CN118751057A - A device for controlling ultra-low emission of particulate matter in catalytic cracking flue gas - Google Patents
A device for controlling ultra-low emission of particulate matter in catalytic cracking flue gas Download PDFInfo
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 137
- 239000003546 flue gas Substances 0.000 title claims abstract description 137
- 238000004523 catalytic cracking Methods 0.000 title claims abstract description 22
- 239000013618 particulate matter Substances 0.000 title abstract description 22
- 239000000428 dust Substances 0.000 claims abstract description 166
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 124
- 230000023556 desulfurization Effects 0.000 claims abstract description 124
- 239000003595 mist Substances 0.000 claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 239000002245 particle Substances 0.000 claims abstract description 22
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 12
- 150000003568 thioethers Chemical class 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
- 239000002002 slurry Substances 0.000 claims description 38
- 238000011010 flushing procedure Methods 0.000 claims description 30
- 230000007246 mechanism Effects 0.000 claims description 30
- 239000007921 spray Substances 0.000 claims description 24
- 238000009833 condensation Methods 0.000 claims description 10
- 230000005494 condensation Effects 0.000 claims description 10
- 238000007789 sealing Methods 0.000 claims description 7
- 238000007667 floating Methods 0.000 claims description 3
- 239000007789 gas Substances 0.000 abstract description 7
- 239000002894 chemical waste Substances 0.000 abstract description 2
- 238000003795 desorption Methods 0.000 abstract 1
- 230000011218 segmentation Effects 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 19
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 16
- 238000005516 engineering process Methods 0.000 description 15
- 239000010408 film Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 238000010521 absorption reaction Methods 0.000 description 7
- 230000009471 action Effects 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 230000008859 change Effects 0.000 description 6
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 5
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000007791 dehumidification Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 101000827703 Homo sapiens Polyphosphoinositide phosphatase Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 102100023591 Polyphosphoinositide phosphatase Human genes 0.000 description 1
- 101100233916 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) KAR5 gene Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005200 wet scrubbing Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/80—Semi-solid phase processes, i.e. by using slurries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D45/00—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
- B01D45/04—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia
- B01D45/08—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia by impingement against baffle separators
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D45/00—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
- B01D45/12—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces
- B01D45/14—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces generated by rotating vanes, discs, drums or brushes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/266—Drying gases or vapours by filtration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B01D53/504—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
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Abstract
Description
技术领域Technical Field
本发明涉及化工废气排放前处理技术领域,尤其涉及一种催化裂化烟气颗粒物超低排放控制装置。The invention relates to the technical field of chemical waste gas emission pre-treatment, and in particular to an ultra-low emission control device for catalytic cracking flue gas particulate matter.
背景技术Background Art
催化裂化烟气脱硫除尘技术包括湿法、干法和半干法技术,通常具有除尘、脱硫一体化的功能,在三种技术中,以湿法脱硫技术为主,在湿法脱硫技术中,主要包含钠碱法、镁法、钙法和氨法等,其中,因催化裂化装置要求长周期稳定运行,以钠碱法应用最为广泛。Catalytic cracking flue gas desulfurization and dust removal technologies include wet, dry and semi-dry technologies, which usually have the integrated functions of dust removal and desulfurization. Among the three technologies, wet desulfurization technology is the main one. Among the wet desulfurization technologies, they mainly include sodium alkali method, magnesium method, calcium method and ammonia method. Among them, the sodium alkali method is the most widely used because the catalytic cracking unit requires long-term stable operation.
当前应用钠碱法脱硫的技术主要包括BELCO公司的EDV湿法脱硫技术、中石油中国昆仑工程有限公司大连分公司的WGS技术和中石化宁波工程公司“双循环湍冲文丘里脱硫除尘技术”等,利用以上技术的同时,因使用氢氧化钠等强碱性物质作为中和剂,二氧化硫可实现超低排放(≤35mg/Nm3),但颗粒物仅能维持在30mg/Nm3的控制指标,不能满足颗粒物超低排放要求的≤10mg/Nm3。The current sodium-alkali desulfurization technologies mainly include BELCO's EDV wet desulfurization technology, CNPC China Kunlun Engineering Co., Ltd. Dalian Branch's WGS technology and Sinopec Ningbo Engineering Company's "Dual Circulation Turbulent Venturi Desulfurization and Dust Removal Technology". While using the above technologies, due to the use of strong alkaline substances such as sodium hydroxide as neutralizers, sulfur dioxide can achieve ultra-low emissions (≤35mg/Nm3), but particulate matter can only be maintained at a control index of 30mg/Nm3, which cannot meet the ultra-low emission requirements of particulate matter of ≤10mg/Nm3.
催化裂化再生烟气中,因颗粒物粒径较小,大部分小于5μm,因此去除难度较大,EDV技术去除二氧化硫和颗粒物主要包括采用了模块化的组合,其吸收系统由多个部分组成,例如降温冷却和吸收模块、过滤器清洁模块和水珠分离器,这些都设置在一个塔上。烟道气体在通过洗涤塔时,冷却的区域的温度在达到了相应的饱和度时,就会将烟气当中体积大的粒子进行清除。在吸收液的吸收板块,其专属的喷嘴喷射的吸收液与SO2反向接触,最终去除SO2。在喷嘴上方的过滤单元当中清除细颗粒及微珠,经过净化的烟气在通过液滴分离器当中会进行液相以及气体的分离过程。液滴进行分离后产生清洁气体再通过上烟囱排放到大气中,并回收吸收性溶液。为了避免催化剂的积累,一些洗涤液将被排放到污水处理系统中。In the catalytic cracking regeneration flue gas, the particle size is small, most of which are less than 5μm, so it is difficult to remove. The EDV technology removes sulfur dioxide and particulate matter mainly by using a modular combination. Its absorption system consists of multiple parts, such as cooling and absorption modules, filter cleaning modules and water droplet separators, all of which are set on a tower. When the flue gas passes through the scrubber, when the temperature of the cooling area reaches the corresponding saturation, the large particles in the flue gas will be removed. In the absorption plate of the absorption liquid, the absorption liquid sprayed by its exclusive nozzle contacts SO2 in the opposite direction, and finally removes SO2. Fine particles and micro beads are removed in the filter unit above the nozzle, and the purified flue gas will undergo a liquid and gas separation process when passing through the droplet separator. After the droplets are separated, clean gas is generated and then discharged into the atmosphere through the upper chimney, and the absorbent solution is recovered. In order to avoid the accumulation of catalysts, some washing liquid will be discharged into the sewage treatment system.
WGS技术湿洗工艺主要包括湿式洗气元件(WGSR)与净化处理元件(PTU)这两个部分。用富碱性溶液来用作吸收剂。在烟道气体第一次进入WGSR后,颗粒和SOx会被分离取出。WGSR主要由文丘里管及分离塔两部分构成。吸收剂与烟气同时进入文丘里管后,吸收过程会发生在文丘里管的湍流部分。吸收液在减速墙中吸收液体,最终形成一层薄膜,随机被分解成液滴,由于进入喉部位置的速度不同步,烟气和液滴两者间会发生惯性碰撞,就会把催化剂粒子保留在喉咙位置,用缓冲溶液洗掉了;SOx被吸收在喉部和膨胀节段中,产生亚硫酸钠和硫酸钠。The WGS technology wet scrubbing process mainly includes two parts: wet scrubber (WGSR) and purification treatment unit (PTU). A rich alkaline solution is used as an absorbent. After the flue gas enters the WGSR for the first time, the particles and SOx will be separated and taken out. The WGSR is mainly composed of a venturi tube and a separation tower. After the absorbent and flue gas enter the venturi tube at the same time, the absorption process will occur in the turbulent part of the venturi tube. The absorption liquid absorbs the liquid in the deceleration wall and eventually forms a thin film, which is randomly decomposed into droplets. Due to the asynchronous speed of entering the throat position, inertial collision will occur between the flue gas and the droplets, which will retain the catalyst particles in the throat position and wash them away with a buffer solution; SOx is absorbed in the throat and expansion section, producing sodium sulfite and sodium sulfate.
技术难点主要集中在微小颗粒(<1μm)的颗粒物的去除,上述技术仅通过文丘里和旋风板进行除尘除雾,效果具有局限性,大量实际工程应用表明,通过上述技术路线仅能实现颗粒物不大于30mg/Nm3,距离超低排放颗粒物小于10mg/Nm3还有较大的差距。The technical difficulties mainly focus on the removal of tiny particles (<1μm). The above technology only removes dust and mist through Venturi and cyclone plates, and the effect is limited. A large number of actual engineering applications have shown that the above technical route can only achieve particulate matter no greater than 30mg/ Nm3 , which is still a long way from ultra-low emission of particulate matter less than 10mg/ Nm3 .
现有的处理技术是将废气通过脱硫除尘塔对废气中的颗粒浮尘以及硫化物进行催化反应沉降,降低废气中颗粒物以及硫化物的含量,如公告号为CN111905554B公开了一种除尘除雾脱硫塔,其包括顺序连通的脱硫段、除雾段和排放烟囱;所述除雾段安装管束式除尘除雾器和折流板除雾器,所述折流板除雾器设置在所述管束式除尘除雾器的上方。The existing treatment technology is to pass the exhaust gas through a desulfurization and dust removal tower to catalyze the precipitation of particulate dust and sulfides in the exhaust gas, thereby reducing the content of particulate matter and sulfides in the exhaust gas. For example, announcement number CN111905554B discloses a dust removal and demisting desulfurization tower, which includes a desulfurization section, a demisting section and an emission chimney connected in sequence; the demisting section is equipped with a tube bundle dust removal and demisting device and a baffle demisting device, and the baffle demisting device is arranged above the tube bundle dust removal and demisting device.
