CN118547240B - Mask plate preparation method and mask plate - Google Patents
Mask plate preparation method and mask plate Download PDFInfo
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- CN118547240B CN118547240B CN202411046489.6A CN202411046489A CN118547240B CN 118547240 B CN118547240 B CN 118547240B CN 202411046489 A CN202411046489 A CN 202411046489A CN 118547240 B CN118547240 B CN 118547240B
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/68—Preparation processes not covered by groups G03F1/20 - G03F1/50
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
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- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
- C23C14/042—Coating on selected surface areas, e.g. using masks using masks
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/164—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using vacuum deposition
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/166—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using selective deposition, e.g. using a mask
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Abstract
本发明公开了一种掩膜板制备方法及掩膜板,涉及掩膜板技术领域。所述方法包括以下步骤:步骤S1.在载板其中一表面形成一光阻膜;步骤S2.在光阻膜上形成倒梯形结构的槽孔;步骤S3.在光阻膜表面设置一加强筋;步骤S4.通过真空镀膜的方法在光阻膜及加强筋表面形成第一真空镀箔膜,在槽孔中形成第二真空镀箔膜;步骤S5.去除光阻膜,将加强筋和第一真空镀箔膜与载板及第二真空镀箔膜分离,得到掩膜片组合,该掩膜片组合由加强筋和第一真空镀箔膜构成;步骤S6.将掩膜片组合转移至掩膜框上,并与掩膜框绑定,得到掩膜板。通过该方法,可获得具有扩口状开口部的掩膜板,且制备过程中掩膜片不易起皱、变形、开裂。
The present invention discloses a method for preparing a mask plate and a mask plate, and relates to the technical field of mask plates. The method comprises the following steps: step S1. forming a photoresist film on one surface of a carrier plate; step S2. forming a slot with an inverted trapezoidal structure on the photoresist film; step S3. setting a reinforcing rib on the surface of the photoresist film; step S4. forming a first vacuum-plated foil film on the surface of the photoresist film and the reinforcing rib by a vacuum coating method, and forming a second vacuum-plated foil film in the slot; step S5. removing the photoresist film, separating the reinforcing rib and the first vacuum-plated foil film from the carrier plate and the second vacuum-plated foil film, and obtaining a mask sheet combination, which is composed of the reinforcing rib and the first vacuum-plated foil film; step S6. transferring the mask sheet combination to a mask frame, and binding it to the mask frame to obtain a mask plate. By this method, a mask plate with a flared opening can be obtained, and the mask sheet is not easy to wrinkle, deform, or crack during the preparation process.
Description
技术领域Technical Field
本发明涉及掩膜板技术领域,特别涉及一种掩膜板制备方法及掩膜板。The present invention relates to the technical field of mask plates, and in particular to a mask plate preparation method and a mask plate.
背景技术Background Art
在OLED显示屏制造过程中,为了将RGB发光层有机材料分别蒸镀到基板的RGB像素点上,会设置用于遮蔽其它像素的精密掩膜板(FMM)。现行的量产用FMM掩膜板的厚度一般为20~50μm,通常采用湿法刻蚀出蒸镀时材料蒸气穿过的孔洞(蒸镀图案)。然而,由于湿法刻蚀的各向同性,较厚的箔材难以把孔洞做更小,导致其分辨率受限;此外,由于一些有机材料蒸气蒸镀至基板时有一定的蒸发入射角,为使基板像素内均匀充填有机膜,往往将掩膜片制作得很薄,一般而言,像素分辨率越高,需要的掩膜片越薄。然而,掩膜片越薄,其强度也就越弱,强度弱的掩膜片容易起皱或破裂,给绑定、搬送、存储和有机材料镀膜带来难解之题。In the manufacturing process of OLED display screens, in order to evaporate the RGB light-emitting layer organic materials onto the RGB pixels of the substrate respectively, a precision mask (FMM) is set up to shield other pixels. The thickness of the current mass production FMM mask is generally 20 to 50 μm, and wet etching is usually used to form holes (evaporation patterns) through which the material vapor passes during evaporation. However, due to the isotropy of wet etching, it is difficult to make the holes smaller with thicker foils, resulting in limited resolution; in addition, since some organic materials have a certain evaporation incident angle when vapor is evaporated onto the substrate, in order to evenly fill the organic film in the substrate pixels, the mask is often made very thin. Generally speaking, the higher the pixel resolution, the thinner the mask is required. However, the thinner the mask, the weaker its strength. Weak mask sheets are prone to wrinkling or cracking, which brings difficult problems to binding, transportation, storage and organic material coating.
对此,公开号为CN117418193A的中国发明专利申请公开了一种掩膜板制备方法及掩膜板,该制备方法通过在脱模处理前先将掩膜片组件与掩膜框贴合绑定,通过透明载板的固定作用,可使掩膜片保持水平状态,并且在贴合绑定时不易破裂。但是,该方法采用电铸法形成掩膜片,为湿法铸膜,不但要求载板上具有导电膜,且掩膜片形成的开口部无法是弧形,并容易引入杂质,并且在去除导电膜和载板时,易导致掩膜片起皱、变形或破裂,使得该方法的推广受限。In this regard, the Chinese invention patent application with publication number CN117418193A discloses a method for preparing a mask plate and a mask plate. The method first bonds the mask sheet assembly to the mask frame before demolding, and the transparent carrier plate is used to fix the mask sheet so that the mask sheet can remain horizontal and is not easily broken when bonded. However, the method uses electroforming to form the mask sheet, which is a wet casting method. It not only requires a conductive film on the carrier plate, but also the opening formed by the mask sheet cannot be arc-shaped, and it is easy to introduce impurities. When the conductive film and the carrier plate are removed, the mask sheet is easily wrinkled, deformed or broken, which limits the promotion of this method.
