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CN118001915A - Tail gas treatment device of fermentation system - Google Patents

Tail gas treatment device of fermentation system Download PDF

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Publication number
CN118001915A
CN118001915A CN202410378422.6A CN202410378422A CN118001915A CN 118001915 A CN118001915 A CN 118001915A CN 202410378422 A CN202410378422 A CN 202410378422A CN 118001915 A CN118001915 A CN 118001915A
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tank
pipe
alkaline
liquid
washing tower
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CN118001915B (en
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霍志强
周健廷
董宁
田杨
刘亚婷
臧金金
白瑞霞
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China Chemical Engineering Second Construction Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/79Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/005Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor

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  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a tail gas treatment device of a fermentation system, which comprises a hydrocyclone, a water sealed tank, an alkaline washing tower, a post-treatment tank and a tail gas fan. The tail gas inlet end of the hydrocyclone is connected with the fermentation tank through a gas phase pipe of the fermentation tank; the gas outlet at the top of the cyclone liquid separator is connected with a water seal tank through a gas outlet pipe of the cyclone liquid separator, the top of a water seal tank gas inlet distributor is connected with a gas outlet pipe of the cyclone liquid separator, the gas outlet at the top of the water seal tank is connected with an alkaline cleaning tower through a gas outlet pipe of the water seal tank, the top of the alkaline cleaning tower is provided with a centrifugal rotary spray head, the centrifugal rotary spray head is connected with a circulating pipeline of the alkaline cleaning tower, cooling pipes are arranged inside liquid tanks of the alkaline cleaning tower and the alkaline cleaning tower, the top of the alkaline cleaning tower is connected with a post-treatment tank through a gas outlet pipe of the alkaline cleaning tower, the top of the post-treatment tank is connected with a tail gas fan through a gas outlet pipe of the post-treatment tank, and the tail gas fan is connected with an exhaust pipe through a fan outlet pipe. The invention adopts a mode of combining physical absorption and chemical absorption, has simple process operation, low running cost and simple maintenance.

Description

发酵系统尾气处理装置Fermentation system tail gas treatment device

技术领域Technical Field

本发明涉及尾气处理,具体而言,涉及一种发酵系统尾气处理装置。The invention relates to tail gas treatment, and in particular to a tail gas treatment device for a fermentation system.

背景技术Background technique

生物发酵是微生物工业中最常用的一种反应体系,利用微生物或者各种酶的特异生物功能来生产相应的目标产物。生物发酵广泛应用于农业、食品、化学品、药品、新材料等领域。Bio-fermentation is the most commonly used reaction system in the microbial industry, which uses the specific biological functions of microorganisms or various enzymes to produce the corresponding target products. Bio-fermentation is widely used in agriculture, food, chemicals, medicines, new materials and other fields.

在发酵过程中,由于需要鼓入大量的无菌空气供微生物生长需要,大部分的空气无法被微生物吸收利用,通过尾气管道排出,在排出的过程中会夹杂一些有机原料、半成品或代谢产物,甚至有浓烈的刺激性气味排出,对环境造成了污染,对人体也会造成一定的危害。During the fermentation process, a large amount of sterile air needs to be blown in for the growth of microorganisms. Most of the air cannot be absorbed and utilized by the microorganisms and is discharged through the exhaust pipe. In the process of discharge, it will be mixed with some organic raw materials, semi-finished products or metabolites, and even strong irritating odors will be discharged, which pollutes the environment and causes certain harm to the human body.

发酵废气的成分比较复杂,主要包括曝气系统释放的空气、菌种的代谢产物、发酵过程中产生的酸性和碱性气体,多种有机物比如:丙酮、丁酯、丁醇、乙酸乙酯、苯、甲苯、二甲苯、甲醇、正丙醇、二氯甲烷、四氢呋喃类、醚类等。The composition of fermentation waste gas is relatively complex, mainly including air released by the aeration system, metabolic products of bacteria, acidic and alkaline gases produced during the fermentation process, and various organic substances such as: acetone, butyl esters, butanol, ethyl acetate, benzene, toluene, xylene, methanol, n-propanol, dichloromethane, tetrahydrofuran, ethers, etc.

