CN118853011B - Modified water-oxygen barrier film, flexible perovskite battery, and preparation methods and applications thereof - Google Patents
Modified water-oxygen barrier film, flexible perovskite battery, and preparation methods and applications thereof Download PDFInfo
- Publication number
- CN118853011B CN118853011B CN202411339177.4A CN202411339177A CN118853011B CN 118853011 B CN118853011 B CN 118853011B CN 202411339177 A CN202411339177 A CN 202411339177A CN 118853011 B CN118853011 B CN 118853011B
- Authority
- CN
- China
- Prior art keywords
- layer
- oxygen barrier
- water
- film
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000004888 barrier function Effects 0.000 title claims abstract description 118
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 107
- 239000001301 oxygen Substances 0.000 title claims abstract description 107
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 65
- 239000000853 adhesive Substances 0.000 claims abstract description 25
- 230000001070 adhesive effect Effects 0.000 claims abstract description 25
- 239000010410 layer Substances 0.000 claims description 129
- 239000002313 adhesive film Substances 0.000 claims description 52
- 239000011248 coating agent Substances 0.000 claims description 39
- 238000000576 coating method Methods 0.000 claims description 39
- -1 polyethylene terephthalate Polymers 0.000 claims description 37
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 230000002708 enhancing effect Effects 0.000 claims description 21
- 239000012790 adhesive layer Substances 0.000 claims description 20
- 229920002635 polyurethane Polymers 0.000 claims description 20
- 239000004814 polyurethane Substances 0.000 claims description 20
- 239000004831 Hot glue Substances 0.000 claims description 18
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 18
- 239000002516 radical scavenger Substances 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 16
- 229940123457 Free radical scavenger Drugs 0.000 claims description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 229920002397 thermoplastic olefin Polymers 0.000 claims description 11
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 claims description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 10
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 10
- 239000002390 adhesive tape Substances 0.000 claims description 8
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 8
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims description 7
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 7
- 239000004642 Polyimide Substances 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 239000011888 foil Substances 0.000 claims description 6
- 238000010030 laminating Methods 0.000 claims description 6
- 229920001721 polyimide Polymers 0.000 claims description 6
- 238000002834 transmittance Methods 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 5
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 230000002093 peripheral effect Effects 0.000 claims description 5
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 229920000307 polymer substrate Polymers 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 4
- 229920001780 ECTFE Polymers 0.000 claims description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
- 239000002033 PVDF binder Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 229920002620 polyvinyl fluoride Polymers 0.000 claims description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 4
- MWPUWFXSWHXSAB-UHFFFAOYSA-N N1=NN=CC2=C1C=CC=C2.OC2=C(C=CC=C2)O Chemical class N1=NN=CC2=C1C=CC=C2.OC2=C(C=CC=C2)O MWPUWFXSWHXSAB-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- QKYQJGWRJWJDII-UHFFFAOYSA-N benzene-1,2-diol;2h-benzotriazole Chemical class OC1=CC=CC=C1O.C1=CC=CC2=NNN=C21 QKYQJGWRJWJDII-UHFFFAOYSA-N 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- MABAWBWRUSBLKQ-UHFFFAOYSA-N ethenyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C=C MABAWBWRUSBLKQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002346 layers by function Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 238000005538 encapsulation Methods 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 229920006334 epoxy coating Polymers 0.000 claims 2
- 239000011527 polyurethane coating Substances 0.000 claims 2
- 239000012943 hotmelt Substances 0.000 claims 1
- 229920005549 butyl rubber Polymers 0.000 abstract description 21
- 238000000034 method Methods 0.000 abstract description 7
- 238000003475 lamination Methods 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 12
- 239000003973 paint Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 230000003014 reinforcing effect Effects 0.000 description 7
- 239000006096 absorbing agent Substances 0.000 description 6
- 239000012669 liquid formulation Substances 0.000 description 6
- 230000032683 aging Effects 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 229920006124 polyolefin elastomer Polymers 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920005570 flexible polymer Polymers 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- SITYOOWCYAYOKL-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(3-dodecoxy-2-hydroxypropoxy)phenol Chemical compound OC1=CC(OCC(O)COCCCCCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 SITYOOWCYAYOKL-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 238000000231 atomic layer deposition Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229920000891 common polymer Polymers 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 230000033001 locomotion Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012536 packaging technology Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005903 polyol mixture Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000012945 sealing adhesive Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/50—Photovoltaic [PV] devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/80—Constructional details
- H10K30/88—Passivation; Containers; Encapsulations
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/322—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of solar panels
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/20—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
- C09J2301/208—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive layer being constituted by at least two or more adjacent or superposed adhesive layers, e.g. multilayer adhesive
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
Abstract
本发明公开了一种改性水氧阻隔膜、柔性钙钛矿电池及其制备方法、应用，属于柔性钙钛矿太阳能电池技术领域。本发明的改性水氧阻隔膜，包括基层水氧阻隔材料、粘接增强层和丁基胶层，所述粘接增强层涂覆在基层水氧阻隔材料的表面外围，所述基层水氧阻隔材料和丁基胶层通过粘接增强层粘接；所述粘接增强层的厚度为1‑10μm，所述丁基胶层的厚度为50‑1000μm。本发明在丁基胶与基层水氧阻隔材料之间引入粘接增强层，可以在层压过程中实现丁基胶和基层水氧阻隔材料界面更好的界面粘接，粘接力大、施工简单、成本低，可以有效改善丁基胶与水氧阻隔膜界面粘接力低的问题。
The present invention discloses a modified water-oxygen barrier film, a flexible perovskite battery and a preparation method and application thereof, and belongs to the technical field of flexible perovskite solar cells. The modified water-oxygen barrier film of the present invention comprises a base water-oxygen barrier material, an adhesive enhancement layer and a butyl rubber layer, wherein the adhesive enhancement layer is coated on the surface periphery of the base water-oxygen barrier material, and the base water-oxygen barrier material and the butyl rubber layer are bonded by the adhesive enhancement layer; the thickness of the adhesive enhancement layer is 1-10 μm, and the thickness of the butyl rubber layer is 50-1000 μm. The present invention introduces an adhesive enhancement layer between the butyl rubber and the base water-oxygen barrier material, which can achieve better interface bonding between the butyl rubber and the base water-oxygen barrier material during the lamination process, has large bonding force, simple construction and low cost, and can effectively improve the problem of low bonding force between the butyl rubber and the water-oxygen barrier film interface.
