CN118039993A - Integrated electric pile - Google Patents
Integrated electric pile Download PDFInfo
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- CN118039993A CN118039993A CN202311406570.6A CN202311406570A CN118039993A CN 118039993 A CN118039993 A CN 118039993A CN 202311406570 A CN202311406570 A CN 202311406570A CN 118039993 A CN118039993 A CN 118039993A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Abstract
Description
技术领域Technical Field
本发明涉及燃料电池技术领域,特别是涉及一种可集成式电堆。The present invention relates to the technical field of fuel cells, and in particular to an integrable fuel cell stack.
背景技术Background technique
固体氧化物燃料电池(SOFC)是一种将燃料中的化学能清洁高效地直接转化为电能的发电装置。为了获得所需的电压和功率,SOFC发电系统中通常含有一个以上燃料电池单元,所述燃料电池单元间通过连接部件隔开,连接部件还起到电连接作用,经过多层叠加后就组成一个SOFC电堆。SOFC作为一种新型的绿色发电技术,其能量转换效率高、安全环保,但是SOFC需要在较高的工作温度下运行,高温会降低SOFC系统及电堆的使用寿命及工作效能,因此目前行业内的趋势是研发低温运行的SOFC电堆。Solid oxide fuel cell (SOFC) is a power generation device that directly converts the chemical energy in fuel into electrical energy cleanly and efficiently. In order to obtain the required voltage and power, the SOFC power generation system usually contains more than one fuel cell unit, and the fuel cell units are separated by connecting components, which also play an electrical connection role. After multiple layers are stacked, a SOFC stack is formed. As a new type of green power generation technology, SOFC has high energy conversion efficiency, safety and environmental protection, but SOFC needs to operate at a higher operating temperature. High temperature will reduce the service life and working efficiency of the SOFC system and stack. Therefore, the current trend in the industry is to develop low-temperature operating SOFC stacks.
参见图1,在SOFC电堆中,气流分配歧管通常用于为电堆提供运行所需的反应气体,平板式SOFC电堆的反应气体流道均为贯穿电堆的内部分配歧管,使用内部分配歧管的电堆,需要单独给电堆设计燃气和空气的管道,空气管路无法集成化,会增加系统设计的复杂性,会导致整个系统的重量加重、体积增大;另外在SOFC电堆运行过程中,电堆所需的空气流量较大,空气在狭小的电堆内部流道流通时压力损失会随着流量的增大而增大,导致电堆的工作压力增大,从而影响电堆的封接材料的性能,降低电堆的使用寿命和运行稳定性,同时会增加系统空气的用电负荷,降低系统能效。Referring to FIG1 , in a SOFC stack, an air flow distribution manifold is usually used to provide the stack with the reaction gas required for operation. The reaction gas flow channels of a flat-plate SOFC stack are all internal distribution manifolds that penetrate the stack. For a stack using an internal distribution manifold, it is necessary to design separate gas and air pipelines for the stack. The air pipeline cannot be integrated, which will increase the complexity of system design and cause the weight and volume of the entire system to increase. In addition, during the operation of the SOFC stack, the stack requires a large air flow rate. When the air flows through the narrow internal flow channel of the stack, the pressure loss will increase with the increase in flow rate, resulting in an increase in the working pressure of the stack, thereby affecting the performance of the sealing material of the stack, reducing the service life and operating stability of the stack, and at the same time increasing the power load of the system air and reducing the system energy efficiency.
参见图2,对于使用内部分配歧管进行空气流通的SOFC电堆,需要从下往上或从上往下供应空气,空气经过电堆的空气入口到达电堆的空气出口这段路程,其温度由于电堆的电化学反应的加热逐渐升高,会造成电堆进出口的温差较高,产生较大的应力,容易导致密封材料失效,并且空气封接区域大,会导致整个电堆的封接难度增加,不利于电堆的长期稳定运行。如图2所示,空气与燃气在电堆内部有各自的腔体,彼此独立,互相密封。As shown in Figure 2, for SOFC stacks that use internal distribution manifolds for air circulation, air needs to be supplied from bottom to top or from top to bottom. The temperature of the air gradually increases during the journey from the air inlet of the stack to the air outlet of the stack due to the heating of the electrochemical reaction of the stack, which will cause a high temperature difference between the inlet and outlet of the stack, generate large stress, and easily cause the sealing material to fail. In addition, the large air sealing area will increase the difficulty of sealing the entire stack, which is not conducive to the long-term stable operation of the stack. As shown in Figure 2, air and gas have their own cavities inside the stack, which are independent and sealed from each other.
参见图3,目前的SOFC电堆结构可以分为两种:电解质支撑结构和阳极支撑结构。阳极支撑结构的SOFC电堆具有较薄的电解质隔膜,相对于电解质支撑结构,可以降低电解质厚度造成的欧姆损失,使操作温度更低。相对于阳极支撑结构的电堆,电解质支撑的电堆对电池电解质层的力学性能要求更高,因此需要增加电解质层的厚度来增强电池片的刚性,否则在运行过程中容易发生应力集中、断裂失效等一系列问题。但更厚的电解质层同样带来一些问题,厚度的增加会使电池的欧姆损耗增加,使其工作温度比阳极支撑电堆更高,而工作温度高会使得电堆材料更容易失效。如图3所示,电解质支撑结构的电堆的电池片面积基本上与连接体的面积相等。由于电解质支撑结构的电堆工作温度较高,因此该型电堆对密封材料要求更高,对连接体的材料及机械性能要求也更加苛刻,更高的工作温度也意味着更高的系统设计难度。Referring to FIG3 , the current SOFC stack structure can be divided into two types: electrolyte support structure and anode support structure. The SOFC stack with an anode support structure has a thinner electrolyte diaphragm, which can reduce the ohmic loss caused by the electrolyte thickness and make the operating temperature lower than that of the electrolyte support structure. Compared with the stack with an anode support structure, the stack with an electrolyte support has higher requirements on the mechanical properties of the battery electrolyte layer, so it is necessary to increase the thickness of the electrolyte layer to enhance the rigidity of the battery cell, otherwise a series of problems such as stress concentration and fracture failure are likely to occur during operation. However, a thicker electrolyte layer also brings some problems. The increase in thickness will increase the ohmic loss of the battery, making its operating temperature higher than that of the anode support stack, and the high operating temperature will make the stack material more susceptible to failure. As shown in FIG3 , the cell area of the stack with an electrolyte support structure is basically equal to the area of the connector. Since the operating temperature of the stack with an electrolyte support structure is higher, this type of stack has higher requirements on sealing materials, and more stringent requirements on the materials and mechanical properties of the connector. Higher operating temperatures also mean higher system design difficulties.
因此研发低温运行的SOFC电堆,首选就是采用阳极支撑结构的电堆。Therefore, when developing a SOFC stack that operates at low temperatures, the first choice is to use a stack with an anode support structure.
发明内容Summary of the invention
本发明的目的是:提供一种可集成式电堆,提高了电堆的可靠性和可集成性,极大地降低了电堆集成的设计难度,提高了系统集成的体积功率比。The purpose of the present invention is to provide an integrable fuel cell stack, which improves the reliability and integrability of the fuel cell stack, greatly reduces the design difficulty of fuel cell stack integration, and improves the volume-to-power ratio of system integration.
为了实现上述目的,本发明提供了一种可集成式电堆,包括堆体,所述堆体包括多个间隔堆叠的连接体,相邻的所述连接体之间设有电池片和密封单元,连接体包括设有空气流道的阴极侧和设有燃气流道的阳极侧,所述阴极侧与所述电池片的阴极相对设置从而为单电池阴极提供阴极流道,所述阳极侧与所述电池片的阳极相对设置从而为单电池阳极提供阳极流道;所述连接体上分别设置有围绕所述阳极流道设置的第一边缘体以及绕所述阴极流道设置的第二边缘体;其中,In order to achieve the above-mentioned object, the present invention provides an integrable battery stack, including a stack body, the stack body including a plurality of spaced and stacked connectors, battery cells and sealing units are arranged between adjacent connectors, the connector includes a cathode side provided with an air flow channel and an anode side provided with a gas flow channel, the cathode side is arranged opposite to the cathode of the battery cell so as to provide a cathode flow channel for the cathode of a single battery, and the anode side is arranged opposite to the anode of the battery cell so as to provide an anode flow channel for the anode of a single battery; the connector is respectively provided with a first edge body arranged around the anode flow channel and a second edge body arranged around the cathode flow channel; wherein,
所述第一边缘体围成的区域内设置有用于提供燃气在所述阳极流道上流通并贯穿所述连接体的进气口和出气口;The area surrounded by the first edge body is provided with an air inlet and an air outlet for providing fuel gas to flow on the anode flow channel and penetrate the connector;
所述第二边缘体内设置有将所述堆体的外部空间与所述阴极流道相流通的进气缺口和出气缺口,所述进气缺口为进气侧,所述出气缺口为出气侧;The second edge body is provided with an air inlet notch and an air outlet notch for communicating the external space of the stack body with the cathode flow channel, the air inlet notch is the air inlet side, and the air outlet notch is the air outlet side;
相邻的两个所述连接体通过所述密封单元连接,所述密封单元包括盖板和用于密封所述阳极流道的密封框,所述盖板的一侧通过至少一部分所述密封框与其中一所述连接体配合连接,所述盖板的另一侧与另一所述连接体焊接,所述盖板设有流道通槽、第一通孔和第二通孔,所述电池片与所述流道通槽相对应设置、并且所述电池片通过部分所述密封框与所述盖板连接,所述电池片沿第一方向的两个相对面分别与所述阴极流道的流道凸条和所述阳极流道的流道凸条相抵接,其中第一方向为相邻所述连接体的堆叠方向;Two adjacent connectors are connected through the sealing unit, and the sealing unit includes a cover plate and a sealing frame for sealing the anode flow channel, one side of the cover plate is connected to one of the connectors through at least a portion of the sealing frame, and the other side of the cover plate is welded to the other connector, the cover plate is provided with a flow channel groove, a first through hole and a second through hole, the battery cell is arranged corresponding to the flow channel groove, and the battery cell is connected to the cover plate through a portion of the sealing frame, and two opposite surfaces of the battery cell along a first direction are respectively in contact with the flow channel convex strip of the cathode flow channel and the flow channel convex strip of the anode flow channel, wherein the first direction is the stacking direction of the adjacent connectors;
所述阴极侧设有连接密封凸台,所述进气口和所述出气口的外周分别环绕有所述连接密封凸台,所述进气口通过所述连接密封凸台与所述第一通孔连通,所述出气口通过所述连接密封凸台与所述第二通孔连通。The cathode side is provided with a connecting sealing boss, and the outer peripheries of the air inlet and the air outlet are respectively surrounded by the connecting sealing bosses. The air inlet is connected to the first through hole through the connecting sealing bosses, and the air outlet is connected to the second through hole through the connecting sealing bosses.
本发明实施例一种可集成式电堆与现有技术相比,其有益效果在于:可集成式电堆提高了电堆的可靠性和可集成性,极大地降低了电堆集成的设计难度,提高了系统集成的体积功率比;同时,有效解决阴极内部通气型电堆的温差过大等问题,让大量稳定的空气均匀地流过每一层连接体的阴极侧,有效解决了温差过大造成的密封材料失效、燃料利用率降低等问题,十分适合多电堆集成;通过连接体与盖板焊接,从而减少了密封材料的使用,有效缓解了密封材料的失效问题。Compared with the prior art, the integrable fuel cell stack of the embodiment of the present invention has the following beneficial effects: the integrable fuel cell stack improves the reliability and integrability of the fuel cell stack, greatly reduces the design difficulty of fuel cell stack integration, and improves the volume-to-power ratio of system integration; at the same time, it effectively solves the problem of excessive temperature difference in the ventilation type fuel cell stack inside the cathode, allowing a large amount of stable air to flow evenly through the cathode side of each layer of the connector, effectively solving the problems of sealing material failure and reduced fuel utilization caused by excessive temperature difference, and is very suitable for multi-fuel cell stack integration; by welding the connector and the cover plate, the use of sealing material is reduced, effectively alleviating the problem of sealing material failure.
