CN118556342A - Bus bar with improved flame retardancy and battery pack including the same - Google Patents
Bus bar with improved flame retardancy and battery pack including the same Download PDFInfo
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Abstract
Description
技术领域Technical Field
本申请要求于2022年9月8日提交的韩国专利申请No.2022-0114234和于2023年9月7日提交的韩国专利申请No.2023-0118950的优先权权益,这两个韩国专利申请的公开的全部内容以引用方式并入本文中。This application claims the benefit of priority to Korean Patent Application No. 2022-0114234 filed on September 8, 2022 and Korean Patent Application No. 2023-0118950 filed on September 7, 2023, the disclosures of which are incorporated herein by reference in their entirety.
本发明涉及具有改进的阻燃性的汇流条(所述汇流条将电池模块彼此连接),并且更具体地,涉及被配置为向由导电金属材料制成的金属板添加多个绝缘构件以便保护金属板免受外部影响从而改进阻燃性的汇流条和包括该汇流条的电池组。The present invention relates to a bus bar with improved flame retardancy, which connects battery modules to each other, and more particularly, to a bus bar configured to add a plurality of insulating members to a metal plate made of a conductive metal material so as to protect the metal plate from external influences, thereby improving flame retardancy, and a battery pack including the bus bar.
背景技术Background Art
随着由于因使用化石燃料造成的空气污染和能源耗竭,最近发展替代能量,对能够储存产生的电能的二次电池的需求已增加。能够被充电和放电的二次电池在日常生活中被密切使用。例如,二次电池用于移动装置、电动车辆和混合动力电动车辆。With the recent development of alternative energy due to air pollution and energy depletion caused by the use of fossil fuels, the demand for secondary batteries that can store the generated electrical energy has increased. Secondary batteries that can be charged and discharged are closely used in daily life. For example, secondary batteries are used in mobile devices, electric vehicles and hybrid electric vehicles.
由于移动装置使用的增加、移动装置复杂性的增加和电动车辆的发展,用作现代社会中不可避免地使用的各种电子装置的能量源的锂二次电池所需容量已增加。为了满足用户的需求,在小型装置中设置多个电池电芯,而在车辆等中使用包括彼此电连接的多个电池电芯的电池模块或包括多个电池模块的电池组。Due to the increase in the use of mobile devices, the increase in the complexity of mobile devices, and the development of electric vehicles, the required capacity of lithium secondary batteries used as energy sources for various electronic devices inevitably used in modern society has increased. In order to meet the needs of users, a plurality of battery cells are provided in small devices, and a battery module including a plurality of battery cells electrically connected to each other or a battery pack including a plurality of battery modules is used in vehicles, etc.
随着如上所述使用锂二次电池作为能量源的装置种类的扩展,锂二次电池在需要高容量和高输出的装置中的应用也得以扩展。As the types of devices using lithium secondary batteries as energy sources expand as described above, the application of lithium secondary batteries to devices requiring high capacity and high output is also expanding.
与这一趋势相符,多个电池电芯彼此电连接的电池模块以及电池模块彼此串联和/或并联连接的电池组的制造和使用已增加。In line with this trend, manufacture and use of battery modules in which a plurality of battery cells are electrically connected to one another and battery packs in which battery modules are connected to one another in series and/or in parallel have increased.
此外,汇流条被广泛用作电池模块之间的电连接装置,并且可用作大电流传导装置,因为汇流条即使与电缆相比厚度相对小,也能够允许大电流稳定地流过其中。Furthermore, the bus bar is widely used as an electrical connection means between battery modules, and can be used as a large current conducting means because the bus bar can allow a large current to stably flow therethrough even though the bus bar has a relatively small thickness compared to a cable.
通常,汇流条可以以诸如铜或铝这样的金属棒形式设置,金属棒表现出优异的导电性,并且为安全起见,金属棒的不包括连接到端子的相反端部的其余部分被管或注射成型的产品覆盖。Generally, the bus bar may be provided in the form of a metal bar such as copper or aluminum, which exhibits excellent conductivity, and the remaining portion of the metal bar excluding the opposite end connected to the terminal is covered by a tube or an injection-molded product for safety.
具体地,汇流条可以按以下的形式使用:包括表现出优异导电性的铜或铝的金属板设置在内部,并且金属板外表面的不包括用于联接的相反端部的其余部分被管或注射成型的产品覆盖,以便确保电绝缘。Specifically, the bus bar may be used in the form that a metal plate including copper or aluminum exhibiting excellent conductivity is provided inside, and the rest of the outer surface of the metal plate excluding opposite ends for coupling is covered with a tube or an injection molded product to ensure electrical insulation.
与此相关,图1是示出因火灾而损坏之前和之后的常规汇流条的立体图。In connection with this, FIG. 1 is a perspective view showing a conventional bus bar before and after being damaged by fire.
使用汇流条是为了实现电池模块之间的电连接,并且图1示出了汇流条的结构和汇流条因火灾而损坏的状态。The bus bar is used to achieve electrical connection between battery modules, and FIG. 1 shows the structure of the bus bar and a state in which the bus bar is damaged due to fire.
参照图1,常规汇流条包括由导电材料制成的金属板110、被配置为包围金属板110外表面的不包括其相反端部的其余部分的绝缘带120以及添加到绝缘带120外表面的硅树脂管130。1 , the conventional bus bar includes a metal plate 110 made of a conductive material, an insulating tape 120 configured to surround the remaining portion of the outer surface of the metal plate 110 excluding opposite ends thereof, and a silicone tube 130 added to the outer surface of the insulating tape 120 .
绝缘带120和硅树脂管130中的每一个都由电绝缘材料制成,由此可以确保除了联接到汇流条的相反端部的装置以外的构造的绝缘。Each of the insulating tape 120 and the silicone tube 130 is made of an electrically insulating material, whereby insulation of a configuration other than a device coupled to the opposite ends of the bus bar can be ensured.
