CN118854327A - AEM water electrolysis hydrogen production electrolyzer - Google Patents
AEM water electrolysis hydrogen production electrolyzer Download PDFInfo
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- CN118854327A CN118854327A CN202411338933.1A CN202411338933A CN118854327A CN 118854327 A CN118854327 A CN 118854327A CN 202411338933 A CN202411338933 A CN 202411338933A CN 118854327 A CN118854327 A CN 118854327A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/60—Constructional parts of cells
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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Abstract
Description
技术领域Technical Field
本发明涉及电解槽技术领域,具体为AEM电解水制氢电解槽。The invention relates to the technical field of electrolyzers, in particular to an AEM electrolyzer for producing hydrogen by electrolyzing water.
背景技术Background Art
AEM(阴离子交换膜)电解水制氢技术是一种基于电解水原理的制氢方法,它利用阴离子交换膜作为电解质,通过电解水产生氢气和氧气,在电解槽的阳极和阴极两端外加直流电压,水分子在阴极催化剂的作用下接收电子发生析氢反应(HER),产生氢气并透过气体扩散层释放出来,同时,析氢反应产生的氢氧根离子(OH-)穿过阴离子交换膜回到阳极,在阳极催化剂的作用下发生析氧反应(OER),产生氧气并释放到大气中或进行其他利用。AEM (anion exchange membrane) water electrolysis hydrogen production technology is a hydrogen production method based on the principle of water electrolysis. It uses anion exchange membrane as an electrolyte to produce hydrogen and oxygen by electrolyzing water. A DC voltage is applied to the anode and cathode of the electrolyzer. Water molecules receive electrons under the action of the cathode catalyst to undergo a hydrogen evolution reaction (HER), produce hydrogen and release it through the gas diffusion layer. At the same time, the hydroxide ions (OH-) produced by the hydrogen evolution reaction pass through the anion exchange membrane back to the anode, and undergo an oxygen evolution reaction (OER) under the action of the anode catalyst to produce oxygen and release it into the atmosphere or for other uses.
现有技术中,如公开号为CN202369653U的高效电解槽,包括槽体、支撑杆、叶片和防水发电机,槽体底部均布有四个防水发电机,防水发电机上安装有叶片,支撑杆位于叶片的上方并固定在槽体壁上;叶片为钛合金材料,支撑杆为PVDF材质。由于电解槽底部设有旋转叶片,促进液体相互流通,在电解时可大大加快阴阳离子交换速率,从而大大提高电解速度。In the prior art, for example, the high-efficiency electrolytic cell with publication number CN202369653U includes a cell body, a support rod, blades and a waterproof generator. Four waterproof generators are evenly distributed at the bottom of the cell body, and blades are installed on the waterproof generator. The support rod is located above the blades and fixed to the wall of the cell body; the blades are made of titanium alloy, and the support rod is made of PVDF. Since the bottom of the electrolytic cell is provided with rotating blades, the mutual circulation of liquids is promoted, and the anion and cation exchange rate can be greatly accelerated during electrolysis, thereby greatly improving the electrolysis speed.
在实际使用过程中,在电解槽底部位置设置旋转叶片,促进液体的相互流通,但是,现有技术中电解水在电解槽底部进行流动,难以实现电解槽内的均匀分布,容易造成电解液在电解槽内形成死区或短路现象;并且在电解过程中,氢气、氧气产生进入气体腔,无法控制气体的流动路径,导致气体在槽体内积聚,促使压力升高,降低电解水制氢电解槽的稳定性和安全性。In actual use, rotating blades are set at the bottom of the electrolytic cell to promote the mutual circulation of liquids. However, in the prior art, electrolyzed water flows at the bottom of the electrolytic cell, making it difficult to achieve uniform distribution in the electrolytic cell, and easily causing the electrolyte to form a dead zone or short circuit in the electrolytic cell; and during the electrolysis process, hydrogen and oxygen are generated and enter the gas cavity, and the flow path of the gas cannot be controlled, resulting in gas accumulation in the cell body, causing the pressure to increase, thereby reducing the stability and safety of the electrolytic water hydrogen production electrolytic cell.
因此,本发明提出了AEM电解水制氢电解槽,来解决现有电解液分布不均以及排出气体的稳定性较差,从而影响电解槽稳定和安全的问题。Therefore, the present invention proposes an AEM water electrolysis hydrogen production electrolyzer to solve the problems of uneven electrolyte distribution and poor stability of exhaust gas in the existing electrolyzer, which affects the stability and safety of the electrolyzer.
发明内容Summary of the invention
针对现有技术存在的不足,本发明目的是提供AEM电解水制氢电解槽,具备电解效率高、稳定性好的优点。In view of the shortcomings of the prior art, the object of the present invention is to provide an AEM water electrolysis hydrogen production electrolyzer, which has the advantages of high electrolysis efficiency and good stability.
