CN117871451A - A system for measuring combustion temperature and monitoring flammable and explosive gases - Google Patents
A system for measuring combustion temperature and monitoring flammable and explosive gases Download PDFInfo
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Abstract
Description
技术领域Technical Field
本发明涉及气体监测的技术领域,尤其涉及一种测量燃烧温度监测可燃易爆气体的系统。The invention relates to the technical field of gas monitoring, and in particular to a system for measuring combustion temperature and monitoring flammable and explosive gases.
背景技术Background technique
现有技术中,蓄热式氧化炉即RTO炉是目前针对中、低浓度废气,净化效率最高的废气处理设备之一。但焚烧炉装置常采用明火进行工作,容易产生爆炸事故,因此应实时监测废气浓度防止其浓度在爆炸上限和爆炸下限之间发生爆炸。In the existing technology, the regenerative thermal oxidation furnace, or RTO furnace, is one of the waste gas treatment equipment with the highest purification efficiency for medium and low concentration waste gas. However, the incinerator device often uses open flames to work, which is prone to explosion accidents. Therefore, the waste gas concentration should be monitored in real time to prevent its concentration from exploding between the upper and lower explosion limits.
当下可燃气体监测系统多采用FID检测器,其原理是利用氢火焰作电离源,使有机物电离,产生微电流而响应。FID检测器能满足所有有机废气浓度的测量。At present, most combustible gas monitoring systems use FID detectors, which use hydrogen flame as an ionization source to ionize organic matter and generate microcurrent to respond. FID detectors can meet the measurement of all organic waste gas concentrations.
但是,FID检测器的目前使用过程中,其存在一些不足:However, there are some shortcomings in the current use of FID detectors:
1、FID检测器对无机可燃气体没有响应;1. The FID detector does not respond to inorganic combustible gases;
2、复杂组份浓度时,配比浓度变化大,由于FID响应因子的偏差,会影响测量总碳氢的精度。2. When the concentration of components is complex, the ratio concentration changes greatly. Due to the deviation of the FID response factor, the accuracy of measuring total hydrocarbons will be affected.
因此,目前大量使用于可燃气体检测的FID检测器无法应用于可燃无机气体较多的环境当中。Therefore, the FID detector currently used in large quantities for combustible gas detection cannot be applied to environments with a large amount of combustible inorganic gases.
其次,当下火焰温度测量原理检测器对氧浓度要求十分苛刻,对于氧浓度低的环境进行测量时,出现火焰不稳定,火焰温度偏差大的现象,因此只能适应高浓度氧的环境。Secondly, the detector based on the flame temperature measurement principle has very strict requirements on oxygen concentration. When measuring in an environment with low oxygen concentration, the flame will be unstable and the flame temperature will deviate greatly. Therefore, it can only adapt to an environment with high oxygen concentration.
因此,寻求一种可用于所有可燃气体测量,且满足低氧环境需求的LEL在线监测系统具有显著的安全、环保和经济效应。Therefore, seeking an LEL online monitoring system that can be used for all combustible gas measurements and meet the needs of low-oxygen environments has significant safety, environmental and economic effects.
发明内容Summary of the invention
本部分的目的在于概述本发明的实施例的一些方面以及简要介绍一些较佳实施例。在本部分以及本申请的说明书摘要和发明名称中可能会做些简化或省略以避免使本部分、说明书摘要和发明名称的目的模糊,而这种简化或省略不能用于限制本发明的范围。The purpose of this section is to summarize some aspects of embodiments of the present invention and briefly introduce some preferred embodiments. Some simplifications or omissions may be made in this section and the specification abstract and the invention title of this application to avoid blurring the purpose of this section, the specification abstract and the invention title, and such simplifications or omissions cannot be used to limit the scope of the present invention.
鉴于上述现有测量燃烧温度监测可燃易爆气体的系统存在的问题,提出了本发明。In view of the above problems existing in the existing system for measuring combustion temperature and monitoring flammable and explosive gases, the present invention is proposed.
因此,本发明目的是提供一种测量燃烧温度监测可燃易爆气体的系统,其通过采用FTA检测器以及红外监测探头配合,实现了不同组分可燃废气的LEL在线监测,此监测可以在废气氧气含量较低的情况下进行。Therefore, the purpose of the present invention is to provide a system for measuring combustion temperature and monitoring flammable and explosive gases, which realizes online LEL monitoring of combustible exhaust gases of different components by adopting an FTA detector and an infrared monitoring probe. This monitoring can be carried out when the oxygen content of the exhaust gas is low.