目前大部分的处理方式存在处理效率不高,运行成本高的缺点。使用投资较高的膜分离技术和分子筛技术,虽然分离效率提高了,但设备投资大,膜组件等易耗材料需要频繁更换,不是一种经济的选择。发酵系统气相夹带的物料得不到有效的回收,不但加大了物料的浪费,而且还加大了污水量。净化效果较差,处理达标保证率不高,处理过程中的产生了废弃的吸收液或者固体废弃物,还需要进一步处理,造成二次污染。工艺操作复杂,运行费用高,易耗件易损件多,维护成本较高。发酵压力对微生物的生长及发酵反应至关重要,压力的波动会影响发酵的效率,当前发酵系统的压力稳定性较差,当发酵异常出现了雾沫夹带或者起泡等突发情况,可能会对现有的尾气系统造成负面的冲击,不利于尾气吸收系统的稳定运行。尾气吸收系统在长期运行后容易造成杂菌污染,噬菌体的繁殖等,和发酵系统的连接可能会加大发酵系统染菌概率,不利于反应系统的正常运行。无有效措施避免工艺物料和菌体伴随着曝气的尾气进入尾气洗涤系统,加重了后续尾气处理系统的负担。尾气吸收系统的能耗高,运行效率低,经济和持续性较差。设备设计不合理导致占地面积大,设备投资成本高。At present, most of the treatment methods have the disadvantages of low treatment efficiency and high operating costs. The use of membrane separation technology and molecular sieve technology with high investment has improved the separation efficiency, but the equipment investment is large, and consumable materials such as membrane components need to be replaced frequently, which is not an economical choice. The materials entrained in the gas phase of the fermentation system cannot be effectively recovered, which not only increases the waste of materials, but also increases the amount of sewage. The purification effect is poor, the guarantee rate of treatment compliance is not high, and the waste absorption liquid or solid waste generated during the treatment process needs further treatment, causing secondary pollution. The process operation is complicated, the operating cost is high, there are many consumable parts, and the maintenance cost is high. Fermentation pressure is crucial to the growth of microorganisms and fermentation reactions. Pressure fluctuations will affect the efficiency of fermentation. The pressure stability of the current fermentation system is poor. When fermentation is abnormal and sudden situations such as mist entrainment or bubbling occur, it may have a negative impact on the existing tail gas system, which is not conducive to the stable operation of the tail gas absorption system. After long-term operation, the tail gas absorption system is prone to bacterial contamination and the reproduction of bacteriophages. The connection with the fermentation system may increase the probability of bacterial contamination in the fermentation system, which is not conducive to the normal operation of the reaction system. There are no effective measures to prevent process materials and bacteria from entering the tail gas washing system along with the aerated tail gas, which increases the burden on the subsequent tail gas treatment system. The tail gas absorption system has high energy consumption, low operating efficiency, poor economy and sustainability. The unreasonable equipment design leads to a large footprint and high equipment investment cost.

发明内容Summary of the invention

本发明要解决的技术问题是提供一种发酵系统尾气处理装置,至少达到提高处理效率,降低运行成本的目的。The technical problem to be solved by the present invention is to provide a fermentation system tail gas treatment device, which at least achieves the purpose of improving the treatment efficiency and reducing the operating cost.

为解决以上以上技术问题,本发明采用的技术方案是:In order to solve the above technical problems, the technical solution adopted by the present invention is:

一种发酵系统尾气处理装置,包括:A fermentation system tail gas treatment device, comprising:

——旋液分离器,旋液分离器的尾气入口端通过发酵罐气相管连接发酵罐;旋液分离器顶部的出气口通过旋液分离器出气管连接水封罐,旋液分离器底部的排液口通过旋液分离器出液管连接至发酵罐;- Hydrocyclone separator, the tail gas inlet end of the hydrocyclone separator is connected to the fermentation tank through the fermentation tank gas phase pipe; the gas outlet at the top of the hydrocyclone separator is connected to the water seal tank through the hydrocyclone separator gas outlet pipe, and the liquid discharge port at the bottom of the hydrocyclone separator is connected to the fermentation tank through the hydrocyclone separator liquid outlet pipe;

——水封罐,水封罐内设置有水封罐进气分布器,水封罐进气分布器顶部连接旋液分离器出气管;水封罐中上部侧壁连接水封物料溢流管,水封物料溢流管末端连接至发酵罐;水封罐顶部的出气口通过水封罐出气管连接碱洗塔;水封罐顶部连接有用于向水封罐内输入无菌蒸馏水的无菌蒸馏水补水管;——Water seal tank, a water seal tank air inlet distributor is arranged in the water seal tank, the top of the water seal tank air inlet distributor is connected to the cyclone separator air outlet pipe; the upper side wall of the water seal tank is connected to the water seal material overflow pipe, and the end of the water seal material overflow pipe is connected to the fermentation tank; the air outlet at the top of the water seal tank is connected to the alkali washing tower through the water seal tank air outlet pipe; the top of the water seal tank is connected to a sterile distilled water replenishing pipe for inputting sterile distilled water into the water seal tank;

——碱洗塔,碱洗塔内顶部设置有离心式旋转喷头,碱洗塔底部具有碱洗塔接液罐,碱洗塔接液罐连接碱液出料管,离心式旋转喷头与碱洗塔循环管道相连接,碱液出料管和碱洗塔循环管道分别与碱洗塔循环泵进出料端口连接;碱洗塔接液罐上设置有用于输入碱液的碱洗塔碱液补充管,碱洗塔和碱洗塔接液罐内部设置有冷却管,冷却管一端连接用于输入冷却水的碱洗塔冷却水进水管,冷却管另一端连接碱洗塔冷却水出水管;碱洗塔接液罐中上部侧壁连接碱洗塔碱液溢流管,碱洗塔碱液溢流管末端连接至碱液接收罐,碱液接收罐通过管路连接至发酵罐;碱洗塔顶部通过碱洗塔出气管连接后处理罐;——Alkali washing tower, a centrifugal rotating nozzle is arranged on the top of the alkali washing tower, an alkali washing tower receiving tank is arranged at the bottom of the alkali washing tower, the alkali washing tower receiving tank is connected to the alkali liquid discharge pipe, the centrifugal rotating nozzle is connected to the alkali washing tower circulation pipeline, the alkali liquid discharge pipe and the alkali washing tower circulation pipeline are respectively connected to the inlet and outlet ports of the alkali washing tower circulation pump; an alkali washing tower alkali liquid replenishing pipe for inputting alkali liquid is arranged on the alkali washing tower receiving tank, a cooling pipe is arranged inside the alkali washing tower and the alkali washing tower receiving tank, one end of the cooling pipe is connected to the alkali washing tower cooling water inlet pipe for inputting cooling water, and the other end of the cooling pipe is connected to the alkali washing tower cooling water outlet pipe; the upper side wall of the alkali washing tower receiving tank is connected to the alkali washing tower alkali liquid overflow pipe, the end of the alkali washing tower alkali liquid overflow pipe is connected to the alkali liquid receiving tank, and the alkali liquid receiving tank is connected to the fermentation tank through a pipeline; the top of the alkali washing tower is connected to the post-processing tank through the alkali washing tower outlet pipe;