Description
Technical Field
The invention belongs to the technical field of flexible perovskite solar cells, and particularly relates to a modified water-oxygen barrier film, a flexible perovskite cell, a preparation method and application thereof.
Background
Perovskite batteries are used as novel photovoltaic cells, have the advantages of high efficiency, low cost, flexibility and the like, but the use stability of the perovskite batteries is still a key challenge. The packaging can well solve the stability problem and prolong the service life of equipment, and the reliable packaging technology can realize excellent sealing performance of the packaging, so that a stable working environment is formed, the invasion of external water and oxygen is prevented, and the products of battery decomposition can be prevented from overflowing from the system. The problem of water vapor permeation at the edges of perovskite batteries is a key factor limiting the use of perovskite batteries, and the water vapor permeation can cause chemical reactions of materials inside the batteries, thereby affecting the performance and the service life of the batteries. The side methyl groups in the butyl rubber molecular chain are densely arranged, so that the thermal movement of polymer molecules is limited, and the butyl rubber has lower water vapor permeability and good air tightness. At present, the durability of the glass-based perovskite solar cell can be improved by using a simple and low-cost encapsulation technology of polyisobutene, polyolefin low-temperature adhesive films and glass combination.
The flexible perovskite photovoltaic is a novel solar cell technology with wider application scenes, and can meet the requirements of different fields on efficient, lightweight and flexible solar power supplies. The ultra-light and ultra-thin flexible perovskite device is prepared on the micron-sized polymer substrate, so that the requirements of high efficiency and ultra-light and thin can be met, and the ultra-light and ultra-thin perovskite device has outstanding high-mass specific power. However, the polymer substrate is made of common polymer materials such as PET (polyethylene terephthalate), PEN (polyethylene naphthalate), PI (polyimide) and the like, and the water vapor barrier property of the substrate is poor, so that higher requirements are put on flexible perovskite battery packaging. The device is typically packaged using a combination of ultra-high water-oxygen barrier film in combination with a polyolefin film and butyl rubber, which is required to ensure a moisture barrier level (< 10 -3g/m2/day) across the upper and lower surfaces of the cell. Because the water blocking performance of the adhesive film is poor (generally more than 5g/m 2/day), the higher requirement is put on the water vapor blocking performance of the edge of the battery, and the high-performance formula butyl adhesive is required to be adopted for sealing the edge of the component, so that the water vapor is blocked outside in the quality guarantee period of the component, and the sealing adhesive is not penetrated so as to enter the battery area.
The interface adhesion between the butyl rubber and the flexible polymer base material is poor, and under the effects of various ageing and external force bending, the phenomenon of interface layering easily occurs, so that water vapor is quickly permeated into the battery from the layered interface, and the battery is caused to fail.
The Chinese patent CN118271980A provides a photovoltaic module, a manufacturing method thereof and a battery module, wherein the photovoltaic module comprises a plurality of layers of film materials, at least one layer of film material in the plurality of layers of film materials is a micro-crosslinking film with thermosetting property, and the rest film materials except the micro-crosslinking film in the plurality of layers of film materials are adhesive films with thermoplasticity. According to the technical scheme, the problem that the photovoltaic adhesive film is softened and deformed at high temperature can be solved, and the mechanical strength of the photovoltaic adhesive film can be effectively improved, so that when the photovoltaic adhesive film is applied to a battery assembly, the stability of the battery assembly can be improved by the micro-crosslinked film with thermosetting property, and the problems that the mechanical load of the battery assembly is reduced and the backboard is separated at high temperature are solved. However, the proposal does not relate to the use of butyl adhesive films, and can not solve the problem of water vapor permeation at the edge caused by poor interfacial adhesion between butyl adhesive and a flexible polymer substrate.
Therefore, how to effectively solve the water vapor permeation at the edge of the flexible perovskite battery is a technical problem to be solved in the present day.
Disclosure of Invention
In view of the above, the invention aims to provide a packaged flexible perovskite battery and a preparation method thereof, and the adhesive enhancement layer is introduced at the edge, so that the fastness between butyl rubber and a water vapor barrier film substrate is improved, and the problems of delamination and water vapor entering at the interface from the edge of the butyl rubber after aging are prevented, thereby effectively prolonging the service life of the flexible perovskite battery.