当电池组中的电池电芯着火或爆炸时,电池电芯的热能可以被传递到与其相邻的电池电芯,由此引发火灾。当连接电池模块的汇流条的硅树脂管130因电池电芯中的火灾而损坏时,绝缘带120可能断开,由此绝缘带中的金属板110可能被暴露。When a battery cell in a battery pack catches fire or explodes, the heat energy of the battery cell may be transferred to the battery cell adjacent thereto, thereby causing a fire. When the silicone tube 130 connecting the bus bars of the battery module is damaged by a fire in the battery cell, the insulating tape 120 may be disconnected, whereby the metal plate 110 in the insulating tape may be exposed.
当这样暴露的金属板与导电电池组结构接触时,可能发生短路,并且这种内部短路可以在电池组中形成电闭合电路,从而可能加速电池组中的热失控。When such exposed metal plates come into contact with conductive battery structures, a short circuit may occur, and such internal short circuit may form an electrically closed circuit in the battery pack, thereby potentially accelerating thermal runaway in the battery pack.
与此相关,专利文献1公开了一种汇流条,该汇流条包括由金属材料制成的金属棒、被配置为覆盖金属棒的不包括其相反端部的其余部分的绝缘管、被配置为将金属棒封入到绝缘管中的防火带以及由耐火材料制成的绷带构件,绷带构件介于绝缘管和防火带之间,绷带构件被配置为包围防火带以被固定到金属棒。In connection with this, patent document 1 discloses a bus bar comprising a metal rod made of a metal material, an insulating tube configured to cover the remaining portion of the metal rod excluding its opposite end portions, a fireproof belt configured to seal the metal rod into the insulating tube, and a bandage member made of a fire-resistant material, the bandage member being interposed between the insulating tube and the fireproof belt, the bandage member being configured to surround the fireproof belt to be fixed to the metal rod.
在专利文献1中,即使绝缘管因火灾而被烧掉,绷带构件也可以强力地固定防火带,由此可以防止金属棒与周围金属物体之间直接接触,因此可以防止短路。In Patent Document 1, even if the insulating tube is burned due to fire, the bandage member can strongly fix the fireproof tape, thereby preventing direct contact between the metal rod and surrounding metal objects, thereby preventing a short circuit.
专利文献2公开了一种汇流条,该汇流条包括由金属材料制成的金属棒、被配置为包围金属棒的不包括其相反端部的其余部分的绷带构件以及被配置为包围金属棒和绷带构件二者的绝缘管。Patent Document 2 discloses a bus bar including a metal rod made of a metal material, a bandage member configured to surround the remaining portion of the metal rod excluding opposite ends thereof, and an insulating tube configured to surround both the metal rod and the bandage member.
在专利文献2中,即使在有火灾的情况下,设置在金属棒表面上的绷带构件也保持附接到金属棒的表面,由此金属棒不直接接触周围的金属物体,因此可以防止短路。In Patent Document 2, even in the event of a fire, the bandage member provided on the surface of the metal bar remains attached to the surface of the metal bar, whereby the metal bar does not directly contact surrounding metal objects, and thus a short circuit can be prevented.
然而,由于专利文献1的汇流条和专利文献2的汇流条中的每一个还包括绷带构件,因此汇流条的厚度和重量会增加。However, since each of the bus bar of Patent Document 1 and the bus bar of Patent Document 2 further includes a bandage member, the thickness and weight of the bus bar increase.
当在电池组中发生火灾时,包围金属棒的管或注射成型的产品可能烧毁,由此金属棒可能暴露于外部。当暴露于外部的金属棒与周围的金属物体接触时,可能发生短路。When a fire occurs in a battery pack, the tube or injection molded product surrounding the metal rod may burn, whereby the metal rod may be exposed to the outside. When the metal rod exposed to the outside comes into contact with surrounding metal objects, a short circuit may occur.
另外,仅使用具有耐火的耐热绝缘体的汇流条无法积极应对火焰。In addition, using only bus bars with fire-resistant heat-resistant insulators cannot actively deal with flames.
因此,需要一种汇流条,该汇流条在火灾的情况下能够防止火焰在电池模块之间蔓延,同时即使添加到汇流条外表面的绝缘材料因火灾而烧毁,也防止设置在其中的金属棒或金属板暴露。Therefore, there is a need for a bus bar that can prevent flames from spreading between battery modules in the event of a fire while preventing metal bars or metal plates provided therein from being exposed even if an insulating material added to an outer surface of the bus bar is burned due to the fire.
(现有技术文献)(Prior art literature)
(专利文献1)韩国专利申请公开No.2021-0050983(2021年5月10日)(Patent Document 1) Korean Patent Application Publication No. 2021-0050983 (May 10, 2021)
(专利文献2)韩国专利申请公开No.2021-0141095(2021年11月23日)(Patent Document 2) Korean Patent Application Publication No. 2021-0141095 (November 23, 2021)
发明内容Summary of the invention
技术问题Technical issues
本发明是鉴于以上问题而做出的,并且本发明的目的是提供一种汇流条和包括该汇流条的电池组,所述汇流条被配置为使得多个绝缘构件被添加到由导电金属材料制成的金属板的外表面以便保护金属板免受外部影响,由此改进阻燃性。The present invention is made in view of the above problems, and an object of the present invention is to provide a bus bar and a battery pack including the bus bar, wherein the bus bar is configured such that a plurality of insulating members are added to the outer surface of a metal plate made of a conductive metal material so as to protect the metal plate from external influences, thereby improving flame retardancy.
技术方案Technical Solution
根据本发明的一种汇流条,该汇流条包括:金属板;以及多个绝缘构件,所述多个绝缘构件被添加到所述金属板的外表面,其中,所述多个绝缘构件中的至少一些与所述金属板形成化学键(chemical bond)。A bus bar according to the present invention includes: a metal plate; and a plurality of insulating members added to an outer surface of the metal plate, wherein at least some of the plurality of insulating members form a chemical bond with the metal plate.
所述多个绝缘构件可以包括添加到所述金属板的第一绝缘构件和添加到所述第一绝缘构件以包围所述第一绝缘构件的外表面的第二绝缘构件,其中,所述第一绝缘构件可以由无机材料制成。The plurality of insulating members may include a first insulating member added to the metal plate and a second insulating member added to the first insulating member to surround an outer surface of the first insulating member, wherein the first insulating member may be made of an inorganic material.
所述无机材料可以是无机金属氧化物。The inorganic material may be an inorganic metal oxide.
