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CN118392945B - MEMS gas sensor and method for manufacturing the same - Google Patents

MEMS gas sensor and method for manufacturing the same Download PDF

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CN118392945B
CN118392945B CN202410840478.9A CN202410840478A CN118392945B CN 118392945 B CN118392945 B CN 118392945B CN 202410840478 A CN202410840478 A CN 202410840478A CN 118392945 B CN118392945 B CN 118392945B
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heat
layer
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cavity wall
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CN118392945A (en
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马天军
李娜
孙建海
薛宁
张淼
程建群
孙旭光
方刚
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/04Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
    • G01N27/12Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
    • G01N27/125Composition of the body, e.g. the composition of its sensitive layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B7/00Microstructural systems; Auxiliary parts of microstructural devices or systems
    • B81B7/02Microstructural systems; Auxiliary parts of microstructural devices or systems containing distinct electrical or optical devices of particular relevance for their function, e.g. microelectro-mechanical systems [MEMS]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00015Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
    • B81C1/00023Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems without movable or flexible elements
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00436Shaping materials, i.e. techniques for structuring the substrate or the layers on the substrate
    • B81C1/00523Etching material
    • B81C1/00531Dry etching

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Abstract

The application provides an MEMS gas sensor, which comprises a silicon substrate, a supporting layer, a heating element, an isolating layer, a testing element and a gas sensitive element, wherein the silicon substrate comprises a front surface and a back surface deviating from the front surface; the supporting layer is connected between the first cavity wall and the second cavity wall and is positioned in the heat insulation cavity, and the supporting layer isolates the heat insulation cavity from the heat collection cavity; the heating element is arranged on the supporting layer and positioned in the heat insulation cavity; the isolating layer covers the supporting layer and the heating element; the test element is arranged on one surface of the isolation layer, which is away from the heating element; the gas sensor is arranged in the test the side of the element facing away from the barrier layer. In addition, the application also provides a manufacturing method of the MEMS gas sensor.

Description

MEMS气体传感器及其制作方法MEMS gas sensor and method for manufacturing the same

技术领域Technical Field

本申请涉及半导体技术领域,尤其涉及一种MEMS气体传感器及其制作方法。The present application relates to the field of semiconductor technology, and in particular to a MEMS gas sensor and a manufacturing method thereof.

背景技术Background Art

医疗检测常通过人体呼出气体检测相应指标来对人体进行非侵害性和安全性的检测。现有技术中,常采用半导体金属氧化物MEMS气体传感器来检测人体呼出气体。半导体金属氧化物MEMS气体传感器需要微型加热平台使得敏感材料在适宜的温度中工作,微型加热平台根据支撑膜结构的不同类型可以分为悬空膜型和封闭膜型。Medical testing often uses human exhaled gas to detect corresponding indicators to perform non-invasive and safe testing on the human body. In the prior art, semiconductor metal oxide MEMS gas sensors are often used to detect human exhaled gas. Semiconductor metal oxide MEMS gas sensors require a micro-heating platform to allow sensitive materials to work at a suitable temperature. The micro-heating platform can be divided into suspended membrane type and closed membrane type according to the different types of supporting membrane structures.

然而,悬空膜型的MEMS气体传感器由于需要支撑梁的支撑,机械强度低、易断裂、稳定性低,且悬空膜型的MEMS气体传感器从硅片到气体传感器的制作工艺复杂、成品的良率低。另外,悬空膜型的MEMS气体传感器在制作空腔时需要额外掩模版的制作,使得MEMS气体传感器成本增加的同时,制作空腔时还因腐蚀角度易出现在支撑梁下方遗留硅岛而增加功耗。而封闭膜型的MEMS气体传感器的微热平台因过度散热而使得MEMS气体传感器的功率损耗变大。However, suspended membrane type MEMS gas sensors require the support of support beams, so they have low mechanical strength, are easy to break, and have low stability. In addition, the manufacturing process from silicon wafers to gas sensors is complex, and the yield of finished products is low. In addition, suspended membrane type MEMS gas sensors require the production of additional masks when making cavities, which increases the cost of MEMS gas sensors. When making cavities, silicon islands are easily left under the support beams due to corrosion angles, which increases power consumption. The micro-thermal platform of closed membrane type MEMS gas sensors increases the power loss of MEMS gas sensors due to excessive heat dissipation.

发明内容Summary of the invention

本申请提供了一种MEMS气体传感器及其制作方法,可提高MEMS气体传感器的机械强度、降低其功率损耗的同时,还能减小其内的器材体积。The present application provides a MEMS gas sensor and a manufacturing method thereof, which can improve the mechanical strength of the MEMS gas sensor, reduce its power loss, and reduce the volume of the equipment therein.

第一方面,本申请实施例提供一种MEMS气体传感器,所述MEMS气体传感器包括硅衬底、支撑层、加热元件、隔离层、测试元件、以及气敏元件,硅衬底包括正面、以及背离所述正面的背面,所述正面设有隔热腔,所述背面设有聚热腔,所述隔热腔和所述聚热腔连通,所述硅衬底还包括所述隔热腔相对设置的第一腔壁和第二腔壁;支撑层连接于所述第一腔壁和所述第二腔壁之间并位于所述隔热腔,且所述支撑层将所述隔热腔和所述聚热腔隔离;加热元件设置于所述支撑层并位于所述隔热腔内;隔离层覆盖于所述支撑层并覆盖所述加热元件;测试元件设置于所述隔离层背离所述加热元件的一面;气敏元件设置于所述测试元件背离所述隔离层的一面。In a first aspect, an embodiment of the present application provides a MEMS gas sensor, which includes a silicon substrate, a supporting layer, a heating element, an isolation layer, a test element, and a gas sensitive element. The silicon substrate includes a front side and a back side facing away from the front side, the front side is provided with a heat insulation cavity, the back side is provided with a heat collection cavity, the heat insulation cavity and the heat collection cavity are connected, and the silicon substrate also includes a first cavity wall and a second cavity wall arranged opposite to the heat insulation cavity; the supporting layer is connected between the first cavity wall and the second cavity wall and is located in the heat insulation cavity, and the supporting layer isolates the heat insulation cavity from the heat collection cavity; the heating element is arranged on the supporting layer and is located in the heat insulation cavity; the isolation layer covers the supporting layer and covers the heating element; the test element is arranged on a side of the isolation layer facing away from the heating element; and the gas sensitive element is arranged on a side of the test element facing away from the isolation layer.