In order to achieve the above object, the present invention has the following technical scheme:
The invention provides a modified water-oxygen barrier film, which comprises a base water-oxygen barrier material, an adhesion enhancement layer and a butyl adhesive layer, wherein the adhesion enhancement layer is coated on the periphery of the surface of the base water-oxygen barrier material, the base water-oxygen barrier material and the butyl adhesive layer are adhered through the adhesion enhancement layer, the thickness of the adhesion enhancement layer is 1-10 mu m, and the thickness of the butyl adhesive layer is 50-1000 mu m;
the base layer water-oxygen barrier material is a transparent water-oxygen barrier material or a non-transparent water-oxygen barrier material, the transparent water-oxygen barrier material comprises a weather-resistant layer, a coating substrate and a water-oxygen barrier layer, and the non-transparent water-oxygen barrier material comprises a weather-resistant layer (outer layer), an aluminum foil layer, a polymer substrate and a weather-resistant layer (inner layer);
The adhesion enhancement layer consists of, by weight, 85-97 parts of polyurethane hot melt adhesive, 1-5 parts of silane coupling agent, 1-5 parts of ultraviolet absorber and 1-5 parts of free radical scavenger;
wherein the viscosity of the polyurethane hot melt adhesive is 3000-30000 mPa.s.
Preferably, the adhesion enhancing layer has a thickness of 2-5 μm.
Preferably, in one specific embodiment of the present invention, the width of the adhesion enhancing layer is 5mm at the peripheral edge of the surface of the water-oxygen barrier material of the base layer, and the width of the butyl rubber layer is 10-20mm.
Preferably, in the transparent water oxygen barrier material:
The coating substrate is at least one selected from polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polyethylene, polypropylene, polyimide and polytetrafluoroethylene, and can be a single layer or a plurality of layers, wherein the thickness of the coating substrate is 5-500 mu m, and more preferably 12-100 mu m;
the water-oxygen barrier layer is an inorganic barrier layer or a pair of layers comprising an inorganic barrier layer or an organic barrier layer;
The weather-proof layer is selected from a weather-proof coating or a weather-proof film layer, the weather-proof coating is selected from one or more of fluorine-containing paint, acrylic paint, polyester paint, epoxy paint and polyurethane paint, and the weather-proof film layer is a film containing polyvinyl fluoride, polyvinylidene fluoride, ethylene-tetrafluoroethylene copolymer, ethylene-chlorotrifluoroethylene copolymer or modified polyvinyl chloride.
Preferably, in the non-transparent water oxygen barrier material:
the thickness of the aluminum foil layer is 10-40 μm.
The polymeric substrate is polyethylene terephthalate.
The weather-proof layer is selected from a weather-proof coating or a weather-proof film layer, the weather-proof coating is one or more of fluorine-containing paint, acrylic acid paint, polyester paint, epoxy paint and polyurethane paint, and the weather-proof film layer is a film made of at least one material selected from polyvinyl fluoride, polyvinylidene fluoride, ethylene-tetrafluoroethylene copolymer, ethylene-chlorotrifluoroethylene copolymer and modified polyvinyl chloride. As a specific example, the base water-oxygen barrier material may be prepared by a vacuum coating method, and further preferably, the vacuum coating method is at least one selected from the group consisting of plasma chemical vapor deposition, magnetron sputtering and atomic layer deposition, and the water vapor permeability of the base water-oxygen barrier material is not higher than 5×10 -3g/m2/day (in the present invention, the test condition is 38 ℃, the humidity is 100% rh, and the rh is Relative Humidity (relative humidity) english abbreviation).
Preferably, the viscosity of the polyurethane hot melt adhesive is 3000-30000 mPa.s.
Preferably, the silane coupling agent is at least one selected from vinyltrimethoxysilane, vinyltris (beta-methoxyethoxy) silane, vinyltriisopropoxysilane, vinyltriethoxysilane, gamma-methacryloxypropyl trimethoxysilane, vinyltriacetoxysilane.
Preferably, the ultraviolet absorber is at least one selected from the group consisting of hydroxyphenol benzotriazoles and hydroxyphenol benzotriazines.
Preferably, the radical scavenger is a hindered amine radical scavenger.
Preferably, the butyl rubber layer is a butyl rubber tape or is prepared by coating butyl rubber, and the thickness is 40-120 mu m. Further preferably, the thickness of the butyl rubber layer is 50-1000 μm.
As a specific example of the invention, the width of the butyl rubber layer is 10-20mm.
In a second aspect, the present invention provides a method for preparing the water-oxygen barrier film, comprising the steps of:
(1) Coating the peripheral edge of the surface of the water-oxygen barrier film with coating liquid prepared by the adhesion enhancing layer, and curing completely under moisture;
(2) And (3) coating butyl glue or pasting butyl adhesive tape on the upper surface of the cured bonding enhancement layer to form a butyl adhesive layer.
In a third aspect, the present invention provides the use of a water-oxygen barrier film as described above in encapsulating perovskite cells.
Preferably, the perovskite cell is a flexible perovskite cell.
In a fourth aspect, the invention provides a flexible perovskite battery, which sequentially comprises a window water-oxygen barrier film, an upper adhesive film, a flexible perovskite battery piece, a lower adhesive film and a bottom water-oxygen barrier film from top to bottom, wherein the window water-oxygen barrier film and the bottom water-oxygen barrier film are the modified water-oxygen barrier film.
Preferably, the upper adhesive film is a UV-light conversion thermoplastic polyolefin adhesive film, which can convert ultraviolet light into visible light, and has a thickness of 50-500 mu m.
The term "UV light conversion" means converting ultraviolet light into visible light.