所述无机金属氧化物可以是从由氧化铝Al2O3、氮化铝AlN、二氧化锆ZrO2、二氧化钛TiO2、碳酸钙CaCO3、二氧化硅SiO2、氧化锌ZnO和二氧化铈CeO2组成的组中选择的至少一种。The inorganic metal oxide may be at least one selected from the group consisting of aluminum oxide Al2O3 , aluminum nitride AlN, zirconium dioxide ZrO2 , titanium dioxide TiO2 , calcium carbonate CaCO3 , silicon dioxide SiO2 , zinc oxide ZnO, and cerium dioxide CeO2 .
所述第一绝缘构件可以被配置为纳米无机氧化物分散体(nano-inorganic oxidedispersion)的形式。The first insulating member may be configured in the form of a nano-inorganic oxide dispersion.
所述第二绝缘构件可以在高温下被陶瓷化。The second insulating member may be ceramicized at a high temperature.
所述第二绝缘构件可以由从硼类阻燃涂层剂、磷类阻燃涂层剂和硅类阻燃涂层剂组成的组中选择的至少一种制成。The second insulating member may be made of at least one selected from the group consisting of a boron-based flame retardant coating agent, a phosphorus-based flame retardant coating agent, and a silicon-based flame retardant coating agent.
所述第二绝缘构件包括从由氢氧化镁MDH、磷酸一铵MAP和氢氧化铝ATH组成的组中选择的至少一种。The second insulating member includes at least one selected from the group consisting of magnesium hydroxide MDH, monoammonium phosphate MAP, and aluminum hydroxide ATH.
所述第二绝缘构件可以包括从由耐火硅酮、耐火塑料、聚苯硫醚、聚醚醚酮、聚邻苯二甲酰胺(polyphthalamide)、聚酰胺、聚砜、聚醚砜、聚醚酰亚胺、丙烯酸纤维和聚苯并咪唑组成的组中选择的至少一种。The second insulating member may include at least one selected from the group consisting of fire-resistant silicone, fire-resistant plastic, polyphenylene sulfide, polyetheretherketone, polyphthalamide, polyamide, polysulfone, polyethersulfone, polyetherimide, acrylic fiber, and polybenzimidazole.
所述金属板可以由包括铜、铝、镍、金、银或其组合的导电材料制成。The metal plate may be made of a conductive material including copper, aluminum, nickel, gold, silver, or a combination thereof.
所述多个绝缘构件中的每一个绝缘构件可以被配置为可附接胶带的形式或能被涂覆的泡沫的形式,或者通过施加其中分散有绝缘材料的浆料、通过添加热收缩管、通过嵌件成型、或通过在各自具有铰链结构或紧固结构的上壳体和下壳体之间进行联接来形成。Each of the multiple insulating members can be configured in the form of an attachable tape or a coatable foam, or can be formed by applying a slurry in which an insulating material is dispersed, by adding a heat shrink tube, by insert molding, or by connecting an upper shell and a lower shell each having a hinge structure or a fastening structure.
另外,本发明提供了一种电池组,该电池组包括经由汇流条彼此电连接的多个电池模块。In addition, the present invention provides a battery pack including a plurality of battery modules electrically connected to each other via a bus bar.
在所述电池组中,所述多个电池模块可以被容纳在电池组外壳中,在所述电池组外壳中安装栅格状的分隔壁,一个电池模块可以位于一个栅格空间中,并且所述汇流条可以被设置为横跨(traverse)所述分隔壁的上部,以便将所述多个电池模块彼此电连接。In the battery pack, the plurality of battery modules may be accommodated in a battery pack housing, a grid-like partition wall may be installed in the battery pack housing, one battery module may be located in one grid space, and the bus bar may be arranged to traverse the upper portion of the partition wall so as to electrically connect the plurality of battery modules to each other.
另外,本发明可以提供以上解决手段的各种组合。In addition, the present invention can provide various combinations of the above-mentioned solving means.
有益效果Beneficial Effects
从以上的描述中清楚的是,根据本发明,即使在有火灾的情况下汇流条与其周围的导电物体接触时,也可以确保汇流条的绝缘。As is apparent from the above description, according to the present invention, even when the bus bar comes into contact with conductive objects around it in the event of a fire, insulation of the bus bar can be ensured.
另外,由氧化铝制成的第一绝缘构件在高温下与由Cu制成的金属板形成化学键,由此第一绝缘构件牢固地结合到金属板,因此可以物理地保护汇流条。In addition, the first insulating member made of alumina forms a chemical bond with the metal plate made of Cu at a high temperature, whereby the first insulating member is firmly bonded to the metal plate, and thus the bus bar can be physically protected.
另外,第二绝缘构件的部分在膨胀的同时被陶瓷化,由此可以保持绝缘和气密性能。In addition, part of the second insulating member is ceramicized while expanding, whereby insulating and airtight properties can be maintained.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是示出常规汇流条因火灾而损坏之前和之后的立体图。FIG. 1 is a perspective view showing a conventional bus bar before and after being damaged by fire.
图2是根据本发明的汇流条的平面图和垂直截面图。FIG. 2 is a plan view and a vertical cross-sectional view of a bus bar according to the present invention.
图3是示出根据本发明的汇流条因火灾而损坏之前和之后的垂直截面图。FIG. 3 is a vertical cross-sectional view showing a bus bar according to the present invention before and after being damaged by fire.
图4是示出被配置为将两个电池模块彼此连接的汇流条被设置成延伸穿过分隔壁的状态的立体图和垂直截面图。4 is a perspective view and a vertical sectional view illustrating a state in which a bus bar configured to connect two battery modules to each other is provided to extend through a partition wall.
图5是电池组的立体图,在该电池组中,多个电池模块被容纳在由分隔壁分隔的电池组外壳中。FIG. 5 is a perspective view of a battery pack in which a plurality of battery modules are accommodated in a battery pack case partitioned by partition walls.
具体实施方式DETAILED DESCRIPTION
现在,将参考附图来详细描述本发明的优选实施方式,使得本发明所属领域的普通技术人员可以容易地实现本发明的优选实施方式。然而,在详细描述本发明的优选实施方式的操作原理时,当对并入本文中的已知功能和配置的详细描述会使本发明的主题不清楚时,将省略该详细描述。Now, the preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those skilled in the art can easily implement the preferred embodiments of the present invention. However, when describing the operating principle of the preferred embodiments of the present invention in detail, when the detailed description of the known functions and configurations incorporated herein will make the subject matter of the present invention unclear, the detailed description will be omitted.
