CN118702342A - A sewage treatment equipment - Google Patents
A sewage treatment equipment Download PDFInfo
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- CN118702342A CN118702342A CN202410928328.3A CN202410928328A CN118702342A CN 118702342 A CN118702342 A CN 118702342A CN 202410928328 A CN202410928328 A CN 202410928328A CN 118702342 A CN118702342 A CN 118702342A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/16—Regeneration of sorbents, filters
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
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- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Water Treatment By Sorption (AREA)
Abstract
本发明公开了一种污水处理设备,涉及污水处理技术领域;具体包括依次连通的沉淀池、初滤吸附池、反应池和中和精滤部,所述中和精滤部包括处理管、设置于处理管下游侧壁的酸碱检测仪、设置于处理管上游侧壁的中和液供应机构以及设置于处理管上游内部的精滤机构,所述精滤机构位于中和液供应机构的上游,所述中和液供应机构包括酸液箱和碱液箱,所述酸液箱与碱液箱的出液口连接有三通开度阀。本发明通过设置酸液箱与碱液箱,利用输送泵进行输送,再结合酸碱检测仪对处理管内污水酸碱度的感知,从而配合阀芯的位置,能实现中和的同时,还能根据具体酸性和碱性的强度来具体调节酸液和碱液的用量,增加了中和的可靠性。
The invention discloses a sewage treatment equipment, which relates to the technical field of sewage treatment; specifically, it comprises a sedimentation tank, a primary filtration adsorption tank, a reaction tank and a neutralization fine filtration part which are connected in sequence, the neutralization fine filtration part comprises a treatment pipe, an acid-base detector arranged on the downstream side wall of the treatment pipe, a neutralization liquid supply mechanism arranged on the upstream side wall of the treatment pipe, and a fine filtration mechanism arranged inside the upstream of the treatment pipe, the fine filtration mechanism is located upstream of the neutralization liquid supply mechanism, the neutralization liquid supply mechanism comprises an acid tank and an alkali tank, and the liquid outlets of the acid tank and the alkali tank are connected with a three-way opening valve. The invention arranges an acid tank and an alkali tank, uses a delivery pump for delivery, and then combines the acid-base detector to sense the acidity and alkalinity of the sewage in the treatment pipe, thereby coordinating with the position of the valve core, can achieve neutralization, and can also specifically adjust the amount of acid and alkali according to the specific acidity and alkalinity strength, thereby increasing the reliability of neutralization.
Description
技术领域Technical Field
本发明涉及污水处理技术领域,尤其涉及一种污水处理设备。The present invention relates to the technical field of sewage treatment, and in particular to sewage treatment equipment.
背景技术Background Art
污水处理为使污水达到排入某一水体或再次使用的水质要求而对其进行净化的过程。污水处理被广泛应用于建筑、农业、交通、能源、石化、环保、城市景观、医疗、餐饮等各个领域,也越来越多地走进寻常百姓的日常生活。Wastewater treatment is the process of purifying wastewater to meet the water quality requirements for discharge into a water body or reuse. Wastewater treatment is widely used in various fields such as construction, agriculture, transportation, energy, petrochemicals, environmental protection, urban landscape, medical care, and catering, and is increasingly entering the daily lives of ordinary people.
中国专利公开号为CN108947104A的专利,公开了污水处理设备,包括依次连通的沉淀池、过滤吸附池、氧化池、消毒池及清水池;其中,所述过滤吸附池包括池体、滤网、活性炭层、砂石层及石块层,所述池体底部设置有出水口连通于所述氧化池,所述池体顶部设置有进水口连通于所述沉淀池,所述滤网设置在所述出水口顶部,所述滤网顶部依次设置有活性炭层、砂石层及石块层。The Chinese patent publication number CN108947104A discloses sewage treatment equipment, including a sedimentation tank, a filtration and adsorption tank, an oxidation tank, a disinfection tank and a clean water tank connected in sequence; wherein the filtration and adsorption tank includes a tank body, a filter screen, an activated carbon layer, a sand and gravel layer and a stone layer, a water outlet is arranged at the bottom of the tank body to be connected to the oxidation tank, a water inlet is arranged at the top of the tank body to be connected to the sedimentation tank, the filter screen is arranged on the top of the water outlet, and an activated carbon layer, a sand and gravel layer and a stone layer are arranged in sequence on the top of the filter screen.
上述专利存在以下不足:由于在氧化和消毒的过程中会引入酸性或者碱性物质,这就会使得净化后的水也会呈酸性或者碱性,导致处理效果差。The above patent has the following shortcomings: since acidic or alkaline substances are introduced during the oxidation and disinfection process, the purified water will also be acidic or alkaline, resulting in poor treatment effect.
为此,本发明提出一种污水处理设备。To this end, the present invention provides a sewage treatment device.
发明内容Summary of the invention
本发明的目的是为了解决现有技术中存在的缺点,而提出的一种污水处理设备。The purpose of the present invention is to solve the shortcomings of the prior art and to propose a sewage treatment device.
为了实现上述目的,本发明采用了如下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:
一种污水处理设备,包括依次连通的沉淀池、初滤吸附池、反应池和中和精滤部,A sewage treatment device comprises a sedimentation tank, a primary filtration adsorption tank, a reaction tank and a neutralization and fine filtration part which are connected in sequence.
