CN118489325A - Active hydrogen equipment and application for improving soil compaction and saline-alkali land - Google Patents
Active hydrogen equipment and application for improving soil compaction and saline-alkali land Download PDFInfo
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Abstract
本发明属于土壤改良技术领域,提供了一种改善土壤板结和改良盐碱地的活性氢设备及应用,该活性氢设备包括控制系统、活性氢生成装置和土壤混合器;活性氢生成装置出口处和土壤混合器连接;活性氢生成装置可以产生活性氢;土壤混合器用于混合活性氢、待处理土壤和有机物质;控制系统用于监控和管理所述活性氢设备的工作过程。本发明利用活性氢改善土壤板结和盐碱化问题,具有操作简单、效果显著、环保无污染等优点。通过实际应用表明,该设备可以有效降低土壤盐碱度,改善土壤结构,提高土壤肥力和生物多样性,为农业生产提供有力支持。The present invention belongs to the technical field of soil improvement, and provides an active hydrogen device and application for improving soil compaction and saline-alkali land. The active hydrogen device includes a control system, an active hydrogen generating device and a soil mixer; the outlet of the active hydrogen generating device is connected to the soil mixer; the active hydrogen generating device can generate active hydrogen; the soil mixer is used to mix active hydrogen, soil to be treated and organic matter; the control system is used to monitor and manage the working process of the active hydrogen device. The present invention uses active hydrogen to improve soil compaction and salinization problems, and has the advantages of simple operation, significant effect, environmental protection and no pollution. Practical application shows that the equipment can effectively reduce soil salinity, improve soil structure, increase soil fertility and biodiversity, and provide strong support for agricultural production.
Description
技术领域Technical Field
本发明涉及土壤改良技术领域,尤其涉及一种改善土壤板结和改良盐碱地的活性氢设备及应用。The invention relates to the technical field of soil improvement, and in particular to an active hydrogen device for improving soil compaction and saline-alkali land and its application.
背景技术Background Art
土壤板结和盐碱化是农业生产中常见的土壤问题,严重影响作物生长和产量。传统的土壤改良方法如翻耕、加入有机物质等虽然在一定程度上可以改善土壤结构,但操作繁琐且效果有限。近年来,随着氢气在环境保护和修复领域的研究深入,发现氢气对土壤重金属污染等具有良好的修复作用,因此本发明提出了一种改善土壤板结和改良盐碱地的活性氢设备及应用。Soil compaction and salinization are common soil problems in agricultural production, which seriously affect crop growth and yield. Although traditional soil improvement methods such as tillage and addition of organic matter can improve soil structure to a certain extent, the operation is cumbersome and the effect is limited. In recent years, with the in-depth research on hydrogen in the field of environmental protection and restoration, it has been found that hydrogen has a good repair effect on soil heavy metal pollution, etc. Therefore, the present invention proposes an active hydrogen device and application for improving soil compaction and improving saline-alkali land.
发明内容Summary of the invention
本发明的目的在于提供一种改善土壤板结和改良盐碱地的活性氢设备及应用,以克服现有技术存在的缺陷。The purpose of the present invention is to provide an active hydrogen device and application for improving soil compaction and ameliorating saline-alkali land, so as to overcome the defects of the prior art.
为了实现上述发明目的,本发明提供以下技术方案:In order to achieve the above-mentioned object of the invention, the present invention provides the following technical solutions:
本发明提供了一种改善土壤板结和改良盐碱地的活性氢设备,所述活性氢设备包括控制系统、活性氢生成装置和土壤混合器;所述活性氢生成装置出口处和土壤混合器连接;所述活性氢生成装置可以产生活性氢;所述土壤混合器用于混合活性氢、待处理土壤和有机物质;所述控制系统用于监控和管理所述活性氢设备的工作过程。The present invention provides an active hydrogen device for improving soil compaction and ameliorizing saline-alkali land, the active hydrogen device comprising a control system, an active hydrogen generating device and a soil mixer; the outlet of the active hydrogen generating device is connected to the soil mixer; the active hydrogen generating device can generate active hydrogen; the soil mixer is used to mix active hydrogen, soil to be treated and organic matter; the control system is used to monitor and manage the working process of the active hydrogen device.
作为优选,所述混合的搅拌速率为200~500r/min;Preferably, the mixing stirring rate is 200 to 500 r/min;
所述混合的时间为3~5h。The mixing time is 3 to 5 hours.
作为优选,所述活性氢生成装置包括纳米多孔材料、电解液、电解槽和电源。Preferably, the active hydrogen generating device comprises a nanoporous material, an electrolyte, an electrolytic cell and a power source.