——后处理罐,后处理罐底部通过后处理罐液封管连接碱液出料管,后处理罐顶部通过后处理罐出气管连接尾气风机;——Post-processing tank, the bottom of the post-processing tank is connected to the alkali solution discharge pipe through the post-processing tank liquid sealing pipe, and the top of the post-processing tank is connected to the exhaust fan through the post-processing tank outlet pipe;

——尾气风机,尾气风机通过风机出口管连接排气筒。——Exhaust fan, the exhaust fan is connected to the exhaust pipe through the fan outlet pipe.

进一步地,发酵罐气相管上设置有发酵系统压力传感器和发酵罐气相控制阀。Furthermore, a fermentation system pressure sensor and a fermentation tank gas phase control valve are provided on the fermentation tank gas phase pipe.

进一步地,旋液分离器出液管上设置有旋液分离器出液管龙门弯,旋液分离器出液管龙门弯的底部连接有旋液分离器出液管排净阀。Furthermore, a cyclone separator liquid outlet pipe gantry bend is provided on the liquid outlet pipe of the cyclone separator, and a cyclone separator liquid outlet pipe drain valve is connected to the bottom of the cyclone separator liquid outlet pipe gantry bend.

进一步地,所述水封物料溢流管上设置有水封物料液封管,水封物料液封管上设置有液封段排净阀。Furthermore, a water seal material liquid seal pipe is provided on the water seal material overflow pipe, and a liquid seal section drain valve is provided on the water seal material liquid seal pipe.

进一步地,所述水封罐内设置有格栅填料层。Furthermore, a grid filler layer is provided in the water seal tank.

进一步地,所述碱洗塔上部安装有波纹板填料层,碱洗塔下部安装有矩鞍环散堆填料层。Furthermore, a corrugated plate packing layer is installed at the upper part of the alkali washing tower, and a rectangular saddle ring random packing layer is installed at the lower part of the alkali washing tower.

进一步地,所述后处理罐中上层设置有丝网结构层。Furthermore, a wire mesh structure layer is provided in the upper layer of the post-processing tank.

进一步地,包括灭菌系统,所述灭菌系统包括灭菌蒸汽源,灭菌蒸汽源分别通过管路与旋液分离器、水封罐、碱洗塔和碱液接收罐相连接。Furthermore, it comprises a sterilization system, wherein the sterilization system comprises a sterilization steam source, and the sterilization steam source is connected to the hydrocyclone separator, the water seal tank, the alkali washing tower and the alkali solution receiving tank through pipelines respectively.

本发明采用物理吸收和化学吸收相结合的方式,工艺操作简单,运行费用低,可控性强,净化效果好,达标保证率高,不产生二次污染,维护简单,可以有效应对发酵异常出现的雾沫夹带,起泡等突发情况,可以回收有用物质重回系统,避免浪费。The present invention adopts a combination of physical absorption and chemical absorption, and has simple process operation, low operating cost, strong controllability, good purification effect, high standard guarantee rate, no secondary pollution, simple maintenance, and can effectively deal with sudden situations such as mist entrainment and foaming caused by abnormal fermentation, and can recycle useful substances back into the system to avoid waste.

采用本发明可以保证工艺物料和菌体溶液重新回收到系统中参与反应,还可以保证进入尾气洗涤系统的尾气洁净,降低了后续处理的负担。The present invention can ensure that process materials and bacterial solution are recycled into the system to participate in the reaction, and can also ensure that the tail gas entering the tail gas washing system is clean, thereby reducing the burden of subsequent treatment.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

图1是本发明提供的发酵系统尾气处理装置的流程图。FIG1 is a flow chart of a fermentation system tail gas treatment device provided by the present invention.