所述中和精滤部包括处理管、设置于处理管下游侧壁的酸碱检测仪、设置于处理管上游侧壁的中和液供应机构以及设置于处理管上游内部的精滤机构,所述精滤机构位于中和液供应机构的上游;The neutralization and fine filtration section comprises a treatment tube, an acid-base detector arranged on the downstream side wall of the treatment tube, a neutralization liquid supply mechanism arranged on the upstream side wall of the treatment tube, and a fine filtration mechanism arranged inside the upstream of the treatment tube, wherein the fine filtration mechanism is located upstream of the neutralization liquid supply mechanism;
所述中和液供应机构包括酸液箱和碱液箱,所述酸液箱与碱液箱的出液口连接有三通开度阀,三通开度阀的出液口连接有三通管,三通管通过输送泵连接于处理管的侧壁;The neutralizing liquid supply mechanism comprises an acid liquid tank and an alkali liquid tank, the liquid outlets of the acid liquid tank and the alkali liquid tank are connected with a three-way opening valve, the liquid outlet of the three-way opening valve is connected with a three-way pipe, and the three-way pipe is connected to the side wall of the treatment pipe through a delivery pump;
所述三通开度阀包括阀壳和滑动连接于阀壳内壁的阀芯,所述阀壳的内壁开设有“Y”型流道,阀芯的内壁开设有两个与“Y”型流道配合的透孔,且所述阀芯的一侧通过螺栓固定有电磁铁B,阀壳的内壁通过螺栓固定有电磁铁A,电磁铁B与电磁铁A相对布置;The three-way opening valve comprises a valve housing and a valve core slidably connected to the inner wall of the valve housing, the inner wall of the valve housing is provided with a "Y"-shaped flow channel, the inner wall of the valve core is provided with two through holes matching the "Y"-shaped flow channel, and an electromagnet B is fixed to one side of the valve core by bolts, an electromagnet A is fixed to the inner wall of the valve housing by bolts, and the electromagnet B is arranged opposite to the electromagnet A;
所述阀芯的外壁套设有密封圈,密封圈贴合于阀壳的内部;The outer wall of the valve core is sleeved with a sealing ring, which fits the inside of the valve housing;
所述酸碱检测仪包括通过连接块固定于处理管侧壁的参比电极、氢离子选择性电极和磁屏蔽罩,所述磁屏蔽罩通过螺栓固定于处理管的侧壁,磁屏蔽罩的内壁固定有铁芯,铁芯的两端分别卷绕有线圈A和线圈B,所述线圈B的两端通过逆变器电连接于参比电极和氢离子选择性电极,所述线圈B的两端分别通过一组滑动接触组件电性连接于电磁铁A和电磁铁B,且所述电磁铁A与电磁铁B的电流方向相反。The acid-base detector includes a reference electrode, a hydrogen ion selective electrode and a magnetic shielding cover fixed to the side wall of the processing tube through a connecting block. The magnetic shielding cover is fixed to the side wall of the processing tube by bolts. An iron core is fixed to the inner wall of the magnetic shielding cover. Coil A and coil B are respectively wound around the two ends of the iron core. The two ends of coil B are electrically connected to the reference electrode and the hydrogen ion selective electrode through an inverter. The two ends of coil B are electrically connected to electromagnet A and electromagnet B through a group of sliding contact components, and the current directions of electromagnet A and electromagnet B are opposite.
优选的:两组所述滑动接触组件对称式布置,所述铁芯内壁固定设置有导向滑杆,所述滑动接触组件包括导向滑杆以及滑动连接于导向滑杆外壁的磁吸块。Preferably, the two groups of sliding contact components are arranged symmetrically, a guide slide bar is fixedly provided on the inner wall of the iron core, and the sliding contact component comprises a guide slide bar and a magnetic block slidably connected to the outer wall of the guide slide bar.
进一步的:所述磁吸块的侧壁固定有弹簧触头,弹簧触头接触并电性连接于线圈B的侧壁,磁吸块的侧壁扣接有绝缘弹簧,绝缘弹簧的另一端扣接于铁芯的侧壁。Furthermore: a spring contact is fixed to the side wall of the magnetic block, the spring contact contacts and is electrically connected to the side wall of the coil B, an insulating spring is buckled to the side wall of the magnetic block, and the other end of the insulating spring is buckled to the side wall of the iron core.
在前述方案的基础上:所述精滤机构包括固定于处理管内壁的滤板以及通过驱动轴转动连接于滤板的刮板,且所述刮板贴合于滤板的过滤面,所述驱动轴的端部设置有驱动组件。On the basis of the above scheme: the fine filtration mechanism includes a filter plate fixed to the inner wall of the processing tube and a scraper rotatably connected to the filter plate through a drive shaft, and the scraper is attached to the filtration surface of the filter plate, and a drive assembly is provided at the end of the drive shaft.
在前述方案中更佳的方案是:所述处理管位于滤板上游的底部外壁开设有漏槽,漏槽的底部外壁通过螺栓固定有集污盒。A better solution among the above solutions is that: a leakage groove is opened on the bottom outer wall of the processing pipe located upstream of the filter plate, and a dirt collecting box is fixed to the bottom outer wall of the leakage groove by bolts.
作为本发明进一步的方案:所述刮板包括固定于驱动轴端部的连接板以及多组通过连接轴转动连接于连接板的转辊,一组内的两个所述转辊的外壁配合有连接带。As a further solution of the present invention: the scraper includes a connecting plate fixed to the end of the driving shaft and multiple groups of rollers rotatably connected to the connecting plate through connecting shafts, and the outer walls of two of the rollers in one group are equipped with connecting belts.
同时,所述连接带的外壁固定有均匀的输送板,所述滤板的侧壁固定有固定圈,转辊与连接轴通过同步带传动配合。At the same time, a uniform conveying plate is fixed on the outer wall of the connecting belt, a fixing ring is fixed on the side wall of the filter plate, and the rotating roller and the connecting shaft are matched through synchronous belt transmission.
作为本发明的一种优选的:所述驱动组件包括滑动配合于驱动轴外壁的滑环以及多个通过转盘转动连接于滑环外壁的涡轮叶片。As a preferred embodiment of the present invention, the driving assembly comprises a slip ring slidably fitted on the outer wall of the driving shaft and a plurality of turbine blades rotatably connected to the outer wall of the slip ring via a rotating disk.
同时,所述驱动轴一侧设置有弹性体,且所述滑环通过弹性体与驱动轴的端部相连接。At the same time, an elastic body is arranged on one side of the driving shaft, and the slip ring is connected to the end of the driving shaft through the elastic body.
