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CN118517810A - Phase-change heat storage device and solar water heating system - Google Patents

Phase-change heat storage device and solar water heating system Download PDF

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Publication number
CN118517810A
CN118517810A CN202410817067.8A CN202410817067A CN118517810A CN 118517810 A CN118517810 A CN 118517810A CN 202410817067 A CN202410817067 A CN 202410817067A CN 118517810 A CN118517810 A CN 118517810A
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China
Prior art keywords
heat storage
heat
phase change
storage device
working medium
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CN202410817067.8A
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CN118517810B (en
Inventor
吕石磊
贾涵茜
王敬博
李磊
王朝亮
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Tianjin University
State Grid Zhejiang Electric Power Co Ltd
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Tianjin University
State Grid Zhejiang Electric Power Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S60/00Arrangements for storing heat collected by solar heat collectors
    • F24S60/10Arrangements for storing heat collected by solar heat collectors using latent heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • F28D20/021Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat the latent heat storage material and the heat-exchanging means being enclosed in one container

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Heat-Pump Type And Storage Water Heaters (AREA)
  • Central Heating Systems (AREA)

Abstract

The invention relates to the technical field of heat storage devices, and particularly provides a phase-change heat storage device and a solar water heating system. Wherein, the shell is provided with an inlet and an outlet for the heat transfer working medium to enter and exit the shell. The rotating shaft is rotatably arranged in the shell, and the heat storage module comprises a shell and a heat storage working medium accommodated in the shell. In the process that the heat storage module rotates along with the rotating shaft, the heat storage working medium exchanges heat with the heat transfer working medium in the shell. The heat storage working medium comprises an inorganic hydrated salt phase change material, and phase change occurs in the process of heat exchange with the heat transfer working medium so as to store heat in the heat storage working medium. The solar water heating system comprises a solar heat collector, at least one phase-change heat storage device and a user side. The phase change heat storage device is configured to exchange heat with a heat transfer medium from the solar collector. The user side is configured to pump tap water to the phase-change heat storage device, exchange heat with the heat storage working medium and then convey the tap water to the user.

Description

相变储热装置及太阳能热水系统Phase change heat storage device and solar water heating system

技术领域Technical Field

本发明的至少一种实施例涉及储热装置技术领域,更具体地,涉及一种相变储热装置及太阳能热水系统。At least one embodiment of the present invention relates to the technical field of heat storage devices, and more specifically, to a phase change heat storage device and a solar water heating system.

背景技术Background Art

随着能源消耗的不断增长,可再生能源的利用和节能减排已成为关注热点。在可再生能源中,太阳能作为一种清洁、可再生的能源,具有广泛的应用前景。其中,太阳能热水系统是非常典型的一种应用。With the continuous growth of energy consumption, the use of renewable energy and energy conservation and emission reduction have become a hot topic. Among renewable energy sources, solar energy, as a clean and renewable energy, has a wide range of application prospects. Among them, solar water heating system is a very typical application.

太阳能的能量密度低,且具有间歇性和波动性的特点,需要将太阳能转化为热能后进行存储,以便于后续使用。目前,潜热蓄能技术使用较为广泛,其主要原理为材料在相变过程中吸收或释放热量,以实现将热量存储于材料中,或从材料中释放。其中的相变材料导热效果好、吸放热量大且相变过程中温度变化小等特点,例如常用于太阳能热水系统中的无机水合盐材料。Solar energy has a low energy density and is intermittent and volatile. It needs to be converted into thermal energy and stored for subsequent use. At present, latent heat storage technology is widely used. Its main principle is that the material absorbs or releases heat during the phase change process to store heat in the material or release it from the material. Phase change materials have the characteristics of good thermal conductivity, large heat absorption and release, and small temperature change during phase change. For example, inorganic hydrated salt materials are commonly used in solar water heating systems.

在相关技术中,相变储热装置通常将相变材料封装于球形壳体内,再将多个这种球形壳体密集布置,以在水流经这些球体时进行换热。但在自然对流下,换热效果仍然不够理想。并且无机水合盐材料在处于相变温度附近时,由于溶解度的变化,导致相分离,影响换热。因此,如何进一步提高相变储热装置的换热性能,成为亟待解决的技术问题。In the related art, phase change heat storage devices usually encapsulate phase change materials in spherical shells, and then densely arrange multiple such spherical shells to exchange heat when water flows through these spheres. However, under natural convection, the heat exchange effect is still not ideal. In addition, when the inorganic hydrated salt material is near the phase change temperature, the solubility changes, resulting in phase separation, which affects the heat exchange. Therefore, how to further improve the heat exchange performance of the phase change heat storage device has become a technical problem that needs to be solved urgently.

发明内容Summary of the invention

鉴于上述问题,本发明提供了一种相变储热装置及太阳能热水系统,能够强化对流传热,并降低相分离发生的可能,提高换热性能。In view of the above problems, the present invention provides a phase change heat storage device and a solar water heating system, which can enhance convective heat transfer, reduce the possibility of phase separation, and improve heat exchange performance.

为了实现上述目的,作为本发明提供一种相变储热装置,包括:壳体,上述壳体上形成有进口和出口,以供传热工质进出上述壳体;转轴,可转动的安装于上述壳体内;储热模块,设置于上述转轴上,上述储热模块包括外壳以及容置在上述外壳内的储热工质,其中,在上述储热模块在随上述转轴转动的过程中,上述储热工质与上述壳体内的传热工质换热;其中,上述储热工质包括无机水合盐相变材料,响应于与传热工质换热过程中发生相变,以将热量存储于上述储热工质内。In order to achieve the above-mentioned purpose, the present invention provides a phase change heat storage device, comprising: a shell, an inlet and an outlet are formed on the shell for a heat transfer medium to enter and exit the shell; a rotating shaft rotatably installed in the shell; a heat storage module, arranged on the rotating shaft, the heat storage module comprises a shell and a heat storage medium accommodated in the shell, wherein, when the heat storage module rotates with the rotating shaft, the heat storage medium exchanges heat with the heat transfer medium in the shell; wherein the heat storage medium comprises an inorganic hydrated salt phase change material, which undergoes a phase change in response to the heat exchange process with the heat transfer medium, so as to store heat in the heat storage medium.