第二方面,本申请实施例提供一种MEMS气体传感器的制作方法,所述MEMS气体传感器的制作方法包括:从所述硅衬底的正面向背离所述正面的背面刻蚀形成隔热腔,所述隔热腔包括相对设置的第一腔壁和第二腔壁;在所述隔热腔内交替沉积氧化硅薄膜和氮化硅薄膜,以依次形成氧化硅层和氮化硅层而形成支撑层,并使所述支撑层连接于所述第一腔壁和所述第二腔壁;在所述隔热腔内制备加热元件并设置于所述支撑层;在所述支撑层朝向所述正面的一面和所述加热元件朝向所述正面的一面沉积氮化硅薄膜形成隔离层,以使所述隔离层覆盖于所述支撑层并覆盖所述加热元件;在所述隔离层背离所述加热元件的一面制备测试元件;在所述测试元件背离所述隔离层的一面制备气敏元件;从所述背面向所述正面刻蚀形成聚热腔,以使所述支撑层将所述隔热腔和所述聚热腔隔离。In a second aspect, an embodiment of the present application provides a method for manufacturing a MEMS gas sensor, the method for manufacturing the MEMS gas sensor comprising: etching from the front side of the silicon substrate to the back side facing away from the front side to form an insulating cavity, the insulating cavity comprising a first cavity wall and a second cavity wall arranged opposite to each other; alternately depositing silicon oxide films and silicon nitride films in the insulating cavity to sequentially form silicon oxide layers and silicon nitride layers to form a supporting layer, and connecting the supporting layer to the first cavity wall and the second cavity wall; preparing a heating element in the insulating cavity and arranging it on the supporting layer; depositing a silicon nitride film on a side of the supporting layer facing the front side and a side of the heating element facing the front side to form an isolation layer, so that the isolation layer covers the supporting layer and covers the heating element; preparing a test element on a side of the isolation layer facing away from the heating element; preparing a gas sensitive element on a side of the test element facing away from the isolation layer; etching from the back side to the front side to form a heat collecting cavity, so that the support layer isolates the insulating cavity from the heat collecting cavity.

上述MEMS气体传感器及其制作方法,通过在硅衬底的正面和背面分别设有隔热腔和聚热腔,在隔热腔设有连接于隔热腔腔壁的支撑层来连接于硅衬底,并在支撑层朝向正面的方向上依次布设加热元件、隔离层、测试元件和气敏元件,使得MEMS气体传感器的其他组件能够稳固设置于隔热腔,提高MEMS气体传感器的机械强度的同时,隔热腔能够减缓热对流导致加热元件产生的热量的散失情况,聚热腔能够将加热元件产生的热量更多地聚集在支撑层,进而减少MEMS气体传感器的功率损耗。另外,利用深硅刻蚀工艺和电感耦合等离子刻蚀工艺制作隔热腔和聚热腔,节约制作成本,还通过加热元件电极和测试元件电极的设置方式来缩减器件的体积,进而减小电极占据的空间。The above-mentioned MEMS gas sensor and its manufacturing method are provided with a heat-insulating cavity and a heat-collecting cavity on the front and back of the silicon substrate respectively, and a support layer connected to the wall of the heat-insulating cavity is provided in the heat-insulating cavity to connect to the silicon substrate, and a heating element, an isolation layer, a test element and a gas-sensitive element are arranged in sequence in the direction of the support layer toward the front, so that other components of the MEMS gas sensor can be stably arranged in the heat-insulating cavity, and the mechanical strength of the MEMS gas sensor is improved. At the same time, the heat-insulating cavity can slow down the heat loss generated by the heating element due to heat convection, and the heat-collecting cavity can collect more heat generated by the heating element on the support layer, thereby reducing the power loss of the MEMS gas sensor. In addition, the heat-insulating cavity and the heat-collecting cavity are manufactured by deep silicon etching process and inductively coupled plasma etching process, which saves manufacturing costs, and the volume of the device is reduced by the arrangement of the heating element electrode and the test element electrode, thereby reducing the space occupied by the electrode.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

为了更清楚地说明本申请实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图示出的结构获得其他的附图。In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings required for use in the embodiments or the description of the prior art will be briefly introduced below. Obviously, the drawings described below are only some embodiments of the present application. For ordinary technicians in this field, other drawings can be obtained based on the structures shown in these drawings without paying any creative work.

图1为本申请实施例提供的MEMS气体传感器的剖视图。FIG1 is a cross-sectional view of a MEMS gas sensor provided in an embodiment of the present application.

图2为本申请实施例提供的MEMS气体传感器的立体图。FIG. 2 is a three-dimensional diagram of a MEMS gas sensor provided in an embodiment of the present application.

图3为本申请实施例提供的MEMS气体传感器的制作方法的流程图。FIG3 is a flow chart of a method for manufacturing a MEMS gas sensor provided in an embodiment of the present application.

本申请目的的实现、功能特点及优点将结合实施例,参照附图做进一步说明。The realization of the purpose, functional features and advantages of this application will be further explained in conjunction with embodiments and with reference to the accompanying drawings.

具体实施方式DETAILED DESCRIPTION

为了使本申请的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本申请进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本申请,并不用于限定本申请。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the purpose, technical solutions and advantages of the present application more clearly understood, the present application is further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present application and are not intended to limit the present application. Based on the embodiments in the present application, all other embodiments obtained by ordinary technicians in the field without making creative work are within the scope of protection of the present application.

