CN118518834B - A purification process monitoring system and method based on gas data identification - Google Patents
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Abstract
本发明涉及气体纯化监测技术领域,尤其涉及一种基于气体数据识别的纯化过程监测系统及方法,该方法的步骤包括:将待纯化气体导入纯化流程中,通过传感器实时采集气体含量信息;根据第一氧气含量信息和正常氧气含量范围信息计算氧气供给系数;根据氧气供给系数、第一杂质气体含量信息和理化环境信息计算催化氧化工艺指数;根据第二氧气含量信息和第二杂质气体含量信息计算脱氧吸附工艺指数;根据催化氧化工艺指数和脱氧吸附工艺指数计算气体纯化指数,并根据气体纯化指数对纯化过程进行实时监测。本发明通过气体纯化指数对气体纯化过程进行监测,在提高气体纯化速率的同时提升了纯化过程监测的及时性和准确性。
The present invention relates to the field of gas purification monitoring technology, and in particular to a purification process monitoring system and method based on gas data identification, the steps of which include: introducing the gas to be purified into the purification process, collecting gas content information in real time through a sensor; calculating the oxygen supply coefficient according to the first oxygen content information and the normal oxygen content range information; calculating the catalytic oxidation process index according to the oxygen supply coefficient, the first impurity gas content information and the physical and chemical environment information; calculating the deoxygenation adsorption process index according to the second oxygen content information and the second impurity gas content information; calculating the gas purification index according to the catalytic oxidation process index and the deoxygenation adsorption process index, and monitoring the purification process in real time according to the gas purification index. The present invention monitors the gas purification process through the gas purification index, which improves the timeliness and accuracy of the purification process monitoring while increasing the gas purification rate.
Description
技术领域Technical Field
本发明涉及气体纯化监测技术领域,尤其涉及一种基于气体数据识别的纯化过程监测系统及方法。The present invention relates to the technical field of gas purification monitoring, and in particular to a purification process monitoring system and method based on gas data identification.
背景技术Background Art
超高纯度气体是LED、太阳能电池、大规模集成电路等电子工业生产不可或缺的基础支撑性原材料,主要用作电子工业生产过程中的载气和保护气,其纯度对产品的质量和性能至关重要。Ultra-high purity gases are indispensable basic supporting raw materials for the production of electronic industries such as LEDs, solar cells, and large-scale integrated circuits. They are mainly used as carrier gases and protective gases in the production process of the electronic industry. Their purity is crucial to the quality and performance of the products.
气体纯化是利用化学或物理的方式将气体中的杂质组分分离,并将杂质组分降低到一定标准的技术,其中,化学方式是让杂质组分与纯化器中的催化剂发生可逆或不可逆的化学反应,固定杂质并让原料气顺利通过,从而达到纯化原料气的目的。Gas purification is a technology that uses chemical or physical methods to separate impurity components in the gas and reduce the impurity components to a certain standard. The chemical method is to allow the impurity components to undergo a reversible or irreversible chemical reaction with the catalyst in the purifier, fix the impurities and allow the raw gas to pass smoothly, thereby achieving the purpose of purifying the raw gas.
例如通过化学方式对氮气进行纯化的技术原理是:首先,通过催化氧化工艺流程对氮气中的、以及先进行脱除,利用贵金属催化剂使氮气中的、、与发生化学反应,使其反应生成和;然后,利用脱氧吸附工艺流程对氮气中的、和进行脱除,从而确保氮气在脱除杂质气体后达到级。For example, the technical principle of chemical nitrogen purification is: first, the nitrogen in the nitrogen is purified by catalytic oxidation process. , as well as First, remove the nitrogen using a precious metal catalyst. , , and A chemical reaction occurs, producing and Then, the deoxygenation adsorption process is used to remove , and Remove to ensure that the nitrogen reaches class.
催化剂是促进化学反应的关键因素,在催化氧化的过程中,氮气中的氧含量会存在波动,这种波动在正常范围内不会对催化剂造成明显的影响。然而,如果发生长时间的脱氧状况,即氧含量持续偏低,会降低催化剂的活性、增加副反应的发生,严重影响最终的反应速率和转化效率。现有的气体纯化过程监测方法忽略了反应过程中氧含量的波动性,使得催化氧化速率无法达到最大化,降低了气体的纯化速率。Catalysts are key factors in promoting chemical reactions. During the catalytic oxidation process, the oxygen content in nitrogen will fluctuate. This fluctuation will not have a significant impact on the catalyst within the normal range. However, if deoxygenation occurs for a long time, that is, the oxygen content continues to be low, it will reduce the activity of the catalyst, increase the occurrence of side reactions, and seriously affect the final reaction rate and conversion efficiency. The existing gas purification process monitoring method ignores the volatility of oxygen content during the reaction, making it impossible to maximize the catalytic oxidation rate and reducing the gas purification rate.
发明内容Summary of the invention
为了克服现有技术存在的缺陷与不足,本发明提供一种基于气体数据识别的纯化过程监测系统及方法,通过气体纯化指数对气体纯化过程进行监测,在提高气体纯化速率的同时提升了气体纯化过程监测的及时性和准确性。In order to overcome the defects and shortcomings of the prior art, the present invention provides a purification process monitoring system and method based on gas data identification, which monitors the gas purification process through the gas purification index, thereby improving the timeliness and accuracy of gas purification process monitoring while increasing the gas purification rate.
