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CN117957207A - Cement plastic mixture - Google Patents

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Publication number
CN117957207A
CN117957207A CN202280041018.9A CN202280041018A CN117957207A CN 117957207 A CN117957207 A CN 117957207A CN 202280041018 A CN202280041018 A CN 202280041018A CN 117957207 A CN117957207 A CN 117957207A
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weight
cement
mixture
plastic
plastic mixture
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纳吉·奥托
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Terratico Ltd
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Terratico Ltd
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Priority claimed from PCT/SK2022/000004 external-priority patent/WO2022260605A1/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The cement plastic mixture contains 29 to 43% by weight of plastic particles, 56 to 69% by weight of cement and 1.0 to 2.0% by weight of superplasticizer, and 6.0 to 12% by weight of sand of the order 0.3 to 2.0mm and 4.0 to 14.0% by weight of water.

Description

水泥塑料混合物Cement plastic mixture

技术领域Technical Field

本发明涉及可用于生产建筑和石材产品的水泥塑料混合物。本发明属于建筑和石制品的领域。The present invention relates to a cement-plastic mixture which can be used to produce building and stone products. The present invention belongs to the field of building and stone products.

背景技术Background technique

目前,基于水泥、硅砂和硅石、花岗岩或大理石的产品,例如水磨石,是建筑和石制品领域中公知的。水磨石是一种复合材料,现场浇筑或预制,用于地面和墙面处理。它包括大理石、石英、花岗岩、玻璃或其他合适材料的碎片,用水泥粘合剂(用于化学粘合)、聚合物(用于物理粘合)或两者的组合浇筑。Currently, products based on cement, silica sand and silica, granite or marble, such as terrazzo, are well known in the field of construction and stone products. Terrazzo is a composite material, cast on site or prefabricated, used for floor and wall treatment. It consists of chips of marble, quartz, granite, glass or other suitable materials, cast with a cement binder (for chemical bonding), a polymer (for physical bonding) or a combination of both.

文献RU2739910C1是现有技术中已知的,其描述了含有波特兰水泥、聚合物粘合剂、砂、玻璃纤维和改性剂的聚合物-水泥干式建筑混合物。聚合物粘合剂是可再分散的聚乙酸乙烯酯聚合物粉末或聚乙酸乙烯酯共聚物。Document RU 2739910 C1 is known from the prior art and describes a polymer-cement dry building mix containing Portland cement, a polymer binder, sand, glass fibers and a modifier. The polymer binder is a redispersible polyvinyl acetate polymer powder or a polyvinyl acetate copolymer.

双组分快速固化塑性水泥根据文献CN112063160A也是已知的,其中第一组分是聚醚多元醇、固化剂、表面羟基改性石蜡、增稠剂和固体填料。第二组分是聚醚多元醇、催化剂、交联剂、表面羟基改性石蜡、增稠剂和固体填料。具有特定羟基的石蜡引入到这些双组分中。Two-component fast-curing plastic cement is also known from document CN112063160A, wherein the first component is polyether polyol, curing agent, surface hydroxyl-modified paraffin, thickener and solid filler. The second component is polyether polyol, catalyst, crosslinking agent, surface hydroxyl-modified paraffin, thickener and solid filler. Paraffin with specific hydroxyl groups is introduced into these two components.

还存在将丙烯酸酯橡胶沥青混入到水泥中的趋势,如与申请SK1692U一样的情况,以降低体密度,提高隔热性能并且确保不透水性。There is also a trend to mix acrylate rubber asphalt into cement, as in the case of application SK1692U, in order to reduce the bulk density, improve the thermal insulation properties and ensure impermeability.

包含水泥和纸浆的建筑混合物也是已知的,如申请SK4239U中所述,其节省了生产成本并且减轻了产品重量。Building mixes comprising cement and paper pulp are also known, as described in application SK 4239 U, which save production costs and reduce the weight of the product.