为实现上述目的,本发明提供如下技术方案:AEM电解水制氢电解槽,包括电解槽本体,所述电解槽本体的两端分别设置有阳极板和阴极板,所述阳极板、阴极板的内表面贯穿连接有紧固螺栓,所述电解槽本体与阳极板、阴极板分别通过紧固螺栓固定连接,所述电解槽本体的内侧设置有框板一和框板二,所述框板一及框板二的中间设置有气体扩散层板,所述框板一的内部安装有电解液均布机构,所述电解液均布机构包括有下弧形流道槽板和上弧形流道槽板,所述下弧形流道槽板及上弧形流道槽板之间设置有流动通道组件,所述下弧形流道槽板靠近上弧形流道槽板的外表面固定安装有弧形架,所述弧形架上设置有扰流组件,所述电解槽本体的上端固定连接有氢气排出管,所述氢气排出管的内部设置有气体腔,所述气体腔的内侧设置有气体调整机构,所述气体调整机构包括有进气分割组件和气腔出口流量开度调节组件,所述气腔出口流量开度调节组件活动安装在氢气排出管的两端,所述进气分割组件设置在氢气排出管的下端。To achieve the above-mentioned purpose, the present invention provides the following technical solutions: an AEM water electrolysis hydrogen production electrolyzer, comprising an electrolyzer body, wherein an anode plate and a cathode plate are respectively arranged at both ends of the electrolyzer body, and the inner surfaces of the anode plate and the cathode plate are penetrated and connected with fastening bolts, and the electrolyzer body is fixedly connected to the anode plate and the cathode plate respectively by fastening bolts, and a frame plate 1 and a frame plate 2 are arranged on the inner side of the electrolyzer body, and a gas diffusion layer plate is arranged between the frame plate 1 and the frame plate 2, and an electrolyte uniform distribution mechanism is installed inside the frame plate 1, and the electrolyte uniform distribution mechanism includes a lower arc flow channel plate and an upper arc flow channel plate, and the A flow channel assembly is arranged between the lower arc flow channel plate and the upper arc flow channel plate, an arc frame is fixedly installed on the outer surface of the lower arc flow channel plate close to the upper arc flow channel plate, a spoiler assembly is arranged on the arc frame, a hydrogen exhaust pipe is fixedly connected to the upper end of the electrolyzer body, a gas cavity is arranged inside the hydrogen exhaust pipe, a gas adjustment mechanism is arranged on the inner side of the gas cavity, the gas adjustment mechanism includes an air intake splitting assembly and an air cavity outlet flow opening adjustment assembly, the air cavity outlet flow opening adjustment assembly is movably installed at both ends of the hydrogen exhaust pipe, and the air intake splitting assembly is arranged at the lower end of the hydrogen exhaust pipe.
优选的,所述流动通道组件包括有导流直管,所述导流直管的两端分别贯通下弧形流道槽板及上弧形流道槽板的内壁,所述下弧形流道槽板与上弧形流道槽板关于导流直管的水平中心轴线镜像分布,所述下弧形流道槽板及上弧形流道槽板整体呈弧形空腔板状结构,所述下弧形流道槽板的一端密封连接有电解液出口,所述电解液出口的外表面贯穿阳极板的内部,所述上弧形流道槽板的一端密封连接有电解液进口,所述电解液进口延伸至阳极板的外部。Preferably, the flow channel assembly includes a guide straight pipe, both ends of which pass through the inner walls of the lower arc flow channel groove plate and the upper arc flow channel groove plate respectively, the lower arc flow channel groove plate and the upper arc flow channel groove plate are mirror-distributed about the horizontal center axis of the guide straight pipe, the lower arc flow channel groove plate and the upper arc flow channel groove plate are overall present as an arc-shaped cavity plate structure, one end of the lower arc flow channel groove plate is sealed with an electrolyte outlet, the outer surface of the electrolyte outlet passes through the interior of the anode plate, one end of the upper arc flow channel groove plate is sealed with an electrolyte inlet, and the electrolyte inlet extends to the outside of the anode plate.
优选的,所述导流直管的内壁上均匀开设有圆形孔,所述下弧形流道槽板的内环表面上贯通连接有下弯管,所述上弧形流道槽板的内环表面上贯通连接有上弯管,所述上弯管及下弯管关于导流直管的水平中心轴线对称分布。Preferably, circular holes are evenly opened on the inner wall of the guide straight pipe, a lower bend pipe is connected through the inner ring surface of the lower arc-shaped flow channel groove plate, and an upper bend pipe is connected through the inner ring surface of the upper arc-shaped flow channel groove plate, and the upper and lower bend pipes are symmetrically distributed about the horizontal center axis of the guide straight pipe.
优选的,所述扰流组件包括有连接套环,所述连接套环固定安装在弧形架的中心,所述连接套环呈圆形环状结构,所述连接套环的内表面与导流直管的外表面固定连接,所述弧形架的两端内壁上分别转动连接有轴杆,所述轴杆的上侧外表面固定连接有扰流片。Preferably, the spoiler assembly includes a connecting ring, which is fixedly installed at the center of the arc frame. The connecting ring is a circular ring structure, and the inner surface of the connecting ring is fixedly connected to the outer surface of the guide straight pipe. The inner walls at both ends of the arc frame are respectively rotatably connected with shafts, and the upper outer surface of the shaft is fixedly connected with a spoiler.
优选的,所述进气分割组件包括有导气罩,所述导气罩整体呈下宽上窄的锥形斗状结构,所述导气罩的上端内壁贯穿氢气排出管的下表面,所述导气罩的内部设置有进气锥腔,所述进气锥腔的下端内表面固定安装有导流板。Preferably, the air intake splitting assembly includes an air guide hood, which is an overall conical bucket-shaped structure that is wider at the bottom and narrower at the top. The inner wall of the upper end of the air guide hood penetrates the lower surface of the hydrogen exhaust pipe. An air intake cone cavity is provided inside the air guide hood, and a guide plate is fixedly installed on the inner surface of the lower end of the air intake cone cavity.
优选的,所述导流板的内表面上固定安装有均布进气管,所述均布进气管呈柱状空心结构,所述均布进气管的内表面开设有导气孔,所述导气孔的内壁上固定安装有分割板,所述分割板呈“米”字形结构。Preferably, a uniformly distributed air inlet pipe is fixedly mounted on the inner surface of the guide plate, the uniformly distributed air inlet pipe is a cylindrical hollow structure, air guide holes are opened on the inner surface of the uniformly distributed air inlet pipe, a dividing plate is fixedly mounted on the inner wall of the air guide hole, and the dividing plate is a "M"-shaped structure.