另外,将在附图中始终使用相同的附图标记来表示执行类似功能或操作的部件。在整个说明书中一个部件连接到另一部件的情况下,不仅这个部件可以直接连接到另一部件,而且这个部件可以经由其它部件而间接连接到另一部件。另外,除非另有说明,否则包括特定元件并不意味着排除其它元件,而是意味着还可以包括这样的元件。In addition, the same reference numerals will be used throughout the drawings to represent components that perform similar functions or operations. Where a component is connected to another component throughout the specification, not only may the component be directly connected to the other component, but the component may also be indirectly connected to the other component via other components. In addition, unless otherwise specified, the inclusion of a particular element does not mean the exclusion of other elements, but rather means that such elements may also be included.
另外,除非特别限制,否则通过限制或添加来实施元件的描述可以应用到所有发明,并没有不特别限制发明。In addition, unless otherwise specifically limited, the description of implementing elements by limitation or addition can be applied to all the inventions, and does not specifically limit the invention.
另外,在本发明的描述和本申请的权利要求中,除非另外提到,否则单数形式旨在包括复数形式。In addition, in the description of the present invention and the claims of this application, unless otherwise mentioned, the singular form is intended to include the plural form.
另外,在本发明的描述和本申请的权利要求中,除非另外提到,否则“或”包括“和”。因此,“包括A或B”意指三种情况,即,包括A的情况、包括B的情况和包括A和B的情况。In addition, in the description of the present invention and the claims of the present application, unless otherwise mentioned, "or" includes "and." Therefore, "including A or B" means three cases, namely, the case including A, the case including B, and the case including A and B.
下文中,将参考附图来详细地描述本发明的实施方式。Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
根据本发明的汇流条是一种用作电连接装置的汇流条,本说明书中使用的模块间汇流条是指用作被配置为将设置在电池组中的电池模块互连的装置的汇流条,并且术语“汇流条”可以被理解为包括术语“模块间汇流条”。The busbar according to the present invention is a busbar used as an electrical connection device, and the inter-module busbar used in this specification refers to a busbar used as a device configured to interconnect battery modules arranged in a battery pack, and the term "busbar" can be understood to include the term "inter-module busbar".
在一个具体示例中,汇流条的长度可以考虑将要连接的电池模块之间的距离来设置,并且汇流条的宽度和厚度可以考虑流过汇流条的电流量和汇流条的电阻来设置。In a specific example, the length of the bus bar may be set in consideration of the distance between battery modules to be connected, and the width and thickness of the bus bar may be set in consideration of the amount of current flowing through the bus bar and the resistance of the bus bar.
另外,汇流条的形状可以考虑电池模块的连接器的位置来配置,并且汇流条可以被形成为具有各种形状中的任一种,诸如,汇流条向上或向下弯曲以平行于其总宽度的形状、汇流条在平面内弯曲90度的L形、或汇流条在平面内在其相反端部弯曲90度的[形或└┓形。In addition, the shape of the bus bar can be configured considering the position of the connector of the battery module, and the bus bar can be formed to have any of a variety of shapes, such as a shape in which the bus bar is bent upward or downward to be parallel to its total width, an L-shape in which the bus bar is bent 90 degrees in a plane, or a [-shape or └┓-shape in which the bus bar is bent 90 degrees at its opposite ends in a plane.
由于汇流条的相反端部中的每一端经常被用作联接到外部装置的连接部分,因此设置了用于连接的结构,诸如用于螺栓紧固的紧固孔。Since each of the opposite end portions of the bus bar is often used as a connection portion coupled to an external device, a structure for connection such as a fastening hole for bolt fastening is provided.
图2是根据本发明的汇流条的平面图和垂直截面图,其中,在图2的上部沿着平面图中的A-A截取的截面被示出为在图2的下部的垂直截面图。2 is a plan view and a vertical sectional view of a bus bar according to the present invention, wherein a section taken along A-A in the plan view in the upper portion of FIG. 2 is shown as a vertical sectional view in the lower portion of FIG. 2 .
参照图2,汇流条200包括用于电连接的金属板210和添加到金属板210的外表面的多个绝缘构件。2 , the bus bar 200 includes a metal plate 210 for electrical connection and a plurality of insulating members added to an outer surface of the metal plate 210 .
多个绝缘构件包括:第一绝缘构件220,其被配置为包围金属板210的至少部分,第一绝缘构件在诸如火焰产生这样的高温环境下与构成金属板210的金属形成化学键;以及第二绝缘构件230,其被添加到第一绝缘构件220以包围其外表面,第二绝缘构件被配置为在高温下被陶瓷化。The plurality of insulating members include: a first insulating member 220 configured to surround at least a portion of the metal plate 210, the first insulating member forming a chemical bond with a metal constituting the metal plate 210 in a high temperature environment such as flame generation; and a second insulating member 230 added to the first insulating member 220 to surround an outer surface thereof, the second insulating member being configured to be ceramicized at a high temperature.
汇流条可以包括形成在其相反端部中的每一个端部处的连接结构以便连接电池模块,并且汇流条可以被配置为具有以下的结构:设置形成为由导电金属材料制成的金属棒形状的金属板,并且向金属板的不包括相反端部的部分添加多个绝缘构件,其中,多个绝缘构件被设置为具有多个分层结构。The bus bar may include a connecting structure formed at each of its opposite ends so as to connect the battery modules, and the bus bar may be configured to have the following structure: a metal plate formed in the shape of a metal rod made of a conductive metal material is provided, and a plurality of insulating members are added to a portion of the metal plate excluding the opposite ends, wherein the plurality of insulating members are provided to have a plurality of layered structures.
构成金属板的金属可以是铜、铝、镍、金、银或其组合,并且多个绝缘构件中的每一个可以由塑料、无机氧化物和非导电金属中的至少一种制成。The metal constituting the metal plate may be copper, aluminum, nickel, gold, silver, or a combination thereof, and each of the plurality of insulating members may be made of at least one of plastic, inorganic oxide, and non-conductive metal.