为了达到上述目的,本发明采用以下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:
本发明提供一种基于气体数据识别的纯化过程监测方法,包括下述步骤:The present invention provides a purification process monitoring method based on gas data identification, comprising the following steps:
S1、将待纯化气体导入纯化流程中,通过传感器实时采集催化氧化工艺流程中的第一氧气含量信息、第一杂质气体含量信息和理化环境信息,同时采集脱氧吸附工艺流程的第二氧气含量信息和第二杂质气体含量信息,同时获取催化氧化工艺流程中的正常氧气含量范围信息;S1. Introduce the gas to be purified into the purification process, collect the first oxygen content information, the first impurity gas content information and the physical and chemical environment information in the catalytic oxidation process in real time through the sensor, collect the second oxygen content information and the second impurity gas content information of the deoxygenation adsorption process, and obtain the normal oxygen content range information in the catalytic oxidation process;
S2、根据所述第一氧气含量信息和所述正常氧气含量范围信息计算氧气供给系数;S2. calculating an oxygen supply coefficient according to the first oxygen content information and the normal oxygen content range information;
S3、根据所述氧气供给系数、所述第一杂质气体含量信息和所述理化环境信息计算催化氧化工艺指数;S3, calculating a catalytic oxidation process index according to the oxygen supply coefficient, the first impurity gas content information and the physical and chemical environment information;
S4、根据所述第二氧气含量信息和所述第二杂质气体含量信息计算脱氧吸附工艺指数;S4, calculating a deoxygenation adsorption process index according to the second oxygen content information and the second impurity gas content information;
S5、根据所述催化氧化工艺指数和所述脱氧吸附工艺指数计算气体纯化指数,并根据所述气体纯化指数对纯化过程进行实时监测。S5. Calculate a gas purification index according to the catalytic oxidation process index and the deoxygenation adsorption process index, and monitor the purification process in real time according to the gas purification index.
作为优选的技术方案,所述步骤S2包括以下具体步骤:As a preferred technical solution, step S2 includes the following specific steps:
S21、获取采集到的催化氧化工艺流程中的所述第一氧气含量信息,同时获取催化氧化工艺流程中的所述正常氧气含量范围信息;S21, acquiring the first oxygen content information in the collected catalytic oxidation process flow, and simultaneously acquiring the normal oxygen content range information in the catalytic oxidation process flow;
S22、将所述第一氧气含量信息和所述正常氧气含量范围信息代入氧气供给系数计算公式中计算所述氧气供给系数,所述氧气供给系数计算公式为:;S22, substituting the first oxygen content information and the normal oxygen content range information into an oxygen supply coefficient calculation formula to calculate the oxygen supply coefficient, the oxygen supply coefficient calculation formula is: ;
式中表示时刻的第一氧气含量信息,表示正常氧气含量范围信息的最小值,表示正常氧气含量范围信息的最大值,表示监测周期的时长,表示氧气供给系数。In the formula express The first oxygen content information at the moment, Indicates the minimum value of the normal oxygen content range information, Indicates the maximum value of the normal oxygen content range information, Indicates the duration of the monitoring cycle. Indicates the oxygen supply coefficient.
作为优选的技术方案,所述步骤S3包括以下具体步骤:As a preferred technical solution, step S3 includes the following specific steps:
S31、获取计算得到的所述氧气供给系数,同时获取采集到的催化氧化工艺流程中的所述第一杂质气体含量信息和所述理化环境信息,所述理化环境信息包括温度信息、压力信息、正常温度范围信息和正常压力范围信息;S31, obtaining the calculated oxygen supply coefficient, and simultaneously obtaining the first impurity gas content information and the physical and chemical environment information collected in the catalytic oxidation process, wherein the physical and chemical environment information includes temperature information, pressure information, normal temperature range information, and normal pressure range information;
S32、将所述理化环境信息代入理化环境系数计算公式中计算理化环境系数;S32, substituting the physical and chemical environment information into a physical and chemical environment coefficient calculation formula to calculate the physical and chemical environment coefficient;
S33、将所述氧气供给系数、所述理化环境系数和所述第一杂质气体含量信息代入催化氧化工艺指数计算公式中计算所述催化氧化工艺指数,所述催化氧化工艺指数计算公式为:;S33, substituting the oxygen supply coefficient, the physical and chemical environment coefficient and the first impurity gas content information into a catalytic oxidation process index calculation formula to calculate the catalytic oxidation process index, the catalytic oxidation process index calculation formula is: ;
式中表示氧气供给系数,表示理化环境系数,表示第一杂质气体含量信息中的催化氧化前杂质气体含量信息,表示第一杂质气体含量信息中的催化氧化后杂质气体含量信息,表示调节因子,表示催化氧化工艺指数。In the formula represents the oxygen supply coefficient, It represents the physical and chemical environmental coefficient. represents the impurity gas content information before catalytic oxidation in the first impurity gas content information, represents the impurity gas content information after catalytic oxidation in the first impurity gas content information, represents the adjustment factor, Represents the catalytic oxidation process index.
作为优选的技术方案,所述步骤S32中的理化环境系数计算公式为:As a preferred technical solution, the calculation formula of the physical and chemical environment coefficient in step S32 is:
; ;
式中表示时刻的温度信息,表示正常温度范围信息的最小值,表示正常温度范围信息的最大值,表示时刻的压力信息,表示正常压力范围信息的最小值,表示正常压力范围信息的最大值,表示监测周期的时长,表示取最大值,表示理化环境系数。In the formula express Temperature information at the moment, Indicates the minimum value of the normal temperature range information, Indicates the maximum value of the normal temperature range information, express Pressure information at all times, Indicates the minimum value of the normal pressure range information, Indicates the maximum value of the normal pressure range information, Indicates the duration of the monitoring cycle. Indicates taking the maximum value, Represents the physical and chemical environmental coefficient.
作为优选的技术方案,所述步骤S4包括以下具体步骤:As a preferred technical solution, step S4 includes the following specific steps:
S41、获取采集到的脱氧吸附工艺流程中的所述第二氧气含量信息和所述第二杂质气体含量信息;S41, acquiring the second oxygen content information and the second impurity gas content information collected in the deoxygenation adsorption process flow;
S42、将所述第二氧气含量信息和所述第二杂质气体含量信息代入脱氧吸附工艺指数计算公式中计算所述脱氧吸附工艺指数,所述脱氧吸附工艺指数计算公式为:;S42, substituting the second oxygen content information and the second impurity gas content information into a deoxygenation adsorption process index calculation formula to calculate the deoxygenation adsorption process index, the deoxygenation adsorption process index calculation formula is: ;
式中表示第二氧气含量信息中的脱氧吸附前氧气含量信息,表示第二氧气含量信息中的脱氧吸附后氧气含量信息,表示第二杂质气体含量信息中的脱氧吸附前杂质气体含量信息,表示第二杂质气体含量信息中的脱氧吸附后杂质气体含量信息,表示氧气脱除权重,表示杂质气体脱除权重,表示脱氧吸附工艺指数。In the formula represents the oxygen content information before deoxygenation adsorption in the second oxygen content information, represents the oxygen content information after deoxygenation adsorption in the second oxygen content information, represents the impurity gas content information before deoxygenation adsorption in the second impurity gas content information, represents the impurity gas content information after deoxygenation adsorption in the second impurity gas content information, represents the oxygen removal weight, represents the impurity gas removal weight, Represents the deoxygenation adsorption process index.
