CN118383374B - A composition containing afolanar and bromocyanamide - Google Patents
A composition containing afolanar and bromocyanamideInfo
- Publication number
- CN118383374B CN118383374B CN202410456529.8A CN202410456529A CN118383374B CN 118383374 B CN118383374 B CN 118383374B CN 202410456529 A CN202410456529 A CN 202410456529A CN 118383374 B CN118383374 B CN 118383374B
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- CN
- China
- Prior art keywords
- composition
- cyantraniliprole
- polyoxyethylene ether
- aforana
- agent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/02—Acaricides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
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- Life Sciences & Earth Sciences (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Insects & Arthropods (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明提供一种含有阿福拉纳和溴氰虫酰胺的组合物，其中阿福拉纳与溴氰虫酰胺的重量比为1:100至100:1。本发明还涉及所述的组合物用于防治农业昆虫中的应用，具有协同增效作用。This invention provides a composition containing afolanar and broflanilide, wherein the weight ratio of afolanar to broflanilide is 1:100 to 100:1. This invention also relates to the application of the composition in the control of agricultural insects, exhibiting a synergistic effect.
Description
Technical Field
The invention belongs to the field of agriculture, and particularly relates to a composition containing aforana and cyantraniliprole and application thereof.
Background
Afrana (Afoxolaner) is an isoxazoline insecticide and acaricide, which acts on ligand-gated chloride ion channels, especially inhibit neurotransmitter gamma-aminobutyric acid (GABA) -gated channels, so as to block the transmission of chloride ions from a presynaptic membrane to a postsynaptic membrane, thereby increasing the activity of animal neurons and causing excessive excitation and death. The afrana is firstly used in the field of veterinary medicines, is an in-vitro insect repellent for dogs which kill two parasites, namely ticks and fleas, and has the characteristics of quick response, high safety, convenience in oral administration and the like. Next, aforana was found to be useful in agriculture for controlling agricultural pests.
Cyantraniliprole (Cyantraniliprole) is a second-generation ryanodine receptor inhibitor pesticide successfully developed by DuPont company after chlorantraniliprole, and cyantraniliprole is formed by changing various polar groups on benzene rings, so that the insecticidal composition has higher efficiency, wider application range and can effectively control lepidoptera, hemiptera and coleopteran pests.
CN109068651a discloses a composition comprising an isoxazoline compound which may be a compound of the structure (Ia) (i.e. aforana) and at least one further active agent which may be abamectin or the like, which composition is useful in the veterinary field.
No report related to the combination of aforana and cyantraniliprole is found in the prior art.
Summary of The Invention
The inventor discovers that the aforana and the cyantraniliprole have a synergistic effect in the aspect of insect control through researches. Based on this, the present invention has been completed.
The invention relates to a composition containing aforana and cyantraniliprole, wherein the weight ratio of aforana to cyantraniliprole is 1:100-100:1.
The composition according to the invention is characterized in that the weight ratio of aforana to cyantraniliprole is preferably 1:50 to 100:1.
The composition according to the invention is characterized in that it further comprises agriculturally acceptable adjuvants and/or carriers.
The composition is characterized in that the pesticide composition is prepared into suspending agents, aqueous emulsion, wettable powder, water dispersible granules, emulsifiable concentrates and microemulsions.
The composition according to the invention is characterized in that the active ingredient content of the composition is 1-90% by weight.
The use of the composition according to the invention for controlling agricultural insects.
The use according to the invention is characterized in that the agricultural insect is preferably a lepidopteran insect.
The method for controlling agricultural insects by using the composition is characterized in that the composition is contacted with the agricultural insects or the composition is applied to the living environment of the agricultural insects.
Detailed Description
In one aspect, the invention provides a composition containing aforana and cyantraniliprole, wherein the weight ratio of aforana to cyantraniliprole in the composition is 1:100-100:1.
Preferably, the weight ratio of aforana to cyantraniliprole is from 1:50 to 100:1, more preferably from 1:25 to 75:1, for example from 1:25, 1:20, 1:15, 1:10, 1:5, 1:1, 5:1, 10:1, 15:1, 20:1, 25:1, 50:1, 75:1, most preferably from 10:1 to 50:1.
In one embodiment of the invention, the composition further comprises agriculturally acceptable auxiliary agents and/or carriers, and the pesticide composition is prepared into suspending agents, aqueous emulsion, wettable powder, water dispersible granules, emulsifiable concentrates and microemulsions. Preferably preparing suspending agents, aqueous emulsion, water dispersible granules and wettable powder.