本发明实施例的可集成式电堆,所述盖板的一侧通过至少一部分所述密封框与其中一所述连接体的阳极侧配合连接,所述盖板的另一侧与另一所述连接体的阴极侧焊接。In the integrable fuel cell stack of the embodiment of the present invention, one side of the cover plate is cooperatively connected to the anode side of one of the connectors through at least a portion of the sealing frame, and the other side of the cover plate is welded to the cathode side of the other connector.
本发明实施例的可集成式电堆,所述盖板的另一侧仅与另一所述连接体的连接密封凸台焊接,具体为:所述盖板朝向所述连接密封凸台的一侧设有第一密封面,所述连接密封凸台朝向所述盖板的一侧设有凸台焊接面,所述第一密封面与所述凸台焊接面焊接。In the integrated fuel cell stack of the embodiment of the present invention, the other side of the cover plate is welded only to the connecting sealing boss of the other connector, specifically: a first sealing surface is provided on the side of the cover plate facing the connecting sealing boss, and a boss welding surface is provided on the side of the connecting sealing boss facing the cover plate, and the first sealing surface is welded to the boss welding surface.
本发明实施例的可集成式电堆,所述连接密封凸台呈环形,所述第一通孔或/和所述第二通孔的直径为D1,所述连接密封凸台的外径为D2,D1<D2。In the integrable fuel cell stack of the embodiment of the present invention, the connection sealing boss is annular, the diameter of the first through hole and/or the second through hole is D1, the outer diameter of the connection sealing boss is D2, and D1<D2.
本发明实施例的可集成式电堆,所述连接密封凸台的高度为H1,所述第二边缘体的高度为H2,H1=H2。In the integrable fuel cell stack of the embodiment of the present invention, the height of the connecting sealing boss is H1, the height of the second edge body is H2, and H1=H2.
本发明实施例的可集成式电堆,所述第二边缘体包括两个第二子边缘体,两个所述子边缘体之间形成有所述进气缺口和所述出气缺口,所述第二子边缘体包括依次连接的翼段、弯段以及平段,所述翼段与所述阴极流道方向平行,所述平段与所述阴极流道方向垂直,所述弯段连接所述翼段和所述平段。In the integrated fuel cell stack of an embodiment of the present invention, the second edge body includes two second sub-edge bodies, the air inlet gap and the air outlet gap are formed between the two sub-edge bodies, the second sub-edge body includes a wing segment, a curved segment and a flat segment connected in sequence, the wing segment is parallel to the direction of the cathode flow channel, the flat segment is perpendicular to the direction of the cathode flow channel, and the curved segment connects the wing segment and the flat segment.
本发明实施例的可集成式电堆,所述密封框包括密封外框和密封内框,所述密封外框沿着所述第一边缘体设置,所述盖板的一侧通过所述密封外框与其中一所述连接体的所述第一边缘体密封连接,所述密封内框环绕所述流道通槽设置,所述盖板的另一侧与另一所述连接体焊接,所述电池片通过所述密封内框与盖板连接。In the integrated battery stack of the embodiment of the present invention, the sealing frame includes a sealing outer frame and a sealing inner frame, the sealing outer frame is arranged along the first edge body, one side of the cover plate is sealed and connected to the first edge body of one of the connectors through the sealing outer frame, the sealing inner frame is arranged around the flow channel groove, the other side of the cover plate is welded to the other connector, and the battery cell is connected to the cover plate through the sealing inner frame.
本发明实施例的可集成式电堆,所述盖板的一侧通过至少一部分所述密封框与其中一所述连接体的阴极侧配合连接,所述盖板的另一侧与另一所述连接体的所述第一边缘体之间通过焊接形成刚性焊接密封层。In the integrable fuel cell stack of the embodiment of the present invention, one side of the cover plate is connected to the cathode side of one of the connectors through at least a portion of the sealing frame, and a rigid welding sealing layer is formed between the other side of the cover plate and the first edge body of the other connector by welding.
本发明实施例的可集成式电堆,所述密封框包括密封凸台圈、密封外框、密封内框和压条,所述第一通孔和所述第二通孔通过所述密封凸台圈与所述连接密封凸台密封连接,所述盖板的一侧通过所述密封外框与其中一所述连接体的阴极侧配合连接;所述密封内框环绕所述电池片的边缘设置,所述密封内框通过所述压条与所述密封外框连接。In the integrated battery stack of the embodiment of the present invention, the sealing frame includes a sealing boss ring, a sealing outer frame, a sealing inner frame and a pressure strip; the first through hole and the second through hole are sealedly connected to the connecting sealing boss through the sealing boss ring; one side of the cover plate is cooperatively connected to the cathode side of one of the connectors through the sealing outer frame; the sealing inner frame is arranged around the edge of the battery cell, and the sealing inner frame is connected to the sealing outer frame through the pressure strip.
本发明实施例的可集成式电堆,所述压条沿垂直于所述阴极流道的气体流动方向延伸,所述第二边缘体设有相对设置的第一凹槽和第二凹槽,所述压条的两端分别连接于所述第一凹槽和所述第二凹槽;所述密封外框包含密封边框和密封连接条,所述密封连接条两端分别与相分离的两个所述密封边框连接;所述密封边框沿着所述第二边缘体设置,所述密封连接条沿着所述压条设置,所述盖板的一侧通过所述密封边框与所述第二边缘体配合连接,所述盖板的一侧通过所述密封连接条与所述压条配合连接;所述密封内框通过所述压条与所述密封连接条连接。In the integrated fuel cell stack of the embodiment of the present invention, the pressure strip extends along a gas flow direction perpendicular to the cathode flow channel, the second edge body is provided with a first groove and a second groove arranged opposite to each other, and the two ends of the pressure strip are respectively connected to the first groove and the second groove; the sealing outer frame includes a sealing frame and a sealing connecting strip, and the two ends of the sealing connecting strip are respectively connected to the two separated sealing frames; the sealing frame is arranged along the second edge body, and the sealing connecting strip is arranged along the pressure strip, one side of the cover plate is connected to the second edge body through the sealing frame, and one side of the cover plate is connected to the pressure strip through the sealing connecting strip; the sealing inner frame is connected to the sealing connecting strip through the pressure strip.
本发明的附加方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本发明的实践了解到。Additional aspects and advantages of the present invention will be given in part in the following description and in part will be obvious from the following description, or will be learned through practice of the present invention.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是现有电堆的集成结构示意图;FIG1 is a schematic diagram of the integrated structure of an existing battery stack;
图2是现有电堆的空气内部流道示意图;FIG2 is a schematic diagram of the internal air flow channel of a conventional fuel cell stack;
图3是现有电堆的电解质支撑结构示意图;FIG3 is a schematic diagram of an electrolyte support structure of an existing battery stack;
图4是本发明实施例的可集成式电堆的结构示意图;FIG4 is a schematic diagram of the structure of an integrable fuel cell stack according to an embodiment of the present invention;
图5是本发明实施例的可集成式电堆的部分爆炸图;FIG5 is a partial exploded view of an integrable fuel cell stack according to an embodiment of the present invention;
图6是本发明实施例的可集成式电堆的连接体与盖板的结构示意图;FIG6 is a schematic structural diagram of a connector and a cover plate of an integrable battery stack according to an embodiment of the present invention;
图7是本发明实施例的连接体的阳极侧的结构示意图;7 is a schematic structural diagram of the anode side of the connector according to an embodiment of the present invention;
图8是本发明实施例的连接体的阴极侧的结构示意图;8 is a schematic structural diagram of the cathode side of the connector according to an embodiment of the present invention;
图9是本发明实施例的阴极流道的结构示意图;9 is a schematic structural diagram of a cathode flow channel according to an embodiment of the present invention;
图10是本发明实施例的阴极侧的部分放大结构示意图;FIG10 is a partially enlarged schematic diagram of the cathode side of an embodiment of the present invention;
图11是本发明实施例的盖板的结构示意图;11 is a schematic structural diagram of a cover plate according to an embodiment of the present invention;
图12是本发明实施例的盖板的俯视图;FIG12 is a top view of a cover plate according to an embodiment of the present invention;
图13是本发明实施例的盖板焊接于第一边缘体的组装结构示意图;13 is a schematic diagram of the assembly structure of the cover plate welded to the first edge body according to an embodiment of the present invention;
图14是本发明实施例的盖板焊接于第一边缘体的拆分结构示意图;14 is a schematic diagram of a disassembled structure of a cover plate welded to a first edge body according to an embodiment of the present invention;
图15是本发明实施例的相邻的两个连接体的盖板焊接于第一边缘体的拆分结构示意图;15 is a schematic diagram of a split structure in which the cover plates of two adjacent connecting bodies are welded to the first edge body according to an embodiment of the present invention;
图16是本发明实施例的盖板焊接于第一边缘体情况下的密封框的结构示意图;16 is a schematic structural diagram of a sealing frame in which a cover plate is welded to a first edge body according to an embodiment of the present invention;
图17是本发明实施例的盖板焊接于第一边缘体的阴极侧的结构示意图;17 is a schematic structural diagram of a cover plate welded to the cathode side of a first edge body according to an embodiment of the present invention;
图18是本发明实施例的可集成式电堆与供气平台的连接示意图。FIG. 18 is a schematic diagram of the connection between the integrable fuel cell stack and the gas supply platform according to an embodiment of the present invention.
图19是本发明实施例的盖板与连接密封凸台焊接的步骤一的状态结构示意图。FIG. 19 is a schematic diagram of the state structure of step 1 of welding the cover plate and the connecting sealing boss according to an embodiment of the present invention.
图20是本发明实施例的盖板与连接密封凸台焊接的步骤二的状态结构示意图。FIG. 20 is a schematic diagram of the state structure of step 2 of welding the cover plate and the connecting sealing boss according to an embodiment of the present invention.
图21是本发明实施例的盖板与连接密封凸台焊接的步骤三的状态结构示意图。FIG. 21 is a schematic diagram of the state structure of step three of welding the cover plate and the connecting sealing boss according to an embodiment of the present invention.
图22是本发明实施例的盖板与连接密封凸台焊接的步骤四的状态结构示意图。FIG. 22 is a schematic diagram of the state structure of step four of welding the cover plate and the connecting sealing boss according to an embodiment of the present invention.
图23是本发明实施例的盖板与连接密封凸台焊接的步骤五的状态结构示意图。FIG. 23 is a schematic diagram of the state structure of step five of welding the cover plate and the connecting sealing boss according to an embodiment of the present invention.
图24是本发明实施例的图23中的B处结构放大图。FIG. 24 is an enlarged view of the structure at point B in FIG. 23 according to an embodiment of the present invention.
图25是本发明实施例的盖板与第一边缘体焊接的步骤一的状态结构示意图。FIG. 25 is a schematic diagram of the state structure of step one of welding the cover plate and the first edge body according to an embodiment of the present invention.
图26是本发明实施例的盖板与第一边缘体焊接的步骤二的状态结构示意图。FIG. 26 is a schematic diagram of the state structure of step 2 of welding the cover plate and the first edge body according to an embodiment of the present invention.
图27是本发明实施例的盖板与第一边缘体焊接的步骤三的状态结构示意图。FIG. 27 is a schematic diagram of the state structure of step three of welding the cover plate and the first edge body according to an embodiment of the present invention.
图28是本发明实施例的图27中的A处的放大结构示意图。FIG. 28 is an enlarged structural schematic diagram of point A in FIG. 27 according to an embodiment of the present invention.