图中,1-无菌空气曝气管、2-发酵罐、3-发酵罐气相管、4-旋液分离器、5-旋液分离器出气管、6-旋液分离器灭菌蒸汽管、7-旋液分离器出液管、8-旋液分离器出液管龙门弯、9-旋液分离器出液管排净阀、10-水封罐进气分布器、11-水封罐、12-格栅填料层、13-水封物料溢流管、14-水封物料液封管、15-液封段排净阀、16-水封罐灭菌蒸汽管、17-水封罐出气管、18-无菌蒸馏水补水管、19-碱洗塔灭菌蒸汽管、20-碱洗塔冷却水出水管、21-离心式旋转喷头、22-波纹板填料层、23-冷却管、24-矩鞍环散堆填料层、25-碱洗塔、26-碱洗塔接液罐、27-碱液出料管、28-碱洗塔循环泵、29-碱洗塔循环管道、30-后处理罐液封管、31-碱洗塔出气管、32-后处理罐、33-丝网结构层、34-后处理罐出气管、35-尾气风机、36-风机出口管、37-排气筒、38-碱洗塔碱液溢流管、39-碱洗塔冷却水进水管、40-碱洗塔碱液补充管、41-碱液接收罐、42-碱液接收罐灭菌蒸汽管、43-碱液回料管、44-碱液过滤器、45-发酵系统补碱泵、46-发酵系统补碱管、47-发酵系统压力传感器、48-发酵罐气相控制阀。In the figure, 1-sterile air aeration pipe, 2-fermentation tank, 3-fermentation tank gas phase pipe, 4-cyclone separator, 5-cyclone separator outlet pipe, 6-cyclone separator sterilization steam pipe, 7-cyclone separator outlet pipe, 8-cyclone separator outlet pipe gantry bend, 9-cyclone separator outlet pipe drain valve, 10-water seal tank air inlet distributor, 11-water seal tank, 12-grid packing layer, 13-water seal material overflow pipe, 14-water seal material liquid seal pipe, 15-liquid seal section drain valve, 16-water seal tank sterilization steam pipe, 17-water seal tank outlet pipe, 18-sterile distilled water replenishment pipe, 19-alkali washing tower sterilization steam pipe, 20-alkali washing tower cooling water outlet pipe, 21-centrifugal rotating nozzle, 22-corrugated plate packing layer, 23-cooling pipe, 24-rectangular saddle Annular random packing layer, 25-alkali washing tower, 26-alkali washing tower liquid receiving tank, 27-alkali liquid discharge pipe, 28-alkali washing tower circulation pump, 29-alkali washing tower circulation pipeline, 30-post-treatment tank liquid seal pipe, 31-alkali washing tower air outlet pipe, 32-post-treatment tank, 33-wire mesh structure layer, 34-post-treatment tank air outlet pipe, 35-exhaust fan, 36-fan outlet pipe, 37-exhaust pipe, 38-alkali liquid overflow pipe of alkali washing tower, 39-alkali washing tower cooling water inlet pipe, 40-alkali liquid replenishing pipe of alkali washing tower, 41-alkali liquid receiving tank, 42-alkali liquid receiving tank sterilization steam pipe, 43-alkali liquid return pipe, 44-alkali liquid filter, 45-fermentation system alkali replenishing pump, 46-fermentation system alkali replenishing pipe, 47-fermentation system pressure sensor, 48-fermentation tank gas phase control valve.

具体实施方式Detailed ways

本发明一种典型的实施方式提供的发酵系统尾气处理装置,如图1所示,主要由旋液分离器4、水封罐11、碱洗塔25、后处理罐32和尾气风机35组成。A typical embodiment of the present invention provides a fermentation system tail gas treatment device, as shown in FIG. 1 , which is mainly composed of a cyclone separator 4 , a water seal tank 11 , an alkali washing tower 25 , a post-treatment tank 32 and a tail gas fan 35 .

其中,旋液分离器4的尾气入口端通过发酵罐气相管3连接发酵罐2。旋液分离器4顶部的出气口通过旋液分离器出气管5连接水封罐11,旋液分离器4底部的排液口通过旋液分离器出液管7连接至发酵罐2。The tail gas inlet of the hydrocyclone 4 is connected to the fermenter 2 through the fermenter gas phase pipe 3. The gas outlet at the top of the hydrocyclone 4 is connected to the water seal tank 11 through the hydrocyclone gas outlet pipe 5, and the liquid discharge port at the bottom of the hydrocyclone 4 is connected to the fermenter 2 through the hydrocyclone liquid outlet pipe 7.

发酵罐2底部通过无菌空气曝气管1连接无菌空气源。本实施方式提供尾气处理装置的处理的对象为发酵系统发酵罐2产生的混合气体。The bottom of the fermentation tank 2 is connected to a sterile air source via a sterile air aeration pipe 1. The tail gas treatment device provided in this embodiment treats the mixed gas generated by the fermentation tank 2 of the fermentation system.

发酵罐2产生的混合气体,通过发酵罐气相管3进入旋液分离器4。 由于混合气体中可能会带少量的液态反应物和生成物,气液混合物进入旋液分离器4后,在旋液分离器4中形成旋转流场,液体的密度大,气体的密度小,在旋转流场中,密度大的向下部运行,密度小的向上部运行,即气体从旋液分离器4上部的出气口排出,液体从旋液分离器4下部的排液口回收到发酵罐2中,避免了液态物料的浪费,实现了气液的高效分离过程。The mixed gas produced by the fermentation tank 2 enters the hydrocyclone 4 through the fermentation tank gas phase pipe 3. Since the mixed gas may contain a small amount of liquid reactants and products, after the gas-liquid mixture enters the hydrocyclone 4, a rotating flow field is formed in the hydrocyclone 4. The density of the liquid is large and the density of the gas is small. In the rotating flow field, the high-density gas flows downward and the low-density gas flows upward, that is, the gas is discharged from the gas outlet at the top of the hydrocyclone 4, and the liquid is recovered from the liquid outlet at the bottom of the hydrocyclone 4 to the fermentation tank 2, thereby avoiding the waste of liquid materials and realizing an efficient gas-liquid separation process.