水泥混合物的问题尚未被完全探索,目前已引起设计同样允许塑料废物的生态使用和消耗的这样一种水泥混合物组成。这一努力的成果即是本发明描述的水泥塑料混合物。The problem of cement mixtures has not been fully explored and has now led to the design of such a cement mixture composition that also allows for the ecological use and consumption of plastic waste. The result of this effort is the cement plastic mixture described in the present invention.

发明内容Summary of the invention

水泥混合物的上述问题通过本发明提出的干式或湿式的水泥塑料混合物得以解决。技术方案的本质在于这样的事实:依据组成,干式混合物含有三种基础组分。它是一种含有压碎塑料的混合物,优选不能再循环利用的塑料。可以使用等级为1mm至20mm或甚至更高等级的所有类型的塑料,或切碎的塑料条,塑料颗粒除外。也可以是水泥,优选强度为32.5MPa至52.5MPa的波特兰灰或白。The above-mentioned problems of cement mixtures are solved by the dry or wet cement-plastic mixture proposed by the invention. The essence of the technical solution lies in the fact that the dry mixture contains three basic components according to the composition. It is a mixture containing crushed plastic, preferably non-recyclable plastic. All types of plastics with a grade of 1 mm to 20 mm or even higher can be used, or chopped plastic strips, except plastic granules. It can also be cement, preferably Portland grey or white with a strength of 32.5 MPa to 52.5 MPa.

波特兰灰和波特兰白代表水泥的历史名称,其可用作水硬性粘合剂的同义词。Portland grey and Portland white represent historical names for cement, which may be used as synonyms for hydraulic binders.

最后,它可以是超塑化剂,优选超塑化剂的密度为10/40(超塑化剂的40%)。根据本发明,所述超塑化剂可基于或可包括或可制成自三聚氰胺甲醛,和或可满足EN 934-22019+A1:2012标准和/或可满足EN 934-2+A1标准。这种干式水泥塑料混合物可包装在例如纸袋中,并且在使用时,它优选地可仅与水混合。依据消费者的需要,可向这三种基础组分中添加额外组分,例如优选具有等级为0.3mm至2.0mm的硅砂,和/或固化促进剂,例如Betodur A5,因此无氯混凝土和/或合成纤维,例如ARC 42/30mm,即耐碱(AR)玻璃纤维,其可专门设计用于混凝土和/或粉末涂料,例如以干式彩色颜料粉末的形式用于混凝土。如果是在使用或生产的场所混合的湿式水泥塑料混合物,水也可被视为额外组分。Finally, it may be a superplasticizer, preferably with a density of 10/40 (40% of superplasticizer). According to the invention, the superplasticizer may be based on or may include or may be made from melamine formaldehyde, and or may meet the EN 934-22019+A1:2012 standard and/or may meet the EN 934-2+A1 standard. This dry cement plastic mixture may be packaged, for example, in paper bags, and at the time of use, it may preferably be mixed with water only. Depending on the needs of the consumer, additional components may be added to these three basic components, such as silica sand, preferably with a grade of 0.3 mm to 2.0 mm, and/or a curing accelerator, such as Betodur A5, thus chlorine-free concrete and/or synthetic fibers, such as ARC 42/30 mm, i.e. alkali-resistant (AR) glass fibers, which may be specially designed for concrete and/or powder coatings, for example in the form of dry color pigment powders for concrete. In case of a wet cement plastic mixture mixed at the site of use or production, water may also be considered as an additional component.

本发明的本质通过水泥塑料混合物的各个组分的组成加以体现。根据优选实施方案,基础组分中的水泥塑料混合物包含:The essence of the present invention is embodied by the composition of each component of cement plastic mixture. According to a preferred embodiment, the cement plastic mixture in the base component comprises:

重量的29%至重量的43%的塑料碎料,29% by weight to 43% by weight of plastic scraps,

重量的56%至重量的69%的水泥,56% by weight to 69% by weight of cement,

重量的1.0%至重量的2.0%的超塑化剂,合计为100%并且表示基础混合物。1.0% by weight to 2.0% by weight of superplasticizer, totaling 100% and representing the base mixture.