该除尘除雾脱硫塔可以利用现有湿法脱硫塔进行改造,投资小,施工速度快;对上下固定板结构进行调整,增强了管束式除尘除雾器的稳定性、施工方便、便于检修和维护;通过对脱硫塔折流板等结构进行改造,可以消除管束除尘除雾过程中捕集的液膜形成二次夹带,消除石膏雨,实现烟气超低排放,但是在具体使用时,由于管束式除雾器会减小烟气的流经面积,从而提高烟气的流速,使烟气与管束式除雾器之间的接触时间缩短,降低除雾效率,同时管束式除雾器内部设有气旋板,通过气旋板改变烟气方向,使烟气旋转起来,由于旋转的角度固定,所以旋转产生的离心力固定,烟气扰流规律,液滴结合速度慢,且无法将较小的液滴甩到液膜上吸附,从而导致部分液滴会随烟气一起排出,会提高烟囱处形成“落雨”的概率。The dust and mist removal desulfurization tower can be modified using the existing wet desulfurization tower, with small investment and fast construction speed; the upper and lower fixed plate structures are adjusted to enhance the stability of the tube bundle dust and mist removal device, facilitate construction, and facilitate inspection and maintenance; by modifying the desulfurization tower baffle and other structures, the liquid film captured in the tube bundle dust and mist removal process can be eliminated to form secondary entrainment, eliminate gypsum rain, and achieve ultra-low flue gas emissions. However, in specific use, the tube bundle demister will reduce the flow area of the flue gas, thereby increasing the flow rate of the flue gas, shortening the contact time between the flue gas and the tube bundle demister, and reducing the demisting efficiency. At the same time, a cyclone plate is provided inside the tube bundle demister, which changes the direction of the flue gas and rotates the flue gas. Since the rotation angle is fixed, the centrifugal force generated by the rotation is fixed, the flue gas turbulence is regular, the droplet combination speed is slow, and smaller droplets cannot be thrown onto the liquid film for adsorption, resulting in some droplets being discharged with the flue gas, which will increase the probability of "rainfall" at the chimney.
因此可采用一种新型的催化裂化烟气颗粒物超低排放控制装置来解决现有技术的不足之处。Therefore, a new type of catalytic cracking flue gas particulate matter ultra-low emission control device can be used to solve the shortcomings of the existing technology.
发明内容Summary of the invention
本发明的目的是为了解决现有技术中存在烟气与管束式除雾器接触时间短,除雾效率低以及烟气旋转角度固定,微小液滴凝结效率低的问题,而提出的一种催化裂化烟气颗粒物超低排放控制装置。The purpose of the present invention is to solve the problems in the prior art of short contact time between flue gas and tube bundle demister, low demister efficiency, fixed flue gas rotation angle and low condensation efficiency of tiny droplets, and to propose an ultra-low emission control device for catalytic cracking flue gas particulate matter.
为了实现上述目的,本发明采用了如下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:
一种催化裂化烟气颗粒物超低排放控制装置,包括脱硫除尘塔以及外界电源;A catalytic cracking flue gas particulate matter ultra-low emission control device, comprising a desulfurization and dust removal tower and an external power supply;
脱硫除尘部,安装在脱硫除尘塔的底部,用于烟气中硫化物的清除,同时可对烟气中的浮尘进行沉降,所述脱硫除尘部包括安装在脱硫除尘塔内部脱硫机构;The desulfurization and dust removal part is installed at the bottom of the desulfurization and dust removal tower, and is used to remove sulfides in the flue gas and simultaneously settle the floating dust in the flue gas. The desulfurization and dust removal part includes a desulfurization mechanism installed inside the desulfurization and dust removal tower;
粗除尘除雾部,安装在脱硫除尘部的上方,用于脱硫除尘后的除尘,减少烟气中尘雾的含量,所述粗除尘除雾部包括安装在脱硫除尘塔内部的粗除尘除雾机构;A coarse dust removal and demisting unit is installed above the desulfurization and demisting unit and is used for dust removal after desulfurization and demisting to reduce the dust and mist content in the flue gas. The coarse dust removal and demisting unit includes a coarse dust removal and demisting mechanism installed inside the desulfurization and demisting tower;
精除尘除雾部,安装在粗除尘除雾部的上方,用于粗除尘除雾部后的再次除尘除雾,进一步减少烟气中尘雾的含量,所述精除尘除雾部包括安装在脱硫除尘塔内部的精除尘除雾机构;A fine dust removal and demisting unit is installed above the rough dust removal and demisting unit and is used for further dust removal and demisting after the rough dust removal and demisting unit to further reduce the dust and mist content in the flue gas. The fine dust removal and demisting unit includes a fine dust removal and demisting mechanism installed inside the desulfurization dust removal tower;
除雾除水部,安装在精除尘除雾部的上方,位于脱硫除尘塔的顶部,用于对烟气脱硫后形成的饱和湿烟气中的小液滴进行去除,所述除雾除水部包括安装在脱硫除尘塔内部的除水除雾机构。The demisting and dewatering part is installed above the fine dust removal and demisting part and is located at the top of the desulfurization and dust removal tower. It is used to remove small droplets in the saturated wet flue gas formed after flue gas desulfurization. The demisting and dewatering part includes a demisting and dewatering mechanism installed inside the desulfurization and dust removal tower.
优选的,所述脱硫机构包括固定安装在脱硫除尘塔底层的锥罩,所述锥罩上贯穿固定安装有多个文丘里管束,所述脱硫除尘塔内部固定安装有浆液喷淋管一以及浆液喷淋管二,所述浆液喷淋管一上固定连通有多个与对应文丘里管束相配合的喷嘴一,所述浆液喷淋管二上固定连通有多个与对应文丘里管束相配合的喷嘴二,所述锥罩底部连通有浆液引出管。Preferably, the desulfurization mechanism includes a cone cover fixedly installed on the bottom layer of the desulfurization and dust removal tower, a plurality of Venturi tube bundles are fixedly installed on the cone cover, a slurry spray pipe 1 and a slurry spray pipe 2 are fixedly installed inside the desulfurization and dust removal tower, the slurry spray pipe 1 is fixedly connected with a plurality of nozzles 1 that match the corresponding Venturi tube bundles, the slurry spray pipe 2 is fixedly connected with a plurality of nozzles 2 that match the corresponding Venturi tube bundles, and the bottom of the cone cover is connected with a slurry outlet pipe.
优选的,所述粗除尘除雾机构包括固定安装在脱硫除尘塔内部的管式除雾器,所述管式除雾器位于脱硫除尘塔的中下层,所述管式除雾器上部固定安装有凝结环,所述凝结环上部固定安装有两个屋脊除雾器,所述脱硫除尘塔内通过支撑梁一固定安装有两个与对应屋脊除雾器相配合的冲洗水管路一,两个所述冲洗水管路一上均固定连通有多个喷嘴三。Preferably, the coarse dust removal and demisting mechanism includes a tubular demister fixedly installed inside the desulfurization and dust removal tower, the tubular demister is located in the middle and lower layers of the desulfurization and dust removal tower, a condensation ring is fixedly installed on the upper part of the tubular demister, two ridge demisters are fixedly installed on the upper part of the condensation ring, and two flushing water pipes 1 that match the corresponding ridge demisters are fixedly installed in the desulfurization and dust removal tower through a support beam 1, and multiple nozzles 3 are fixedly connected to the two flushing water pipes 1.
优选的,所述精除尘除雾机构包括通过支撑梁二固定安装在脱硫除尘塔内部的支撑格栅,所述支撑格栅位于脱硫除尘塔的中上层,所述支撑格栅上固定安装有多个管束式除雾器,每个所述管束式除雾器内均开设有一个环形凹槽,每个所述管束式除雾器内壁上均固定安装有液膜,所述脱硫除尘塔内部固定安装有与多个管束式除雾器相配合的管束式除雾器上封板,所述脱硫除尘塔内部固定安装有除雾器冲洗水管支撑架,所述除雾器冲洗水管支撑架底部固定安装有冲洗水连接软管,所述冲洗水连接软管上固定连通多个与对应管束式除雾器相配合的冲洗水管路二,所述冲洗水管路二位于管束式除雾器的上方;Preferably, the fine dust removal and demisting mechanism includes a support grille fixedly installed inside the desulfurization and dust removal tower through a second support beam, the support grille is located in the middle and upper layers of the desulfurization and dust removal tower, a plurality of tube bundle demisters are fixedly installed on the support grille, each of the tube bundle demisters is provided with an annular groove, a liquid film is fixedly installed on the inner wall of each of the tube bundle demisters, a tube bundle demister upper sealing plate matched with the plurality of tube bundle demisters is fixedly installed inside the desulfurization and dust removal tower, a demister flushing water pipe support frame is fixedly installed inside the desulfurization and dust removal tower, a flushing water connecting hose is fixedly installed at the bottom of the demister flushing water pipe support frame, a plurality of flushing water pipelines two matched with the corresponding tube bundle demisters are fixedly connected on the flushing water connecting hose, and the flushing water pipeline two is located above the tube bundle demister;
每个所述管束式除雾器内部均通过支撑钢架固定安装在脱硫除尘塔内部的一个中置架,每个所述中置架上均转动安装有多个气旋叶一,每个所述中置架上均安装有与多个气旋叶一相配合的调节机构,每个所述气旋叶一上均转动安装有一个气旋叶二,所述管束式除雾器内固定安装有两个导流环,两个所述导流环分别位于中置架的上下两侧。Each of the tube bundle type demisters is fixedly mounted on a center frame inside the desulfurization and dust removal tower through a supporting steel frame, a plurality of cyclone blades 1 are rotatably mounted on each of the center frames, an adjustment mechanism matching the plurality of cyclone blades 1 is mounted on each of the center frames, a cyclone blade 2 is rotatably mounted on each of the cyclone blades 1, and two guide rings are fixedly mounted inside the tube bundle type demister, and the two guide rings are respectively located on the upper and lower sides of the center frame.