图29是本发明实施例的盖板与第一边缘体焊接的步骤四的状态结构示意图。FIG. 29 is a schematic diagram of the state structure of step four of welding the cover plate and the first edge body according to an embodiment of the present invention.
图30是本发明实施例的盖板与第一边缘体焊接的步骤五的状态结构示意图。FIG. 30 is a schematic diagram of the state structure of step five of welding the cover plate and the first edge body according to an embodiment of the present invention.
图31是本发明实施例的盖板与第一边缘体焊接的步骤六的状态结构示意图。FIG. 31 is a schematic diagram of the state structure of step six of welding the cover plate and the first edge body according to an embodiment of the present invention.
图32是本发明实施例的盖板与第一边缘体焊接的步骤七的状态结构示意图。FIG. 32 is a schematic diagram of the state structure of step seven of welding the cover plate and the first edge body in an embodiment of the present invention.
图33是本发明实施例的图32中的C处的结构放大图。FIG33 is an enlarged view of the structure at C in FIG32 of an embodiment of the present invention.
附图标记:Reference numerals:
1、堆体;2、密封单元;21、电池片;22、盖板;225、第一密封面;23、密封框;231、第二密封面;232、密封外框;2321、第一外框缺口;2322、第二外框缺口;2323、密封边框;2324、密封连接条;2325、内框安装槽;233、密封内框;234、密封凸台圈;221、第一通孔;222、第二通孔;224、流道通槽;3、连接体;31、第一边缘体;311、进气口;312、出气口;32、第二边缘体;321、进气侧;322、出气侧;323、连接密封凸台;3231、凸台焊接面;324、翼段;325、弯段;326、平段;327、第二子边缘体;3271、阴极底面;328、第一凹槽;329、第二凹槽;4、顶板;5、底板;6、配气平台;61、燃气管道;611、燃气通道;6111、燃气进气通道;6112、燃气出气通道;62、空气管道;621、空气通道;;8、阳极流道;9、阴极流道; 91、压条;92、流道凸条。1. Stack; 2. Sealing unit; 21. Cell; 22. Cover plate; 225. First sealing surface; 23. Sealing frame; 231. Second sealing surface; 232. Sealing outer frame; 2321. First outer frame notch; 2322. Second outer frame notch; 2323. Sealing frame; 2324. Sealing connecting strip; 2325. Inner frame mounting groove; 233. Sealing inner frame; 234. Sealing boss ring; 221. First through hole; 222. Second through hole; 224. Flow channel groove; 3. Connector; 31. First edge body; 311. Air inlet; 312. Air outlet; 3 2. Second edge body; 321. Air inlet side; 322. Air outlet side; 323. Connecting sealing boss; 3231. Boss welding surface; 324. Wing section; 325. Bend section; 326. Flat section; 327. Second sub-edge body; 3271. Cathode bottom surface; 328. First groove; 329. Second groove; 4. Top plate; 5. Bottom plate; 6. Gas distribution platform; 61. Gas pipeline; 611. Gas channel; 6111. Gas inlet channel; 6112. Gas outlet channel; 62. Air pipeline; 621. Air channel; 8. Anode flow channel; 9. Cathode flow channel; 91. Pressure strip; 92. Flow channel convex strip.
具体实施方式Detailed ways
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。Embodiments of the present invention are described in detail below, examples of which are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements having the same or similar functions. The embodiments described below with reference to the accompanying drawings are exemplary and are only used to explain the present invention, and cannot be understood as limiting the present invention.
在本发明的描述中,需要理解的是,涉及到方位描述,例如上、下、前、后、左、右等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be understood that descriptions involving orientations, such as up, down, front, back, left, right, etc., and orientations or positional relationships indicated are based on the orientations or positional relationships shown in the accompanying drawings, and are only for the convenience of describing the present invention and simplifying the description, and do not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be understood as a limitation on the present invention.
在本发明的描述中,若干的含义是一个或者多个,多个的含义是两个以上,大于、小于、超过等理解为不包括本数,以上、以下、以内等理解为包括本数。如果有描述到第一、第二只是用于区分技术特征为目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量或者隐含指明所指示的技术特征的先后关系。In the description of the present invention, "several" means one or more, "more" means more than two, "greater than", "less than", "exceed" etc. are understood to exclude the number itself, and "above", "below", "within" etc. are understood to include the number itself. If there is a description of "first" or "second", it is only used for the purpose of distinguishing the technical features, and cannot be understood as indicating or implying the relative importance or implicitly indicating the number of the indicated technical features or implicitly indicating the order of the indicated technical features.
本发明的描述中,除非另有明确的限定,设置、安装、连接等词语应做广义理解,所属技术领域技术人员可以结合技术方案的具体内容合理确定上述词语在本发明中的具体含义。In the description of the present invention, unless otherwise clearly defined, terms such as setting, installing, connecting, etc. should be understood in a broad sense, and technicians in the relevant technical field can reasonably determine the specific meanings of the above terms in the present invention in combination with the specific content of the technical solution.
如图4~图13所示,本发明优选实施例的可集成式电堆,其包括堆体1,堆体1包括多个间隔堆叠的连接体3,相邻的连接体之间设有电池片21和密封单元2,连接体3包括设有空气流道的阴极侧和设有燃气流道的阳极侧,连接体3阴极侧与电池片21阴极相对设置从而为单电池阴极提供阴极流道9,连接体3阳极侧与电池片21阳极相对设置从而为单电池阳极提供阳极流道8;As shown in FIGS. 4 to 13 , an integrable battery stack according to a preferred embodiment of the present invention comprises a stack body 1, the stack body 1 comprises a plurality of spaced and stacked connectors 3, battery cells 21 and sealing units 2 are arranged between adjacent connectors, the connector 3 comprises a cathode side provided with an air flow channel and an anode side provided with a gas flow channel, the cathode side of the connector 3 is arranged opposite to the cathode of the battery cell 21 so as to provide a cathode flow channel 9 for the cathode of the single battery, and the anode side of the connector 3 is arranged opposite to the anode of the battery cell 21 so as to provide an anode flow channel 8 for the anode of the single battery;
如图6-图9所示,连接体3上分别设置有围绕阳极流道8的第一边缘体31以及围绕阴极流道9的第二边缘体32;其中,如图5所示,电池片21位于两个相邻的连接体3之间,具体的,电池片21位于一个连接体3的阴极侧与另一个连接体3的阳极侧之间。电池片21沿第一方向的两个相对面分别与阴极流道9的流道凸条92和阳极流道8的流道凸条92相抵接,其中第一方向为相邻连接体3的堆叠方向。As shown in Fig. 6 to Fig. 9, the connector 3 is provided with a first edge body 31 surrounding the anode flow channel 8 and a second edge body 32 surrounding the cathode flow channel 9; as shown in Fig. 5, the battery cell 21 is located between two adjacent connectors 3, specifically, the battery cell 21 is located between the cathode side of one connector 3 and the anode side of another connector 3. Two opposite surfaces of the battery cell 21 along the first direction are respectively in contact with the flow channel ridge 92 of the cathode flow channel 9 and the flow channel ridge 92 of the anode flow channel 8, wherein the first direction is the stacking direction of adjacent connectors 3.
如图7所示,第一边缘体31围成的区域内设置有用于提供燃气在阳极流道8上流通的进气口311和出气口312,进气口311与出气口312分别与阳极流道8连通,燃气从进气口311进入阳极流道8,阳极流道8内的燃气与电池片21接触并反应,反应后的燃气从出气口312排出;As shown in FIG7 , the area surrounded by the first edge body 31 is provided with an air inlet 311 and an air outlet 312 for providing gas to flow through the anode flow channel 8. The air inlet 311 and the air outlet 312 are respectively connected to the anode flow channel 8. The gas enters the anode flow channel 8 from the air inlet 311. The gas in the anode flow channel 8 contacts and reacts with the battery cell 21. The reacted gas is discharged from the air outlet 312.
作为其中一实施例,如图14-图15所示,第一边缘体31与盖板22密封连接,通过电池片21和密封框23密封盖板22中部的流道通槽224,使连接体3的阳极侧、盖板22以及电池片21形成一个密封燃气反应室,阳极流道8的开口朝向电池片21,燃气从进气口311进入密封燃气反应室,并通过阳极流道8与电池片21反应,反应后的燃气从出气口312排出,避免燃气从阳极侧发生泄漏,同时,保证燃气在阳极侧与电池片21充分发生反应,提升阳极侧的燃气与电池片21的反应效率。As one of the embodiments, as shown in FIGS. 14 and 15 , the first edge body 31 is sealedly connected to the cover plate 22, and the flow channel groove 224 in the middle of the cover plate 22 is sealed by the battery cell 21 and the sealing frame 23, so that the anode side of the connector 3, the cover plate 22 and the battery cell 21 form a sealed gas reaction chamber, the opening of the anode flow channel 8 faces the battery cell 21, the gas enters the sealed gas reaction chamber from the air inlet 311, and reacts with the battery cell 21 through the anode flow channel 8, and the reacted gas is discharged from the gas outlet 312, so as to avoid gas leakage from the anode side, and at the same time, ensure that the gas fully reacts with the battery cell 21 on the anode side, thereby improving the reaction efficiency of the gas on the anode side and the battery cell 21.
如图8所示,第二边缘体32内设置有将堆体1的外部空间与阴极流道9相流通的进气缺口和出气缺口,进气缺口为进气侧321,出气缺口为出气侧322,进气侧321和出气侧322分别与阴极流道9相连通,空气从进气侧321进入阴极流道9,阴极流道9内的空气与电池片21接触并反应,反应后的空气从出气侧322排出;As shown in FIG8 , the second edge body 32 is provided with an air inlet notch and an air outlet notch for communicating the external space of the stack body 1 with the cathode flow channel 9. The air inlet notch is the air inlet side 321, and the air outlet notch is the air outlet side 322. The air inlet side 321 and the air outlet side 322 are respectively connected to the cathode flow channel 9. The air enters the cathode flow channel 9 from the air inlet side 321. The air in the cathode flow channel 9 contacts and reacts with the battery cell 21. The air after the reaction is discharged from the air outlet side 322.
作为其中一实施例,如图5-图6所示,进气侧321和出气侧322为开口结构,通过电池片21和密封框23密封盖板22中部的流道通槽224,使连接体3的阴极侧、盖板22以及电池片21形成一个空气反应室,进气侧321与出气侧322分别位于水平方向的相对两侧并与外界连通,以使每个连接体3阴极侧的空气从进气侧321进入空气反应室内,阴极流道9的开口朝向电池片21,空气通过阴极流道9与电池片21反应,反应后的空气从出气侧322排出,空气反应室内的空气流向呈水平方向流动,使空气从进气侧321均匀地流过每一层连接体3的阴极流道9,空气在电池片21上发生反应,产生的废气从出气侧322排出。空气从堆体1正面即进气侧321直接流入堆体1,由于空气流量远大于燃气流量,且空气能够均匀流过堆体1的每一层连接体3的阴极侧,因此堆体1的上下温差较现有技术更加均匀,提高了堆体1的可靠性和可集成性,且配气平台只需要向堆体1供应燃气,极大地降低了堆体1集成的设计难度,提高系统集成的体积功率比;有效解决阴极内部通气型电堆的温差过大的问题,让大量稳定的空气均匀地流过堆体1每一层连接体3的阴极侧,有效解决了温差过大造成的绝缘密封材料失效、燃料利用率降低等问题,十分适合多电堆集成。As one of the embodiments, as shown in Figures 5 and 6, the air inlet side 321 and the air outlet side 322 are open structures, and the flow channel groove 224 in the middle of the cover plate 22 is sealed by the battery cell 21 and the sealing frame 23, so that the cathode side of the connector 3, the cover plate 22 and the battery cell 21 form an air reaction chamber, the air inlet side 321 and the air outlet side 322 are respectively located on opposite sides in the horizontal direction and are connected to the outside, so that the air on the cathode side of each connector 3 enters the air reaction chamber from the air inlet side 321, the opening of the cathode flow channel 9 faces the battery cell 21, the air reacts with the battery cell 21 through the cathode flow channel 9, and the reacted air is discharged from the air outlet side 322, and the air flow direction in the air reaction chamber flows in a horizontal direction, so that the air flows evenly from the air inlet side 321 through the cathode flow channel 9 of each layer of the connector 3, the air reacts on the battery cell 21, and the generated waste gas is discharged from the air outlet side 322. Air flows directly into the stack body 1 from the front side of the stack body 1, i.e., the air inlet side 321. Since the air flow rate is much larger than the gas flow rate, and the air can flow evenly through the cathode side of each layer of the connector 3 of the stack body 1, the upper and lower temperature differences of the stack body 1 are more uniform than those of the prior art, thereby improving the reliability and integrability of the stack body 1. The gas distribution platform only needs to supply gas to the stack body 1, which greatly reduces the design difficulty of the stack body 1 integration and improves the volume-power ratio of the system integration. It effectively solves the problem of excessive temperature difference in the cathode internal ventilation type fuel cell stack, allowing a large amount of stable air to flow evenly through the cathode side of each layer of the connector 3 of the stack body 1, effectively solving the problems of failure of insulating sealing materials and reduced fuel utilization caused by excessive temperature difference, and is very suitable for multi-fuel stack integration.