作为本发明的一种更优的方案:所述驱动轴的外侧开设有限位槽,转盘通过其内壁焊接的两个转辊活动限位配合于限位槽的内壁,且所述限位槽为弧线和直线的组合型结构。As a more optimal solution of the present invention: a limiting groove is opened on the outer side of the driving shaft, and the turntable is movably limited and matched with the inner wall of the limiting groove through two rollers welded on the inner wall of the turntable, and the limiting groove is a combination structure of an arc and a straight line.
本发明的有益效果为:The beneficial effects of the present invention are:
1.通过设置酸液箱与碱液箱并利用输送泵进行输送,再结合酸碱检测仪对处理管内污水酸碱度的感知,从而配合阀芯的位置,可以在实现中和的同时,还能根据具体酸性和碱性的强度来调节酸液和碱液的用量,增加了中和的可靠性。1. By setting up an acid tank and an alkali tank and using a delivery pump for delivery, and combining the acid-base detector to sense the pH of the sewage in the treatment pipe, and thus coordinating the position of the valve core, it is possible to achieve neutralization while adjusting the amount of acid and alkali according to the specific acidity and alkalinity, thereby increasing the reliability of neutralization.
2.首先利用参比电极与氢离子选择性电极对氢离子浓度进行感知,再利用其感知产生电动势的特点,可以使产生的电动势用于驱动电磁铁A与电磁铁B,从而能实现既“感知”、也“驱动”的效果,同时再结合三通开度阀的工作特性,能实现酸液箱与碱液箱的自动切换和流道大小的自适应调节。2. First, the reference electrode and the hydrogen ion selective electrode are used to sense the hydrogen ion concentration, and then the characteristic of sensing and generating electromotive force can be used to drive electromagnet A and electromagnet B, thereby achieving the effect of both "sensing" and "driving". At the same time, combined with the working characteristics of the three-way opening valve, the automatic switching of the acid tank and the alkali tank and the adaptive adjustment of the flow channel size can be realized.
3.通过利用铁芯导磁时产生的交变磁场,使其能利用磁吸力改变磁吸块的位置,从而使得弹簧触头与线圈B的配合位置根据磁力大小而改变,当线圈A电动势改变时,线圈B的感应电动势同样改变,且改变幅度较大,从而使得电磁铁A与电磁铁B具有一个相对较大的电动势范围,进而能更加精确地控制三通开度阀的状态,增加中和的精度。3. By utilizing the alternating magnetic field generated when the iron core is magnetically conductive, the magnetic attraction force can be used to change the position of the magnetic attraction block, so that the matching position of the spring contact and the coil B changes according to the size of the magnetic force. When the electromotive force of coil A changes, the induced electromotive force of coil B also changes, and the change amplitude is large, so that electromagnet A and electromagnet B have a relatively large electromotive force range, and thus the state of the three-way opening valve can be controlled more accurately, increasing the accuracy of neutralization.
4.通过设置的刮板从而对滤板表面的污物进行清除,防止堵塞。在此基础上,通过设置连接轴、固定圈、同步带以及转辊、连接带、输送板,可以在清除的同时利用连接板的旋转使得输送板运动,从而可将污物向外侧拨动,能更好的使污物进入集污盒内进行收集。4. The scraper is used to remove the dirt on the surface of the filter plate to prevent clogging. On this basis, by setting the connecting shaft, fixed ring, synchronous belt, roller, connecting belt and conveying plate, the conveying plate can be moved by the rotation of the connecting plate while cleaning, so that the dirt can be pushed outward, which can better allow the dirt to enter the dirt collection box for collection.
5.通过设置涡轮叶片,从而可以利用水流作用力驱使驱动轴旋转,即为驱动轴旋转提供了动力源布置。另外,通过设置的限位槽、限位柱以及弹性体的配合,从而使得涡轮叶片的“偏转”角度与水流速度相关,进而实现负反馈调节,从而能使得涡轮叶片对驱动轴的驱动转速相对“适中”,保证污物去除的可靠性。5. By setting the turbine blades, the water flow force can be used to drive the drive shaft to rotate, that is, a power source arrangement is provided for the rotation of the drive shaft. In addition, through the coordination of the setting of the limit groove, the limit column and the elastic body, the "deflection" angle of the turbine blade is related to the water flow speed, thereby realizing negative feedback regulation, so that the driving speed of the turbine blade to the drive shaft can be relatively "moderate", ensuring the reliability of dirt removal.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本发明提出的一种污水处理设备的整体布置结构示意图;FIG1 is a schematic diagram of the overall layout structure of a sewage treatment equipment proposed by the present invention;
图2为本发明提出的一种污水处理设备的中和精滤部结构示意图;FIG2 is a schematic structural diagram of a neutralization and fine filtration unit of a sewage treatment device proposed by the present invention;
图3为本发明提出的一种污水处理设备的中和液供应机构结构示意图;FIG3 is a schematic structural diagram of a neutralization liquid supply mechanism for a sewage treatment device proposed by the present invention;
图4为本发明提出的一种污水处理设备的三通开度阀剖视结构示意图;FIG4 is a schematic cross-sectional view of a three-way opening valve of a sewage treatment equipment proposed by the present invention;
图5为本发明提出的一种污水处理设备的酸碱检测仪剖视结构示意图;FIG5 is a schematic cross-sectional view of an acid-base detector for a sewage treatment device according to the present invention;
图6为本发明提出的一种污水处理设备的酸碱检测仪内部结构示意图;FIG6 is a schematic diagram of the internal structure of an acid-base detector for a sewage treatment device proposed by the present invention;
图7为本发明提出的一种污水处理设备的精滤机构结构示意图;FIG7 is a schematic structural diagram of a fine filtration mechanism of a sewage treatment device proposed by the present invention;
图8为本发明提出的一种污水处理设备的刮板剖视结构示意图一;FIG8 is a schematic diagram of a cross-sectional structure of a scraper of a sewage treatment equipment proposed by the present invention;
图9为本发明提出的一种污水处理设备的刮板剖视结构示意图二;FIG9 is a second schematic cross-sectional structural diagram of a scraper of a sewage treatment equipment proposed by the present invention;
图10为本发明提出的一种污水处理设备的驱动组件结构示意图;FIG10 is a schematic diagram of the structure of a driving component of a sewage treatment device proposed by the present invention;
图11为本发明提出的一种污水处理设备的驱动组件剖视结构示意图;FIG11 is a schematic cross-sectional view of a driving assembly of a sewage treatment device proposed by the present invention;
图12为本发明提出的一种污水处理设备的限位槽结构示意图。FIG. 12 is a schematic diagram of the limit groove structure of a sewage treatment device proposed by the present invention.
