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CN118028846B - Off-grid carbon neutralization fuel synthesis system and regulation and control method and device thereof - Google Patents

Off-grid carbon neutralization fuel synthesis system and regulation and control method and device thereof Download PDF

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CN118028846B
CN118028846B CN202410134874.XA CN202410134874A CN118028846B CN 118028846 B CN118028846 B CN 118028846B CN 202410134874 A CN202410134874 A CN 202410134874A CN 118028846 B CN118028846 B CN 118028846B
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electrolyzer
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CN118028846A (en
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徐宪东
鹿耕源
赵禹泽
张鹏
贾宏杰
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Tianjin University
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    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60Constructional parts of cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
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    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
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Abstract

本发明提供离网碳中和燃料合成系统及其调控方法、装置,涉及碳中和技术领域,系统包括:碳捕集装置,用于采集环境中的二氧化碳;储气罐,与碳捕集装置连接,用于储存二氧化碳;电解槽,与储气罐连接,用于对二氧化碳进行电解,得到电解产品;储能装置,用于对碳捕集装置以及电解槽供能;光伏装置,用于产生电能,向碳捕集装置、电解槽以及储能装置供能。本发明可以实现绿色能源驱动的碳捕集和转化。

The present invention provides an off-grid carbon-neutral fuel synthesis system and a control method and device thereof, which relates to the field of carbon neutrality technology. The system includes: a carbon capture device for collecting carbon dioxide in the environment; a gas storage tank connected to the carbon capture device for storing carbon dioxide; an electrolyzer connected to the gas storage tank for electrolyzing carbon dioxide to obtain an electrolysis product; an energy storage device for supplying energy to the carbon capture device and the electrolyzer; and a photovoltaic device for generating electricity to supply energy to the carbon capture device, the electrolyzer, and the energy storage device. The present invention can achieve carbon capture and conversion driven by green energy.

Description

离网碳中和燃料合成系统及其调控方法、装置Off-grid carbon neutral fuel synthesis system and control method and device thereof

技术领域Technical Field

本发明涉及碳中和技术领域,尤其涉及离网碳中和燃料合成系统及其调控方法、装置。The present invention relates to the field of carbon neutrality technology, and in particular to an off-grid carbon neutral fuel synthesis system and a control method and device thereof.

背景技术Background Art

利用环境空气中捕获的二氧化碳电解合成碳氢化合物燃料可以关闭其碳循环,是实现可持续能源的重要途径。目前针对二氧化碳捕集利用与封存(CO2 capture,utilization,and storage,CCUS)技术的研究主要侧重点在于二氧化碳捕集,寻求最优方法来提高二氧化碳捕集的效率,降低其成本。Using carbon dioxide captured from ambient air to electrolyze hydrocarbon fuels can close its carbon cycle and is an important way to achieve sustainable energy. Currently, research on carbon dioxide capture, utilization, and storage (CCUS) technology mainly focuses on carbon dioxide capture, seeking the best method to improve the efficiency of carbon dioxide capture and reduce its cost.

绿色能源能够进一步降低碳排放,提高环保型,但是现有技术中没有将绿色能源与碳捕集-转化进行结合的技术方案。Green energy can further reduce carbon emissions and improve environmental protection, but there is no technical solution in the existing technology to combine green energy with carbon capture-conversion.

发明内容Summary of the invention

本发明提供一种离网碳中和燃料合成系统及其调控方法、装置,用以解决现有技术中没有将绿色能源与碳捕集-转化进行结合的技术方案的缺陷,实现利用绿色能源的碳捕集-转化。The present invention provides an off-grid carbon-neutral fuel synthesis system and a control method and device thereof, so as to solve the defect of the prior art that there is no technical solution combining green energy with carbon capture-conversion, and realize carbon capture-conversion using green energy.

本发明提供一种离网碳中和燃料合成系统,包括:The present invention provides an off-grid carbon neutral fuel synthesis system, comprising:

碳捕集装置,所述碳捕集装置用于采集环境中的二氧化碳;A carbon capture device, wherein the carbon capture device is used to collect carbon dioxide in the environment;

储气罐,所述储气罐与所述碳捕集装置连接,用于储存二氧化碳;A gas storage tank, the gas storage tank is connected to the carbon capture device and is used to store carbon dioxide;

电解槽,所述电解槽与所述储气罐连接,用于对二氧化碳进行电解,得到电解产品;An electrolytic cell, the electrolytic cell being connected to the gas storage tank and being used to electrolyze carbon dioxide to obtain an electrolysis product;

储能装置,所述储能装置用于对所述碳捕集装置以及所述电解槽供能;An energy storage device, the energy storage device is used to supply energy to the carbon capture device and the electrolyzer;

光伏装置,所述光伏装置用于产生电能,向所述碳捕集装置、所述电解槽以及所述储能装置供能。A photovoltaic device is used to generate electrical energy to supply energy to the carbon capture device, the electrolyzer and the energy storage device.

根据本发明提供的离网碳中和燃料合成系统,还包括箱体,所述光伏装置设置在所述箱体的外顶部,所述碳捕集装置、所述储气罐、所述电解槽以及所述储能装置设置在所述箱体内部。The off-grid carbon-neutral fuel synthesis system provided according to the present invention also includes a box, the photovoltaic device is arranged on the outer top of the box, and the carbon capture device, the gas storage tank, the electrolyzer and the energy storage device are arranged inside the box.

本发明还提供一种基于如上述任一种所述离网碳中和燃料合成系统的调控方法,包括:The present invention also provides a control method based on any of the above-mentioned off-grid carbon-neutral fuel synthesis systems, comprising:

获取所述碳捕集装置、所述储气罐、所述电解槽、所述储能装置、所述光伏装置的性能参数、以及调控时段内的太阳短波辐照度;Obtaining performance parameters of the carbon capture device, the gas storage tank, the electrolyzer, the energy storage device, the photovoltaic device, and the solar shortwave irradiance during the regulation period;

基于所述性能参数、所述太阳短波辐照度,求解目标优化函数,得到所述系统在所述调控时段内的控制策略,所述调控时段内的控制策略包括所述系统中的各个装置在所述调控时段内的运行参数,其中,所述目标优化函数的优化目标为所述电解产品的产量最大。Based on the performance parameters and the solar shortwave irradiance, the target optimization function is solved to obtain the control strategy of the system during the regulation period. The control strategy during the regulation period includes the operating parameters of each device in the system during the regulation period, wherein the optimization goal of the target optimization function is to maximize the output of the electrolysis product.

根据本发明提供的一种调控方法,所述基于所述性能参数、所述太阳短波辐照度,求解目标优化函数,得到所述系统在所述调控时段内的控制策略,包括:According to a control method provided by the present invention, the target optimization function is solved based on the performance parameter and the solar shortwave irradiance to obtain the control strategy of the system in the control period, including:

基于所述性能参数、所述太阳短波辐照度,在预设的约束条件下,求解所述目标优化函数,得到所述系统在所述调控时段内的控制策略;Based on the performance parameters and the solar shortwave irradiance, under preset constraints, solving the target optimization function to obtain a control strategy for the system within the regulation period;

其中,所述约束条件包括所述系统内的装置的关联约束以及所述系统内的装置的运行约束;The constraint conditions include association constraints of devices in the system and operation constraints of devices in the system;

所述系统内的装置的关联约束用于约束二氧化碳在所述碳捕集装置、所述储气罐和所述电解槽之间的流动,以及约束所述系统的电能来自于所述储能装置和所述光伏装置;The associated constraints of the devices in the system are used to constrain the flow of carbon dioxide between the carbon capture device, the gas storage tank and the electrolyzer, and to constrain the electrical energy of the system to come from the energy storage device and the photovoltaic device;

所述系统内的装置的运行约束用于约束所述系统内的各个装置的运行状态。The operation constraints of the devices in the system are used to constrain the operation status of each device in the system.