作为其中一实施例,如图7-图8所示,连接体3为一体成型结构,第一边缘体31和第二边缘体32为连接体3的其中一部分,第一边缘体31和第二边缘体32的主要作用配合盖板22连接以使在连接体3的阴极侧和阳极侧分别形成两个密封反应室,提升阴极流道9和阳极流道8内的密封性,同时第二边缘体32内设置有供外部空气直接在阴极流道9上流通的进气侧321和出气侧322,这样空气可以直接从外部流入,不需要电堆再提供专门的通空气结构,大大简化了电堆的结构,提高其稳定性和可靠性,有效解决阴极内部通气型电堆的温差过大等问题,让大量稳定的空气均匀地流过每一层连接体3的阴极侧,有效解决了温差过大造成的密封材料失效、燃料利用率降低等问题,十分适合多电堆集成。As one of the embodiments, as shown in Figures 7 and 8, the connector 3 is an integrally formed structure, and the first edge body 31 and the second edge body 32 are part of the connector 3. The main function of the first edge body 31 and the second edge body 32 is to cooperate with the cover plate 22 to connect so that two sealed reaction chambers are formed on the cathode side and the anode side of the connector 3 respectively, thereby improving the sealing of the cathode flow channel 9 and the anode flow channel 8. At the same time, the second edge body 32 is provided with an air inlet side 321 and an air outlet side 322 for external air to flow directly on the cathode flow channel 9. In this way, air can flow in directly from the outside, and there is no need for the battery stack to provide a special air ventilation structure, which greatly simplifies the structure of the battery stack, improves its stability and reliability, and effectively solves the problem of excessive temperature difference in the ventilation type battery stack inside the cathode, allowing a large amount of stable air to flow evenly through the cathode side of each layer of the connector 3, effectively solving the problems of failure of sealing materials and reduced fuel utilization caused by excessive temperature difference, and is very suitable for multi-battery stack integration.
如图5和图6、图15和图16所示,相邻的两个连接体3通过密封单元2连接,密封单元2包括盖板22和密封框23,盖板22的一侧通过至少部分密封框23与其中一连接体3配合连接,盖板22的另一侧与另一连接体3焊接,其中,盖板22与连接体3焊接,盖板22朝向连接体3设有第一密封面225,密封框23朝向连接体3设有第二密封面,第一密封面225与第二密封面231分别与两个不同的连接体3连接,具体的,第一密封面225与一个连接体3的第一边缘体31连接,则第二密封面231与另一个连接体3的第二边缘体32连接;第一密封面225与一个连接体3第二边缘体32连接,则第二密封面231与另一个连接体3的第一边缘体31连接。其中,盖板22设有流道通槽224、第一通孔221和第二通孔222,电池片21与流道通槽224对应设置、并且电池片21通过部分密封框23与盖板22连接,流道通槽224和密封框23为电池片21的提供安装空间,同时,通过流道通槽224使电池片21在第一方向的两个相对面能露出并分别与阳极流道8和阴极流道接触。具体的,第一方向为相邻的连接体3的堆叠方向,电池片21沿第一方向的两个相对面分别与阴极流道9的流道凸条92和阳极流道8的流道凸条92相抵接,以使电池片21在第一方向的两个相对面分别与阳极流道8中的燃气和阴极流道9中的空气接触并发生反应,相邻的连接体3通过电池片21、盖板22和密封框23以实现阳极流道8和阴极流道9的密封隔离。As shown in Figures 5 and 6, Figures 15 and 16, two adjacent connectors 3 are connected by a sealing unit 2, and the sealing unit 2 includes a cover plate 22 and a sealing frame 23, one side of the cover plate 22 is connected to one of the connectors 3 through at least a portion of the sealing frame 23, and the other side of the cover plate 22 is welded to the other connector 3, wherein the cover plate 22 is welded to the connector 3, the cover plate 22 is provided with a first sealing surface 225 facing the connector 3, and the sealing frame 23 is provided with a second sealing surface facing the connector 3, the first sealing surface 225 and the second sealing surface 231 are respectively connected to two different connectors 3, specifically, the first sealing surface 225 is connected to the first edge body 31 of one connector 3, and the second sealing surface 231 is connected to the second edge body 32 of the other connector 3; the first sealing surface 225 is connected to the second edge body 32 of one connector 3, and the second sealing surface 231 is connected to the first edge body 31 of the other connector 3. The cover plate 22 is provided with a flow channel groove 224, a first through hole 221 and a second through hole 222. The battery cell 21 is arranged corresponding to the flow channel groove 224, and the battery cell 21 is connected to the cover plate 22 through a part of the sealing frame 23. The flow channel groove 224 and the sealing frame 23 provide installation space for the battery cell 21. At the same time, the two opposite faces of the battery cell 21 in the first direction can be exposed and contact the anode flow channel 8 and the cathode flow channel respectively through the flow channel groove 224. Specifically, the first direction is the stacking direction of the adjacent connectors 3. The two opposite faces of the battery cell 21 along the first direction are respectively in contact with the flow channel convex strips 92 of the cathode flow channel 9 and the flow channel convex strips 92 of the anode flow channel 8, so that the two opposite faces of the battery cell 21 in the first direction are respectively in contact with the gas in the anode flow channel 8 and the air in the cathode flow channel 9 and react. The adjacent connectors 3 are sealed and isolated by the battery cell 21, the cover plate 22 and the sealing frame 23 to achieve the anode flow channel 8 and the cathode flow channel 9.
如图7-图9以及图11所示,阴极侧设有连接密封凸台323,进气口311和出气口312的外周分别环绕有连接密封凸台323,进气口311与第一通孔221连通,出气口312与第二通孔222连通,以使燃气从进气口311进入阳极流道8并从出气口312流出阳极流道8,燃气通过第一通孔221向上流动至下一进气口311,并从第二通孔222向下流动至下一出气口312,以实现燃气的流通。As shown in Figures 7 to 9 and 11, a connecting sealing boss 323 is provided on the cathode side, and the outer peripheries of the air inlet 311 and the air outlet 312 are respectively surrounded by connecting sealing bosses 323, the air inlet 311 is connected with the first through hole 221, and the air outlet 312 is connected with the second through hole 222, so that the gas enters the anode flow channel 8 from the air inlet 311 and flows out of the anode flow channel 8 from the air outlet 312, and the gas flows upward through the first through hole 221 to the next air inlet 311, and flows downward from the second through hole 222 to the next air outlet 312, so as to realize the circulation of the gas.
其中,连接体3的阴极侧和阳极侧的气体流通空间是相互隔离的,堆体1内的阴极侧相互连通,阳极侧相互连通,保证燃气只在电池片21阳极流动、空气只在电池片21阴极流动。Among them, the gas flow spaces on the cathode side and the anode side of the connector 3 are isolated from each other, the cathode sides in the stack 1 are interconnected, and the anode sides are interconnected, ensuring that the fuel gas only flows at the anode of the battery cell 21 and the air only flows at the cathode of the battery cell 21.
现有的阴极侧与盖板22的连接通过软性的绝缘密封材料进行密封连接,以避免燃料在阴极侧的泄露。堆体在发电时处于高温工况中,软性的绝缘密封材料在长期的高温工况下容易发生形变,导致燃料在阴极侧发生泄露。如图8-图9以及图11所示,阴极侧设有连接密封凸台323,进气口311和出气口312的外周分别环绕有连接密封凸台323,第一密封面225与第二边缘体32连接时,连接密封凸台323与第一密封面225通过焊接形成刚性焊接密封层。阴极流道9的两端分别为进气侧321以及出气侧322,进气侧321以及出气侧322分别凸出设有连接密封凸台323,连接密封凸台323与盖板22焊接形成刚性焊接密封层,连接密封凸台323为耐高温金属材料,连接密封凸台323背离阳极侧并朝向盖板22方向凸出以缩短连接体3与盖板22之间的连接距离,同时,连接密封凸台323与盖板22的连接方式为焊接形成刚性焊接密封层,由于连接密封凸台323与刚性焊接密封层耐高温,在长期的高温工况中不容易发生变形,进而提升了阴极侧与盖板22的连接密封性,防止燃气在阴极侧发生泄露,同时降低了生产成本。其中,焊接方式包括激光焊、钎焊或氩弧焊。The existing connection between the cathode side and the cover plate 22 is sealed by a soft insulating sealing material to avoid leakage of fuel on the cathode side. The stack is in a high-temperature condition during power generation. The soft insulating sealing material is easily deformed under long-term high-temperature conditions, causing fuel leakage on the cathode side. As shown in Figures 8-9 and 11, a connecting sealing boss 323 is provided on the cathode side, and the outer peripheries of the air inlet 311 and the air outlet 312 are respectively surrounded by connecting sealing bosses 323. When the first sealing surface 225 is connected to the second edge body 32, the connecting sealing boss 323 and the first sealing surface 225 are welded to form a rigid welding sealing layer. The two ends of the cathode flow channel 9 are respectively an air inlet side 321 and an air outlet side 322. The air inlet side 321 and the air outlet side 322 are respectively protruded with a connecting sealing boss 323. The connecting sealing boss 323 is welded with the cover plate 22 to form a rigid welding sealing layer. The connecting sealing boss 323 is a high temperature resistant metal material. The connecting sealing boss 323 is away from the anode side and protrudes toward the cover plate 22 to shorten the connection distance between the connector 3 and the cover plate 22. At the same time, the connecting sealing boss 323 and the cover plate 22 are connected by welding to form a rigid welding sealing layer. Since the connecting sealing boss 323 and the rigid welding sealing layer are resistant to high temperatures, they are not easily deformed in long-term high temperature conditions, thereby improving the connection sealing between the cathode side and the cover plate 22, preventing gas leakage on the cathode side, and reducing production costs. Among them, the welding method includes laser welding, brazing or argon arc welding.
进一步的,盖板22的一侧通过至少部分密封框23与其中一连接体3的阳极侧配合连接,盖板22的另一侧与另一连接体3的阴极侧焊接,进一步提升阴极侧的密封性,使阴极流道内的空气流动更为均匀。Furthermore, one side of the cover plate 22 is connected to the anode side of one of the connectors 3 through at least a portion of the sealing frame 23, and the other side of the cover plate 22 is welded to the cathode side of the other connector 3, further improving the sealing of the cathode side and making the air flow in the cathode flow channel more uniform.