优选的,所述调节机构包括固定安装在气旋叶一上的轴杆一,所述气旋叶一上固定安装有轴杆一,所述轴杆一与中置架之间为贯穿转动连接,所述中置架上固定安装有电机,所述电机驱动端上固定安装有转轴,所述转轴上通过离合结构安装有摩擦罩,所述摩擦罩上固定安装有环形架,所述环形架与中置架之间为转动连接,所述环形架上固定安装有全齿环,所述轴杆一上固定安装有与全齿环相啮合的齿轮一,所述电机与气旋叶二之间安装有带动结构。Preferably, the adjustment mechanism includes a shaft rod one fixedly mounted on cyclone blade one, a shaft rod one fixedly mounted on the cyclone blade one, a through-connection rotation between the shaft rod one and the center frame, a motor fixedly mounted on the center frame, a rotating shaft fixedly mounted on the motor driving end, a friction cover mounted on the rotating shaft via a clutch structure, an annular frame fixedly mounted on the friction cover, a rotation connection between the annular frame and the center frame, a full gear ring fixedly mounted on the annular frame, a gear one meshing with the full gear ring fixedly mounted on the shaft rod one, and a driving structure installed between the motor and cyclone blade two.
优选的,所述离合结构包括固定安装在转轴远离电机一端的安装板,所述安装板上滑动安装有两个与摩擦罩相配合的摩擦板;Preferably, the clutch structure comprises a mounting plate fixedly mounted on an end of the rotating shaft away from the motor, and two friction plates cooperating with the friction cover are slidably mounted on the mounting plate;
所述转轴上滑动安装有滑套,所述滑套上固定安装有固定环,所述固定环上转动安装有两组转杆,两组所述转杆与对应的摩擦板之间均为转动连接,所述摩擦罩与滑套之间安装有移动结构。A sliding sleeve is slidably mounted on the rotating shaft, a fixing ring is fixedly mounted on the sliding sleeve, two groups of rotating rods are rotatably mounted on the fixing ring, the two groups of rotating rods are rotatably connected to the corresponding friction plates, and a moving structure is installed between the friction cover and the sliding sleeve.
优选的,所述移动结构包括转动安装在滑套上的转动环,所述摩擦罩上通用锁定架固定安装有电推杆,所述电推杆与转动环之间通过连接支架固定连接,所述电推杆与外界电源之间安装有接线部件。Preferably, the movable structure includes a rotating ring rotatably mounted on the sliding sleeve, an electric push rod is fixedly mounted on the universal locking frame on the friction cover, the electric push rod and the rotating ring are fixedly connected via a connecting bracket, and a wiring component is installed between the electric push rod and the external power supply.
优选的,所述接线部件包括通过转动架转动安装在电推杆上的多个导电滚轮,所述电推杆内设置正接线极以及负接线极,其中一个所述导电滚轮与电推杆内的正接线极固定连接,所述管束式除雾器内固定安装有导电环,所述导电环套设在多个导电滚轮上,所述导电环与外界电源之间通过导线一相连接;Preferably, the wiring component includes a plurality of conductive rollers rotatably mounted on the electric push rod through a rotating frame, a positive wiring electrode and a negative wiring electrode are arranged in the electric push rod, one of the conductive rollers is fixedly connected to the positive wiring electrode in the electric push rod, a conductive ring is fixedly installed in the tube bundle type defogger, the conductive ring is sleeved on the plurality of conductive rollers, and the conductive ring is connected to an external power supply through a wire.
所述电推杆上固定安装有轴承,所述电推杆内的负接线极与轴承之间固定连接,所述轴承内圈固定安装有导电柱,所述导电柱与管束式除雾器内壁之间固定连接,所述导电柱与外界电源之间通过导线二相连接。A bearing is fixedly installed on the electric push rod, the negative terminal in the electric push rod is fixedly connected to the bearing, a conductive column is fixedly installed on the inner ring of the bearing, the conductive column is fixedly connected to the inner wall of the tube bundle type defogger, and the conductive column is connected to an external power supply through a two-phase wire.
优选的,所述带动结构包括转动安装在轴杆一内部的轴杆二,所述轴杆二贯穿轴杆一,所述轴杆一与轴杆二之间固定安装有弹簧卷,所述轴杆二与气旋叶二之间固定连接,所述轴杆二上固定安装有齿轮二,所述电机驱动端固定安装有弧形架,所述弧形架上固定安装有与齿轮二相啮合的不完全齿环。Preferably, the driving structure includes shaft rod 2 rotatably installed inside shaft rod 1, shaft rod 2 passes through shaft rod 1, a spring roll is fixedly installed between shaft rod 1 and shaft rod 2, shaft rod 2 is fixedly connected to cyclone blade 2, gear 2 is fixedly installed on shaft rod 2, an arc frame is fixedly installed on the motor driving end, and an incomplete gear ring meshing with gear 2 is fixedly installed on the arc frame.
优选的,所述除水除雾机构包括固定安装在脱硫除尘塔内顶层的气旋除水除雾器,所述脱硫除尘塔顶部固定安装有烟囱。Preferably, the dewatering and demisting mechanism comprises a cyclone dewatering and demisting device fixedly installed on the top floor of the desulfurization and dust removal tower, and a chimney is fixedly installed on the top of the desulfurization and dust removal tower.
与现有的技术相比,本发明优点在于:Compared with the prior art, the present invention has the following advantages:
1、本发明通过设置文丘里管束、管式除雾器、屋脊除雾器、管束式除雾器以及气旋除雾器,可对脱硫除尘塔内的烟气进行逐级脱硫除尘除雾操作,大大降低烟气中硫化物以及尘雾的含量,经过逐级处理后的烟气中微小颗粒可达到小于10mg/Nm3,超过排放标准,环保性更高。1. The present invention can perform step-by-step desulfurization, dust removal and mist removal operations on the flue gas in the desulfurization and dust removal tower by arranging venturi tube bundles, tubular demisters, ridge demisters, tube bundle demisters and cyclone demisters, thereby greatly reducing the content of sulfide and dust in the flue gas. After step-by-step treatment, the tiny particles in the flue gas can reach less than 10 mg/Nm 3 , exceeding the emission standard, and having higher environmental protection.
2、本发明通过设置中置架以及气旋叶一,可改变烟气流动方向,使烟气在管束式除雾器内旋转,利用旋转产生的离心力使烟气中的微小液滴凝结成较大液滴,然后利用液膜对液滴进行吸收,对液滴的去除更加彻底,还可改变气旋叶一与中置架之间的角度,来改变烟气通过的阻力,加快烟气的流速,提高离心力,从而使得液滴更容易被液膜吸附,同时配合管束式除雾器内的环形凹槽来增大烟气与管束式除雾器内壁之间的接触面积,从而提高液滴的吸附效率。2. The present invention can change the flow direction of the flue gas by arranging a center frame and a cyclone blade, so that the flue gas rotates in the tube bundle demister, and the centrifugal force generated by the rotation is used to condense the tiny droplets in the flue gas into larger droplets, and then the droplets are absorbed by the liquid film, so that the droplets are removed more thoroughly. The angle between the cyclone blade and the center frame can also be changed to change the resistance of the flue gas passing through, speed up the flow rate of the flue gas, and increase the centrifugal force, so that the droplets are more easily adsorbed by the liquid film. At the same time, the annular groove in the tube bundle demister is used to increase the contact area between the flue gas and the inner wall of the tube bundle demister, so as to improve the adsorption efficiency of the droplets.
3、本发明通过设置弧形架、不完全齿环以及齿轮二,可带动气旋叶二转动,利用电机持续转动来间歇性带动气旋叶二转动,通过气旋叶二的转动来改变烟气的流动方向,从而使管束式除雾器内的烟气流动方向更加扰动,以此来加快微小液滴的凝结速度,使得对微小液滴清理更加彻底。3. The present invention can drive the rotation of cyclone blade 2 by arranging an arc frame, an incomplete gear ring and gear 2, and utilizes the continuous rotation of the motor to intermittently drive the rotation of cyclone blade 2. The flow direction of the flue gas is changed by the rotation of cyclone blade 2, so that the flow direction of the flue gas in the tube bundle demister is more disturbed, thereby accelerating the condensation speed of tiny droplets and making the cleaning of tiny droplets more thorough.
