rail and the second guide rail is D3;
at the entrance of the fourth working area, the distance between the first guide rail and the second guide rail is D4;
At the outlet of the fourth working area, the distance between the first guide rail and the second guide rail is D5;
Wherein d1=d2, D2 > D3, d3=d4, d4.ltoreq.d5; and/or D1: d2: d3: d4:
D5=1:1:0.95~0.99:0.95~0.99:0.95~0.99。
4. A transmission device according to claim 3, characterized in that:
length of the first working area: length of the second working area: length of the third working area: fourth working area length=1: 3:2.5:1.5;
and/or the working temperature of the first working area is 200-260 ℃; the working temperature of the second working area is 450-720 ℃; the working temperature of the third working area is 900-1600 ℃; the working temperature of the fourth working area is room temperature.
5. The transmission device according to any one of claims 1 to 4, characterized in that:
in the conveying direction, a plurality of stretching structures are respectively staggered on the first guide rail and the second guide rail.
6. The transmission apparatus according to claim 5, wherein:
The plurality of stretching structures are arranged on the first guide rail at equal intervals;
and/or a plurality of the stretching structures arranged on the second guide rail are distributed at equal intervals.
7. The transmission device according to any one of claims 1 to 4, characterized in that:
the opposite sides of the first guide rail and the second guide rail are respectively provided with a chute arranged along the extending direction, the sections of the two sliding grooves are circular, and the openings of the two sliding grooves are opposite;
The sliding part is a ball head, the ball head is slidably arranged in the chute, and the first guide rail and the second guide rail are limited in the direction towards the centers of the first guide rail and the second guide rail to block the ball head.
8. The transmission apparatus according to claim 7, wherein:
The connecting part comprises a first pressing plate and a second pressing plate, one side, close to the sliding groove, of the first pressing plate is connected with the ball heads, and the two ball heads are sequentially arranged along the extending direction of the sliding groove; the first pressing plate and the second pressing plate are oppositely arranged to form a clamping position, and the edge of the carbon paper is clamped by the first pressing plate and the second pressing plate.
9. The transmission device according to any one of claims 1 to 4, characterized in that:
front transmission mechanisms and rear transmission mechanisms are respectively arranged on the front side and the rear side of the carbonization furnace;
The front transmission mechanism and the rear transmission mechanism respectively comprise two driving rollers which are oppositely arranged, carbon paper passes through a slit between the two driving rollers which are oppositely arranged, the carbon paper is clamped by the two driving rollers which are oppositely arranged, and when the driving rollers rotate, the carbon paper moves forward along the conveying direction under the action of friction force.
10. A carbonization system, characterized by comprising a carbonization furnace and a conveying device according to any one of claims 1 to 9 for conveying carbon paper through the carbonization furnace for carbonization.
CN202410935859.5A 2024-07-12 2024-07-12 A transmission device and a carbonization system Pending CN118896492A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119121690A (en) * 2024-11-13 2024-12-13 国科领纤新材料(常州)有限公司 A tensioning device suitable for high-temperature carbonization and graphitization and a method of using the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119121690A (en) * 2024-11-13 2024-12-13 国科领纤新材料(常州)有限公司 A tensioning device suitable for high-temperature carbonization and graphitization and a method of using the same

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