作为其中一实施例,第一密封面225分别与第二边缘体32和凸台焊接面3231焊接,进一步提升阴极侧的密封性,使阴极流道内的空气流动更为均匀。As one embodiment, the first sealing surface 225 is welded to the second edge body 32 and the boss welding surface 3231 respectively, so as to further improve the sealing performance of the cathode side and make the air flow in the cathode flow channel more uniform.
进一步的,如图8-图9以及图11所示,盖板22的一侧仅与另一连接体3的连接密封凸台323焊接,具体为:连接密封凸台323呈环形,连接密封凸台323分别与进气口311以及第一通孔221同轴连通,连接密封凸台323分别与出气口312以及第二通孔222同轴连通,第一密封面225朝向连接密封凸台323为盖板22的第一焊接面,连接密封凸台323背向阳极侧且朝向盖板22的一端设有凸台焊接面3231,凸台焊接面3231与盖板22的第一焊接面焊接形成刚性焊接密封层。连接体3仅通过连接密封凸台323与盖板22进行密封焊接,一方面可以保证盖板22与连接体3之间的结合强度,防止燃气从盖板22与凸台焊接面3231之间发生泄漏,另一方面简化了焊接工艺。其中,盖板22与第二边缘体32抵接,未形成连接。Further, as shown in Fig. 8-Fig. 9 and Fig. 11, one side of the cover plate 22 is only welded with the connection sealing boss 323 of another connector 3, specifically: the connection sealing boss 323 is annular, the connection sealing boss 323 is coaxially connected with the air inlet 311 and the first through hole 221 respectively, the connection sealing boss 323 is coaxially connected with the air outlet 312 and the second through hole 222 respectively, the first sealing surface 225 is the first welding surface of the cover plate 22 facing the connection sealing boss 323, and the connection sealing boss 323 is provided with a boss welding surface 3231 at one end facing away from the anode side and facing the cover plate 22, and the boss welding surface 3231 is welded with the first welding surface of the cover plate 22 to form a rigid welding sealing layer. The connector 3 is only sealed and welded with the cover plate 22 through the connection sealing boss 323, which can ensure the bonding strength between the cover plate 22 and the connector 3 on the one hand, prevent the gas from leaking from between the cover plate 22 and the boss welding surface 3231, and simplify the welding process on the other hand. The cover plate 22 abuts against the second edge body 32 , but no connection is formed.
其中,如图8和图12所示, 第一通孔221或/和第二通孔222的直径为D1,连接密封凸台323的外径为D2,若D1>D2,由于第一通孔221及第二通孔222的孔径过大,甚至将连接密封凸台323完全裸露了出来,增加了燃气在阴极侧发生泄漏的可能性,同时需进行焊接的区域面积对应增大,造成了不必要的浪费。D1<D2,以使盖板22与凸台焊接面3231在高度方向上的投影具有重叠部分以形成焊接区域,在焊接区域形成刚性焊接密封层实现对阴极侧与盖板的密封连接,避免在阴极侧的燃气泄露。As shown in FIG8 and FIG12, the diameter of the first through hole 221 or/and the second through hole 222 is D1, and the outer diameter of the connection sealing boss 323 is D2. If D1>D2, due to the excessive aperture of the first through hole 221 and the second through hole 222, the connection sealing boss 323 is even completely exposed, which increases the possibility of gas leakage on the cathode side, and the area required for welding is correspondingly increased, resulting in unnecessary waste. D1<D2, so that the projection of the cover plate 22 and the boss welding surface 3231 in the height direction has an overlapping part to form a welding area, and a rigid welding sealing layer is formed in the welding area to achieve a sealed connection between the cathode side and the cover plate, thereby avoiding gas leakage on the cathode side.
作为优选的,如图8和图12所示,虽然D1可以小于D3,然而此时第一通孔221和第二通孔222的直径小于连接密封凸台323的内径,连接密封凸台323相对盖板22没有外露的焊接部分,导致焊接时需要通过穿透焊进行焊接,不便于焊接操作,同时也提升了焊接难度和焊接要求。连接密封凸台323的内径为D3,D3≤D1<D2,连接密封凸台323相对盖板外露出凸台焊接面3231,便于焊接操作。As a preferred embodiment, as shown in FIG8 and FIG12, although D1 can be smaller than D3, at this time, the diameter of the first through hole 221 and the second through hole 222 is smaller than the inner diameter of the connecting sealing boss 323, and the connecting sealing boss 323 has no exposed welding part relative to the cover plate 22, resulting in the need for welding by penetration welding, which is inconvenient for welding operation and also increases the welding difficulty and welding requirements. The inner diameter of the connecting sealing boss 323 is D3, D3≤D1<D2, and the connecting sealing boss 323 exposes the boss welding surface 3231 relative to the cover plate, which is convenient for welding operation.
作为其中一实施例,如图10所示,连接密封凸台323的高度为H1,第二边缘体32的高度为H2,H1=H2,连接密封凸台323与第二边缘体32的高度相同,保证空气在阴极流道9中均匀流动,若两者的高度不相等,一方面会导致多个间隔堆叠的连接体3、电池片21和盖板22之间的结构不稳定,易造成电堆出现倾斜、缝隙等异常状态,另一方面由于两者高度不相等,导致连接体3阴极侧与盖板22间的缝隙较大,空气可从这些缝隙处经过,而不从空气流道处通过,影响了电堆内部的空气分配。As one of the embodiments, as shown in Figure 10, the height of the connecting sealing boss 323 is H1, and the height of the second edge body 32 is H2, H1=H2. The height of the connecting sealing boss 323 is the same as that of the second edge body 32, ensuring that the air flows evenly in the cathode flow channel 9. If the heights of the two are not equal, on the one hand, it will lead to structural instability between the multiple spaced-together stacked connectors 3, battery cells 21 and cover plates 22, which may easily cause abnormal conditions such as tilting and gaps in the battery stack. On the other hand, due to the unequal heights of the two, the gap between the cathode side of the connector 3 and the cover plate 22 is larger, and air can pass through these gaps instead of through the air flow channel, affecting the air distribution inside the battery stack.
作为其中一实施例,如图8-图9所示,第二边缘体32包括沿空气流动方向镜像设置的第二子边缘体,两个第二子边缘体之间形成有进气缺口和出气缺口;第二子边缘体包括依次连接的翼段324、弯段325以及平段326,翼段324与阴极流道9方向平行,平段326与阴极流道9方向垂直,弯段325连接翼段324和平段326,减少外部流道电堆中的空气泄露,其中,平段326沿垂直于空气流动方向延伸,平段326的长度为L,L≥4mm,平段326在垂直于空气流动的方向延伸,延长了连接体3的阴极侧与盖板22的封接面积,保证阴极侧的空气沿设定的流动轨迹流动。As one of the embodiments, as shown in Figures 8 and 9, the second edge body 32 includes a second sub-edge body mirror-set along the air flow direction, and an air inlet gap and an air outlet gap are formed between the two second sub-edge bodies; the second sub-edge body includes a wing section 324, a curved section 325 and a flat section 326 connected in sequence, the wing section 324 is parallel to the direction of the cathode flow channel 9, the flat section 326 is perpendicular to the direction of the cathode flow channel 9, the curved section 325 connects the wing section 324 and the flat section 326, reducing air leakage in the external flow channel stack, wherein the flat section 326 extends in a direction perpendicular to the air flow direction, the length of the flat section 326 is L, L ≥ 4mm, and the flat section 326 extends in a direction perpendicular to the air flow direction, extending the sealing area between the cathode side of the connector 3 and the cover plate 22, ensuring that the air on the cathode side flows along the set flow trajectory.
作为其中一实施例,如图5-图7所示,第一边缘体31通过密封框23与盖板22密封连接,第二边缘体32直接与盖板22的相对面连接。As one embodiment, as shown in FIG. 5 to FIG. 7 , the first edge body 31 is sealedly connected to the cover plate 22 via the sealing frame 23 , and the second edge body 32 is directly connected to the opposite surface of the cover plate 22 .
进一步的,如图5所示,密封框23包括密封外框232和密封内框233,密封外框232沿着第一边缘体31设置,盖板22的一侧通过密封外框232与其中一连接体3的第一边缘体31密封连接,密封内框233环绕流道通槽224设置,电池片21通过密封内框233与盖板22连接,以实现阴极流道9与阳极流道8的隔离,密封外框232对阳极侧与盖板22之间形成一密封燃气空间,防止燃气外漏,提升使用安全性。Furthermore, as shown in FIG5 , the sealing frame 23 includes a sealing outer frame 232 and a sealing inner frame 233. The sealing outer frame 232 is arranged along the first edge body 31. One side of the cover plate 22 is sealed and connected to the first edge body 31 of one of the connectors 3 through the sealing outer frame 232. The sealing inner frame 233 is arranged around the flow channel groove 224. The battery cell 21 is connected to the cover plate 22 through the sealing inner frame 233 to achieve isolation of the cathode flow channel 9 and the anode flow channel 8. The sealing outer frame 232 forms a sealed gas space between the anode side and the cover plate 22 to prevent gas leakage and improve safety of use.
值得说明的,绝缘密封材料可以是玻璃或者陶瓷材料,采用预装并烧结的方式对电堆进行密封,密封材料也可以是蛭石、云母或硅酸盐等高温密封材料,通过材料预压紧的方式对电堆进行密封。It is worth noting that the insulating sealing material can be glass or ceramic material, and the battery stack is sealed by pre-installation and sintering. The sealing material can also be high-temperature sealing material such as vermiculite, mica or silicate, and the battery stack is sealed by pre-compression of the material.
值得说明的是,连接体3可以是耐高温金属材料,高温金属包括铁基合金、镍基合金或其他具有高温抗氧化的金属合金,如SUS 310s、SUS 316s、SUS 444、SUS 420、inconel600、inconel 625和GH 3030等;电池片21采用YSZ材料。It is worth noting that the connector 3 can be a high-temperature resistant metal material, and the high-temperature metal includes an iron-based alloy, a nickel-based alloy or other metal alloys with high-temperature oxidation resistance, such as SUS 310s, SUS 316s, SUS 444, SUS 420, inconel600, inconel 625 and GH 3030; the battery cell 21 adopts YSZ material.
作为其中一实施例,如图5所示,盖板22与第一边缘体31通过密封框23密封连接,其中,密封框23为绝缘密封材料,密封框23与连接体3的阳极侧及盖板22之间的连接为非刚性连接,进一步防止燃气在阳极侧的泄漏。绝缘密封材料包括:玻璃、云母、蛭石、陶瓷等。As one embodiment, as shown in FIG5 , the cover plate 22 is sealed and connected to the first edge body 31 through a sealing frame 23, wherein the sealing frame 23 is an insulating sealing material, and the connection between the sealing frame 23 and the anode side of the connector 3 and the cover plate 22 is a non-rigid connection, further preventing the leakage of the gas on the anode side. The insulating sealing material includes: glass, mica, vermiculite, ceramics, etc.
进一步的,如图13-14以及图16所示,盖板22的一侧通过至少部分密封框23与其中一连接体3的阴极侧配合连接,盖板22的另一侧与另一连接体3的第一边缘体31焊接,作为其中一实施例,第一密封面225与第一边缘体31之间通过焊接形成刚性焊接密封层。将盖板22与连接体3的阳极侧以直接焊接的方式固定连接,同样可以避免盖板22与连接体3的阳极侧使用绝缘密封材料进行密封的操作,降低了成本,并且在高温工况下发生微小形变时不会产生缝隙,解决了高温工况下由于绝缘密封材料变形而导致燃气从连接体3周围发生泄漏的问题。同时,保证了盖板22与连接体3之间焊接后的结合强度,同时防止了燃气从盖板22与第一边缘体31的配合面区域发生泄漏。直接焊接的方式包括激光焊、钎焊、氩弧焊。Further, as shown in FIGS. 13-14 and 16, one side of the cover plate 22 is connected to the cathode side of one of the connectors 3 through at least part of the sealing frame 23, and the other side of the cover plate 22 is welded to the first edge body 31 of the other connector 3. As one embodiment, a rigid welding sealing layer is formed between the first sealing surface 225 and the first edge body 31 by welding. The cover plate 22 is fixedly connected to the anode side of the connector 3 by direct welding, which can also avoid the operation of sealing the cover plate 22 and the anode side of the connector 3 using insulating sealing materials, reducing costs, and no gaps will be generated when slight deformation occurs under high temperature conditions, solving the problem of gas leakage from around the connector 3 due to deformation of the insulating sealing material under high temperature conditions. At the same time, the bonding strength between the cover plate 22 and the connector 3 after welding is guaranteed, and the gas leakage from the mating surface area of the cover plate 22 and the first edge body 31 is prevented. Direct welding methods include laser welding, brazing, and argon arc welding.