Further preferably, the transmittance of the UV light-converting thermoplastic polyolefin adhesive film under the light with the wavelength of 380-1100nm is more than or equal to 85%, and the transmittance of the UV light with the wavelength of 280-380nm is less than 0.5%.
Preferably, the lower adhesive film is a thermoplastic polyolefin adhesive film with the thickness of 50-500 mu m.
Further preferably, the transmittance of the thermoplastic polyolefin adhesive film under the light with the wavelength of 380-1100nm is more than or equal to 85%.
Preferably, the flexible perovskite battery piece comprises a support substrate, a perovskite battery device functional layer and a conductive tape.
Further preferably, the supporting substrate is selected from at least one of polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polyethylene, polypropylene and polyimide, and is a single-layer or multi-layer film, and the thickness of the supporting substrate is 20-300 mu m;
further preferably, the perovskite battery device functional layer is selected from one of formal (n-i-p) or trans-structure (p-i-n);
further preferably, the conductive adhesive tape is a tinned copper tape containing a pressure sensitive conductive adhesive.
In a fifth aspect, the present invention provides a method for preparing the flexible perovskite battery, comprising the steps of:
(1) Paving an adhesive film on the surface of the water-oxygen barrier film of the window;
(2) Paving a flexible perovskite battery piece on the surface of the upper adhesive film in the step (1);
(3) Paving a lower adhesive film on the surface of the flexible perovskite battery piece in the step (2);
(4) Paving a bottom water oxygen barrier film on the surface of the lower adhesive film in the step (3);
(5) Laminating the materials paved in the step (4) to obtain the flexible perovskite battery.
Preferably, in the step (5), the lamination condition is that the temperature is 105-120 ℃, the pressure is 60-90KPa and the time is 10-30min, and further preferably, the lamination condition is that the temperature is 115 ℃, the pressure is 80KPa and the time is 20min.
The beneficial effects of the invention are as follows:
(1) According to the invention, the adhesion enhancement layer is introduced between the butyl rubber and the water-oxygen barrier film, and meanwhile, the adhesion enhancement layer consists of the polyurethane hot melt adhesive, the silane coupling agent, the ultraviolet absorbent and the free radical scavenger in a specific proportion, so that better interface adhesion of the butyl rubber and the water-oxygen barrier film can be realized in the lamination process, the adhesion force is high, the construction is simple, and the cost is low. And the width of the bonding enhancement layer is controlled to be smaller than that of the butyl adhesive layer, so that the butyl adhesive can effectively prevent the water vapor at the edge from penetrating into the battery, and the problem of layering and water permeability caused by low bonding force between the edge of the butyl adhesive and the water-oxygen barrier film can be solved.
(2) After the polyurethane hot melt adhesive, the silane coupling agent, the ultraviolet absorbent and the free radical scavenger are compounded according to a specific proportion, the interfacial adhesion after initiation and aging is obviously improved, the material has longer service life, and the long-term working stability of the adhesion enhancement layer at low temperature and high temperature is ensured.
(3) The UV light conversion adhesive film is adopted by the upper adhesive film, so that the photoelectric conversion efficiency of the flexible perovskite battery can be improved, the ultraviolet irradiation stability of the packaged flexible perovskite battery can be effectively improved, the interface adhesion between the water-oxygen barrier and the whole surface of the perovskite battery piece is improved, and the service life of the battery is prolonged.
Drawings
FIG. 1 is a schematic structural view of a flexible perovskite battery of the invention;
In the figure, a 1-window water oxygen barrier film, a 2-upper adhesive film, a 3-flexible perovskite cell slice, a 4-lower adhesive film and a 5-bottom water oxygen barrier film are shown.
FIG. 2 is a top view of the edge structure of the modified water-oxygen barrier film of the present invention;
in the figure, 11-base layer water oxygen barrier material and 13-butyl adhesive layer.
FIG. 3 is a cross-sectional view of a modified water oxygen barrier film of the present invention;
in the figure, the water oxygen barrier material of the 11-base layer, the bonding enhancement layer of the 12-base layer and the 13-butyl adhesive layer are shown.
Detailed Description
The following non-limiting examples will enable those of ordinary skill in the art to more fully understand the invention and are not intended to limit the invention in any way. The following is merely exemplary of the scope of the invention as claimed and many variations and modifications of the invention will be apparent to those skilled in the art in light of the disclosure, which should be construed to fall within the scope of the invention as claimed.
The invention is further illustrated by means of the following specific examples. The various chemical reagents used in the examples of the present invention were obtained by conventional commercial means unless otherwise specified. Unless otherwise specified, the contents are mass contents in the following. Unless otherwise indicated, it is understood that it is carried out at room temperature.
In the following examples:
The base layer water oxygen barrier material was 35cm by 35cm in size (U.S. 3M, UBF 512).
The butyl tape WVTR is less than or equal to 3X 10 -2g/m2/day (test condition 38 ℃,100 RH%).
UV light-converting adhesive films, saiwu Raybo series thermoplastic POE (polyolefin elastomer), gram weight 500g/m 2, adhesive film dimensions 320mm x 320mm.
The lower adhesive film is thermoplastic polyolefin elastomer (TPO) with gram weight of 100g/m 2 and adhesive film size of 320mm multiplied by 320mm.
The model SF-01-35X 35 of the flexible perovskite battery piece.
The polyurethane hot melt adhesive (SUNTIP 2011L) is a liquid reaction type single-component polyurethane hot melt adhesive, which is prepared by taking a polyol mixture as a soft chain segment and excessive diisocyanate as a hard chain segment through reaction. The viscosity is 10000-20000 mPa.s (25 ℃). The hot melt adhesive has excellent adhesive strength to PET film and other base materials, excellent high temperature and high humidity resistance and high temperature peeling strength.