The total amount of active ingredient in the formulation is 1-90%, preferably 5-80%, more preferably 6-50%.
Agriculturally acceptable adjuvants and/or carriers include, but are not limited to, dispersants, wetting agents, emulsifiers, solvents, thickeners, antifreeze agents, binders, disintegrants, defoamers, carriers, and the like. Wherein, the
The dispersing agent can be selected from one or more of nonylphenol polyoxyethylene ether, glycerin fatty acid polyoxyethylene ether, polyoxyethylene alkylaryl ether, polyoxyethylene lanolin alcohol, alkyl naphthalene sulfonate, naphthalene sulfonate formaldehyde condensate sodium salt, lignin sulfonate, sodium p-hydroxyphenyl lignin sulfonate, fatty alcohol polyoxyethylene ether sulfate, alkylphenol polyoxyethylene ether formaldehyde condensate, dodecyl trimethyl ammonium salt, alkyl dimethyl benzyl ammonium salt, p-methoxy fatty acid amide benzene sulfonic acid, p-methoxy fatty acid amide benzene sulfonate, fatty alcohol polyoxyethylene ether phosphate and polyoxyethylene sorbitan fatty acid ester.
The wetting agent can be selected from one or more of sodium lauroyl sarcosinate, sodium N-lauroyl glutamate, dioctyl sulfosuccinate, polyoxyethylene alkylaryl ether phosphate, trisiloxane polyoxyethylene ether, sodium dodecyl sulfate, calcium dodecyl benzene sulfonate, sodium isooctyl succinate sulfonate, sodium oleoyl methyl taurate, triphenyl ethylphenol polyoxyethylene ether, castor oil polyoxyethylene ether, polyoxyethylene fatty acid ester, higher fatty acid glyceride, sorbitan fatty acid ester, fatty alcohol polyoxyethylene ether and alkylphenol polyoxyethylene ether phosphate.
The emulsifier can be selected from one or more of lignin sulfonate, naphthalene sulfonate formaldehyde condensate, benzyl dimethyl phenol polyoxyethylene ether, styrylphenyl polyoxyethylene ether, phenethyl phenol polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, polyoxyethylene alkyl ether, alkylphenol formaldehyde resin polyoxyethylene ether, polyoxyethylene sorbitol fatty acid ester, sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, calcium dodecyl benzene sulfonate, nonylphenol polyoxyethylene ether phosphate, phenylphenol polyoxyethylene ether phosphate, styrene polyoxyethylene ether ammonium sulfate salt, sorbitan monostearate polyoxyethylene ether and sorbitan fatty acid ester polyoxyethylene ether.
The solvent can be selected from one or more of acetone, dimethylformamide, dimethyl sulfoxide, xylene, chloroform, dichloromethane, ethyl acetate, cyclohexane, ethyl glycol ether, cyclohexanone, N-methylpyrrolidone, coconut oil fatty acid methyl ester, cyclohexanol, methyl glycol ether, acetonitrile, paraffin, tetrahydronaphthalene, isophorone, soybean oil, cotton seed oil, methyl esterified vegetable oil and dimethyl phthalate.
The thickener is selected from one or more of acacia, carboxymethyl cellulose, sodium carboxymethyl cellulose, xanthan gum, gelatin, polyvinyl alcohol, magnesium aluminum silicate, and sodium alginate.
The antifreezing agent can be one or more selected from ethylene glycol, propylene glycol, glycerol, polyethylene glycol and sorbitol.
The binder may be one or more selected from starch, dextrin, sucrose, carboxymethyl cellulose, carboxyethyl cellulose, gelatin, acacia, and xanthan gum.
The disintegrating agent can be one or more selected from sodium sulfate, calcium sulfate, sodium bicarbonate, ammonium sulfate, magnesium chloride, sodium carboxymethyl starch and urea.
The defoamer can be selected from one or more of silicone, butyl phosphate, isobutyl phosphate and n-octanol.
The carrier is one or more selected from diatomite, kaolin, bentonite, attapulgite, montmorillonite, calcium carbonate, zeolite, acid clay, water, castor oil, soybean oil, corn oil, turpentine, rapeseed oil, methyl oleate, coconut oil, and mineral oil.
Another aspect of the invention relates to the use of said composition for controlling agricultural insects. Wherein:
suitable agricultural plants include:
crops such as rice, wheat, barley, sorghum, corn, cotton, soybean, bean, peanut, buckwheat, beet, rape, sunflower, sugarcane, tobacco, etc.