在一种示意性的实施例中,上述储热模块设置至少一个,且沿周向方向间隔布置于上述转轴上。In an illustrative embodiment, at least one of the heat storage modules is provided and is spaced apart on the rotating shaft along a circumferential direction.

在一种示意性的实施例中,上述储热模块包括:多个储热单元,多个上述储热单元被构造成沿行和/或列形式间隔排布,每个上述储热单元内均充有储热工质;多个桁架,上述桁架被构造成为中空管状杆件,布置于两个相邻的上述储热单元之间以连通相邻的上述储热单元,从而使上述储热工质在相邻的储热单元之间流动。In an illustrative embodiment, the heat storage module comprises: a plurality of heat storage units, the plurality of heat storage units are configured to be arranged in rows and/or columns, each of the heat storage units is filled with a heat storage medium; a plurality of trusses, the trusses are configured to be hollow tubular rods, arranged between two adjacent heat storage units to connect the adjacent heat storage units, so that the heat storage medium flows between the adjacent heat storage units.

在一种示意性的实施例中,还包括散流板,设置于上述进口和上述转轴之间;上述散流板上开设有多个通孔,以使来自于上述进口的传热工质经上述散流板的上述通孔分散后流至上述储热模块上。In an illustrative embodiment, it further includes a diffuser plate, which is arranged between the above-mentioned inlet and the above-mentioned rotating shaft; the above-mentioned diffuser plate is provided with a plurality of through holes, so that the heat transfer medium from the above-mentioned inlet can be dispersed through the above-mentioned through holes of the above-mentioned diffuser plate and then flow to the above-mentioned heat storage module.

在一种示意性的实施例中,上述进口的轴线和上述出口的轴线共线,且均与上述转轴的轴线垂直。In an illustrative embodiment, the axis of the inlet and the axis of the outlet are collinear and both are perpendicular to the axis of the rotating shaft.

在一种示意性的实施例中,上述进口和上述出口沿竖直方向布置于同一直线上。In an illustrative embodiment, the inlet and the outlet are arranged on the same straight line along the vertical direction.

在一种示意性的实施例中,上述壳体被构造成中空球形壳体。In an illustrative embodiment, the shell is configured as a hollow spherical shell.

本发明还提供了一种太阳能热水系统,包括:太阳能集热器,适用于将太阳能转化为热能,并对传热工质进行加热;至少一个如上述任一实施例中的的相变储热装置,被配置为与来自上述太阳能集热器的传热工质换热,以将热量存储于储热工质内;用户端,被配置为将自来水泵送至上述相变储热装置,与上述储热工质换热后输送至用户处。The present invention also provides a solar water heating system, comprising: a solar collector, suitable for converting solar energy into thermal energy and heating a heat transfer medium; at least one phase change heat storage device as in any of the above embodiments, configured to exchange heat with the heat transfer medium from the above solar collector to store heat in the heat storage medium; a user end, configured to pump tap water to the above phase change heat storage device, exchange heat with the above heat storage medium and then transport it to the user.

在一种示意性的实施例中,还包括蓄热水箱,被配置为接收并存储来自于上述相变储热装置和上述太阳能集热器的传热工质,以及利用传热工质与上述用户端泵送的自来水换热。In an illustrative embodiment, a heat storage tank is further included, which is configured to receive and store the heat transfer medium from the phase change heat storage device and the solar collector, and to use the heat transfer medium to exchange heat with the tap water pumped from the user end.

在一种示意性的实施例中,上述相变储热装置顺次布置有三个,其中,第一相变储热装置的进口与上述太阳能集热器相连,第二相变储热装置的进口与第一相变储热装置的出口相连,第三相变储热装置的进口与第二相变储热装置的出口相连,第三相变储热装置的出口与上述太阳能集热器和上述用户端分别相连。In an illustrative embodiment, three of the above-mentioned phase change heat storage devices are arranged in sequence, wherein the inlet of the first phase change heat storage device is connected to the above-mentioned solar thermal collector, the inlet of the second phase change heat storage device is connected to the outlet of the first phase change heat storage device, the inlet of the third phase change heat storage device is connected to the outlet of the second phase change heat storage device, and the outlet of the third phase change heat storage device is connected to the above-mentioned solar thermal collector and the above-mentioned user end, respectively.

在一种示意性的实施例中,上述第一相变储热装置的储热工质的相变温度范围为t1~t2,上述第二相变储热装置的储热工质的相变温度范围为t2~t3,上述第三相变储热装置的储热工质的相变温度范围为t3~t4,且t1-t2=t2-t3=t3-t4。In an illustrative embodiment, the phase change temperature range of the heat storage medium of the first phase change heat storage device is t1~t2, the phase change temperature range of the heat storage medium of the second phase change heat storage device is t2~t3, the phase change temperature range of the heat storage medium of the third phase change heat storage device is t3~t4, and t1-t2=t2-t3=t3-t4.

本发明所提供的热相变储热装置及太阳能热水系统,通过在壳体内设置随转轴转动的储热模块,改变传热工质流经壳体时的流动状态,强化对流传热,提高换热效果。储热模块内的储热工质包括无机水合盐相变材料,其储热能力强,成本低,且由于储热模块随转轴转动,降低了改材料发生相分离的可能性,进一步提高了换热性能。在太阳能热水系统中,通过将太阳能集热器加热的传热工质与相变储热装置换热,以将太阳能转化为热能进行存储,从而弥补太阳能的波动性的缺点。The thermal phase change heat storage device and solar water heating system provided by the present invention change the flow state of the heat transfer medium when flowing through the shell, strengthen the convective heat transfer, and improve the heat exchange effect by arranging a heat storage module that rotates with the rotating shaft in the shell. The heat storage medium in the heat storage module includes an inorganic hydrated salt phase change material, which has a strong heat storage capacity and low cost. In addition, since the heat storage module rotates with the rotating shaft, the possibility of phase separation of the material is reduced, and the heat exchange performance is further improved. In the solar water heating system, the heat transfer medium heated by the solar collector is exchanged with the phase change heat storage device to convert solar energy into thermal energy for storage, thereby compensating for the disadvantage of the volatility of solar energy.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