根据本发明提供的一种调控方法,所述调控时段有多个;所述系统内的装置的运行约束包括第一约束条件,所述第一约束条件用于约束在所述调控时段结束时,所述储能装置中的能量总变化量以及所述储气罐内的二氧化碳的量总变化量均为0。According to a control method provided by the present invention, there are multiple control time periods; the operating constraints of the devices in the system include a first constraint condition, and the first constraint condition is used to constrain that at the end of the control time period, the total change in energy in the energy storage device and the total change in the amount of carbon dioxide in the gas storage tank are both 0.

根据本发明提供的一种调控方法,所述系统内的装置的运行约束包括第二约束条件,所述第二约束条件用于约束所述碳捕集装置以及所述电解槽的运行状态;According to a control method provided by the present invention, the operation constraint of the device in the system includes a second constraint condition, and the second constraint condition is used to constrain the operation state of the carbon capture device and the electrolyzer;

所述第二约束条件为:The second constraint is:

其中,B(ti)代表第i个颗粒度时段内参数B的值,nh为所述调控时段,表示所述储气罐进气物质的量,代表所述碳捕集装置捕集二氧化碳物质的量,ucc、uelec是一个0,1变量,代表所述碳捕集装置和所述电解槽的开关状态,Pcc代表所述碳捕集装置的功率,acc表示所述碳捕集装置的碳捕集转换系数,Pelec代表所述电解槽的功率,aelec代表所述电解槽的电解量转换系数,awas代表所述电解槽处理二氧化碳的损耗系数。Wherein, B(t i ) represents the value of parameter B in the i-th granularity period, nh is the control period, Indicates the amount of gas inlet material in the gas tank, represents the amount of carbon dioxide captured by the carbon capture device, u cc and u elec are 0, 1 variables, representing the switching status of the carbon capture device and the electrolyzer, P cc represents the power of the carbon capture device, a cc represents the carbon capture conversion coefficient of the carbon capture device, P elec represents the power of the electrolyzer, a elec represents the electrolysis amount conversion coefficient of the electrolyzer, and a was represents the loss coefficient of the electrolyzer in processing carbon dioxide.

根据本发明提供的一种调控方法,所述系统内的装置的运行约束包括第三约束条件,所述第三约束条件用于约束所述碳捕集装置以及所述电解槽在所述调控时段内最大连续运行颗粒度时段个数;所述第三约束为:According to a control method provided by the present invention, the operation constraints of the devices in the system include a third constraint condition, and the third constraint condition is used to constrain the maximum number of continuous operation particle size time periods of the carbon capture device and the electrolyzer within the control period; the third constraint is:

其中,分别代表所述碳捕集装置和所述电解槽在调控时间范围内最大连续运行颗粒度时段的个数。in, and They respectively represent the number of maximum continuous operating particle size periods of the carbon capture device and the electrolyzer within the regulation time range.

本发明还提供一种基于如上述任一种所述离网碳中和燃料合成系统的调控装置,包括:The present invention also provides a control device based on any of the above-mentioned off-grid carbon-neutral fuel synthesis systems, comprising:

参数获取模块,用于获取所述碳捕集装置、所述储气罐、所述电解槽、所述储能装置、所述光伏装置的性能参数、以及调控时段内的太阳短波辐照度;A parameter acquisition module, used to acquire performance parameters of the carbon capture device, the gas storage tank, the electrolyzer, the energy storage device, the photovoltaic device, and the solar shortwave irradiance during a control period;

调控模块,用于基于所述性能参数、所述太阳短波辐照度,求解目标优化函数,得到所述系统在所述调控时段内的控制策略,所述调控时段内的控制策略包括所述系统中的各个装置在所述调控时段内的运行参数,其中,所述目标优化函数的优化目标为所述电解产品的产量最大。A control module is used to solve the target optimization function based on the performance parameters and the solar shortwave irradiance to obtain the control strategy of the system during the control period. The control strategy during the control period includes the operating parameters of each device in the system during the control period, wherein the optimization goal of the target optimization function is to maximize the output of the electrolysis product.

本发明还提供一种电子设备,包括存储器、处理器及存储在存储器上并可在处理器上运行的计算机程序,所述处理器执行所述计算机程序时实现如上述任一种所述调控方法。The present invention also provides an electronic device, comprising a memory, a processor, and a computer program stored in the memory and executable on the processor, wherein the processor implements any of the control methods described above when executing the computer program.

本发明还提供一种非暂态计算机可读存储介质,其上存储有计算机程序,该计算机程序被处理器执行时实现如上述任一种所述调控方法。The present invention also provides a non-transitory computer-readable storage medium having a computer program stored thereon, and when the computer program is executed by a processor, the control method described in any one of the above is implemented.

本发明提供的离网碳中和燃料合成系统及其调控方法、装置,系统包括碳捕集装置、储气罐、电解槽、储能装置以及光伏装置,通过光伏装置向碳捕集装置、储气罐、电解槽供能进行二氧化碳的捕获与电解转化,得到电解产品,实现碳中和燃料的合成,并且考虑到了光伏装置出力在一天范围内波动较大,在系统中还设置储能装置与光伏装置配合,共同供能,可以实现绿色能源驱动的碳捕集和转化。进一步地,本发明还提供了调控该系统的方法,可以实现对该系统的调控,实现燃料合成量的最大化。The present invention provides an off-grid carbon-neutral fuel synthesis system and a control method and device thereof. The system includes a carbon capture device, a gas tank, an electrolyzer, an energy storage device, and a photovoltaic device. The photovoltaic device supplies energy to the carbon capture device, the gas tank, and the electrolyzer to capture and electrolyze carbon dioxide to obtain an electrolysis product, thereby realizing the synthesis of carbon-neutral fuel. In addition, considering that the output of the photovoltaic device fluctuates greatly within a day, an energy storage device is also provided in the system to cooperate with the photovoltaic device to jointly supply energy, thereby realizing green energy-driven carbon capture and conversion. Furthermore, the present invention also provides a method for controlling the system, which can realize the control of the system and maximize the amount of fuel synthesis.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

为了更清楚地说明本发明或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作一简单地介绍,显而易见地,下面描述中的附图是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the present invention or the prior art, the following briefly introduces the drawings required for use in the embodiments or the description of the prior art. Obviously, the drawings described below are some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative work.

图1是本发明提供的离网碳中和燃料合成系统的示意图;FIG1 is a schematic diagram of an off-grid carbon-neutral fuel synthesis system provided by the present invention;

图2是本发明提供的离网碳中和燃料合成系统的调控方法的流程示意图;FIG2 is a schematic flow diagram of a control method for an off-grid carbon-neutral fuel synthesis system provided by the present invention;

图3是本发明提供的离网碳中和燃料合成系统的调控方法的验证实验中碳捕集装置开关状态示意图;3 is a schematic diagram of the switch state of the carbon capture device in the verification experiment of the control method of the off-grid carbon-neutral fuel synthesis system provided by the present invention;

图4是本发明提供的离网碳中和燃料合成系统的调控方法的验证实验中电解槽开关状态示意图;4 is a schematic diagram of the switch state of the electrolyzer in the verification experiment of the control method of the off-grid carbon-neutral fuel synthesis system provided by the present invention;

图5是本发明提供的离网碳中和燃料合成系统的调控方法的验证实验中碳捕集装置运行功率变化图;FIG5 is a graph showing the operating power variation of a carbon capture device in a verification experiment of a control method for an off-grid carbon-neutral fuel synthesis system provided by the present invention;