综上所述,本发明通过文丘里管束脱硫除尘、粗除尘除雾、精除尘除雾和除雾除水四段式梯级协同除尘除雾布置,不仅能大大降低烟气出口的雾滴含量,解决烟囱雨问题,同时通过分段分级协同脱除不同粒径大小的颗粒物,有效实现颗粒物超低排放的技术要求。In summary, the present invention adopts a four-stage cascade coordinated dust and mist removal arrangement of Venturi tube bundle desulfurization and dust removal, coarse dust and mist removal, fine dust and mist removal, and mist and water removal, which can not only greatly reduce the droplet content at the flue gas outlet and solve the chimney rain problem, but also effectively achieve the technical requirements of ultra-low emission of particulate matter by collaboratively removing particulate matter of different particle sizes in a segmented and graded manner.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
下面结合附图对本发明的具体实施方式作进一步详细的说明,其中:The specific embodiments of the present invention are further described in detail below with reference to the accompanying drawings, wherein:
图1为本发明提出的一种催化裂化烟气颗粒物超低排放控制装置的结构示意图;FIG1 is a schematic structural diagram of an ultra-low emission control device for catalytic cracking flue gas particulate matter proposed by the present invention;
图2为图1的剖视结构示意详图;FIG2 is a schematic detailed cross-sectional view of the structure of FIG1 ;
图3为图2中文丘里管束以及锥罩等部件的放大结构示意详图;FIG3 is an enlarged structural schematic diagram of the Venturi tube bundle and cone cover and other components in FIG2;
图4为图2中凝结环及其周边部件转动一定角度后的放大结构示意详图;FIG4 is a detailed schematic diagram of the enlarged structure of the condensation ring and its surrounding components in FIG2 after being rotated by a certain angle;
图5为图2中屋脊除雾器以及冲洗水管路一的放大结构示意详图;FIG5 is an enlarged structural schematic detailed diagram of the roof ridge demister and flushing water pipeline 1 in FIG2;
图6为图5中去除屋脊除雾器后冲洗水管路一的放大结构示意详图;FIG6 is an enlarged structural schematic detailed diagram of the flushing water pipeline 1 after removing the ridge demister in FIG5;
图7为图2中管束式除雾器、管束式除雾器上封板以及气旋除雾器等部件的放大结构示意详图;FIG7 is an enlarged structural schematic detailed diagram of the tube bundle demister, the upper sealing plate of the tube bundle demister, and the cyclone demister in FIG2;
图8为图7转动一定角度后的结构示意详图;FIG8 is a detailed schematic diagram of the structure of FIG7 after being rotated to a certain angle;
图9为图8中管束式除雾器的平面结构示意详图;FIG9 is a schematic detailed plan view of the tube bundle demister in FIG8 ;
图10为图9沿A-A方向的剖面立体结构示意详图;FIG10 is a schematic detailed view of the cross-sectional three-dimensional structure of FIG9 along the A-A direction;
图11为图10中气旋叶一的放大结构示意详图;FIG11 is an enlarged structural schematic detailed diagram of the cyclone blade 1 in FIG10;
图12为图11转动一定角度后的结构示意详图;FIG12 is a detailed schematic diagram of the structure of FIG11 after being rotated to a certain angle;
图13为图12中去除下封罩后的结构示意详图;FIG13 is a detailed schematic diagram of the structure of FIG12 after removing the lower sealing cover;
图14为图13中去除中置架以及上封罩后的结构示意详图;FIG14 is a detailed schematic diagram of the structure of FIG13 after removing the middle frame and the upper cover;
图15为图14中去除多个气旋叶一以及气旋叶二后的结构示意详图;FIG15 is a detailed schematic diagram of the structure of FIG14 after removing a plurality of cyclone blades 1 and cyclone blades 2;
图16为图15中电机、不完全齿环、全齿环以及摩擦罩等部件的放大结构示意详图;FIG16 is an enlarged structural schematic detailed diagram of the motor, incomplete gear ring, full gear ring, friction cover and other components in FIG15;
图17为图16转动一定角度后的结构示意详图;FIG17 is a detailed schematic diagram of the structure of FIG16 after being rotated to a certain angle;
图18为图16中去除不完全齿环、全齿环、弧形架以及环形架后的结构示意详图;FIG18 is a detailed schematic diagram of the structure of FIG16 after removing the incomplete gear ring, the full gear ring, the arc frame and the annular frame;
图19为图18中去除电机并转动一定角度后的结构示意详图;FIG19 is a detailed schematic diagram of the structure of FIG18 after the motor is removed and rotated to a certain angle;
图20为图19转动一定角度后的结构示意详图;FIG20 is a detailed schematic diagram of the structure of FIG19 after being rotated to a certain angle;
图21为图14中气旋叶一以及气旋叶二等部件的放大结构示意详图;FIG21 is an enlarged structural schematic detailed diagram of the cyclone blade 1 and cyclone blade 2 in FIG14;
图22为图21中轴杆一、轴杆二、齿轮一以及齿轮二的放大结构示意详图。Figure 22 is an enlarged structural schematic detailed diagram of shaft rod 1, shaft rod 2, gear 1 and gear 2 in Figure 21.
图中:1脱硫除尘塔、2浆液引出管、3浆液喷淋管一、4喷嘴一、5锥罩、6文丘里管束、7浆液喷淋管二、8喷嘴二、9管式除雾器、10屋脊除雾器、11冲洗水管路一、12支撑梁一、13支撑格栅、14支撑梁二、15管束式除雾器、16管束式除雾器上封板、17除雾器冲洗水管支撑架、18冲洗水管路二、19冲洗水连接软管、20气旋除水除雾器、21烟囱、22凝结环、23喷嘴三、24导流环、25气旋叶一、26中置架、27上封罩、28下封罩、29气旋叶二、30电机、31环形架、32全齿环、33弧形架、34不完全齿环、35摩擦罩、36电推杆、37连接支架、38转轴、39安装板、40滑套、41摩擦板、42转杆、43转动环、44固定环、45锁定架、46导电环、47导电滚轮、48导电柱、49导线一、50导线二、51轴杆一、52轴杆二、53齿轮一、54齿轮二、55弹簧卷、56轴承。In the figure: 1 desulfurization dust removal tower, 2 slurry outlet pipe, 3 slurry spray pipe 1, 4 nozzle 1, 5 cone cover, 6 venturi tube bundle, 7 slurry spray pipe 2, 8 nozzle 2, 9 tubular demister, 10 roof demister, 11 flushing water pipeline 1, 12 support beam 1, 13 support grid, 14 support beam 2, 15 bundle demister, 16 bundle demister upper cover plate, 17 demister flushing water pipe support frame, 18 flushing water pipeline 2, 19 flushing water connecting hose, 20 cyclone dewatering demister, 21 chimney, 22 condensation ring, 23 nozzle 3, 24 guide ring, 25 cyclone Blade one, 26 center frame, 27 upper sealing cover, 28 lower sealing cover, 29 cyclone blade two, 30 motor, 31 annular frame, 32 full gear ring, 33 arc frame, 34 incomplete gear ring, 35 friction cover, 36 electric push rod, 37 connecting bracket, 38 rotating shaft, 39 mounting plate, 40 sliding sleeve, 41 friction plate, 42 rotating rod, 43 rotating ring, 44 fixing ring, 45 locking frame, 46 conductive ring, 47 conductive roller, 48 conductive column, 49 wire one, 50 wire two, 51 shaft rod one, 52 shaft rod two, 53 gear one, 54 gear two, 55 spring roll, 56 bearing.
具体实施方式DETAILED DESCRIPTION
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will be combined with the drawings in the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
实施例一:参照图1-图3,一种催化裂化烟气颗粒物超低排放控制装置,包括脱硫除尘塔1以及外界电源;脱硫除尘部,安装在脱硫除尘塔1的底部,用于烟气中硫化物的清除,同时可对烟气中的浮尘进行沉降,脱硫除尘部包括安装在脱硫除尘塔1内部脱硫机构。Embodiment 1: Referring to Figures 1-3, a catalytic cracking flue gas particulate matter ultra-low emission control device includes a desulfurization and dust removal tower 1 and an external power supply; a desulfurization and dust removal unit is installed at the bottom of the desulfurization and dust removal tower 1, which is used to remove sulfides in the flue gas and simultaneously settle the floating dust in the flue gas, and the desulfurization and dust removal unit includes a desulfurization mechanism installed inside the desulfurization and dust removal tower 1.
脱硫机构包括固定安装在脱硫除尘塔1底层的锥罩5,锥罩5上贯穿固定安装有多个文丘里管束6,脱硫除尘塔1内部固定安装有浆液喷淋管一3以及浆液喷淋管二7,浆液喷淋管一3上固定连通有多个与对应文丘里管束6相配合的喷嘴一4,浆液喷淋管二7上固定连通有多个与对应文丘里管束6相配合的喷嘴二8,锥罩5底部连通有浆液引出管2。The desulfurization mechanism includes a cone cover 5 fixedly installed on the bottom layer of the desulfurization and dust removal tower 1, and a plurality of venturi tube bundles 6 are fixedly installed on the cone cover 5. A slurry spray pipe 1 3 and a slurry spray pipe 2 7 are fixedly installed inside the desulfurization and dust removal tower 1. The slurry spray pipe 1 3 is fixedly connected with a plurality of nozzles 1 4 that match the corresponding venturi tube bundles 6, and the slurry spray pipe 2 7 is fixedly connected with a plurality of nozzles 2 8 that match the corresponding venturi tube bundles 6. The bottom of the cone cover 5 is connected with a slurry outlet pipe 2.
烟气由下往上从文丘里管束6中通过,同时浆液喷淋管一3以及浆液喷淋管二7会通过对应的喷嘴一4以及喷嘴二8将脱硫浆液喷入文丘里管束6中,使烟气和脱硫浆液在文丘里管束6内部两相掺混、反应,实现烟气中SO2和颗粒物的协同脱除,通过锥罩5收集的脱硫浆液通过浆液引出管2引出脱硫除尘塔1,脱硫除尘塔1外部设置固定容器收集,经固定容器收集后处理,再通过泵送至浆液喷淋管二7与浆液喷淋管一3内,循环往复。The flue gas passes through the Venturi tube bundle 6 from bottom to top, and at the same time, the slurry spray pipe 1 3 and the slurry spray pipe 2 7 will spray the desulfurization slurry into the Venturi tube bundle 6 through the corresponding nozzle 1 4 and the nozzle 2 8, so that the flue gas and the desulfurization slurry are mixed and reacted in two phases inside the Venturi tube bundle 6, so as to achieve the coordinated removal of SO2 and particulate matter in the flue gas. The desulfurization slurry collected by the cone cover 5 is led out of the desulfurization dust removal tower 1 through the slurry lead-out pipe 2, and a fixed container is set outside the desulfurization dust removal tower 1 to collect the slurry. After being collected in the fixed container, it is processed and then pumped to the slurry spray pipe 2 7 and the slurry spray pipe 1 3, and the cycle is repeated.
实施例二:本实施例区别于实施例一技术方案在于:参照图1-图6,粗除尘除雾部,安装在脱硫除尘部的上方,用于脱硫除尘后的除尘,减少烟气中尘雾的含量,粗除尘除雾部包括安装在脱硫除尘塔1内部的粗除尘除雾机构。Embodiment 2: The technical solution of this embodiment is different from that of Embodiment 1 in that: referring to Figures 1-6, a coarse dust removal and demisting unit is installed above the desulfurization and dust removal unit, and is used for dust removal after desulfurization and dust removal to reduce the dust and mist content in the flue gas. The coarse dust removal and demisting unit includes a coarse dust removal and demisting mechanism installed inside the desulfurization and dust removal tower 1.