优选的,所述气腔出口流量开度调节组件包括有连接套管一和连接套管二,所述连接套管一采用可拆卸方式安装在氢气排出管的两端,所述连接套管一的外侧面与连接套管二的一侧固定连接,所述连接套管二的上端内壁上开设有避让槽,所述避让槽的内侧活动安装有内齿环,所述内齿环的外环表面固定增设有啮合齿。Preferably, the air cavity outlet flow opening adjustment component includes a connecting sleeve 1 and a connecting sleeve 2, the connecting sleeve 1 is detachably installed at both ends of the hydrogen exhaust pipe, the outer side surface of the connecting sleeve 1 is fixedly connected to one side of the connecting sleeve 2, an avoidance groove is provided on the inner wall of the upper end of the connecting sleeve 2, an inner gear ring is movably installed on the inner side of the avoidance groove, and meshing teeth are fixedly added to the outer ring surface of the inner gear ring.
优选的,所述连接套管一的上表面固定安装有支撑块,所述支撑块的外表面固定安装有马达,所述马达的输出轴上固定连接有主动齿轮,所述主动齿轮的外表面与啮合齿的外表面啮合转动,所述啮合齿的两侧分别设置有限位环,所述限位环分别固定安装在内齿环的两侧,两组所述限位环的外表面与连接套管一及连接套管二的内壁转动连接。Preferably, a support block is fixedly mounted on the upper surface of the connecting sleeve one, a motor is fixedly mounted on the outer surface of the support block, a driving gear is fixedly connected to the output shaft of the motor, the outer surface of the driving gear meshes and rotates with the outer surface of the meshing teeth, limiting rings are respectively provided on both sides of the meshing teeth, the limiting rings are respectively fixedly mounted on both sides of the inner gear ring, and the outer surfaces of the two groups of limiting rings are rotatably connected to the inner walls of the connecting sleeve one and the connecting sleeve two.
优选的,所述内齿环的内侧啮合转动有从动齿轮,所述从动齿轮的中心内表面固定连接有限位柱,所述限位柱的一端外表面与连接套管一的内壁转动连接,所述限位柱的外表面固定连接有调节板。Preferably, a driven gear is meshed and rotated on the inner side of the inner gear ring, the central inner surface of the driven gear is fixedly connected to a limiting column, the outer surface of one end of the limiting column is rotatably connected to the inner wall of the connecting sleeve, and the outer surface of the limiting column is fixedly connected to an adjustment plate.
与现有技术相比,本发明的有益效果是:Compared with the prior art, the present invention has the following beneficial effects:
本发明提出的AEM电解水制氢电解槽,通过优化电解槽本体内部的电解液流动通道,由两组相对分布的下弧形流道槽板和上弧形流道槽板提供电解水分布水路,利用流动通道组件,提高电解液的流动性和分布均匀性,从而提高反应效率和产氢量,且配合扰流组件的设置,促进电解槽本体内部电解液充分流经电极表面,提高电解效率;通过在氢气排出管的下端设置水平阵列排布的进气分割组件,确保扩散气体平缓稳定进入氢气排出管的内部,确保气体以稳定的速度进入气体腔进行排出和收集,利用气腔出口流量开度调节组件控制气体排出的流量,减少气体在槽内的积聚和压力升高,进一步提升电解水制氢过程的稳定性和安全性。The AEM electrolytic water electrolysis hydrogen production electrolyzer proposed in the present invention optimizes the electrolyte flow channel inside the electrolytic cell body, and provides an electrolytic water distribution water channel by two sets of relatively distributed lower arc flow channel groove plates and upper arc flow channel groove plates. The flow channel component is used to improve the fluidity and distribution uniformity of the electrolyte, thereby improving the reaction efficiency and hydrogen production. In addition, the setting of the spoiler component is used to promote the electrolyte inside the electrolytic cell body to fully flow through the electrode surface, thereby improving the electrolysis efficiency. By arranging a horizontally arrayed air intake splitter component at the lower end of the hydrogen exhaust pipe, it is ensured that the diffused gas enters the interior of the hydrogen exhaust pipe smoothly and stably, and that the gas enters the gas cavity at a stable speed for discharge and collection. The gas cavity outlet flow opening adjustment component is used to control the gas discharge flow rate, reduce the accumulation of gas in the cell and the pressure increase, and further improve the stability and safety of the water electrolysis hydrogen production process.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本发明的立体结构示意图;FIG1 is a schematic diagram of a three-dimensional structure of the present invention;
图2为本发明的立体拆解结构示意图;FIG2 is a schematic diagram of a three-dimensional disassembled structure of the present invention;
图3为本发明的侧视半剖结构示意图;FIG3 is a side view of a half-section structure of the present invention;
图4为本发明的电解液均布机构的结构示意图;FIG4 is a schematic structural diagram of an electrolyte uniform distribution mechanism of the present invention;
图5为本发明的下弧形流道槽板与导流直管的连接截面结构示意图;FIG5 is a schematic diagram of the cross-sectional structure of the connection between the lower arc-shaped flow channel groove plate and the guide straight pipe of the present invention;
图6为本发明的气体调整机构的结构示意图;FIG6 is a schematic diagram of the structure of the gas adjustment mechanism of the present invention;
图7为本发明的进气分割组件的局部截面结构示意图;FIG7 is a partial cross-sectional structural diagram of an air intake splitting assembly of the present invention;
图8为本发明的图7的A处放大结构示意图;FIG8 is an enlarged structural schematic diagram of point A in FIG7 of the present invention;
图9为本发明的气腔出口流量开度调节组件的结构示意图;FIG9 is a schematic structural diagram of an air cavity outlet flow opening adjustment assembly according to the present invention;
图10为本发明的图9的B处放大结构示意图;FIG10 is an enlarged structural schematic diagram of point B in FIG9 of the present invention;
图11为本发明的连接套管一与连接套管二的分解结构示意图;FIG11 is a schematic diagram of the exploded structure of the connecting sleeve 1 and the connecting sleeve 2 of the present invention;
图12为本发明的图11的C处放大结构示意图;FIG12 is an enlarged structural schematic diagram of point C in FIG11 of the present invention;
图13为本发明的框板一与框板二的拆解结构示意图。FIG. 13 is a schematic diagram of the disassembled structure of frame plate 1 and frame plate 2 of the present invention.