图6是本发明提供的离网碳中和燃料合成系统的调控方法的验证实验中电解槽运行功率变化图;6 is a graph showing changes in electrolyzer operating power in a verification experiment of a control method for an off-grid carbon-neutral fuel synthesis system provided by the present invention;

图7是本发明提供的离网碳中和燃料合成系统的调控方法的验证实验中储能能量变化图;7 is a diagram showing changes in energy storage in a verification experiment of a control method for an off-grid carbon-neutral fuel synthesis system provided by the present invention;

图8是本发明提供的离网碳中和燃料合成系统的调控方法的验证实验中储能功率状态变化图;8 is a diagram showing the state change of energy storage power in a verification experiment of the control method of the off-grid carbon-neutral fuel synthesis system provided by the present invention;

图9是本发明提供的离网碳中和燃料合成系统的调控方法的验证实验中储气罐内气压变化图;FIG9 is a diagram showing changes in gas pressure in a gas storage tank in a verification experiment of a control method for an off-grid carbon-neutral fuel synthesis system provided by the present invention;

图10是本发明提供的离网碳中和燃料合成系统的调控方法的验证实验中一氧化碳产出情况图;FIG10 is a diagram showing the carbon monoxide output in a verification experiment of the control method of the off-grid carbon-neutral fuel synthesis system provided by the present invention;

图11是本发明提供的离网碳中和燃料合成系统的调控方法的验证实验中氢气产出情况图;FIG11 is a diagram showing hydrogen production in a verification experiment of a control method for an off-grid carbon-neutral fuel synthesis system provided by the present invention;

图12发明提供的离网碳中和燃料合成系统的调控装置的示意图;FIG12 is a schematic diagram of a control device for an off-grid carbon-neutral fuel synthesis system provided by the invention;

图13发明提供的电子设备的结构示意图。FIG13 is a schematic structural diagram of an electronic device provided by the invention.

具体实施方式DETAILED DESCRIPTION

为使本发明的目的、技术方案和优点更加清楚,下面将结合本发明中的附图,对本发明中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purpose, technical solution and advantages of the present invention clearer, the technical solution of the present invention will be clearly and completely described below in conjunction with the drawings of the present invention. Obviously, the described embodiments are part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

下面结合图1描述本发明提供的离网碳中和燃料合成系统,如图1所示,该系统包括:碳捕集装置10、储气罐20、电解槽30、储能装置40以及光伏装置50。碳捕集装置10与储气罐20连接,碳捕集装置用于采集环境中的二氧化碳,传输给储气罐20进行存储。电解槽30与储气罐20连接,储气罐20将二氧化碳输送至电解槽30进行电解,得到电解产品,电解产品为碳中和燃料(一氧化碳、氢气)。储能装置40和光伏装置50共同向碳捕集装置10、储气罐20和电解槽30供电。光伏装置50可以产生光电,但是由于光伏出力具有波动性,因此,本发明提供的系统中,通过储能装置40进行灵活调节,对光伏装置50的供能不稳定性进行灵活补偿,保障系统中其他装置的运行。The off-grid carbon-neutral fuel synthesis system provided by the present invention is described below in conjunction with Figure 1. As shown in Figure 1, the system includes: a carbon capture device 10, a gas tank 20, an electrolyzer 30, an energy storage device 40, and a photovoltaic device 50. The carbon capture device 10 is connected to the gas tank 20, and the carbon capture device is used to collect carbon dioxide in the environment and transmit it to the gas tank 20 for storage. The electrolyzer 30 is connected to the gas tank 20, and the gas tank 20 transports carbon dioxide to the electrolyzer 30 for electrolysis to obtain an electrolysis product, which is a carbon-neutral fuel (carbon monoxide, hydrogen). The energy storage device 40 and the photovoltaic device 50 jointly supply power to the carbon capture device 10, the gas tank 20, and the electrolyzer 30. The photovoltaic device 50 can generate photoelectricity, but because the photovoltaic output is volatile, therefore, in the system provided by the present invention, the energy storage device 40 is flexibly adjusted to flexibly compensate for the instability of the energy supply of the photovoltaic device 50, thereby ensuring the operation of other devices in the system.

进一步地,该系统还可以包括箱体,该箱体可以为集装箱箱体。光伏装置50设置在箱体的外顶部,用于接收太阳能,实现光伏发电,系统中的其他装置可以设置在箱体内部。Furthermore, the system may also include a box, which may be a container box. The photovoltaic device 50 is arranged on the outer top of the box to receive solar energy and realize photovoltaic power generation, and other devices in the system may be arranged inside the box.

本发明提供的离网碳中和燃料合成系统运行时,环境空气中的二氧化碳被碳捕集装置10捕集后,利用光伏装置50与储能装置40配合平缓功率将其电还原为下游产品,是一种全新高效、低能耗光电驱动碳中和燃料合成的方法,该系统运行过程中可以实现完全离网,即不需要接入传统电网,而是可以通过光伏发电和储能并行处理,实现独立运行。When the off-grid carbon-neutral fuel synthesis system provided by the present invention is in operation, the carbon dioxide in the ambient air is captured by the carbon capture device 10, and then the photovoltaic device 50 and the energy storage device 40 are used to cooperate with each other to smoothly reduce it to downstream products. This is a new, efficient, low-energy photovoltaic-driven carbon-neutral fuel synthesis method. The system can be completely off-grid during operation, that is, it does not need to be connected to the traditional power grid, but can be independently operated through parallel processing of photovoltaic power generation and energy storage.

基于上述的离网碳中和燃料合成系统,本发明还提供该系统的调控方法,通过优化调控方法选择离网碳中和燃料合成系统的运行策略,这样可以系统中的各个装置可以基于运行策略运行,实现系统优化调控。如图2所示,该方法包括步骤:Based on the above-mentioned off-grid carbon-neutral fuel synthesis system, the present invention also provides a control method for the system, which selects the operation strategy of the off-grid carbon-neutral fuel synthesis system by optimizing the control method, so that each device in the system can operate based on the operation strategy to achieve system optimization control. As shown in Figure 2, the method includes the steps of:

S210、获取碳捕集装置、储气罐、电解槽、储能装置、光伏装置的性能参数,以及调控时段内的太阳短波辐照度;S210, obtaining the performance parameters of the carbon capture device, gas storage tank, electrolyzer, energy storage device, photovoltaic device, and the solar shortwave irradiance during the control period;

S220、基于性能参数、太阳短波辐照度,求解目标优化函数,得到系统在调控时段内的控制策略,调控时段内的控制策略包括系统中的各个装置在调控时段内的运行参数,目标优化函数的优化目标为电解产品的产量最大。S220. Based on the performance parameters and solar shortwave irradiance, solve the target optimization function to obtain the control strategy of the system during the regulation period. The control strategy during the regulation period includes the operating parameters of each device in the system during the regulation period. The optimization goal of the target optimization function is to maximize the output of electrolytic products.

碳捕集装置、储气罐、电解槽、储能装置和光伏装置的性能参数反映各自的性能,例如储气罐的体积、光伏装置的装机面积、电解槽电解量转换系数、碳捕集装置的转换系数等。基于光伏装置的性能参数和调控时段内的太阳短波辐照度可以得到光伏装置在调控时段内的输出功率,调控时段内的太阳短波辐照度可以采用光伏装置所在位置的平均太阳短波辐照度,也可以根据天气预报的日照时长和日照强度预计得到。The performance parameters of the carbon capture device, gas storage tank, electrolyzer, energy storage device and photovoltaic device reflect their respective performances, such as the volume of the gas storage tank, the installed area of the photovoltaic device, the conversion coefficient of the electrolysis amount of the electrolyzer, the conversion coefficient of the carbon capture device, etc. Based on the performance parameters of the photovoltaic device and the solar short-wave irradiance during the regulation period, the output power of the photovoltaic device during the regulation period can be obtained. The solar short-wave irradiance during the regulation period can be the average solar short-wave irradiance at the location of the photovoltaic device, or it can be estimated based on the sunshine duration and sunshine intensity of the weather forecast.