Vegetables such as cucumber, eggplant, tomato, white gourd, potato, radish, mustard, kohlrabi, cabbage, broccoli, etc.
Fruit trees such as apples, peaches, cherries, apricots, oranges, lemons, blueberries, grapes, bananas and the like.
Agricultural insects that can be used for control include:
Lepidoptera: plutella xylostella (Plutellaxylostella), cabbage caterpillar (PierisrapaeLinnaeus), spodoptera frugiperda (Spodopterafugiperda), armyworm (spodoptera frugiperda), looper (Rachiplusianu), soybean looper (Pseudoplusiaincludens), spodoptera frugiperda (SESAMIAINFERENS), cnaphalocrocis medinalis (CnaphalocrocismedinalisGuenee), chilo suppressalis (Chilo suppressalis), tomato spotted fly (Tutaabsoluta), spodoptera frugiperda (trichoplusia ni), pholiota namei (Sesamianonagrioides), spodoptera frugiperda (trichoplusia ni), cabbage looper (Mamestrabrassicae), citrus leaf miner (Phyllocnistiscitrella), carposina pyrifolia (Grapholithamolesta), armyworm (PseudaletiaunipunctaHaworth), cotton bollworm (EariasvittellaFabricius), cotton bollworm (Adoxophyesorana), beet armyworm (Adoxophyesorana), plutella xylostella (Adoxophyesorana), cabbage looper (Adoxophyesorana), cotton weeping moth (Adoxophyesorana), and cotton weeping moth (Adoxophyesorana).
Diptera, aedes aegypti (AEDESAEGYPTI), liriomyza sativae (Liriomyzabrassicae), allium fistulosum (Phorbiaantiqua), fruit fly in the middle sea (CERATITISCAPITATA), cabbage species fly (Deliaradicum), melon fruit fly (Bactroceracucurbitae), carrot stem fly (Psilarosae), house fly (MuscadomesticaLinnaeus), citrus fruit fly (Bactroceradorsalis), wheat species fly (Deliacoarctata), wheat red plasmide (Sitodiplosismosellana), midge (Mayetioladestructor), midge (Culextarsalis), leaf miner (Liriomyzatrifolii), sheep lice fly (Melophagusovinus), apple fruit fly (Rhagoletispomonella), cherry fruit fly (Rhagoletiscerasi), rape leaf goiter (Dasineurabrassicae), olive fruit fly (Dacusoleae), alfalfa liriomyza sativae (Agromyzafrontella).
Bai Beifei lice (SogatellafurciferaHorvath), white fly (Trialeurodesvaporariorum), broad bean aphid (AphisfabaeScopoli), strawberry root aphid (Aphisforbesi), fringed plant bug (Leptocorisaoratorius), soybean Aphid (APHISGLYCINES), euphorbia lathyris aphid (Macrosiphumeuphorbiae), brown rice planthopper (Nilaparvatalugens), green plant bug (NezaraviridulaLinnaeus), cabbage aphid (Brevicorynebrassicae), sweet potato whitefly (Bemisiatabaci), citrus psyllid (Diaphorinacitri), black sheet scale (Parlatoriaziziphi), black tail leafhopper (Nephotettixnigropictus), red mealybugs (Ceroplastesrubens), red mealybugs (Aonidiellaaurantii), gray plant hoppers (Laodelphaxstriatellus), cowpea aphid (AphiscraccivoraKoch), citrus binary aphid (Toxopteraaurantiiand), pear psyllid (PSYLLAPIRI), wheat long tube aphid (SitobionavenaeFabricius), wheat binary aphid (SitobionavenaeFabricius), wheat two tail aphid (2), wheat net aphid (SitobionavenaeFabricius), cotton stink bug (SitobionavenaeFabricius), cotton red stink bug (SitobionavenaeFabricius), cotton aphid (SitobionavenaeFabricius), apple tree (SitobionavenaeFabricius), grape root aphid (SitobionavenaeFabricius), grape root nodon (SitobionavenaeFabricius), corn (SitobionavenaeFabricius, corn plant hopper (SitobionavenaeFabricius), corn (SitobionavenaeFabricius, corn 2.