图中:1、沉淀池;2、初滤吸附池;3、反应池;4、中和精滤部;5、处理管;6、酸碱检测仪;7、中和液供应机构;8、精滤机构;9、酸液箱;10、碱液箱;11、三通开度阀;12、三通管;13、输送泵;14、阀壳;15、弹簧一;16、阀芯;17、透孔;18、密封圈;19、电磁铁A;20、电磁铁B;21、“Y”型流道;22、连接块;23、参比电极;24、氢离子选择性电极;25、线圈A;26、线圈B;27、滑动接触组件;28、磁屏蔽罩;29、铁芯;30、弹簧触头;31、绝缘弹簧;32、导向滑杆;33、磁吸块;34、滤板;35、刮板;36、漏槽;37、集污盒;38、驱动组件;39、驱动轴;40、连接板;41、连接轴;42、转辊;43、固定圈;44、连接带;45、输送板;46、限位槽;47、同步带;48、滑环;49、涡轮叶片;50、转盘;51、弹性体;52、限位柱。In the figure: 1, sedimentation tank; 2, primary filtration adsorption tank; 3, reaction tank; 4, neutralization and fine filtration unit; 5, treatment tube; 6, acid-base detector; 7, neutralization liquid supply mechanism; 8, fine filtration mechanism; 9, acid tank; 10, alkali tank; 11, three-way opening valve; 12, three-way pipe; 13, delivery pump; 14, valve housing; 15, spring 1; 16, valve core; 17, through hole; 18, sealing ring; 19, electromagnet A; 20, electromagnet B; 21, "Y" type flow channel; 22, connecting block; 23, reference electrode; 24, hydrogen ion selective electrode; 25, coil A; 26. Coil B; 27. Sliding contact assembly; 28. Magnetic shielding cover; 29. Iron core; 30. Spring contact; 31. Insulating spring; 32. Guide slide rod; 33. Magnetic block; 34. Filter plate; 35. Scraper; 36. Leakage groove; 37. Dirt collecting box; 38. Drive assembly; 39. Drive shaft; 40. Connecting plate; 41. Connecting shaft; 42. Roller; 43. Fixed ring; 44. Connecting belt; 45. Conveyor plate; 46. Limiting groove; 47. Synchronous belt; 48. Slip ring; 49. Turbine blade; 50. Turntable; 51. Elastomer; 52. Limiting column.
具体实施方式DETAILED DESCRIPTION
下面结合具体实施方式对本发明的技术方案作进一步详细地说明。The technical solution of the present invention is further described in detail below in conjunction with specific implementation methods.
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。Embodiments of the present invention are described in detail below, examples of which are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements having the same or similar functions. The embodiments described below with reference to the accompanying drawings are exemplary and are only used to explain the present invention, and cannot be understood as limiting the present invention.
实施例1:Embodiment 1:
一种污水处理设备,如图1-12所示,包括依次连通的沉淀池1、初滤吸附池2、反应池3和中和精滤部4,本实施例中,对所述沉淀池1、初滤吸附池2、反应池3的具体结构不做限定,其为污水处理领域的常规手段,例如中国专利公开号为CN108947104A的专利,其已经公开具体结构和方法,本实施例不做赘述。A sewage treatment equipment, as shown in Figures 1-12, includes a sedimentation tank 1, a primary filtration adsorption tank 2, a reaction tank 3 and a neutralization and fine filtration part 4 connected in sequence. In this embodiment, the specific structure of the sedimentation tank 1, the primary filtration adsorption tank 2, and the reaction tank 3 is not limited. They are conventional means in the field of sewage treatment. For example, the Chinese patent publication number CN108947104A has disclosed the specific structure and method, which will not be repeated in this embodiment.
所述中和精滤部4包括处理管5、设置于处理管5下游侧壁的酸碱检测仪6、设置于处理管5上游侧壁的中和液供应机构7以及设置于处理管5上游内部的精滤机构8,所述精滤机构8位于中和液供应机构7的上游。The neutralization and fine filtration section 4 includes a processing tube 5, an acid-base detector 6 arranged on the downstream side wall of the processing tube 5, a neutralization liquid supply mechanism 7 arranged on the upstream side wall of the processing tube 5, and a fine filtration mechanism 8 arranged inside the upstream of the processing tube 5, and the fine filtration mechanism 8 is located upstream of the neutralization liquid supply mechanism 7.
所述中和液供应机构7包括酸液箱9和碱液箱10,所述酸液箱9与碱液箱10的出液口连接有三通开度阀11,三通开度阀11的出液口连接有三通管12,三通管12通过输送泵13连接于处理管5的侧壁。The neutralizing liquid supply mechanism 7 includes an acid liquid tank 9 and an alkali liquid tank 10, the liquid outlets of the acid liquid tank 9 and the alkali liquid tank 10 are connected with a three-way opening valve 11, the liquid outlet of the three-way opening valve 11 is connected with a three-way pipe 12, and the three-way pipe 12 is connected to the side wall of the treatment tube 5 through a delivery pump 13.
所述三通开度阀11包括阀壳14和滑动连接于阀壳14内壁的阀芯16,所述阀壳14的内壁开设有“Y”型流道21,阀芯16的内壁开设有两个与“Y”型流道21配合的透孔17,且所述阀芯16的一侧通过螺栓固定有电磁铁B20,阀壳14的内壁通过螺栓固定有电磁铁A19,电磁铁B20与电磁铁A19相对布置。The three-way opening valve 11 includes a valve housing 14 and a valve core 16 slidably connected to the inner wall of the valve housing 14, the inner wall of the valve housing 14 is provided with a "Y"-shaped flow channel 21, the inner wall of the valve core 16 is provided with two through holes 17 that cooperate with the "Y"-shaped flow channel 21, and one side of the valve core 16 is fixed with an electromagnet B20 by bolts, and the inner wall of the valve housing 14 is fixed with an electromagnet A19 by bolts, and the electromagnet B20 is arranged opposite to the electromagnet A19.