第一绝缘构件220和第二绝缘构件230没有被添加到金属板210的相反端部的表面,并且金属板210的端部被暴露以构成电连接部分240。The first insulating member 220 and the second insulating member 230 are not added to the surfaces of the opposite ends of the metal plate 210 , and the ends of the metal plate 210 are exposed to constitute the electrical connection portion 240 .
在电连接部分240中的每一个中形成至少一个用于连接的开口241。At least one opening 241 for connection is formed in each of the electrical connection portions 240 .
形成在汇流条200的相反端部处的电连接部分240中的一个可以连接到第一电池模块的正极连接器,并且另一个可以连接到第二电池模块的负极连接器。具体地,当使用螺栓和螺母执行栓接操作使得汇流条连接到电池模块的连接器时,螺栓可以被插入到开口241中并且螺母可以被紧固到螺栓,由此汇流条200可以连接到第一电池模块和第二电池模块。One of the electrical connection portions 240 formed at opposite ends of the bus bar 200 may be connected to the positive connector of the first battery module, and the other may be connected to the negative connector of the second battery module. Specifically, when a bolting operation is performed using bolts and nuts so that the bus bar is connected to the connectors of the battery modules, the bolts may be inserted into the openings 241 and the nuts may be fastened to the bolts, whereby the bus bar 200 may be connected to the first battery module and the second battery module.
第一绝缘构件与金属板形成化学键的温度可以是800℃至1500℃。通常,电池组处于异常状态时的着火温度为1000℃或更高。因此,当电池组处于异常状态时,可以在构成金属板的金属(特别地,铜)和构成第一绝缘构件的材料(特别地,氧化铝(Al2O3))之间形成化学键221。The temperature at which the first insulating member forms a chemical bond with the metal plate may be 800° C. to 1500° C. Generally, the ignition temperature of the battery pack when it is in an abnormal state is 1000° C. or higher. Therefore, when the battery pack is in an abnormal state, a chemical bond 221 may be formed between the metal constituting the metal plate (particularly, copper) and the material constituting the first insulating member (particularly, aluminum oxide (Al 2 O 3 )).
通过作为金属板材料的Cu与作为第一绝缘构件材料的氧化铝之间的化学反应形成的材料可以包括CuAlO2和CuAl2O中的至少一者。The material formed by a chemical reaction between Cu as the material of the metal plate and aluminum oxide as the material of the first insulating member may include at least one of CuAlO 2 and CuAl 2 O.
即,可以发生Cu与Al2O3之间的化学键合以形成CuAlO2和/或CuAl2O,其中,通过在金属板与第一绝缘构件之间的界面处形成的材料,在金属板与第一绝缘构件之间形成类似于焊接的强结合。另外,由于CuAlO2和/或CuAl2O,可以物理地保护金属板免受周围部件的影响,由此可以消除诸如短路这样的另外的异常现象的发生。That is, chemical bonding between Cu and Al2O3 can occur to form CuAlO2 and/or CuAl2O , wherein a strong bond similar to welding is formed between the metal plate and the first insulating member by the material formed at the interface between the metal plate and the first insulating member. In addition, due to CuAlO2 and/or CuAl2O , the metal plate can be physically protected from the influence of surrounding components, thereby eliminating the occurrence of other abnormal phenomena such as short circuits.
第一绝缘构件可以由无机材料制成,其中,无机材料可以是无机金属氧化物。The first insulating member may be made of an inorganic material, wherein the inorganic material may be an inorganic metal oxide.
无机金属氧化物可以包括从由氧化铝(Al2O3)、氮化铝(AlN)、二氧化锆(ZrO2)、二氧化钛(TiO2)、碳酸钙(CaCO3)、二氧化硅(SiO2)、氧化锌(ZnO)和二氧化铈(CeO2)组成的组中选择的至少一种。The inorganic metal oxide may include at least one selected from the group consisting of aluminum oxide ( Al2O3 ), aluminum nitride ( AlN ), zirconium dioxide (ZrO2), titanium dioxide ( TiO2 ), calcium carbonate ( CaCO3 ), silicon dioxide ( SiO2 ), zinc oxide (ZnO), and cerium dioxide ( CeO2 ).
第一绝缘构件可以是施加到金属板外表面的纳米无机氧化物分散体(nano-inorganic oxide dispersion)。The first insulating member may be a nano-inorganic oxide dispersion applied to the outer surface of the metal plate.
纳米无机氧化物分散体可以包括从由氯化醇酸、溴化环氧树脂、氢氧化铝、氯化石蜡和氧化锑组成的组中选择的至少一种。The nano inorganic oxide dispersion may include at least one selected from the group consisting of chlorinated alkyd, brominated epoxy, aluminum hydroxide, chlorinated paraffin, and antimony oxide.
另外,纳米无机氧化物分散体可以是从由卤素、磷、氮、矿物和氧化物组成的组中选择的至少一种添加剂的形式,或者是可膨胀纳米填料的形式。In addition, the nano inorganic oxide dispersion may be in the form of at least one additive selected from the group consisting of halogen, phosphorus, nitrogen, minerals and oxides, or in the form of an expandable nano filler.
由于第二绝缘构件230构成在有火灾的情况下火焰与其直接接触的最外侧表面,因此第二绝缘构件可以包括从由耐火硅树脂、耐火塑料、聚苯硫醚、聚醚醚酮、聚邻苯二甲酰胺、聚酰胺、聚砜、聚醚砜、聚醚酰亚胺、丙烯酸纤维和聚苯并咪唑组成的组中选择的至少一种。Since the second insulating member 230 constitutes the outermost surface with which the flame directly contacts in the event of a fire, the second insulating member may include at least one selected from the group consisting of fire-resistant silicone, fire-resistant plastic, polyphenylene sulfide, polyetheretherketone, polyphthalamide, polyamide, polysulfone, polyethersulfone, polyetherimide, acrylic fiber and polybenzimidazole.
具体地,第二绝缘构件230可以由当暴露于火焰或高温气体时被陶瓷化的耐火硅树脂制成。Specifically, the second insulation member 230 may be made of a fire-resistant silicone resin that is ceramized when exposed to flame or high-temperature gas.