发酵罐气相管3上设置有发酵系统压力传感器47和发酵罐气相控制阀48。由于发酵罐2内对压力有一定的要求,通过发酵系统压力传感器47和发酵罐气相控制阀48的联锁控制作用,可以使得发酵罐2的压力稳定在设定的范围内,如:当发酵罐2内的实际压力值高于设定值时,发酵系统压力传感器47会给出信号传递到发酵罐气相控制阀48,阀门的开度会增大,以此来降低发酵罐2的压力到设定值;当发酵罐2内的实际压力值低于设定值时,发酵系统压力传感器47会给出信号传递到发酵罐气相控制阀48,阀门的开度会减小,以此来增加发酵罐2的压力到设定值。The fermentation tank gas phase pipe 3 is provided with a fermentation system pressure sensor 47 and a fermentation tank gas phase control valve 48. Since there are certain requirements for the pressure in the fermentation tank 2, the pressure of the fermentation tank 2 can be stabilized within a set range through the interlocking control of the fermentation system pressure sensor 47 and the fermentation tank gas phase control valve 48, such as: when the actual pressure value in the fermentation tank 2 is higher than the set value, the fermentation system pressure sensor 47 will give a signal to transmit to the fermentation tank gas phase control valve 48, and the valve opening will increase, thereby reducing the pressure of the fermentation tank 2 to the set value; when the actual pressure value in the fermentation tank 2 is lower than the set value, the fermentation system pressure sensor 47 will give a signal to transmit to the fermentation tank gas phase control valve 48, and the valve opening will decrease, thereby increasing the pressure of the fermentation tank 2 to the set value.

旋液分离器出液管7上设置有旋液分离器出液管龙门弯8,旋液分离器出液管龙门弯8的底部连接有旋液分离器出液管排净阀9。液体在回收管道上设置龙门形的旋液分离器出液管龙门弯8,目的是使得旋液分离器出液管7始终充满液柱,将发酵系统和旋液分离器4物理性隔离,也起到了稳定压力的作用。旋液分离器出液管排净阀9用于停产时的排净。The cyclone outlet pipe 7 is provided with a cyclone outlet pipe gantry bend 8, and the bottom of the cyclone outlet pipe gantry bend 8 is connected with a cyclone outlet pipe drain valve 9. The gantry-shaped cyclone outlet pipe gantry bend 8 is provided on the liquid recovery pipeline, so that the cyclone outlet pipe 7 is always filled with liquid column, the fermentation system and the cyclone 4 are physically isolated, and the pressure is stabilized. The cyclone outlet pipe drain valve 9 is used for draining when the production is stopped.

其中,水封罐11内设置有水封罐进气分布器10,水封罐进气分布器10顶部连接旋液分离器出气管5;水封罐11中上部侧壁连接水封物料溢流管13,水封物料溢流管13末端连接至发酵罐2。水封罐11顶部的出气口通过水封罐出气管17连接碱洗塔25。水封罐11顶部连接有用于向水封罐11内输入无菌蒸馏水的无菌蒸馏水补水管18。Among them, a water seal tank air inlet distributor 10 is arranged in the water seal tank 11, and the top of the water seal tank air inlet distributor 10 is connected to the cyclone separator outlet pipe 5; the upper side wall of the water seal tank 11 is connected to the water seal material overflow pipe 13, and the end of the water seal material overflow pipe 13 is connected to the fermentation tank 2. The air outlet at the top of the water seal tank 11 is connected to the alkali washing tower 25 through the water seal tank outlet pipe 17. The top of the water seal tank 11 is connected to a sterile distilled water replenishment pipe 18 for inputting sterile distilled water into the water seal tank 11.

经过旋液分离器4的分离,将大部分聚集态的液态分离了出来,但是气相中仍然夹带一些分子态的有机组分。分离出来的气相通过旋液分离器出气管5进入水封罐11,水封罐11中采用10-水封罐进气分布器进气,使得进气能够分布均匀,采用无菌蒸馏水作为水封罐内的吸收介质。在水封罐中,有机态的分子会被水捕集下来,慢慢漂浮在液面上,这时就通过水封物料溢流管13溢流到了发酵系统内,实现了有机成分的有效回收利用。After separation by the hydrocyclone 4, most of the aggregated liquid is separated out, but some molecular organic components are still entrained in the gas phase. The separated gas phase enters the water seal tank 11 through the hydrocyclone outlet pipe 5. The water seal tank 11 adopts a 10-water seal tank air inlet distributor to inlet air, so that the air can be evenly distributed, and sterile distilled water is used as the absorption medium in the water seal tank. In the water seal tank, organic molecules will be captured by water and slowly float on the liquid surface. At this time, they overflow into the fermentation system through the water seal material overflow pipe 13, realizing the effective recycling of organic components.