进一步的, 如图15所示,在盖板22与连接体3的阳极侧直接焊接的方式固定连接的情况下,盖板22与连接体3的阴极侧通过绝缘密封材料进行连接,具体的,盖板22分别与连接密封凸台323以及第二边缘体32通过绝缘密封材料进行连接,进一步防止燃气的泄漏。绝缘密封材料与连接体3的阴极侧及盖板22之间的连接为非刚性连接,保证密封性良好。其中,绝缘密封材料包括:玻璃、云母、蛭石或陶瓷等。Further, as shown in FIG. 15 , when the cover plate 22 is fixedly connected to the anode side of the connector 3 by direct welding, the cover plate 22 is connected to the cathode side of the connector 3 by an insulating sealing material. Specifically, the cover plate 22 is connected to the connection sealing boss 323 and the second edge body 32 by insulating sealing materials, respectively, to further prevent gas leakage. The connection between the insulating sealing material and the cathode side of the connector 3 and the cover plate 22 is a non-rigid connection to ensure good sealing. Among them, the insulating sealing material includes: glass, mica, vermiculite or ceramics.
进一步的,如图11、图15-17所示,密封框23包括密封凸台圈234、密封外框232、密封内框233和压条91,第一通孔221和第二通孔222通过密封凸台圈234与连接密封凸台323密封连接,以防止阳极侧的燃气外漏。密封外框232与第二边缘体32密封连接,以保证阴极侧的空气沿设定的空气流道流动,保证在电堆内的空气分配。盖板22的一侧通过密封外框232与其中一连接体3的阴极侧配合连接,密封内框233环绕电池片21的边缘设置,密封内框233通过压条91与密封外框232连接。具体的,密封外框232的相对两侧分别设有第一外框缺口2321和第二外框缺口2322,第一外框缺口2321的位置与进气侧321的的位置对应设置,第一外框缺口2321与进气侧321连通,第二外框缺口2322的位置与出气侧322的位置对应设置,第二外框缺口2322与出气侧322连通,以避免绝缘密封材料对进气侧321和出气侧322的空气流道被堵塞,保证空气流道的正常流通。Further, as shown in FIG. 11 and FIG. 15-17, the sealing frame 23 includes a sealing boss ring 234, a sealing outer frame 232, a sealing inner frame 233 and a pressure strip 91. The first through hole 221 and the second through hole 222 are sealed and connected to the sealing boss 323 through the sealing boss ring 234 to prevent the gas on the anode side from leaking out. The sealing outer frame 232 is sealed and connected to the second edge body 32 to ensure that the air on the cathode side flows along the set air flow channel to ensure the air distribution in the battery stack. One side of the cover plate 22 is connected to the cathode side of one of the connectors 3 through the sealing outer frame 232. The sealing inner frame 233 is arranged around the edge of the battery cell 21, and the sealing inner frame 233 is connected to the sealing outer frame 232 through the pressure strip 91. Specifically, a first outer frame notch 2321 and a second outer frame notch 2322 are respectively provided on opposite sides of the sealing outer frame 232. The position of the first outer frame notch 2321 corresponds to the position of the air inlet side 321, and the first outer frame notch 2321 is connected to the air inlet side 321. The position of the second outer frame notch 2322 corresponds to the position of the air outlet side 322, and the second outer frame notch 2322 is connected to the air outlet side 322 to avoid the insulating sealing material from blocking the air flow channels of the air inlet side 321 and the air outlet side 322, thereby ensuring the normal circulation of the air flow channels.
作为优选的,第一外框缺口2321形状尺寸与进气侧321的形状尺寸对应设置,第二外框缺口2322的形状尺寸与出气侧322的形状尺寸对应设置,以保证空气的进气量和排气量处于正常状态。密封内框233环绕电池片21的边缘并与电池片21的外周连接,连接体3的阴极侧通过密封内框233将电池片21压紧以密封阳极流道8,防止阳极侧的燃气外漏。具体的,压条91将密封内框233和密封外框232朝向阳极侧压紧,密封内框233将电池片21压紧密封阳极流道8,阳极流道8通过盖板22、密封外框232、密封内框233以及电池片21共同实现密封。其中,压条91的上表面与第二边缘体32的上表面齐平。Preferably, the shape and size of the first outer frame notch 2321 are set corresponding to the shape and size of the air inlet side 321, and the shape and size of the second outer frame notch 2322 are set corresponding to the shape and size of the air outlet side 322 to ensure that the air intake and exhaust volume are in a normal state. The sealing inner frame 233 surrounds the edge of the battery cell 21 and is connected to the outer periphery of the battery cell 21. The cathode side of the connector 3 presses the battery cell 21 through the sealing inner frame 233 to seal the anode flow channel 8 to prevent the gas on the anode side from leaking out. Specifically, the pressure strip 91 presses the sealing inner frame 233 and the sealing outer frame 232 toward the anode side, and the sealing inner frame 233 presses the battery cell 21 to seal the anode flow channel 8. The anode flow channel 8 is sealed by the cover plate 22, the sealing outer frame 232, the sealing inner frame 233 and the battery cell 21. Among them, the upper surface of the pressure strip 91 is flush with the upper surface of the second edge body 32.
进一步的,如图17所示,压条91沿垂直于阴极流道9的空气流动方向延伸。阴极侧连接有压条91,压条91垂直于空气流动的两端分别连接于阴极侧,通过压条91朝向阳极侧的一面将密封框23朝向阳极侧压紧,压条91的另一面与阴极侧形成有空气流动间隙,进气侧321、空气流动间隙、阴极流道以及出气侧322连通,通过压条91的设置,避免密封框23封堵阴极侧的空气流道,使空气流道保持畅通。作为其中一实施例,压条91为硬质材料。Further, as shown in FIG17 , the pressure strip 91 extends in a direction perpendicular to the air flow direction of the cathode flow channel 9. The pressure strip 91 is connected to the cathode side, and the two ends of the pressure strip 91 perpendicular to the air flow are respectively connected to the cathode side. The sealing frame 23 is pressed toward the anode side by the side of the pressure strip 91 facing the anode side, and the other side of the pressure strip 91 forms an air flow gap with the cathode side. The air inlet side 321, the air flow gap, the cathode flow channel and the air outlet side 322 are connected. By setting the pressure strip 91, the sealing frame 23 is prevented from blocking the air flow channel on the cathode side, so that the air flow channel remains unobstructed. As one embodiment, the pressure strip 91 is made of a hard material.
作为其中一实施例,第二边缘体设有相对设置的第一凹槽和第二凹槽,压条的两端分别连接于第一凹槽和第二凹槽;密封外框232包含密封边框2323和密封连接条2324,密封连接条2324的两端分别与相分离的两个密封边框2323连接;密封边框2323沿着第二边缘体32设置,密封连接条2324沿着压条91设置,盖板22的一侧通过密封边框2323与第二边缘体32配合连接,盖板22的一侧通过密封连接条2324与压条91配合连接;密封内框233通过压条91与密封连接条2324连接。As one of the embodiments, the second edge body is provided with a first groove and a second groove which are arranged opposite to each other, and the two ends of the pressure strip are respectively connected to the first groove and the second groove; the sealing outer frame 232 includes a sealing frame 2323 and a sealing connecting strip 2324, and the two ends of the sealing connecting strip 2324 are respectively connected to the two separated sealing frames 2323; the sealing frame 2323 is arranged along the second edge body 32, and the sealing connecting strip 2324 is arranged along the pressure strip 91, one side of the cover plate 22 is connected to the second edge body 32 through the sealing frame 2323, and one side of the cover plate 22 is connected to the pressure strip 91 through the sealing connecting strip 2324; the sealing inner frame 233 is connected to the sealing connecting strip 2324 through the pressure strip 91.
本发明的一些实施例中,如图15所示,盖板22上开设有流道通槽224,电池片21安装于流道通槽224上,电池片21的外周与流道通槽224之间具有间隙,以避免与盖板22连接发生短路。具体的,盖板22的中间开设有流道通槽224,电池片21通过密封框23与盖板22的流道通槽224封接,这样电池片21一面接触阳极流道8内的燃气,另一面与阴极流道9内的空气接触,既保证了电化学反应的进行,又保证了电池片21的稳固安装;盖板22外侧与连接体3外侧通过密封框23进行封接,将阳极侧腔体和阴极侧腔体隔开,形成独立的阳极侧腔体供燃气流通。In some embodiments of the present invention, as shown in FIG. 15 , a flow channel groove 224 is provided on the cover plate 22, and the battery cell 21 is installed on the flow channel groove 224. There is a gap between the outer periphery of the battery cell 21 and the flow channel groove 224 to avoid short circuit caused by connection with the cover plate 22. Specifically, a flow channel groove 224 is provided in the middle of the cover plate 22, and the battery cell 21 is sealed with the flow channel groove 224 of the cover plate 22 through a sealing frame 23, so that one side of the battery cell 21 contacts the gas in the anode flow channel 8, and the other side contacts the air in the cathode flow channel 9, which not only ensures the progress of the electrochemical reaction, but also ensures the stable installation of the battery cell 21; the outer side of the cover plate 22 is sealed with the outer side of the connector 3 through a sealing frame 23, separating the anode side cavity and the cathode side cavity, forming an independent anode side cavity for gas circulation.
值得说明的,盖板22可以是耐高温金属材料,高温金属包括铁基合金、镍基合金或其他具有高温抗氧化的金属合金,如SUS 310s、SUS 316s、SUS 444、SUS 420、inconel 600、inconel 625和GH 3030等。It is worth noting that the cover plate 22 can be a high temperature resistant metal material, and the high temperature metal includes iron-based alloy, nickel-based alloy or other metal alloys with high temperature oxidation resistance, such as SUS 310s, SUS 316s, SUS 444, SUS 420, inconel 600, inconel 625 and GH 3030.
值得说明的是,使用机械加工、粉末冶金或蚀刻等方法对连接体3的流道、气体分配区域进行加工,提高流道、气体分配区域的位置精度,达到气体均匀分配的效果;使用激光切割或机械加工等方法对盖板22进行加工。It is worth noting that the flow channel and gas distribution area of the connector 3 are processed by mechanical processing, powder metallurgy or etching to improve the position accuracy of the flow channel and the gas distribution area and achieve the effect of uniform gas distribution; the cover plate 22 is processed by laser cutting or mechanical processing.