作为优选的技术方案,所述步骤S5中计算气体纯化指数包括以下具体步骤:As a preferred technical solution, the calculation of the gas purification index in step S5 includes the following specific steps:
S51、获取计算得到的所述催化氧化工艺指数和所述脱氧吸附工艺指数;S51, obtaining the calculated catalytic oxidation process index and the deoxidation adsorption process index;
S52、将所述催化氧化工艺指数和所述脱氧吸附工艺指数代入气体纯化指数计算公式中计算所述气体纯化指数,所述气体纯化指数计算公式为:S52, substituting the catalytic oxidation process index and the deoxygenation adsorption process index into a gas purification index calculation formula to calculate the gas purification index, the gas purification index calculation formula is:
; ;
式中表示催化氧化工艺指数,表示脱氧吸附工艺指数,表示催化氧化工艺占比系数,表示脱氧吸附工艺占比系数,表示气体纯化指数。In the formula represents the catalytic oxidation process index, represents the deoxygenation adsorption process index, represents the catalytic oxidation process ratio, represents the deoxygenation adsorption process ratio, Indicates the gas purification index.
作为优选的技术方案,所述步骤S5中根据气体纯化指数对纯化过程进行实时监测包括以下具体步骤:As a preferred technical solution, the real-time monitoring of the purification process according to the gas purification index in step S5 includes the following specific steps:
S53、当所述气体纯化指数大于等于预设气体纯化阈值时,维持当前纯化工艺流程;S53, when the gas purification index is greater than or equal to a preset gas purification threshold, maintaining the current purification process flow;
S54、当所述气体纯化指数小于预设气体纯化阈值时,发出纯化工艺流程预警并将所述氧气供给系数、所述理化环境系数、所述催化氧化工艺指数和所述脱氧吸附工艺指数发送至运维人员。S54. When the gas purification index is less than a preset gas purification threshold, a purification process warning is issued and the oxygen supply coefficient, the physical and chemical environment coefficient, the catalytic oxidation process index and the deoxygenation adsorption process index are sent to operation and maintenance personnel.
在此需要说明的是,这里的调节因子、氧气脱除权重、杂质气体脱除权重、催化氧化工艺占比系数、脱氧吸附工艺占比系数和预设气体纯化阈值的取值方式为:采集5000组第一氧气含量信息、第一杂质气体含量信息、理化环境信息、第二氧气含量信息、第二杂质气体含量信息和正常氧气含量范围信息,对气体纯化过程是否满足生产要求进行区分,将第一氧气含量信息、第一杂质气体含量信息、理化环境信息、第二氧气含量信息、第二杂质气体含量信息和正常氧气含量范围信息代入气体纯化指数计算公式中进行计算,将计算得到的气体纯化指数和区分结果同时导入拟合软件中,输出符合区分结果区分准确率的最优调节因子、氧气脱除权重、杂质气体脱除权重、催化氧化工艺占比系数、脱氧吸附工艺占比系数和预设气体纯化阈值。It should be noted here that the adjustment factor, oxygen removal weight, impurity gas removal weight, catalytic oxidation process ratio, deoxygenation adsorption process ratio and preset gas purification threshold are obtained as follows: 5000 sets of first oxygen content information, first impurity gas content information, physical and chemical environment information, second oxygen content information, second impurity gas content information and normal oxygen content range information are collected to distinguish whether the gas purification process meets the production requirements, and the first oxygen content information, first impurity gas content information, physical and chemical environment information, second oxygen content information, second impurity gas content information and normal oxygen content range information are substituted into the gas purification index calculation formula for calculation, and the calculated gas purification index and the distinction result are simultaneously imported into the fitting software to output the optimal adjustment factor, oxygen removal weight, impurity gas removal weight, catalytic oxidation process ratio, deoxygenation adsorption process ratio and preset gas purification threshold that meet the distinction accuracy of the distinction result.
本发明还提供一种基于气体数据识别的纯化过程监测系统,包括:The present invention also provides a purification process monitoring system based on gas data identification, comprising:
信息采集模块,用于将待纯化气体导入纯化流程中,通过传感器实时采集催化氧化工艺流程中的第一氧气含量信息、第一杂质气体含量信息和理化环境信息,同时采集脱氧吸附工艺流程的第二氧气含量信息和第二杂质气体含量信息,同时获取催化氧化工艺流程中的正常氧气含量范围信息;An information collection module is used to introduce the gas to be purified into the purification process, collect the first oxygen content information, the first impurity gas content information and the physical and chemical environment information in the catalytic oxidation process in real time through the sensor, collect the second oxygen content information and the second impurity gas content information of the deoxygenation adsorption process, and obtain the normal oxygen content range information in the catalytic oxidation process;
氧气供给系数计算模块,用于根据所述第一氧气含量信息和所述正常氧气含量范围信息计算氧气供给系数;an oxygen supply coefficient calculation module, configured to calculate an oxygen supply coefficient according to the first oxygen content information and the normal oxygen content range information;
催化氧化工艺指数计算模块,用于根据所述氧气供给系数、所述第一杂质气体含量信息和所述理化环境信息计算催化氧化工艺指数;A catalytic oxidation process index calculation module, used to calculate a catalytic oxidation process index according to the oxygen supply coefficient, the first impurity gas content information and the physical and chemical environment information;
脱氧吸附工艺指数计算模块,用于根据所述第二氧气含量信息和所述第二杂质气体含量信息计算脱氧吸附工艺指数;a deoxygenation adsorption process index calculation module, configured to calculate a deoxygenation adsorption process index according to the second oxygen content information and the second impurity gas content information;
气体纯化指数计算模块,用于根据所述催化氧化工艺指数和所述脱氧吸附工艺指数计算气体纯化指数,并根据所述气体纯化指数对纯化过程进行实时监测;A gas purification index calculation module, used to calculate the gas purification index according to the catalytic oxidation process index and the deoxygenation adsorption process index, and to monitor the purification process in real time according to the gas purification index;
控制模块,用于控制所述信息采集模块、所述氧气供给系数计算模块、所述催化氧化工艺指数计算模块、所述脱氧吸附工艺指数计算模块和所述气体纯化指数计算模块的运行。A control module is used to control the operation of the information acquisition module, the oxygen supply coefficient calculation module, the catalytic oxidation process index calculation module, the deoxygenation adsorption process index calculation module and the gas purification index calculation module.