本申请的说明书和权利要求书及上述附图中的术语“第一”、“第二”、“第三”、“第四”等(如果存在)是用于区别类似的规划对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,换句话说,描述的实施例根据除了这里图示或描述的内容以外的顺序实施。此外,术语“包括”和“具有”以及他们的任何变形,还可以包含其他内容,例如,包含了一系列步骤或单元的过程、方法、系统、产品或设备不必限于只清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法、产品或设备固有的其它步骤或单元。The terms "first", "second", "third", "fourth", etc. (if any) in the specification and claims of this application and the above-mentioned drawings are used to distinguish similar planning objects, and are not necessarily used to describe a specific order or sequence. It should be understood that the data used in this way can be interchangeable where appropriate. In other words, the described embodiments are implemented according to an order other than that illustrated or described herein. In addition, the terms "including" and "having" and any of their variations may also include other content. For example, a process, method, system, product or device that includes a series of steps or units is not necessarily limited to only those steps or units that are clearly listed, but may include other steps or units that are not clearly listed or inherent to these processes, methods, products or devices.

需要说明的是,在本申请中涉及“第一”、“第二”等的描述仅用于描述目的,而不能理解为指示或暗示其相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者多个该特征。另外,各个实施例之间的技术方案可以相互结合,但是必须是以本领域普通技术人员能够实现为基础,当技术方案的结合出现相互矛盾或无法实现时应当认为这种技术方案的结合不存在,也不在本申请要求的保护范围之内。It should be noted that the descriptions involving "first", "second", etc. in this application are only for descriptive purposes and cannot be understood as indicating or implying their relative importance or implicitly indicating the number of technical features indicated. Therefore, the features defined as "first" and "second" may explicitly or implicitly include one or more of the features. In addition, the technical solutions between the various embodiments can be combined with each other, but they must be based on the ability of ordinary technicians in this field to implement them. When the combination of technical solutions is contradictory or cannot be implemented, it should be deemed that such combination of technical solutions does not exist and is not within the scope of protection required by this application.

请参看图1,其为本申请实施例提供的MEMS气体传感器的剖视图。本申请提供一种MEMS气体传感器10,可提高MEMS气体传感器10的机械强度、降低MEMS气体传感器10功率损耗的同时,还能减小MEMS气体传感器10内的器材体积。下面将详尽阐述MEMS气体传感器10中各组件的具体特征。Please refer to Figure 1, which is a cross-sectional view of a MEMS gas sensor provided in an embodiment of the present application. The present application provides a MEMS gas sensor 10, which can improve the mechanical strength of the MEMS gas sensor 10, reduce the power loss of the MEMS gas sensor 10, and reduce the volume of the equipment in the MEMS gas sensor 10. The specific features of each component in the MEMS gas sensor 10 will be described in detail below.

请结合参看图1和图2,MEMS气体传感器10为一种基于半导体金属氧化物的气体传感器。MEMS气体传感器10包括硅衬底1、支撑层2、加热元件3、隔离层4、测试元件5和气敏元件6。硅衬底1整体呈长方体状。硅衬底1包括正面13、以及背离正面13的背面14。其中,正面13设有隔热腔11,隔热腔11用于减少热对流的散失。背面14设有镂空的聚热腔12,聚热腔12用于聚集MEMS气体传感器10中因热传导散失的热量。隔热腔11和聚热腔12连通。硅衬底1还包括隔热腔11相对设置的第一腔壁111和第二腔壁112。本申请通过隔热腔11和聚热腔12来减少MEMS气体传感器10在工作时的功率损耗。Please refer to Figures 1 and 2. The MEMS gas sensor 10 is a gas sensor based on semiconductor metal oxide. The MEMS gas sensor 10 includes a silicon substrate 1, a support layer 2, a heating element 3, an isolation layer 4, a test element 5 and a gas sensitive element 6. The silicon substrate 1 is in the shape of a rectangular parallelepiped as a whole. The silicon substrate 1 includes a front side 13 and a back side 14 facing away from the front side 13. Among them, the front side 13 is provided with an insulating cavity 11, and the insulating cavity 11 is used to reduce the loss of heat convection. The back side 14 is provided with a hollow heat collection cavity 12, and the heat collection cavity 12 is used to collect the heat lost by heat conduction in the MEMS gas sensor 10. The insulating cavity 11 is connected to the heat collection cavity 12. The silicon substrate 1 also includes a first cavity wall 111 and a second cavity wall 112 arranged opposite to the insulating cavity 11. The present application reduces the power loss of the MEMS gas sensor 10 during operation by using the insulating cavity 11 and the heat collection cavity 12.

在本实施例中,支撑层2连接于第一腔壁111和第二腔壁112之间并位于隔热腔11,以在实现支撑MEMS气体传感器10的同时,增强MEMS气体传感器10的机械强度。支撑层2将隔热腔11和聚热腔12隔离。其中,支撑层2由氧化硅薄膜和氮化硅薄膜分别沉积得到的氧化硅层21和氮化硅层22组成。氧化硅层21靠近聚热腔12。氮化硅层22位于氧化硅层21背离聚热腔12的一面。其中,氧化硅层21的厚度为500-700nm。氮化硅层22的厚度为1300-1500nm。本申请中自正面13向支撑层2朝向正面13的一面形成隔热腔11的深度,自背面14向支撑层2朝向背面14的一面形成聚热腔12的深度。隔热腔11的深度小于聚热腔12的深度。优选地,隔热腔11的深度为5-20um。聚热腔12的深度为300-600um。In this embodiment, the support layer 2 is connected between the first cavity wall 111 and the second cavity wall 112 and is located in the heat-insulating cavity 11, so as to support the MEMS gas sensor 10 while enhancing the mechanical strength of the MEMS gas sensor 10. The support layer 2 isolates the heat-insulating cavity 11 from the heat-collecting cavity 12. Among them, the support layer 2 is composed of a silicon oxide layer 21 and a silicon nitride layer 22 obtained by depositing a silicon oxide film and a silicon nitride film respectively. The silicon oxide layer 21 is close to the heat-collecting cavity 12. The silicon nitride layer 22 is located on the side of the silicon oxide layer 21 away from the heat-collecting cavity 12. Among them, the thickness of the silicon oxide layer 21 is 500-700nm. The thickness of the silicon nitride layer 22 is 1300-1500nm. In this application, the depth of the heat-insulating cavity 11 is formed from the front side 13 to the side of the support layer 2 facing the front side 13, and the depth of the heat-collecting cavity 12 is formed from the back side 14 to the side of the support layer 2 facing the back side 14. The depth of the heat-insulating cavity 11 is less than the depth of the heat-collecting cavity 12. Preferably, the depth of the heat insulation cavity 11 is 5-20 um, and the depth of the heat collection cavity 12 is 300-600 um.