可见,现有技术还有待改进和提高。It can be seen that the existing technology still needs to be improved and enhanced.
发明内容Summary of the invention
鉴于上述现有技术的不足之处,本发明的目的在于提供一种掩膜板制备方法及掩膜板,旨在解决掩膜片制备过程中易起皱、变形及破裂的缺陷。In view of the above-mentioned deficiencies in the prior art, an object of the present invention is to provide a mask plate preparation method and a mask plate, aiming to solve the defects of the mask plate being prone to wrinkling, deformation and cracking during the preparation process.
为了达到上述目的,本发明采取了以下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:
一种掩膜板制备方法,其中,所述方法包括以下步骤:A method for preparing a mask plate, wherein the method comprises the following steps:
步骤S1.在载板其中一表面形成一光阻膜;Step S1. forming a photoresist film on one surface of the carrier;
步骤S2.在光阻膜上形成倒梯形结构的槽孔;Step S2. forming a groove having an inverted trapezoidal structure on the photoresist film;
步骤S3.在光阻膜表面设置一加强筋;Step S3. Arranging a reinforcing rib on the surface of the photoresist film;
步骤S4.通过真空镀膜的方法在光阻膜及加强筋表面形成第一真空镀箔膜,在槽孔中形成第二真空镀箔膜;Step S4. forming a first vacuum-plated foil film on the surface of the photoresist film and the reinforcing ribs by a vacuum coating method, and forming a second vacuum-plated foil film in the slots;
步骤S5.去除光阻膜,将加强筋和第一真空镀箔膜与载板及第二真空镀箔膜分离,得到掩膜片组合,该掩膜片组合由加强筋和第一真空镀箔膜构成;Step S5. removing the photoresist film, separating the reinforcing ribs and the first vacuum-plated foil film from the carrier and the second vacuum-plated foil film, and obtaining a mask sheet assembly, wherein the mask sheet assembly is composed of the reinforcing ribs and the first vacuum-plated foil film;
步骤S6.将掩膜片组合转移至掩膜框上,并与掩膜框绑定,得到掩膜板。Step S6: Transfer the mask sheet assembly to the mask frame and bind it to the mask frame to obtain a mask plate.
所述的掩膜板制备方法中,在所述步骤S3中,先在载板与光阻膜相背的表面设置一磁板,并利用磁板的磁性在光阻膜表面吸附一加强筋。In the mask plate preparation method, in step S3, a magnetic plate is firstly arranged on the surface of the carrier plate opposite to the photoresist film, and a reinforcing rib is adsorbed on the surface of the photoresist film by utilizing the magnetism of the magnetic plate.
所述的掩膜板制备方法中,所述步骤S3中,在加强筋的表面涂覆一层有机透明胶膜,并通过该有机透明胶膜将加强筋附着于光阻膜上。In the mask plate preparation method, in step S3, a layer of organic transparent adhesive film is coated on the surface of the reinforcing rib, and the reinforcing rib is attached to the photoresist film through the organic transparent adhesive film.
所述的掩膜板制备方法中,所述第一真空镀箔膜和第二真空镀箔膜的厚度小于槽孔的深度,且第一真空镀箔膜与第二真空镀箔膜不相连。In the mask plate preparation method, the thickness of the first vacuum-plated foil film and the second vacuum-plated foil film is less than the depth of the slot, and the first vacuum-plated foil film is not connected to the second vacuum-plated foil film.
所述的掩膜板制备方法中,所述步骤S4中,真空镀膜的方法选自磁控溅射、离子镀、电子束蒸镀及激光蒸镀法中的一种。In the mask preparation method, in step S4, the vacuum coating method is selected from magnetron sputtering, ion plating, electron beam evaporation and laser evaporation.
所述的掩膜板制备方法中,所述第一真空镀箔膜和第二真空镀箔膜的材质选自镍铁合金、铁钴镍合金、铁钴钐合金、陶瓷、玻璃、金刚石、类金刚石中的一种或多种的组合。In the mask plate preparation method, the material of the first vacuum-plated foil film and the second vacuum-plated foil film is selected from a combination of one or more of nickel-iron alloy, iron-cobalt-nickel alloy, iron-cobalt-smium alloy, ceramic, glass, diamond, and diamond-like carbon.
所述的掩膜板制备方法中,所述载板为透明载板,并且在载板与光阻膜之间还设有剥离膜。In the mask plate preparation method, the carrier plate is a transparent carrier plate, and a stripping film is provided between the carrier plate and the photoresist film.
所述的掩膜板制备方法中,所述剥离膜为氮化镓膜或氮化铟锌膜,或者为热剥离膜。In the mask plate preparation method, the stripping film is a gallium nitride film or an indium zinc nitride film, or a thermal stripping film.