此外,向基础混合物的重量中可添加至少一种额外成分,该额外成分包含以下或由以下组成:Furthermore, at least one additional ingredient may be added to the weight of the base mixture, the additional ingredient comprising or consisting of:

重量的6.0%至重量的12%的硅砂,和/或6.0% by weight to 12% by weight of silica sand, and/or

重量的0.4%至重量的0.9%的固化促进剂,和/或0.4% to 0.9% by weight of a curing accelerator, and/or

重量的0.04%至重量的0.07%的ARC合成纤维,和/或0.04% to 0.07% by weight of ARC synthetic fibers, and/or

重量的0.02%至重量的0.08%的涂料,和/或0.02% to 0.08% by weight of the coating, and/or

重量的4.0%至重量的14.0%的水,和/或4.0% by weight to 14.0% by weight of water, and/or

水泥重量的重量的4.0%至重量的10%的硅灰(微硅粉)SiO2Silica fume (microsilica powder) SiO 2 4.0% by weight to 10% by weight of cement.

根据本发明的额外成分的重量的百分比是指除了基础混合物的重量之外的百分比,使得最终产品具有Y个重量单位(例如,千克)的基础混合物+例如6%附加重量的额外成分,根据该示例合计为基础混合物质量Y*1.06的总质量。The percentage by weight of the additional ingredient according to the invention refers to the percentage in addition to the weight of the basic mixture, so that the final product has Y weight units (e.g., kilograms) of basic mixture + for example 6% additional weight of additional ingredients, which according to this example totals a total mass of the base mixture mass Y*1.06.

因此,额外成分的重量百分比在基础混合物的质量之外,并且计算为在不含额外成分的基础混合物为100%的情况下在上述示例中导致总的最终产品(水泥塑料混合物)质量为相对于基础混合物的质量的106%。Therefore, the weight percentage of the additional ingredients is in addition to the mass of the base mix and is calculated as 100% of the base mix without the additional ingredients resulting in a total final product (cementitious plastic mix) mass of 106% relative to the mass of the base mix in the above example.

根据本发明的水泥塑料混合物的优点从其外部效果可以看出。效果和独创性在于其独特的组成,其中水泥塑料混合物的目标是通过使用廉价的投入原材料-塑料废物以及减少所得产品的重量来节省成本。不可否认的益处是,包含该水泥塑料混合物的砂浆看起来像水磨石。The advantages of the cement plastic mixture according to the present invention can be seen from its external effects. The effect and originality lie in its unique composition, where the cement plastic mixture aims to save costs by using cheap input raw materials - plastic waste and reducing the weight of the resulting product. The undeniable benefit is that the mortar containing this cement plastic mixture looks like terrazzo.

水磨石是一种复合材料,现场浇筑或预制,用于地面和墙面处理。它包括大理石、石英、花岗岩、玻璃或其他合适材料的碎片,用水泥粘合剂(用于化学粘合)、聚合物(用于物理粘合)或两者的组合进行浇筑。Terrazzo is a composite material, cast on site or precast, used for floor and wall treatments. It consists of chips of marble, quartz, granite, glass or other suitable material, cast with a cement binder (for chemical bonding), a polymer (for physical bonding), or a combination of both.