耐火硅树脂在室温下表现出一般硅树脂的性能,但在高温下,耐火硅树脂的结构变为陶瓷化结构,由此耐火硅树脂具有陶瓷性能。耐火硅树脂的这种现象在本说明书中被称为陶瓷化。耐火硅树脂在高温下保持形状不变。另外,耐火硅树脂具有高阻燃性,因此火焰不会穿过耐火硅树脂。Refractory silicone resin shows the performance of general silicone resin at room temperature, but at high temperature, the structure of refractory silicone resin becomes a ceramic structure, so that refractory silicone resin has ceramic properties. This phenomenon of refractory silicone resin is referred to as ceramicization in this specification. Refractory silicone resin keeps its shape unchanged at high temperature. In addition, refractory silicone resin has high flame retardancy, so flames will not pass through refractory silicone resin.
第二绝缘构件230可以由在高温下被陶瓷化的材料制成。例如,当电池模块中的电池电芯着火和爆炸并且热量被传递到联接到电池模块的汇流条时,第二绝缘构件可以因从电池电芯释放出的气体或火焰而被陶瓷化,但第二绝缘构件的形状可以保持。The second insulating member 230 may be made of a material that is ceramicized at high temperatures. For example, when a battery cell in a battery module catches fire and explodes and heat is transferred to a bus bar coupled to the battery module, the second insulating member may be ceramicized by gas or flame released from the battery cell, but the shape of the second insulating member may be maintained.
因此,可以防止以下的常规问题:当硅树脂管被添加到金属板的外表面时,硅树脂管被烧毁,由此金属板被暴露。Therefore, it is possible to prevent a conventional problem in which, when a silicone tube is added to the outer surface of a metal plate, the silicone tube is burned and thereby the metal plate is exposed.
此外,第二绝缘构件可以包括在高温下可膨胀的可膨胀阻燃硅树脂。Furthermore, the second insulating member may include expandable flame-retardant silicone that is expandable at high temperatures.
即,当由于火灾而形成高温环境时,第二绝缘构件在从其外部开始被陶瓷化的同时膨胀。当被设置成延伸通过开口的汇流条膨胀时,开口中的间隙可以被堵塞,因此可以防止火焰或火花通过开口中的间隙蔓延。That is, when a high temperature environment is formed due to a fire, the second insulating member expands while being ceramicized from the outside thereof. When the bus bar arranged to extend through the opening expands, the gap in the opening can be blocked, thereby preventing flames or sparks from spreading through the gap in the opening.
因此,金属板没有在汇流条的添加有第一绝缘构件和第二绝缘构件的部分处暴露于外部,并且利用第一绝缘构件和第二绝缘构件的高耐热性能,可以确保汇流条的耐热性和绝缘性。Therefore, the metal plate is not exposed to the outside at the portion of the bus bar to which the first and second insulating members are added, and the heat resistance and insulation of the bus bar can be ensured by utilizing the high heat resistance of the first and second insulating members.
取决于构成第一绝缘构件或第二绝缘构件的材料的类型,可以使用以下方法中的任一种来添加第一绝缘构件或第二绝缘构件,并且添加第一绝缘构件的方法与添加第二绝缘构件的方法可以彼此不同。例如,第一绝缘构件或第二绝缘构件可以被配置为在内表面上具有粘合表面的可附接胶带的形式或可被涂覆的泡沫的形式,或者可以通过施加其中分散有绝缘材料的浆料、通过添加热收缩管、通过嵌件成型、或通过在各自具有铰链结构或紧固结构的上壳体和下壳体之间进行联接来形成。Depending on the type of material constituting the first insulating member or the second insulating member, any of the following methods may be used to add the first insulating member or the second insulating member, and the method of adding the first insulating member and the method of adding the second insulating member may be different from each other. For example, the first insulating member or the second insulating member may be configured in the form of an attachable tape having an adhesive surface on the inner surface or in the form of a foam that can be coated, or may be formed by applying a slurry in which an insulating material is dispersed, by adding a heat shrink tube, by insert molding, or by coupling between an upper shell and a lower shell each having a hinge structure or a fastening structure.
图3是示出根据本发明的汇流条因火灾而损坏之前和之后的垂直截面图。FIG. 3 is a vertical cross-sectional view showing a bus bar according to the present invention before and after being damaged by fire.
图3示出了汇流条因火灾而损坏的过程中的两个步骤,其中,时间从上到下进行。FIG. 3 shows two steps in the process of a busbar being damaged by fire, wherein time proceeds from top to bottom.
参照图3的上部图(其是没有发生火灾的普通汇流条200的垂直截面图),最内侧金属板210的外表面依次被由具有绝缘性能的无机金属氧化物制成的第一绝缘构件220和在高温下被陶瓷化的第二绝缘构件230包围。3 , which is a vertical cross-sectional view of a normal busbar 200 where no fire occurs, the outer surface of the innermost metal plate 210 is sequentially surrounded by a first insulating member 220 made of an inorganic metal oxide having insulating properties and a second insulating member 230 ceramicized at high temperature.
参照图3的下部图,当在电池电芯中发生火灾时,火焰或高温气体可以传递到汇流条,由此可以在由金属(特别地,铜制成的金属板)与由无机金属氧化物制成的第一绝缘构件之间形成化学键221。3 , when a fire occurs in a battery cell, flames or high-temperature gases may be transferred to the bus bar, thereby forming chemical bonds 221 between a metal (particularly, a metal plate made of copper) and a first insulating member made of an inorganic metal oxide.
第二绝缘构件可以表现出第二绝缘构件随着陶瓷化的进行而膨胀的膨胀性能。因此,当汇流条被设置成延伸通过开口时,开口可以因第二绝缘构件的膨胀性能而被堵塞。如果在开口中存在间隙,则在发生火灾的电池模块中的火焰或火花可以通过间隙被排放,并且间隙可以被膨胀后的第二绝缘构件填充,由此可以防止火焰或火花通过间隙蔓延到邻近的电池模块。The second insulating member may exhibit an expansion property in which the second insulating member expands as ceramicization proceeds. Therefore, when the bus bar is arranged to extend through the opening, the opening may be blocked due to the expansion property of the second insulating member. If there is a gap in the opening, the flame or spark in the battery module where a fire occurs may be discharged through the gap, and the gap may be filled by the expanded second insulating member, thereby preventing the flame or spark from spreading through the gap to the adjacent battery module.