所述的掩膜板制备方法中,所述步骤S6中,所述掩膜框在绑定前有经过冷却处理。In the mask plate preparation method, in step S6, the mask frame is cooled before being bound.
一种掩膜板,其中,其由如上所述的方法制备得到,所述掩膜板包括掩膜框和掩膜片,所述掩膜片的厚度为0.1~30μm。A mask plate is prepared by the method as described above, wherein the mask plate comprises a mask frame and a mask sheet, and the thickness of the mask sheet is 0.1-30 μm.
有益效果:本发明提供了一种掩膜板制备方法及掩膜板,该制备方法中,通过具有倒梯形槽孔的光阻膜,可实现通过真空镀膜获得具有扩口状开口部的第一真空镀箔膜,通过在光阻膜上贴附加强筋,可实现第一真空镀箔膜在分离、转移、绑定时始终保持展开状态,并且能避免掩膜片起皱、变形、破裂,能更好的保护掩膜片。Beneficial effect: The present invention provides a mask plate preparation method and a mask plate. In the preparation method, a photoresist film with inverted trapezoidal slots can be used to obtain a first vacuum-coated foil film with a flared opening through vacuum coating. By attaching additional reinforcing ribs to the photoresist film, the first vacuum-coated foil film can always remain in an unfolded state during separation, transfer, and binding, and the mask plate can be prevented from wrinkling, deformation, and cracking, thereby better protecting the mask plate.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本发明提供的掩膜板制备方法的工艺流程图。FIG. 1 is a process flow chart of the method for preparing a mask provided by the present invention.
图2为通过结构示意图表示的掩膜板制备步骤图一。FIG. 2 is a diagram showing the first step of preparing a mask plate through a structural schematic diagram.
图3为通过结构示意图表示的掩膜板制备步骤图二。FIG. 3 is a second diagram of mask plate preparation steps represented by a structural schematic diagram.
图4为图2中A处的放大示意。FIG. 4 is an enlarged view of point A in FIG. 2 .
图5为通过结构示意图表示的掩膜板制备步骤图三。FIG. 5 is a third diagram of mask preparation steps represented by a structural schematic diagram.
附图中标记:1-载板,2-光阻膜,3-槽孔,4-磁板,5-加强筋,6-第一真空镀箔膜,7-第二真空镀箔膜,8-掩膜框,9-掩膜片组合,10-剥离膜,11-有机透明胶膜。Markings in the attached drawings: 1-carrier, 2-photoresist film, 3-slot, 4-magnetic plate, 5-reinforcing rib, 6-first vacuum-plated foil film, 7-second vacuum-plated foil film, 8-mask frame, 9-mask sheet assembly, 10-peeling film, 11-organic transparent adhesive film.
具体实施方式DETAILED DESCRIPTION
本发明提供一种掩膜板制备方法及掩膜板,为使本发明的目的、技术方案及效果更加清楚、明确,以下举实施例对本发明进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。The present invention provides a method for preparing a mask plate and a mask plate. To make the purpose, technical solution and effect of the present invention clearer and more specific, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention and are not used to limit the present invention.
请参阅图1或图2,本发明较佳实施例提供的一种掩膜板制备方法,该制备方法包括以下步骤:Please refer to FIG. 1 or FIG. 2 , a preferred embodiment of the present invention provides a method for preparing a mask plate, and the method comprises the following steps:
步骤S1.在载板1其中一表面形成一光阻膜2,如,通过涂胶的方式在载板1的上表面或下表面形成一层光阻膜2,该光阻膜2的厚度大于待制备的掩膜片的厚度。Step S1. Form a photoresist film 2 on one surface of the carrier 1, for example, by forming a layer of photoresist film 2 on the upper surface or the lower surface of the carrier 1 by coating with glue, wherein the thickness of the photoresist film 2 is greater than the thickness of the mask to be prepared.
步骤S2.在光阻膜2上形成倒梯形结构的槽孔3,如,依据待制备的掩膜片的蒸镀图案,对光阻膜2的局部进行曝光和显影,以获得横截面为倒梯形结构的槽孔3,该倒梯形结构的槽孔3的槽口宽度小于槽底的宽度,具体形状如图2或图4所示,以便于后续位于槽孔3中的箔膜不与位于光阻膜2上的箔膜发生粘连。Step S2. forming a slot 3 with an inverted trapezoidal structure on the photoresist film 2. For example, according to the evaporation pattern of the mask sheet to be prepared, partially exposing and developing the photoresist film 2 to obtain a slot 3 with an inverted trapezoidal structure in cross section. The slot mouth width of the inverted trapezoidal structure slot 3 is smaller than the width of the slot bottom. The specific shape is shown in FIG. 2 or FIG. 4, so that the foil film subsequently located in the slot 3 does not adhere to the foil film located on the photoresist film 2.