所述阀芯16的外壁套设有密封圈18,密封圈18贴合于阀壳14的内部。The outer wall of the valve core 16 is sleeved with a sealing ring 18 , which is fitted into the interior of the valve housing 14 .
所述酸碱检测仪6包括通过连接块22固定于处理管5侧壁的参比电极23、氢离子选择性电极24和磁屏蔽罩28,所述磁屏蔽罩28通过螺栓固定于处理管5的侧壁,磁屏蔽罩28的内壁固定有铁芯29,铁芯29的两端分别卷绕有线圈A25和线圈B26,所述线圈B26的两端通过逆变器电连接于参比电极23和氢离子选择性电极24,所述线圈B26的两端分别通过一组滑动接触组件27电性连接于电磁铁A19和电磁铁B20,且所述电磁铁A19与电磁铁B20的电流方向相反。The acid-base detector 6 includes a reference electrode 23, a hydrogen ion selective electrode 24 and a magnetic shielding cover 28 fixed to the side wall of the processing tube 5 through a connecting block 22. The magnetic shielding cover 28 is fixed to the side wall of the processing tube 5 by bolts. An iron core 29 is fixed to the inner wall of the magnetic shielding cover 28. Coil A25 and coil B26 are respectively wound around the two ends of the iron core 29. The two ends of the coil B26 are electrically connected to the reference electrode 23 and the hydrogen ion selective electrode 24 through an inverter. The two ends of the coil B26 are electrically connected to the electromagnet A19 and the electromagnet B20 through a group of sliding contact components 27, and the current directions of the electromagnet A19 and the electromagnet B20 are opposite.
本装置在使用时污水经过沉淀池1、初滤吸附池2、反应池3处理,处理后进入处理管5的上游位置,然后被精滤机构8过滤,过滤后,滤液经过参比电极23和氢离子选择性电极24,参比电极23和对滤液中的氢离子进行感知,从而参比电极23与氢离子选择性电极24之间形成电动势,电动势经过逆变器转化为交流电后施加于线圈A25,从而在铁芯29内产生交变磁通量,线圈B26内会产生感应电动势,从而将感应电动势施加于电磁铁A19与电磁铁B20内,当水呈碱性时,氢离子浓度较低,此时阀芯16受到弹簧一15的弹力作用使得透孔17连通于酸液箱9,当污水中的氢离子的浓度逐渐升高,碱性降低时,此时电磁铁A19与电磁铁B20内的感应电动势增加,其磁斥力增加,从而使得阀芯16移动,使得连通于酸液箱9的透孔17与“Y”型流道21错开,重叠面积减少,从而对酸液节流,降低流速,直至溶液达到中性时,两个透孔17与“Y”型流道21均不连通,随后当氢离子浓度逐渐上升时,电磁铁A19与电磁铁B20的感应电动势继续增加,阀芯16继续移动,使得透孔17与碱液箱10连通,从而使得碱液箱10流入处理管5内进行中和,并且氢离子浓度继续上升,酸性增加时,透孔17与“Y”型流道21的重叠面积增加,从而使得碱液的流道面积增加。When the device is in use, sewage is treated by sedimentation tank 1, primary filtration adsorption tank 2, and reaction tank 3, and then enters the upstream position of treatment pipe 5 after treatment, and then is filtered by fine filtration mechanism 8. After filtration, the filtrate passes through reference electrode 23 and hydrogen ion selective electrode 24, and reference electrode 23 senses hydrogen ions in the filtrate, so that electromotive force is formed between reference electrode 23 and hydrogen ion selective electrode 24, and the electromotive force is converted into alternating current by inverter and applied to coil A25, so that alternating magnetic flux is generated in iron core 29, and induced electromotive force is generated in coil B26, so that the induced electromotive force is applied to electromagnet A19 and electromagnet B20. When the water is alkaline, the concentration of hydrogen ions is low. At this time, valve core 16 is acted on by the elastic force of spring 15 so that through hole 17 is connected to acid tank 9. When the concentration of hydrogen ions in sewage is high, the valve core 16 is connected to acid tank 9 by the elastic force of spring 15. As the degree gradually increases and the alkalinity decreases, the induced electromotive force in the electromagnet A19 and the electromagnet B20 increases, and the magnetic repulsion increases, thereby moving the valve core 16, so that the through hole 17 connected to the acid liquid tank 9 and the "Y"-shaped flow channel 21 are staggered, and the overlapping area is reduced, thereby throttling the acid liquid and reducing the flow rate, until the solution reaches neutrality, the two through holes 17 are not connected to the "Y"-shaped flow channel 21, and then when the hydrogen ion concentration gradually increases, the induced electromotive force of the electromagnet A19 and the electromagnet B20 continues to increase, and the valve core 16 continues to move, so that the through hole 17 is connected to the alkali liquid tank 10, so that the alkali liquid tank 10 flows into the treatment tube 5 for neutralization, and the hydrogen ion concentration continues to rise. When the acidity increases, the overlapping area between the through hole 17 and the "Y"-shaped flow channel 21 increases, thereby increasing the flow channel area of the alkali liquid.
本装置,通过设置酸液箱9与碱液箱10,利用输送泵13进行输送,再结合酸碱检测仪6对处理管5内污水酸碱度的感知,从而配合阀芯16的位置,能实现中和的同时,还能根据具体酸性和碱性的强度来具体调节酸液和碱液的用量,增加了中和的可靠性。This device, by setting up an acid tank 9 and an alkali tank 10, uses a delivery pump 13 for delivery, and then combines the acid-base detector 6 to sense the acidity and alkalinity of the sewage in the treatment pipe 5, thereby coordinating the position of the valve core 16, can achieve neutralization, and can also specifically adjust the amount of acid and alkali solution according to the specific acidity and alkalinity strength, thereby increasing the reliability of neutralization.