本发明的一种电子设备,包括:处理器和存储器,其中,所述存储器中存储有可供处理器调用的计算机程序,所述处理器通过调用所述存储器中存储的计算机程序,执行一种基于气体数据识别的纯化过程监测方法。An electronic device of the present invention comprises: a processor and a memory, wherein the memory stores a computer program that can be called by the processor, and the processor executes a purification process monitoring method based on gas data identification by calling the computer program stored in the memory.
本发明的一种计算机可读存储介质,储存有指令,当所述指令在计算机上运行时,使得计算机执行一种基于气体数据识别的纯化过程监测方法。A computer-readable storage medium of the present invention stores instructions, and when the instructions are executed on a computer, the computer is enabled to execute a purification process monitoring method based on gas data identification.
本发明与现有技术相比,具有如下优点和有益效果:Compared with the prior art, the present invention has the following advantages and beneficial effects:
本发明通过实时监测催化氧化和脱氧吸附两个工艺流程中的氧气含量和杂质气体含量,分别计算催化氧化工艺指数和脱氧吸附工艺指数,通过催化氧化工艺指数量化了氧气含量对催化氧化效率的影响程度,使催化氧化效率最大化,提升了气体纯化速率;同时,通过脱氧吸附工艺指数量化了脱氧吸附工艺对氧气和杂质气体的去除效率,最后综合上述两个指数计算气体纯化指数,并根据气体纯化指数对纯化过程进行实时监测,提升了气体纯化过程监测的及时性和准确性。The present invention monitors the oxygen content and impurity gas content in the two process flows of catalytic oxidation and deoxygenation adsorption in real time, calculates the catalytic oxidation process index and the deoxygenation adsorption process index respectively, and quantifies the influence of the oxygen content on the catalytic oxidation efficiency through the catalytic oxidation process index, thereby maximizing the catalytic oxidation efficiency and improving the gas purification rate; at the same time, quantifies the removal efficiency of the deoxygenation adsorption process for oxygen and impurity gases through the deoxygenation adsorption process index, finally calculates the gas purification index by combining the above two indices, and monitors the purification process in real time according to the gas purification index, thereby improving the timeliness and accuracy of the gas purification process monitoring.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
通过阅读参照以下附图所作的对非限制性实施例的详细描述,本发明的其它特征、目的和优点将会变得更明显:Other features, objects and advantages of the present invention will become more apparent from the detailed description of non-limiting embodiments made with reference to the following drawings:
图1为本发明的一种基于气体数据识别的纯化过程监测方法的整体流程示意图;FIG1 is a schematic diagram of the overall process of a purification process monitoring method based on gas data recognition of the present invention;
图2为本发明的一种基于气体数据识别的纯化过程监测方法中所述纯化流程示意图;FIG2 is a schematic diagram of a purification process in a purification process monitoring method based on gas data recognition according to the present invention;
图3为本发明的一种基于气体数据识别的纯化过程监测系统的结构示意图。FIG. 3 is a schematic diagram of the structure of a purification process monitoring system based on gas data recognition according to the present invention.
具体实施方式DETAILED DESCRIPTION
下面通过附图以及具体实施例对本发明技术方案做详细地说明,应当理解本发明实施例以及实施例中的具体特征是对本发明技术方案的详细的说明,而不是对本发明技术方案的限定,在不冲突的情况下,本发明实施例以及实施例中的技术特征可以相互组合。The technical solution of the present invention is described in detail below through the accompanying drawings and specific embodiments. It should be understood that the embodiments of the present invention and the specific features in the embodiments are detailed descriptions of the technical solution of the present invention, rather than limitations on the technical solution of the present invention. The embodiments of the present invention and the technical features in the embodiments may be combined with each other unless there is a conflict.
实施例1Example 1
如图1所示,本实施例提供一种基于气体数据识别的纯化过程监测方法,具体包括下述步骤:As shown in FIG1 , this embodiment provides a purification process monitoring method based on gas data recognition, which specifically includes the following steps:
S1:将待纯化气体导入纯化流程中,通过传感器实时采集催化氧化工艺流程中的第一氧气含量信息、第一杂质气体含量信息和理化环境信息,同时采集脱氧吸附工艺流程的第二氧气含量信息和第二杂质气体含量信息,同时获取催化氧化工艺流程中的正常氧气含量范围信息;S1: introducing the gas to be purified into the purification process, collecting the first oxygen content information, the first impurity gas content information and the physical and chemical environment information in the catalytic oxidation process in real time through the sensor, collecting the second oxygen content information and the second impurity gas content information of the deoxygenation adsorption process, and obtaining the normal oxygen content range information in the catalytic oxidation process;
如图2所示,气体纯化流程包括催化氧化工艺流程和脱氧吸附工艺流程,首先,将待纯化气体导入催化反应器中进行催化氧化反应,然后,反应完成后的气体将进入脱氧吸附工艺流程,脱氧吸附工艺流程由两台脱氧反应器和相应切换阀门组成,用于脱除氧气和杂质气体,最终得到纯化气体,以氮气纯化为例,催化氧化工艺流程用于转化脱除氮气中的、和,催化氧化流程的反应原理为:,其中,cat表示催化剂,表示加热,脱氧吸附工艺流程用于脱除氮气中的、和,最终得到高纯度氮气。As shown in Figure 2, the gas purification process includes a catalytic oxidation process and a deoxygenation adsorption process. First, the gas to be purified is introduced into a catalytic reactor for catalytic oxidation reaction. Then, the gas after the reaction is completed will enter the deoxygenation adsorption process. The deoxygenation adsorption process consists of two deoxygenation reactors and corresponding switching valves to remove oxygen and impurity gases to finally obtain purified gas. Taking nitrogen purification as an example, the catalytic oxidation process is used to convert and remove nitrogen. , and , the reaction principle of the catalytic oxidation process is: , where cat represents a catalyst, Indicates heating, deoxygenation adsorption process is used to remove nitrogen , and , and finally obtain high-purity nitrogen.