步骤S3.在载板1另一表面设置一磁板4,即载板1与光阻膜2相背的一面设置磁板4,该磁板4的大小能全面覆盖载板1,并利用磁板4的磁性在光阻膜2表面吸附一加强筋5,该加强筋5采用软磁性材料制备得到,其能在磁板4的磁吸作用下,贴附于光阻膜2的表面;该加强筋5包括框架和设置于框架上的筋条,所述框架的内侧壁由上至下向外倾斜,所述筋条的横截面均呈倒梯形结构,即,筋条的上边较下边长,因此其顶部的导角θ<90°,优选的,该导角θ为30°≤θ≤60°,所以在蒸镀时,能在加强筋5表面形成连续的箔膜(第一真空镀箔膜),且该箔膜不与位于槽孔中的箔膜(第二真空镀箔膜)相连。此外,设置加强筋5的表面具有一定的粗糙度,粗糙的表面便于后续蒸镀时箔膜附着其上,提高第一真空镀箔膜6在加强筋5表面的附着力。由于该加强筋5具有支撑和展开第一真空镀箔膜的作用,便于后续第一真空镀箔膜的转移和固定,并能防止第一真空镀箔膜在后续使用过程中破裂。Step S3. A magnetic plate 4 is arranged on the other surface of the carrier 1, that is, a magnetic plate 4 is arranged on the side of the carrier 1 opposite to the photoresist film 2. The size of the magnetic plate 4 can fully cover the carrier 1, and a reinforcing rib 5 is adsorbed on the surface of the photoresist film 2 by utilizing the magnetism of the magnetic plate 4. The reinforcing rib 5 is made of soft magnetic material and can be attached to the surface of the photoresist film 2 under the magnetic attraction of the magnetic plate 4; the reinforcing rib 5 includes a frame and ribs arranged on the frame, the inner side wall of the frame is inclined outward from top to bottom, and the cross-section of the ribs is an inverted trapezoidal structure, that is, the upper side of the rib is longer than the lower side, so the guide angle θ of the top thereof is less than 90°, and preferably, the guide angle θ is 30°≤θ≤60°, so during evaporation, a continuous foil film (first vacuum-plated foil film) can be formed on the surface of the reinforcing rib 5, and the foil film is not connected to the foil film (second vacuum-plated foil film) located in the slot. In addition, the surface on which the reinforcing rib 5 is provided has a certain degree of roughness, and the rough surface facilitates the foil film to adhere thereto during subsequent evaporation, thereby improving the adhesion of the first vacuum-plated foil film 6 to the surface of the reinforcing rib 5. Since the reinforcing rib 5 has the function of supporting and unfolding the first vacuum-plated foil film, it is convenient for the subsequent transfer and fixation of the first vacuum-plated foil film, and can prevent the first vacuum-plated foil film from breaking during subsequent use.
步骤S4.通过真空镀膜的方法在光阻膜2及加强筋5表面形成第一真空镀箔膜6(该第一真空镀箔膜6在后续步骤用作掩膜片,因此也可以称作掩膜片),在槽孔3中形成第二真空镀箔膜7,具体为:通过物理气相沉积的方法将材料沉积于光阻膜2、加强筋5及槽孔3中,利用槽孔3的倒梯形结构,使沉积于光阻膜2和加强筋5表面的箔膜与沉积于槽孔3中的箔膜相分离,其中,沉积于光阻膜2和加强筋5表面的箔膜能形成连续的膜片,定义为第一真空镀箔膜6,而沉积于各槽孔3中的箔膜各自独立且不相连,定义为第二真空镀箔膜7,由于第一真空镀箔膜6与第二真空镀箔膜7并不相连,使得第一真空镀箔膜6对应第二真空镀箔膜7的位置可形成开口,并由于沉积的作用,这些开口呈扩口状,同时,这些开口的分布与基板待蒸镀的图案相同,相当于是,在第一真空镀箔膜6上形成了与蒸镀图案适配的开口部。Step S4. Forming a first vacuum-coated foil film 6 on the surface of the photoresist film 2 and the reinforcing rib 5 by a vacuum coating method (the first vacuum-coated foil film 6 is used as a mask in subsequent steps, so it can also be called a mask), and forming a second vacuum-coated foil film 7 in the slot 3, specifically: depositing the material on the photoresist film 2, the reinforcing rib 5 and the slot 3 by a physical vapor deposition method, and using the inverted trapezoidal structure of the slot 3 to separate the foil film deposited on the surface of the photoresist film 2 and the reinforcing rib 5 from the foil film deposited in the slot 3, wherein the foil film deposited on the photoresist film 2 and the reinforcing rib 5 is The foil film on the surface can form a continuous film sheet, which is defined as the first vacuum-plated foil film 6, and the foil films deposited in each slot 3 are independent and unconnected, which are defined as the second vacuum-plated foil film 7. Since the first vacuum-plated foil film 6 is not connected to the second vacuum-plated foil film 7, openings can be formed at the positions of the first vacuum-plated foil film 6 corresponding to the second vacuum-plated foil film 7, and due to the effect of deposition, these openings are expanded. At the same time, the distribution of these openings is the same as the pattern to be evaporated on the substrate, which is equivalent to forming an opening portion adapted to the evaporation pattern on the first vacuum-plated foil film 6.