第二绝缘构件可以由从包含硼类阻燃涂层剂、磷类阻燃涂层剂和硅类阻燃涂层剂组成的组中选择的至少一种制成。The second insulating member may be made of at least one selected from the group consisting of a boron-based flame retardant coating agent, a phosphorus-based flame retardant coating agent, and a silicon-based flame retardant coating agent.
第二绝缘构件可以包括氢氧化镁(MDH)、磷酸一铵(MAP)和氢氧化铝(ATH)中的至少一种。The second insulating member may include at least one of magnesium hydroxide (MDH), monoammonium phosphate (MAP), and aluminum hydroxide (ATH).
可以通过上述部件改进第二绝缘构件的绝缘性能。The insulating performance of the second insulating member can be improved by the above-mentioned components.
如上所述,第一绝缘构件220利用与金属板的化学键221防止金属板短路,并且第二绝缘构件230在高温度下被陶瓷化以确保高绝缘性。因此,即使由于火灾而形成高温环境,也可以保持添加到金属板外部的第一绝缘构件220和第二绝缘构件230包围金属板的状态,因此没有暴露汇流条中的金属板。As described above, the first insulating member 220 prevents the metal plate from short-circuiting by chemical bonds 221 with the metal plate, and the second insulating member 230 is ceramicized at a high temperature to ensure high insulation. Therefore, even if a high temperature environment is formed due to a fire, the first insulating member 220 and the second insulating member 230 added to the outside of the metal plate can be kept to surround the metal plate, so that the metal plate in the bus bar is not exposed.
第一绝缘构件可以由氧化铝(Al2O3)制成。当由于电池模块的异常而引发火灾时,与用作现有普通绝缘构件的诸如塑料这样的有机材料不同,第一绝缘构件没有被烧毁,由此可以保持汇流条的绝缘性能。The first insulating member may be made of aluminum oxide (Al 2 O 3 ). When a fire occurs due to abnormality of the battery module, the first insulating member is not burned unlike organic materials such as plastic used as an existing general insulating member, thereby maintaining the insulating performance of the bus bar.
在电池模块的正常状态下,利用包括由铜(Cu)制成的金属板的汇流条来形成电池模块之间的电和物理连接,并且可以通过添加到汇流条的多个绝缘构件来确保汇流条与周围电气部件的绝缘。In a normal state of the battery module, electrical and physical connections between the battery modules are formed using a bus bar including a metal plate made of copper (Cu), and insulation of the bus bar from surrounding electrical components may be ensured by a plurality of insulating members added to the bus bar.
在电池模块着火的状态下,内部温度为1,000℃或更高,因此,在由铜制成的金属板与由氧化铝制成的第一绝缘构件之间可以形成化学键。In a state where the battery module is on fire, the internal temperature is 1,000° C. or higher, and thus, a chemical bond may be formed between the metal plate made of copper and the first insulating member made of aluminum oxide.
由于Cu与Al2O3之间的化学键,金属板与第一绝缘构件彼此结合,类似于焊接。如上所述,通过牢固结合到金属板外表面的第一绝缘构件,金属板被物理地保护免受周围电气部件的影响,由此可以消除诸如短路这样的其它异常现象的发生。Due to the chemical bond between Cu and Al2O3 , the metal plate and the first insulating member are bonded to each other, similar to welding. As described above, by the first insulating member firmly bonded to the outer surface of the metal plate, the metal plate is physically protected from the influence of surrounding electrical components, thereby eliminating the occurrence of other abnormal phenomena such as short circuits.
第二绝缘构件可以由耐火硅树脂制成。当由于电池模块的异常而引发火灾时,与用作现有普通绝缘构件的诸如塑料这样的有机材料不同,第二绝缘构件没有被烧毁,由此可以保持汇流条的绝缘性能。The second insulating member may be made of fire-resistant silicone resin. When a fire occurs due to abnormality of the battery module, the second insulating member is not burned unlike organic materials such as plastic used as conventional general insulating members, thereby maintaining the insulating performance of the bus bar.
在电池模块的正常状态下,第二绝缘构件保持包围第一绝缘构件和由铜制成的金属板。第二绝缘构件在正常状况下具有弹性性能,由此第二绝缘构件保护易碎的第一绝缘构件(例如,陶瓷)。另外,为了改进绝缘功能,可以在第一绝缘构件中形成附加绝缘层。In a normal state of the battery module, the second insulating member keeps surrounding the first insulating member and the metal plate made of copper. The second insulating member has elastic properties under normal conditions, whereby the second insulating member protects the fragile first insulating member (e.g., ceramic). In addition, in order to improve the insulation function, an additional insulating layer may be formed in the first insulating member.
在电池模块着火的状态下,包括耐火硅树脂的第二绝缘构件从暴露于外部的部分开始被陶瓷化。然而,取决于第二绝缘构件的材料,第二绝缘构件可以在被陶瓷化的同时膨胀。In a state where the battery module is on fire, the second insulating member including the fire-resistant silicone resin is ceramicized from a portion exposed to the outside. However, depending on the material of the second insulating member, the second insulating member may expand while being ceramicized.
即,常规的汇流条绝缘构件简单地覆盖由Cu制成的金属板,而根据本发明的绝缘构件被配置为具有以下的结构:第一绝缘构件被添加到由Cu制成的金属板的周缘以包围金属板,并且包括耐火硅树脂材料的第二绝缘构件在包围汇流条最外侧的同时支承金属板。That is, whereas a conventional busbar insulating member simply covers a metal plate made of Cu, the insulating member according to the present invention is configured to have the following structure: a first insulating member is added to the periphery of the metal plate made of Cu to surround the metal plate, and a second insulating member comprising a refractory silicone material supports the metal plate while surrounding the outermost side of the busbar.
图4是示出被配置为将两个电池模块彼此连接的汇流条被设置成延伸穿过分隔壁的状态的立体图和垂直截面图。4 is a perspective view and a vertical sectional view illustrating a state in which a bus bar configured to connect two battery modules to each other is provided to extend through a partition wall.