光伏装置的输出功率具体可以采用以下公式确定:The output power of the photovoltaic device can be determined by the following formula:

其中,Ppv是光伏装置的输出功率,HA是太阳短波辐照度,PAZ是光伏装置的装机容量,K是光伏装置的效率,是光伏功率密度,S是光伏装置的装机面积,Ea表示标准条件下的辐照度。Where P pv is the output power of the photovoltaic device, HA is the solar shortwave irradiance, P AZ is the installed capacity of the photovoltaic device, K is the efficiency of the photovoltaic device, is the photovoltaic power density, S is the installed area of the photovoltaic device, and Ea represents the irradiance under standard conditions.

在求解目标优化函数之前,还需要计算储气罐内压力具体可以采用下式计算:Before solving the target optimization function, it is also necessary to calculate the pressure in the gas tank The specific calculation can be done using the following formula:

其中,代表储气罐内二氧化碳物质的量,R是气体摩尔常数,T是温度,是储气罐体积。气体物质的量参数由气体体积及理想气体状态方程得到。in, represents the amount of carbon dioxide in the gas tank, R is the gas molar constant, T is the temperature, is the volume of the gas tank. The amount parameters of the gas substance are obtained from the gas volume and the ideal gas state equation.

碳捕集装置捕集的二氧化碳的气压patmos满足下式:The gas pressure p atmos of carbon dioxide captured by the carbon capture device satisfies the following formula:

式中代表储气罐进、出气体积,代表储气罐进、出气物质的量。In the formula Represents the volume of gas inlet and outlet of the gas storage tank, Represents the amount of gas entering and exiting the gas tank.

本发明提供的方法中,以电解产品的产量最大化作为目标优化函数的优化目标,可以实现碳中和燃料产量的最大化。目标优化函数可以用公式表示为:In the method provided by the present invention, the maximum output of the electrolysis product is used as the optimization target of the target optimization function, which can achieve the maximum output of carbon-neutral fuel. The target optimization function can be expressed as:

式中B(ti)代表第i个颗粒度时段内参数B的值,nh为调控时段,nco代表一氧化碳产出物质的量,代表一氧化碳转化系数,nH2代表氢气产出物质的量,代表氢气转化系数。设置目标函数的目的是保证在调控时间范围内得到产品一氧化碳/氢气的产量最大值,从而使收益最大化。Where B(t i ) represents the value of parameter B in the i-th particle size period, nh is the control period, and n co represents the amount of carbon monoxide output. represents the carbon monoxide conversion coefficient, n H2 represents the amount of hydrogen produced, Represents the hydrogen conversion coefficient. The purpose of setting the objective function is to ensure that the maximum output of product carbon monoxide/hydrogen is obtained within the control time range, thereby maximizing the profit.

求解目标优化函数得到的结果应当能够满足实际运行条件,在本发明提供的方法中,为了保证求解目标优化函数得到的控制策略的可行性,设置了约束条件,在求解目标优化函数时,需要满足各约束条件。即,基于性能参数、太阳短波辐照度,在预设的约束条件下,求解目标优化函数,得到系统在调控时段内的控制策略。The result obtained by solving the target optimization function should be able to meet the actual operating conditions. In the method provided by the present invention, in order to ensure the feasibility of the control strategy obtained by solving the target optimization function, constraints are set. When solving the target optimization function, each constraint needs to be satisfied. That is, based on the performance parameters and solar shortwave irradiance, under the preset constraints, the target optimization function is solved to obtain the control strategy of the system during the regulation period.

具体来说,约束条件包括系统内的装置的关联约束以及系统内的装置的运行约束。Specifically, the constraint conditions include association constraints of devices in the system and operation constraints of devices in the system.

关联约束用于约束二氧化碳在碳捕集装置、储气罐和电解槽之间的流动以及约束系统的电能来自储能装置和光伏装置。碳捕集装置、储气罐、电解槽的关联约束可以表示为:The association constraints are used to constrain the flow of carbon dioxide between the carbon capture device, the gas storage tank and the electrolyzer, and to constrain the system's electrical energy to come from the energy storage device and the photovoltaic device. The association constraints of the carbon capture device, the gas storage tank and the electrolyzer can be expressed as:

代表碳捕集装置捕集二氧化碳物质的量,代表储气罐进气物质的量,代表储气罐出气物质的量,代表电解槽电解的二氧化碳物质的量,该二式约束规定了碳捕集装置捕集二氧化碳进入储气罐,储气罐出气进入电解槽。 Represents the amount of carbon dioxide captured by the carbon capture device, Represents the amount of gas entering the gas tank. Represents the amount of gas discharged from the gas tank. Represents the amount of carbon dioxide electrolyzed by the electrolyzer. This two-equation constraint stipulates that the carbon capture device captures carbon dioxide into the gas storage tank, and the gas out of the gas storage tank enters the electrolyzer.

代表每颗粒度时段内储气罐新增储气物质的量,代表储气罐最大进气、出气速度,该式约束规定了储气罐实时储气量。 Represents the amount of new gas storage material in the gas tank during each granularity period. Represents the maximum air intake and outlet speed of the gas tank. This constraint stipulates the real-time gas storage capacity of the gas tank.

储能装置和光伏装置的关联约束可以表示为:The associated constraints between the energy storage device and the photovoltaic device can be expressed as:

Pexp(ti)=Ppv(ti)+Pess(ti)i∈nh;P exp (t i )=P pv (t i )+P ess (t i )i∈nh;

其中,Pexp代表储能装置和光伏装置配合输出功率,Pess代表代表储能装置的工作功率。该式约束规定了系统中功率的供给部分。Among them, P exp represents the output power of the energy storage device and the photovoltaic device, and P ess represents the working power of the energy storage device. This constraint specifies the power supply part of the system.

在系统运行时,有多个调控时段,为了系统长期稳定运行,在每个调控时段结束时,储能装置内要有足够的电能以保障下个调控时段内的光伏出力波动,并且,储气罐内也要有足够的其他保障下个调控时段内的二氧化碳处理。而由于目标优化函数的目标是使得电解产品的产量最大,如果不对储能装置的能量和储气罐内的气体量进行约束,最终求解结果会使得调控时段结束后,储能装置和储气罐内的气体量尽可能小,甚至达到0,这样无法支撑下一个调控时段的运行。为了保证系统的长期稳定运行,本发明提供的方法中,系统内的装置的运行约束包括第一约束条件,第一约束条件用于约束在调控时段结束时,储能装置中的能量总变化量吧以及储气罐内的二氧化碳的量的总变化量均为0。第一约束可以用公式表示为:When the system is running, there are multiple control periods. In order to ensure the long-term stable operation of the system, at the end of each control period, there must be enough electric energy in the energy storage device to ensure the photovoltaic output fluctuations in the next control period, and there must be enough other energy in the gas tank to ensure the carbon dioxide treatment in the next control period. Since the goal of the objective optimization function is to maximize the output of electrolysis products, if the energy of the energy storage device and the amount of gas in the gas tank are not constrained, the final solution result will make the amount of gas in the energy storage device and the gas tank as small as possible, or even reach 0 after the end of the control period, which cannot support the operation of the next control period. In order to ensure the long-term stable operation of the system, in the method provided by the present invention, the operation constraints of the devices in the system include a first constraint condition, and the first constraint condition is used to constrain the total change in energy in the energy storage device and the total change in the amount of carbon dioxide in the gas tank to be 0 at the end of the control period. The first constraint can be expressed by the formula:

Eess(tnh)=Eess0 Eess ( tnh )= Eess0

其中,Eess代表储能中能量保有量,Eess0代表调控时段开始时储能能量初始值。上述两个公式约束了在调控时段范围内,储能中的能量总变化量为0,储气罐内的二氧化碳量总变化量为0。Among them, E ess represents the energy storage, and E ess0 represents the initial value of the energy storage at the beginning of the regulation period. The above two formulas constrain that within the regulation period, the total change in energy in the energy storage is 0, and the total change in the amount of carbon dioxide in the gas tank is 0.