步骤S5.去除光阻膜2,将加强筋5和第一真空镀箔膜6与载板1及第二真空镀箔膜7分离,得到掩膜片组合9。该步骤具体为:先将磁板4移除,然后将叠合于一体的载板1、光阻膜2、加强筋5、第一真空镀箔膜6、第二真空镀箔膜7浸入清洗液中,该清洗液为乙醇胺和二甲基亚砜的混合液,其可将光阻膜2慢慢溶解,进而使加强筋5及第一真空镀箔膜6与载板1及第二真空镀箔膜7分离,得到掩膜片组合9,该掩膜片组合9由加强筋5和第一真空镀箔膜6构成。Step S5. Remove the photoresist film 2, separate the reinforcing ribs 5 and the first vacuum-plated foil film 6 from the carrier 1 and the second vacuum-plated foil film 7, and obtain a mask sheet assembly 9. This step is specifically as follows: first remove the magnetic plate 4, and then immerse the carrier 1, the photoresist film 2, the reinforcing ribs 5, the first vacuum-plated foil film 6, and the second vacuum-plated foil film 7 that are superimposed on one another in a cleaning solution, which is a mixture of ethanolamine and dimethyl sulfoxide, which can slowly dissolve the photoresist film 2, and then separate the reinforcing ribs 5 and the first vacuum-plated foil film 6 from the carrier 1 and the second vacuum-plated foil film 7, and obtain a mask sheet assembly 9, which is composed of the reinforcing ribs 5 and the first vacuum-plated foil film 6.
步骤S6.将掩膜片组合9转移至掩膜框8上,并通过焊接与掩膜框8绑定,得到掩膜板。在该步骤中,利用加强筋5的支撑作用,可非常方便的将第一真空镀箔膜(相当于是掩膜片)转移至掩膜框8上,在转移的过程中,无需其他辅助工具,也能保证第一真空镀箔膜不变形、起皱、开裂、破碎,非常的方便;此外,当掩膜片组合9没有立即焊接于掩膜框8上,作为备用先储存起来时,在存储过程中,加强筋5也能使掩膜片保持展开状态。Step S6. Transfer the mask sheet assembly 9 to the mask frame 8, and bind it to the mask frame 8 by welding to obtain a mask plate. In this step, the first vacuum-plated foil film (equivalent to the mask sheet) can be very conveniently transferred to the mask frame 8 by utilizing the supporting function of the reinforcing ribs 5. During the transfer process, no other auxiliary tools are required, and the first vacuum-plated foil film can be ensured not to be deformed, wrinkled, cracked, or broken, which is very convenient; in addition, when the mask sheet assembly 9 is not immediately welded to the mask frame 8 and is stored as a backup, the reinforcing ribs 5 can also keep the mask sheet in an unfolded state during storage.
由此可见,本实施例所述掩膜板制备方法,通过在载板1表面形成光阻膜2,以便利用光刻作用,在光阻膜2上形成特定的图案,该特定的图案与待制备的掩膜片的蒸镀图案相同,即,其可以使掩膜片具有与蒸镀图案适配的开口部,该开口部应用于基板蒸镀有机膜时,蒸汽可通过开口部附着于基板表面形成有机膜。同时,设置槽孔3为倒梯形结构,其倾斜边可使形成的第一真空镀箔膜6和第二真空镀箔膜7相互分离,并且能使第一真空镀箔膜6在对应槽孔3的位置形成斜边或具有弧度的斜边,即,使第一真空镀箔膜6形成的开口为扩口,因此应用于基板的蒸镀时,可形成更为均匀的有机膜。再者,由于待制备的掩膜片的厚度非常薄,为了防止掩膜片起皱、破裂,同时为了便于掩膜片转移,在本制备方法中还设置有加强筋5,利用加强筋5的支撑作用,使第一真空镀箔膜6与光阻膜2分离后,可防止掩膜片起皱、破裂,并且能使掩膜片的转移更为方便。此外,为了便于加强筋5附着于光阻膜2表面,所述加强筋5采用软磁性材料制备得到,通过在基板一侧设置磁板4,利用磁板4的磁吸作用,可使加强筋5贴附于光阻膜2表面,而当磁板4撤离时,该加强板又能方便的从光阻膜2表面脱附,便于分离。It can be seen that the method for preparing the mask plate described in this embodiment forms a photoresist film 2 on the surface of the carrier plate 1 so as to form a specific pattern on the photoresist film 2 by means of photolithography. The specific pattern is the same as the evaporation pattern of the mask plate to be prepared, that is, it can make the mask plate have an opening adapted to the evaporation pattern. When the opening is applied to the substrate to evaporate the organic film, the steam can adhere to the surface of the substrate through the opening to form an organic film. At the same time, the slot 3 is set to an inverted trapezoidal structure, and its inclined edge can separate the formed first vacuum-plated foil film 6 and the second vacuum-plated foil film 7 from each other, and can make the first vacuum-plated foil film 6 form a bevel or a bevel with a curvature at the position corresponding to the slot 3, that is, the opening formed by the first vacuum-plated foil film 6 is expanded, so when it is applied to the evaporation of the substrate, a more uniform organic film can be formed. Furthermore, since the thickness of the mask sheet to be prepared is very thin, in order to prevent the mask sheet from wrinkling and cracking, and to facilitate the transfer of the mask sheet, a reinforcing rib 5 is also provided in the preparation method. The supporting effect of the reinforcing rib 5 can prevent the mask sheet from wrinkling and cracking after the first vacuum-plated foil film 6 is separated from the photoresist film 2, and the transfer of the mask sheet can be more convenient. In addition, in order to facilitate the attachment of the reinforcing rib 5 to the surface of the photoresist film 2, the reinforcing rib 5 is made of soft magnetic material. By setting a magnetic plate 4 on one side of the substrate, the reinforcing rib 5 can be attached to the surface of the photoresist film 2 by the magnetic attraction of the magnetic plate 4. When the magnetic plate 4 is withdrawn, the reinforcing plate can be easily detached from the surface of the photoresist film 2, which is convenient for separation.