The thysanoptera is selected from thrips oryzae (Baliothrips biformis), thrips tabaci (Frankliniellafusca), thrips frankliniella occidentalis (Frankliniellaoccidentalis), thrips citri (Scirtothripscitri), thrips theae (Scirtothripsdorsalis), thrips flavescens (THRIPSHAWAIIENSIS), bean Huang Jima (Thripsnigropilosus) and thrips orientalis (Thripsorientalis);
Hymenoptera (Iridomyrmexhumilis), formica fusca (Solenopsisrichtery), formica rupestris (Solenopsisinvicta), formica rupestris (Pogonomyrmexbarbatus), wasps (Polistesrubiginosa), wasps (Vespacrabro), ji Hufeng (Dolichovespulamaculata), formica Fusca (Crematogaster), formica Fusca (Solenopsisxyloni), formica Fusca (Attacephalotes), formica Fusca tropicalis (Solenopsisgeminata), velvet ants (Dasymutillaoccidcntalis), formica Fusca (Monomoriumminimum), and Apis sinkiangensis (Athaliarosae).
Coleoptera include Egypt alfalfa leaf image (Hyperabrunneipennis), dark click beetle (Agriotesobscurus), chinese cabbage seed tortoise image (Ceutorhynchusassimilis), bean image (Acanthoscelidesobtectus), broad bean image (Bruchusrufimanus), strawberry root image (Otiorrhynchusovatus), cotton boll weeping (AnthonomusgrandisBoheman), cotton boll weeping (Anthonomusgrandis), ladybug (EPILACHNAVARIVESTIS), south American leaf image (Diabroticaspeciosa), red bean image (Callosobruchusmaculatus), pea image (Bruchuspisorum), corn root leaf image (Diabroticavirgifera), corn root leaf image (DiabroticavirgiferavirgiferaLeConte), corn click beetle (Melanotuscommunis), corn image (Sitophiluszeamais), blue grass weeping (ListronotusmaculicollisDietz), alfalfa leaf image (Hyperapostica).
The orthoptera is selected from the group consisting of Eyew migratory locust (Locustamigratoria), gryllotalpa africana (Gryllotalpaafricana), gryllotalpa (ScapteriscusvicinusScudder), america desert locust (Schistocercaamericana), american grasshopper (SchistocercaamericanaDrury), migratory black locust (Melanoplussanguinipes), migratory grasshopper (LocustamigratoriaLinnaeus), migratory grasshopper (MelanoplussanguinipesFabricius, desert grasshopper (SchistocercagregariaForskal), umbilicaria glabra (Melanoplusspretus), double-vein black grasshopper (Melanoplusbivittatus), striped red grasshopper (Nomadacrisseptemfasciata) and brown grasshopper (Locustanapardalina).
In a preferred embodiment of the invention, the agricultural insect is selected from lepidoptera, hemiptera insects, preferably comprising Chilo suppressalis (Chilo suppressalis), plutella xylostella (Plutellaxylostella), brown planthopper (Nilaparvatalugens).
Another aspect of the invention relates to a method for controlling agricultural insects with the composition according to the invention, characterized in that the composition is contacted with the agricultural insects or the composition is applied to the living environment of the agricultural insects.
Detailed Description
The present invention will be further described with reference to examples, but the present invention is not limited thereto. The percentages described in the examples below are by weight unless otherwise indicated.
1. Combined toxicity test
And selecting healthy larvae with the same size from the test subjects, namely Chilo suppressalis (Chilo suppressalis).
The test agent is aforana raw material and cyantraniliprole raw material, and is obtained through commercial purchase.
The test method is to test the biological activity of the single agent and the compound preparation with different proportions on the Chilo suppressalis by referring to the insecticidal activity test immersion method of the 6 th part of the pesticide in the pesticide indoor biological test rule NY/T1154.6-2006 and the combined action test of the 7 th part of the pesticide in the pesticide indoor biological test rule NY/T1154.7-2006. The method comprises the following steps:
The treatment agent was dissolved with an appropriate amount of acetone in the proportions set in table 1 below, and then formulated into a series of concentrations (calculated as pesticidal active ingredient) with 1% tween 80 in water. Then, the test insects are immersed in the liquid medicine for 10 seconds, then taken out, the excessive liquid medicine on the insect bodies is absorbed by filter paper, and the test insects are transferred to normal conditions for feeding. For 3 replicates of treatment, 20 heads of insects were immersed for each replicate, and 1% tween 80 aqueous solution treatment was used as a blank. After 48h of treatment, the mortality of the test insects was investigated, the corrected mortality was calculated and LC 50 was calculated for each treatment. And then calculating the co-toxicity coefficient CTC of each treatment according to Sun Yunpei method, and evaluating the synergy. Wherein CTC <80 is antagonism, CTC 80-120 is additive, CTC 120 is synergistic.