通过以下参照附图对本公开实施例的描述,本公开的上述以及其他目的、特征和优点将更为清楚,在附图中:The above and other objects, features and advantages of the present disclosure will become more apparent through the following description of the embodiments of the present disclosure with reference to the accompanying drawings, in which:

图1是本发明所提供的一种相变储热装置立体结构图;FIG1 is a three-dimensional structural diagram of a phase change heat storage device provided by the present invention;

图2是图1所示的示例性实施例中储热模块3的平面示意图;FIG2 is a schematic plan view of the heat storage module 3 in the exemplary embodiment shown in FIG1 ;

图3是图1所示的示例性实施例中散流板4的平面示意图;FIG3 is a schematic plan view of the diffuser plate 4 in the exemplary embodiment shown in FIG1 ;

图4是本发明所提供的一种太阳能热水系统示意图;FIG4 is a schematic diagram of a solar water heating system provided by the present invention;

图5是图4所示的示例性实施例中多个相变储热装置的布置方式图;FIG5 is a diagram showing an arrangement of multiple phase change heat storage devices in the exemplary embodiment shown in FIG4 ;

图6是另一示例性实施例中太阳能热水系统示意图。FIG. 6 is a schematic diagram of a solar water heating system in another exemplary embodiment.

上述附图中,附图标记含义具体如下:In the above drawings, the meanings of the reference numerals are as follows:

1、壳体;1. Shell;

11、进口;11. Import;

12、出口;12. Export;

2、转轴;2. Rotating shaft;

3、储热模块;3. Heat storage module;

31、储热单元;31. Heat storage unit;

32、桁架;32. Truss;

4、散流板;4. Diffuser plate;

5、太阳能集热器;5. Solar collector;

6、相变储热装置;6. Phase change heat storage device;

61、第一相变储热装置;61. A first phase change heat storage device;

62、第二相变储热装置;62. A second phase change heat storage device;

63、第三相变储热装置;63. The third phase change heat storage device;

7、蓄热水箱。7. Heat storage tank.

具体实施方式DETAILED DESCRIPTION

为使本发明的目的、技术方案和优点更加清楚明白,以下结合具体实施例,并参照附图,对本发明作进一步的详细说明。在此使用的术语仅仅是为了描述具体实施例,而并非意在限制本发明。In order to make the purpose, technical solution and advantages of the present invention more clearly understood, the present invention is further described in detail below in conjunction with specific embodiments and with reference to the accompanying drawings. The terms used herein are only for describing specific embodiments and are not intended to limit the present invention.

在此使用的术语“包括”、“包含”等表明了所述特征、步骤、操作和/或组件的存在,但是并不排除存在或添加一个或多个其他特征、步骤、操作或组件。在此使用的所有术语包括技术和科学术语具有本领域技术人员通常所理解的含义,除非另外定义。应注意,这里使用的术语应解释为具有与本说明书的上下文相一致的含义,而不应以理想化或过于刻板的方式来解释。The terms "include", "comprising", etc. used herein indicate the presence of the features, steps, operations and/or components, but do not exclude the presence or addition of one or more other features, steps, operations or components. All terms used herein, including technical and scientific terms, have the meanings commonly understood by those skilled in the art unless otherwise defined. It should be noted that the terms used herein should be interpreted as having a meaning consistent with the context of this specification and should not be interpreted in an idealized or overly rigid manner.

在本文中,除非另有特别说明,诸如“上”、“下”、“左”、“右”、“内”、“外”等方向性术语用于表示基于附图所示的方位或位置关系,仅是为了便于描述本发明,而不是指示或暗示所指的装置、元件或组件件必须具有特定的方位、以特定的方位构造或操作。需要理解的是,当被描述对象的绝对位置改变后,则它们表示的相对位置关系也可能相应地改变。因此,这些方向性术语不能理解为对本发明的限制。In this document, unless otherwise specified, directional terms such as "upper", "lower", "left", "right", "inner", "outer", etc. are used to indicate the orientation or positional relationship based on the drawings, and are only for the convenience of describing the present invention, and do not indicate or imply that the device, element or component referred to must have a specific orientation, be constructed or operate in a specific orientation. It should be understood that when the absolute position of the described object changes, the relative positional relationship they represent may also change accordingly. Therefore, these directional terms should not be understood as limiting the present invention.

在使用类似于“A、B和C等中至少一个”这样的表述的情况下,一般来说应该按照本领域技术人员通常理解该表述的含义来予以解释例如,“具有A、B和C中至少一个的系统”应包括但不限于单独具有A、单独具有B、单独具有C、具有A和B、具有A和C、具有B和C、和/或具有A、B、C的系统等。在使用类似于“A、B或C等中至少一个”这样的表述的情况下,一般来说应该按照本领域技术人员通常理解该表述的含义来予以解释例如,“具有A、B或C中至少一个的系统”应包括但不限于单独具有A、单独具有B、单独具有C、具有A和B、具有A和C、具有B和C、和/或具有A、B、C的系统等。When using expressions such as "at least one of A, B, and C, etc.", it should generally be interpreted as the meaning of the expression generally understood by those skilled in the art. For example, "a system having at least one of A, B, and C" should include but not be limited to a system having A alone, B alone, C alone, A and B, A and C, B and C, and/or A, B, C, etc. When using expressions such as "at least one of A, B, or C, etc.", it should generally be interpreted as the meaning of the expression generally understood by those skilled in the art. For example, "a system having at least one of A, B, or C" should include but not be limited to a system having A alone, B alone, C alone, A and B, A and C, B and C, and/or A, B, C, etc.