Example 1
(1) Coating liquid for coating an adhesion enhancing layer on the periphery of the inner surface of the base layer water-oxygen barrier material (35 cm×35 cm), the formulation of the coating liquid for the adhesion enhancing layer is as follows:
Polyurethane hot melt adhesive (SUNTIP 2011L) 85%
Silane coupling agent (vinyltris (. Beta. -methoxyethoxy) silane) 5%
UV absorber (BASF Tinuvin 479) 5%
5% Of free radical scavenger (BASF Tinuvin 123),
Curing at 40RH% humidity for 60min, and completely curing to obtain an adhesive reinforcing layer with width of 5mm and thickness of 5 μm.
And (3) applying a butyl adhesive tape on the surface of the adhesion enhancement layer, wherein the width is 10mm, and the thickness is 650 mu m, so as to obtain the modified water-oxygen barrier film.
(2) The water-oxygen barrier film is used as a window transparent water-oxygen barrier film, and an upper adhesive film (the upper adhesive film is UV light conversion adhesive films, saiwu Raybo series) is paved on the surface of the window transparent water-oxygen barrier film, and the gram weight is 500g/m 2.
(3) And placing a flexible perovskite battery piece on the surface of the upper adhesive film.
(4) And paving a lower adhesive film on the surface of the flexible perovskite battery, wherein the gram weight is 100g/m 2.
(5) And paving a water-oxygen barrier film on the surface of the lower adhesive film to serve as a bottom water-oxygen barrier film.
(6) The laid material is put into a laminating machine, the laminating temperature is 115 ℃, the laminating pressure is 80KPa, and the laminating time is 20min. And cooling to complete the flexible perovskite solar cell package.
The structure of the obtained flexible perovskite battery is shown in figure 1, the flexible perovskite battery sequentially comprises a window water-oxygen barrier film 1, an upper adhesive film 2, a flexible perovskite battery piece 3, a lower adhesive film 4 and a bottom water-oxygen barrier film 5 from top to bottom, wherein the window water-oxygen barrier film 1 and the bottom water-oxygen barrier film 5 are both modified water-oxygen barrier films, as shown in figure 2, the modified water-oxygen barrier films comprise a base water-oxygen barrier material 11, an adhesion enhancement layer 12 and a butyl adhesive layer 13, the adhesion enhancement layer is coated on the periphery of the surface of the base water-oxygen barrier material, and the base water-oxygen barrier material and the butyl adhesive layer are adhered through the adhesion enhancement layer.
Example 2
Unlike example 1, the coating liquid formulation of the adhesion enhancing layer was as follows:
polyurethane hot melt adhesive (SUNTIP 2011L) 90%
Silane coupling agent (vinyltris (. Beta. -methoxyethoxy) silane) 4%
UV absorber (BASF Tinuvin 479) 4%
2% Of free radical scavenger (BASF Tinuvin 123),
Curing at 40RH% humidity for 60min, and completely curing to obtain an adhesive reinforcing layer with width of 5mm and thickness of 5 μm.
The remainder was the same as in example 1.
Example 3
Unlike example 2, the coating liquid formulation of the adhesion enhancing layer was as follows:
polyurethane hot melt adhesive (SUNTIP 2011L) 93%
Silane coupling agent (vinyltris (. Beta. -methoxyethoxy) silane) 3%
UV absorber (BASF Tinuvin 479) 3%
1% Of free radical scavenger (BASF Tinuvin 123),
Curing at 40RH% humidity for 60min, and completely curing to obtain an adhesive reinforcing layer with width of 5mm and thickness of 5 μm.
The remainder was the same as in example 2.
Example 4
Unlike example 2, the coating liquid formulation of the adhesion enhancing layer was as follows:
polyurethane hot melt adhesive (SUNTIP 2011L) 95%
Silane coupling agent (vinyltris (. Beta. -methoxyethoxy) silane) 2%
UV absorber (BASF Tinuvin 479) 1%
2% Of free radical scavenger (BASF Tinuvin 123),
Curing at 40RH% humidity for 60min, and completely curing to obtain an adhesive reinforcing layer with width of 5mm and thickness of 5 μm.
The remainder was the same as in example 2.
Example 5
Unlike example 2, the coating liquid formulation of the adhesion enhancing layer was as follows:
polyurethane hot melt adhesive (SUNTIP 2011L) 97%
Silane coupling agent (vinyltris (. Beta. -methoxyethoxy) silane) 1%
UV absorber (BASF Tinuvin 479) 1%
1% Of free radical scavenger (BASF Tinuvin 123),
Curing at 40RH% humidity for 60min, and completely curing to obtain an adhesive reinforcing layer with width of 5mm and thickness of 5 μm.
The remainder was the same as in example 2.
Example 6
Unlike example 2, the silane coupling agent was γ -methacryloxypropyl trimethoxysilane, and the remainder was the same as in example 2.
Example 7
Unlike example 2, the silane coupling agent was vinyltriacetoxy silane, and the remainder was the same as in example 2.
Example 8
Unlike example 1, the silane coupling agent was vinyltriacetoxy silane, and the remainder was the same as in example 1.
Example 9
Unlike example 2, the ultraviolet absorber was BASF Tinuvin 400, the radical scavenger was BASF Tinuvin 123, and the remainder was the same as in example 2.