图中:1、电解槽本体;11、框板一;12、框板二;13、气体扩散层板;2、阳极板;3、阴极板;4、紧固螺栓;5、电解液出口;51、电解液进口;6、电解液均布机构;61、下弧形流道槽板;62、上弧形流道槽板;63、导流直管;630、圆形孔;611、下弯管;621、上弯管;64、弧形架;640、连接套环;641、轴杆;642、扰流片;7、氢气排出管;70、气体腔;71、导气罩;711、进气锥腔;712、导流板;7121、均布进气管;7122、导气孔;7123、分割板;72、连接套管一;721、连接套管二;7210、避让槽;722、支撑块;723、马达;724、主动齿轮;7251、啮合齿;725、内齿环;726、从动齿轮;7261、限位柱;727、调节板。In the figure: 1, electrolytic cell body; 11, frame plate 1; 12, frame plate 2; 13, gas diffusion layer plate; 2, anode plate; 3, cathode plate; 4, fastening bolts; 5, electrolyte outlet; 51, electrolyte inlet; 6, electrolyte uniform distribution mechanism; 61, lower arc flow channel groove plate; 62, upper arc flow channel groove plate; 63, flow guide straight pipe; 630, circular hole; 611, lower bend pipe; 621, upper bend pipe; 64, arc frame; 640, connecting ring; 641, shaft; 642, flow disturbance Plate; 7, hydrogen discharge pipe; 70, gas cavity; 71, air guide cover; 711, intake cone cavity; 712, guide plate; 7121, uniform intake pipe; 7122, air guide hole; 7123, dividing plate; 72, connecting sleeve 1; 721, connecting sleeve 2; 7210, avoidance groove; 722, support block; 723, motor; 724, driving gear; 7251, meshing teeth; 725, inner gear ring; 726, driven gear; 7261, limit column; 727, adjustment plate.
具体实施方式DETAILED DESCRIPTION
为了使本发明的目的、技术方案进行清楚、完整的描述,及优点更加清楚明白,以下结合附图对本发明实施例进行进一步详细说明。应当理解,此处所描述的具体实施例是本发明一部分实施例,而不是全部的实施例,仅仅用以解释本发明实施例,并不用于限定本发明实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purpose and technical solution of the present invention clearly and completely described, and the advantages more clearly understood, the embodiments of the present invention are further described in detail with reference to the accompanying drawings. It should be understood that the specific embodiments described herein are part of the embodiments of the present invention, not all of them, and are only used to explain the embodiments of the present invention, and are not used to limit the embodiments of the present invention. All other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
实施例一中,请参阅图1-图13,本发明提供一种技术方案:AEM电解水制氢电解槽,包括电解槽本体1,电解槽本体1的两端分别设置有阳极板2和阴极板3,阳极板2、阴极板3的内表面贯穿连接有紧固螺栓4,电解槽本体1与阳极板2、阴极板3分别通过紧固螺栓4固定连接,电解槽本体1的内侧设置有框板一11和框板二12,框板一11及框板二12的中间设置有气体扩散层板13,框板一11的内部安装有电解液均布机构6,电解液均布机构6包括有下弧形流道槽板61和上弧形流道槽板62,下弧形流道槽板61及上弧形流道槽板62之间设置有流动通道组件,下弧形流道槽板61靠近上弧形流道槽板62的外表面固定安装有弧形架64,弧形架64上设置有扰流组件,电解槽本体1的上端固定连接有氢气排出管7,氢气排出管7的内部设置有气体腔70,气体腔70的内侧设置有气体调整机构,气体调整机构包括有进气分割组件和气腔出口流量开度调节组件,气腔出口流量开度调节组件活动安装在氢气排出管7的两端,进气分割组件设置在氢气排出管7的下端;通过优化电解槽本体1内部的电解液流动通道,由两组相对分布的下弧形流道槽板61和上弧形流道槽板62提供电解水分布水路,利用流动通道组件,提高电解液的流动性和分布均匀性,从而提高反应效率和产氢量,且配合扰流组件的设置,促进电解槽本体1内部电解液充分流经电极表面,提高电解效率;通过在氢气排出管7的下端设置水平阵列排布的进气分割组件,确保扩散气体平缓稳定进入氢气排出管7的内部,确保气体以稳定的速度进入气体腔70进行排出和收集,利用气腔出口流量开度调节组件控制气体排出的流量,减少气体在槽内的积聚和压力升高,进一步提升电解水制氢过程的稳定性和安全性。In the first embodiment, please refer to Figures 1 to 13. The present invention provides a technical solution: an AEM water electrolysis hydrogen production electrolyzer, comprising an electrolyzer body 1, wherein an anode plate 2 and a cathode plate 3 are respectively arranged at both ends of the electrolyzer body 1, and a fastening bolt 4 is connected through the inner surfaces of the anode plate 2 and the cathode plate 3, and the electrolyzer body 1 is fixedly connected to the anode plate 2 and the cathode plate 3 by the fastening bolt 4, and a frame plate 11 and a frame plate 2 12 are arranged on the inner side of the electrolyzer body 1, and a gas diffusion layer plate 13 is arranged between the frame plate 11 and the frame plate 2 12, and the frame plate 11 and the frame plate 2 12 are provided with a gas diffusion layer plate 13, and the frame plate 11 and the frame plate ... The electrolyte uniform distribution mechanism 6 is installed inside the plate 11, and the electrolyte uniform distribution mechanism 6 includes a lower arc flow channel groove plate 61 and an upper arc flow channel groove plate 62. A flow channel component is arranged between the lower arc flow channel groove plate 61 and the upper arc flow channel groove plate 62. The lower arc flow channel groove plate 61 is fixedly installed with an arc frame 64 on the outer surface close to the upper arc flow channel groove plate 62, and a spoiler component is arranged on the arc frame 64. The upper end of the electrolytic cell body 1 is fixedly connected with a hydrogen exhaust pipe 7, and a gas cavity 70 is arranged inside the hydrogen exhaust pipe 7. The inner side of the gas cavity 70 is provided with a A gas adjustment mechanism is provided, and the gas adjustment mechanism includes an air intake splitting component and an air cavity outlet flow opening adjustment component. The air cavity outlet flow opening adjustment component is movably installed at both ends of the hydrogen discharge