本领域技术人员可以理解,本发明的各个实施例和/或权利要求中记载的特征可以进行多种组合或/或结合,即使这样的组合或结合没有明确记载于本发明中。特别地,在不脱离本发明精神和教导的情况下,本发明的各个实施例和/或权利要求中记载的特征可以进行多种组合和/或结合。所有这些组合和/或结合均落入本发明的范围。It will be appreciated by those skilled in the art that the features described in the various embodiments and/or claims of the present invention may be combined and/or combined in various ways, even if such combinations and/or combinations are not explicitly described in the present invention. In particular, the features described in the various embodiments and/or claims of the present invention may be combined and/or combined in various ways without departing from the spirit and teachings of the present invention. All of these combinations and/or combinations fall within the scope of the present invention.

图1是本发明所提供的一种相变储热装置立体结构图。FIG1 is a three-dimensional structural diagram of a phase change heat storage device provided by the present invention.

本发明的示例性实施例提供一种相变储热装置,如图1所示,包括壳体1、转轴2和储热模块3。其中,壳体1上形成有进口11和出口12,以供传热工质进出壳体1。转轴2可转动的安装于壳体1内,储热模块3设置于转轴2上,储热模块3包括外壳以及容置在外壳内的储热工质。在储热模块3随转轴2转动的过程中,储热工质与壳体1内的传热工质换热。其中,储热工质包括无机水合盐相变材料,响应于与传热工质换热过程中发生相变,以将热量存储于储热工质内。An exemplary embodiment of the present invention provides a phase change heat storage device, as shown in FIG1 , comprising a shell 1, a rotating shaft 2 and a heat storage module 3. The shell 1 is formed with an inlet 11 and an outlet 12 for the heat transfer medium to enter and exit the shell 1. The rotating shaft 2 is rotatably installed in the shell 1, and the heat storage module 3 is arranged on the rotating shaft 2. The heat storage module 3 includes an outer shell and a heat storage medium accommodated in the outer shell. In the process of the heat storage module 3 rotating with the rotating shaft 2, the heat storage medium exchanges heat with the heat transfer medium in the shell 1. The heat storage medium includes an inorganic hydrated salt phase change material, which undergoes a phase change in response to the heat exchange process with the heat transfer medium to store heat in the heat storage medium.

在这样的实施方式中,壳体1内形成有一空腔,传热工质自进口11进入壳体1的空腔,并由出口12流出壳体1。在壳体1的空腔内,储热模块3设置于转轴2上并随转轴2转动,从而改变传热工质在壳体1内的流动状态,强化对流传热,提高了换热效果。采用无机水合盐相变材料作为储热模块3内的储热工质,不仅储热能力强,且由于储热模块3随转轴2转动,不易发生相分离,进一步提高了换热性能。In such an embodiment, a cavity is formed in the shell 1, and the heat transfer medium enters the cavity of the shell 1 from the inlet 11 and flows out of the shell 1 from the outlet 12. In the cavity of the shell 1, the heat storage module 3 is arranged on the rotating shaft 2 and rotates with the rotating shaft 2, thereby changing the flow state of the heat transfer medium in the shell 1, strengthening the convective heat transfer, and improving the heat exchange effect. The use of inorganic hydrated salt phase change material as the heat storage medium in the heat storage module 3 not only has a strong heat storage capacity, but also because the heat storage module 3 rotates with the rotating shaft 2, it is not easy to separate phases, further improving the heat exchange performance.

在本公开的实施例中,转轴2通过轴承贯穿安装于壳体1上,并且与电机的驱动轴相连,由电机驱动旋转。In the embodiment of the present disclosure, the rotating shaft 2 is installed on the housing 1 through a bearing, and is connected to the driving shaft of the motor and is driven to rotate by the motor.

在本公开的实施例中,无机水合盐相变材料的相变温度范围为45℃~60℃。In the embodiments of the present disclosure, the phase change temperature range of the inorganic hydrated salt phase change material is 45°C to 60°C.

在一种示例性的实施例中,壳体1被构造成中空球形壳体,由于转轴2带动储热模块3在壳体1内部旋转,因此球形壳体能够提高空间利用率,且球形外壳的表面积相较于其他(例如立方体外壳)外壳的表面积更小,能够减少换热过程中的热量损耗。In an exemplary embodiment, the shell 1 is constructed as a hollow spherical shell. Since the rotating shaft 2 drives the heat storage module 3 to rotate inside the shell 1, the spherical shell can improve space utilization, and the surface area of the spherical shell is smaller than the surface area of other shells (such as cubic shells), which can reduce heat loss during heat exchange.

图2是图1所示的示例性实施例中储热模块3的平面示意图。FIG. 2 is a schematic plan view of the heat storage module 3 in the exemplary embodiment shown in FIG. 1 .

在一种示例性的实施例中,如图2所示,储热模块3设置至少一个,且沿周向方向间隔布置于转轴2上。如图1所示出的,储热模块3设置有8个,且沿周向方向间隔分布。进一步的,位于同一圆周面上的多个储热模块3为一个储热模组,储热模组沿轴向方向间隔布置多个,以增加储热模块3的覆盖范围,提高换热效果。In an exemplary embodiment, as shown in FIG2 , at least one heat storage module 3 is provided, and is spaced apart on the rotating shaft 2 along the circumferential direction. As shown in FIG1 , eight heat storage modules 3 are provided, and are spaced apart along the circumferential direction. Further, a plurality of heat storage modules 3 located on the same circumferential surface constitute a heat storage module, and a plurality of heat storage modules are spaced apart in the axial direction to increase the coverage of the heat storage module 3 and improve the heat exchange effect.

根据本公开的实施例,储热模块3包括多个储热单元31和多个桁架32,其中,多个储热单元31被构造成沿行和/或列的形式间隔排布,每个储热单元31内均充有储热工质。桁架32被构造成为中空管状杆件,布置于两个相邻的储热单元31之间以连通相邻的储热单元31,从而使储热工质在相邻的储热单元31之间流动。According to an embodiment of the present disclosure, the heat storage module 3 includes a plurality of heat storage units 31 and a plurality of trusses 32, wherein the plurality of heat storage units 31 are configured to be arranged in rows and/or columns, and each heat storage unit 31 is filled with a heat storage medium. The trusses 32 are configured as hollow tubular rods, and are arranged between two adjacent heat storage units 31 to connect the adjacent heat storage units 31, so that the heat storage medium flows between the adjacent heat storage units 31.