该效果是通过用塑料废弃碎料代替大理石碎料来实现的,这降低了上至80%的成本。根据本发明的水泥塑料混合物制成的产品留下更低的碳足迹,同时解决了最难之一的回收塑料废物的问题。即使是几十年前老旧的降解塑料,即使暴露在阳光下,也可以用这种方式进行处理。添加塑料碎料可能会使产品具有表面结构马赛克和/或添加合成纤维可能会使产品具有柔韧性以防止开裂。添加硅砂可能会增加产品的刚度。This effect is achieved by replacing marble chips with plastic waste chips, which reduces costs by up to 80%. Products made from cement plastic mixtures according to the invention leave a lower carbon footprint while solving one of the most difficult problems of recycling plastic waste. Even old degraded plastics from decades ago, even if exposed to sunlight, can be processed in this way. Adding plastic chips may give the product a surface structure mosaic and/or adding synthetic fibers may give the product flexibility to prevent cracking. Adding silica sand may increase the rigidity of the product.

根据基于本发明的该水泥塑料混合物,可以生产庭院家具,例如长凳、花盆、垃圾篮、桌子、大幅面铺料、立面元件和铸造预制件,其可被切割、打磨、喷砂、浸渍,并且采用切割或非切割技术进行类似机器加工。According to the cement-plastic mixture according to the invention, it is possible to produce garden furniture, such as benches, flower pots, waste baskets, tables, large-format paving materials, facade elements and cast prefabricated parts, which can be cut, ground, sandblasted, impregnated and similarly machined using cutting or non-cutting techniques.

具体实施方式Detailed ways

应当理解,根据本发明的水泥塑料混合物的各个实施方案是为了说明而不是作为解决方案的限制而呈现的。本领域技术人员仅使用常规实验就会发现或者能够确定根据本发明的水泥塑料混合物的特定实施例的许多等同物。这些等同物也将落入权利要求的范围内。It should be understood that the various embodiments of cement plastic mixture according to the present invention are presented for illustration rather than as a limitation of the solution. Those skilled in the art will find or be able to determine many equivalents of the specific embodiments of cement plastic mixture according to the present invention using only routine experiments. These equivalents will also fall within the scope of the claims.

对于本领域技术人员来说,将水泥塑料混合物的各个组分进行最佳混合不是问题,因此没有详细描述这些特征。For a person skilled in the art, optimal mixing of the individual components of the cement-plastic mixture is not a problem, so these features are not described in detail.

示例1Example 1

在本发明的特定实施例的该示例中,也就是描述了水泥塑料混合物或干式标准水泥-塑料混合物,优选用于具有通过研磨的表面抛光的产品,优选包装在纸袋中,主要旨在用于小型消费者。干基水泥塑料混合物(基础混合物)包含:In this example of a particular embodiment of the invention, a cement-plastic mixture or dry standard cement-plastic mixture is described, preferably for products with a surface finish by grinding, preferably packaged in paper bags, mainly intended for small consumers. The dry cement-plastic mixture (base mixture) comprises:

19kg的塑料碎料,占重量的42.7%,19kg of plastic scraps, accounting for 42.7% of the weight,

25kg的灰水泥42.5(或者灰水泥52.5),占重量的56.1%,25kg of grey cement 42.5 (or grey cement 52.5), accounting for 56.1% of the weight,

0.5kg的超塑化剂10/40(密度),占重量的1.2%。0.5 kg of superplasticizer 10/40 (density), accounting for 1.2% of the weight.

示例2Example 2

在本发明的特定实施例的该示例中,也就是描述了水泥塑料混合物或干式标准水泥-塑料混合物,优选用于具有砂磨/研磨抛光、包装在纸袋中的产品,主要旨在用于小型消费者。干基水泥塑料混合物(基础混合物)包含:In this example of a particular embodiment of the invention, a cement-plastic mixture or dry standard cement-plastic mixture is described, preferably for products with a sanded/ground finish, packaged in paper bags, mainly intended for small consumers. The dry cement-plastic mixture (base mixture) comprises:

19kg的塑料碎料,占重量的42.7%,19kg of plastic scraps, accounting for 42.7% of the weight,

25kg的灰水泥42.5(或者白水泥52.5),占重量的56.1%,25kg of grey cement 42.5 (or white cement 52.5), accounting for 56.1% of the weight,

0.5kg的超塑化剂,占重量的1.2%。0.5 kg of superplasticizer, accounting for 1.2% of the weight.