参照图4,用于防火焰的分隔壁330形成在两个电池模块301之间,并且供汇流条200延伸通过的通孔302形成在分隔壁中。汇流条200被设置为延伸通过通孔302,以便将两个电池模块301彼此电连接。4, a partition wall 330 for flame prevention is formed between two battery modules 301, and a through hole 302 through which a bus bar 200 extends is formed in the partition wall. The bus bar 200 is provided to extend through the through hole 302 to electrically connect the two battery modules 301 to each other.
当汇流条200的第二绝缘构件包括可膨胀的阻燃硅树脂时,如果汇流条的温度由于火灾而升高,则第二绝缘构件可以膨胀并阻塞通孔302,由此可以防止火焰和火花蔓延到相邻的电池模块。When the second insulating member of the bus bar 200 includes expandable flame-retardant silicone, if the temperature of the bus bar increases due to fire, the second insulating member may expand and block the through-hole 302 , thereby preventing flames and sparks from spreading to adjacent battery modules.
另选地,可以设置分隔壁的位置和大小,以便引导在电池模块中产生的火焰和火花的蔓延方向。Alternatively, the position and size of the partition wall may be set so as to guide the spreading direction of flames and sparks generated in the battery module.
图5是多个电池模块被容纳在由分隔壁分隔的电池组外壳中的电池组的立体图。FIG. 5 is a perspective view of a battery pack in which a plurality of battery modules are accommodated in a battery pack case partitioned by partition walls.
参照图5,根据本发明,电池组300被配置为使得多个电池模块301经由汇流条200彼此电连接。尽管图5示出了包括九个电池模块的电池组(这只是出于例示目的的示例),但构成电池组的电池模块的布置和数量以及用于将电池模块彼此连接的汇流条的联接位置和形状并不限于此。5 , according to the present invention, a battery pack 300 is configured such that a plurality of battery modules 301 are electrically connected to each other via a bus bar 200. Although FIG. 5 shows a battery pack including nine battery modules (this is just an example for illustrative purposes), the arrangement and number of battery modules constituting the battery pack and the coupling position and shape of the bus bar for connecting the battery modules to each other are not limited thereto.
在根据本发明的电池组300中,多个电池模块被容纳在电池组外壳中,栅格状的分隔壁被安装在电池组外壳中,一个电池模块位于一个栅格空间中,并且汇流条被设置为横跨分隔壁330的上表面311,以便将多个电池模块彼此电连接。In the battery pack 300 according to the present invention, a plurality of battery modules are accommodated in a battery pack housing, a grid-like partition wall is installed in the battery pack housing, one battery module is located in one grid space, and a bus bar is arranged to span an upper surface 311 of the partition wall 330 so as to electrically connect the plurality of battery modules to each other.
栅格状的分隔壁可以执行防火焰功能。因此,即使在任一个电池模块中发生火灾,也可以防止火焰或火花蔓延到与其相邻的电池模块。The grid-like partition walls can perform a flame prevention function. Therefore, even if a fire occurs in any one battery module, it is possible to prevent the flame or spark from spreading to the battery modules adjacent thereto.
另外,当汇流条被设置为横跨分隔壁330的上表面311时,在电池模块中发生火灾的情况下,金属板不通过第一绝缘构件和第二绝缘构件暴露于外部。因此,即使汇流条在分隔壁330的上表面311处与构成电池组并由导电金属材料制成的部件接触,也可以保持汇流条与由导电金属材料制成的部件之间的绝缘。In addition, when the bus bar is provided across the upper surface 311 of the partition wall 330, in the event of a fire in the battery module, the metal plate is not exposed to the outside through the first insulating member and the second insulating member. Therefore, even if the bus bar contacts a component that constitutes the battery pack and is made of a conductive metal material at the upper surface 311 of the partition wall 330, insulation between the bus bar and the component made of the conductive metal material can be maintained.
在本发明中,如上所述,添加到金属板的第一绝缘构件和第二绝缘构件没有被烧毁,并且在发生火灾的情况下仍被添加到金属板的外表面,由此金属板不会暴露于外部。因此,即使汇流条和与其相邻的金属部件接触,汇流条的绝缘也可以得到保持。In the present invention, as described above, the first insulating member and the second insulating member added to the metal plate are not burned and are still added to the outer surface of the metal plate in the event of a fire, so that the metal plate is not exposed to the outside. Therefore, even if the bus bar contacts the metal parts adjacent thereto, the insulation of the bus bar can be maintained.
本发明所属领域的技术人员将理解,基于以上描述,在本发明的类别内各种应用和修改都是可能的。Those skilled in the art to which the present invention pertains will appreciate that various applications and modifications are possible within the category of the present invention based on the above description.
(对附图标记的描述)(Description of Reference Numerals)
110、210:金属板110, 210: Metal plate
120:绝缘带120: Insulation tape
130:硅树脂管130: Silicone tube
200:汇流条200: Busbar
220:第一绝缘构件220: First insulating member
221:化学键221: Chemical Bonds
230:第二绝缘构件230: Second insulating member
240:电连接部分240: Electrical connection part
241:开口241: Opening
300:电池组300: Battery Pack
301:电池模块301: Battery module
302:通孔302: Through hole
310:电池组框架310: Battery Pack Frame
311:电池组框架的上表面311: Upper surface of battery pack frame
320:电池组外壳320: Battery pack housing
330:分隔壁330: Partition wall
Claims (13)
Applications Claiming Priority (4)
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KR10-2022-0114234 | 2022-09-08 | ||
KR1020230118950A KR20240035365A (en) | 2022-09-08 | 2023-09-07 | Busbar with improved flame resistance and battery pack comprising the same |
KR10-2023-0118950 | 2023-09-07 | ||
PCT/KR2023/013530 WO2024054098A1 (en) | 2022-09-08 | 2023-09-08 | Busbar having improved flame resistance, and battery pack including same |
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Publication Number | Publication Date |
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CN118556342A true CN118556342A (en) | 2024-08-27 |
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CN202380017800.1A Pending CN118556342A (en) | 2022-09-08 | 2023-09-08 | Bus bar with improved flame retardancy and battery pack including the same |
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