示例性的,如图2所示,多个储热单元31按照8行4列的矩形阵列式布置,在该阵列中,每两个相邻的储热单元31之间均连接有桁架32,且如X形交叉布置的两个桁架32彼此连通。Exemplarily, as shown in FIG. 2 , a plurality of heat storage units 31 are arranged in a rectangular array of 8 rows and 4 columns. In the array, a truss 32 is connected between every two adjacent heat storage units 31 , and two trusses 32 arranged in an X-shape are connected to each other.

在一些其他实施例中,储热单元31也被构造为球形壳体,易于增大与传热流体的换热面积,且球形壳体以及桁架32的连接在布置时便于增加系统结构的复杂程度,提高空间利用率且有利于增强对流传热。In some other embodiments, the heat storage unit 31 is also constructed as a spherical shell, which makes it easy to increase the heat exchange area with the heat transfer fluid, and the connection between the spherical shell and the truss 32 is convenient for increasing the complexity of the system structure during arrangement, improving space utilization and helping to enhance convective heat transfer.

更为具体的,储热单元31和桁架32均由耐高温、耐腐蚀以及力学性能优异的塑料制成,其中,包括但不限于聚醚醚酮、聚酰亚胺等。More specifically, the heat storage unit 31 and the truss 32 are both made of plastics that are resistant to high temperatures and corrosion and have excellent mechanical properties, including but not limited to polyetheretherketone, polyimide, and the like.

图3是图1所示的示例性实施例中散流板4的平面示意图。FIG. 3 is a schematic plan view of the diffuser plate 4 in the exemplary embodiment shown in FIG. 1 .

在一种示例性的实施例中,如图3所示,上述相变储热装置还包括散流板4,设置于进口11和转轴12之间。散流板4上开设有多个通孔,以使来自于进口11的传热工质经散流板4的通孔分散口流至储热模块3上。In an exemplary embodiment, as shown in FIG3 , the phase change heat storage device further includes a diffuser plate 4 disposed between the inlet 11 and the rotating shaft 12. The diffuser plate 4 is provided with a plurality of through holes, so that the heat transfer medium from the inlet 11 flows to the heat storage module 3 through the through hole dispersion ports of the diffuser plate 4.

在这样的实施方式中,散流板4通过夹持或一体成型的方式设于壳体1内,散流板4与转轴12之间的距离大于储热模块3的最大长度尺寸,以避免影响储热模块3随转轴2旋转。散流板4所处的水平面与进口11的轴线垂直,当有传热工质从进口11进入壳体1时,会先冲击到散流板4的表面,沿散流板4的表面扩散开后,再沿散流板4上的通孔流至储热模块3上,如此能够使得传热工质在壳体1内分布更均匀,进一步强化对流传热。In such an embodiment, the diffuser plate 4 is disposed in the housing 1 by clamping or integrally forming, and the distance between the diffuser plate 4 and the rotating shaft 12 is greater than the maximum length dimension of the heat storage module 3, so as to avoid affecting the heat storage module 3 from rotating with the rotating shaft 2. The horizontal plane where the diffuser plate 4 is located is perpendicular to the axis of the inlet 11. When the heat transfer medium enters the housing 1 from the inlet 11, it will first impact the surface of the diffuser plate 4, diffuse along the surface of the diffuser plate 4, and then flow along the through holes on the diffuser plate 4 to the heat storage module 3, so that the heat transfer medium can be distributed more evenly in the housing 1, and the convective heat transfer can be further enhanced.

根据本公开的实施例,进口11的轴线与出口12的轴线共线,且均与转轴2的轴线垂直。According to an embodiment of the present disclosure, the axis of the inlet 11 is colinear with the axis of the outlet 12 , and both are perpendicular to the axis of the rotating shaft 2 .

更为具体的,进口11和出口12沿竖直方向布置于同一直线上。More specifically, the inlet 11 and the outlet 12 are arranged on the same straight line along the vertical direction.

在这样的实施方式中,通过将进口11和出口12共线且沿竖直方向布置,使得进入壳体1的传热工质经过散流板4后,能够在重力作用下流动并冲击储热模块3,使得储热模块3对转轴2的转动起到一定的辅助作用,降低电机驱动的负荷。In such an embodiment, the inlet 11 and the outlet 12 are arranged in a colinear manner and in a vertical direction, so that the heat transfer medium entering the shell 1 can flow under the action of gravity and impact the heat storage module 3 after passing through the diffuser 4, so that the heat storage module 3 plays a certain auxiliary role in the rotation of the rotating shaft 2, thereby reducing the load of the motor drive.

图4是本发明所提供的一种太阳能热水系统示意图。FIG. 4 is a schematic diagram of a solar water heating system provided by the present invention.

本发明的示例性实施例还提供一种太阳能热水系统,包括太阳能集热器5、至少一个如上述任一实施例中的相变储热装置6和用户端。其中,太阳能集热器5适用于将太阳能转化为热能,并对传热工质进行热。相变储热装置6被配置为与来自太阳能集热器5的传热工质换热,以将热量存储于储热工质内。用户端被配置为将自来水泵送至相变储热装置6,与储热工质换热后输送至用户处。An exemplary embodiment of the present invention further provides a solar water heating system, comprising a solar collector 5, at least one phase change heat storage device 6 as in any of the above embodiments, and a user end. The solar collector 5 is suitable for converting solar energy into thermal energy and heating a heat transfer medium. The phase change heat storage device 6 is configured to exchange heat with the heat transfer medium from the solar collector 5 to store heat in the heat storage medium. The user end is configured to pump tap water to the phase change heat storage device 6, exchange heat with the heat storage medium, and then deliver it to the user.