另外,本装置利用参比电极23与氢离子选择性电极24对氢离子浓度进行感知,再利用其感知产生电动势的特点,再且产生的电动势用于驱动电磁铁A19与电磁铁B20,从而能实现既“感知”、也“驱动”的效果,同时再结合三通开度阀11的工作特性,能实现酸液箱9与碱液箱10的自动切换和流道大小的自适应调节。In addition, the device uses the reference electrode 23 and the hydrogen ion selective electrode 24 to sense the hydrogen ion concentration, and then uses the characteristics of the sensing to generate electromotive force, and the generated electromotive force is used to drive the electromagnet A19 and the electromagnet B20, thereby achieving both "sensing" and "driving" effects. At the same time, combined with the working characteristics of the three-way opening valve 11, it can realize the automatic switching of the acid tank 9 and the alkali tank 10 and the adaptive adjustment of the flow channel size.
为了解决控制效果问题;如图6所示,两组所述滑动接触组件27对称式布置,所述铁芯29内壁固定设置有导向滑杆32,所述滑动接触组件27包括导向滑杆32以及滑动连接于导向滑杆32外壁的磁吸块33,所述磁吸块33的侧壁固定有弹簧触头30,弹簧触头30接触并电性连接于线圈B26的侧壁,磁吸块33的侧壁扣接有绝缘弹簧31,绝缘弹簧31的另一端扣接于铁芯29的侧壁。In order to solve the control effect problem; as shown in Figure 6, the two groups of sliding contact components 27 are arranged symmetrically, and a guide slide rod 32 is fixedly provided on the inner wall of the iron core 29. The sliding contact component 27 includes a guide slide rod 32 and a magnetic block 33 slidably connected to the outer wall of the guide slide rod 32. The side wall of the magnetic block 33 is fixed with a spring contact 30, and the spring contact 30 contacts and is electrically connected to the side wall of the coil B26. The side wall of the magnetic block 33 is buckled with an insulating spring 31, and the other end of the insulating spring 31 is buckled to the side wall of the iron core 29.
由于铁芯29内会产生交变磁场,交变磁场会对磁吸块33施加一个等效磁场,且等效磁场的场强与交变磁场的场强相关,等效磁场会施加于磁吸块33,从而使得磁吸块33克服绝缘弹簧31的弹力移动,从而使得弹簧触头30与线圈B26的配合位置改变,从而使得线圈B26接入电路的匝数改变,从而能将参比电极23与氢离子选择性电极24之间电动势的改变放大后再施加于电磁铁A19与电磁铁B20。Since an alternating magnetic field is generated in the iron core 29, the alternating magnetic field will apply an equivalent magnetic field to the magnetic block 33, and the field strength of the equivalent magnetic field is related to the field strength of the alternating magnetic field. The equivalent magnetic field will be applied to the magnetic block 33, so that the magnetic block 33 overcomes the elastic force of the insulating spring 31 and moves, thereby changing the matching position of the spring contact 30 and the coil B26, thereby changing the number of turns of the coil B26 connected to the circuit, so that the change in the electromotive force between the reference electrode 23 and the hydrogen ion selective electrode 24 can be amplified and then applied to the electromagnet A19 and the electromagnet B20.
本装置,通过利用铁芯29导磁时产生的交变磁场,其能利用磁吸力改变磁吸块33的位置,从而使得弹簧触头30与线圈B26的配合位置根据磁力大小而改变,从而使得线圈A25电动势改变时,线圈B26的感应电动势同样改变,且改变幅度较大,从而使得电磁铁A19与电磁铁B20具有一个相对较大的电动势范围,从而能更加精确地控制三通开度阀11的状态,增加中和的精度。This device, by utilizing the alternating magnetic field generated when the iron core 29 is magnetically conductive, can use the magnetic attraction force to change the position of the magnetic attraction block 33, so that the matching position of the spring contact 30 and the coil B26 changes according to the magnitude of the magnetic force, so that when the electromotive force of the coil A25 changes, the induced electromotive force of the coil B26 also changes, and the change amplitude is large, so that the electromagnet A19 and the electromagnet B20 have a relatively large electromotive force range, so that the state of the three-way opening valve 11 can be controlled more accurately, and the accuracy of neutralization is increased.
为了解决过滤问题;如图1、7-12所示,所述精滤机构8包括固定于处理管5内壁的滤板34以及通过驱动轴39转动连接于滤板34的刮板35,且所述刮板35贴合于滤板34的过滤面,所述驱动轴39的端部设置有驱动组件38,且所述处理管5位于滤板34上游的底部外壁开设有漏槽36,漏槽36的底部外壁通过螺栓固定有集污盒37。In order to solve the filtering problem; as shown in Figures 1, 7-12, the fine filtration mechanism 8 includes a filter plate 34 fixed to the inner wall of the processing tube 5 and a scraper 35 rotatably connected to the filter plate 34 through a drive shaft 39, and the scraper 35 is attached to the filtering surface of the filter plate 34, a drive assembly 38 is provided at the end of the drive shaft 39, and a leakage groove 36 is opened on the bottom outer wall of the processing tube 5 located upstream of the filter plate 34, and a dirt collecting box 37 is fixed to the bottom outer wall of the leakage groove 36 by bolts.
当污水流经滤板34时,其内污物会被滤板34截留,并且随着污水的流动,驱动组件38会驱使驱动轴39旋转,从而将滤板34表面的污物刮下落入集污盒37内收集。When sewage flows through the filter plate 34 , dirt therein will be intercepted by the filter plate 34 , and as the sewage flows, the drive assembly 38 will drive the drive shaft 39 to rotate, thereby scraping the dirt on the surface of the filter plate 34 and dropping it into the dirt collecting box 37 for collection.