Example 10
Unlike example 2, the adhesion enhancing layer had a thickness of 10 μm, and the remainder was the same as in example 2.
Example 11
Unlike example 2, the adhesion enhancing layer had a thickness of 2 μm, and the remainder was the same as in example 2.
Example 12
Unlike example 2, the adhesion enhancing layer had a thickness of 1 μm, and the remainder was the same as in example 2.
Comparative example 1
Unlike example 2, comparative example 1 did not prepare an adhesion enhancing layer, and the rest was the same as example 2.
Comparative example 2
Different from example 2, a non-UV light-converting thermoplastic POE adhesive film is paved on the surface of the transparent water-oxygen barrier film of the window, the gram weight is 450g/m 2, the adhesive film size is 320mm multiplied by 320mm, and the rest is the same as example 2.
Comparative example 3
Unlike example 2, the coating liquid formulation of the adhesion enhancing layer was as follows:
polyurethane hot melt adhesive (SUNTIP 2011L) 98%
Silane coupling agent (vinyltris (. Beta. -methoxyethoxy) silane) 1%
UV absorber (BASF Tinuvin 479) 0.5%
0.5% Of free radical scavenger (BASF Tinuvin 123),
Curing at 40RH% humidity for 60min, and completely curing to obtain an adhesive reinforcing layer with width of 5mm and thickness of 5 μm.
The remainder was the same as in example 2.
Comparative example 4
Unlike example 2, the adhesion enhancing layer had a thickness of 15 μm, and the remainder was the same as in example 2.
Comparative example 5
Unlike example 2, the adhesion enhancing layer had a thickness of 0.5 μm, and the remainder was the same as in example 2.
Comparative example 6
Unlike example 2, the coating liquid formulation of the adhesion enhancing layer was as follows:
polyurethane hot melt adhesive (SUNTIP 2011L) 90%
Silane coupling agent (vinyltris (. Beta. -methoxyethoxy) silane) 4%
An ultraviolet absorber (BASF Tinuvin 479) 6%,
Curing at 40RH% humidity for 60min, and completely curing to obtain an adhesive reinforcing layer with width of 5mm and thickness of 5 μm.
The remainder was the same as in example 2.
Results testing
The flexible perovskite batteries prepared in the above examples and comparative examples were subjected to an interlayer adhesion test of a butyl rubber and a water-oxygen barrier film, a photoelectric conversion efficiency test, and an interlayer adhesion test and a photoelectric conversion efficiency test after aging respectively by a damp-heat test DH1000 (ultra-high stability is required for continuous operation for more than 1000 hours in a state of 85 ℃ and 85% RH) and an ultraviolet irradiation amount UV120kWh/m 2.
The testing method comprises the following steps:
(1) Interlayer adhesion test was performed according to GB/T2790-1995, 180℃peel strength test method of the adhesive.
(2) The photoelectric conversion efficiency test is carried out according to GB/T34160-2017 'method for detecting photoelectric conversion efficiency of photovoltaic component for ground'.
The test results were as follows:
Table 1.
Table 2.
The result shows that the flexible perovskite battery prepared by the embodiment of the invention has better improved binding force and durability. As can be seen from the results of the comparative examples, the arrangement of the adhesion enhancing layer, the composition formulation and the thickness have significant effects on the thickness of the battery, and in addition, the selection of the non-light-converting adhesive film for the upper adhesive film significantly reduces the photoelectric conversion efficiency.
Claims (13)
1. The flexible perovskite battery is characterized by sequentially comprising a window water-oxygen barrier film, an upper adhesive film, a flexible perovskite battery piece, a lower adhesive film and a bottom water-oxygen barrier film from top to bottom, wherein the window water-oxygen barrier film and the bottom water-oxygen barrier film are modified water-oxygen barrier films;
The upper adhesive film is a UV light conversion thermoplastic polyolefin adhesive film;
The modified water-oxygen barrier film comprises a base water-oxygen barrier material, an adhesion enhancement layer and a butyl adhesive layer, wherein the adhesion enhancement layer is coated on the periphery of the surface of the base water-oxygen barrier material, the base water-oxygen barrier material and the butyl adhesive layer are adhered through the adhesion enhancement layer, the thickness of the adhesion enhancement layer is 1-10 mu m, and the thickness of the butyl adhesive layer is 50-1000 mu m;
The base layer water-oxygen barrier material is a transparent water-oxygen barrier material or a non-transparent water-oxygen barrier material, the transparent water-oxygen barrier material comprises a weather-resistant layer, a coating substrate and a water-oxygen barrier layer, and the non-transparent water-oxygen barrier material comprises an outer weather-resistant layer, an aluminum foil layer, a polymer substrate and an inner weather-resistant layer;
The adhesion enhancement layer consists of, by weight, 85-97 parts of polyurethane hot melt adhesive, 1-5 parts of silane coupling agent, 1-5 parts of ultraviolet absorber and 1-5 parts of free radical scavenger;
The adhesive enhancement layer is arranged at the peripheral edge of the surface of the water-oxygen barrier material of the base layer, the width is 5mm, and the width of the butyl adhesive layer is 10-20mm.