进一步地,系统内的装置的运行约束还包括第二约束条件,第二约束条件用于约束碳捕集装置以及电解槽的运行状态,第二约束条件为:Furthermore, the operation constraints of the devices in the system also include a second constraint condition, which is used to constrain the operation state of the carbon capture device and the electrolyzer. The second constraint condition is:

ucc、uelec是一个0,1变量,代表碳捕集装置和电解槽的开关状态,Pcc代表碳捕集装置的功率,acc表示碳捕集装置的碳捕集转换系数,Pelec代表电解槽的功率,aelec代表电解槽的电解量转换系数,awas代表电解槽处理二氧化碳的损耗系数。第二约束规定了碳捕集装置捕集二氧化碳物质的量以及电解槽电解的二氧化碳物质的量,且约束中规定了电解二氧化碳的损耗返还,更加符合系统的实际运行情况。u cc and u elec are 0, 1 variables, representing the switch status of the carbon capture device and the electrolyzer, P cc represents the power of the carbon capture device, a cc represents the carbon capture conversion coefficient of the carbon capture device, P elec represents the power of the electrolyzer, a elec represents the electrolysis conversion coefficient of the electrolyzer, and a was represents the loss coefficient of the electrolyzer for processing carbon dioxide. The second constraint stipulates the amount of carbon dioxide captured by the carbon capture device and the amount of carbon dioxide electrolyzed by the electrolyzer, and the constraint stipulates the loss return of electrolyzed carbon dioxide, which is more in line with the actual operation of the system.

系统内的装置的运行约束还包括第三约束条件,第三约束条件用于约束碳捕集装置和电解槽在调控时段内最大连续运行颗粒度时段个数,第三约束用公式表示为:The operating constraints of the devices in the system also include a third constraint condition, which is used to constrain the maximum number of continuous operation particle size periods of the carbon capture device and the electrolyzer within the control period. The third constraint is expressed by the formula:

其中,分别代表碳捕集装置和电解槽在调控时间范围内最大连续运行颗粒度时段的个数。in, and They represent the number of maximum continuous operating particle size periods of the carbon capture device and the electrolyzer within the control time range respectively.

考虑碳捕集装置和电解槽连续运行过长时间会导致过负载,本发明提供的方法中,通过第三约束条件,可以约束碳捕集装置和电解槽在调控时段内最大连续运行时长在一个范围内,防止装置长时间连续运行带来的损耗,同时约束了调控时段内最大连续关断时长在规定的颗粒度时段个数范围内,防止装置长时间关断后重启带来的额外损耗。Considering that continuous operation of the carbon capture device and the electrolyzer for too long may lead to overload, in the method provided by the present invention, the third constraint condition can be used to constrain the maximum continuous operation time of the carbon capture device and the electrolyzer within the control period to be within a range, thereby preventing losses caused by long-term continuous operation of the device. At the same time, the maximum continuous shutdown time within the control period is constrained to be within the specified number of granularity time periods, thereby preventing additional losses caused by restarting the device after being shut down for a long time.

进一步地,系统内的装置的运行约束还包括系统功率平衡约束,该约束用于规定系统内的装置的功率平衡,该约束可以用公式表示为:Furthermore, the operation constraints of the devices in the system also include a system power balance constraint, which is used to specify the power balance of the devices in the system. The constraint can be expressed by the formula:

ucc(ti)Pcc+uelec(ti)Pelec-ucc(ti)Pcom=Pess(ti)+Ppv(ti)i∈nh;u cc (t i )P cc +u elec (t i )P elec -u cc (t i )P com =P ess (t i )+P pv (t i )i∈nh;

Pcc代表碳捕集装置功率,Pelec代表电解槽功率,Pcom代表CO2泵入储气罐的压缩功率。P cc represents the power of the carbon capture device, P elec represents the power of the electrolyzer, and P com represents the compression power of CO2 pumped into the gas tank.

进一步地,系统内的装置的运行约束还包括储气罐储气约束,该约束用于规定储气罐内的气体变化情况。该约束可以表示为:Furthermore, the operation constraints of the devices in the system also include gas storage constraints of the gas storage tank, which are used to specify the change of the gas in the gas storage tank. The constraint can be expressed as:

代表储气罐初始储气量,代表储气罐最低/最高储气量,代表储气罐内最高气压。 Represents the initial gas storage capacity of the gas tank, Represents the minimum/maximum gas storage capacity of the gas tank. Represents the maximum air pressure in the gas tank.

系统内的装置的运行约束还包括储能效率约束,该约束用于规定储能的效率变化,该约束可以表示为:The operating constraints of the devices in the system also include energy storage efficiency constraints, which are used to specify the efficiency change of energy storage. The constraint can be expressed as:

0≤Eess≤Eess_max Pess_min≤Pess≤Pess_max0≤E ess ≤E ess_max P ess_min ≤P ess ≤P ess_max ;

式中b代表储能效率,Eess_max代表储能最大能量,Pess_min/max代表储能功率上下限。Where b represents the energy storage efficiency, E ess_max represents the maximum energy storage energy, and P ess_min/max represents the upper and lower limits of the energy storage power.

系统内的装置的运行约束还包括二氧化碳压缩功率约束,该约束用于规定将二氧化碳压入储气罐的压缩功率,该约束可以表示为:The operating constraints of the devices in the system also include a carbon dioxide compression power constraint, which is used to specify the compression power for compressing carbon dioxide into the gas storage tank. The constraint can be expressed as:

在上述所有约束条件下,求解目标函数,得到系统在调控时段内的控制策略,该控制策略中包括系统中的各装置在调控时段内应该以什么样的状态运行。Under all the above constraints, the objective function is solved to obtain the control strategy of the system during the regulation period, which includes the state in which each device in the system should operate during the regulation period.

为了验证本发明提供的调控方法的有效性,构建了系统样例并进行实验验证。在实验中,采用20GP标准集装箱,集装箱顶部铺设光伏装置,系统中的装置的参数如表1所示,通过表1所示的装置参数计算,集装箱体积足够集成系统中的各个装置。In order to verify the effectiveness of the control method provided by the present invention, a system sample was constructed and experimental verification was performed. In the experiment, a 20GP standard container was used, and a photovoltaic device was laid on the top of the container. The parameters of the devices in the system are shown in Table 1. According to the device parameters shown in Table 1, the container volume is sufficient to integrate the various devices in the system.