在水封罐11的中部设置有规整格栅填料层12,利用其压降较小的优点,可以使得气相和液相充分接触的前提下不影响气相的释放。A regular grid packing layer 12 is arranged in the middle of the water seal tank 11. By taking advantage of its small pressure drop, the gas phase and the liquid phase can be fully contacted without affecting the release of the gas phase.

此外,为了避免气相的紊乱,在水封物料溢流管13上设计有水封物料液封管14,从而将水封罐11和发酵罐进行了物理隔离,起到了稳定压力的作用,水封物料液封管14上设置有液封段排净阀。In addition, in order to avoid gas phase turbulence, a water seal material liquid seal pipe 14 is designed on the water seal material overflow pipe 13, thereby physically isolating the water seal tank 11 and the fermentation tank, thereby stabilizing the pressure. A liquid seal section drain valve is provided on the water seal material liquid seal pipe 14.

其中,碱洗塔25内顶部设置有离心式旋转喷头21,碱洗塔25底部具有碱洗塔接液罐26,碱洗塔接液罐26连接碱液出料管27,离心式旋转喷头21与碱洗塔循环管道29相连接,碱液出料管27和碱洗塔循环管道29分别与碱洗塔循环泵28的进出料端口连接。碱洗塔接液罐26上设置有用于输入碱液的碱洗塔碱液补充管40,碱洗塔25和碱洗塔接液罐26内部设置有冷却管23,冷却管23一端连接用于输入冷却水的碱洗塔冷却水进水管39,冷却管23另一端连接碱洗塔冷却水出水管2。碱洗塔接液罐26中上部侧壁连接碱洗塔碱液溢流管38,碱洗塔碱液溢流管38末端连接至碱液接收罐41,碱液接收罐41通过管路连接至发酵罐2;碱洗塔25顶部通过碱洗塔出气管31连接后处理罐32。Among them, a centrifugal rotating nozzle 21 is arranged at the top of the alkali washing tower 25, and an alkali washing tower receiving tank 26 is arranged at the bottom of the alkali washing tower 25. The alkali washing tower receiving tank 26 is connected to the alkali liquid discharge pipe 27, and the centrifugal rotating nozzle 21 is connected to the alkali washing tower circulation pipeline 29. The alkali liquid discharge pipe 27 and the alkali washing tower circulation pipeline 29 are respectively connected to the inlet and outlet ports of the alkali washing tower circulation pump 28. An alkali washing tower alkali liquid replenishing pipe 40 for inputting alkali liquid is arranged on the alkali washing tower receiving tank 26, and a cooling pipe 23 is arranged inside the alkali washing tower 25 and the alkali washing tower receiving tank 26. One end of the cooling pipe 23 is connected to the alkali washing tower cooling water inlet pipe 39 for inputting cooling water, and the other end of the cooling pipe 23 is connected to the alkali washing tower cooling water outlet pipe 2. The upper side wall of the alkali washing tower liquid receiving tank 26 is connected to the alkali washing tower alkali liquid overflow pipe 38, the end of the alkali washing tower alkali liquid overflow pipe 38 is connected to the alkali liquid receiving tank 41, and the alkali liquid receiving tank 41 is connected to the fermentation tank 2 through a pipeline; the top of the alkali washing tower 25 is connected to the post-treatment tank 32 through the alkali washing tower outlet pipe 31.

经过水封罐11的气相通过水封罐出气管17进入碱洗塔25,通过液碱将最终尾气中的杂质彻底清洗干净。碱洗吸收液来自碱洗塔碱液补充管40,贮存在碱洗塔25底部的26-碱洗塔接液罐26。碱洗塔25和碱洗塔接液罐26为一体化设计,能够极大地节省了占地面积,也节约了设备投资。通过碱洗塔循环泵28将碱洗塔接液罐26中的液碱泵送到塔顶,通过碱洗塔循环管道29和离心式旋转喷头21将液碱从塔顶喷淋而下,喷头的作用是加强液相的初始分布。气相通过碱洗塔25的底部进入,气相和液相通过逆流接触的方式,实现了尾气洗涤彻底的目的。碱洗塔25在运行一段时间后会产生温升,通过冷却管23的冷却作用,将热量带走,保证碱液在低温下具有更强的吸收效果。采用蛇形环绕冷却管,冷却管23除了有冷却的功能外,还起到了扰动水流和气流的作用,避免短流现象,一定程度上增强了吸收效果。The gas phase passing through the water seal tank 11 enters the alkali washing tower 25 through the water seal tank outlet pipe 17, and the impurities in the final tail gas are thoroughly cleaned by liquid alkali. The alkali washing absorption liquid comes from the alkali washing tower alkali liquid replenishing pipe 40 and is stored in the alkali washing tower 26 at the bottom of the alkali washing tower 25. The alkali washing tower 25 and the alkali washing tower liquid receiving tank 26 are integrated designs, which can greatly save floor space and equipment investment. The liquid alkali in the alkali washing tower liquid receiving tank 26 is pumped to the top of the tower by the alkali washing tower circulating pump 28, and the liquid alkali is sprayed down from the top of the tower by the alkali washing tower circulating pipeline 29 and the centrifugal rotating nozzle 21. The function of the nozzle is to strengthen the initial distribution of the liquid phase. The gas phase enters through the bottom of the alkali washing tower 25, and the gas phase and the liquid phase are contacted in a countercurrent manner, so as to achieve the purpose of thorough tail gas washing. The alkali washing tower 25 will produce a temperature rise after running for a period of time, and the heat is taken away by the cooling effect of the cooling pipe 23, so as to ensure that the alkali solution has a stronger absorption effect at low temperatures. The serpentine cooling pipe 23 not only has the cooling function, but also plays the role of disturbing the water flow and air flow to avoid short-flow phenomenon, thereby enhancing the absorption effect to a certain extent.