本发明的一些实施例中,如图14所示,进气口311和出气口312开设于连接体3上;其中,盖板22设有第一通孔221和第二通孔222,进气口311与第一通孔221连通,出气口312与第二通孔222连通,相邻连接体3上的进气口311之间穿过盖板22的第一通孔221后连通,相邻连接体3上的出气口312之间穿过盖板22的第二通孔222后连通。具体的,通过将进气口311和出气口312直接设置于连接体3上,可以大大简化电堆的结构,并且相邻连接体3之间的进气口311相连和出气口312分别穿过盖板22后相连形成了堆体1的燃气供气道,保证了燃气内部的连通分布,在简化结构的同时保证了内部结构的可行性,此外也突出盖板22在内部结构布置的作用,即可以安装电池片21的稳固安装、实现对连接体3的阳极侧以及阴极侧的密封,也可以方便连接体3之间内部气口的分布连接。In some embodiments of the present invention, as shown in Figure 14, the air inlet 311 and the air outlet 312 are opened on the connecting body 3; wherein, the cover plate 22 is provided with a first through hole 221 and a second through hole 222, the air inlet 311 is connected to the first through hole 221, the air outlet 312 is connected to the second through hole 222, the air inlets 311 on adjacent connecting bodies 3 are connected after passing through the first through hole 221 of the cover plate 22, and the air outlets 312 on adjacent connecting bodies 3 are connected after passing through the second through hole 222 of the cover plate 22. Specifically, by directly arranging the air inlet 311 and the air outlet 312 on the connector 3, the structure of the fuel cell stack can be greatly simplified, and the air inlets 311 and the air outlets 312 between adjacent connectors 3 are connected and respectively connected after passing through the cover plate 22 to form a fuel gas supply passage of the stack 1, thereby ensuring the internal connectivity distribution of the fuel gas, simplifying the structure while ensuring the feasibility of the internal structure, and also highlighting the role of the cover plate 22 in the internal structure arrangement, that is, it can install the battery cell 21 stably, realize the sealing of the anode side and the cathode side of the connector 3, and also facilitate the distribution and connection of the internal gas ports between the connectors 3.
本发明的一些实施例中,如图4所示,堆体1的顶端设置有顶板4,堆体1的底端设置有底板5,底板5上开设有与进气口311和第一通孔221连通的第三进气口以及与出气口312和第二通孔222连通的第三出气口。具体的,顶板4和底板5可以起到合理分配燃气,使燃气能够均匀到达每一层连接体3,提高电堆的燃料利用率的作用,也可以增强电堆的整体刚度,使电堆易于搬运、移动,电堆的底板5和顶板4上有工装夹持孔,方便电堆的运输,电堆顶板4与底板5也作为电连接接口进行引电;在使用的过程中,将底板5的第三进气口与外部的燃气配气平台6的供气口连通,第三出气口与外部的配气平台6的排气口连通,这样就可以通过配气平台6为电堆内部供气,并且保证合理分配。In some embodiments of the present invention, as shown in FIG4 , a top plate 4 is provided at the top of the stack body 1, and a bottom plate 5 is provided at the bottom of the stack body 1. The bottom plate 5 is provided with a third air inlet connected to the air inlet 311 and the first through hole 221, and a third air outlet connected to the air outlet 312 and the second through hole 222. Specifically, the top plate 4 and the bottom plate 5 can reasonably distribute the gas, so that the gas can reach each layer of the connector 3 evenly, improve the fuel utilization rate of the stack, and can also enhance the overall rigidity of the stack, so that the stack is easy to carry and move. There are tooling clamping holes on the bottom plate 5 and the top plate 4 of the stack to facilitate the transportation of the stack. The top plate 4 and the bottom plate 5 of the stack are also used as electrical connection interfaces for power supply. During use, the third air inlet of the bottom plate 5 is connected to the air supply port of the external gas distribution platform 6, and the third air outlet is connected to the exhaust port of the external gas distribution platform 6, so that the gas distribution platform 6 can be used to supply gas to the inside of the stack and ensure reasonable distribution.
本发明的一些实施例中,如图8-图9所示,第二边缘体32内设置有将堆体1的外部空间与阴极流道9相流通的进气缺口和出气缺口,进气缺口为进气侧321,出气缺口为出气侧322,且进气侧321和出气侧322相对设置。具体的,在第二边缘体32上开设供外部空气直接进入到阴极流道9上流通的进气侧321和出气侧322,进一步简化了电堆的结构,提高其稳定性和可靠性。更进一步的,进气侧321和出气侧322以凹槽的形式分别设置于第二边缘体32的两个侧壁上。In some embodiments of the present invention, as shown in FIG8-9, an air inlet notch and an air outlet notch are provided in the second edge body 32 for communicating the external space of the stack body 1 with the cathode flow channel 9, the air inlet notch is the air inlet side 321, the air outlet notch is the air outlet side 322, and the air inlet side 321 and the air outlet side 322 are arranged opposite to each other. Specifically, the air inlet side 321 and the air outlet side 322 are provided on the second edge body 32 for external air to directly enter and circulate on the cathode flow channel 9, further simplifying the structure of the stack and improving its stability and reliability. Furthermore, the air inlet side 321 and the air outlet side 322 are respectively arranged on the two side walls of the second edge body 32 in the form of grooves.
本发明的一些实施例中,如图4所示,堆体1包括5~200个连接体3。具体的,少于5个的电堆过小,不利于集成开发,能量密度较低,大于200个的电堆的装配、流体分配、温度管理等性能较差,容易造成电堆整体效能下降,且会造成电堆倾斜度等公差过大,不利于多电堆堆叠集成。In some embodiments of the present invention, as shown in FIG4 , the stack body 1 includes 5 to 200 connectors 3. Specifically, a stack with less than 5 connectors is too small, which is not conducive to integrated development and has a low energy density. A stack with more than 200 connectors has poor performance in assembly, fluid distribution, temperature management, etc., which can easily cause the overall efficiency of the stack to decrease, and will cause the tolerance of the stack inclination to be too large, which is not conducive to the stacking and integration of multiple stacks.
本发明的一些实施例中,如图7-图9所示,连接体3的长宽比为0.5~4,阴极流道9和阳极流道8的长度分别为20~120mm。具体的,阴极流道9和阳极流道8的长度少于20mm气体,会导致反应速率不足,会导致电堆的燃料利用率降低;大于120mm则会增大气体压损。In some embodiments of the present invention, as shown in Figures 7 to 9, the aspect ratio of the connector 3 is 0.5 to 4, and the lengths of the cathode flow channel 9 and the anode flow channel 8 are 20 to 120 mm, respectively. Specifically, if the lengths of the cathode flow channel 9 and the anode flow channel 8 are less than 20 mm, the reaction rate will be insufficient, resulting in a decrease in the fuel utilization rate of the fuel cell stack; if the lengths are greater than 120 mm, the gas pressure loss will increase.
本发明的一些实施例中,如图7-图9所示,进气口311和出气口312的个数均不大于八个;且其设置有多种形状。具体的,进气口311个数越多越有利于燃气分配,由于需要兼顾连接体3阴极流道9一侧的设计,所以进气口311个数不宜多余8个。In some embodiments of the present invention, as shown in FIG. 7 to FIG. 9 , the number of the air inlet 311 and the air outlet 312 is no more than eight, and they are provided in various shapes. Specifically, the more the number of the air inlet 311 is, the more favorable the gas distribution is. Since the design of the cathode flow channel 9 side of the connector 3 needs to be taken into consideration, the number of the air inlet 311 should not exceed 8.
参见图18,本发明的工作过程为:将电堆放置于配气平台6上,将配气平台6上的供气口和排气口分别与电堆的进气口311和出气口312对齐连通,并添加密封材料进行封接,并在电堆侧面且避开进气侧321和出气侧322处封上绝缘材料,绝缘材料为硅酸盐、氧化铝或云母等,最好为软性材料,然后在电堆外罩上外罩,使绝缘材料紧贴在外罩内壁与电堆之间,最后对外罩顶部和底部进行密封。Referring to Figure 18, the working process of the present invention is: placing the battery stack on the gas distribution platform 6, aligning the air supply port and the exhaust port on the gas distribution platform 6 with the air inlet 311 and the air outlet 312 of the battery stack respectively, and adding sealing material for sealing, and sealing the insulating material on the side of the battery stack and avoiding the air inlet side 321 and the air outlet side 322. The insulating material is silicate, alumina or mica, etc., preferably a soft material, and then put an outer cover on the battery stack so that the insulating material is tightly attached between the inner wall of the outer cover and the battery stack, and finally seal the top and bottom of the outer cover.
在配气平台6向电堆内部通入燃气,并且在配气平台6的底部通入足量且温度足够的空气,空气将均匀地从电堆正面即进气侧321均匀地流过每一层连接体3阴极流道9,与电堆内部的阳极燃气进行电化学反应,并产生废气从电堆背面即出气侧322排出。Fuel gas is introduced into the fuel cell stack through the gas distribution platform 6, and sufficient air with a sufficient temperature is introduced into the bottom of the gas distribution platform 6. The air will flow evenly through the cathode flow channel 9 of each layer of the connector 3 from the front side of the fuel cell stack, i.e., the air inlet side 321, and react electrochemically with the anode fuel gas inside the fuel cell stack to generate exhaust gas which is discharged from the back side of the fuel cell stack, i.e., the air outlet side 322.
本发明的安装过程:The installation process of the present invention:
实施例一,盖板22与连接密封凸台323焊接。In the first embodiment, the cover plate 22 is welded to the connecting sealing boss 323 .
如图19所示,连接体3的阴极侧朝上,其中,流道凸条92凸出于阴极底面3271并沿空气流动方向设置,流道凸条92在阴极侧间隔设置形成阴极流道9,连接体3的阴极底面3271连接有分布在阴极流道9两端的四个连接密封凸台323,其中,两个连接密封凸台323位于进气侧321,另外两个连接密封凸台323位于出气侧322,其中两个连接密封凸台323分别环绕进气口311设置形成燃气进气通道6111,另外两个连接密封凸台323分别环绕出气口312设置形成燃气出气通道6112。As shown in Figure 19, the cathode side of the connector 3 faces upward, wherein the flow channel protrusion 92 protrudes from the cathode bottom surface 3271 and is arranged along the air flow direction, and the flow channel protrusion 92 is arranged at intervals on the cathode side to form a cathode flow channel 9, and the cathode bottom surface 3271 of the connector 3 is connected to four connecting sealing bosses 323 distributed at both ends of the cathode flow channel 9, wherein two connecting sealing bosses 323 are located on the air inlet side 321, and the other two connecting sealing bosses 323 are located on the air outlet side 322, wherein two connecting sealing bosses 323 are respectively arranged around the air inlet port 311 to form a gas inlet channel 6111, and the other two connecting sealing bosses 323 are respectively arranged around the air outlet port 312 to form a gas outlet channel 6112.
如图6、图12、图19以及图20所示,盖板22的第一通孔221与燃气进气通道6111连通,第二通孔222与燃气出气通道6112连通,盖板22的第一密封面225朝向阴极侧,第一密封面225中位于第一通孔221的边缘区域和第二通孔222的边缘区域分别与四个连接密封凸台323的凸台焊接面3231焊接。阴极流道9通过流道通槽224外露形成与电池片21的接触反应区域。而第二边缘体32相对阴极底面3271凸起并与第一密封面225抵接,两个第二子边缘体327之间形成有进气缺口和出气缺口,进气缺口、阴极流道9以及出气缺口连通形成空气通道,使空气沿空气通道流动。As shown in Fig. 6, Fig. 12, Fig. 19 and Fig. 20, the first through hole 221 of the cover plate 22 is connected to the gas inlet channel 6111, the second through hole 222 is connected to the gas outlet channel 6112, the first sealing surface 225 of the cover plate 22 faces the cathode side, and the edge area of the first through hole 221 and the edge area of the second through hole 222 in the first sealing surface 225 are respectively welded to the four boss welding surfaces 3231 connected to the sealing boss 323. The cathode flow channel 9 is exposed through the flow channel groove 224 to form a contact reaction area with the battery cell 21. The second edge body 32 is raised relative to the cathode bottom surface 3271 and abuts against the first sealing surface 225. An air inlet gap and an air outlet gap are formed between the two second sub-edge bodies 327. The air inlet gap, the cathode flow channel 9 and the air outlet gap are connected to form an air channel, so that air flows along the air channel.