进一步地,硅衬底1还包括隔热腔11相对设置于第一腔壁111和第二腔壁112之间的第三腔壁113和第四腔壁114。支撑层2还连接于第三腔壁113和第四腔壁114之间,即第一腔壁111、第三腔壁113、第二腔壁112和第四腔壁114依次连接围成隔热腔11。Furthermore, the silicon substrate 1 further includes a third cavity wall 113 and a fourth cavity wall 114 which are arranged between the first cavity wall 111 and the second cavity wall 112. The support layer 2 is also connected between the third cavity wall 113 and the fourth cavity wall 114, that is, the first cavity wall 111, the third cavity wall 113, the second cavity wall 112 and the fourth cavity wall 114 are sequentially connected to form the thermal insulation cavity 11.

在一些可行的实施例中,支撑层2还由氧化硅薄膜和氮化硅薄膜沉积得到的氧化硅层21和两个氮化硅层22组成。其中,氧化硅层21位于两个氮化硅层22之间。两个氮化硅层22的一者位于氧化硅层21朝向加热元件3的一面,另一者位于氧化硅层21朝向聚热腔12的一面。In some feasible embodiments, the support layer 2 is further composed of a silicon oxide layer 21 and two silicon nitride layers 22 obtained by depositing a silicon oxide film and a silicon nitride film. The silicon oxide layer 21 is located between the two silicon nitride layers 22. One of the two silicon nitride layers 22 is located on the side of the silicon oxide layer 21 facing the heating element 3, and the other is located on the side of the silicon oxide layer 21 facing the heat collecting chamber 12.

在另一些可行的实施例中,支撑层2还可以为其他导热系数低的材料,例如聚酰亚胺,以减少MEMS气体传感器10中因热传导导致热量的散失。In other feasible embodiments, the support layer 2 may also be made of other materials with low thermal conductivity, such as polyimide, to reduce heat loss in the MEMS gas sensor 10 due to heat conduction.

在本实施例中,加热元件3设置于支撑层2并位于隔热腔11内,即加热元件3设置于氮化硅层22背离氧化硅层21的一面。加热元件3的材质包括但不限于钨、多晶硅、铂金等。加热丝的加热元件3包括但不限于圆形、S型、回型等。优选地,加热元件3的厚度为100-500nm。In this embodiment, the heating element 3 is disposed on the support layer 2 and located in the heat insulation cavity 11, that is, the heating element 3 is disposed on the side of the silicon nitride layer 22 away from the silicon oxide layer 21. The material of the heating element 3 includes but is not limited to tungsten, polysilicon, platinum, etc. The heating element 3 of the heating wire includes but is not limited to round, S-shaped, round-shaped, etc. Preferably, the thickness of the heating element 3 is 100-500nm.

在本实施例中,隔离层4由氮化硅薄膜沉积而成。隔离层4覆盖于支撑层2并覆盖加热元件3。本申请中支撑层2和隔离层4为平行设置。测试元件5设置于隔离层4背离加热元件3的一面。测试元件5用于根据气敏元件6感测到的气体获取相应的预设指标,例如呼出气体的成分、呼出气体反映出的呼吸谱等。测试元件5的材料包括但不限于铂金、钯等。测试元件5的形状包括但不限于叉指电极、条形、叉指三电极等。测试元件5的厚度为100-500nm,即加热元件3与测试元件5的厚度可以相等或者不相等。气敏元件6用于感测气体。气敏元件6设置于测试元件5背离隔离层4的一面。In this embodiment, the isolation layer 4 is formed by depositing a silicon nitride film. The isolation layer 4 covers the support layer 2 and covers the heating element 3. In the present application, the support layer 2 and the isolation layer 4 are arranged in parallel. The test element 5 is arranged on the side of the isolation layer 4 away from the heating element 3. The test element 5 is used to obtain corresponding preset indicators according to the gas sensed by the gas sensor 6, such as the composition of the exhaled gas, the respiratory spectrum reflected by the exhaled gas, etc. The material of the test element 5 includes but is not limited to platinum, palladium, etc. The shape of the test element 5 includes but is not limited to forked electrodes, strips, forked three electrodes, etc. The thickness of the test element 5 is 100-500nm, that is, the thickness of the heating element 3 and the test element 5 can be equal or unequal. The gas sensor 6 is used to sense gas. The gas sensor 6 is arranged on the side of the test element 5 away from the isolation layer 4.

在本实施例中,支撑层2包括用于支撑加热元件3的第一支撑部23、以及分别连接于第一支撑部23靠近第一腔壁111和第二腔壁112的两侧的第二支撑部24和第三支撑部25。MEMS气体传感器10设有为MEMS气体传感器10正常工作提供能量的电极7。第二支撑部24和第三支撑部25背离第一支撑部23的一面都设有电极7。第二支撑部24和第三支撑部25还连接于第三腔壁113和第四腔壁114之间且位于隔热腔11内。当电极7设置于第二支撑部24和第三支撑部25背离第一支撑部23的一面时,电极7未凸出于正面13,以减小MEMS气体传感器10的大小。In this embodiment, the support layer 2 includes a first support portion 23 for supporting the heating element 3, and a second support portion 24 and a third support portion 25 respectively connected to both sides of the first support portion 23 close to the first cavity wall 111 and the second cavity wall 112. The MEMS gas sensor 10 is provided with an electrode 7 for providing energy for the normal operation of the MEMS gas sensor 10. The second support portion 24 and the third support portion 25 are provided with electrodes 7 on one side away from the first support portion 23. The second support portion 24 and the third support portion 25 are also connected between the third cavity wall 113 and the fourth cavity wall 114 and are located in the thermal insulation cavity 11. When the electrode 7 is provided on one side of the second support portion 24 and the third support portion 25 away from the first support portion 23, the electrode 7 does not protrude from the front side 13 to reduce the size of the MEMS gas sensor 10.