所述碱洗塔25上部安装有波纹板填料层22,结构简单,更有利于碱液的分布和气流的分散。碱洗塔25下部安装有矩鞍环散堆填料层24,该填料层拥有极强的耐腐蚀性和优良的耐热性,其在结构上的优点是阻力小、通量大、填料强度和刚度好,有利于液体分布,增加气体通道。鞍形两侧的翻边和两端下部的齿形结构共同增加了填料之间的比表面积,孔隙率高的结构使得填料的通量增大,压降降低,极大地改善了传质性能。The alkali washing tower 25 is provided with a corrugated plate packing layer 22 on the top, which has a simple structure and is more conducive to the distribution of alkali solution and the dispersion of airflow. The alkali washing tower 25 is provided with a rectangular saddle ring random packing layer 24 on the bottom, which has extremely strong corrosion resistance and excellent heat resistance. Its structural advantages are small resistance, large flux, good packing strength and rigidity, which is conducive to liquid distribution and increases gas channels. The flanges on both sides of the saddle and the toothed structure at the bottom of both ends jointly increase the specific surface area between the packings. The high porosity structure increases the flux of the packing and reduces the pressure drop, which greatly improves the mass transfer performance.

由于在发酵过程中的酸度会降低,为了维持发酵过程中的pH,需要额外补充一定量的液碱。此时可以利用尾气吸收后的液碱作为这部分液碱的补充。碱洗塔25的碱液通过碱洗塔碱液溢流管38流入碱液接收罐41作为缓冲,再通过碱液料回管43、碱液过滤器44、发酵系统补碱泵45和发酵系统补碱管46输送到发酵罐2中,补充量根据发酵罐2内液体的pH要求来控制。碱液作为发酵系统调节pH用,实现闭路循环,不产生额外的废碱液,不增加污水处理的负荷。Since the acidity during the fermentation process decreases, in order to maintain the pH during the fermentation process, a certain amount of liquid alkali needs to be supplemented. At this time, the liquid alkali after tail gas absorption can be used as a supplement for this part of the liquid alkali. The alkali solution of the alkali washing tower 25 flows into the alkali solution receiving tank 41 through the alkali washing tower alkali solution overflow pipe 38 as a buffer, and then is transported to the fermentation tank 2 through the alkali solution material return pipe 43, the alkali solution filter 44, the fermentation system alkali supplementation pump 45 and the fermentation system alkali supplementation pipe 46. The supplementary amount is controlled according to the pH requirement of the liquid in the fermentation tank 2. The alkali solution is used as a fermentation system to adjust the pH, realize closed-loop circulation, do not produce additional waste alkali solution, and do not increase the load of sewage treatment.

其中,后处理罐32底部通过后处理罐液封管30连接碱液出料管27,后处理罐32顶部通过后处理罐出气管34连接尾气风机35。尾气风机35通过风机出口管36连接排气筒37。The bottom of the post-processing tank 32 is connected to the alkali solution discharge pipe 27 through the post-processing tank liquid sealing pipe 30, and the top of the post-processing tank 32 is connected to the exhaust fan 35 through the post-processing tank outlet pipe 34. The exhaust fan 35 is connected to the exhaust pipe 37 through the fan outlet pipe 36.

经过洗涤后的气相通过碱洗塔出气管31进入后处理罐32干燥,经过干燥后的洁净气体通过34-后处理罐出气管进入35-尾气风机,再通过36-风机出口管直接连接到37-排气筒,即处理达标后的尾气排向大气。The washed gas phase enters the post-treatment tank 32 for drying through the alkali washing tower outlet pipe 31. The dried clean gas enters the tail gas fan 35 through the post-treatment tank outlet pipe 34, and then is directly connected to the exhaust pipe 37 through the fan outlet pipe 36, that is, the tail gas that meets the treatment standards is discharged to the atmosphere.

在后处理罐32的中上部设计有33-丝网结构层,目的是将尾气中的水分截留下来,起到了干燥的作用,截留下来的水分会通过30-后处理罐液封管重新回到系统中。A wire mesh structure layer 33 is designed in the middle and upper part of the post-processing tank 32, the purpose of which is to intercept the moisture in the exhaust gas and play a drying role. The intercepted moisture will return to the system through the post-processing tank liquid seal pipe 30.