如图21所示,在盖板22的上方连接密封框23,具体的,密封框23包括密封外框232和密封内框233,密封外框232环绕盖板22的边缘密封连接,密封内框233环绕流道通槽224的边缘密封连接,使阴极流道9露出于密封内框233的中部即形成电池片21的接触反应区域。As shown in FIG21 , a sealing frame 23 is connected above the cover plate 22. Specifically, the sealing frame 23 includes a sealing outer frame 232 and a sealing inner frame 233. The sealing outer frame 232 is sealed around the edge of the cover plate 22, and the sealing inner frame 233 is sealed around the edge of the flow channel groove 224, so that the cathode flow channel 9 is exposed in the middle of the sealing inner frame 233, thereby forming a contact reaction area of the battery cell 21.
如图22所示,在密封内框233上连接有电池片21,电池片21的边缘与密封内框233连接,电池片21的中部通过电池片21的接触反应区域与阴极流道9的空气接触。其中,通过在连接体3上盖板22、密封框23以及电池片21的安装实现了阴极侧和阳极侧的隔离。As shown in FIG22 , the battery cell 21 is connected to the sealed inner frame 233, the edge of the battery cell 21 is connected to the sealed inner frame 233, and the middle of the battery cell 21 is in contact with the air of the cathode flow channel 9 through the contact reaction area of the battery cell 21. The isolation of the cathode side and the anode side is achieved by installing the cover plate 22, the sealing frame 23 and the battery cell 21 on the connector 3.
如图7、图19、22-图24所示,下一连接体3的阳极侧朝向密封框23连接,该连接体3的进气口311与出气口312分别与燃气进气通道6111和燃气出气通道6112对应相连。其中,第一边缘体31环绕阳极侧的边缘设置,第一边缘体31与密封外框232对应设置并密封连接,阳极流道8朝向电池片21,以实现阳极侧的密封,燃气通过进气口311进入盖板22与阳极侧之间,燃气通过阳极流道8与电池片21反应后从出气口312流出。As shown in Fig. 7, Fig. 19, and Fig. 22-24, the anode side of the next connector 3 is connected toward the sealing frame 23, and the air inlet 311 and the air outlet 312 of the connector 3 are respectively connected to the gas inlet channel 6111 and the gas outlet channel 6112. Among them, the first edge body 31 is arranged around the edge of the anode side, and the first edge body 31 is correspondingly arranged and sealed with the sealing outer frame 232. The anode flow channel 8 faces the battery cell 21 to achieve the sealing of the anode side. The gas enters between the cover plate 22 and the anode side through the air inlet 311, and the gas flows out from the air outlet 312 after reacting with the battery cell 21 through the anode flow channel 8.
连接体3、盖板22、密封框23依次按照图19-图23的连接方式组装,以实现盖板22与连接密封凸台323的焊接组装。The connector 3 , the cover plate 22 , and the sealing frame 23 are assembled in sequence according to the connection methods shown in FIGS. 19 to 23 to achieve welding assembly of the cover plate 22 and the connecting sealing boss 323 .
实施例二,盖板22与第一边缘体31焊接。In the second embodiment, the cover plate 22 is welded to the first edge body 31 .
如图25所示,与图19的区别在于,在第二边缘体32垂直于空气流动方向的两侧分别设有第一凹槽328和第二凹槽329,第一凹槽328和第二凹槽329的底面高于阴极底面3271,其中,阴极流道9的两端分别设有第一凹槽328和第二凹槽329。As shown in Figure 25, the difference from Figure 19 is that a first groove 328 and a second groove 329 are respectively provided on both sides of the second edge body 32 perpendicular to the air flow direction, and the bottom surfaces of the first groove 328 and the second groove 329 are higher than the cathode bottom surface 3271, wherein the first groove 328 and the second groove 329 are respectively provided at both ends of the cathode flow channel 9.
如图26所示,在图25的基础上,压条91沿垂直于阴极流道9的空气流动方向延伸,压条91的两端分别连接于第一凹槽328和第二凹槽329,以实现压条91的固定。其中,压条91的下端面与阴极底面3271之间具有空气流动间隙,以使进气缺口、空气流动间隙、阴极流道9以及出气缺口依次连通形成空气通道。压条91的上端面与第二子边缘体327的上端面齐平。在阴极流道9的两端分别连接有压条91。其中,阴极流道9通过压条91和第二子边缘体327围合露出电池片21的接触反应区域。As shown in FIG. 26, on the basis of FIG. 25, the pressure strip 91 extends along the air flow direction perpendicular to the cathode flow channel 9, and the two ends of the pressure strip 91 are respectively connected to the first groove 328 and the second groove 329 to fix the pressure strip 91. There is an air flow gap between the lower end surface of the pressure strip 91 and the cathode bottom surface 3271, so that the air inlet gap, the air flow gap, the cathode flow channel 9 and the air outlet gap are connected in sequence to form an air channel. The upper end surface of the pressure strip 91 is flush with the upper end surface of the second sub-edge body 327. Pressure strips 91 are respectively connected at both ends of the cathode flow channel 9. The cathode flow channel 9 is surrounded by the pressure strip 91 and the second sub-edge body 327 to expose the contact reaction area of the battery cell 21.
如图27和图30所示,密封框23包括密封内框233、密封外框232和密封凸台圈234,密封内框233的长边连接于压条91的上端面,密封内框233的短边连接于第二子边缘体327的上端面,密封内框233环绕阴极流道9设置,阴极流道9露出形成电池片21的接触反应区域。As shown in Figures 27 and 30, the sealing frame 23 includes a sealing inner frame 233, a sealing outer frame 232 and a sealing boss ring 234. The long side of the sealing inner frame 233 is connected to the upper end surface of the pressure strip 91, and the short side of the sealing inner frame 233 is connected to the upper end surface of the second sub-edge body 327. The sealing inner frame 233 is arranged around the cathode flow channel 9, and the cathode flow channel 9 is exposed to form a contact reaction area of the battery cell 21.
如图27所示,图28为图27中A处的放大图,从图28中明显看出,在压条91的底面与阴极底面3271之间形成有空气流动间隙。As shown in FIG. 27 , FIG. 28 is an enlarged view of point A in FIG. 27 . It can be clearly seen from FIG. 28 that an air flow gap is formed between the bottom surface of the pressure strip 91 and the bottom surface 3271 of the cathode.
如图29所示,在密封内框233上连接电池片21,电池片21的边缘与密封内框233连接,电池片21的一侧面朝向阴极流道9,并通过电池片21的接触反应区域与阴极流道9中的空气接触。As shown in Figure 29, the battery cell 21 is connected to the sealed inner frame 233, the edge of the battery cell 21 is connected to the sealed inner frame 233, one side of the battery cell 21 faces the cathode channel 9, and contacts the air in the cathode channel 9 through the contact reaction area of the battery cell 21.
如图30所示,在图29的基础上,密封外框232包括密封边框2323以及密封连接条2324,密封边框2323的形状与第二子边缘体327的形状对应设置,两个密封边框2323沿空气流动方向镜像设置,两个密封边框2323通过两个密封连接条2324连接,密封边框2323与密封连接条2324围合形成内框安装槽2325,电池片21以及密封内框233位于内框安装槽2325内,密封边框2323连接于第二子边缘体327的上端面,密封连接条2324连接于压条91的上端面,密封凸台圈234的形状与连接密封凸台323对应设置,密封凸台圈234与连接密封凸台323连接。电池片21通过内框安装槽2325外露形成电池片21的接触反应区域。As shown in FIG30, based on FIG29, the sealing outer frame 232 includes a sealing frame 2323 and a sealing connection strip 2324. The shape of the sealing frame 2323 corresponds to the shape of the second sub-edge body 327. The two sealing frames 2323 are mirrored along the air flow direction. The two sealing frames 2323 are connected by two sealing connection strips 2324. The sealing frame 2323 and the sealing connection strip 2324 enclose an inner frame mounting groove 2325. The battery cell 21 and the sealing inner frame 233 are located in the inner frame mounting groove 2325. The sealing frame 2323 is connected to the upper end surface of the second sub-edge body 327. The sealing connection strip 2324 is connected to the upper end surface of the pressure strip 91. The shape of the sealing boss ring 234 corresponds to the connection sealing boss 323. The sealing boss ring 234 is connected to the connection sealing boss 323. The battery cell 21 is exposed through the inner frame mounting groove 2325 to form a contact reaction area of the battery cell 21.
如图31所示,第二密封面231与密封外框232连接,电池片21通过流道通槽224外露,盖板22的第一通孔221和第二通孔222分别与燃气进气通道6111和燃气出气通道6112连通,实现阴极侧与下一连接体3的阳极侧的隔离。As shown in Figure 31, the second sealing surface 231 is connected to the sealing outer frame 232, the battery cell 21 is exposed through the flow channel groove 224, and the first through hole 221 and the second through hole 222 of the cover plate 22 are respectively connected to the gas inlet channel 6111 and the gas outlet channel 6112, thereby isolating the cathode side from the anode side of the next connector 3.
如图32和图33所示,盖板22的第一密封面225的边缘与下一连接体3的阳极侧的第一边缘体31焊接,实现阳极侧的密封连接。As shown in FIG. 32 and FIG. 33 , the edge of the first sealing surface 225 of the cover plate 22 is welded to the first edge body 31 on the anode side of the next connector 3 to achieve a sealed connection on the anode side.
连接体3、盖板22、密封框23依次按照图25-图33的连接方式组装,以实现盖板22与第一边缘体31的焊接组装。The connecting body 3 , the cover plate 22 , and the sealing frame 23 are assembled in sequence according to the connection methods shown in FIGS. 25 to 33 to achieve welding assembly of the cover plate 22 and the first edge body 31 .
需要说明的是,虚线箭头表示空气流动方向,实现箭头表示燃气流动方向。It should be noted that the dotted arrows indicate the direction of air flow, and the solid arrows indicate the direction of gas flow.
综上,本发明实施例提供一种可集成式电堆,配气平台6仅需要给电堆供应燃气,设计难度降低。空气流道设计是直接外露的,空气从电堆正面直接流入电堆,由于空气流量远大于燃气流量,且空气能够均匀流过每一层电堆连接体3,因此电堆的上下温差较现有技术更加均匀,提高了电堆的可靠性和可集成性,且配气平台6只需要向电堆供应燃气,极大地降低了电堆集成的设计难度,提高系统集成的体积功率比;有效解决阴极内部通气型电堆的温差过大等问题,让大量稳定的空气均匀地流过每一层连接体3的阴极侧,有效解决了温差过大造成的密封材料失效、燃料利用率降低等问题,十分适合多电堆集成。In summary, the embodiment of the present invention provides an integrable fuel cell stack, and the gas distribution platform 6 only needs to supply fuel gas to the fuel cell stack, which reduces the design difficulty. The air flow channel design is directly exposed, and the air flows directly into the fuel cell stack from the front of the fuel cell stack. Since the air flow rate is much greater than the fuel gas flow rate, and the air can flow evenly through each layer of the fuel cell stack connector 3, the upper and lower temperature difference of the fuel cell stack is more uniform than the prior art, which improves the reliability and integrability of the fuel cell stack, and the gas distribution platform 6 only needs to supply fuel gas to the fuel cell stack, which greatly reduces the design difficulty of fuel cell stack integration and improves the volume power ratio of system integration; effectively solves the problem of excessive temperature difference of the internal ventilation fuel cell stack of the cathode, allowing a large amount of stable air to flow evenly through the cathode side of each layer of connector 3, effectively solving the problems of sealing material failure and reduced fuel utilization caused by excessive temperature difference, and is very suitable for multi-fuel cell integration.
以上仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和替换,这些改进和替换也应视为本发明的保护范围。The above are only preferred embodiments of the present invention. It should be pointed out that, for ordinary technicians in this technical field, several improvements and substitutions can be made without departing from the technical principles of the present invention. These improvements and substitutions should also be regarded as the scope of protection of the present invention.
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