进一步地,隔离层4分别与第二支撑部24和第三支撑部25具有一定间隙。电极7包括加热元件电极71和测试元件电极72。其中,加热元件电极71设有容置于间隙的电极连接部711,以使加热元件电极71通过电极连接部711电连接于加热元件3。测试元件电极72套设于电极连接部711且与测试元件5电连接,以减小MEMS气体传感器10的器材大小。测试元件5在测试元件电极72提供的能量下根据气体来获取预设指标。加热元件3在加热元件电极71提供的能量下产生热量而使气敏元件6和测试元件5具有一定温度,以提高气敏元件6和测试元件5的灵敏度,进而提高MEMS气体传感器10的感测效率。Further, the isolation layer 4 has a certain gap with the second support portion 24 and the third support portion 25 respectively. The electrode 7 includes a heating element electrode 71 and a test element electrode 72. Among them, the heating element electrode 71 is provided with an electrode connecting portion 711 accommodated in the gap, so that the heating element electrode 71 is electrically connected to the heating element 3 through the electrode connecting portion 711. The test element electrode 72 is sleeved on the electrode connecting portion 711 and is electrically connected to the test element 5 to reduce the equipment size of the MEMS gas sensor 10. The test element 5 obtains a preset index according to the gas under the energy provided by the test element electrode 72. The heating element 3 generates heat under the energy provided by the heating element electrode 71 so that the gas sensitive element 6 and the test element 5 have a certain temperature, so as to improve the sensitivity of the gas sensitive element 6 and the test element 5, thereby improving the sensing efficiency of the MEMS gas sensor 10.

请参看图3,其为本申请实施例提供的MEMS气体传感器的制作方法的流程图。本申请还提供一种MEMS气体传感器的制作方法,用于制作MEMS气体传感器10。MEMS气体传感器10已在上文详尽阐述,在此不做赘述。MEMS气体传感器的制作方法包括步骤S101-S107。Please refer to FIG. 3, which is a flow chart of a method for manufacturing a MEMS gas sensor provided in an embodiment of the present application. The present application also provides a method for manufacturing a MEMS gas sensor, which is used to manufacture a MEMS gas sensor 10. The MEMS gas sensor 10 has been described in detail above and will not be described here. The method for manufacturing a MEMS gas sensor includes steps S101-S107.

步骤S101,从硅衬底的正面向背离正面的背面刻蚀形成隔热腔。Step S101, etching from the front side of the silicon substrate to the back side facing away from the front side to form a heat-insulating cavity.

在步骤S101中,采用电感耦合等离子体-反应离子刻蚀(ICP-RIE)工艺自正面13向背面14刻蚀,以形成隔热腔11。隔热腔11的深度为5-20um。本申请还可以采用绝缘衬底上的硅(Silicon-On-Insulator,SOI),即SOI片来替代硅衬底1进行隔热腔11的刻蚀,以减少ICP-RIE工艺中二氧化硅的制作流程。其中,隔热腔11包括相对设置的第一腔壁111和第二腔壁112。隔热腔11还包括相对设置于第一腔壁111和第二腔壁112之间的第三腔壁113和第四腔壁114。在硅衬底1的正面13刻蚀隔热腔11的同时,还在隔热腔11以外的位置且分别靠近第一腔壁111和第二腔壁112的两侧刻蚀有用于容置电极7的容置件(图未示),以使电极7在MEMS气体传感器10中未凸出于正面13,进而减小MEMS气体传感器10的大小。In step S101, an inductively coupled plasma-reactive ion etching (ICP-RIE) process is used to etch from the front side 13 to the back side 14 to form an insulating cavity 11. The depth of the insulating cavity 11 is 5-20um. The present application can also use silicon-on-insulator (SOI), that is, SOI wafer to replace the silicon substrate 1 to etch the insulating cavity 11, so as to reduce the silicon dioxide manufacturing process in the ICP-RIE process. Among them, the insulating cavity 11 includes a first cavity wall 111 and a second cavity wall 112 arranged opposite to each other. The insulating cavity 11 also includes a third cavity wall 113 and a fourth cavity wall 114 arranged opposite to each other between the first cavity wall 111 and the second cavity wall 112. While the insulation cavity 11 is being etched on the front side 13 of the silicon substrate 1, a receiving member (not shown) for receiving the electrode 7 is also etched outside the insulation cavity 11 and on both sides of the first cavity wall 111 and the second cavity wall 112, respectively, so that the electrode 7 does not protrude from the front side 13 in the MEMS gas sensor 10, thereby reducing the size of the MEMS gas sensor 10.

步骤S102,在隔热腔内交替沉积氧化硅薄膜和氮化硅薄膜,以依次形成氧化硅层和氮化硅层而形成支撑层,并使支撑层连接于第一腔壁和第二腔壁。Step S102 , alternately depositing silicon oxide films and silicon nitride films in the heat-insulating cavity to sequentially form a silicon oxide layer and a silicon nitride layer to form a support layer, and connecting the support layer to the first cavity wall and the second cavity wall.