在这样的实施方式中,传热工质为水,太阳能集热器5将水加热后,输送至相变储热装置6的进口11,并与相变储热装置6内的储热工质换热将热量储存至储热工质内,温度下降后的水由出口12流出,并流回至太阳能集热器5处继续加热。在此过程中,用户端将温度较低的自来水泵送至相变储热装置6处进行换热,吸收预先储存的热量,并将热水输送至用户处,以此能够解决在夜晚或太阳照射不足时,热水供应不稳定的问题。需要说明的是,在储热过程中,用户若需要热水,则将自来水泵送至辅助加热装置处进行加热,待储热完成后,再从相变储热装置6处取热。In such an embodiment, the heat transfer medium is water. After the solar collector 5 heats the water, it is transported to the inlet 11 of the phase change heat storage device 6, and heat is exchanged with the heat storage medium in the phase change heat storage device 6 to store the heat in the heat storage medium. The water after the temperature drops flows out from the outlet 12 and flows back to the solar collector 5 to continue heating. In this process, the user end pumps the lower temperature tap water to the phase change heat storage device 6 for heat exchange, absorbs the pre-stored heat, and transports the hot water to the user, which can solve the problem of unstable hot water supply at night or when the sun is insufficient. It should be noted that during the heat storage process, if the user needs hot water, the tap water is pumped to the auxiliary heating device for heating. After the heat storage is completed, heat is taken from the phase change heat storage device 6.

根据本公开的实施例,上述太阳能热水系统还包括蓄热水箱7,被配置为接收并存储来自于相变蓄热装置6和太阳能集热器5的传热工质,以及利用传热工质与与用户端泵送的自来水换热。According to an embodiment of the present disclosure, the solar water heating system further comprises a heat storage tank 7, which is configured to receive and store heat transfer medium from the phase change heat storage device 6 and the solar collector 5, and to exchange heat with tap water pumped from the user end using the heat transfer medium.

具体参照图4所,其中,太阳能集热器5的出口端与第一三通阀的A1口相连,第一三通阀A2口与相变蓄热装置6的进口11相连,A3口与蓄热水箱7相连;相变蓄热装置6的出口12与第二三通阀的B2口相连,蓄热水箱7同时与第二三通阀的B3口相连,第二三通阀的B1口与太阳能集热器5相连。4 , wherein the outlet end of the solar collector 5 is connected to the A1 port of the first three-way valve, the A2 port of the first three-way valve is connected to the inlet 11 of the phase change heat storage device 6, and the A3 port is connected to the hot water storage tank 7; the outlet 12 of the phase change heat storage device 6 is connected to the B2 port of the second three-way valve, the hot water storage tank 7 is also connected to the B3 port of the second three-way valve, and the B1 port of the second three-way valve is connected to the solar collector 5.

在储热时,太阳能集热器5通过第一三通阀将热水相变蓄热装置6和蓄热水箱7,与相变蓄热装置6换热后的冷水通过第二三通阀回流至太阳能集热器5,蓄热水箱7将热水暂时存储。用户端有热水需求时,首先将自来水泵送至蓄热水箱7处进行换热,若无法满足需求,则启用辅助加热装置进行加热。待储热完成后,蓄热水箱7内的水可泵送至相变蓄热装置6进行取热,或回流至太阳能集热器5处。When storing heat, the solar collector 5 transfers the hot water phase change heat storage device 6 and the hot water storage tank 7 through the first three-way valve, and the cold water after heat exchange with the phase change heat storage device 6 flows back to the solar collector 5 through the second three-way valve, and the hot water storage tank 7 temporarily stores the hot water. When the user needs hot water, the tap water is first pumped to the hot water storage tank 7 for heat exchange. If the demand cannot be met, the auxiliary heating device is activated for heating. After the heat storage is completed, the water in the hot water storage tank 7 can be pumped to the phase change heat storage device 6 for heat extraction, or flow back to the solar collector 5.

图5是图4所示的示例性实施例中多个相变储热装置的布置方式图。FIG. 5 is a diagram showing an arrangement of multiple phase change heat storage devices in the exemplary embodiment shown in FIG. 4 .

在一种示例性的实施例中,相变储热装置6顺次布置有三个,其中,第一相变储热装置61的进口11与太阳能集热器5相连,第二相变储热装置62的进口11与第一相变储热装置61的出口12相连,第三相变储热装置63的进口11与第二相变储热装置62的出口12相连,第三相变储热装置63的出口与太阳能集热器5和用户端分别相连。In an exemplary embodiment, three phase change heat storage devices 6 are arranged in sequence, wherein the inlet 11 of the first phase change heat storage device 61 is connected to the solar collector 5, the inlet 11 of the second phase change heat storage device 62 is connected to the outlet 12 of the first phase change heat storage device 61, the inlet 11 of the third phase change heat storage device 63 is connected to the outlet 12 of the second phase change heat storage device 62, and the outlet of the third phase change heat storage device 63 is connected to the solar collector 5 and the user end respectively.

在这样的实施方式中,通过增加相变储热装置的数量,延长传热工质的换热行程与时间,使得换热更加充分。In such an embodiment, by increasing the number of phase change heat storage devices, the heat exchange stroke and time of the heat transfer medium are extended, making the heat exchange more sufficient.

根据本公开的实施例,第一相变储热装置61的储热工质的相变温度范围为t1~t2,第二相变储热装置62的储热工质的相变温度范围为t2~t3,第三相变储热装置63的储热工质的相变温度范围为t3~t4,且t1-t2=t2-t3=t3-t4。According to an embodiment of the present disclosure, the phase change temperature range of the heat storage medium of the first phase change heat storage device 61 is t1~t2, the phase change temperature range of the heat storage medium of the second phase change heat storage device 62 is t2~t3, the phase change temperature range of the heat storage medium of the third phase change heat storage device 63 is t3~t4, and t1-t2=t2-t3=t3-t4.