S2:根据第一氧气含量信息和正常氧气含量范围信息计算氧气供给系数;S2: calculating an oxygen supply coefficient according to the first oxygen content information and the normal oxygen content range information;
氧含量的控制对于催化氧化工艺流程至关重要,氧含量过低会导致催化剂失活、副反应增加和积碳现象,而氧含量过高则能够引发催化剂烧结,从而降低其比表面积和活性,最终都会导致反应速率和转化效率下降,因此,保持氧含量在正常范围内,对于确保催化氧化工艺流程的高效安全运行具有重要意义,计算氧气供给系数的具体步骤包括:The control of oxygen content is crucial for the catalytic oxidation process. Too low oxygen content will lead to catalyst deactivation, increased side reactions and carbon deposition, while too high oxygen content can cause catalyst sintering, thereby reducing its specific surface area and activity, which will eventually lead to a decrease in reaction rate and conversion efficiency. Therefore, keeping the oxygen content within the normal range is of great significance to ensure the efficient and safe operation of the catalytic oxidation process. The specific steps for calculating the oxygen supply coefficient include:
S21、获取采集到的催化氧化工艺流程中的第一氧气含量信息,同时获取催化氧化工艺流程中的正常氧气含量范围信息;S21, obtaining the first oxygen content information collected in the catalytic oxidation process, and simultaneously obtaining the normal oxygen content range information in the catalytic oxidation process;
S22、将第一氧气含量信息和正常氧气含量范围信息代入氧气供给系数计算公式中计算氧气供给系数,氧气供给系数计算公式为:;S22, substituting the first oxygen content information and the normal oxygen content range information into the oxygen supply coefficient calculation formula to calculate the oxygen supply coefficient, the oxygen supply coefficient calculation formula is: ;
式中表示时刻的第一氧气含量信息,表示正常氧气含量范围信息的最小值,表示正常氧气含量范围信息的最大值,表示监测周期的时长,表示氧气供给系数。In the formula express The first oxygen content information at the moment, Indicates the minimum value of the normal oxygen content range information, Indicates the maximum value of the normal oxygen content range information, Indicates the duration of the monitoring cycle. Indicates the oxygen supply coefficient.
S3:根据氧气供给系数、第一杂质气体含量信息和理化环境信息计算催化氧化工艺指数;S3: calculating a catalytic oxidation process index according to the oxygen supply coefficient, the first impurity gas content information and the physical and chemical environment information;
温度和压力是催化反应的重要条件,适宜的温度和压力能够有效提高反应速率,通过理化环境信息计算理化环境系数,量化催化氧化工艺流程中温度和压力的适宜程度,以确保催化氧化过程在最佳条件下进行;杂质气体去除效率则直接反映了催化氧化工艺的核心效果,即对杂质气体的脱除能力,高催化氧化工艺指数表明氧气供给合理、理化环境适宜、杂质气体去除效率高,计算催化氧化工艺指数的具体步骤包括:Temperature and pressure are important conditions for catalytic reactions. Appropriate temperature and pressure can effectively increase the reaction rate. The physical and chemical environmental coefficient is calculated through physical and chemical environmental information to quantify the suitability of temperature and pressure in the catalytic oxidation process to ensure that the catalytic oxidation process is carried out under optimal conditions. The impurity gas removal efficiency directly reflects the core effect of the catalytic oxidation process, that is, the ability to remove impurity gases. A high catalytic oxidation process index indicates that the oxygen supply is reasonable, the physical and chemical environment is suitable, and the impurity gas removal efficiency is high. The specific steps for calculating the catalytic oxidation process index include:
S31、获取计算得到的氧气供给系数,同时获取采集到的催化氧化工艺流程中的第一杂质气体含量信息和理化环境信息,理化环境信息包括温度信息、压力信息、正常温度范围信息和正常压力范围信息;S31, obtaining the calculated oxygen supply coefficient, and simultaneously obtaining the first impurity gas content information and physical and chemical environment information collected in the catalytic oxidation process, the physical and chemical environment information including temperature information, pressure information, normal temperature range information and normal pressure range information;
S32、将理化环境信息代入理化环境系数计算公式中计算理化环境系数,理化环境系数计算公式为:;S32. Substitute the physical and chemical environment information into the physical and chemical environment coefficient calculation formula to calculate the physical and chemical environment coefficient. The physical and chemical environment coefficient calculation formula is: ;
式中表示时刻的温度信息,表示正常温度范围信息的最小值,表示正常温度范围信息的最大值,表示时刻的压力信息,表示正常压力范围信息的最小值,表示正常压力范围信息的最大值,表示监测周期的时长,表示取最大值,表示理化环境系数。In the formula express Temperature information at the moment, Indicates the minimum value of the normal temperature range information, Indicates the maximum value of the normal temperature range information, express Pressure information at all times, Indicates the minimum value of the normal pressure range information, Indicates the maximum value of the normal pressure range information, Indicates the duration of the monitoring cycle. Indicates taking the maximum value, Represents the physical and chemical environmental coefficient.
S33、将氧气供给系数、理化环境系数和第一杂质气体含量信息代入催化氧化工艺指数计算公式中计算催化氧化工艺指数,催化氧化工艺指数计算公式为:;S33, substituting the oxygen supply coefficient, the physical and chemical environment coefficient and the first impurity gas content information into the catalytic oxidation process index calculation formula to calculate the catalytic oxidation process index, the catalytic oxidation process index calculation formula is: ;
式中表示氧气供给系数,表示理化环境系数,表示第一杂质气体含量信息中的催化氧化前杂质气体含量信息,表示第一杂质气体含量信息中的催化氧化后杂质气体含量信息,表示调节因子,表示催化氧化工艺指数。In the formula represents the oxygen supply coefficient, It represents the physical and chemical environmental coefficient. represents the impurity gas content information before catalytic oxidation in the first impurity gas content information, represents the impurity gas content information after catalytic oxidation in the first impurity gas content information, represents the adjustment factor, Represents the catalytic oxidation process index.