表1Table 1

参数parameter value 参数parameter value 光伏板面积S(m2)Photovoltaic panel area S (m 2 ) 1515 光伏综合效率KPhotovoltaic comprehensive efficiency K 0.850.85 光伏功率密度(KW/m2)Photovoltaic power density (KW/m 2 ) 0.80.8 储能能量密度(KWh/kg)Energy storage density (KWh/kg) 0.150.15 储气罐容积(L)Gas tank capacity (L) 200200 集装箱(GP)Container (GP) 2020

以调控时间范围(nh)48h,颗粒度为1小时进行优化调控。储能的功率及容量会对结果产生影响,在储能效率(b)为0.9时,改变储能的功率限制及容量,对模型进行测试,确定合适的储能容量及功率限制,储能容量(Eess/max)20KWh,储能功率限制(Pess_min/max)±5KW。The optimization control is performed with a control time range (nh) of 48h and a granularity of 1 hour. The power and capacity of energy storage will affect the results. When the energy storage efficiency (b) is 0.9, the power limit and capacity of energy storage are changed, and the model is tested to determine the appropriate energy storage capacity and power limit. The energy storage capacity (E ess/max ) is 20KWh, and the energy storage power limit (P ess_min/max ) is ±5KW.

图3-4展示了在调控时间范围内碳捕集装置和电解槽的开关状态,图5-6展示了在调控时间范围内碳捕集装置和电解槽的运行功率状态,图7-8展示了储能能量和储能功率在调控时间内的变化情况,图9展示了储气罐内气压状态。Figures 3-4 show the switching status of the carbon capture device and the electrolyzer within the control time range. Figures 5-6 show the operating power status of the carbon capture device and the electrolyzer within the control time range. Figures 7-8 show the changes in energy storage energy and energy storage power within the control time. Figure 9 shows the gas pressure status in the gas tank.

图10-11展示了在优化调控时间范围内的产品一氧化碳/氢气的产出情况,表明了在所述目标方法的目标线性规划模型下目标函数的最优解。在上述算例条件下,并采取运行结果展示的控制方法,计算得到调控时间范围内目标函数一氧化碳/氢气产出量最大值为33.9386mol/111.6144mol。Figures 10-11 show the output of carbon monoxide/hydrogen products within the optimized control time range, indicating the optimal solution of the objective function under the target linear programming model of the target method. Under the above example conditions and the control method shown in the running results, the maximum value of the carbon monoxide/hydrogen output of the objective function within the control time range is calculated to be 33.9386mol/111.6144mol.

在实验过程中,该系统稳定运行,证明本发明提供的调控方法可以实现对系统的稳定有效控制。During the experiment, the system operated stably, proving that the regulation method provided by the present invention can achieve stable and effective control of the system.

下面对本发明提供的调控装置进行描述,下文描述的调控装置与上文描述的调控方法可相互对应参照。如图12所示,本发明提供的调控装置包括:The control device provided by the present invention is described below. The control device described below and the control method described above can be referred to each other. As shown in FIG12 , the control device provided by the present invention includes:

参数获取模块1210,用于获取碳捕集装置、储气罐、所述电解槽、储能装置、光伏装置的性能参数、以及调控时段内的太阳短波辐照度;The parameter acquisition module 1210 is used to obtain the performance parameters of the carbon capture device, the gas storage tank, the electrolyzer, the energy storage device, the photovoltaic device, and the solar shortwave irradiance during the control period;

调控模块1220,用于基于性能参数、太阳短波辐照度,求解目标优化函数,得到系统在调控时段内的控制策略,调控时段内的控制策略包括系统中的各个装置在调控时段内的运行参数,其中,目标优化函数的优化目标为电解产品的产量最大。The control module 1220 is used to solve the target optimization function based on the performance parameters and the solar shortwave irradiance to obtain the control strategy of the system during the control period. The control strategy during the control period includes the operating parameters of each device in the system during the control period. The optimization goal of the target optimization function is to maximize the output of the electrolytic product.

图13示例了一种电子设备的实体结构示意图,如图13所示,该电子设备可以包括:处理器(processor)1310、通信接口(Communications Interface)1320、存储器(memory)1330和通信总线1340,其中,处理器1310,通信接口1320,存储器1330通过通信总线1340完成相互间的通信。处理器1310可以调用存储器1330中的逻辑指令,以执行离网碳中和燃料合成系统的调控方法,该方法包括:获取碳捕集装置、储气罐、电解槽、储能装置、光伏装置的性能参数、以及调控时段内的太阳短波辐照度;基于性能参数、太阳短波辐照度,求解目标优化函数,得到系统在调控时段内的控制策略,调控时段内的控制策略包括系统中的各个装置在调控时段内的运行参数,其中,目标优化函数的优化目标为电解产品的产量最大。FIG13 illustrates a schematic diagram of the physical structure of an electronic device. As shown in FIG13 , the electronic device may include: a processor 1310, a communication interface 1320, a memory 1330 and a communication bus 1340, wherein the processor 1310, the communication interface 1320 and the memory 1330 communicate with each other through the communication bus 1340. The processor 1310 may call the logic instructions in the memory 1330 to execute the control method of the off-grid carbon neutral fuel synthesis system, the method comprising: obtaining the performance parameters of the carbon capture device, the gas storage tank, the electrolyzer, the energy storage device, the photovoltaic device, and the solar shortwave irradiance during the control period; based on the performance parameters and the solar shortwave irradiance, solving the target optimization function, and obtaining the control strategy of the system during the control period, the control strategy during the control period includes the operating parameters of each device in the system during the control period, wherein the optimization target of the target optimization function is to maximize the output of the electrolysis product.

此外,上述的存储器1330中的逻辑指令可以通过软件功能单元的形式实现并作为独立的产品销售或使用时,可以存储在一个计算机可读取存储介质中。基于这样的理解,本发明的技术方案本质上或者说对现有技术做出贡献的部分或者该技术方案的部分可以以软件产品的形式体现出来,该计算机软件产品存储在一个存储介质中,包括若干指令用以使得一台计算机设备(可以是个人计算机,服务器,或者网络设备等)执行本发明各个实施例所述方法的全部或部分步骤。而前述的存储介质包括:U盘、移动硬盘、只读存储器(ROM,Read-Only Memory)、随机存取存储器(RAM,Random Access Memory)、磁碟或者光盘等各种可以存储程序代码的介质。In addition, the logic instructions in the above-mentioned memory 1330 can be implemented in the form of a software functional unit and can be stored in a computer-readable storage medium when it is sold or used as an independent product. Based on such an understanding, the technical solution of the present invention, in essence, or the part that contributes to the prior art or the part of the technical solution, can be embodied in the form of a software product, and the computer software product is stored in a storage medium, including a number of instructions for a computer device (which can be a personal computer, a server, or a network device, etc.) to perform all or part of the steps of the method described in each embodiment of the present invention. The aforementioned storage medium includes: U disk, mobile hard disk, read-only memory (ROM, Read-Only Memory), random access memory (RAM, Random Access Memory), disk or optical disk and other media that can store program codes.

又一方面,本发明还提供一种非暂态计算机可读存储介质,其上存储有计算机程序,该计算机程序被处理器执行时实现以执行上述各方法提供的离网碳中和燃料合成系统的调控方法,该方法包括:获取碳捕集装置、储气罐、电解槽、储能装置、光伏装置的性能参数、以及调控时段内的太阳短波辐照度;基于性能参数、太阳短波辐照度,求解目标优化函数,得到系统在调控时段内的控制策略,调控时段内的控制策略包括系统中的各个装置在调控时段内的运行参数,其中,目标优化函数的优化目标为电解产品的产量最大。On the other hand, the present invention also provides a non-transitory computer-readable storage medium having a computer program stored thereon, which, when executed by a processor, is implemented to execute the control method of an off-grid carbon-neutral fuel synthesis system provided by the above-mentioned methods, the method comprising: obtaining performance parameters of a carbon capture device, a gas storage tank, an electrolyzer, an energy storage device, a photovoltaic device, and the solar shortwave irradiance during a control period; based on the performance parameters and the solar shortwave irradiance, solving a target optimization function to obtain a control strategy for the system during the control period, the control strategy during the control period including the operating parameters of each device in the system during the control period, wherein the optimization target of the target optimization function is to maximize the output of electrolysis products.