粗除尘除雾机构包括固定安装在脱硫除尘塔1内部的管式除雾器9,管式除雾器9位于脱硫除尘塔1的中下层,管式除雾器9上部固定安装有凝结环22,凝结环22上部固定安装有两个屋脊除雾器10,脱硫除尘塔1内通过支撑梁一12固定安装有两个与对应屋脊除雾器10相配合的冲洗水管路一11,两个冲洗水管路一11上均固定连通有多个喷嘴三23。The coarse dust removal and demisting mechanism includes a tubular demister 9 fixedly installed inside the desulfurization and dust removal tower 1. The tubular demister 9 is located in the middle and lower layers of the desulfurization and dust removal tower 1. A condensation ring 22 is fixedly installed on the upper part of the tubular demister 9. Two ridge demisters 10 are fixedly installed on the upper part of the condensation ring 22. Two flushing water pipes 11 that match the corresponding ridge demisters 10 are fixedly installed in the desulfurization and dust removal tower 1 through a support beam 12. Multiple nozzles 23 are fixedly connected to the two flushing water pipes 11.
经过文丘里管束6脱硫除尘后的净烟气其含有大量的雾滴,雾滴由浆液液滴、凝结液滴和尘颗粒组成,经过管式除雾器9以及屋脊除雾器10后,可以捕集一部分烟气中的含盐液滴、尘颗粒和凝结液滴等,通过定期开启冲洗水管路一11对管式除雾器9以及屋脊除雾器10进行冲洗,去除捕集下来的含盐液滴、尘颗粒和凝结液滴等。同时可以对烟气流场重新进行均布,为后续烟气除尘除雾创造有利条件。The clean flue gas after desulfurization and dust removal by the venturi tube bundle 6 contains a large number of droplets, which are composed of slurry droplets, condensed droplets and dust particles. After passing through the tubular demister 9 and the ridge demister 10, a part of the salt droplets, dust particles and condensed droplets in the flue gas can be captured. The tubular demister 9 and the ridge demister 10 can be flushed by regularly opening the flushing water pipeline 11 to remove the captured salt droplets, dust particles and condensed droplets. At the same time, the flue gas flow field can be re-distributed evenly, creating favorable conditions for subsequent flue gas dust removal and demisting.
实施例三:本实施例区别于实施例二技术方案在于:参照图1-图2、图7-图22,精除尘除雾部,安装在粗除尘除雾部的上方,用于粗除尘除雾部后的再次除尘除雾,进一步减少烟气中尘雾的含量,精除尘除雾部包括安装在脱硫除尘塔1内部的精除尘除雾机构。Embodiment 3: This embodiment is different from the technical solution of Embodiment 2 in that: referring to Figures 1-2 and 7-22, the fine dust removal and demisting section is installed above the coarse dust removal and demisting section, and is used for dust removal and demisting again after the coarse dust removal and demisting section, so as to further reduce the dust and mist content in the flue gas. The fine dust removal and demisting section includes a fine dust removal and demisting mechanism installed inside the desulfurization dust removal tower 1.
精除尘除雾机构包括通过支撑梁二14固定安装在脱硫除尘塔1内部的支撑格栅13,支撑格栅13位于脱硫除尘塔1的中上层,支撑格栅13上固定安装有多个管束式除雾器15,每个管束式除雾器15内均开设有一个环形凹槽,每个管束式除雾器15内壁上均固定安装有液膜,脱硫除尘塔1内部固定安装有与多个管束式除雾器15相配合的管束式除雾器上封板16,脱硫除尘塔1内部固定安装有除雾器冲洗水管支撑架17,除雾器冲洗水管支撑架17底部固定安装有冲洗水连接软管19,冲洗水连接软管19上固定连通多个与对应管束式除雾器15相配合的冲洗水管路二18,冲洗水管路二18位于管束式除雾器15的上方;The fine dust removal and mist removal mechanism includes a support grille 13 fixedly installed inside the desulfurization and dust removal tower 1 through a support beam 14, the support grille 13 is located in the middle and upper layers of the desulfurization and dust removal tower 1, a plurality of tube bundle demisters 15 are fixedly installed on the support grille 13, each tube bundle demister 15 is provided with an annular groove, a liquid film is fixedly installed on the inner wall of each tube bundle demister 15, a tube bundle demister upper sealing plate 16 matched with the plurality of tube bundle demisters 15 is fixedly installed inside the desulfurization and dust removal tower 1, a demister flushing water pipe support frame 17 is fixedly installed inside the desulfurization and dust removal tower 1, a flushing water connecting hose 19 is fixedly installed at the bottom of the demister flushing water pipe support frame 17, a plurality of flushing water pipelines 18 matched with the corresponding tube bundle demisters 15 are fixedly connected to the flushing water connecting hose 19, and the flushing water pipeline 18 is located above the tube bundle demister 15;
每个管束式除雾器15内部均通过支撑钢架固定安装在脱硫除尘塔1内部的一个中置架26,每个中置架26上均转动安装有多个气旋叶一25,每个中置架26上均安装有与多个气旋叶一25相配合的调节机构;Each tube bundle demister 15 is fixedly mounted on a middle frame 26 inside the desulfurization and dust removal tower 1 through a supporting steel frame, and each middle frame 26 is rotatably mounted with a plurality of cyclone blades 25, and each middle frame 26 is mounted with an adjustment mechanism that matches the plurality of cyclone blades 25;
经过管式除雾器9以及屋脊除雾器10除尘除雾处理后的净烟气进入管束式除雾器15内,多个管束式除雾器15内的气旋叶一25使脱硫净烟气在管束式除雾器15内旋转起来,在管束式除雾器15内部的上方形成气液两相的剧烈旋转及扰动,从而使得净烟气中的细小液滴、细微粉尘颗粒、气溶胶等微小颗粒物互相碰撞团聚凝聚成大液滴,再在气旋叶一25的作用下,使脱硫净烟气向外离心运动,聚合形成的大液滴与气旋筒壁碰撞,并被气旋筒壁液膜捕获吸收,实现对微小颗粒物的控制,高效除雾除尘。The clean flue gas after dust removal and demisting treatment by the tubular demister 9 and the ridge demister 10 enters the tube bundle demister 15. The cyclone blades 25 in the multiple tube bundle demisters 15 make the desulfurized clean flue gas rotate in the tube bundle demister 15, and form a violent rotation and disturbance of the gas-liquid two phases above the inside of the tube bundle demister 15, so that the tiny droplets, fine dust particles, aerosols and other tiny particles in the clean flue gas collide with each other, agglomerate and condense into large droplets. Then, under the action of the cyclone blades 25, the desulfurized clean flue gas moves centrifugally outward, and the large droplets formed by aggregation collide with the cyclone cylinder wall and are captured and absorbed by the cyclone cylinder wall liquid film, thereby realizing the control of tiny particles and efficient demisting and dust removal.
调节机构包括固定安装在气旋叶一25上的轴杆一51,轴杆一51与中置架26之间为贯穿转动连接,中置架26上固定安装有电机30,电机30驱动端上固定安装有转轴38,转轴38上通过离合结构安装有摩擦罩35,摩擦罩35上固定安装有环形架31,环形架31与中置架26之间为转动连接,环形架31上固定安装有全齿环32,轴杆一51上固定安装有与全齿环32相啮合的齿轮一53。The adjustment mechanism includes a shaft rod 51 fixedly mounted on a cyclone blade 25, the shaft rod 51 and the center frame 26 are rotatably connected, a motor 30 is fixedly mounted on the center frame 26, a rotating shaft 38 is fixedly mounted on the driving end of the motor 30, a friction cover 35 is mounted on the rotating shaft 38 via a clutch structure, an annular frame 31 is fixedly mounted on the friction cover 35, the annular frame 31 and the center frame 26 are rotatably connected, a full gear ring 32 is fixedly mounted on the annular frame 31, and a gear 53 meshing with the full gear ring 32 is fixedly mounted on the shaft rod 51.
电机30驱动端转动带动转轴38转动,可在离合结构的作用下,使摩擦罩35随转轴38转动(离合结构也可使电机30驱动端转动的过程中,保持摩擦罩35不动),摩擦罩35转动带动环形架31转动,环形架31转动带动全齿环32转动,从而带动齿轮一53转动,齿轮一53转动带动轴杆一51转动,从而带动气旋叶一25转动,以此来改变气旋叶一25的角度。The rotation of the driving end of the motor 30 drives the rotating shaft 38 to rotate, and under the action of the clutch structure, the friction cover 35 can rotate with the rotating shaft 38 (the clutch structure can also keep the friction cover 35 stationary during the rotation of the driving end of the motor 30). The rotation of the friction cover 35 drives the annular frame 31 to rotate, and the rotation of the annular frame 31 drives the full gear ring 32 to rotate, thereby driving the gear 53 to rotate. The rotation of the gear 53 drives the shaft 51 to rotate, thereby driving the cyclone blade 25 to rotate, so as to change the angle of the cyclone blade 25.
改变气旋叶一25的角度,可改变烟气流动方向,使烟气在管束式除雾器15内旋转,利用旋转产生的离心力使烟气中的微小液滴凝结成较大液滴,然后利用液膜对液滴进行吸收,对液滴的去除更加彻底,还可改变气旋叶一25与中置架26之间的角度,角度越小,烟气通过的面积越小,烟气通过阻力越大,加快烟气的流速,提高离心力,从而使得液滴更容易被液膜吸附,同时配合管束式除雾器15内的环形凹槽来增大烟气与管束式除雾器15内壁之间的接触面积,从而提高液滴的吸附效率;Changing the angle of the cyclone blade 25 can change the direction of flue gas flow, causing the flue gas to rotate in the tube bundle demister 15, and using the centrifugal force generated by the rotation to condense tiny droplets in the flue gas into larger droplets, and then using the liquid film to absorb the droplets, so that the droplets can be removed more thoroughly. The angle between the cyclone blade 25 and the center frame 26 can also be changed. The smaller the angle, the smaller the area through which the flue gas passes, and the greater the resistance to the passage of the flue gas, which speeds up the flow rate of the flue gas and increases the centrifugal force, so that the droplets are more easily adsorbed by the liquid film. At the same time, the annular groove in the tube bundle demister 15 is used to increase the contact area between the flue gas and the inner wall of the tube bundle demister 15, thereby improving the adsorption efficiency of the droplets.