上述制备方法中,为了防止第一真空镀箔膜6与第二真空镀箔膜7发生粘连,除了使槽孔3为倒梯形结构外,还需控制好第一真空镀箔膜6和第二真空镀箔膜7的厚度。对此,在一种较佳的实施例中,所述第一真空镀箔膜6和第二真空镀箔膜7的厚度小于槽孔3的深度,因此利用槽孔3的倾斜壁可使第一真空镀箔膜6和第二真空镀箔膜7不会形成连续状。具体实施过程中,所述槽孔3的深度可根据待制备的掩膜片的厚度设置,以使其深度大于第一真空镀箔膜6和第二真空镀箔膜7的厚度。具体而言,一方面,掩膜片的厚度需要根据像素密度等因素来选定,另一方面还要考虑掩膜片的强度,因此,作为一种优选的实施方式,所述第一真空镀箔膜6和第二真空镀箔膜7的厚度为0.1~30μm,此时,槽孔3深度优选为>30μm。更优选的,所述第一真空镀箔膜6和第二真空镀箔膜7的厚度为10~15μm,槽孔3深度应>15μm。In the above preparation method, in order to prevent the first vacuum-plated foil film 6 and the second vacuum-plated foil film 7 from sticking together, in addition to making the slot 3 an inverted trapezoidal structure, the thickness of the first vacuum-plated foil film 6 and the second vacuum-plated foil film 7 must be controlled. In this regard, in a preferred embodiment, the thickness of the first vacuum-plated foil film 6 and the second vacuum-plated foil film 7 is less than the depth of the slot 3, so the inclined wall of the slot 3 can be used to prevent the first vacuum-plated foil film 6 and the second vacuum-plated foil film 7 from forming a continuous shape. In the specific implementation process, the depth of the slot 3 can be set according to the thickness of the mask sheet to be prepared so that its depth is greater than the thickness of the first vacuum-plated foil film 6 and the second vacuum-plated foil film 7. Specifically, on the one hand, the thickness of the mask sheet needs to be selected according to factors such as pixel density, and on the other hand, the strength of the mask sheet must also be considered. Therefore, as a preferred embodiment, the thickness of the first vacuum-plated foil film 6 and the second vacuum-plated foil film 7 is 0.1-30μm, and at this time, the depth of the slot 3 is preferably>30μm. More preferably, the thickness of the first vacuum-plated foil film 6 and the second vacuum-plated foil film 7 is 10-15 μm, and the depth of the slot 3 should be greater than 15 μm.
具体的,所述步骤S4中,真空镀膜的方法选自磁控溅射、离子镀、电子束蒸镀及激光蒸镀法中的一种,可在加强筋5及光阻膜2表面沉积形成第一真空镀箔膜6,在槽孔3中沉积形成第二真空镀箔膜7。Specifically, in step S4, the vacuum coating method is selected from one of magnetron sputtering, ion plating, electron beam evaporation and laser evaporation, and a first vacuum-coated foil film 6 can be deposited on the surface of the reinforcing rib 5 and the photoresist film 2, and a second vacuum-coated foil film 7 can be deposited in the slot 3.
在所述步骤S4中,真空镀膜沉积的材料可以是镍铁合金、铁钴镍合金、铁钴钐合金、陶瓷、玻璃、金刚石、类金刚石(DLC)中的一种或多种的组合,也可以是其他具有较好热稳定性及力学强度的材料,具体实施过程中,可根据实际需要选择,以满足掩膜板对性能的要求。如,所述第一真空镀箔膜6由铁镍合金和金刚石两种材料构成,在真空镀膜时,可先沉积其中一种材料,然后再沉积另一种材料,也可以进行共镀,具体可根据实际需要选择。In step S4, the material deposited by vacuum coating can be a combination of one or more of nickel-iron alloy, iron-cobalt-nickel alloy, iron-cobalt-samarium alloy, ceramic, glass, diamond, diamond-like carbon (DLC), or other materials with good thermal stability and mechanical strength. In the specific implementation process, it can be selected according to actual needs to meet the performance requirements of the mask. For example, the first vacuum-coated foil film 6 is composed of two materials, iron-nickel alloy and diamond. During vacuum coating, one of the materials can be deposited first, and then the other material can be deposited, or co-plating can be performed. It can be selected according to actual needs.