作为优选,所述纳米多孔材料包括阳极材料和阴极材料;Preferably, the nanoporous material comprises an anode material and a cathode material;
所述阳极材料为依金属、钌金属、氧化铱和氧化钌中的一种或几种;The anode material is one or more of metal, ruthenium metal, iridium oxide and ruthenium oxide;
所述阴极材料为铂金属、镍金属和铂镍合金中的一种或几种。The cathode material is one or more of platinum metal, nickel metal and platinum-nickel alloy.
作为优选,所述纳米多孔材料的孔径为20~80nm。Preferably, the pore diameter of the nanoporous material is 20-80 nm.
作为优选,所述电解液为水、氢氧化钾溶液和氢氧化钠溶液中的一种或几种;Preferably, the electrolyte is one or more of water, potassium hydroxide solution and sodium hydroxide solution;
所述氢氧化钾溶液的质量浓度为20~30%;The mass concentration of the potassium hydroxide solution is 20-30%;
所述氢氧化钠溶液的质量浓度为20~30%。The mass concentration of the sodium hydroxide solution is 20-30%.
作为优选,所述活性氢生成装置的电流密度为2500~3500A/cm3。Preferably, the current density of the active hydrogen generator is 2500 to 3500 A/cm 3 .
作为优选,所述电解槽的温度为70~90℃。Preferably, the temperature of the electrolytic cell is 70-90°C.
作为优选,所述有机物质为腐熟堆肥或腐殖土;Preferably, the organic matter is decomposed compost or humus soil;
所述有机物质的质量为待处理土壤质量的1~5%。The mass of the organic matter is 1-5% of the mass of the soil to be treated.
本发明还提供了所述的一种改善土壤板结和改良盐碱地的活性氢设备在土壤改善中的应用。The present invention also provides the application of the active hydrogen device for improving soil compaction and saline-alkali land in soil improvement.
有益效果:Beneficial effects:
本发明提供了一种改善土壤板结和改良盐碱地的活性氢设备,利用活性氢改善土壤板结和盐碱化问题,具有操作简单、效果显著、环保无污染等优点。通过实际应用表明,该设备可以有效降低土壤盐碱度,改善土壤结构,提高土壤肥力和生物多样性,为农业生产提供有力支持。The present invention provides an active hydrogen device for improving soil compaction and saline-alkali land, which uses active hydrogen to improve soil compaction and salinization problems, and has the advantages of simple operation, significant effect, environmental protection and no pollution. Practical application shows that the device can effectively reduce soil salinity, improve soil structure, increase soil fertility and biodiversity, and provide strong support for agricultural production.
具体实施方式DETAILED DESCRIPTION
本发明提供了一种改善土壤板结和改良盐碱地的活性氢设备,所述活性氢设备优选包括控制系统、活性氢生成装置和土壤混合器;所述活性氢生成装置出口处和土壤混合器连接;所述活性氢生成装置可以产生活性氢;所述土壤混合器用于混合活性氢、待处理土壤和有机物质;所述控制系统用于监控和管理所述活性氢设备的工作过程。The present invention provides an active hydrogen device for improving soil compaction and ameliorizing saline-alkali land. The active hydrogen device preferably comprises a control system, an active hydrogen generating device and a soil mixer; the outlet of the active hydrogen generating device is connected to the soil mixer; the active hydrogen generating device can generate active hydrogen; the soil mixer is used to mix active hydrogen, soil to be treated and organic matter; the control system is used to monitor and manage the working process of the active hydrogen device.
在本发明中,所述混合的搅拌速率优选为200~500r/min,进一步优选为250~450r/min,更优选为300~400r/min。In the present invention, the stirring rate of the mixing is preferably 200 to 500 r/min, more preferably 250 to 450 r/min, and more preferably 300 to 400 r/min.
在本发明中,所述混合的时间优选为3~5h,进一步优选为3.4~4.6h,更优选为3.8~4.2h。In the present invention, the mixing time is preferably 3 to 5 hours, more preferably 3.4 to 4.6 hours, and even more preferably 3.8 to 4.2 hours.
在本发明中,所述活性氢生成装置优选包括纳米多孔材料、电解液、电解槽和电源。In the present invention, the active hydrogen generating device preferably includes a nanoporous material, an electrolyte, an electrolytic cell and a power source.
在本发明中,所述纳米多孔材料优选包括阳极材料和阴极材料。In the present invention, the nanoporous material preferably includes an anode material and a cathode material.