2. The flexible perovskite battery of claim 1, wherein the adhesion enhancing layer has a thickness of 2-5 μιη.
3. The flexible perovskite battery of claim 1, wherein in the transparent water oxygen barrier material:
the film-coated substrate is at least one of polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polyethylene, polypropylene, polyimide and polytetrafluoroethylene, the thickness of the film-coated substrate is 5-500 mu m, the water-oxygen barrier layer is an inorganic barrier layer or a pair layer containing an inorganic barrier layer or an organic barrier layer, the weather-resistant layer is a weather-resistant coating or a weather-resistant film layer, the weather-resistant coating is one or more of fluorine-containing coating, acrylic coating, polyester coating, epoxy coating and polyurethane coating, and the weather-resistant film layer is a film containing polyvinyl fluoride, polyvinylidene fluoride, ethylene-tetrafluoroethylene copolymer, ethylene-chlorotrifluoroethylene copolymer or modified polyvinyl chloride;
The non-transparent water-oxygen barrier material comprises an aluminum foil layer with the thickness of 10-40 mu m, a polymer base material of polyethylene terephthalate, and a weather-resistant layer selected from a weather-resistant coating or a weather-resistant film layer.
4. The flexible perovskite battery of claim 1, wherein the polyurethane hot melt adhesive has a viscosity of 3000-30000 mPa-s.
5. The flexible perovskite battery according to claim 1, wherein the silane coupling agent is selected from at least one of vinyltrimethoxysilane, vinyltris (β -methoxyethoxy) silane, vinyltriisopropoxysilane, vinyltriethoxysilane, γ -methacryloxypropyl trimethoxysilane, vinyltriacetoxysilane;
The ultraviolet absorber is at least one selected from the group consisting of hydroxyphenol benzotriazoles and hydroxyphenol benzotriazines;
The free radical scavenger is a hindered amine free radical scavenger;
the butyl adhesive layer is a butyl adhesive tape or is prepared by coating butyl adhesive.
6. The flexible perovskite battery according to claim 1, wherein the thickness of the UV light-converting thermoplastic polyolefin adhesive film is 50-500 μm, the transmittance of the UV light-converting thermoplastic polyolefin adhesive film under the light with the wavelength of 380-1100nm is more than or equal to 85%, and the transmittance in the UV wave band of 280-380nm is less than 0.5%;
The lower adhesive film is a thermoplastic polyolefin adhesive film with the thickness of 50-500 mu m, and the transmittance of the thermoplastic polyolefin adhesive film under the light with the wavelength of 380-1100nm is more than or equal to 85%;
The flexible perovskite battery piece comprises a supporting base material, a perovskite battery device functional layer and a conductive adhesive tape;
The supporting base material is at least one selected from polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polyethylene, polypropylene and polyimide, the thickness of the supporting base material is 20-300 mu m, and the conductive adhesive tape is tinned copper tape containing pressure-sensitive conductive adhesive.
7. A method of manufacturing a flexible perovskite battery as claimed in any one of claims 1 to 6, comprising the steps of:
(1) Paving an adhesive film on the surface of the water-oxygen barrier film of the window;
(2) Paving a flexible perovskite battery piece on the surface of the upper adhesive film in the step (1);
(3) Paving a lower adhesive film on the surface of the flexible perovskite battery piece in the step (2);
(4) Paving a bottom water oxygen barrier film on the surface of the lower adhesive film in the step (3);
(5) Laminating the materials paved in the step (4) to obtain the flexible perovskite battery.
8. The method of manufacturing according to claim 7, wherein the method of manufacturing the bottom water oxygen barrier film and the window water oxygen barrier film comprises the steps of:
(1) Coating the peripheral edge of the surface of the water-oxygen barrier film with coating liquid prepared by the adhesion enhancing layer, and curing completely under moisture;
(2) And (3) coating butyl glue or pasting butyl adhesive tape on the upper surface of the cured bonding enhancement layer to form a butyl adhesive layer.
9. The application of the modified water-oxygen barrier film in the encapsulation of the perovskite battery is characterized in that the modified water-oxygen barrier film comprises a base water-oxygen barrier material, an adhesion enhancement layer and a butyl adhesive layer, wherein the adhesion enhancement layer is coated on the periphery of the surface of the base water-oxygen barrier material, the base water-oxygen barrier material and the butyl adhesive layer are adhered through the adhesion enhancement layer, the thickness of the adhesion enhancement layer is 1-10 mu m, and the thickness of the butyl adhesive layer is 50-1000 mu m;
The base layer water-oxygen barrier material is a transparent water-oxygen barrier material or a non-transparent water-oxygen barrier material, the transparent water-oxygen barrier material comprises a weather-resistant layer, a coating substrate and a water-oxygen barrier layer, and the non-transparent water-oxygen barrier material comprises an outer weather-resistant layer, an aluminum foil layer, a polymer substrate and an inner weather-resistant layer;
The adhesion enhancement layer consists of, by weight, 85-97 parts of polyurethane hot melt adhesive, 1-5 parts of silane coupling agent, 1-5 parts of ultraviolet absorber and 1-5 parts of free radical scavenger;
The adhesive enhancement layer is arranged at the peripheral edge of the surface of the water-oxygen barrier material of the base layer, the width is 5mm, and the width of the butyl adhesive layer is 10-20mm.