前述实施例中,在去除光阻膜2时,需将脱模前的多个层级结构置于清洗液中,然而,由于光阻膜2夹持于载板1和加强筋5及第一真空镀箔膜6之间,导致其与清洗液的接触面较小,使得浸泡时长较长,生产效率低。对此,在一种较佳的实施例中,如图3所示,为了使光阻膜2更好的暴露,设置所述载板1为透明载板1,并且在载板1与光阻膜2之间还设有剥离膜10,该剥离膜10在受热或激光作用下,可将载板1与光阻膜2分离,进而非常方便的将载板1从光阻膜2表面移除,以使光阻膜2表面较大面积的暴露,在浸泡时,可大大增大光阻膜2与清洗液的接触面积,缩短清洗时间,提高清洗效率。具体实施过程中,具有剥离膜的掩膜板的制备方法如图3所示,其在形成光阻膜前,先在载板上形成剥离膜,然后在剥离膜上形成光阻膜;此外,在去除光阻膜前,先通过激光照射或加热使剥离膜与光阻膜分离,然后再进行其他步骤。In the above-mentioned embodiment, when removing the photoresist film 2, the multiple hierarchical structures before demolding need to be placed in the cleaning liquid. However, since the photoresist film 2 is clamped between the carrier 1, the reinforcing ribs 5 and the first vacuum-plated foil film 6, the contact surface between the photoresist film 2 and the cleaning liquid is small, resulting in a long soaking time and low production efficiency. In this regard, in a preferred embodiment, as shown in FIG3, in order to better expose the photoresist film 2, the carrier 1 is set as a transparent carrier 1, and a stripping film 10 is also provided between the carrier 1 and the photoresist film 2. The stripping film 10 can separate the carrier 1 from the photoresist film 2 under the action of heat or laser, and then the carrier 1 can be very conveniently removed from the surface of the photoresist film 2, so that a larger area of the surface of the photoresist film 2 is exposed. During soaking, the contact area between the photoresist film 2 and the cleaning liquid can be greatly increased, the cleaning time can be shortened, and the cleaning efficiency can be improved. In the specific implementation process, the preparation method of the mask plate with a stripping film is shown in Figure 3. Before forming the photoresist film, the stripping film is first formed on the carrier plate, and then the photoresist film is formed on the stripping film; in addition, before removing the photoresist film, the stripping film is first separated from the photoresist film by laser irradiation or heating, and then other steps are performed.
在一种较佳的实施例中,所述剥离膜10为非晶氮化镓膜、氮化铟锌膜或热剥离膜,通过激光剥离技术或热剥离技术,可实现将载板1与光阻膜2分离。具体的,所述热剥离膜为牌号为REVALPHA的膜,该牌号的膜在热作用下,可实现将载板1与光阻膜2分离。In a preferred embodiment, the stripping film 10 is an amorphous gallium nitride film, an indium zinc nitride film or a thermal stripping film, and the carrier 1 can be separated from the photoresist film 2 by laser stripping technology or thermal stripping technology. Specifically, the thermal stripping film is a film with the brand name REVALPHA, which can separate the carrier 1 from the photoresist film 2 under the action of heat.
此外,在前述实施例中,为了使掩膜片与掩膜框8绑定后,能处于较好的展开状态,在所述步骤S6中,所述掩膜框8在绑定前有经过冷却处理,即,将掩膜框8温度降低,使其进行冷缩,而在绑定后,再使掩膜框8恢复常温,在升温时框体具有一定的膨胀性,因此能使掩膜片处于张紧状态,完全展开,在后续使用时,能使蒸镀图案更为精准。In addition, in the aforementioned embodiment, in order to ensure that the mask sheet is in a better unfolded state after being bound to the mask frame 8, in the step S6, the mask frame 8 is cooled before being bound, that is, the temperature of the mask frame 8 is lowered to shrink it, and after binding, the mask frame 8 is restored to room temperature. When heated, the frame has a certain degree of expansion, so that the mask sheet can be in a tensioned state and fully unfolded, so that the vapor deposition pattern can be more precise when used later.
前述实施例所述的制备方法是通过清洗液清洗的方式将光阻膜与加强筋和第一真空镀箔膜分离,该方式耗时较长,但适合掩膜片厚度较薄的掩膜框的制备,而对于一些掩膜片厚度大于等于10μm的掩膜框的制备,还可采用更为简洁的制备方法制备得到。具体的,在另一种较佳的实施例中,采用另一种掩膜板制备方法,如图5所示,该制备方法的制备步骤与前述实施例的制备方法基本相同,区别在于:(1)在步骤S1中,采用透明载板作为载板,便于激光透过;(2)步骤S3为:在加强筋的表面涂覆一层有机透明胶膜11,该有机透明胶膜11为在特定波长或/和特定脉冲宽度的激光作用下可分解或熔融的胶膜,如PI膜、PP膜,并通过该有机透明胶膜将加强筋附着于光阻膜上,因此,无需磁板,即可将加强筋固定于光阻膜上;(3)步骤S5为:通过将激光对焦于有机透明胶膜11与加强筋接触的界面,以及光阻膜与第一真空镀箔膜接触的界面上,利用激光的作用,将有机透明胶膜及部分光阻膜分解或熔融,使得光阻膜与加强筋及第一真空镀箔膜分离,得到掩膜片组合。The preparation method described in the above embodiment is to separate the photoresist film from the reinforcing ribs and the first vacuum-plated foil film by cleaning with a cleaning liquid. This method is time-consuming, but is suitable for the preparation of mask frames with thinner mask sheets. For the preparation of mask frames with a mask sheet thickness greater than or equal to 10 μm, a simpler preparation method can be used. Specifically, in another preferred embodiment, another mask plate preparation method is adopted, as shown in FIG5 , the preparation steps of the preparation method are basically the same as those of the preparation method of the aforementioned embodiment, except that: (1) in step S1, a transparent carrier is used as the carrier to facilitate laser transmission; (2) step S3 is: a layer of organic transparent adhesive film 11 is coated on the surface of the reinforcing rib, the organic transparent adhesive film 11 is an adhesive film that can be decomposed or melted under the action of a laser of a specific wavelength or/and a specific pulse width, such as a PI film or a PP film, and the reinforcing rib is attached to the photoresist film through the organic transparent adhesive film, so that the reinforcing rib can be fixed to the photoresist film without a magnetic plate; (3) step S5 is: by focusing the laser on the interface where the organic transparent adhesive film 11 contacts the reinforcing rib, and on the interface where the photoresist film contacts the first vacuum-plated foil film, the organic transparent adhesive film and part of the photoresist film are decomposed or melted by the action of the laser, so that the photoresist film is separated from the reinforcing rib and the first vacuum-plated foil film, and a mask plate assembly is obtained.