在本发明中,所述阳极材料优选为铱金属、钌金属、氧化铱和氧化钌中的一种或几种。In the present invention, the anode material is preferably one or more of iridium metal, ruthenium metal, iridium oxide and ruthenium oxide.
在本发明中,所述阴极材料优选为铂金属、镍金属和铂镍合金中的一种或几种。In the present invention, the cathode material is preferably one or more of platinum metal, nickel metal and platinum-nickel alloy.
在本发明中,所述纳米多孔材料的孔径优选为20~80nm,进一步优选为30~70nm,更优选为40~60nm。In the present invention, the pore diameter of the nanoporous material is preferably 20 to 80 nm, more preferably 30 to 70 nm, and even more preferably 40 to 60 nm.
在本发明中,所述电解液优选为水、氢氧化钾溶液和氢氧化钠溶液中的一种或几种。In the present invention, the electrolyte is preferably one or more of water, potassium hydroxide solution and sodium hydroxide solution.
在本发明中,所述氢氧化钾溶液的质量浓度优选为20~30%,进一步优选为22~28%,更优选为24~26%。In the present invention, the mass concentration of the potassium hydroxide solution is preferably 20-30%, more preferably 22-28%, and more preferably 24-26%.
在本发明中,所述氢氧化钠溶液的质量浓度优选为20~30%,进一步优选为22~28%,更优选为24~26%。In the present invention, the mass concentration of the sodium hydroxide solution is preferably 20-30%, more preferably 22-28%, and more preferably 24-26%.
在本发明中,所述活性氢生成装置的电流密度优选为2500~3500A/cm3,进一步优选为2700~3300A/cm3,更优选为2900~3000A/cm3。In the present invention, the current density of the active hydrogen generator is preferably 2500 to 3500 A/cm 3 , more preferably 2700 to 3300 A/cm 3 , and even more preferably 2900 to 3000 A/cm 3 .
在本发明中,所述电解槽的温度优选为70~90℃,进一步优选为74~86℃,更优选为78~82℃。In the present invention, the temperature of the electrolytic cell is preferably 70 to 90°C, more preferably 74 to 86°C, and even more preferably 78 to 82°C.
在本发明中,所述活性氢生成装置还包括气体净化系统。In the present invention, the active hydrogen generating device further includes a gas purification system.
在本发明中,使用氧化锌吸附活性氢粗产物的硫化物、氯化物得到活性氢。In the present invention, zinc oxide is used to adsorb sulfides and chlorides of the crude active hydrogen product to obtain active hydrogen.
在本发明中,所述有机物质优选为腐熟堆肥或腐殖土。In the present invention, the organic matter is preferably decomposed compost or humus.
在本发明中,所述有机物质的质量优选为待处理土壤质量的1~5%,进一步优选为1.5~4.5%,更优选为2~4%。In the present invention, the mass of the organic matter is preferably 1-5% of the mass of the soil to be treated, more preferably 1.5-4.5%, and even more preferably 2-4%.
在本发明中,通过控制系统设定土壤板结程度和盐碱度参数,可自动调整活性氢气体的生成速率和释放量,在土壤混合器中混合活性氢、待处理土壤和有机物质,即可得到改良后的土壤。In the present invention, the soil compaction degree and salinity parameters are set by the control system, and the generation rate and release amount of active hydrogen gas can be automatically adjusted. Active hydrogen, soil to be treated and organic matter are mixed in a soil mixer to obtain improved soil.
本发明还提供了一种改善土壤板结和改良盐碱地的活性氢设备在土壤改善中的应用The present invention also provides an application of an active hydrogen device for improving soil compaction and saline-alkali land in soil improvement.
下面结合实施例对本发明提供的技术方案进行详细的说明,但是不能把它们理解为对本发明保护范围的限定。The technical solutions provided by the present invention are described in detail below in conjunction with the embodiments, but they should not be construed as limiting the protection scope of the present invention.