10. The use according to claim 9, wherein the adhesion enhancing layer has a thickness of 2-5 μm.
11. The use according to claim 9, wherein in the transparent water-oxygen barrier material:
the film-coated substrate is at least one of polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polyethylene, polypropylene, polyimide and polytetrafluoroethylene, the thickness of the film-coated substrate is 5-500 mu m, the water-oxygen barrier layer is an inorganic barrier layer or a pair layer containing an inorganic barrier layer or an organic barrier layer, the weather-resistant layer is a weather-resistant coating or a weather-resistant film layer, the weather-resistant coating is one or more of fluorine-containing coating, acrylic coating, polyester coating, epoxy coating and polyurethane coating, and the weather-resistant film layer is a film containing polyvinyl fluoride, polyvinylidene fluoride, ethylene-tetrafluoroethylene copolymer, ethylene-chlorotrifluoroethylene copolymer or modified polyvinyl chloride;
The non-transparent water-oxygen barrier material comprises an aluminum foil layer with the thickness of 10-40 mu m, a polymer base material of polyethylene terephthalate, and a weather-resistant layer selected from a weather-resistant coating or a weather-resistant film layer.
12. The use according to claim 9, characterized in that the polyurethane hotmelt has a viscosity of 3000-30000 mPa-s.
13. The use according to claim 9, wherein the silane coupling agent is selected from at least one of vinyltrimethoxysilane, vinyltris (β -methoxyethoxy) silane, vinyltriisopropoxysilane, vinyltriethoxysilane, γ -methacryloxypropyl trimethoxysilane, vinyltriacetoxysilane;
The ultraviolet absorber is at least one selected from the group consisting of hydroxyphenol benzotriazoles and hydroxyphenol benzotriazines;
The free radical scavenger is a hindered amine free radical scavenger;
the butyl adhesive layer is a butyl adhesive tape or is prepared by coating butyl adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202411339177.4A CN118853011B (en) | 2024-09-25 | 2024-09-25 | Modified water-oxygen barrier film, flexible perovskite battery, and preparation methods and applications thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202411339177.4A CN118853011B (en) | 2024-09-25 | 2024-09-25 | Modified water-oxygen barrier film, flexible perovskite battery, and preparation methods and applications thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN118853011A CN118853011A (en) | 2024-10-29 |
| CN118853011B true CN118853011B (en) | 2025-01-14 |
Family
ID=93181292
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202411339177.4A Active CN118853011B (en) | 2024-09-25 | 2024-09-25 | Modified water-oxygen barrier film, flexible perovskite battery, and preparation methods and applications thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN118853011B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104884214A (en) * | 2013-01-18 | 2015-09-02 | Sika技术股份公司 | Method for producing a lining segment with a thermoplastic barrier layer |
| CN112510152A (en) * | 2020-12-15 | 2021-03-16 | 华能新能源股份有限公司 | Perovskite solar cell packaging structure and packaging method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012080060A (en) * | 2010-09-07 | 2012-04-19 | Mitsubishi Chemicals Corp | Organic solar battery module |
| CN207009447U (en) * | 2017-03-31 | 2018-02-13 | 乐凯胶片股份有限公司 | A solar cell double glass module |
| CN118574436A (en) * | 2024-05-28 | 2024-08-30 | 湖北万度光能有限责任公司 | Encapsulation structure, encapsulation method and application of perovskite solar cell |
-
2024
- 2024-09-25 CN CN202411339177.4A patent/CN118853011B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104884214A (en) * | 2013-01-18 | 2015-09-02 | Sika技术股份公司 | Method for producing a lining segment with a thermoplastic barrier layer |
| CN112510152A (en) * | 2020-12-15 | 2021-03-16 | 华能新能源股份有限公司 | Perovskite solar cell packaging structure and packaging method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN118853011A (en) | 2024-10-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101314698B1 (en) | Backside protective sheet for solar cell and solar cell module comprising the same | |
| US20090272436A1 (en) | Non-glass photovoltaic module and methods for manufacture | |
| JP6034308B2 (en) | Adhesive tape and solar cell assembly, and articles made therefrom | |
| US20050224108A1 (en) | Enhanced photovoltaic module | |
| WO2010150759A1 (en) | Organic electronic device and method for producing the same | |
| US20120080065A1 (en) | Thin Film Photovoltaic Modules with Structural Bonds | |
| EP1228536A1 (en) | Backside covering material for a solar cell module and its use | |
| CN207303123U (en) | A kind of high-barrier solar cell backboard | |
| CN103072349A (en) | Composite film for back plate of solar battery | |
| EP2571061A1 (en) | Backside protective sheet for solar cell and solar cell module comprising same | |
| JP2012064645A (en) | Organic photoelectric conversion element and method for manufacturing the same | |
| CN105990459A (en) | Flexible package composite film and manufacturing method thereof | |
| CN102272945A (en) | Frameless solar panel and manufacturing method thereof | |
| KR20120122541A (en) | Adhesive composition for encapsulating cell and adhesive film | |
| WO2010039836A1 (en) | Solar module having an encapsulant mounting adhesive | |
| CN102582175B (en) | Encapsulating material for solar cell module and use thereof | |
| JP5805366B2 (en) | Solar cell back surface protection sheet and solar cell module using the same | |
| CN215988795U (en) | Photovoltaic module and roofing structure | |
| CN118853011B (en) | Modified water-oxygen barrier film, flexible perovskite battery, and preparation methods and applications thereof | |
| JP2000307137A (en) | Solar cell cover film and solar cell module using the same | |
| US11984527B2 (en) | Method for manufacturing a photovoltaic module | |
| JP5644456B2 (en) | Solar cell back surface protection sheet, method for producing the sheet, and solar cell module | |
| CN109244166B (en) | Packaging front plate and preparation process thereof | |
| CN115763581A (en) | Solar cell front plate and preparation method thereof | |
| WO2023043448A1 (en) | Bendable photovoltaic device packaging structures and encapsulant material containing cured silicone |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |