CN118186376B - Microwave plasma equipment for silicon dioxide film growth - Google Patents
Microwave plasma equipment for silicon dioxide film growth Download PDFInfo
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- CN118186376B CN118186376B CN202410299272.XA CN202410299272A CN118186376B CN 118186376 B CN118186376 B CN 118186376B CN 202410299272 A CN202410299272 A CN 202410299272A CN 118186376 B CN118186376 B CN 118186376B
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 120
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 28
- 235000012239 silicon dioxide Nutrition 0.000 title claims abstract description 27
- 239000004020 conductor Substances 0.000 claims abstract description 60
- 238000007789 sealing Methods 0.000 claims abstract description 43
- 238000003825 pressing Methods 0.000 claims abstract description 17
- 230000008021 deposition Effects 0.000 claims abstract description 9
- 238000003860 storage Methods 0.000 claims description 31
- 230000000903 blocking effect Effects 0.000 claims description 11
- 230000000149 penetrating effect Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 10
- 238000000151 deposition Methods 0.000 abstract description 8
- 238000005229 chemical vapour deposition Methods 0.000 abstract description 3
- 239000000284 extract Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 52
- 239000010409 thin film Substances 0.000 description 13
- 239000000758 substrate Substances 0.000 description 8
- 238000010586 diagram Methods 0.000 description 7
- 239000010408 film Substances 0.000 description 6
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 1
- 101000827703 Homo sapiens Polyphosphoinositide phosphatase Proteins 0.000 description 1
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 1
- 102100023591 Polyphosphoinositide phosphatase Human genes 0.000 description 1
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 1
- 101100233916 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) KAR5 gene Proteins 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
- C23C16/511—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using microwave discharges
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/40—Oxides
- C23C16/401—Oxides containing silicon
- C23C16/402—Silicon dioxide
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/54—Apparatus specially adapted for continuous coating
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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Abstract
本发明公开了一种用于二氧化硅薄膜生长的微波等离子装备,涉及微波等离子体化学气相沉积技术领域,包括基座和盖于基座顶部的罩盖,所述基座和罩盖之间形成反应腔,还包括天线内导体,天线内导体顶部形成有沉积区,且天线内导体与基座之间设有石英玻璃环,所述反应腔与天线外导体之间通过石英玻璃环隔开,环形防脱件,其弹性套设于天线内导体的外部,所述罩盖内安装有与环形防脱件相抵的弹性抵压件。本发明在罩盖盖合的过程中,通过下压环形防脱件来抽取环形容纳槽内存在的气体,使环形容纳槽内的密封垫圈和石英玻璃环的顶端面紧密贴合,在罩盖完全盖合抽真空前,让石英玻璃环和天线内导体之间的密封更加牢靠,保证抽真空工序的顺利进行。
The present invention discloses a microwave plasma equipment for silicon dioxide film growth, which relates to the technical field of microwave plasma chemical vapor deposition, including a base and a cover covering the top of the base, a reaction chamber is formed between the base and the cover, and also includes an antenna inner conductor, a deposition area is formed on the top of the antenna inner conductor, and a quartz glass ring is arranged between the antenna inner conductor and the base, the reaction chamber and the antenna outer conductor are separated by the quartz glass ring, an annular anti-slipping part, which is elastically sleeved on the outside of the antenna inner conductor, and an elastic pressing part that resists the annular anti-slipping part is installed in the cover. In the process of closing the cover, the present invention extracts the gas in the annular containing groove by pressing down the annular anti-slipping part, so that the sealing gasket in the annular containing groove and the top surface of the quartz glass ring are closely fitted, and before the cover is completely closed and vacuumed, the seal between the quartz glass ring and the antenna inner conductor is made more reliable, so as to ensure the smooth progress of the vacuuming process.
Description
技术领域Technical Field
本发明涉及微波等离子体化学气相沉积技术领域,具体为一种用于二氧化硅薄膜生长的微波等离子装备。The invention relates to the technical field of microwave plasma chemical vapor deposition, in particular to microwave plasma equipment for growing silicon dioxide thin films.
背景技术Background Art
等离子增强化学气相淀积通常是用于在半导体晶片的基材上淀积薄膜,等离子增强化学气相淀积(PECVD)一般是通过将反应气体引入工艺腔并通过微波使反应气体产生等离子体而实现,以制备二氧化硅膜为例,微波系统产生的微波进入等离子体反应室,在自旋转天线内导体上方激发供气系统提供的气体产生等离子体球,等离子体球紧贴在成膜衬底材料表面,通过调整不同的反应气体以及调整等离子体的工艺参数,就可以在天线内导体表面沉积二氧化硅薄膜。Plasma enhanced chemical vapor deposition is usually used to deposit thin films on the substrate of semiconductor wafers. Plasma enhanced chemical vapor deposition (PECVD) is generally achieved by introducing reaction gases into the process chamber and generating plasma from the reaction gases through microwaves. Taking the preparation of silicon dioxide film as an example, the microwaves generated by the microwave system enter the plasma reaction chamber and excite the gas provided by the gas supply system above the inner conductor of the self-rotating antenna to generate a plasma ball. The plasma ball is tightly attached to the surface of the film-forming substrate material. By adjusting different reaction gases and adjusting the process parameters of the plasma, a silicon dioxide film can be deposited on the surface of the inner conductor of the antenna.
现有的专利申请的专利公开号为:CN219861573U,公开日为2023年10月20日,该专利的名称为“一种微波等离子体化学气相沉积设备反应腔结构”,该专利包括上盖板、基座及由两者围成的反应腔,基座上设置用于将反应腔内部抽真空的抽气口,还包括冷却天线内导体和石英玻璃环,冷却天线内导体插入设置在基座中间,石英玻璃环设置在冷却天线内导体与基座之间,石英玻璃环内部中空,基座下方向下延伸有延伸部,延伸部内部设置环形汇流腔,石英玻璃环内部空腔以及反应腔分别通过第二气管和第一气管连通汇流腔,抽气口也连通汇流腔,本实用新型提高了密封效果,延长了石英玻璃环和密封垫圈的使用寿命,生产使用成本更低,也便于维修更换。The patent publication number of the existing patent application is: CN219861573U, and the publication date is October 20, 2023. The name of the patent is "A reaction chamber structure of a microwave plasma chemical vapor deposition device". The patent includes an upper cover plate, a base and a reaction chamber surrounded by the two. The base is provided with an exhaust port for evacuating the inside of the reaction chamber. It also includes a cooling antenna inner conductor and a quartz glass ring. The cooling antenna inner conductor is inserted and arranged in the middle of the base. The quartz glass ring is arranged between the cooling antenna inner conductor and the base. The quartz glass ring is hollow inside, and an extension portion extends downward from the bottom of the base. An annular confluence chamber is arranged inside the extension portion. The internal cavity of the quartz glass ring and the reaction chamber are connected to the confluence chamber through the second air pipe and the first air pipe respectively, and the exhaust port is also connected to the confluence chamber. The utility model improves the sealing effect, extends the service life of the quartz glass ring and the sealing gasket, has lower production and use costs, and is also easy to repair and replace.
上述申请具有不足之处,在进行抽真空的过程中,由于反应腔以及石英玻璃环内部空腔是同步开始进行真空抽取的,若石英玻璃环与冷却天线内导体和基座之间的密封不够牢靠,往往会导致抽真空效率变慢甚至失败,无法在反应腔抽真空前提前判断石英玻璃环是否完全将反应腔内的气体和外界空气隔开。The above application has shortcomings. During the vacuuming process, since the reaction chamber and the cavity inside the quartz glass ring are vacuumed synchronously, if the seal between the quartz glass ring and the inner conductor and base of the cooling antenna is not strong enough, it will often lead to slower vacuuming efficiency or even failure. It is impossible to judge in advance whether the quartz glass ring completely separates the gas in the reaction chamber from the outside air before the reaction chamber is vacuumed.
发明内容Summary of the invention
本发明的目的是提供一种用于二氧化硅薄膜生长的微波等离子装备,以解决上述现有技术中的不足之处。The object of the present invention is to provide a microwave plasma equipment for growing silicon dioxide thin films to solve the above-mentioned deficiencies in the prior art.
为了实现上述目的,本发明提供如下技术方案:In order to achieve the above object, the present invention provides the following technical solutions:
一种用于二氧化硅薄膜生长的微波等离子装备,包括基座和盖于基座顶部的罩盖,所述基座和罩盖之间形成反应腔,还包括天线内导体,其安装于反应腔中,天线内导体顶部形成有沉积区,且天线内导体与基座之间设有石英玻璃环,所述基座上设有天线外导体,所述反应腔与天线外导体之间通过石英玻璃环隔开,环形防脱件,其弹性套设于天线内导体的外部,所述罩盖内安装有与环形防脱件相抵的弹性抵压件,所述环形防脱件内壁开设有若干个储气腔,所述天线内导体底面开设有与各储气腔连通的环形容纳槽,环形容纳槽内嵌设有密封垫圈,所述石英玻璃环顶部嵌入该环形容纳槽并与密封垫圈相抵,当所述罩盖盖合时,弹性抵压件下压环形防脱件,迫使环形容纳槽内的气体抽入储气腔,使密封垫圈与石英玻璃环端面贴合。A microwave plasma equipment for growing silicon dioxide thin film comprises a base and a cover covering the top of the base, a reaction chamber is formed between the base and the cover, and an antenna inner conductor is installed in the reaction chamber, a deposition area is formed on the top of the antenna inner conductor, a quartz glass ring is arranged between the antenna inner conductor and the base, an antenna outer conductor is arranged on the base, the reaction chamber and the antenna outer conductor are separated by the quartz glass ring, an annular anti-slipping part is elastically sleeved on the outside of the antenna inner conductor, an elastic pressing part abutting against the annular anti-slipping part is installed in the cover, a plurality of gas storage cavities are formed on the inner wall of the annular anti-slipping part, an annular receiving groove communicating with each gas storage cavity is formed on the bottom surface of the antenna inner conductor, a sealing gasket is embedded in the annular receiving groove, the top of the quartz glass ring is embedded in the annular receiving groove and abuts against the sealing gasket, when the cover is closed, the elastic pressing part presses down the annular anti-slipping part, forcing the gas in the annular receiving groove to be drawn into the gas storage cavity, so that the sealing gasket fits with the end face of the quartz glass ring.
优选的,所述罩盖内部于天线内导体上方活动安装有微波反射罩和嵌入微波反射罩内的微波反射板,且微波反射板顶部固定连接有贯穿罩盖的进气管。Preferably, a microwave reflection cover and a microwave reflection plate embedded in the microwave reflection cover are movably installed inside the cover above the inner conductor of the antenna, and an air inlet pipe penetrating the cover is fixedly connected to the top of the microwave reflection plate.
优选的,所述弹性抵压件包括固定于罩盖内壁的伸缩杆,所述伸缩杆上套设有压簧,所述伸缩杆底端与环形防脱件外壁相抵。Preferably, the elastic pressing member comprises a telescopic rod fixed to the inner wall of the cover, a compression spring is sleeved on the telescopic rod, and the bottom end of the telescopic rod abuts against the outer wall of the annular anti-slip member.
优选的,所述环形防脱件包括活动套设于天线内导体外的挡环,所述挡环内壁开设有若干个限位槽,所述天线内导体外壁于限位槽内安装有封堵块,所述限位槽和封堵块之间形成储气腔。Preferably, the annular anti-slip component includes a retaining ring movably mounted outside the inner conductor of the antenna, a plurality of limiting grooves are formed on the inner wall of the retaining ring, a sealing block is installed in the limiting groove on the outer wall of the inner conductor of the antenna, and an air storage chamber is formed between the limiting groove and the sealing block.
优选的,所述封堵块底部安装有L形输气管和复位拉簧,所述复位拉簧底端与限位槽底部相抵,所述L形输气管一端于储气腔内开设有输气孔,另一端与环形容纳槽相连通,且其连通处处于密封垫圈和石英玻璃环之间。Preferably, an L-shaped gas pipe and a reset spring are installed at the bottom of the blocking block, the bottom end of the reset spring is against the bottom of the limit groove, one end of the L-shaped gas pipe is provided with a gas hole in the gas storage cavity, and the other end is connected to the annular accommodating groove, and the connection point is between the sealing gasket and the quartz glass ring.
优选的,所述石英玻璃环顶面外沿开设有环形导气槽。Preferably, an annular air guide groove is provided on the outer edge of the top surface of the quartz glass ring.
优选的,所述基座顶部开设有环形定位槽,所述石英玻璃环的顶端和底端均嵌设有密封环,所述环形定位槽与环形容纳槽内均开设有与密封环相匹配的嵌入槽。Preferably, an annular positioning groove is provided at the top of the base, sealing rings are embedded at the top and bottom of the quartz glass ring, and embedding grooves matching the sealing rings are provided in the annular positioning groove and the annular receiving groove.
优选的,所述石英玻璃环顶部开设有若干个排气口,所述排气口内安装有单向排气阀。Preferably, a plurality of exhaust ports are provided at the top of the quartz glass ring, and a one-way exhaust valve is installed in each of the exhaust ports.
优选的,所述伸缩杆底部固定连接有与环形防脱件外壁抵接配合的楔形压块。Preferably, a wedge-shaped pressing block abutting against the outer wall of the annular anti-slip component is fixedly connected to the bottom of the telescopic rod.
优选的,所述罩盖两侧均安装有观察窗。Preferably, observation windows are installed on both sides of the cover.
在上述技术方案中,通过设置在罩盖内的弹性抵压件来下压天线内导体上的环形防脱件,在罩盖盖合的过程中,通过下压环形防脱件来抽取环形容纳槽内存在的气体,使环形容纳槽内的密封垫圈和石英玻璃环的顶端面紧密贴合,同时也使天线内导体能够进一步下压石英玻璃环,让石英玻璃环的底端面和基座密封牢靠,在罩盖完全盖合抽真空前,让石英玻璃环的整体密封更加牢靠,保证抽真空工序的顺利进行,并且罩盖打开后环形防脱件又能够复位抬升,从而防止生长后的薄膜掉落出沉积区。In the above technical solution, the annular anti-slipping piece on the conductor inside the antenna is pressed down by an elastic pressing piece arranged in the cover. During the closing process of the cover, the gas in the annular containing groove is extracted by pressing down the annular anti-slipping piece, so that the sealing gasket in the annular containing groove and the top end surface of the quartz glass ring are tightly fitted. At the same time, the conductor inside the antenna can further press down the quartz glass ring, so that the bottom end surface of the quartz glass ring and the base are firmly sealed. Before the cover is completely closed for vacuuming, the overall sealing of the quartz glass ring is made more secure, ensuring the smooth progress of the vacuuming process. After the cover is opened, the annular anti-slipping piece can be reset and lifted, thereby preventing the grown film from falling out of the deposition area.
应当理解,前面的一般描述和以下详细描述都仅是示例性和说明性的,而不是用于限制本公开。It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the disclosure.
本申请文件提供本公开中描述的技术的各种实现或示例的概述,并不是所公开技术的全部范围或所有特征的全面公开。This application document provides an overview of various implementations or examples of the technology described in the present disclosure, and is not a comprehensive disclosure of the entire scope or all features of the disclosed technology.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本申请实施例或现有技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明中记载的一些实施例,对于本领域普通技术人员来讲,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings required for use in the embodiments will be briefly introduced below. Obviously, the drawings described below are only some embodiments recorded in the present invention. For ordinary technicians in this field, other drawings can also be obtained based on these drawings.
图1为本发明一种用于二氧化硅薄膜生长的微波等离子装备的整体结构示意图;FIG1 is a schematic diagram of the overall structure of a microwave plasma equipment for growing silicon dioxide thin films according to the present invention;
图2为本发明一种用于二氧化硅薄膜生长的微波等离子装备的内部结构示意图;FIG2 is a schematic diagram of the internal structure of a microwave plasma equipment for growing silicon dioxide thin films according to the present invention;
图3为本发明一种用于二氧化硅薄膜生长的微波等离子装备中罩盖的结构示意图;FIG3 is a schematic structural diagram of a cover in a microwave plasma equipment for growing silicon dioxide thin films according to the present invention;
图4为本发明一种用于二氧化硅薄膜生长的微波等离子装备中石英玻璃环与基座和天线内导体的连接意图;FIG4 is a schematic diagram of the connection between a quartz glass ring, a base and an inner conductor of an antenna in a microwave plasma device for growing silicon dioxide thin films according to the present invention;
图5为本发明一种用于二氧化硅薄膜生长的微波等离子装备的A处放大图;FIG5 is an enlarged view of point A of a microwave plasma equipment for growing silicon dioxide thin films according to the present invention;
图6为本发明一种用于二氧化硅薄膜生长的微波等离子装备中挡环的结构示意图;FIG6 is a schematic structural diagram of a retaining ring in a microwave plasma equipment for growing silicon dioxide thin films according to the present invention;
图7为本发明一种用于二氧化硅薄膜生长的微波等离子装备中石英玻璃环的整体结构示意图;FIG7 is a schematic diagram of the overall structure of a quartz glass ring in a microwave plasma device for growing silicon dioxide thin films according to the present invention;
图8为本发明一种用于二氧化硅薄膜生长的微波等离子装备中单向排气阀的结构示意图。FIG8 is a schematic diagram of the structure of a one-way exhaust valve in a microwave plasma device for growing silicon dioxide thin films according to the present invention.
附图标记说明:Description of reference numerals:
1、基座;101、天线外导体;102、环形定位槽;103、嵌入槽;104、密封垫片;2、罩盖;201、微波反射罩;202、微波反射板;203、进气管;204、观察窗;205、调节套管;206、电动升降杆;3、反应腔;4、天线内导体;401、环形容纳槽;402、密封垫圈;403、封堵块;404、L形输气管;405、复位拉簧;406、输气孔;407、基片台;5、石英玻璃环;501、环形导气槽;502、密封环;503、排气口;6、环形防脱件;601、储气腔;602、挡环;603、限位槽;604、插接槽;7、弹性抵压件;701、伸缩杆;702、压簧;703、楔形压块;8、单向排气阀;801、阀板;802、连接拉簧;803、导流框。1. Base; 101. Antenna outer conductor; 102. Annular positioning groove; 103. Embedding groove; 104. Sealing gasket; 2. Cover; 201. Microwave reflection cover; 202. Microwave reflection plate; 203. Air inlet pipe; 204. Observation window; 205. Adjustment sleeve; 206. Electric lifting rod; 3. Reaction chamber; 4. Antenna inner conductor; 401. Annular receiving groove; 402. Sealing gasket; 403. Blocking block; 404. L-shaped air pipe; 405. Reset tension spring; 406, gas delivery hole; 407, substrate stage; 5, quartz glass ring; 501, annular gas guide groove; 502, sealing ring; 503, exhaust port; 6, annular anti-slip part; 601, gas storage cavity; 602, retaining ring; 603, limit groove; 604, plug-in groove; 7, elastic pressure part; 701, telescopic rod; 702, compression spring; 703, wedge-shaped pressure block; 8, one-way exhaust valve; 801, valve plate; 802, connecting tension spring; 803, guide frame.
具体实施方式DETAILED DESCRIPTION
为使得本公开实施例的目的、技术方案和优点更加清楚,下面将结合本公开实施例的附图,对本公开实施例的技术方案进行清楚、完整地描述。显然,所描述的实施例是本公开的一部分实施例,而不是全部的实施例。基于所描述的本公开的实施例,本领域普通技术人员在无需创造性劳动的前提下所获得的所有其他实施例,都属于本公开保护的范围。In order to make the purpose, technical solution and advantages of the embodiments of the present disclosure clearer, the technical solution of the embodiments of the present disclosure will be clearly and completely described below in conjunction with the drawings of the embodiments of the present disclosure. Obviously, the described embodiments are part of the embodiments of the present disclosure, not all of the embodiments. Based on the described embodiments of the present disclosure, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present disclosure.
请参阅图1-8,本发明实施例提供的一种用于二氧化硅薄膜生长的微波等离子装备,包括基座1和盖于基座1顶部的罩盖2,基座1和罩盖2之间形成反应腔3,还包括天线内导体4,其安装于反应腔3中,天线内导体4顶部形成有沉积区,且天线内导体4与基座1之间设有石英玻璃环5,基座1上设有天线外导体101,反应腔3与天线外导体101之间通过石英玻璃环5隔开,环形防脱件6,其弹性套设于天线内导体4的外部,罩盖2内安装有与环形防脱件6相抵的弹性抵压件7,环形防脱件6内壁开设有若干个储气腔601,天线内导体4底面开设有与各储气腔601连通的环形容纳槽401,环形容纳槽401内嵌设有密封垫圈402,石英玻璃环5顶部嵌入该环形容纳槽401并与密封垫圈402相抵,当罩盖2盖合时,弹性抵压件7下压环形防脱件6,迫使环形容纳槽401内的气体抽入储气腔601,使密封垫圈402与石英玻璃环5端面贴合。Referring to FIGS. 1-8 , a microwave plasma device for growing a silicon dioxide thin film provided in an embodiment of the present invention comprises a base 1 and a cover 2 covering the top of the base 1, a reaction chamber 3 is formed between the base 1 and the cover 2, and an antenna inner conductor 4 is installed in the reaction chamber 3, a deposition area is formed on the top of the antenna inner conductor 4, and a quartz glass ring 5 is provided between the antenna inner conductor 4 and the base 1, an antenna outer conductor 101 is provided on the base 1, the reaction chamber 3 and the antenna outer conductor 101 are separated by the quartz glass ring 5, and an annular anti-slipping member 6 is elastically sleeved on the outside of the antenna inner conductor 4. An elastic pressing member 7 that abuts against the annular anti-slipping member 6 is installed in the cover 2. A plurality of gas storage cavities 601 are provided on the inner wall of the annular anti-slipping member 6. An annular receiving groove 401 that communicates with each gas storage cavity 601 is provided on the bottom surface of the antenna inner conductor 4. A sealing gasket 402 is embedded in the annular receiving groove 401. The top of the quartz glass ring 5 is embedded in the annular receiving groove 401 and abuts against the sealing gasket 402. When the cover 2 is closed, the elastic pressing member 7 presses down the annular anti-slipping member 6, forcing the gas in the annular receiving groove 401 to be drawn into the gas storage cavity 601, so that the sealing gasket 402 fits the end face of the quartz glass ring 5.
具体的,基座1上安装有与反应腔3相连通的抽真空管,天线内导体4的沉积区处安装有基片台407,在使用时,先将二氧化硅放在基片台407上,接着将罩盖2向下盖合在基座1上,在盖合的过程中,罩盖2内的环形分布的多个弹性抵压件7先行下压天线内导体4外的环形防脱件6,让环形防脱件6在天线内导体4外向下移动,使环形容纳槽401内密封垫圈402和石英玻璃环5顶端之间的气体抽入各储气腔601中,让环形容纳槽401内的密封垫圈402和石英玻璃环5顶端面连接密封更加紧密,并且挤压时也会迫使天线内导体4进一步的对石英玻璃环5进行施压,使石英玻璃环5底端面和基座1之间的密封也更加牢靠,在保证好石英玻璃环5与天线内导体4和基座1之间的密封性能后,罩盖2才会完全盖合在基座1上,然后再对罩盖2和基座1中形成的反应腔3进行抽真空作业,从而避免因石英玻璃环5密封不佳导致抽真空效率变慢,同时也无需经常检查石英玻璃环5密封处的密封性能,使用效果好,接着朝反应腔3内注入反应气体,从天线外导体101进入的微波再经过天线内导体4的引导作用,传递到玻璃环窗口并进入到反应腔3,让微波能量电离激发气体从而在基片台407上形成的等离子体,以促进二氧化硅薄膜生长。Specifically, a vacuum tube connected to the reaction chamber 3 is installed on the base 1, and a substrate stage 407 is installed at the deposition area of the antenna inner conductor 4. When in use, silicon dioxide is first placed on the substrate stage 407, and then the cover 2 is downwardly covered on the base 1. During the covering process, a plurality of elastic pressing members 7 distributed in an annular manner in the cover 2 first press down the annular anti-slipping member 6 outside the antenna inner conductor 4, so that the annular anti-slipping member 6 moves downward outside the antenna inner conductor 4, so that the gas between the sealing gasket 402 in the annular receiving groove 401 and the top end of the quartz glass ring 5 is sucked into each gas storage cavity 601, so that the sealing gasket 402 in the annular receiving groove 401 and the top end surface of the quartz glass ring 5 are more tightly connected and sealed, and the antenna inner conductor 4 is also forced to further exert pressure on the quartz glass ring 5 during squeezing. The pressure is increased to make the seal between the bottom end surface of the quartz glass ring 5 and the base 1 more reliable. After ensuring the sealing performance between the quartz glass ring 5, the antenna inner conductor 4 and the base 1, the cover 2 will be completely covered on the base 1, and then the reaction chamber 3 formed by the cover 2 and the base 1 will be evacuated, thereby avoiding the slow vacuuming efficiency due to the poor sealing of the quartz glass ring 5. At the same time, there is no need to frequently check the sealing performance of the quartz glass ring 5, and the use effect is good. Then, the reaction gas is injected into the reaction chamber 3, and the microwave entering from the antenna outer conductor 101 is guided by the antenna inner conductor 4, transmitted to the glass ring window and enters the reaction chamber 3, so that the microwave energy ionizes the excited gas to form a plasma on the substrate stage 407, so as to promote the growth of the silicon dioxide film.
与现有技术相比,本发明实施例通过设置在罩盖2内的弹性抵压件7来下压天线内导体4上的环形防脱件6,在罩盖2盖合的过程中,通过下压环形防脱件6来抽取环形容纳槽401内存在的气体,使环形容纳槽401内的密封垫圈402和石英玻璃环5的顶端面紧密贴合,同时也使天线内导体4能够进一步下压石英玻璃环5,让石英玻璃环5的底端面和基座1密封牢靠,在罩盖2完全盖合抽真空前,让石英玻璃环5的整体密封更加牢靠,保证抽真空工序的顺利进行,并且罩盖2打开后环形防脱件6又能够复位抬升,从而防止生长后的薄膜掉落出沉积区。Compared with the prior art, the embodiment of the present invention presses down the annular anti-slipping member 6 on the antenna inner conductor 4 by means of the elastic pressing member 7 arranged in the cover 2. During the closing process of the cover 2, the gas in the annular accommodating groove 401 is extracted by pressing down the annular anti-slipping member 6, so that the sealing gasket 402 in the annular accommodating groove 401 and the top end surface of the quartz glass ring 5 are tightly fitted. At the same time, the antenna inner conductor 4 can further press down the quartz glass ring 5, so that the bottom end surface of the quartz glass ring 5 and the base 1 are firmly sealed. Before the cover 2 is completely closed for vacuuming, the overall sealing of the quartz glass ring 5 is more secure, ensuring the smooth progress of the vacuuming process. After the cover 2 is opened, the annular anti-slipping member 6 can be reset and lifted, thereby preventing the grown film from falling out of the deposition area.
本发明进一步的实施例中,罩盖2内部于天线内导体4上方活动安装有微波反射罩201和嵌入微波反射罩201内的微波反射板202,且微波反射板202顶部固定连接有贯穿罩盖2的进气管203,进气管203处在基片台407上方,微波反射罩201顶部固定连接有贯穿罩盖2的调节套管205,调节套管205套接于进气管203外,进气管203和调节套管205一侧均安装有与罩盖2相连接的电动升降杆206,具体的,微波反射罩201和微波反射板202能将微波反射聚集到天线内导体4上的沉积区,同时也能够控制电动升降杆206对提前调整微波反射罩201和微波反射板202的高度,也能够单独对两者的高度进行调整,将进气管203设置在微波反射板202上,且进气管203处在基片台407的正上方,能够让注入的促反应的气体快速的充满天线内导体4上的沉积区。In a further embodiment of the present invention, a microwave reflection cover 201 and a microwave reflection plate 202 embedded in the microwave reflection cover 201 are movably installed inside the cover 2 above the inner conductor 4 of the antenna, and an air inlet pipe 203 penetrating the cover 2 is fixedly connected to the top of the microwave reflection plate 202, and the air inlet pipe 203 is located above the substrate stage 407. An adjusting sleeve 205 penetrating the cover 2 is fixedly connected to the top of the microwave reflection cover 201, and the adjusting sleeve 205 is sleeved on the outside of the air inlet pipe 203. One side of the air inlet pipe 203 and the adjusting sleeve 205 are both installed with a The connected electric lifting rod 206, specifically, the microwave reflection cover 201 and the microwave reflection plate 202 can reflect and concentrate the microwaves to the deposition area on the inner conductor 4 of the antenna, and can also control the electric lifting rod 206 to adjust the height of the microwave reflection cover 201 and the microwave reflection plate 202 in advance, and can also adjust the height of the two separately, and set the air inlet pipe 203 on the microwave reflection plate 202, and the air inlet pipe 203 is directly above the substrate table 407, so that the injected reaction-promoting gas can quickly fill the deposition area on the inner conductor 4 of the antenna.
本发明进一步的实施例中,弹性抵压件7包括固定于罩盖2内壁的伸缩杆701,伸缩杆701上套设有压簧702,伸缩杆701底端与环形防脱件6外壁相抵,具体的,在伸缩杆701外加装压簧702能够使其对环形防脱件6的挤压具有一定的缓冲区间,能够让伸缩杆701的伸缩长度不受限制,避免其对环形防脱件6的施压不足或施压过度的问题出现,保证环形容纳槽401内的气体能够完全抽入储气腔601,也能够避免环形防脱件6受到硬性撞击。In a further embodiment of the present invention, the elastic pressure member 7 includes a telescopic rod 701 fixed to the inner wall of the cover 2, and a compression spring 702 is sleeved on the telescopic rod 701. The bottom end of the telescopic rod 701 is against the outer wall of the annular anti-slip component 6. Specifically, the compression spring 702 is installed outside the telescopic rod 701 so that the annular anti-slip component 6 has a certain buffer zone when it is squeezed, and the telescopic length of the telescopic rod 701 is not restricted, thereby avoiding the problem of insufficient or excessive pressure on the annular anti-slip component 6, ensuring that the gas in the annular containing groove 401 can be completely drawn into the gas storage chamber 601, and also avoiding the annular anti-slip component 6 from being subjected to hard impact.
本发明进一步的实施例中,环形防脱件6包括活动套设于天线内导体4外的挡环602,挡环602内壁开设有若干个限位槽603,天线内导体4外壁于限位槽603内安装有封堵块403,限位槽603和封堵块403之间形成储气腔601,具体的,各限位槽603环形分布在挡环602的内壁,封堵块403的形状大小和限位槽603的形状大小相同,储气腔601的大小随着封堵块403在限位槽603内的位置而相应的发生改变,在挡环602下移时,储气腔601的腔体变大,而在挡环602上移时,储气腔601的腔体变小,能够通过挡环602的下降来将环形容纳槽401内的多余气体抽吸进储气腔601内储存,防止抽真空时密封垫圈402和石英玻璃环5之间留有空隙。In a further embodiment of the present invention, the annular anti-slip component 6 includes a retaining ring 602 movably sleeved on the outside of the antenna inner conductor 4, a plurality of limiting grooves 603 are provided on the inner wall of the retaining ring 602, a blocking block 403 is installed in the limiting groove 603 on the outer wall of the antenna inner conductor 4, and an air storage cavity 601 is formed between the limiting groove 603 and the blocking block 403. Specifically, each limiting groove 603 is annularly distributed on the inner wall of the retaining ring 602, and the shape and size of the blocking block 403 and the shape of the limiting groove 603 are the same. The size of the gas storage cavity 601 is the same, and the size of the gas storage cavity 601 changes accordingly with the position of the blocking block 403 in the limiting groove 603. When the retaining ring 602 moves down, the cavity of the gas storage cavity 601 becomes larger, and when the retaining ring 602 moves up, the cavity of the gas storage cavity 601 becomes smaller. The excess gas in the annular containing groove 401 can be sucked into the gas storage cavity 601 for storage by the descending of the retaining ring 602, so as to prevent a gap from being left between the sealing gasket 402 and the quartz glass ring 5 when vacuuming.
本发明进一步的实施例中,封堵块403底部安装有L形输气管404和复位拉簧405,复位拉簧405底端与限位槽603底部相抵,L形输气管404一端于储气腔601内开设有输气孔406,另一端与环形容纳槽401相连通,且其连通处处于密封垫圈402和石英玻璃环5之间,具体的,L形输气管404用来连接储气腔601和环形容纳槽401,在挡环602下降时,从环形容纳槽401中抽取的气体通过L形输气管404上的输气孔406排入到储气腔601中暂存,当薄膜生长完成后打开罩盖2,让弹性抵压件7松开环形防脱件6,让环形防脱件6中的挡环602在复位拉簧405的作用力下向上抬升,挡环602向上抬升的过程中储气腔601受压,其内部暂存的气体再顺着L形输气管404排出储气腔601,以方便再次抽吸作业。In a further embodiment of the present invention, an L-shaped gas delivery pipe 404 and a reset spring 405 are installed at the bottom of the blocking block 403, and the bottom end of the reset spring 405 is against the bottom of the limit groove 603. One end of the L-shaped gas delivery pipe 404 is provided with a gas delivery hole 406 in the gas storage cavity 601, and the other end is connected to the annular receiving groove 401, and the connection point is between the sealing gasket 402 and the quartz glass ring 5. Specifically, the L-shaped gas delivery pipe 404 is used to connect the gas storage cavity 601 and the annular receiving groove 401. When the retaining ring 602 descends, the gas delivery hole 406 is opened. When the growth of the film is completed, the cover 2 is opened to allow the elastic pressure member 7 to release the annular anti-slip member 6, so that the retaining ring 602 in the annular anti-slip member 6 is lifted upward under the action of the reset spring 405. During the upward lifting of the retaining ring 602, the air storage chamber 601 is pressurized, and the temporarily stored gas therein is discharged from the air storage chamber 601 along the L-shaped air delivery pipe 404 to facilitate the suction operation again.
本发明进一步的实施例中,石英玻璃环5顶面外沿开设有环形导气槽501,具体的,在石英玻璃环5上开设一圈环形导气槽501,让L形输气管404和环形容纳槽401的连通处处在和环形导气槽501同一高度,能够避免因石英玻璃环5意外偏转导致L形输气管404和环形容纳槽401之间的连通处受堵。In a further embodiment of the present invention, an annular gas guide groove 501 is provided on the outer edge of the top surface of the quartz glass ring 5. Specifically, a circle of annular gas guide grooves 501 is provided on the quartz glass ring 5, so that the connection between the L-shaped gas pipe 404 and the annular receiving groove 401 is at the same height as the annular gas guide groove 501, which can avoid the connection between the L-shaped gas pipe 404 and the annular receiving groove 401 from being blocked due to accidental deflection of the quartz glass ring 5.
本发明进一步的实施例中,基座1顶部开设有环形定位槽102,环形定位槽102内嵌设有密封垫片104,石英玻璃环5的顶端和底端均嵌设有密封环502,密封环502包括内环和外环,环形定位槽102与环形容纳槽401内均开设有与密封环502相匹配的嵌入槽103,石英玻璃环5的底部抵在环形定位槽102的密封垫片104上,顶部抵在环形容纳槽401的密封垫圈402上,同时石英玻璃环5上套接的密封环502又能够进一步提升连接处的密封性能,让反应腔3的密封处理得以保证。In a further embodiment of the present invention, an annular positioning groove 102 is provided on the top of the base 1, a sealing gasket 104 is embedded in the annular positioning groove 102, a sealing ring 502 is embedded in the top and bottom ends of the quartz glass ring 5, and the sealing ring 502 includes an inner ring and an outer ring. An embedding groove 103 matching the sealing ring 502 is provided in the annular positioning groove 102 and the annular receiving groove 401. The bottom of the quartz glass ring 5 abuts against the sealing gasket 104 of the annular positioning groove 102, and the top abuts against the sealing gasket 402 of the annular receiving groove 401. At the same time, the sealing ring 502 sleeved on the quartz glass ring 5 can further improve the sealing performance of the connection, so that the sealing treatment of the reaction chamber 3 can be guaranteed.
本发明进一步的实施例中,石英玻璃环5顶部开设有若干个排气口503,排气口503内安装有单向排气阀8,单向排气阀8包括活动安装于排气口503底部的阀板801,阀板801顶部安装有多个与石英玻璃环5相连接的连接拉簧802,具体的,在挡环602受压来抽吸环形容纳槽401内的空气时,阀板801在连接拉簧802的作用力下始终盖合住石英玻璃环5上的排气口503,避免外部空气抽入挡环602中的储气腔601内,而当挡环602自动抬升时,其储气腔601受压,内部储存的气体顺着L形输气管404回输到环形容纳槽401内,并会挤压打开排气口503处的阀板801,使多余的气体顺着排气口503排出,防止储气腔601和环形容纳槽401内有过多的气体残留,保证连续作业时装置的稳定性。In a further embodiment of the present invention, a plurality of exhaust ports 503 are provided at the top of the quartz glass ring 5, and a one-way exhaust valve 8 is installed in the exhaust port 503. The one-way exhaust valve 8 includes a valve plate 801 movably installed at the bottom of the exhaust port 503, and a plurality of connecting tension springs 802 connected to the quartz glass ring 5 are installed on the top of the valve plate 801. Specifically, when the retaining ring 602 is pressurized to suck the air in the annular receiving groove 401, the valve plate 801 always covers the quartz glass under the action of the connecting tension spring 802. The exhaust port 503 on the ring 5 prevents external air from being drawn into the air storage chamber 601 in the retaining ring 602. When the retaining ring 602 is automatically lifted, its air storage chamber 601 is pressurized, and the gas stored inside is returned to the annular containing groove 401 along the L-shaped air supply pipe 404, and the valve plate 801 at the exhaust port 503 is squeezed open, so that the excess gas is discharged through the exhaust port 503, thereby preventing excessive gas from remaining in the air storage chamber 601 and the annular containing groove 401, thereby ensuring the stability of the device during continuous operation.
本发明更进一步的实施例中,阀板801顶部固定连接有一侧开口的导流框803,该导流框803外壁与排气口503的内壁相接触,具体的,导流框803上的开口靠近石英玻璃环5,在阀板801被挤开后,冲出的气流在导流框803的引导下冲向石英玻璃环5,对石英玻璃环5的表面进行吹尘处理,In a further embodiment of the present invention, a guide frame 803 with an opening on one side is fixedly connected to the top of the valve plate 801, and the outer wall of the guide frame 803 is in contact with the inner wall of the exhaust port 503. Specifically, the opening on the guide frame 803 is close to the quartz glass ring 5. After the valve plate 801 is squeezed open, the outflowing airflow rushes toward the quartz glass ring 5 under the guidance of the guide frame 803, and the surface of the quartz glass ring 5 is subjected to dust blowing treatment.
本发明进一步的实施例中,伸缩杆701底部固定连接有与环形防脱件6外壁抵接配合的楔形压块703,环形防脱件6中的挡环602外壁开设有与楔形压块703相匹配的插接槽604,具体的,在多个伸缩杆701上的楔形压块703分别从环形防脱件6的上方对其边沿进行挤压时,能够对意外偏移的挡环602进行纠偏,当多个楔形压块703完全插入挡环602上相应的插接槽604后,使环形防脱件6和整个天线内导体4处在正中心的位置,既保证了微波输入分布的稳定,又避免密封件过度挤压扭曲。In a further embodiment of the present invention, a wedge-shaped pressure block 703 that abuts against the outer wall of the annular anti-slipping member 6 is fixedly connected to the bottom of the telescopic rod 701, and an outer wall of the retaining ring 602 in the annular anti-slipping member 6 is provided with a plug-in groove 604 that matches the wedge-shaped pressure block 703. Specifically, when the wedge-shaped pressure blocks 703 on multiple telescopic rods 701 squeeze the edges of the annular anti-slipping member 6 from above, the accidentally offset retaining ring 602 can be corrected. When the multiple wedge-shaped pressure blocks 703 are fully inserted into the corresponding plug-in grooves 604 on the retaining ring 602, the annular anti-slipping member 6 and the entire antenna inner conductor 4 are located in the exact center, which not only ensures the stability of the microwave input distribution, but also avoids excessive extrusion and distortion of the seal.
本发明进一步的实施例中,罩盖2两侧均安装有观察窗204,观察窗204的高度高于天线内导体4,具体的,通过加装观察窗204来对反应腔3内的二氧化硅进行观察,调整注入气体的浓度。In a further embodiment of the present invention, observation windows 204 are installed on both sides of the cover 2, and the height of the observation windows 204 is higher than the antenna inner conductor 4. Specifically, the silicon dioxide in the reaction chamber 3 can be observed by installing the observation windows 204 to adjust the concentration of the injected gas.
以上只通过说明的方式描述了本发明的某些示范性实施例,毋庸置疑,对于本领域的普通技术人员,在不偏离本发明的精神和范围的情况下,可以用各种不同的方式对所描述的实施例进行修正。因此,上述附图和描述在本质上是说明性的,不应理解为对本发明权利要求保护范围的限制。The above description is only by way of illustration of certain exemplary embodiments of the present invention. It is undoubted that, for those skilled in the art, the described embodiments can be modified in various ways without departing from the spirit and scope of the present invention. Therefore, the above drawings and descriptions are illustrative in nature and should not be construed as limiting the scope of protection of the claims of the present invention.
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