所述刮板35包括固定于驱动轴39端部的连接板40以及多组通过连接轴41转动连接于连接板40的转辊42,一组内的两个所述转辊42的外壁配合有连接带44。The scraper 35 includes a connecting plate 40 fixed to the end of the driving shaft 39 and a plurality of groups of rollers 42 rotatably connected to the connecting plate 40 via connecting shafts 41 , and outer walls of two of the rollers 42 in one group are equipped with connecting belts 44 .
所述连接带44的外壁固定有均匀的输送板45,滤板34的侧壁固定有固定圈43,转辊42与连接轴41通过同步带47传动配合。A uniform conveying plate 45 is fixed to the outer wall of the connecting belt 44 , a fixing ring 43 is fixed to the side wall of the filter plate 34 , and the rotating roller 42 and the connecting shaft 41 are matched through a synchronous belt 47 .
当驱动轴39旋转时,其能带动连接板40旋转,从而使得连接轴41与固定圈43发生旋转,从而在同步带47的连接作用下使得连接轴41自转,从而驱动转辊42自转,使得连接带44运动,从而在整个旋转过程中,利用整个刮板35将滤板34表面的污物刮除,同时输送板45将刮除的污物向外侧拨动。When the driving shaft 39 rotates, it can drive the connecting plate 40 to rotate, thereby causing the connecting shaft 41 and the fixing ring 43 to rotate, so that the connecting shaft 41 rotates under the connection of the synchronous belt 47, thereby driving the roller 42 to rotate, so that the connecting belt 44 moves, so that during the entire rotation process, the entire scraper 35 is used to scrape off the dirt on the surface of the filter plate 34, and the conveying plate 45 pushes the scraped dirt to the outside.
本装置,通过设置刮板35,其能对滤板34表面的污物进行清除,从而防止堵塞,并且在此基础上,通过设置连接轴41、固定圈43、同步带47的组合以及转辊42、连接带44、输送板45的组合,在清除的同时能利用连接板40的旋转使得输送板45运动,从而可将污物向外侧拨动,能更好的使得污物进入集污盒37内收集。The device, by providing a scraper 35, can remove dirt on the surface of the filter plate 34 to prevent clogging, and on this basis, by providing a combination of a connecting shaft 41, a fixing ring 43, a synchronous belt 47 and a combination of a roller 42, a connecting belt 44, and a conveying plate 45, the conveying plate 45 can be moved by the rotation of the connecting plate 40 while cleaning, so that the dirt can be pushed outward, and the dirt can be better collected in the dirt collecting box 37.
本实施例在使用时,污水经过沉淀池1、初滤吸附池2、反应池3处理,处理后进入处理管5的上游位置,然后被精滤机构8过滤,过滤后,滤液经过参比电极23和氢离子选择性电极24,参比电极23和对滤液中的氢离子进行感知,从而参比电极23与氢离子选择性电极24之间形成电动势,电动势经过逆变器转化为交流电后施加于线圈A25,从而在铁芯29内产生交变磁通量,线圈B26内会产生感应电动势,从而将感应电动势施加于电磁铁A19与电磁铁B20内,当水呈碱性时,氢离子浓度较低,此时阀芯16受到弹簧一15的弹力作用使得透孔17连通于酸液箱9,当污水中的氢离子的浓度逐渐升高,碱性降低时,此时电磁铁A19与电磁铁B20内的感应电动势增加,其磁斥力增加,从而使得阀芯16移动,使得连通于酸液箱9的透孔17与“Y”型流道21错开,重叠面积减少,从而对酸液节流,降低流速,直至溶液达到中性时,两个透孔17与“Y”型流道21均不连通,随后当氢离子浓度逐渐上升时,电磁铁A19与电磁铁B20的感应电动势继续增加,阀芯16继续移动,使得透孔17与碱液箱10连通,从而使得碱液箱10流入处理管5内进行中和,并且氢离子浓度继续上升,酸性增加时,透孔17与“Y”型流道21的重叠面积增加,从而使得碱液的流道面积增加;When the present embodiment is in use, the sewage is treated by the sedimentation tank 1, the primary filtration adsorption tank 2, and the reaction tank 3, and then enters the upstream position of the treatment pipe 5 after treatment, and then is filtered by the fine filtration mechanism 8. After filtration, the filtrate passes through the reference electrode 23 and the hydrogen ion selective electrode 24, and the reference electrode 23 senses the hydrogen ions in the filtrate, so that an electromotive force is formed between the reference electrode 23 and the hydrogen ion selective electrode 24, and the electromotive force is converted into alternating current by the inverter and applied to the coil A25, thereby generating an alternating magnetic flux in the iron core 29, and an induced electromotive force is generated in the coil B26, so that the induced electromotive force is applied to the electromagnet A19 and the electromagnet B20. When the water is alkaline, the hydrogen ion concentration is low. At this time, the valve core 16 is subjected to the elastic force of the spring 15 so that the through hole 17 is connected to the acid tank 9. When the hydrogen ions in the sewage When the concentration gradually increases and the alkalinity decreases, the induced electromotive force in the electromagnet A19 and the electromagnet B20 increases, and the magnetic repulsion increases, so that the valve core 16 moves, so that the through hole 17 connected to the acid tank 9 is staggered with the "Y"-shaped flow channel 21, and the overlapping area is reduced, thereby throttling the acid solution and reducing the flow rate, until the solution reaches neutrality, the two through holes 17 and the "Y"-shaped flow channel 21 are not connected, and then when the hydrogen ion concentration gradually increases, the induced electromotive force of the electromagnet A19 and the electromagnet B20 continues to increase, and the valve core 16 continues to move, so that the through hole 17 is connected with the alkali liquid tank 10, so that the alkali liquid tank 10 flows into the treatment tube 5 for neutralization, and the hydrogen ion concentration continues to rise. When the acidity increases, the overlapping area of the through hole 17 and the "Y"-shaped flow channel 21 increases, so that the flow channel area of the alkali solution increases;