pipe 7, and the air intake splitting component is arranged at the lower end of the hydrogen discharge pipe 7; by optimizing the electrolyte flow channel inside the electrolyzer body 1, two sets of relatively distributed lower arc flow channel groove plates 61 and upper arc flow channel groove plates 62 are provided to provide an electrolytic water distribution waterway, and the flow channel component is used to improve the fluidity and distribution uniformity of the electrolyte, thereby improving the reaction efficiency and hydrogen production The amount of electrolyte in the electrolytic cell body 1 is increased by adjusting the spoiler component, and the spoiler component is arranged to promote the electrolyte in the electrolytic cell body 1 to fully flow through the electrode surface, thereby improving the electrolysis efficiency; by arranging a horizontal array of air intake splitter components at the lower end of the hydrogen exhaust pipe 7, it is ensured that the diffused gas enters the interior of the hydrogen exhaust pipe 7 smoothly and stably, and that the gas enters the gas cavity 70 at a stable speed for discharge and collection, and the gas cavity outlet flow opening adjustment component is used to control the gas discharge flow rate, reduce the accumulation of gas in the cell and the pressure increase, and further improve the stability and safety of the hydrogen production process by electrolyzing water.
实施例二中,参照附图1-图13,在实施例一的基础上,为了实现电解液在电解槽本体1的均匀流通:流动通道组件包括有导流直管63,导流直管63的两端分别贯通下弧形流道槽板61及上弧形流道槽板62的内壁,下弧形流道槽板61与上弧形流道槽板62关于导流直管63的水平中心轴线镜像分布,下弧形流道槽板61及上弧形流道槽板62整体呈弧形空腔板状结构,下弧形流道槽板61的一端密封连接有电解液出口5,电解液出口5的外表面贯穿阳极板2的内部,上弧形流道槽板62的一端密封连接有电解液进口51,电解液进口51延伸至阳极板2的外部;导流直管63的内壁上均匀开设有圆形孔630,下弧形流道槽板61的内环表面上贯通连接有下弯管611,上弧形流道槽板62的内环表面上贯通连接有上弯管621,上弯管621及下弯管611关于导流直管63的水平中心轴线对称分布;In the second embodiment, referring to the accompanying drawings 1 to 13, on the basis of the first embodiment, in order to realize the uniform flow of electrolyte in the electrolytic cell body 1: the flow channel assembly includes a flow guide straight pipe 63, the two ends of the flow guide straight pipe 63 respectively penetrate the inner wall of the lower arc flow channel groove plate 61 and the upper arc flow channel groove plate 62, the lower arc flow channel groove plate 61 and the upper arc flow channel groove plate 62 are mirror-distributed about the horizontal central axis of the flow guide straight pipe 63, the lower arc flow channel groove plate 61 and the upper arc flow channel groove plate 62 are overall in an arc-shaped cavity plate structure, and one end of the lower arc flow channel groove plate 61 is sealed. An electrolyte outlet 5 is connected, and the outer surface of the electrolyte outlet 5 passes through the interior of the anode plate 2. One end of the upper arc-shaped flow channel groove plate 62 is sealed and connected to the electrolyte inlet 51, and the electrolyte inlet 51 extends to the outside of the anode plate 2. Circular holes 630 are evenly opened on the inner wall of the guide straight pipe 63, and a lower bend pipe 611 is connected through the inner ring surface of the lower arc-shaped flow channel groove plate 61, and an upper bend pipe 621 is connected through the inner ring surface of the upper arc-shaped flow channel groove plate 62. The upper bend pipe 621 and the lower bend pipe 611 are symmetrically distributed about the horizontal central axis of the guide straight pipe 63;
在电解槽本体1的内侧设置相对分布的下弧形流道槽板61和上弧形流道槽板62,当电解液经过电解液进口51导入上弧形流道槽板62内腔时,一部分电解液经过上弯管621呈水帘状下落,一部分电解液通过导流直管63导入下弧形流道槽板61的内部,且通过导流直管63上均匀开设的圆形孔630喷出,如此实现电解液在电解槽本体1的内部进行循环流通,避免存在电解液难以接触的死区,提高电解液的流动性和分布均匀性,从而提高反应速率和产氢量,通过这样的电解液流动路径,使电解液能够充分流经电极表面,提高电解效率。A lower arc flow channel plate 61 and an upper arc flow channel plate 62 are relatively distributed on the inner side of the electrolytic cell body 1. When the electrolyte is introduced into the inner cavity of the upper arc flow channel plate 62 through the electrolyte inlet 51, a part of the electrolyte falls in a water curtain shape through the upper bend pipe 621, and a part of the electrolyte is introduced into the interior of the lower arc flow channel plate 61 through the guide straight pipe 63, and is sprayed out through the circular holes 630 evenly opened on the guide straight pipe 63. In this way, the electrolyte is circulated inside the electrolytic cell body 1, avoiding the existence of dead zones that are difficult for the electrolyte to contact, improving the fluidity and distribution uniformity of the electrolyte, thereby improving the reaction rate and hydrogen production. Through such an electrolyte flow path, the electrolyte can fully flow through the electrode surface, thereby improving the electrolysis efficiency.