实施例1Example 1
取孔径为20nm的氧化铱为阳极,取孔径为20nm的铂金属为阴极放置盛有水的电解槽中,通入电源,其中电流密度为2500A/cm3,在70℃下进行电解,生成活性氢粗产物,使用氧化锌对活性氢粗产物进行吸附,依靠控制系统设定土壤板结程度和盐碱度参数自动调整活性氢气体的生成速率和释放量,将吸附后的活性氢通入到含有待处理土壤和有机物质(其中有机物质的质量为待处理土壤质量的1%)的土壤混合器中,按照200r/min的速率混合3h,即得改善后的土壤。Iridium oxide with a pore size of 20 nm is used as an anode, and platinum metal with a pore size of 20 nm is used as a cathode. They are placed in an electrolytic cell filled with water, and a power source is connected. The current density is 2500A/ cm3 . Electrolysis is performed at 70°C to generate a crude active hydrogen product. Zinc oxide is used to adsorb the crude active hydrogen product. The generation rate and release amount of active hydrogen gas are automatically adjusted by setting the soil compaction degree and salinity parameters of the control system. The adsorbed active hydrogen is introduced into a soil mixer containing soil to be treated and organic matter (the mass of the organic matter is 1% of the mass of the soil to be treated), and mixed at a rate of 200r/min for 3h to obtain improved soil.
实施例2Example 2
取孔径为80nm的氧化钌为阳极,取孔径为80nm的镍金属为阴极放置盛有质量浓度为25%的氢氧化钠溶液的电解槽中,通入电源,其中电流密度为3500A/cm3,在90℃下进行电解,生成活性氢粗产物,使用氧化锌对活性氢粗产物进行吸附,依靠控制系统设定土壤板结程度和盐碱度参数自动调整活性氢气体的生成速率和释放量,将吸附后的活性氢通入到含有待处理土壤和有机物质(其中有机物质的质量为待处理土壤质量的5%)的土壤混合器中,按照500r/min的速率混合5h,即得改善后的土壤。A ruthenium oxide with a pore size of 80 nm is used as an anode, and a nickel metal with a pore size of 80 nm is used as a cathode. The two are placed in an electrolytic cell containing a sodium hydroxide solution with a mass concentration of 25%. A power source is connected, wherein the current density is 3500 A/cm 3 , and electrolysis is performed at 90° C. to generate a crude active hydrogen product. Zinc oxide is used to adsorb the crude active hydrogen product. The generation rate and release amount of the active hydrogen gas are automatically adjusted by setting the soil compaction degree and salinity parameters of the control system. The adsorbed active hydrogen is introduced into a soil mixer containing soil to be treated and organic matter (wherein the mass of the organic matter is 5% of the mass of the soil to be treated), and mixed at a rate of 500 r/min for 5 hours to obtain improved soil.
实施例3Example 3
取孔径为50nm的氧化铱为阳极,取孔径为50nm的铂镍金属为阴极放置盛有质量浓度为25%的氢氧化钾溶液的电解槽中,通入电源,其中电流密度为3000A/cm3,在80℃下进行电解,生成活性氢粗产物,使用氧化锌对活性氢粗产物进行吸附,依靠控制系统设定土壤板结程度和盐碱度参数自动调整活性氢气体的生成速率和释放量,将吸附后的活性氢通入到含有待处理土壤和有机物质(其中有机物质的质量为待处理土壤质量的3%)的土壤混合器中,按照350r/min的速率混合4h,即得改善后的土壤。Iridium oxide with a pore size of 50 nm is used as an anode, and platinum nickel metal with a pore size of 50 nm is used as a cathode, and placed in an electrolytic cell containing a potassium hydroxide solution with a mass concentration of 25%. A power source is connected, wherein the current density is 3000A/ cm3 , and electrolysis is performed at 80°C to generate a crude active hydrogen product, which is adsorbed by zinc oxide, and the generation rate and release amount of active hydrogen gas are automatically adjusted by setting soil compaction degree and salinity parameters by a control system, and the adsorbed active hydrogen is introduced into a soil mixer containing soil to be treated and organic matter (wherein the mass of the organic matter is 3% of the mass of the soil to be treated), and mixed at a rate of 350r/min for 4 hours to obtain improved soil.
由以上实施例可知,本发明提供了一种改善土壤板结和改良盐碱地的活性氢设备,利用活性氢改善土壤板结和盐碱化问题,具有操作简单、效果显著、环保无污染等优点。通过实际应用表明,该设备可以有效降低土壤盐碱度,改善土壤结构,提高土壤肥力和生物多样性,为农业生产提供有力支持。It can be seen from the above embodiments that the present invention provides an active hydrogen device for improving soil compaction and saline-alkali land, which uses active hydrogen to improve soil compaction and salinization problems, and has the advantages of simple operation, significant effect, environmental protection and no pollution. Practical application shows that the device can effectively reduce soil salinity, improve soil structure, increase soil fertility and biodiversity, and provide strong support for agricultural production.
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention. It should be pointed out that for ordinary technicians in this technical field, several improvements and modifications can be made without departing from the principle of the present invention. These improvements and modifications should also be regarded as the scope of protection of the present invention.
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