在本实施例中,无需浸泡清洗,通过激光作用,即可非常快速的将有机透明胶膜及光阻膜与加强筋及第一真空镀箔膜分离,可大大缩短生产时间,提高生产效率,并且,在使加强筋附着于光阻膜上时,相较于磁板的吸附作用,通过有机透明胶膜的粘附,可使定位更为精准。In this embodiment, the organic transparent adhesive film and the photoresist film can be separated from the reinforcing ribs and the first vacuum-plated foil film very quickly through the action of laser without the need for immersion and cleaning, which can greatly shorten the production time and improve production efficiency. Moreover, when the reinforcing ribs are attached to the photoresist film, the positioning can be more precise through the adhesion of the organic transparent adhesive film compared to the adsorption effect of the magnetic plate.
本发明第二方面还提供一种掩膜板,该掩膜板采用如上所述制备方法制备得到,所述掩膜板包括掩膜框8和掩膜片组合9,所述掩膜片组合9焊接于掩膜框8上,所述掩膜片组合9包括加强筋5和掩膜片,所述掩膜片的厚度为0.1~30μm,优选为10~15μm,其设有呈扩口状的开口部,当其应用于OLED显示屏的制造时,可在基板上形成均匀的蒸镀膜。The second aspect of the present invention also provides a mask plate, which is prepared by the preparation method as described above, and the mask plate includes a mask frame 8 and a mask sheet assembly 9, and the mask sheet assembly 9 is welded to the mask frame 8. The mask sheet assembly 9 includes a reinforcing rib 5 and a mask sheet. The thickness of the mask sheet is 0.1 to 30 μm, preferably 10 to 15 μm, and is provided with a flared opening. When it is used in the manufacture of an OLED display screen, a uniform evaporated film can be formed on the substrate.
综上所述,本发明提供的掩膜板制备方法,通过具有倒梯形槽孔3的光阻膜2,可实现通过真空镀膜获得具有扩口状开口部的第一真空镀箔膜6,通过在光阻膜2上贴附加强筋5,可实现第一真空镀箔膜6在分离、转移、绑定时始终保持展开状态,并且能避免掩膜片起皱、变形、破裂,能更好的保护掩膜片。In summary, the mask plate preparation method provided by the present invention, through the photoresist film 2 with inverted trapezoidal grooves 3, can realize obtaining the first vacuum-coated foil film 6 with a flared opening through vacuum coating, and by attaching additional reinforcing ribs 5 on the photoresist film 2, the first vacuum-coated foil film 6 can always remain in an unfolded state during separation, transfer, and binding, and can prevent the mask sheet from wrinkling, deformation, and cracking, thereby better protecting the mask sheet.
在本发明实施方式的描述中,需要说明的是,术语“内”、“外”、“上”“下”、“左”、“右”等指示的方位或位置关系为基于附图所示的方位或位置关系,或者是该发明产品使用时惯常摆放的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”等仅用于区分描述,而不能理解为指示或暗示相对重要性。In the description of the embodiments of the present invention, it should be noted that the terms "inside", "outside", "upper", "lower", "left", "right", etc. indicate the orientation or positional relationship based on the orientation or positional relationship shown in the drawings, or the orientation or positional relationship in which the invented product is usually placed when in use, which is only for the convenience of describing the present invention and simplifying the description, and does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as limiting the present invention. In addition, the terms "first", "second", etc. are only used to distinguish the description, and cannot be understood as indicating or implying relative importance.
在本发明实施方式的描述中,还需要说明的是,除非另有明确的规定和限定,术语“设置”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the embodiments of the present invention, it is also necessary to explain that, unless otherwise clearly specified and limited, the term "disposed" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection, a direct connection, or an indirect connection through an intermediate medium, or it can be the internal communication of two elements. For ordinary technicians in this field, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.
可以理解的是,对本领域普通技术人员来说,可以根据本发明的技术方案及其发明构思加以等同替换或改变,而所有这些改变或替换都应属于本发明所附的权利要求的保护范围。It is understandable that those skilled in the art can make equivalent substitutions or changes based on the technical solution and inventive concept of the present invention, and all these changes or substitutions should fall within the protection scope of the claims attached to the present invention.
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