示例性的,t1=60℃,t2=55℃,t3=50℃,t4=45℃,以此将相变温度范围梯级布置,使得在储热(传热工质由入口11流向出口12)和取热(传热工质由出口12流向入口11)时均能够保持较高的换热效率。Exemplarily, t1=60°C, t2=55°C, t3=50°C, t4=45°C, so that the phase change temperature range is arranged in steps, so that a high heat exchange efficiency can be maintained during heat storage (heat transfer medium flows from inlet 11 to outlet 12) and heat extraction (heat transfer medium flows from outlet 12 to inlet 11).

根据本公开的实施例,第一相变储热装置61、第二相变储热装置62和第三相变储热装置63沿水平方向顺次布置,即进口11和出口12的轴线均沿水平方向延伸。在储热时,传热工质由第一相变储热装置61流向第三相变储热装置63,使得传热工质的温度下降的同时,与相变温度范围相适配。在取热时,传热工质由第三相变储热装置63流向第一相变装置61,使得传热工质的温度上升的同时,与相变温度范围相适配。在储热和取热过程中,由水泵以及转轴2的驱动电机为传热工质提供流动的动力,在切换储热/取热模式,即流动方向发生改变时,相应的控制驱动电机进行换向,以使系统能够流畅、稳定运行。According to an embodiment of the present disclosure, the first phase change heat storage device 61, the second phase change heat storage device 62 and the third phase change heat storage device 63 are arranged in sequence in the horizontal direction, that is, the axes of the inlet 11 and the outlet 12 extend in the horizontal direction. When storing heat, the heat transfer medium flows from the first phase change heat storage device 61 to the third phase change heat storage device 63, so that the temperature of the heat transfer medium decreases while adapting to the phase change temperature range. When taking out heat, the heat transfer medium flows from the third phase change heat storage device 63 to the first phase change device 61, so that the temperature of the heat transfer medium increases while adapting to the phase change temperature range. In the process of heat storage and heat taking, the water pump and the drive motor of the rotating shaft 2 provide the power for the flow of the heat transfer medium. When switching the heat storage/heat taking mode, that is, when the flow direction changes, the corresponding control drive motor is reversed so that the system can operate smoothly and stably.

在此需要说明的是,第一相变储热装置61、第二相变储热装置62和第三相变储热装置63也可以沿竖直方向顺次布置,传热工质在重力作用下的流动能够降低驱动电机的负荷。It should be noted that the first phase change heat storage device 61, the second phase change heat storage device 62 and the third phase change heat storage device 63 can also be arranged in sequence in the vertical direction, and the flow of the heat transfer medium under the action of gravity can reduce the load of the drive motor.

图6是另一示例性实施例中太阳能热水系统示意图。FIG. 6 is a schematic diagram of a solar water heating system in another exemplary embodiment.

在一些其他的实施方式中,参照图6所示出的,该太阳能热水系统重还包括阀门a~e,当阀门b、c、e打开,阀门a、e关闭时,来自太阳能集热器5的热水依次流经A2口、相变储热装置6、阀门b、c、e、蓄热水箱7、B3口后回流至太阳能集热器5,该工作模式通常适用于太阳光较充足,太阳能集热器5输出的热水温度较高或能够长时间持续输出热水时,先将热水送至相变储热装置6进行换热,未充分换热或相变储热装置6已达到储热上限时多余的热水流向蓄热水箱7进行存储。当阀门a、c、e打开,阀门b、d关闭时,来自太阳能集热器5的热水依次流经A3口、蓄热水箱7、阀门e、c、a、相变储热装置6、B2口后回流至太阳能集热器5,该工作模式下太阳能集热器5输出的热水先送至蓄热水箱7储存,优先满足用户端的热水需求,经蓄热水箱7排出的水流至相变储热装置6,换热后的冷水回流至太阳能集热器5。In some other embodiments, as shown in FIG. 6 , the solar water heating system further includes valves a to e. When valves b, c, and e are opened and valves a and e are closed, hot water from the solar collector 5 flows through port A2, the phase change heat storage device 6, valves b, c, and e, the water storage tank 7, and port B3 in sequence, and then flows back to the solar collector 5. This working mode is usually suitable for when the sunlight is sufficient, the hot water output by the solar collector 5 is at a high temperature, or the hot water can be continuously output for a long time. The hot water is first sent to the phase change heat storage device 6 for heat exchange. When the heat exchange is not sufficient or the phase change heat storage device 6 has reached the upper limit of the heat storage, the excess hot water flows to the water storage tank 7 for storage. When valves a, c, and e are opened and valves b and d are closed, the hot water from the solar collector 5 flows through port A3, the hot water storage tank 7, valves e, c, a, the phase change heat storage device 6, and port B2 in sequence and then flows back to the solar collector 5. In this working mode, the hot water output by the solar collector 5 is first sent to the hot water storage tank 7 for storage to give priority to meeting the hot water demand of the user end. The water discharged from the hot water storage tank 7 flows to the phase change heat storage device 6, and the cold water after heat exchange flows back to the solar collector 5.

进一步的,在上述任一实施方式基础上,太阳能集热器5的上游处设有水泵,当太阳能集热器5的出口温度与入口温度的差值为预设值或高于预设值时,水泵才会开启,将温度较低的传热介质或冷水泵送回太阳能集热器5处,在本实施方式中,预设值为6℃。Furthermore, based on any of the above-mentioned embodiments, a water pump is provided upstream of the solar collector 5. When the difference between the outlet temperature and the inlet temperature of the solar collector 5 is equal to or higher than a preset value, the water pump will be turned on to pump the heat transfer medium or cold water with a lower temperature back to the solar collector 5. In the present embodiment, the preset value is 6°C.