本实施方式中,灭菌系统包括灭菌蒸汽源,灭菌蒸汽源分别通过旋液分离器灭菌蒸汽管6连接旋液分离器4,通过水封罐灭菌蒸汽管16连接水封罐11,通过碱洗塔灭菌蒸汽管19连接碱洗塔25,通过碱液接收罐灭菌蒸汽管42连接碱液接收罐41。利用灭菌系统可以避免噬菌体的产生和杂菌的污染,保证整个尾气吸收处理系统在无菌环境下操作。In this embodiment, the sterilization system includes a sterilization steam source, which is connected to the hydrocyclone 4 through the hydrocyclone sterilization steam pipe 6, connected to the water seal tank 11 through the water seal tank sterilization steam pipe 16, connected to the alkali wash tower 25 through the alkali wash tower sterilization steam pipe 19, and connected to the alkali liquid receiving tank 41 through the alkali liquid receiving tank sterilization steam pipe 42. The sterilization system can avoid the generation of bacteriophages and contamination by miscellaneous bacteria, ensuring that the entire tail gas absorption treatment system operates in a sterile environment.

Claims (8)

1. A fermentation system tail gas treatment device, characterized by comprising:
The tail gas inlet end of the hydrocyclone is connected with the fermentation tank through a gas phase pipe of the fermentation tank; the gas outlet at the top of the hydrocyclone is connected with a water sealed tank through a gas outlet pipe of the hydrocyclone, and the liquid outlet at the bottom of the hydrocyclone is connected with a fermentation tank through a liquid outlet pipe of the hydrocyclone;
The water-sealed tank is internally provided with a water-sealed tank air inlet distributor, and the top of the water-sealed tank air inlet distributor is connected with an air outlet pipe of the cyclone liquid separator; the side wall of the middle upper part of the water sealed tank is connected with a water sealed material overflow pipe, and the tail end of the water sealed material overflow pipe is connected to the fermentation tank; the air outlet at the top of the water-sealed tank is connected with the alkaline washing tower through an air outlet pipe of the water-sealed tank; the top of the water sealed tank is connected with a sterile distilled water supplementing pipe for inputting sterile distilled water into the water sealed tank;
The top in the alkaline washing tower is provided with a centrifugal rotary spray head, the bottom of the alkaline washing tower is provided with an alkaline washing tower liquid receiving tank which is connected with an alkaline liquid discharging pipe, the centrifugal rotary spray head is connected with an alkaline washing tower circulating pipeline, and the alkaline liquid discharging pipe and the alkaline washing tower circulating pipeline are respectively connected with an alkaline washing tower circulating pump inlet and outlet port; an alkaline tower alkaline liquor replenishing pipe for inputting alkaline liquor is arranged on the alkaline tower liquid receiving tank, cooling pipes are arranged in the alkaline tower and the alkaline tower liquid receiving tank, one end of each cooling pipe is connected with an alkaline tower cooling water inlet pipe for inputting cooling water, and the other end of each cooling pipe is connected with an alkaline tower cooling water outlet pipe; the side wall of the upper part of the liquid receiving tank of the alkaline washing tower is connected with an alkaline liquid overflow pipe of the alkaline washing tower, the tail end of the alkaline liquid overflow pipe of the alkaline washing tower is connected to an alkaline liquid receiving tank, and the alkaline liquid receiving tank is connected to a fermentation tank through a pipeline; the top of the alkaline washing tower is connected with a post-treatment tank through an air outlet pipe of the alkaline washing tower;
the bottom of the post-treatment tank is connected with an alkali liquor discharging pipe through a post-treatment tank liquid sealing pipe, and the top of the post-treatment tank is connected with a tail gas fan through a post-treatment tank gas outlet pipe;
the tail gas fan is connected with the exhaust funnel through a fan outlet pipe.
2. The tail gas treatment device for a fermentation system of claim 1, wherein: the fermentation tank gas phase pipe is provided with a fermentation system pressure sensor and a fermentation tank gas phase control valve.
3. The tail gas treatment device for a fermentation system according to claim 1 or 2, characterized in that: the liquid outlet pipe of the hydrocyclone is provided with a liquid outlet pipe gantry bend of the hydrocyclone, and the bottom of the liquid outlet pipe gantry bend of the hydrocyclone is connected with a liquid outlet pipe drain valve of the hydrocyclone.
4. A tail gas treatment device for a fermentation system according to claim 3, wherein: the water seal material overflow pipe is provided with a water seal material liquid seal pipe, and the water seal material liquid seal pipe is provided with a liquid seal section exhaust valve.
5. The tail gas treatment device for a fermentation system of claim 4, wherein: and a grid packing layer is arranged in the water sealed tank.
6. The tail gas treatment device for a fermentation system according to claim 1 or 5, wherein: the upper part of the alkaline washing tower is provided with a corrugated plate packing layer, and the lower part of the alkaline washing tower is provided with a saddle ring scattered packing layer.
7. The tail gas treatment device for a fermentation system of claim 6, wherein: the upper layer of the post-treatment tank is provided with a silk screen structure layer.
8. The tail gas treatment device for a fermentation system according to claim 1 or 7, wherein: the device comprises a sterilization system, wherein the sterilization system comprises a sterilization steam source, and the sterilization steam source is respectively connected with a hydrocyclone, a water sealed tank, an alkaline washing tower and an alkaline liquid receiving tank through pipelines.
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