以上所描述的装置实施例仅仅是示意性的,其中所述作为分离部件说明的单元可以是或者也可以不是物理上分开的,作为单元显示的部件可以是或者也可以不是物理单元,即可以位于一个地方,或者也可以分布到多个网络单元上。可以根据实际的需要选择其中的部分或者全部模块来实现本实施例方案的目的。本领域普通技术人员在不付出创造性的劳动的情况下,即可以理解并实施。The device embodiments described above are merely illustrative, wherein the units described as separate components may or may not be physically separated, and the components displayed as units may or may not be physical units, that is, they may be located in one place, or may be distributed on multiple network units. Some or all of the modules may be selected according to actual needs to achieve the purpose of the scheme of this embodiment. Those of ordinary skill in the art may understand and implement it without creative effort.

通过以上的实施方式的描述,本领域的技术人员可以清楚地了解到各实施方式可借助软件加必需的通用硬件平台的方式来实现,当然也可以通过硬件。基于这样的理解,上述技术方案本质上或者说对现有技术做出贡献的部分可以以软件产品的形式体现出来,该计算机软件产品可以存储在计算机可读存储介质中,如ROM/RAM、磁碟、光盘等,包括若干指令用以使得一台计算机设备(可以是个人计算机,服务器,或者网络设备等)执行各个实施例或者实施例的某些部分所述的方法。Through the description of the above implementation methods, those skilled in the art can clearly understand that each implementation method can be implemented by means of software plus a necessary general hardware platform, and of course, it can also be implemented by hardware. Based on this understanding, the above technical solution is essentially or the part that contributes to the prior art can be embodied in the form of a software product, and the computer software product can be stored in a computer-readable storage medium, such as ROM/RAM, a disk, an optical disk, etc., including a number of instructions for a computer device (which can be a personal computer, a server, or a network device, etc.) to execute the methods described in each embodiment or some parts of the embodiments.

最后应说明的是:以上实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or make equivalent replacements for some of the technical features therein. However, these modifications or replacements do not deviate the essence of the corresponding technical solutions from the spirit and scope of the technical solutions of the embodiments of the present invention.

Claims (4)