以上对本发明的实施例进行了描述。但是,这些实施例仅仅是为了说明的目的,而并非为了限制本发明的范围。尽管在以上分别描述了各实施例,但是这并不意味着各个实施例中的措施不能有利地结合使用。本发明的范围由所附权利要求及其等同物限定。不脱离本发明的范围,本领域技术人员可以做出多种替代和修改,这些替代和修改都应落在本发明的范围之内。The embodiments of the present invention are described above. However, these embodiments are only for the purpose of illustration, and are not intended to limit the scope of the present invention. Although the embodiments are described above, this does not mean that the measures in the various embodiments cannot be used in combination. The scope of the present invention is defined by the appended claims and their equivalents. Without departing from the scope of the present invention, those skilled in the art may make various substitutions and modifications, which should all fall within the scope of the present invention.

Claims (10)

1. A phase change heat storage device, comprising:
the heat transfer device comprises a shell (1), wherein an inlet (11) and an outlet (12) are formed on the shell (1) for heat transfer working media to enter and exit the shell (1);
The rotating shaft (2) is rotatably arranged in the shell (1);
the heat storage module (3) is arranged on the rotating shaft (2), and the heat storage module (3) comprises a shell and a heat storage working medium accommodated in the shell, wherein the heat storage working medium exchanges heat with the heat transfer working medium in the shell (1) in the process that the heat storage module (3) rotates along with the rotating shaft (2);
the heat storage working medium comprises an inorganic hydrated salt phase change material, and phase change occurs in the process of heat exchange with the heat transfer working medium so as to store heat in the heat storage working medium.
2. Phase change heat storage device according to claim 1, characterized in that the heat storage modules (3) are provided at least one and are arranged on the rotating shaft (2) at intervals in the circumferential direction.
3. Phase change heat storage device according to claim 2, characterized in that the heat storage module (3) comprises:
The heat storage units (31) are configured to be arranged at intervals along rows and/or columns, and each heat storage unit (31) is filled with a heat storage working medium;
-a plurality of trusses (32), the trusses (32) being configured as hollow tubular bars arranged between two adjacent heat storage units (31) to communicate adjacent heat storage units (31) such that the heat storage medium flows between adjacent heat storage units (31).
4. The phase change heat storage device according to claim 1, further comprising a diffuser plate (4) arranged between the inlet (11) and the rotating shaft (2);
The heat storage module is characterized in that the heat dissipation plate (4) is provided with a plurality of through holes so that heat transfer working medium from the inlet (11) flows onto the heat storage module (3) after being dispersed through the through holes of the heat dissipation plate (4).
5. Phase change heat storage device according to claim 4, characterized in that the axis of the inlet (11) and the axis of the outlet (12) are collinear and perpendicular to the axis of the rotating shaft (2).
6. Phase change heat storage device according to claim 1, characterized in that the housing (1) is configured as a hollow spherical housing.
7. A solar water heating system, comprising:
The solar heat collector (5) is suitable for converting solar energy into heat energy and heating a heat transfer working medium;
At least one phase change heat storage device (6) according to any one of claims 1-6 configured to exchange heat with a heat transfer medium from the solar collector (5) to store heat in a heat storage medium;
the user side is configured to pump tap water to the phase-change heat storage device (6), exchange heat with the heat storage working medium and then convey the heat to the user.
8. Solar water heating system according to claim 7, further comprising a heat storage tank (7) configured to receive and store heat transfer medium from the phase change heat storage device (6) and the solar collector (5), and to exchange heat with tap water pumped by the user side using the heat transfer medium.
9. Solar water heating system according to claim 7, characterized in that the phase change heat storage means (6) are arranged in sequence with three, wherein,
The inlet (11) of the first phase-change heat storage device (61) is connected with the solar heat collector (5), the inlet (11) of the second phase-change heat storage device (62) is connected with the outlet (12) of the first phase-change heat storage device (61), the inlet (11) of the third phase-change heat storage device (63) is connected with the outlet (12) of the second phase-change heat storage device (62), and the outlet of the third phase-change heat storage device (63) is connected with the solar heat collector (5) and the user side respectively.
10. Solar water heating system according to claim 9, characterized in that the phase change temperature range of the heat storage working medium of the first phase change heat storage device (61) is t1-t2, the phase change temperature range of the heat storage working medium of the second phase change heat storage device (62) is t2-t3, the phase change temperature range of the heat storage working medium of the third phase change heat storage device (63) is t3-t4, and t1-t2 = t2-t3 = t3-t4.
CN202410817067.8A 2024-06-24 2024-06-24 Phase-change heat storage device and solar water heating system Active CN118517810B (en)

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Citations (6)

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Publication number Priority date Publication date Assignee Title
US5165466A (en) * 1991-12-11 1992-11-24 Morteza Arbabian Modular heat exchanger having delayed heat transfer capability
CN106839851A (en) * 2017-04-01 2017-06-13 武汉理工大学 A kind of stirring solid-liquid phase change heat-storing device certainly
CN112629050A (en) * 2020-12-21 2021-04-09 西安交通大学 Solar phase-change heat storage device supported by array type hollow lattice truss unit
CN115164630A (en) * 2022-06-23 2022-10-11 同济大学 A rotary enhanced heat exchange phase change heat storage device
CN116558343A (en) * 2023-06-01 2023-08-08 烟台大学 An active and passive controllable magnetic eddy current heater
CN116857707A (en) * 2023-07-27 2023-10-10 广州大学 A solar photovoltaic photothermal, phase change heat storage and heat pump coupled hot water system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5165466A (en) * 1991-12-11 1992-11-24 Morteza Arbabian Modular heat exchanger having delayed heat transfer capability
CN106839851A (en) * 2017-04-01 2017-06-13 武汉理工大学 A kind of stirring solid-liquid phase change heat-storing device certainly
CN112629050A (en) * 2020-12-21 2021-04-09 西安交通大学 Solar phase-change heat storage device supported by array type hollow lattice truss unit
CN115164630A (en) * 2022-06-23 2022-10-11 同济大学 A rotary enhanced heat exchange phase change heat storage device
CN116558343A (en) * 2023-06-01 2023-08-08 烟台大学 An active and passive controllable magnetic eddy current heater
CN116857707A (en) * 2023-07-27 2023-10-10 广州大学 A solar photovoltaic photothermal, phase change heat storage and heat pump coupled hot water system

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