由于加快烟气流速的过程中,由于烟气通过阻力增大,所以会导致烟气通过效率降低,此时可反转电机30驱动端,使气旋叶一25反转,且转动的位置超过初始位置,这样可对烟气起到扇动的效果,此时烟气阻力小于原始阻力,而刚才的烟气阻力大于原始阻力,因此来钟模式下的阻力抵消,使得烟气的通过效率保持与原始效率一致,不影响烟气的除尘除雾效率。In the process of accelerating the flue gas flow rate, the resistance of the flue gas passage increases, so the flue gas passage efficiency is reduced. At this time, the driving end of the motor 30 can be reversed to reverse the cyclone blade 25, and the rotation position exceeds the initial position, which can fan the flue gas. At this time, the flue gas resistance is less than the original resistance, and the previous flue gas resistance is greater than the original resistance. Therefore, the resistance in the clock mode is offset, so that the flue gas passage efficiency remains consistent with the original efficiency, and does not affect the dust and mist removal efficiency of the flue gas.
离合结构包括固定安装在转轴38远离电机30一端的安装板39,安装板39上滑动安装有两个与摩擦罩35相配合的摩擦板41;The clutch structure includes a mounting plate 39 fixedly mounted on the end of the rotating shaft 38 away from the motor 30, and two friction plates 41 matching the friction cover 35 are slidably mounted on the mounting plate 39;
转轴38上滑动安装有滑套40,滑套40上固定安装有固定环44,固定环44上转动安装有两组转杆42,两组转杆42与对应的摩擦板41之间均为转动连接,摩擦罩35与滑套40之间安装有移动结构;A sliding sleeve 40 is slidably mounted on the rotating shaft 38, a fixing ring 44 is fixedly mounted on the sliding sleeve 40, two sets of rotating rods 42 are rotatably mounted on the fixing ring 44, and the two sets of rotating rods 42 are rotatably connected to the corresponding friction plates 41, and a moving structure is installed between the friction cover 35 and the sliding sleeve 40;
滑套40向靠近摩擦罩35的一侧移动时,会带动转杆42移动,此时转杆42会抵压摩擦板41,由于转杆42呈倾斜设计,根据力的分解,转杆42会对摩擦板41产生沿安装板39中心方向的抵压作用力,该抵压作用力会推动摩擦板41向靠近摩擦罩35的一侧移动,直至摩擦板41与摩擦罩35相抵为止,此时摩擦板41会通过摩擦力来带动摩擦罩35转动。When the sliding sleeve 40 moves toward the side close to the friction cover 35, it will drive the rotating rod 42 to move. At this time, the rotating rod 42 will press the friction plate 41. Since the rotating rod 42 is designed to be inclined, according to the decomposition of force, the rotating rod 42 will generate a pressing force on the friction plate 41 along the center direction of the mounting plate 39. The pressing force will push the friction plate 41 to move toward the side close to the friction cover 35 until the friction plate 41 and the friction cover 35 are pressed against each other. At this time, the friction plate 41 will drive the friction cover 35 to rotate through the friction force.
移动结构包括转动安装在滑套40上的转动环43,摩擦罩35上通用锁定架45固定安装有电推杆36,电推杆36与转动环43之间通过连接支架37固定连接,电推杆36与外界电源之间安装有接线部件。The movable structure includes a rotating ring 43 rotatably mounted on the sliding sleeve 40, and an electric push rod 36 is fixedly mounted on a universal locking frame 45 on the friction cover 35. The electric push rod 36 is fixedly connected to the rotating ring 43 through a connecting bracket 37, and a wiring component is installed between the electric push rod 36 and the external power supply.
电推杆36伸缩端回收时,会通过连接支架37转动环43带动向靠近摩擦罩35的一侧移动,由于转动环43与滑套40之间为转动连接,转动环43移动会带动滑套40向靠近摩擦罩35的一侧移动。When the telescopic end of the electric push rod 36 is retracted, it will be driven by the rotating ring 43 of the connecting bracket 37 to move toward the side close to the friction cover 35. Since the rotating ring 43 and the sliding sleeve 40 are rotatably connected, the movement of the rotating ring 43 will drive the sliding sleeve 40 to move toward the side close to the friction cover 35.
接线部件包括通过转动架转动安装在电推杆36上的多个导电滚轮47,电推杆36内设置正接线极以及负接线极,其中一个导电滚轮47与电推杆36内的正接线极固定连接,管束式除雾器15内固定安装有导电环46,导电环46套设在多个导电滚轮47上,导电环46与外界电源之间通过导线一49相连接;The wiring component includes a plurality of conductive rollers 47 rotatably mounted on the electric push rod 36 through a rotating frame, a positive wiring electrode and a negative wiring electrode are arranged in the electric push rod 36, one of the conductive rollers 47 is fixedly connected to the positive wiring electrode in the electric push rod 36, a conductive ring 46 is fixedly installed in the tube bundle type defogger 15, the conductive ring 46 is sleeved on the plurality of conductive rollers 47, and the conductive ring 46 is connected to the external power supply through a wire 49;
电推杆36上固定安装有轴承56,电推杆36内的负接线极与轴承56之间固定连接,轴承56内圈固定安装有导电柱48,导电柱48与管束式除雾器15内壁之间固定连接,导电柱48与外界电源之间通过导线二50相连接。A bearing 56 is fixedly mounted on the electric push rod 36, and the negative terminal in the electric push rod 36 is fixedly connected to the bearing 56. A conductive column 48 is fixedly mounted on the inner ring of the bearing 56, and the conductive column 48 is fixedly connected to the inner wall of the tube bundle type defogger 15. The conductive column 48 is connected to an external power supply via a wire 50.
由于摩擦罩35与摩擦板41接触后,摩擦罩35会转动,而电推杆36与摩擦罩35之间通过锁定架45锁定,因此电推杆36也会随着转动,如果电推杆36与外接电源上直接通过导线一49以及导线二50相连接,则会导致导线一49以及导线二50缠绕,此时将导线一49与导电环46相连接,将导线二50与导电柱48相连接,导电柱48与电推杆36负接线极之间通过轴承56相连接,电推杆36转动时不会带动导线二50以及导电柱48转动,同时电推杆36正接线极与其中一个导电滚轮47上的转动架相连接,导线一49与导电环46相连接,因此电推杆36转动不会带动导线一49转动缠绕,这样可避免导线一49以及导线二50缠绕。After the friction cover 35 contacts the friction plate 41, the friction cover 35 will rotate, and the electric push rod 36 and the friction cover 35 are locked by the locking frame 45, so the electric push rod 36 will also rotate. If the electric push rod 36 is directly connected to the external power supply through the wire 1 49 and the wire 2 50, the wire 1 49 and the wire 2 50 will be entangled. At this time, the wire 1 49 is connected to the conductive ring 46, and the wire 2 50 is connected to the conductive column 48. The conductive column 48 and the negative terminal of the electric push rod 36 are connected through the bearing 56. When the electric push rod 36 rotates, it will not drive the wire 2 50 and the conductive column 48 to rotate. At the same time, the positive terminal of the electric push rod 36 is connected to the rotating frame on one of the conductive rollers 47, and the wire 1 49 is connected to the conductive ring 46. Therefore, the rotation of the electric push rod 36 will not drive the wire 1 49 to rotate and entangle, so that the entanglement of the wire 1 49 and the wire 2 50 can be avoided.
在进一步实施例中,电机30与气旋叶二29之间安装有带动结构;带动结构包括转动安装在轴杆一51内部的轴杆二52,轴杆二52贯穿轴杆一51,轴杆一51与轴杆二52之间固定安装有弹簧卷55,轴杆二52与气旋叶二29之间固定连接,轴杆二52上固定安装有齿轮二54,电机30驱动端固定安装有弧形架33,弧形架33上固定安装有与齿轮二54相啮合的不完全齿环34。In a further embodiment, a driving structure is installed between the motor 30 and the cyclone blade 29; the driving structure includes a shaft 2 52 rotatably installed inside the shaft 1 51, the shaft 2 52 passes through the shaft 1 51, a spring roll 55 is fixedly installed between the shaft 1 51 and the shaft 2 52, the shaft 2 52 is fixedly connected to the cyclone blade 2 29, a gear 2 54 is fixedly installed on the shaft 2 52, an arc frame 33 is fixedly installed on the driving end of the motor 30, and an incomplete gear ring 34 meshing with the gear 2 54 is fixedly installed on the arc frame 33.
每个气旋叶一25上均转动安装有一个气旋叶二29,管束式除雾器15内固定安装有两个导流环24,两个导流环24分别位于中置架26的上下两侧。A cyclone blade 2 29 is rotatably mounted on each cyclone blade 1 25 . Two guide rings 24 are fixedly mounted in the tube bundle demister 15 . The two guide rings 24 are respectively located on the upper and lower sides of the middle frame 26 .
电机30驱动端转动带动弧形架33转动,从而带动不完全齿环34转动,不完全齿环34会带动齿轮二54转动,然后通过轴杆二52带动气旋叶二29转动,当不完全齿环34与齿轮二54脱离后,轴杆二52会在弹簧卷55的作用下复位,以此可改变烟气的流动方向,从而实现更大程度的扰动。The driving end of the motor 30 rotates to drive the arc frame 33 to rotate, thereby driving the incomplete gear ring 34 to rotate. The incomplete gear ring 34 will drive the gear 2 54 to rotate, and then drive the cyclone blade 2 29 to rotate through the shaft 2 52. When the incomplete gear ring 34 is separated from the gear 2 54, the shaft 2 52 will be reset under the action of the spring coil 55, thereby changing the flow direction of the smoke, thereby achieving a greater degree of disturbance.