实施例三中,参照附图1-图13,在实施例二的基础上,为了实现下弧形流道槽板61与上弧形流道槽板62之间电解液的扰流,促进电解液的流动性:扰流组件包括有连接套环640,连接套环640固定安装在弧形架64的中心,连接套环640呈圆形环状结构,连接套环640的内表面与导流直管63的外表面固定连接,弧形架64的两端内壁上分别转动连接有轴杆641,轴杆641的上侧外表面固定连接有扰流片642;In the third embodiment, referring to the accompanying drawings 1 to 13, on the basis of the second embodiment, in order to realize the turbulence of the electrolyte between the lower arc-shaped flow channel groove plate 61 and the upper arc-shaped flow channel groove plate 62 and promote the fluidity of the electrolyte: the turbulence component includes a connecting ring 640, the connecting ring 640 is fixedly installed at the center of the arc frame 64, the connecting ring 640 is a circular ring structure, the inner surface of the connecting ring 640 is fixedly connected to the outer surface of the guide straight pipe 63, the inner walls of the two ends of the arc frame 64 are respectively rotatably connected with shafts 641, and the upper outer surface of the shaft 641 is fixedly connected with a spoiler 642;
在下弧形流道槽板61与上弧形流道槽板62之间的电解液流动时,上弧形流道槽板62内腔的电解液受重力向下流出,利用多组阵列排布的上弯管621,使得电解液向扰流片642的表面进行流动,此时扰流片642受到外部电解液的冲击,配合轴杆641在弧形架64上的转动,实现扰流片642的旋转,如此实现电解槽内部电解液的扰动,提高电解反应整体的适应性和可扩展性。When the electrolyte flows between the lower arc flow channel plate 61 and the upper arc flow channel plate 62, the electrolyte in the inner cavity of the upper arc flow channel plate 62 flows downward due to gravity, and the electrolyte is caused to flow toward the surface of the spoiler 642 by utilizing multiple groups of upper curved tubes 621 arranged in an array. At this time, the spoiler 642 is impacted by the external electrolyte, and the rotation of the shaft 641 on the arc frame 64 is coordinated to realize the rotation of the spoiler 642, thereby realizing the disturbance of the electrolyte inside the electrolytic cell and improving the overall adaptability and scalability of the electrolytic reaction.
实施例四中,参照附图1-图13,在实施例三的基础上,为了实现电解反应产生氢气和氧气的稳定排出和高效收集:进气分割组件包括有导气罩71,导气罩71整体呈下宽上窄的锥形斗状结构,导气罩71的上端内壁贯穿氢气排出管7的下表面,导气罩71的内部设置有进气锥腔711,进气锥腔711的下端内表面固定安装有导流板712;导流板712的内表面上固定安装有均布进气管7121,均布进气管7121呈柱状空心结构,均布进气管7121的内表面开设有导气孔7122,导气孔7122的内壁上固定安装有分割板7123,分割板7123呈“米”字形结构;In the fourth embodiment, referring to the accompanying drawings 1 to 13, on the basis of the third embodiment, in order to realize the stable discharge and efficient collection of hydrogen and oxygen generated by the electrolysis reaction: the air intake splitting assembly includes an air guide cover 71, the air guide cover 71 is a tapered bucket-shaped structure that is wide at the bottom and narrow at the top, the upper inner wall of the air guide cover 71 penetrates the lower surface of the hydrogen discharge pipe 7, an air intake cone cavity 711 is arranged inside the air guide cover 71, and a guide plate 712 is fixedly installed on the inner surface of the lower end of the air intake cone cavity 711; a uniform air intake pipe 7121 is fixedly installed on the inner surface of the guide plate 712, the uniform air intake pipe 7121 is a columnar hollow structure, and an air guide hole 7122 is opened on the inner surface of the uniform air intake pipe 7121, and a split plate 7123 is fixedly installed on the inner wall of the air guide hole 7122, and the split plate 7123 is in a "M"-shaped structure;
通过电解产生的扩散气体上升,核心为下宽上窄锥形斗状的导气罩71,其顶端无缝对接氢气排出管7,经过多组导气罩71进入的过程中,导流板712上安装的均布进气管7121将进气锥腔711的底部形成多个微小的通道,经过上升的气体由导气孔7122内部架设的分割板7123进行分割,气体随后通过导气孔7122内的分割板7123被均匀分割并分散,有效防止了气体直接向气体腔70内高压喷发,从而确保了气体排放的稳定性和气体腔70内部压力的均衡,进一步提升形成气体的稳定排出,保证电解槽整体的安全性和稳定性,同时,分割板7123的存在还进一步细化了气体流道,提高了气体的分散效果和收集效率。The diffused gas generated by electrolysis rises, and the core is a conical bucket-shaped gas guide hood 71 that is wide at the bottom and narrow at the top, and its top is seamlessly connected to the hydrogen exhaust pipe 7. In the process of entering through multiple groups of gas guide hoods 71, the evenly distributed air intake pipe 7121 installed on the guide plate 712 forms a plurality of tiny channels at the bottom of the intake cone cavity 711, and the rising gas is divided by the dividing plate 7123 erected inside the gas guide hole 7122. The gas is then evenly divided and dispersed through the dividing plate 7123 in the gas guide hole 7122, effectively preventing the gas from directly erupting into the gas cavity 70 at high pressure, thereby ensuring the stability of gas emission and the balance of pressure inside the gas cavity 70, further improving the stable discharge of the formed gas, and ensuring the overall safety and stability of the electrolytic cell. At the same time, the presence of the dividing plate 7123 further refines the gas flow path, and improves the gas dispersion effect and collection efficiency.