S4:根据第二氧气含量信息和第二杂质气体含量信息计算脱氧吸附工艺指数;S4: calculating a deoxygenation adsorption process index according to the second oxygen content information and the second impurity gas content information;
脱氧吸附工艺是气体纯化过程中的关键步骤,其主要目的是降低气体中的氧气含量和杂质气体含量,以提升气体纯度,通过综合考虑氧气含量和杂质气体含量的变化,以评估脱氧吸附工艺对气体纯化的效果,计算脱氧吸附工艺指数的具体步骤包括:The deoxygenation adsorption process is a key step in the gas purification process. Its main purpose is to reduce the oxygen content and impurity gas content in the gas to improve the gas purity. By comprehensively considering the changes in oxygen content and impurity gas content, the effect of the deoxygenation adsorption process on gas purification is evaluated. The specific steps for calculating the deoxygenation adsorption process index include:
S41、获取采集到的脱氧吸附工艺流程中的第二氧气含量信息和第二杂质气体含量信息;S41, obtaining the second oxygen content information and the second impurity gas content information collected in the deoxygenation adsorption process flow;
S42、将第二氧气含量信息和第二杂质气体含量信息代入脱氧吸附工艺指数计算公式中计算脱氧吸附工艺指数,脱氧吸附工艺指数计算公式为:;S42, substituting the second oxygen content information and the second impurity gas content information into the deoxygenation adsorption process index calculation formula to calculate the deoxygenation adsorption process index. The deoxygenation adsorption process index calculation formula is: ;
式中表示第二氧气含量信息中的脱氧吸附前氧气含量信息,表示第二氧气含量信息中的脱氧吸附后氧气含量信息,表示第二杂质气体含量信息中的脱氧吸附前杂质气体含量信息,表示第二杂质气体含量信息中的脱氧吸附后杂质气体含量信息,表示氧气脱除权重,表示杂质气体脱除权重,表示脱氧吸附工艺指数。In the formula represents the oxygen content information before deoxygenation adsorption in the second oxygen content information, represents the oxygen content information after deoxygenation adsorption in the second oxygen content information, represents the impurity gas content information before deoxygenation adsorption in the second impurity gas content information, represents the impurity gas content information after deoxygenation adsorption in the second impurity gas content information, represents the oxygen removal weight, represents the impurity gas removal weight, Represents the deoxygenation adsorption process index.
S5:根据催化氧化工艺指数和脱氧吸附工艺指数计算气体纯化指数,并根据气体纯化指数对纯化过程进行实时监测;S5: calculating a gas purification index according to the catalytic oxidation process index and the deoxygenation adsorption process index, and monitoring the purification process in real time according to the gas purification index;
综合催化氧化工艺指数和脱氧吸附工艺指数得到气体纯化指数,气体纯化指数反映了整个气体纯化过程从初始步骤到最终得到纯化气体整个流程的气体纯化效果,计算气体纯化指数包括以下具体步骤:The gas purification index is obtained by combining the catalytic oxidation process index and the deoxygenation adsorption process index. The gas purification index reflects the gas purification effect of the entire gas purification process from the initial step to the final purified gas. The calculation of the gas purification index includes the following specific steps:
S51、获取计算得到的催化氧化工艺指数和脱氧吸附工艺指数;S51, obtaining the calculated catalytic oxidation process index and deoxidation adsorption process index;
S52、将催化氧化工艺指数和脱氧吸附工艺指数代入气体纯化指数计算公式中计算气体纯化指数,气体纯化指数计算公式为:;S52. Substituting the catalytic oxidation process index and the deoxygenation adsorption process index into the gas purification index calculation formula to calculate the gas purification index. The gas purification index calculation formula is: ;
式中表示催化氧化工艺指数,表示脱氧吸附工艺指数,表示催化氧化工艺占比系数,表示脱氧吸附工艺占比系数,表示气体纯化指数;In the formula represents the catalytic oxidation process index, represents the deoxygenation adsorption process index, represents the catalytic oxidation process ratio, represents the deoxygenation adsorption process ratio, Indicates the gas purification index;
通过气体纯化指数对纯化过程进行实时监测,能够及时发现并处理纯化过程中出现的异常情况,帮助运维人员快速定位和排查问题工艺流程,从而减少停机时间,提升气体纯化生产效率,根据气体纯化指数对纯化过程进行实时监测包括以下具体步骤:Real-time monitoring of the purification process through the gas purification index can timely discover and handle abnormal situations in the purification process, help operation and maintenance personnel quickly locate and troubleshoot problematic process flows, thereby reducing downtime and improving gas purification production efficiency. Real-time monitoring of the purification process based on the gas purification index includes the following specific steps:
S53、当气体纯化指数大于等于预设气体纯化阈值时,维持当前纯化工艺流程;S53, when the gas purification index is greater than or equal to the preset gas purification threshold, maintaining the current purification process flow;
S54、当气体纯化指数小于预设气体纯化阈值时,发出纯化工艺流程预警并将氧气供给系数、理化环境系数、催化氧化工艺指数和脱氧吸附工艺指数发送至运维人员,用于快速定位和排查问题工艺流程。S54. When the gas purification index is less than the preset gas purification threshold, a purification process warning is issued and the oxygen supply coefficient, physical and chemical environment coefficient, catalytic oxidation process index and deoxygenation adsorption process index are sent to the operation and maintenance personnel for rapid location and troubleshooting of the problem process.