在步骤S102中,采用等离子体增强化学气相沉积(PECVD)工艺和低压力化学气相沉积(LPCVD)工艺在隔热腔11内交替沉积氧化硅薄膜和氮化硅薄膜,以形成支撑层2。氮化硅层22位于隔热腔11朝向正面13的一侧,氧化硅层21位于氮化硅层22背离正面13的一面,即支撑层2自隔热腔11至正面13依次为氧化硅层21和氮化硅层22。氧化硅层21的厚度为500-700nm。氮化硅层22的厚度为1300-1500nm。本申请还分别在隔热腔11和容置件交替沉积氧化硅薄膜和氮化硅薄膜,以形成位于隔热腔11的第一支撑部23、以及分别连接于第一支撑部23靠近第一腔壁111和第二腔壁112的两侧的第二支撑部24和第三支撑部25。第二支撑部24和第三支撑部25用于设置电极7。In step S102, a silicon oxide film and a silicon nitride film are alternately deposited in the insulation cavity 11 by a plasma enhanced chemical vapor deposition (PECVD) process and a low pressure chemical vapor deposition (LPCVD) process to form a support layer 2. The silicon nitride layer 22 is located on the side of the insulation cavity 11 facing the front surface 13, and the silicon oxide layer 21 is located on the side of the silicon nitride layer 22 away from the front surface 13, that is, the support layer 2 is a silicon oxide layer 21 and a silicon nitride layer 22 from the insulation cavity 11 to the front surface 13. The thickness of the silicon oxide layer 21 is 500-700nm. The thickness of the silicon nitride layer 22 is 1300-1500nm. The present application also alternately deposits silicon oxide films and silicon nitride films in the insulation cavity 11 and the accommodating member to form a first support portion 23 located in the insulation cavity 11, and a second support portion 24 and a third support portion 25 respectively connected to the first support portion 23 on both sides close to the first cavity wall 111 and the second cavity wall 112. The second supporting portion 24 and the third supporting portion 25 are used to place the electrode 7 .

步骤S103,在隔热腔内制备加热元件并设置于支撑层。Step S103, preparing a heating element in the heat-insulating cavity and setting it on the support layer.

在步骤S103中,采用磁控溅射工艺和剥离工艺在支撑层2制备加热元件3。其中,加热元件3的厚度为100-500nm。加热元件3的材质包括但不限于金、铂金、钨、多晶硅等。加热元件3的形状包括但不限于S型、回型、圆形、椭圆型等。同时,在第二支撑部24和第三支撑部25分别设有相应的加热元件电极71,并使加热元件3电连接于加热元件电极71。In step S103, a heating element 3 is prepared on the support layer 2 by a magnetron sputtering process and a stripping process. The thickness of the heating element 3 is 100-500 nm. The material of the heating element 3 includes but is not limited to gold, platinum, tungsten, polysilicon, etc. The shape of the heating element 3 includes but is not limited to S-shaped, round, circular, elliptical, etc. At the same time, corresponding heating element electrodes 71 are respectively provided on the second support portion 24 and the third support portion 25, and the heating element 3 is electrically connected to the heating element electrode 71.

步骤S104,在支撑层朝向正面的一面和加热元件朝向正面的一面沉积氮化硅薄膜形成隔离层,以使隔离层覆盖于支撑层并覆盖加热元件。Step S104, depositing a silicon nitride film on a side of the support layer facing the front surface and a side of the heating element facing the front surface to form an isolation layer, so that the isolation layer covers the support layer and the heating element.

在步骤S104中,采用PECVD工艺在支撑层2朝向正面13的一面和加热元件3朝向正面13的一面沉积氮化硅薄膜形成隔离层4。隔离层4的厚度为300-500nm。隔离层4分别与第二支撑部24和第三支撑部25具有一定间隙。加热元件电极71设有容置于间隙的电极连接部711,以使加热元件3通过电极连接部711电连接于加热元件电极71。且加热元件3和加热元件电极71之间具有一定高度差,可减小隔离层4覆盖加热元件3时的垂直高度,进而减少MEMS气体传感器10的材料损耗。In step S104, a silicon nitride film is deposited on one side of the support layer 2 facing the front surface 13 and one side of the heating element 3 facing the front surface 13 by a PECVD process to form an isolation layer 4. The thickness of the isolation layer 4 is 300-500 nm. The isolation layer 4 has a certain gap with the second support portion 24 and the third support portion 25 respectively. The heating element electrode 71 is provided with an electrode connecting portion 711 accommodated in the gap, so that the heating element 3 is electrically connected to the heating element electrode 71 through the electrode connecting portion 711. There is a certain height difference between the heating element 3 and the heating element electrode 71, which can reduce the vertical height when the isolation layer 4 covers the heating element 3, thereby reducing the material loss of the MEMS gas sensor 10.

步骤S105,在隔离层背离加热元件的一面制备测试元件。Step S105 , preparing a test element on a side of the isolation layer facing away from the heating element.

在步骤S105中,采用磁控溅射工艺和剥离技术工艺在隔离层4背离加热元件3的一面制备测试元件5。其中,测试元件5的材质包括但不限于金、铂金、钯等。测试元件5的厚度为100-500nm。优选地,测试元件5的厚度为100-300nm。测试元件5的形状包括但不限于叉指电极、单电极、三电极结构的叉指电极等。同时,在第二支撑部24和第三支撑部25分别设有相应的测试元件电极72,并使测试元件5电连接于测试元件电极72。其中,测试元件电极72套设于电极连接部711。In step S105, a test element 5 is prepared on the side of the isolation layer 4 away from the heating element 3 by using a magnetron sputtering process and a stripping technology process. The material of the test element 5 includes but is not limited to gold, platinum, palladium, etc. The thickness of the test element 5 is 100-500nm. Preferably, the thickness of the test element 5 is 100-300nm. The shape of the test element 5 includes but is not limited to a forked electrode, a single electrode, a forked electrode of a three-electrode structure, etc. At the same time, corresponding test element electrodes 72 are respectively provided on the second support portion 24 and the third support portion 25, and the test element 5 is electrically connected to the test element electrode 72. The test element electrode 72 is sleeved on the electrode connecting portion 711.

步骤S106,在测试元件背离隔离层的一面制备气敏元件。Step S106, preparing a gas sensor on a side of the test element facing away from the isolation layer.

在步骤S106中,采用磁控溅射工艺在测试元件5背离隔离层4的一面制备气敏元件6,以使气敏元件6覆盖于测试元件5。其中,气敏元件6的材质包括但不限于二氧化锡、氧化锌等。In step S106, a gas sensor 6 is prepared on the side of the test element 5 away from the isolation layer 4 by magnetron sputtering process, so that the gas sensor 6 covers the test element 5. The material of the gas sensor 6 includes but is not limited to tin dioxide, zinc oxide and the like.

步骤S107,从背面向正面刻蚀形成聚热腔,以使支撑层将隔热腔和聚热腔隔离。Step S107, etching from the back side to the front side to form a heat collecting cavity, so that the support layer isolates the heat insulating cavity and the heat collecting cavity.