为解决上述技术问题,本发明提供如下技术方案:一种测量燃烧温度监测可燃易爆气体的系统,包括:In order to solve the above technical problems, the present invention provides the following technical solutions: a system for measuring combustion temperature and monitoring flammable and explosive gases, comprising:
FTA检测器,所述FTA检测器设有氢气接口,通过氢气接口FTA检测器连接有氢气管路,氢气管路为FTA检测器提供氢气燃料;FTA detector, the FTA detector is provided with a hydrogen interface, through which the FTA detector is connected to a hydrogen pipeline, and the hydrogen pipeline provides hydrogen fuel for the FTA detector;
所述FTA检测器上还设有样气接口,FTA检测器通过样气接口连接有样气管路,样气管路的输入端设置有采样口;The FTA detector is also provided with a sample gas interface, the FTA detector is connected to a sample gas pipeline via the sample gas interface, and a sampling port is provided at the input end of the sample gas pipeline;
所述样气管路上设有三通接头,且三通接头连接有压缩空气管路,所述样气管路前段设置有红外监测探头,且红外监测探头用来气体测量;The sample gas pipeline is provided with a three-way joint, and the three-way joint is connected to a compressed air pipeline. The front section of the sample gas pipeline is provided with an infrared monitoring probe, and the infrared monitoring probe is used for gas measurement;
所述样气管路上设有第一过滤器和第一阻火器,所述第一过滤器用来防止杂质进入FTA检测器;第一阻火器用来防止氢气火焰回火并保证安全性;The sample gas pipeline is provided with a first filter and a first flame arrester, wherein the first filter is used to prevent impurities from entering the FTA detector; the first flame arrester is used to prevent hydrogen flame flashback and ensure safety;
所述FTA检测器上连接有排气管路,所述排气管路上设有第二过滤器和第二阻火器。The FTA detector is connected to an exhaust pipeline, and a second filter and a second flame arrester are arranged on the exhaust pipeline.
作为本发明所述测量燃烧温度监测可燃易爆气体的系统的一种优选方案,其中:所述FTA检测器后端设置有负压控制模块,通过负压控制模块对通过采样口进入的样气进行抽取。As a preferred solution of the system for measuring combustion temperature and monitoring flammable and explosive gases of the present invention, a negative pressure control module is provided at the rear end of the FTA detector, and the sample gas entering through the sampling port is extracted by the negative pressure control module.
作为本发明所述测量燃烧温度监测可燃易爆气体的系统的一种优选方案,其中:所述负压控制模块包括限流孔板,压力传感器以及与出口连通的射流泵,所述限流孔板通过调节孔板直径来提供流路所需的真空度,所述压差传感器能够发送压力信号至外部的控制平台,通过判断压力变化判断流路是否堵塞。As a preferred solution of the system for measuring combustion temperature and monitoring flammable and explosive gases described in the present invention, the negative pressure control module includes a flow limiting orifice, a pressure sensor and a jet pump connected to the outlet, the flow limiting orifice provides the vacuum required for the flow path by adjusting the orifice diameter, and the differential pressure sensor can send a pressure signal to an external control platform, and judge whether the flow path is blocked by judging the pressure change.
作为本发明所述测量燃烧温度监测可燃易爆气体的系统的一种优选方案,其中:所述压力传感器通过压力变化反馈进样流量,超出范围则输出报警,所述FTA检测器整体气密性好,且FTA检测器进口及出口能够引出管路与压力传感器及喷射泵相连接,所述喷射泵为FTA出口提供负压驱动力。As a preferred solution of the system for measuring combustion temperature and monitoring flammable and explosive gases described in the present invention, the pressure sensor feeds back the sampling flow rate through pressure changes, and outputs an alarm when it exceeds the range. The FTA detector has good overall airtightness, and the inlet and outlet of the FTA detector can lead out pipelines to be connected to the pressure sensor and the jet pump. The jet pump provides negative pressure driving force for the FTA outlet.
作为本发明所述测量燃烧温度监测可燃易爆气体的系统的一种优选方案,其中:所述第二过滤器具有强大的过滤功能,用来防止杂质堵塞限流孔板,所述第二阻火器用来防止回火。As a preferred solution of the system for measuring combustion temperature and monitoring flammable and explosive gases of the present invention, the second filter has a powerful filtering function to prevent impurities from clogging the flow limiting orifice plate, and the second flame arrester is used to prevent backfire.
作为本发明所述测量燃烧温度监测可燃易爆气体的系统的一种优选方案,其中:所述红外监测探头安装在采样管路样气和压缩空气汇合之前,针对气体组分中响应偏差大的气体进行单独测量,从而实现对FTA检测器的温度补偿并提高测量准确性。As a preferred solution of the system for measuring combustion temperature and monitoring flammable and explosive gases described in the present invention, the infrared monitoring probe is installed before the sample gas and compressed air in the sampling pipeline are merged, and a separate measurement is performed on the gas with large response deviation in the gas components, thereby achieving temperature compensation for the FTA detector and improving measurement accuracy.