这三种基础组分占基础混合物的重量的100%,可向其中添加至少一种下列添加剂:These three basic components account for 100% by weight of the basic mixture, to which at least one of the following additives may be added:

3kg的硅砂,等级0.8mm,占重量的6.7%,和/或3kg of silica sand, grade 0.8mm, accounting for 6.7% by weight, and/or

0.2kg的固化促进剂Betodur A5,占重量的0.47%,和/或0.2 kg of curing accelerator Betodur A5, 0.47% by weight, and/or

0.022kg的ARC合成纤维42/30,占重量的0.05%,和/或0.022kg of ARC synthetic fiber 42/30, 0.05% by weight, and/or

0.004kg的涂料,占重量的0.01%。0.004kg of paint, 0.01% by weight.

因此,涂料(如果期望不同的颜色)(可选)和/或固化促进剂(例如,铸造模具的形状需要较少的液态最终混合物)(可选)和/或合成纤维(如果最终产品需要更高的抗机械损伤性)(可选)和/或硅砂。Thus, coating (if a different color is desired) (optional) and/or curing accelerator (e.g. the shape of the casting mold requires less liquid final mixture) (optional) and/or synthetic fibers (if the final product requires higher resistance to mechanical damage) (optional) and/or silica sand.

示例3Example 3

在本发明的特定实施例的该示例中,描述了湿基和标准水泥塑料混合物,即湿式水泥塑料混合物,优选用于具有砂磨/研磨抛光的产品。基础是示例1和2中描述的干式混合物,进一步补充有5升水,其在干式基础混合物质量之外占11.2%的额外重量。In this example of a particular embodiment of the invention, a wet base and a standard cement plastic mix, i.e. a wet cement plastic mix, preferably for a product with a sanded/ground finish, is described. The base is the dry mix described in Examples 1 and 2, further supplemented with 5 liters of water, which accounts for 11.2% additional weight over the mass of the dry base mix.

示例4Example 4

在本发明的特定实施例的该示例中,也就是描述了水泥塑料混合物干基水泥塑料混合物(基础混合物),用于优选包装在纸袋中的未研磨产品,尤其旨在用于小型消费者。所述干基水泥塑料混合物包含:In this example of a particular embodiment of the invention, a cement-plastic mixture dry cement-plastic mixture (base mixture) is described for unground products preferably packaged in paper bags, especially intended for small consumers. The dry cement-plastic mixture comprises:

16kg的塑料碎料,占重量的38%,16kg of plastic scraps, accounting for 38% of the weight,

25kg的灰水泥42.5(或者灰水泥52.5),占重量的60.1%,25kg of grey cement 42.5 (or grey cement 52.5), accounting for 60.1% of the weight,

0.8kg的超塑化剂Melment 20/40,占重量的1.9%。0.8 kg of superplasticizer Melment 20/40, accounting for 1.9% of the weight.

示例5Example 5

在本发明的特定实施例的该示例中,也就是描述了水泥塑料混合物、干基水泥塑料混合物,用于优选包装在纸袋中的未研磨产品,尤其旨在用于小型消费者。所述干基水泥塑料混合物包含:In this example of a particular embodiment of the invention, a cement-plastic mixture, namely a dry cement-plastic mixture, is described for unground products preferably packaged in paper bags, especially intended for small consumers. The dry cement-plastic mixture comprises:

16kg的塑料碎料,占重量的38%,16kg of plastic scraps, accounting for 38% of the weight,

25kg的灰水泥42.5(或者白水泥52.5),占重量的60.1%,25kg of grey cement 42.5 (or white cement 52.5), accounting for 60.1% of the weight,

0.8kg的超塑化剂20/40,占重量的1.9%。0.8 kg of superplasticizer 20/40, accounting for 1.9% of the weight.