在步骤S107中,采用深硅刻蚀工艺自背面14向正面13刻蚀,以形成聚热腔12。聚热腔12的深度为300-600um,即聚热腔12的深度大于隔热腔11的深度。In step S107 , a deep silicon etching process is used to etch from the back surface 14 to the front surface 13 to form a heat collection cavity 12 . The depth of the heat collection cavity 12 is 300-600 um, that is, the depth of the heat collection cavity 12 is greater than the depth of the heat insulation cavity 11 .

上述实施例中,通过在硅衬底的正面和背面分别设有隔热腔和聚热腔,在隔热腔设有连接于隔热腔腔壁的支撑层来连接于硅衬底,并在支撑层朝向正面的方向上依次布设加热元件、隔离层、测试元件和气敏元件,使得MEMS气体传感器的其他组件能够稳固设置于隔热腔,提高MEMS气体传感器的机械强度的同时,隔热腔能够减缓热对流导致加热元件产生的热量的散失情况,聚热腔能够将加热元件产生的热量更多地聚集在支撑层,进而减少MEMS气体传感器的功率损耗。另外,利用深硅刻蚀工艺和电感耦合等离子刻蚀工艺制作隔热腔和聚热腔,节约制作成本,还通过加热元件电极和测试元件电极的设置方式来缩减器件的体积,进而减小电极占据的空间。In the above embodiment, by providing an insulation cavity and a heat collection cavity on the front and back of the silicon substrate respectively, providing a support layer connected to the insulation cavity wall in the insulation cavity to connect to the silicon substrate, and sequentially arranging the heating element, the isolation layer, the test element and the gas-sensitive element in the direction of the support layer toward the front, the other components of the MEMS gas sensor can be stably arranged in the insulation cavity, and the mechanical strength of the MEMS gas sensor can be improved. The insulation cavity can slow down the heat loss caused by the heating element due to heat convection, and the heat collection cavity can gather more heat generated by the heating element on the support layer, thereby reducing the power loss of the MEMS gas sensor. In addition, the insulation cavity and the heat collection cavity are made by deep silicon etching process and inductively coupled plasma etching process, which saves the production cost, and the volume of the device is reduced by the arrangement of the heating element electrode and the test element electrode, thereby reducing the space occupied by the electrode.

显然,本领域的技术人员可以对本申请进行各种改动和变型而不脱离本申请的精神和范围。这样,倘且本申请的这些修改和变型属于本申请权利要求及其等同技术的范围之内,则本申请也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the present application without departing from the spirit and scope of the present application. Thus, if these modifications and variations of the present application fall within the scope of the claims of the present application and their equivalents, the present application is also intended to include these modifications and variations.

应该理解的是,虽然附图的流程图中的各个步骤按照箭头的指示依次显示,但是这些步骤并不是必然按照箭头指示的顺序依次执行。除非本文中有明确的说明,这些步骤的执行并没有严格的顺序限制,其可以以其他的顺序执行。而且,附图的流程图中的至少一部分步骤可以包括多个子步骤或者多个阶段,这些子步骤或者阶段并不必然是在同一时刻执行完成,而是可以在不同的时刻执行,其执行顺序也不必然是依次进行,而是可以与其他步骤或者其他步骤的子步骤或者阶段的至少一部分轮流或者交替地执行。It should be understood that, although the steps in the flowchart of the accompanying drawings are displayed in sequence as indicated by the arrows, these steps are not necessarily executed in sequence in the order indicated by the arrows. Unless otherwise specified herein, there is no strict order restriction on the execution of these steps, and they can be executed in other orders. Moreover, at least a part of the steps in the flowchart of the accompanying drawings may include multiple sub-steps or multiple stages, and these sub-steps or stages are not necessarily executed at the same time, but can be executed at different times, and their execution order is not necessarily sequential, but can be executed in turn or alternately with other steps or at least a part of the sub-steps or stages of other steps.

以上所列举的仅为本申请较佳实施例而已,当然不能以此来限定本申请之权利范围,因此依本申请权利要求所作的等同变化,仍属于本申请所涵盖的范围。The above examples are only preferred embodiments of the present application, and certainly cannot be used to limit the scope of rights of the present application. Therefore, equivalent changes made according to the claims of the present application still fall within the scope covered by the present application.

Claims (4)