实施例三:本实施例区别于实施例二技术方案在于:参照图1-图2、图7-图8,除雾除水部,安装在精除尘除雾部的上方,位于脱硫除尘塔1的顶部,用于对烟气脱硫后形成的饱和湿烟气中的小液滴进行去除,除雾除水部包括安装在脱硫除尘塔1内部的除水除雾机构。Embodiment 3: This embodiment is different from the technical solution of Embodiment 2 in that: referring to Figures 1-2 and 7-8, the demisting and dewatering section is installed above the fine dust removal and demisting section and is located at the top of the desulfurization and dust removal tower 1. It is used to remove small droplets in the saturated wet flue gas formed after flue gas desulfurization. The demisting and dewatering section includes a dewatering and demisting mechanism installed inside the desulfurization and dust removal tower 1.
除水除雾机构包括固定安装在脱硫除尘塔1内顶层的气旋除水除雾器20,脱硫除尘塔1顶部固定安装有烟囱21。The dehumidification and demisting mechanism comprises a cyclone dehumidification and demisting device 20 fixedly installed on the top floor of the desulfurization and dust removal tower 1 , and a chimney 21 is fixedly installed on the top of the desulfurization and dust removal tower 1 .
烟气脱硫后形成的饱和湿烟气会携带部分小液滴,这些携带小液滴的饱和湿烟气中的绝大部分液滴经过管束式除雾器15后可以去除,除去绝大部分液滴后的饱和湿烟气经烟囱21直接排入温度较低的大气环境后,由于环境空气的饱和比湿较低,在烟气温度降低过程中水分就会产生凝结,再次形成微小液滴,从而容易产生烟囱21落雨现象。气旋除水除雾器20安装在烟囱21中,气旋除水除雾器20由一组旋流板组成,在旋流板外旋结构作用下,使脱硫净烟气向外离心运动,将冷凝的微小液滴聚合形成的大液滴后重新回到脱硫除尘塔1内,即可以消除烟囱21落雨现象,同时可以减少系统水耗。The saturated wet flue gas formed after flue gas desulfurization will carry some small droplets. Most of the droplets in the saturated wet flue gas carrying small droplets can be removed after passing through the tube bundle demister 15. After most of the droplets are removed, the saturated wet flue gas is directly discharged into the atmospheric environment with a lower temperature through the chimney 21. Due to the low saturated specific humidity of the ambient air, the water will condense during the process of reducing the flue gas temperature, and form tiny droplets again, which is easy to cause the phenomenon of raining in the chimney 21. The cyclone dehydration demister 20 is installed in the chimney 21. The cyclone dehydration demister 20 is composed of a group of cyclone plates. Under the action of the external cyclone structure of the cyclone plate, the desulfurized clean flue gas is centrifugally moved outward, and the condensed tiny droplets are aggregated to form large droplets and then returned to the desulfurization and dust removal tower 1, which can eliminate the phenomenon of raining in the chimney 21 and reduce the water consumption of the system.
实例证明:某80万吨/年催化裂化装置烟气脱硫除尘装置,处理烟气量为:112440Nm3/h,脱硫除尘塔1入口SO2浓度为560mg/Nm3,脱硫除尘塔1入口颗粒物浓度为261mg/Nm3,经过采用EDV6000湿法脱硫除尘装置处理后,脱硫除尘塔1出口SO2浓度<50mg/Nm3,颗粒物浓度<30mg/Nm3,后经过上述四段式梯级协同除尘除雾装置改造后,脱硫除尘塔1出口颗粒物浓度<10mg/Nm3。The example proves that the flue gas desulfurization and dust removal device of a 800,000 tons/year catalytic cracking unit has a flue gas processing volume of 112440Nm3/h, the SO2 concentration at the inlet of the desulfurization and dust removal tower 1 is 560mg/Nm3, and the particulate matter concentration at the inlet of the desulfurization and dust removal tower 1 is 261mg/Nm3. After being treated with the EDV6000 wet desulfurization and dust removal device, the SO2 concentration at the outlet of the desulfurization and dust removal tower 1 is <50mg/Nm3, and the particulate matter concentration is <30mg/Nm3. After being transformed by the above-mentioned four-stage cascade coordinated dust removal and mist removal device, the particulate matter concentration at the outlet of the desulfurization and dust removal tower 1 is <10mg/Nm3.
本装置的具体操作步骤如下:The specific operation steps of this device are as follows:
烟气由下往上从文丘里管束6中通过,同时浆液喷淋管一3以及浆液喷淋管二7会通过对应的喷嘴一4以及喷嘴二8将脱硫浆液喷入文丘里管束中,使烟气和脱硫浆液在文丘里管束6内部两相掺混、反应,实现烟气中SO2和颗粒物的协同脱除,通过锥罩5收集的脱硫浆液通过浆液引出管2引出脱硫除尘塔1,脱硫除尘塔1外部设置固定容器收集,经固定容器收集后处理,再通过泵送至浆液喷淋管二7与浆液喷淋管一3内,循环往复。The flue gas passes through the Venturi tube bundle 6 from bottom to top, and at the same time, the slurry spray pipe 1 3 and the slurry spray pipe 2 7 will spray the desulfurization slurry into the Venturi tube bundle through the corresponding nozzle 1 4 and the nozzle 2 8, so that the flue gas and the desulfurization slurry are mixed and reacted in two phases inside the Venturi tube bundle 6, so as to achieve the coordinated removal of SO2 and particulate matter in the flue gas. The desulfurization slurry collected by the cone cover 5 is led out of the desulfurization dust removal tower 1 through the slurry lead-out pipe 2, and a fixed container is set outside the desulfurization dust removal tower 1 to collect the desulfurization slurry. After being collected in the fixed container, it is processed and then pumped to the slurry spray pipe 2 7 and the slurry spray pipe 1 3, and the cycle is repeated.
经过文丘里管束6脱硫除尘后的净烟气其含有大量的雾滴,雾滴由浆液液滴、凝结液滴和尘颗粒组成,经过管式除雾器9以及屋脊除雾器10后,可以捕集一部分烟气中的含盐液滴、尘颗粒和凝结液滴等,通过定期开启冲洗水管路一11对管式除雾器9以及屋脊除雾器10进行冲洗,去除捕集下来的含盐液滴、尘颗粒和凝结液滴等。同时可以对烟气流场重新进行均布,为后续烟气除尘除雾创造有利条件。The clean flue gas after desulfurization and dust removal by the venturi tube bundle 6 contains a large number of droplets, which are composed of slurry droplets, condensed droplets and dust particles. After passing through the tubular demister 9 and the ridge demister 10, a part of the salt droplets, dust particles and condensed droplets in the flue gas can be captured. The tubular demister 9 and the ridge demister 10 can be flushed by regularly opening the flushing water pipeline 11 to remove the captured salt droplets, dust particles and condensed droplets. At the same time, the flue gas flow field can be re-distributed evenly, creating favorable conditions for subsequent flue gas dust removal and demisting.
经过管式除雾器9以及屋脊除雾器10除尘除雾处理后的净烟气进入管束式除雾器15内,多个管束式除雾器15内的气旋叶一25使脱硫净烟气在管束式除雾器15内旋转起来,在管束式除雾器15内部的上方形成气液两相的剧烈旋转及扰动,从而使得净烟气中的细小液滴、细微粉尘颗粒、气溶胶等微小颗粒物互相碰撞团聚凝聚成大液滴,再在气旋叶一25的作用下,使脱硫净烟气向外离心运动,聚合形成的大液滴与气旋筒壁碰撞,并被气旋筒壁液膜捕获吸收,实现对微小颗粒物的控制,高效除雾除尘。The clean flue gas after dust removal and demisting treatment by the tubular demister 9 and the ridge demister 10 enters the tube bundle demister 15. The cyclone blades 25 in the multiple tube bundle demisters 15 make the desulfurized clean flue gas rotate in the tube bundle demister 15, and violent rotation and disturbance of the gas-liquid two phases are formed above the inside of the tube bundle demister 15, so that the tiny droplets, fine dust particles, aerosols and other tiny particles in the clean flue gas collide with each other, agglomerate and condense into large droplets. Then, under the action of the cyclone blades 25, the desulfurized clean flue gas moves centrifugally outward, and the large droplets formed by aggregation collide with the cyclone cylinder wall and are captured and absorbed by the cyclone cylinder wall liquid film, thereby realizing the control of tiny particles and efficient demisting and dust removal.
在经过管束式除雾器15过程中,使电推杆36伸缩端往复伸缩,电推杆36伸缩端回收时,会通过连接支架37转动环43带动向靠近摩擦罩35的一侧移动,由于转动环43与滑套40之间为转动连接,转动环43移动会带动滑套40向靠近摩擦罩35的一侧移动(电推杆36伸缩端伸出,则滑套40向远离摩擦罩35的一侧移动);When passing through the tube bundle type mist eliminator 15, the telescopic end of the electric push rod 36 is reciprocated and retracted. When the telescopic end of the electric push rod 36 is retracted, it is driven by the rotating ring 43 of the connecting bracket 37 to move toward the side close to the friction cover 35. Since the rotating ring 43 and the sliding sleeve 40 are rotatably connected, the movement of the rotating ring 43 drives the sliding sleeve 40 to move toward the side close to the friction cover 35 (when the telescopic end of the electric push rod 36 is extended, the sliding sleeve 40 moves toward the side away from the friction cover 35).