实施例2Example 2
如图3所示,本实施例提供一种基于气体数据识别的纯化过程监测系统,包括:As shown in FIG3 , this embodiment provides a purification process monitoring system based on gas data recognition, including:
信息采集模块,用于将待纯化气体导入纯化流程中,通过传感器实时采集催化氧化工艺流程中的第一氧气含量信息、第一杂质气体含量信息和理化环境信息,同时采集脱氧吸附工艺流程的第二氧气含量信息和第二杂质气体含量信息,同时获取催化氧化工艺流程中的正常氧气含量范围信息;An information collection module is used to introduce the gas to be purified into the purification process, collect the first oxygen content information, the first impurity gas content information and the physical and chemical environment information in the catalytic oxidation process in real time through the sensor, collect the second oxygen content information and the second impurity gas content information of the deoxygenation adsorption process, and obtain the normal oxygen content range information in the catalytic oxidation process;
氧气供给系数计算模块,用于根据第一氧气含量信息和正常氧气含量范围信息计算氧气供给系数;An oxygen supply coefficient calculation module, used to calculate the oxygen supply coefficient according to the first oxygen content information and the normal oxygen content range information;
催化氧化工艺指数计算模块,用于根据氧气供给系数、第一杂质气体含量信息和理化环境信息计算催化氧化工艺指数;A catalytic oxidation process index calculation module, used to calculate the catalytic oxidation process index according to the oxygen supply coefficient, the first impurity gas content information and the physical and chemical environment information;
脱氧吸附工艺指数计算模块,用于根据第二氧气含量信息和第二杂质气体含量信息计算脱氧吸附工艺指数;A deoxygenation adsorption process index calculation module, used to calculate the deoxygenation adsorption process index according to the second oxygen content information and the second impurity gas content information;
气体纯化指数计算模块,用于根据催化氧化工艺指数和脱氧吸附工艺指数计算气体纯化指数,并根据气体纯化指数对纯化过程进行实时监测;A gas purification index calculation module is used to calculate the gas purification index according to the catalytic oxidation process index and the deoxygenation adsorption process index, and to monitor the purification process in real time according to the gas purification index;
控制模块,用于控制信息采集模块、氧气供给系数计算模块、催化氧化工艺指数计算模块、脱氧吸附工艺指数计算模块和气体纯化指数计算模块的运行。The control module is used to control the operation of the information acquisition module, the oxygen supply coefficient calculation module, the catalytic oxidation process index calculation module, the deoxygenation adsorption process index calculation module and the gas purification index calculation module.
在本实施例中,氧气供给系数计算模块用于根据第一氧气含量信息和正常氧气含量范围信息计算氧气供给系数,计算氧气供给系数的具体步骤包括:In this embodiment, the oxygen supply coefficient calculation module is used to calculate the oxygen supply coefficient according to the first oxygen content information and the normal oxygen content range information. The specific steps of calculating the oxygen supply coefficient include:
获取采集到的催化氧化工艺流程中的第一氧气含量信息,同时获取催化氧化工艺流程中的正常氧气含量范围信息;Acquire the first oxygen content information collected in the catalytic oxidation process, and simultaneously acquire the normal oxygen content range information in the catalytic oxidation process;
将第一氧气含量信息和正常氧气含量范围信息代入氧气供给系数计算公式中计算氧气供给系数,氧气供给系数计算公式为:;Substitute the first oxygen content information and the normal oxygen content range information into the oxygen supply coefficient calculation formula to calculate the oxygen supply coefficient. The oxygen supply coefficient calculation formula is: ;
式中表示时刻的第一氧气含量信息,表示正常氧气含量范围信息的最小值,表示正常氧气含量范围信息的最大值,表示监测周期的时长,表示氧气供给系数。In the formula express The first oxygen content information at the moment, Indicates the minimum value of the normal oxygen content range information, Indicates the maximum value of the normal oxygen content range information, Indicates the duration of the monitoring cycle. Indicates the oxygen supply coefficient.
在本实施例中,催化氧化工艺指数计算模块用于根据氧气供给系数、第一杂质气体含量信息和理化环境信息计算催化氧化工艺指数,计算催化氧化工艺指数的具体步骤包括:In this embodiment, the catalytic oxidation process index calculation module is used to calculate the catalytic oxidation process index according to the oxygen supply coefficient, the first impurity gas content information and the physical and chemical environment information. The specific steps of calculating the catalytic oxidation process index include:
获取计算得到的氧气供给系数,同时获取采集到的催化氧化工艺流程中的第一杂质气体含量信息和理化环境信息,理化环境信息包括温度信息、压力信息、正常温度范围信息和正常压力范围信息;Obtaining the calculated oxygen supply coefficient, and simultaneously obtaining the first impurity gas content information and physical and chemical environment information collected in the catalytic oxidation process, the physical and chemical environment information including temperature information, pressure information, normal temperature range information and normal pressure range information;
将理化环境信息代入理化环境系数计算公式中计算理化环境系数,理化环境系数计算公式为:;Substitute the physical and chemical environmental information into the physical and chemical environmental coefficient calculation formula to calculate the physical and chemical environmental coefficient. The physical and chemical environmental coefficient calculation formula is: ;
式中表示时刻的温度信息,表示正常温度范围信息的最小值,表示正常温度范围信息的最大值,表示时刻的压力信息,表示正常压力范围信息的最小值,表示正常压力范围信息的最大值,表示监测周期的时长,表示取最大值,表示理化环境系数。In the formula express Temperature information at the moment, Indicates the minimum value of the normal temperature range information, Indicates the maximum value of the normal temperature range information, express Pressure information at all times, Indicates the minimum value of the normal pressure range information, Indicates the maximum value of the normal pressure range information, Indicates the duration of the monitoring cycle. Indicates taking the maximum value, Represents the physical and chemical environmental coefficient.
将氧气供给系数、理化环境系数和第一杂质气体含量信息代入催化氧化工艺指数计算公式中计算催化氧化工艺指数,催化氧化工艺指数计算公式为:Substitute the oxygen supply coefficient, the physical and chemical environment coefficient and the first impurity gas content information into the catalytic oxidation process index calculation formula to calculate the catalytic oxidation process index. The catalytic oxidation process index calculation formula is:
; ;
式中表示氧气供给系数,表示理化环境系数,表示第一杂质气体含量信息中的催化氧化前杂质气体含量信息,表示第一杂质气体含量信息中的催化氧化后杂质气体含量信息,表示调节因子,表示催化氧化工艺指数。In the formula represents the oxygen supply coefficient, It represents the physical and chemical environmental coefficient. represents the impurity gas content information before catalytic oxidation in the first impurity gas content information, represents the impurity gas content information after catalytic oxidation in the first impurity gas content information, represents the adjustment factor, Represents the catalytic oxidation process index.