这三种基础组分占基础混合物的重量的100%,向其中添加的添加剂包含以下或由以下组成:These three basic components account for 100% by weight of the basic mixture, to which the additives added include or consist of:

5kg的石英砂,等级0.8mm,占重量的12%,和/或5kg of quartz sand, grade 0.8mm, accounting for 12% of the weight, and/or

0.4kg的固化促进剂Betodur A5,占重量的0.9%,和/或0.4 kg of curing accelerator Betodur A5, 0.9% by weight, and/or

0.022kg的ARC合成纤维42/30,占重量的0.05%,和/或0.022kg of ARC synthetic fiber 42/30, 0.05% by weight, and/or

0.004kg的涂料,占重量的0.01%,和/或0.004kg of coating, 0.01% by weight, and/or

2.5kg的硅灰(微硅粉)SiO2,占水泥的重量的10%。2.5 kg of silica fume (microsilica powder) SiO2, accounting for 10% of the weight of cement.

示例6Example 6

在本发明的特定实施例的该示例中,描述了湿基和标准水泥塑料混合物,即用于未研磨产品的湿水泥塑料混合物。In this example of a specific embodiment of the invention, a wet base and a standard cement plastic mix, ie a wet cement plastic mix for an unground product, is described.

基础是示例4和5中描述的混合物中的任一种,进一步的添加剂为1.7升水,其在干基混合物质量之外占4%的额外重量。The basis was any of the mixtures described in Examples 4 and 5, with a further additive being 1.7 litres of water, which represented 4% additional weight over the mass of the dry basis mixture.

工业实用性Industrial Applicability

根据本发明的水泥塑料混合物旨在用于建筑和石制品的领域。The cement-plastic mixture according to the invention is intended for use in the field of construction and stonework.

Claims (7)

1. Cement plastic mixture, characterized in that it comprises a base mixture comprising 29% to 43% by weight of plastic particles, 56% to 69% by weight of cement and 1.0% to 2.0% by weight of superplasticizer, the sum of these being 100% by weight of the base mixture.
2. Cement plastic mixture according to claim 1, characterized in that 6.0% to 12% by weight of silica sand is provided outside the weight of the base mixture, said silica sand being of the order of 0.3mm to 2.0mm.
3. Cement plastic mixture according to claim 1, characterized in that the curing accelerator is provided in an amount of 0.4% by weight to 0.9% by weight, outside the weight of the base mixture.
4. A cementitious plastic mixture as claimed in claim 1, wherein from 0.04% by weight to 0.07% by weight of ARC synthetic fibers are provided in addition to the weight of the base mixture.
5. Cement plastic mixture according to claim 1, characterized in that the coating is provided in an amount of 0.01% by weight to 0.08% by weight, outside the weight of the base mixture.
6. Cement plastic mixture according to claim 1, characterized in that water is provided in an amount of 4.0% by weight to 14.0% by weight, outside the weight of the base mixture.
7. Cement plastic mixture according to claim 1, characterized in that outside the weight of the base mixture 4.0% by weight to 10% by weight of silica fume (microsilica) SiO 2 by weight of cement weight is provided.
CN202280041018.9A 2021-06-07 2022-06-07 Cement plastic mixture Pending CN117957207A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
SKPP42-2021 2021-06-07
SKPUV81-2021 2021-06-07
SK812021U SK9398Y1 (en) 2021-06-07 2021-06-07 Cement-plastic mixture
PCT/SK2022/000004 WO2022260605A1 (en) 2021-06-07 2022-06-07 Cement plastic mixture

Publications (1)

Publication Number Publication Date
CN117957207A true CN117957207A (en) 2024-04-30

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SK (1) SK9398Y1 (en)

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SK812021U1 (en) 2021-08-11
SK9398Y1 (en) 2021-12-20

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