1.一种MEMS气体传感器,其特征在于,所述MEMS气体传感器包括:1. A MEMS gas sensor, characterized in that the MEMS gas sensor comprises: 硅衬底,包括正面、以及背离所述正面的背面,所述正面设有隔热腔,所述背面设有聚热腔,所述隔热腔和所述聚热腔连通,所述硅衬底还包括所述隔热腔相对设置的第一腔壁和第二腔壁,所述第一腔壁和所述第二腔壁分别垂直于所述正面;A silicon substrate, comprising a front side and a back side facing away from the front side, wherein the front side is provided with a heat-insulating cavity, the back side is provided with a heat-collecting cavity, the heat-insulating cavity and the heat-collecting cavity are connected, and the silicon substrate further comprises a first cavity wall and a second cavity wall arranged opposite to the heat-insulating cavity, the first cavity wall and the second cavity wall are respectively perpendicular to the front side; 支撑层,连接于所述第一腔壁和所述第二腔壁之间并位于所述隔热腔,且所述支撑层将所述隔热腔和所述聚热腔隔离;A support layer, connected between the first cavity wall and the second cavity wall and located in the heat-insulating cavity, and the support layer isolates the heat-insulating cavity from the heat-collecting cavity; 加热元件,设置于所述支撑层并位于所述隔热腔内;A heating element, disposed on the support layer and located in the heat insulation cavity; 隔离层,覆盖于所述支撑层并覆盖所述加热元件,所述隔离层由氮化硅薄膜沉积而成;An isolation layer, covering the support layer and the heating element, wherein the isolation layer is formed by depositing a silicon nitride film; 测试元件,设置于所述隔离层背离所述加热元件的一面;以及a test element, disposed on a side of the isolation layer facing away from the heating element; and 气敏元件,设置于所述测试元件背离所述隔离层的一面;A gas sensor is arranged on a side of the test element away from the isolation layer; 其中,所述硅衬底还包括所述隔热腔相对设置于所述第一腔壁和所述第二腔壁之间的第三腔壁和第四腔壁,所述支撑层还连接于所述第三腔壁和所述第四腔壁之间;所述MEMS气体传感器设有为所述MEMS气体传感器正常工作提供能量的电极,所述支撑层包括用于支撑所述加热元件的第一支撑部、以及分别连接于所述第一支撑部靠近所述第一腔壁和所述第二腔壁的两侧的第二支撑部和第三支撑部,所述第二支撑部和所述第三支撑部背离所述第一支撑部的一面都设有所述电极;所述第二支撑部和所述第三支撑部还连接于所述第三腔壁和所述第四腔壁之间且位于所述隔热腔内;当电极设置于第二支撑部和第三支撑部背离第一支撑部的一面时,所述电极未凸出于所述正面;所述隔离层分别与所述第二支撑部和所述第三支撑部具有一定间隙,所述电极包括加热元件电极和测试元件电极,所述加热元件电极设有容置于所述间隙的电极连接部,以使所述加热元件电极通过所述电极连接部电连接于所述加热元件,所述测试元件电极套设于所述电极连接部且与所述测试元件电连接。Wherein, the silicon substrate also includes a third cavity wall and a fourth cavity wall which are arranged between the first cavity wall and the second cavity wall relative to the thermal insulation cavity, and the support layer is also connected between the third cavity wall and the fourth cavity wall; the MEMS gas sensor is provided with an electrode for providing energy for the normal operation of the MEMS gas sensor, and the support layer includes a first support portion for supporting the heating element, and a second support portion and a third support portion which are respectively connected to both sides of the first support portion close to the first cavity wall and the second cavity wall, and the second support portion and the third support portion are provided with the electrode on one side facing away from the first support portion; The second support part and the third support part are also connected between the third cavity wall and the fourth cavity wall and are located in the heat-insulating cavity; when the electrode is arranged on the side of the second support part and the third support part facing away from the first support part, the electrode does not protrude from the front side; the isolation layer has a certain gap with the second support part and the third support part respectively, and the electrode includes a heating element electrode and a test element electrode, and the heating element electrode is provided with an electrode connecting part accommodated in the gap so that the heating element electrode is electrically connected to the heating element through the electrode connecting part, and the test element electrode is sleeved on the electrode connecting part and electrically connected to the test element. 2.如权利要求1所述的MEMS气体传感器,其特征在于,所述隔热腔的深度小于所述聚热腔的深度。2 . The MEMS gas sensor according to claim 1 , wherein the depth of the thermal insulation cavity is smaller than the depth of the heat focusing cavity. 3.如权利要求1所述的MEMS气体传感器,其特征在于,所述支撑层由氧化硅薄膜和所述氮化硅薄膜分别沉积得到的氧化硅层和氮化硅层组成,所述氧化硅层靠近所述聚热腔,所述氮化硅层位于所述氧化硅层背离所述聚热腔的一面,所述加热元件设置于所述氮化硅层背离所述氧化硅层的一面。3. The MEMS gas sensor as described in claim 1 is characterized in that the supporting layer is composed of a silicon oxide layer and a silicon nitride layer obtained by depositing a silicon oxide film and a silicon nitride film respectively, the silicon oxide layer is close to the heat focusing cavity, the silicon nitride layer is located on a side of the silicon oxide layer away from the heat focusing cavity, and the heating element is arranged on a side of the silicon nitride layer away from the silicon oxide layer. 4.一种权利要求1-3任一项所述的MEMS气体传感器的制作方法,其特征在于,所述MEMS气体传感器的制作方法包括:4. A method for manufacturing a MEMS gas sensor according to any one of claims 1 to 3, characterized in that the method for manufacturing the MEMS gas sensor comprises: 采用电感耦合等离子体-反应离子刻蚀工艺从硅衬底的正面向背离所述正面的背面刻蚀形成隔热腔,所述隔热腔包括相对设置的第一腔壁和第二腔壁;Using an inductively coupled plasma-reactive ion etching process, etching from the front side of the silicon substrate to the back side away from the front side to form a heat-insulating cavity, wherein the heat-insulating cavity includes a first cavity wall and a second cavity wall that are arranged opposite to each other; 在所述隔热腔内交替沉积氧化硅薄膜和氮化硅薄膜,以依次形成氧化硅层和氮化硅层而形成支撑层,并使所述支撑层连接于所述第一腔壁和所述第二腔壁,所述第一腔壁和所述第二腔壁分别垂直于所述正面;Alternately depositing a silicon oxide film and a silicon nitride film in the heat-insulating cavity to sequentially form a silicon oxide layer and a silicon nitride layer to form a support layer, and connecting the support layer to the first cavity wall and the second cavity wall, wherein the first cavity wall and the second cavity wall are respectively perpendicular to the front surface; 在所述隔热腔内制备加热元件并设置于所述支撑层;A heating element is prepared in the heat-insulating cavity and arranged on the supporting layer; 在所述支撑层朝向所述正面的一面和所述加热元件朝向所述正面的一面沉积氮化硅薄膜形成隔离层,以使所述隔离层覆盖于所述支撑层并覆盖所述加热元件;Depositing a silicon nitride film on a side of the support layer facing the front surface and a side of the heating element facing the front surface to form an isolation layer, so that the isolation layer covers the support layer and the heating element; 在所述隔离层背离所述加热元件的一面制备测试元件;Prepare a test element on a side of the isolation layer facing away from the heating element; 在所述测试元件背离所述隔离层的一面制备气敏元件;以及Preparing a gas sensor on a side of the test element facing away from the isolation layer; and 采用深硅刻蚀工艺从所述背面向所述正面刻蚀形成聚热腔,以使所述支撑层将所述隔热腔和所述聚热腔隔离。A deep silicon etching process is adopted to etch from the back side to the front side to form a heat collecting cavity, so that the support layer isolates the heat insulating cavity from the heat collecting cavity.
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