Toxicity Index (TI) =standard agent LC 50/test agent LC 50 ×100
Actual measurement of mixed virulence index (ATI) =Standard agent LC 50/Mixed agent LC 50 ×100
Theoretical mixed virulence index (TTI) =ti A×PA+TIB×PB
Co-toxicity coefficient (CTC) =measured mixed toxicity index (ATI)/theoretical mixed toxicity index (TTI) ×100
Wherein:
TI A represents the virulence index of agent A;
TI B represents the virulence index of agent B;
p A represents the percentage of agent a in the mix;
p B represents the percentage of agent B in the mix;
TABLE 1 Combined virulence results for each treatment
The table shows that the aforana and the cyantraniliprole have synergistic or additive effects in the range of 1:100 to 100:1. Among them, synergy is more remarkable in the range of 1:25 to 75:1, especially in the range of 10:1 to 50:1.
2. Formulation examples
Example 1 suspending agent
5% Of aforana, 5% of cyantraniliprole, 6% of nonylphenol polyoxyethylene ether, 3% of calcium dodecyl benzene sulfonate, 5% of sodium carboxymethyl cellulose, 0.5% of silicone, 4% of ethylene glycol and the balance of water.
The preparation method comprises the steps of adding the components into water, mixing and stirring, and obtaining the suspending agent through high-speed shearing, dispersing and grinding.
EXAMPLE 2 suspending agent
20% Of afurana, 1% of cyantraniliprole, 9% of naphthalene sulfonic acid formaldehyde condensate sodium salt, 8% of castor oil polyoxyethylene ether, 6% of sodium carboxymethylcellulose, 0.5% of silicone, 7% of propylene glycol and the balance of water.
The preparation method is the same as in example 1.
Example 3 Water dispersible granule
25% Of aforana, 5% of cyantraniliprole, 8% of naphthalene sulfonic acid formaldehyde condensate sodium salt, 12% of castor oil polyoxyethylene ether, 4% of acacia, 6% of ammonium sulfate and the balance of kaolin.
The preparation method comprises the steps of uniformly mixing and crushing all components except the adhesive, adding an aqueous solution of the adhesive for granulating, and drying to obtain the water dispersible granule.
Example 4 Water dispersible granule
10% Of aforana, 1% of cyantraniliprole, 5% of nonylphenol polyoxyethylene ether, 6% of calcium dodecyl benzene sulfonate, 5% of xanthan gum, 5% of sodium sulfate and the balance of kaolin.
The preparation method is the same as in example 3.
It should be noted that the above embodiments are merely for illustrating the technical solution of the present invention and not for limiting the same, and although the present invention has been described in detail with reference to the above embodiments, it should be understood by those skilled in the art that the technical solution described in the above embodiments may be modified or some or all of the technical features may be equivalently replaced, and these modifications or substitutions do not make the essence of the corresponding technical solution deviate from the scope of the technical solution of the embodiments of the present invention.
Claims (6)
1. A composition comprising aforamide and cyantraniliprole, characterized in that the weight ratio of aforamide to cyantraniliprole is from 1:25 to 100:1.
2. The composition of claim 1, wherein the weight ratio of aforamide to cyantraniliprole is from 10:1 to 50:1.
3. The composition according to claim 1 or 2, characterized in that it further comprises agriculturally acceptable adjuvants and/or carriers.
4. A composition according to claim 3, wherein the composition is formulated as a suspension, an aqueous emulsion, a wettable powder, a water dispersible granule, a cream or a microemulsion.
5. The composition according to claim 4, wherein the active ingredient is present in the composition in an amount of 1 to 90% by weight.
6. Use of a composition according to any one of claims 1 to 5 for controlling agricultural insects, characterized in that the agricultural insect is Chilo suppressalis.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101765592A (en) * | 2007-06-26 | 2010-06-30 | 杜邦公司 | Naphthisoxazoline Invertebrate Pest Control Agent |
| CN115735934A (en) * | 2022-11-23 | 2023-03-07 | 山东滨海瀚生生物科技有限公司 | Agricultural insecticidal composition and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| TWI412322B (en) * | 2005-12-30 | 2013-10-21 | Du Pont | Isoxazolines for controlling invertebrate pests |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101765592A (en) * | 2007-06-26 | 2010-06-30 | 杜邦公司 | Naphthisoxazoline Invertebrate Pest Control Agent |
| CN115735934A (en) * | 2022-11-23 | 2023-03-07 | 山东滨海瀚生生物科技有限公司 | Agricultural insecticidal composition and application thereof |
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