滑套40向靠近摩擦罩35的一侧移动时,会带动转杆42移动,此时转杆42会抵压摩擦板41,由于转杆42呈倾斜设计,根据力的分解,转杆42会对摩擦板41产生沿安装板39中心方向的抵压作用力,该抵压作用力会推动摩擦板41向靠近摩擦罩35的一侧移动,直至摩擦板41与摩擦罩35相抵为止;When the sliding sleeve 40 moves toward the side close to the friction cover 35, it will drive the rotating rod 42 to move. At this time, the rotating rod 42 will press the friction plate 41. Since the rotating rod 42 is designed to be inclined, according to the decomposition of force, the rotating rod 42 will generate a pressing force on the friction plate 41 along the center direction of the mounting plate 39. The pressing force will push the friction plate 41 to move toward the side close to the friction cover 35 until the friction plate 41 and the friction cover 35 are pressed against each other.
电机30驱动端转动带动转轴38转动,转轴38会带动滑套40转动以及安装架39转动,安装架39转动会通过摩擦板41带动摩擦罩35转动,摩擦罩35转动带动环形架31转动,环形架31转动带动全齿环32转动,从而带动齿轮一53转动,齿轮一53转动带动轴杆一51转动,从而带动气旋叶一25转动,以此来改变气旋叶一25的角度;The driving end of the motor 30 rotates to drive the rotating shaft 38 to rotate, and the rotating shaft 38 drives the sliding sleeve 40 and the mounting frame 39 to rotate. The rotation of the mounting frame 39 drives the friction cover 35 to rotate through the friction plate 41. The rotation of the friction cover 35 drives the annular frame 31 to rotate. The rotation of the annular frame 31 drives the full gear ring 32 to rotate, thereby driving the gear 1 53 to rotate. The rotation of the gear 1 53 drives the shaft 1 51 to rotate, thereby driving the cyclone blade 1 25 to rotate, so as to change the angle of the cyclone blade 1 25.
电机30驱动端转动带动弧形架33转动,从而带动不完全齿环34转动,不完全齿环34会带动齿轮二54转动,然后通过轴杆二52带动气旋叶二29转动,当不完全齿环34与齿轮二54脱离后,轴杆二52会在弹簧卷55的作用下复位,以此可改变烟气的流动方向,从而实现更大程度的扰动(过程中电机30驱动端往复正反转,每次转动一圈后反转,而电推杆36则在换向的初期缩回,这样可调节气旋叶一25的角度后保持气旋叶一25不动,而气旋叶二29还会随着电机30驱动端转动)。The rotation of the driving end of the motor 30 drives the arc frame 33 to rotate, thereby driving the incomplete toothed ring 34 to rotate. The incomplete toothed ring 34 will drive the gear 2 54 to rotate, and then drive the cyclone blade 2 29 to rotate through the shaft 2 52. When the incomplete toothed ring 34 is disengaged from the gear 2 54, the shaft 2 52 will be reset under the action of the spring roll 55, thereby changing the flow direction of the flue gas, thereby achieving a greater degree of disturbance (during the process, the driving end of the motor 30 reciprocates forward and reverse, reverses after each rotation, and the electric push rod 36 retracts at the beginning of the reversal, so that the angle of the cyclone blade 25 can be adjusted and the cyclone blade 25 can be kept stationary, and the cyclone blade 29 will also rotate with the driving end of the motor 30).
改变气旋叶一25的角度,可改变烟气流动方向,使烟气在管束式除雾器15内旋转,利用旋转产生的离心力使烟气中的微小液滴凝结成较大液滴,然后利用液膜对液滴进行吸收,对液滴的去除更加彻底,还可改变气旋叶一25与中置架26之间的角度,角度越小,烟气通过的面积越小,烟气通过阻力越大,加快烟气的流速,提高离心力,从而使得液滴更容易被液膜吸附,同时配合管束式除雾器15内的环形凹槽来增大烟气与管束式除雾器15内壁之间的接触面积,从而提高液滴的吸附效率;Changing the angle of the cyclone blade 25 can change the direction of flue gas flow, causing the flue gas to rotate in the tube bundle demister 15, and using the centrifugal force generated by the rotation to condense tiny droplets in the flue gas into larger droplets, and then using the liquid film to absorb the droplets, so that the droplets can be removed more thoroughly. The angle between the cyclone blade 25 and the center frame 26 can also be changed. The smaller the angle, the smaller the area through which the flue gas passes, and the greater the resistance to the passage of the flue gas, which speeds up the flow rate of the flue gas and increases the centrifugal force, so that the droplets are more easily adsorbed by the liquid film. At the same time, the annular groove in the tube bundle demister 15 is used to increase the contact area between the flue gas and the inner wall of the tube bundle demister 15, thereby improving the adsorption efficiency of the droplets.
由于加快烟气流速的过程中,由于烟气通过阻力增大,所以会导致烟气通过效率降低,此时可反转电机30驱动端,使气旋叶一25反转,且转动的位置超过初始位置,这样可对烟气起到扇动的效果,此时烟气阻力小于原始阻力,而刚才的烟气阻力大于原始阻力,因此来钟模式下的阻力抵消,使得烟气的通过效率保持与原始效率一致,不影响烟气的除尘除雾效率。In the process of accelerating the flue gas flow rate, the resistance of the flue gas passage increases, so the flue gas passage efficiency is reduced. At this time, the driving end of the motor 30 can be reversed to reverse the cyclone blade 25, and the rotation position exceeds the initial position, which can fan the flue gas. At this time, the flue gas resistance is less than the original resistance, and the previous flue gas resistance is greater than the original resistance. Therefore, the resistance in the clock mode is offset, so that the flue gas passage efficiency remains consistent with the original efficiency, and does not affect the dust and mist removal efficiency of the flue gas.
烟气脱硫后形成的饱和湿烟气会携带部分小液滴,这些携带小液滴的饱和湿烟气中的绝大部分液滴经过管束式除雾器15后可以去除,除去绝大部分液滴后的饱和湿烟气经烟囱21直接排入温度较低的大气环境后,由于环境空气的饱和比湿较低,在烟气温度降低过程中水分就会产生凝结,再次形成微小液滴,从而容易产生烟囱21落雨现象。气旋除水除雾器20安装在烟囱21中,气旋除水除雾器20由一组旋流板组成,在旋流板外旋结构作用下,使脱硫净烟气向外离心运动,将冷凝的微小液滴聚合形成的大液滴后重新回到脱硫除尘塔1内,即可以消除烟囱21落雨现象,同时可以减少系统水耗。The saturated wet flue gas formed after flue gas desulfurization will carry some small droplets. Most of the droplets in the saturated wet flue gas carrying small droplets can be removed after passing through the tube bundle demister 15. After most of the droplets are removed, the saturated wet flue gas is directly discharged into the atmospheric environment with a lower temperature through the chimney 21. Due to the low saturated specific humidity of the ambient air, the water will condense during the process of reducing the flue gas temperature, and form tiny droplets again, which is easy to cause the phenomenon of raining in the chimney 21. The cyclone dehydration demister 20 is installed in the chimney 21. The cyclone dehydration demister 20 is composed of a group of cyclone plates. Under the action of the external cyclone structure of the cyclone plate, the desulfurized clean flue gas is centrifugally moved outward, and the condensed tiny droplets are aggregated to form large droplets and then returned to the desulfurization and dust removal tower 1, which can eliminate the phenomenon of raining in the chimney 21 and reduce the water consumption of the system.
以上,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above are only preferred specific implementation modes of the present invention, but the protection scope of the present invention is not limited thereto. Any technician familiar with the technical field can make equivalent replacements or changes according to the technical solutions and inventive concepts of the present invention within the technical scope disclosed by the present invention, which should be covered by the protection scope of the present invention.
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CN202411001788.8A Active CN118751057B (en) | 2024-07-25 | 2024-07-25 | A device for controlling ultra-low emission of particulate matter in catalytic cracking flue gas |
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Citations (6)
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JPH07229325A (en) * | 1994-02-18 | 1995-08-29 | Mitsubishi Heavy Ind Ltd | Desulfurization stack |
CN205965486U (en) * | 2016-07-15 | 2017-02-22 | 日照广源热动有限公司 | Single tower height is imitated desulfurization and is removed dust in coordination with environmental protection processing device |
CN106731422A (en) * | 2017-02-23 | 2017-05-31 | 哈尔滨锅炉厂环保工程技术有限公司 | A kind of desulfurizing tower dust is grown up and merges dedusting demisting integrated apparatus |
CN206198867U (en) * | 2016-08-25 | 2017-05-31 | 上海海涵环保科技有限公司 | A kind of flue gas demister with the dynamic spiral board of adjustable profile shaft |
CN112023626A (en) * | 2020-08-01 | 2020-12-04 | 内蒙古高原蓝节能环保科技有限公司 | Flue gas treatment system and process |
CN220143029U (en) * | 2023-09-13 | 2023-12-08 | 北京美斯顿科技开发有限公司 | Catalytic cracking flue gas desulfurization dust removal system |
-
2024
- 2024-07-25 CN CN202411001788.8A patent/CN118751057B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH07229325A (en) * | 1994-02-18 | 1995-08-29 | Mitsubishi Heavy Ind Ltd | Desulfurization stack |
CN205965486U (en) * | 2016-07-15 | 2017-02-22 | 日照广源热动有限公司 | Single tower height is imitated desulfurization and is removed dust in coordination with environmental protection processing device |
CN206198867U (en) * | 2016-08-25 | 2017-05-31 | 上海海涵环保科技有限公司 | A kind of flue gas demister with the dynamic spiral board of adjustable profile shaft |
CN106731422A (en) * | 2017-02-23 | 2017-05-31 | 哈尔滨锅炉厂环保工程技术有限公司 | A kind of desulfurizing tower dust is grown up and merges dedusting demisting integrated apparatus |
CN112023626A (en) * | 2020-08-01 | 2020-12-04 | 内蒙古高原蓝节能环保科技有限公司 | Flue gas treatment system and process |
CN220143029U (en) * | 2023-09-13 | 2023-12-08 | 北京美斯顿科技开发有限公司 | Catalytic cracking flue gas desulfurization dust removal system |
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