在本实施例中,脱氧吸附工艺指数计算模块用于根据第二氧气含量信息和第二杂质气体含量信息计算脱氧吸附工艺指数,计算脱氧吸附工艺指数的具体步骤包括:In this embodiment, the deoxygenation adsorption process index calculation module is used to calculate the deoxygenation adsorption process index according to the second oxygen content information and the second impurity gas content information. The specific steps of calculating the deoxygenation adsorption process index include:
获取采集到的脱氧吸附工艺流程中的第二氧气含量信息和第二杂质气体含量信息;Acquire the collected second oxygen content information and second impurity gas content information in the deoxygenation adsorption process;
将第二氧气含量信息和第二杂质气体含量信息代入脱氧吸附工艺指数计算公式中计算脱氧吸附工艺指数,脱氧吸附工艺指数计算公式为:Substitute the second oxygen content information and the second impurity gas content information into the deoxygenation adsorption process index calculation formula to calculate the deoxygenation adsorption process index. The deoxygenation adsorption process index calculation formula is:
; ;
式中表示第二氧气含量信息中的脱氧吸附前氧气含量信息,表示第二氧气含量信息中的脱氧吸附后氧气含量信息,表示第二杂质气体含量信息中的脱氧吸附前杂质气体含量信息,表示第二杂质气体含量信息中的脱氧吸附后杂质气体含量信息,表示氧气脱除权重,表示杂质气体脱除权重,表示脱氧吸附工艺指数。In the formula represents the oxygen content information before deoxygenation adsorption in the second oxygen content information, represents the oxygen content information after deoxygenation adsorption in the second oxygen content information, represents the impurity gas content information before deoxygenation adsorption in the second impurity gas content information, represents the impurity gas content information after deoxygenation adsorption in the second impurity gas content information, represents the oxygen removal weight, represents the impurity gas removal weight, Represents the deoxygenation adsorption process index.
在本实施例中,气体纯化指数计算模块用于根据催化氧化工艺指数和脱氧吸附工艺指数计算气体纯化指数,并根据气体纯化指数对纯化过程进行实时监测,计算气体纯化指数包括以下具体步骤:In this embodiment, the gas purification index calculation module is used to calculate the gas purification index according to the catalytic oxidation process index and the deoxygenation adsorption process index, and to monitor the purification process in real time according to the gas purification index. The calculation of the gas purification index includes the following specific steps:
获取计算得到的催化氧化工艺指数和脱氧吸附工艺指数;Obtaining the calculated catalytic oxidation process index and deoxygenation adsorption process index;
将催化氧化工艺指数和脱氧吸附工艺指数代入气体纯化指数计算公式中计算气体纯化指数,气体纯化指数计算公式为:;Substitute the catalytic oxidation process index and the deoxygenation adsorption process index into the gas purification index calculation formula to calculate the gas purification index. The gas purification index calculation formula is: ;
式中表示催化氧化工艺指数,表示脱氧吸附工艺指数,表示催化氧化工艺占比系数,表示脱氧吸附工艺占比系数,表示气体纯化指数。In the formula represents the catalytic oxidation process index, represents the deoxygenation adsorption process index, represents the catalytic oxidation process ratio, represents the deoxygenation adsorption process ratio, Indicates the gas purification index.
根据气体纯化指数对纯化过程进行实时监测包括以下具体步骤:Real-time monitoring of the purification process based on the gas purification index includes the following specific steps:
当气体纯化指数大于等于预设气体纯化阈值时,维持当前纯化工艺流程;When the gas purification index is greater than or equal to the preset gas purification threshold, the current purification process is maintained;
当气体纯化指数小于预设气体纯化阈值时,发出纯化工艺流程预警并将氧气供给系数、理化环境系数、催化氧化工艺指数和脱氧吸附工艺指数发送至运维人员,用于快速定位和排查问题工艺流程。When the gas purification index is less than the preset gas purification threshold, a purification process warning is issued and the oxygen supply coefficient, physical and chemical environment coefficient, catalytic oxidation process index and deoxygenation adsorption process index are sent to the operation and maintenance personnel for rapid location and troubleshooting of problematic processes.
上述关于本发明的一种基于气体数据识别的纯化过程监测系统中的各参数和各个单元模块实现相应功能的步骤,可参考上文中关于一种基于气体数据识别的纯化过程监测方法的实施例中的各参数和步骤,在此不做赘述。The above-mentioned parameters and steps for each unit module to realize the corresponding functions in a purification process monitoring system based on gas data identification of the present invention can refer to the parameters and steps in the embodiment of a purification process monitoring method based on gas data identification above, and will not be repeated here.
实施例3Example 3
本发明实施例的一种计算机可读存储介质,其上存储有计算机程序,该计算机程序被处理器执行时,实现上述的一种基于气体数据识别的纯化过程监测方法。需要说明的是:一种基于气体数据识别的纯化过程监测方法的所有计算机程序均使用C语言实现,其中,信息采集模块、氧气供给系数计算模块、催化氧化工艺指数计算模块、脱氧吸附工艺指数计算模块、气体纯化指数计算模块和控制模块均由远程服务器控制。A computer-readable storage medium according to an embodiment of the present invention stores a computer program thereon, and when the computer program is executed by a processor, the above-mentioned purification process monitoring method based on gas data identification is implemented. It should be noted that all computer programs of the purification process monitoring method based on gas data identification are implemented using C language, wherein the information acquisition module, oxygen supply coefficient calculation module, catalytic oxidation process index calculation module, deoxygenation adsorption process index calculation module, gas purification index calculation module and control module are all controlled by a remote server.
实施例4Example 4
本实施例提出一种计算机可读存储介质,其上存储有可擦写的计算机程序;This embodiment provides a computer-readable storage medium having a rewritable computer program stored thereon;
当计算机程序在计算机设备上运行时,使得计算机设备执行上述的一种基于气体数据识别的纯化过程监测方法。When the computer program is executed on a computer device, the computer device is enabled to execute the above-mentioned purification process monitoring method based on gas data identification.
例如,计算机可读存储介质能够是只读存储器(Read-Only Memory,简称:ROM)、随机存取存储器(Random Access Memory,简称:RAM)、只读光盘(Compact Disc Read-OnlyMemory,简称:CD-ROM)、磁带、软盘和光数据存储设备等。For example, the computer readable storage medium can be a read-only memory (ROM), a random access memory (RAM), a compact disc (CD-ROM), a magnetic tape, a floppy disk, an optical data storage device, etc.
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