实施例五中,参照附图1-图13,在实施例四的基础上,为了实现氢气排出管7两端气体排进排出的开度,控制气体腔70内腔气体排出流量的大小:气腔出口流量开度调节组件包括有连接套管一72和连接套管二721,连接套管一72采用可拆卸方式安装在氢气排出管7的两端,连接套管一72的外侧面与连接套管二721的一侧固定连接,连接套管二721的上端内壁上开设有避让槽7210,避让槽7210的内侧活动安装有内齿环725,内齿环725的外环表面固定增设有啮合齿7251;连接套管一72的上表面固定安装有支撑块722,支撑块722的外表面固定安装有马达723,马达723的输出轴上固定连接有主动齿轮724,主动齿轮724的外表面与啮合齿7251的外表面啮合转动,啮合齿7251的两侧分别设置有限位环,限位环分别固定安装在内齿环725的两侧,两组限位环的外表面与连接套管一72及连接套管二721的内壁转动连接;内齿环725的内侧啮合转动有从动齿轮726,从动齿轮726的中心内表面固定连接有限位柱7261,限位柱7261的一端外表面与连接套管一72的内壁转动连接,限位柱7261的外表面固定连接有调节板727;In the fifth embodiment, referring to Figures 1 to 13, on the basis of the fourth embodiment, in order to realize the opening of the gas discharge at both ends of the hydrogen discharge pipe 7, the size of the gas discharge flow rate of the inner cavity of the gas chamber 70 is controlled: the gas cavity outlet flow opening adjustment component includes a connecting sleeve 1 72 and a connecting sleeve 2 721, the connecting sleeve 1 72 is detachably installed at both ends of the hydrogen discharge pipe 7, the outer side surface of the connecting sleeve 1 72 is fixedly connected to one side of the connecting sleeve 2 721, and an avoidance groove 7210 is opened on the inner wall of the upper end of the connecting sleeve 2 721, and an inner tooth ring 725 is movably installed on the inner side of the avoidance groove 7210, and the outer ring surface of the inner tooth ring 725 is fixedly provided with meshing teeth 7251; the upper surface of the connecting sleeve 1 72 is fixedly installed with a support block 72 2. A motor 723 is fixedly mounted on the outer surface of the support block 722. A driving gear 724 is fixedly connected to the output shaft of the motor 723. The outer surface of the driving gear 724 meshes and rotates with the outer surface of the meshing tooth 7251. Limiting rings are respectively arranged on both sides of the meshing tooth 7251. The limiting rings are respectively fixedly mounted on both sides of the inner gear ring 725. The outer surfaces of the two groups of limiting rings are rotatably connected with the inner walls of the connecting sleeve 1 72 and the connecting sleeve 2 721. A driven gear 726 is meshed and rotated on the inner side of the inner gear ring 725. A limiting column 7261 is fixedly connected to the central inner surface of the driven gear 726. The outer surface of one end of the limiting column 7261 is rotatably connected with the inner wall of the connecting sleeve 1 72. An adjusting plate 727 is fixedly connected to the outer surface of the limiting column 7261.
当需要控制氢气排出管7端口的开度大小时,通过控制马达723驱动,使得其输出轴转动带动主动齿轮724旋转,在旋转状态下,主动齿轮724与啮合齿7251的外表面之间适配啮合,如此实现内齿环725的转动,此时,当内齿环725限位转动过程中,内侧多组从动齿轮726同步转动,进而实现多组调节板727的同步活动,如此实现气体腔70端口开度的大小调节,具体而言,根据伯努利原理,流速与管道截面积成反比,当调节结构开度减小时,气体通过的面积减小,流速增加;当调节结构开度增大时,气体通过的面积增大,流速减小,进一步满足对气体流量进行精确控制的需求,并有助于提高整个气体处理的稳定性和可靠性。When it is necessary to control the opening size of the port of the hydrogen discharge pipe 7, the motor 723 is driven by controlling its output shaft to rotate and drive the driving gear 724 to rotate. In the rotating state, the driving gear 724 is adapted to mesh with the outer surface of the meshing tooth 7251, thereby realizing the rotation of the inner gear ring 725. At this time, when the inner gear ring 725 is limited and rotated, multiple groups of driven gears 726 on the inside rotate synchronously, thereby realizing the synchronous movement of multiple groups of adjustment plates 727, thereby realizing the size adjustment of the opening size of the port of the gas chamber 70. Specifically, according to Bernoulli's principle, the flow rate is inversely proportional to the cross-sectional area of the pipeline. When the opening of the adjustment structure decreases, the area through which the gas passes decreases and the flow rate increases; when the opening of the adjustment structure increases, the area through which the gas passes increases and the flow rate decreases, further meeting the demand for precise control of the gas flow rate and helping to improve the stability and reliability of the entire gas processing.