1.一种基于离网碳中和燃料合成系统的调控方法,其特征在于,所述离网碳中和燃料合成系统包括:1. A control method based on an off-grid carbon-neutral fuel synthesis system, characterized in that the off-grid carbon-neutral fuel synthesis system comprises: 碳捕集装置,所述碳捕集装置用于采集环境中的二氧化碳;A carbon capture device, wherein the carbon capture device is used to collect carbon dioxide in the environment; 储气罐,所述储气罐与所述碳捕集装置连接,用于储存二氧化碳;A gas storage tank, the gas storage tank is connected to the carbon capture device and is used to store carbon dioxide; 电解槽,所述电解槽与所述储气罐连接,用于对二氧化碳进行电解,得到电解产品;An electrolytic cell, the electrolytic cell being connected to the gas storage tank and being used to electrolyze carbon dioxide to obtain an electrolysis product; 储能装置,所述储能装置用于对所述碳捕集装置以及所述电解槽供能;An energy storage device, the energy storage device is used to supply energy to the carbon capture device and the electrolyzer; 光伏装置,所述光伏装置用于产生电能,向所述碳捕集装置、所述电解槽以及所述储能装置供能;A photovoltaic device, the photovoltaic device is used to generate electrical energy to supply energy to the carbon capture device, the electrolyzer and the energy storage device; 所述方法包括:The method comprises: 获取所述碳捕集装置、所述储气罐、所述电解槽、所述储能装置、所述光伏装置的性能参数、以及调控时段内的太阳短波辐照度;Obtaining performance parameters of the carbon capture device, the gas storage tank, the electrolyzer, the energy storage device, the photovoltaic device, and the solar shortwave irradiance during the regulation period; 基于所述性能参数、所述太阳短波辐照度,求解目标优化函数,得到所述系统在所述调控时段内的控制策略,所述调控时段内的控制策略包括所述系统中的各个装置在所述调控时段内的运行参数,其中,所述目标优化函数的优化目标为所述电解产品的产量最大;Based on the performance parameters and the solar shortwave irradiance, solving the target optimization function, obtaining the control strategy of the system in the regulation period, wherein the control strategy in the regulation period includes the operating parameters of each device in the system in the regulation period, wherein the optimization target of the target optimization function is to maximize the output of the electrolysis product; 所述基于所述性能参数、所述太阳短波辐照度,求解目标优化函数,得到所述系统在所述调控时段内的控制策略,包括:The method of solving the target optimization function based on the performance parameter and the solar shortwave irradiance to obtain the control strategy of the system within the regulation period includes: 基于所述性能参数、所述太阳短波辐照度,在预设的约束条件下,求解所述目标优化函数,得到所述系统在所述调控时段内的控制策略;Based on the performance parameters and the solar shortwave irradiance, under preset constraints, solving the target optimization function to obtain a control strategy for the system within the regulation period; 其中,所述约束条件包括所述系统内的装置的关联约束以及所述系统内的装置的运行约束;The constraint conditions include association constraints of devices in the system and operation constraints of devices in the system; 所述系统内的装置的关联约束用于约束二氧化碳在所述碳捕集装置、所述储气罐和所述电解槽之间的流动,以及约束所述系统的电能来自于所述储能装置和所述光伏装置;The associated constraints of the devices in the system are used to constrain the flow of carbon dioxide between the carbon capture device, the gas storage tank and the electrolyzer, and to constrain the electrical energy of the system to come from the energy storage device and the photovoltaic device; 所述系统内的装置的运行约束用于约束所述系统内的各个装置的运行状态;The operation constraints of the devices in the system are used to constrain the operation status of each device in the system; 所述调控时段有多个;所述系统内的装置的运行约束包括第一约束条件,所述第一约束条件用于约束在所述调控时段结束时,所述储能装置中的能量总变化量以及所述储气罐内的二氧化碳的量总变化量均为0;There are multiple control periods; the operation constraints of the devices in the system include a first constraint condition, which is used to constrain that at the end of the control period, the total change in energy in the energy storage device and the total change in carbon dioxide in the gas storage tank are both 0; 所述系统内的装置的运行约束包括第二约束条件,所述第二约束条件用于约束所述碳捕集装置以及所述电解槽的运行状态;The operation constraints of the devices in the system include a second constraint condition, wherein the second constraint condition is used to constrain the operation states of the carbon capture device and the electrolyzer; 所述第二约束条件为:The second constraint is: 其中,B(ti)代表第i个颗粒度时段内参数B的值,nh为所述调控时段,表示所述储气罐进气物质的量,代表所述碳捕集装置捕集二氧化碳物质的量,ucc、uelec是一个0,1变量,代表所述碳捕集装置和所述电解槽的开关状态,Pcc代表所述碳捕集装置的功率,acc表示所述碳捕集装置的碳捕集转换系数,Pelec代表所述电解槽的功率,aelec代表所述电解槽的电解量转换系数,awas代表所述电解槽处理二氧化碳的损耗系数;Wherein, B(t i ) represents the value of parameter B in the i-th granularity period, nh is the control period, Indicates the amount of gas inlet material in the gas tank, represents the amount of carbon dioxide captured by the carbon capture device, u cc and u elec are 0, 1 variables, representing the switch status of the carbon capture device and the electrolyzer, P cc represents the power of the carbon capture device, a cc represents the carbon capture conversion coefficient of the carbon capture device, P elec represents the power of the electrolyzer, a elec represents the electrolysis conversion coefficient of the electrolyzer, and a was represents the loss coefficient of the electrolyzer in processing carbon dioxide; 所述系统内的装置的运行约束包括第三约束条件,所述第三约束条件用于约束所述碳捕集装置以及所述电解槽在所述调控时段内最大连续运行颗粒度时段个数;所述第三约束条件为:The operation constraints of the devices in the system include a third constraint condition, which is used to constrain the maximum number of continuous operation particle size time periods of the carbon capture device and the electrolyzer within the control period; the third constraint condition is: 其中,分别代表所述碳捕集装置和所述电解槽在调控时间范围内最大连续运行颗粒度时段的个数。in, and They respectively represent the number of maximum continuous operation particle size periods of the carbon capture device and the electrolyzer within the regulation time range. 2.一种基于离网碳中和燃料合成系统的调控装置,其特征在于,所述离网碳中和燃料合成系统包括:2. A control device based on an off-grid carbon-neutral fuel synthesis system, characterized in that the off-grid carbon-neutral fuel synthesis system comprises: 碳捕集装置,所述碳捕集装置用于采集环境中的二氧化碳;A carbon capture device, wherein the carbon capture device is used to collect carbon dioxide in the environment; 储气罐,所述储气罐与所述碳捕集装置连接,用于储存二氧化碳;A gas storage tank, the gas storage tank is connected to the carbon capture device and is used to store carbon dioxide; 电解槽,所述电解槽与所述储气罐连接,用于对二氧化碳进行电解,得到电解产品;An electrolytic cell, the electrolytic cell being connected to the gas storage tank and being used to electrolyze carbon dioxide to obtain an electrolysis product; 储能装置,所述储能装置用于对所述碳捕集装置以及所述电解槽供能;An energy storage device, the energy storage device is used to supply energy to the carbon capture device and the electrolyzer; 光伏装置,所述光伏装置用于产生电能,向所述碳捕集装置、所述电解槽以及所述储能装置供能;A photovoltaic device, the photovoltaic device is used to generate electrical energy to supply energy to the carbon capture device, the electrolyzer and the energy storage device; 所述调控装置包括:The control device comprises: 参数获取模块,用于获取所述碳捕集装置、所述储气罐、所述电解槽、所述储能装置、所述光伏装置的性能参数、以及调控时段内的太阳短波辐照度;A parameter acquisition module, used to acquire performance parameters of the carbon capture device, the gas storage tank, the electrolyzer, the energy storage device, the photovoltaic device, and the solar shortwave irradiance during a control period; 调控模块,用于基于所述性能参数、所述太阳短波辐照度,求解目标优化函数,得到所述系统在所述调控时段内的控制策略,所述调控时段内的控制策略包括所述系统中的各个装置在所述调控时段内的运行参数,其中,所述目标优化函数的优化目标为所述电解产品的产量最大;A control module, used to solve the target optimization function based on the performance parameters and the solar shortwave irradiance, and obtain the control strategy of the system in the control period, wherein the control strategy in the control period includes the operating parameters of each device in the system in the control period, wherein the optimization target of the target optimization function is to maximize the output of the electrolysis product; 所述基于所述性能参数、所述太阳短波辐照度,求解目标优化函数,得到所述系统在所述调控时段内的控制策略,包括:The method of solving the target optimization function based on the performance parameter and the solar shortwave irradiance to obtain the control strategy of the system within the regulation period includes: 基于所述性能参数、所述太阳短波辐照度,在预设的约束条件下,求解所述目标优化函数,得到所述系统在所述调控时段内的控制策略;Based on the performance parameters and the solar shortwave irradiance, under preset constraints, solving the target optimization function to obtain a control strategy for the system within the regulation period; 其中,所述约束条件包括所述系统内的装置的关联约束以及所述系统内的装置的运行约束;The constraint conditions include association constraints of devices in the system and operation constraints of devices in the system; 所述系统内的装置的关联约束用于约束二氧化碳在所述碳捕集装置、所述储气罐和所述电解槽之间的流动,以及约束所述系统的电能来自于所述储能装置和所述光伏装置;The associated constraints of the devices in the system are used to constrain the flow of carbon dioxide between the carbon capture device, the gas storage tank and the electrolyzer, and to constrain the electrical energy of the system to come from the energy storage device and the photovoltaic device; 所述系统内的装置的运行约束用于约束所述系统内的各个装置的运行状态;The operation constraints of the devices in the system are used to constrain the operation status of each device in the system; 所述调控时段有多个;所述系统内的装置的运行约束包括第一约束条件,所述第一约束条件用于约束在所述调控时段结束时,所述储能装置中的能量总变化量以及所述储气罐内的二氧化碳的量总变化量均为0;There are multiple control periods; the operation constraints of the devices in the system include a first constraint condition, which is used to constrain that at the end of the control period, the total change in energy in the energy storage device and the total change in carbon dioxide in the gas storage tank are both 0; 所述系统内的装置的运行约束包括第二约束条件,所述第二约束条件用于约束所述碳捕集装置以及所述电解槽的运行状态;The operation constraints of the devices in the system include a second constraint condition, wherein the second constraint condition is used to constrain the operation states of the carbon capture device and the electrolyzer; 所述第二约束条件为:The second constraint is: 其中,B(ti)代表第i个颗粒度时段内参数B的值,nh为所述调控时段,表示所述储气罐进气物质的量,代表所述碳捕集装置捕集二氧化碳物质的量,ucc、uelec是一个0,1变量,代表所述碳捕集装置和所述电解槽的开关状态,Pcc代表所述碳捕集装置的功率,acc表示所述碳捕集装置的碳捕集转换系数,Pe l ec代表所述电解槽的功率,aelec代表所述电解槽的电解量转换系数,awas代表所述电解槽处理二氧化碳的损耗系数;Wherein, B(t i ) represents the value of parameter B in the i-th granularity period, nh is the control period, Indicates the amount of gas inlet material in the gas tank, represents the amount of carbon dioxide captured by the carbon capture device, u cc and u elec are 0, 1 variables, representing the switch status of the carbon capture device and the electrolyzer, P cc represents the power of the carbon capture device, a cc represents the carbon capture conversion coefficient of the carbon capture device, P e l ec represents the power of the electrolyzer, a elec represents the electrolysis amount conversion coefficient of the electrolyzer, and a was represents the loss coefficient of the electrolyzer in processing carbon dioxide; 所述系统内的装置的运行约束包括第三约束条件,所述第三约束条件用于约束所述碳捕集装置以及所述电解槽在所述调控时段内最大连续运行颗粒度时段个数;所述第三约束条件为:The operation constraints of the devices in the system include a third constraint condition, which is used to constrain the maximum number of continuous operation particle size time periods of the carbon capture device and the electrolyzer within the control period; the third constraint condition is: 其中,分别代表所述碳捕集装置和所述电解槽在调控时间范围内最大连续运行颗粒度时段的个数。in, and They respectively represent the number of maximum continuous operation particle size periods of the carbon capture device and the electrolyzer within the regulation time range. 3.一种电子设备,包括存储器、处理器及存储在所述存储器上并可在所述处理器上运行的计算机程序,其特征在于,所述处理器执行所述计算机程序时实现如权利要求1所述调控方法。3. An electronic device comprising a memory, a processor, and a computer program stored in the memory and executable on the processor, wherein the processor implements the control method as claimed in claim 1 when executing the computer program. 4.一种非暂态计算机可读存储介质,其上存储有计算机程序,其特征在于,所述计算机程序被处理器执行时实现如权利要求1所述调控方法。4. A non-transitory computer-readable storage medium having a computer program stored thereon, wherein the computer program implements the control method as claimed in claim 1 when executed by a processor.
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