由于铁芯29内会产生交变磁场,交变磁场会对磁吸块33施加一个等效磁场,且等效磁场的场强与交变磁场的场强相关,等效磁场会施加于磁吸块33,从而使得磁吸块33克服绝缘弹簧31的弹力移动,从而使得弹簧触头30与线圈B26的配合位置改变,从而使得线圈B26接入电路的匝数改变,从而能将参比电极23与氢离子选择性电极24之间电动势的改变放大后再施加于电磁铁A19与电磁铁B20;Since an alternating magnetic field is generated in the iron core 29, the alternating magnetic field will apply an equivalent magnetic field to the magnetic attraction block 33, and the field strength of the equivalent magnetic field is related to the field strength of the alternating magnetic field. The equivalent magnetic field will be applied to the magnetic attraction block 33, so that the magnetic attraction block 33 overcomes the elastic force of the insulating spring 31 and moves, thereby changing the matching position of the spring contact 30 and the coil B26, thereby changing the number of turns of the coil B26 connected to the circuit, so that the change in the electromotive force between the reference electrode 23 and the hydrogen ion selective electrode 24 can be amplified and then applied to the electromagnet A19 and the electromagnet B20;
当污水流经滤板34时,其内污物会被滤板34截留,并且随着污水的流动,驱动组件38会驱使驱动轴39旋转,从而将滤板34表面的污物刮下落入集污盒37内收集,当驱动轴39旋转时,其能带动连接板40旋转,从而使得连接轴41与固定圈43发生旋转,从而在同步带47的连接作用下使得连接轴41自转,从而驱动转辊42自转,使得连接带44运动,从而在整个旋转过程中,利用整个刮板35将滤板34表面的污物刮除,同时输送板45将刮除的污物向外侧拨动。When sewage flows through the filter plate 34, the dirt inside it will be intercepted by the filter plate 34, and as the sewage flows, the driving assembly 38 will drive the driving shaft 39 to rotate, thereby scraping the dirt on the surface of the filter plate 34 and dropping it into the dirt collecting box 37 for collection. When the driving shaft 39 rotates, it can drive the connecting plate 40 to rotate, thereby causing the connecting shaft 41 and the fixing ring 43 to rotate, so that the connecting shaft 41 rotates under the connection action of the synchronous belt 47, thereby driving the roller 42 to rotate, so that the connecting belt 44 moves, so that during the entire rotation process, the entire scraper 35 is used to scrape off the dirt on the surface of the filter plate 34, and at the same time, the conveying plate 45 pushes the scraped dirt to the outside.
实施例2:Embodiment 2:
一种污水处理设备,如图10-12所示,为了解决驱动问题;本实施例在实施例1的基础上作出以下改进:所述驱动组件38包括滑动配合于驱动轴39外壁的滑环48以及多个通过转盘50转动连接于滑环48外壁的涡轮叶片49。A sewage treatment equipment, as shown in Figures 10-12, in order to solve the driving problem; this embodiment makes the following improvements on the basis of Example 1: the driving assembly 38 includes a slip ring 48 that slides on the outer wall of the driving shaft 39 and a plurality of turbine blades 49 that are rotatably connected to the outer wall of the slip ring 48 through a turntable 50.
所述驱动轴39一侧设置有弹性体51,且滑环48通过弹性体51与驱动轴39的端部相连接。An elastic body 51 is disposed on one side of the driving shaft 39 , and the slip ring 48 is connected to the end of the driving shaft 39 through the elastic body 51 .
所述驱动轴39的外侧开设有限位槽46,转盘50通过其内壁焊接的两个转辊42活动限位配合于限位槽46的内壁。A limiting groove 46 is provided on the outer side of the driving shaft 39 , and the rotating disk 50 is movably limited and matched with the inner wall of the limiting groove 46 through two rotating rollers 42 welded to the inner wall of the rotating disk 50 .
且所述限位槽46为弧线和直线的组合型结构。Furthermore, the limiting groove 46 is a combination structure of an arc and a straight line.
本实施例在使用时,当污水流速相对较小时,涡轮叶片49受到水流作用力也较小,此时滑环48受到弹性体51的弹力作用滑移,从而利用限位柱52与涡轮叶片49的配合使得涡轮叶片49旋转,且涡轮叶片49的旋转方向为沿水流方向投影面积增加的趋势旋转,此时涡轮叶片49会受到水流的作用力增加,反之亦然。When this embodiment is in use, when the sewage flow rate is relatively small, the force exerted by the water flow on the turbine blades 49 is also small. At this time, the slip ring 48 slides due to the elastic force of the elastomer 51, so that the turbine blades 49 rotate by utilizing the cooperation between the limit column 52 and the turbine blades 49, and the rotation direction of the turbine blades 49 is along the water flow direction. The projected area tends to increase. At this time, the turbine blades 49 will be subjected to an increased force from the water flow, and vice versa.
本装置,通过设置涡轮叶片49对驱动轴39驱动,从而利用水流作用力即可驱使驱动轴39旋转,并且通过设置限位槽46与限位柱52以及弹性体51的配合,从而能使得涡轮叶片49的“偏转”角度与水流速度相关,能实现负反馈调节,从而能使得涡轮叶片49对驱动轴39的驱动转速相对“适中”,保证污物去除的可靠性。The present device drives the drive shaft 39 by setting a turbine blade 49, so that the drive shaft 39 can be driven to rotate by utilizing the force of water flow, and by setting the cooperation of the limit groove 46, the limit column 52 and the elastic body 51, the "deflection" angle of the turbine blade 49 can be related to the water flow speed, and negative feedback regulation can be achieved, so that the driving speed of the drive shaft 39 by the turbine blade 49 can be relatively "moderate", thereby ensuring the reliability of dirt removal.
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above description is only a preferred specific implementation manner of the present invention, but the protection scope of the present invention is not limited thereto. Any technician familiar with the technical field can make equivalent replacements or changes according to the technical scheme and inventive concept of the present invention within the technical scope disclosed by the present invention, which should be covered by the protection scope of the present invention.
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CN119306356A (en) * | 2024-12-02 | 2025-01-14 | 广东江铜桃林生态环境有限公司 | A treatment process for acid mine wastewater and its combined reactor |
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