实施例六中,参照附图1-图13,在实施例五的基础上,提出了AEM电解水制氢电解槽的使用方法,方法包括以下步骤:In Example 6, referring to Figures 1 to 13, on the basis of Example 5, a method for using an AEM water electrolysis hydrogen production electrolyzer is proposed, and the method comprises the following steps:
步骤一:在电解槽本体1的内侧设置相对分布的下弧形流道槽板61和上弧形流道槽板62,电解液进口51输入端外接抽吸泵,抽吸泵开启后,电解液经过电解液进口51导入上弧形流道槽板62内腔,一部分电解液经过上弯管621呈水帘状下落,一部分电解液通过导流直管63导入下弧形流道槽板61的内部,且通过导流直管63上均匀开设的圆形孔630喷出,如此实现电解液在电解槽本体1的内部进行循环流通,避免存在电解液难以接触的死区,提高电解液的流动性和分布均匀性;Step 1: A relatively distributed lower arc-shaped flow channel plate 61 and an upper arc-shaped flow channel plate 62 are arranged on the inner side of the electrolytic cell body 1, and an external suction pump is connected to the input end of the electrolyte inlet 51. After the suction pump is turned on, the electrolyte is introduced into the inner cavity of the upper arc-shaped flow channel plate 62 through the electrolyte inlet 51, and a part of the electrolyte falls in a water curtain shape through the upper curved pipe 621, and a part of the electrolyte is introduced into the interior of the lower arc-shaped flow channel plate 61 through the guide straight pipe 63, and is sprayed out through the circular holes 630 uniformly opened on the guide straight pipe 63, so that the electrolyte is circulated in the electrolytic cell body 1, avoiding the existence of a dead zone that is difficult for the electrolyte to contact, and improving the fluidity and distribution uniformity of the electrolyte;
步骤二:在下弧形流道槽板61与上弧形流道槽板62之间的电解液流动时,上弧形流道槽板62内腔的电解液受重力向下流出,利用多组阵列排布的上弯管621,使得电解液向扰流片642的表面进行流动,此时扰流片642受到外部电解液的冲击,配合轴杆641在弧形架64上的转动,实现扰流片642的旋转,如此实现电解槽内部电解液的扰动;Step 2: When the electrolyte flows between the lower arc-shaped flow channel plate 61 and the upper arc-shaped flow channel plate 62, the electrolyte in the inner cavity of the upper arc-shaped flow channel plate 62 flows downward due to gravity, and the electrolyte flows toward the surface of the spoiler 642 by using multiple groups of upper curved pipes 621 arranged in an array. At this time, the spoiler 642 is impacted by the external electrolyte, and the rotation of the shaft 641 on the arc frame 64 is coordinated to realize the rotation of the spoiler 642, thereby realizing the disturbance of the electrolyte inside the electrolytic cell;
步骤三:电解液持续反应产生氢气并透过气体扩散层板13释放出来,扩散气体上升,经过多组导气罩71进入的过程中,导流板712上安装的均布进气管7121将进气锥腔711的底部形成多个细小的通道,经过上升的气体由导气孔7122内部架设的分割板7123进行分割,将气体进行分散,避免直接向气体腔70的内部进行喷发,造成气体腔70内部气体压力过高的情况,进一步提升形成气体的稳定排出;Step 3: The electrolyte continuously reacts to generate hydrogen and is released through the gas diffusion layer 13. The diffused gas rises and enters through the multiple groups of gas guide covers 71. The evenly distributed air inlet pipes 7121 installed on the guide plate 712 form multiple small channels at the bottom of the air inlet cone cavity 711. The rising gas is divided by the dividing plate 7123 set up inside the gas guide hole 7122, and the gas is dispersed to avoid directly erupting into the gas cavity 70, causing the gas pressure inside the gas cavity 70 to be too high, and further improve the stable discharge of the formed gas;
步骤四:通过控制马达723驱动,使得其输出轴转动带动主动齿轮724旋转,在旋转状态下,主动齿轮724与啮合齿7251的外表面之间适配啮合,如此实现内齿环725的转动,此时,当内齿环725限位转动过程中,内侧多组从动齿轮726同步转动,进而实现多组调节板727的同步活动,如此实现气体腔70端口开度的大小调节,具体而言,根据伯努利原理,流速与管道截面积成反比,当调节结构开度减小时,气体通过的面积减小,流速增加;当调节结构开度增大时,气体通过的面积增大,流速减小,进一步满足对气体流量进行精确控制的需求,并有助于提高整个气体处理的稳定性和可靠性。Step 4: By controlling the motor 723 to drive, its output shaft rotates to drive the driving gear 724 to rotate. In the rotating state, the driving gear 724 is adapted to mesh with the outer surface of the meshing tooth 7251, so that the rotation of the inner gear ring 725 is realized. At this time, when the inner gear ring 725 is limited and rotated, multiple groups of driven gears 726 on the inside rotate synchronously, thereby realizing the synchronous movement of multiple groups of adjustment plates 727, so as to realize the size adjustment of the opening of the gas chamber 70 port. Specifically, according to Bernoulli's principle, the flow rate is inversely proportional to the cross-sectional area of the pipeline. When the opening of the adjustment structure decreases, the area through which the gas passes decreases and the flow rate increases; when the opening of the adjustment structure increases, the area through which the gas passes increases and the flow rate decreases, which further meets the demand for precise control of the gas flow and helps to improve the stability and reliability of the entire gas processing.
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the present invention, and that the scope of the present invention is defined by the appended claims and their equivalents.
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