本发明的有益效果:Beneficial effects of the present invention:
1、通过采用FTA检测器以及红外监测探头配合,实现了不同组分可燃废气的LEL在线监测,此监测可以在废气氧气含量较低的情况下进行。克服了FID检测器对无机可燃气体没有响应的弊端,同时克服了传统FTA检测器在低氧浓度下温度偏差的问题。2、红外监测探头为FTA对个别气体响应偏差做出了温度补偿,使测量更加精准。3、采用负压进样,使响应时间更短,加强了安全性。4、FTA检测器对于样品流量的波动接受范围优势,解决了FID检测器必须严格控制进样量的问题。1. By using the FTA detector and the infrared monitoring probe, the LEL online monitoring of combustible waste gas with different components is realized. This monitoring can be carried out when the oxygen content of the waste gas is low. It overcomes the disadvantage that the FID detector has no response to inorganic combustible gases, and at the same time overcomes the problem of temperature deviation of the traditional FTA detector under low oxygen concentration. 2. The infrared monitoring probe makes temperature compensation for the FTA response deviation of individual gases, making the measurement more accurate. 3. The use of negative pressure injection shortens the response time and enhances safety. 4. The FTA detector has an advantage in the range of acceptance of sample flow fluctuations, which solves the problem that the FID detector must strictly control the injection volume.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本发明实施例的技术方案,下面将对实施例描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其它的附图。其中:In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the following briefly introduces the drawings required for describing the embodiments. Obviously, the drawings described below are only some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without creative labor. Among them:
图1为本发明测量燃烧温度监测可燃易爆气体的系统的系统结构示意图。FIG. 1 is a schematic diagram of the system structure of the system for measuring combustion temperature and monitoring flammable and explosive gases according to the present invention.
具体实施方式Detailed ways
为使本发明的上述目的、特征和优点能够更加明显易懂,下面结合说明书附图对本发明的具体实施方式做详细的说明。In order to make the above-mentioned objects, features and advantages of the present invention more obvious and easy to understand, the specific implementation methods of the present invention are described in detail below in conjunction with the accompanying drawings.
在下面的描述中阐述了很多具体细节以便于充分理解本发明,但是本发明还可以采用其他不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本发明内涵的情况下做类似推广,因此本发明不受下面公开的具体实施例的限制。In the following description, many specific details are set forth to facilitate a full understanding of the present invention, but the present invention may also be implemented in other ways different from those described herein, and those skilled in the art may make similar generalizations without violating the connotation of the present invention. Therefore, the present invention is not limited to the specific embodiments disclosed below.
其次,此处所称的“一个实施例”或“实施例”是指可包含于本发明至少一个实现方式中的特定特征、结构或特性。在本说明书中不同地方出现的“在一个实施例中”并非均指同一个实施例,也不是单独的或选择性的与其他实施例互相排斥的实施例。Secondly, the term "one embodiment" or "embodiment" as used herein refers to a specific feature, structure, or characteristic that may be included in at least one implementation of the present invention. The term "in one embodiment" that appears in different places in this specification does not necessarily refer to the same embodiment, nor does it refer to a separate or selective embodiment that is mutually exclusive with other embodiments.
再其次,本发明结合示意图进行详细描述,在详述本发明实施例时,为便于说明,表示器件结构的剖面图会不依一般比例作局部放大,而且所述示意图只是示例,其在此不应限制本发明保护的范围。此外,在实际制作中应包含长度、宽度及深度的三维空间尺寸。Secondly, the present invention is described in detail with reference to schematic diagrams. When describing the embodiments of the present invention in detail, for the sake of convenience, the cross-sectional diagrams showing the device structure will not be partially enlarged according to the general scale, and the schematic diagrams are only examples, which should not limit the scope of protection of the present invention. In addition, in actual production, the three-dimensional dimensions of length, width and depth should be included.
参照图1,提供了一种测量燃烧温度监测可燃易爆气体的系统,包括:Referring to FIG. 1 , a system for measuring combustion temperature and monitoring flammable and explosive gases is provided, comprising:
FTA检测器1,FTA检测器1设有氢气接口,通过氢气接口FTA检测器1连接有氢气管路2,氢气管路2为FTA检测器1提供氢气燃料;FTA detector 1, FTA detector 1 is provided with a hydrogen interface, through which FTA detector 1 is connected to hydrogen pipeline 2, hydrogen pipeline 2 provides hydrogen fuel for FTA detector 1;
FTA检测器1上还设有样气接口,FTA检测器1通过样气接口连接有样气管路3,样气管路3的输入端设置有采样口4;The FTA detector 1 is also provided with a sample gas interface, through which the FTA detector 1 is connected to a sample gas pipeline 3, and an input end of the sample gas pipeline 3 is provided with a sampling port 4;
样气管路3上设有三通接头,且三通接头连接有压缩空气管路5,样气管路3前段设置有红外监测探头14,且红外监测探头14用来气体测量,红外监测探头14安装在采样管路样气和压缩空气汇合之前,针对气体组分中响应偏差大的气体进行单独测量,从而实现对FTA检测器的温度补偿并提高测量准确性;A three-way joint is provided on the sample gas pipeline 3, and the three-way joint is connected to the compressed air pipeline 5. An infrared monitoring probe 14 is provided at the front section of the sample gas pipeline 3, and the infrared monitoring probe 14 is used for gas measurement. The infrared monitoring probe 14 is installed before the sample gas and the compressed air in the sampling pipeline merge, and performs separate measurement on the gas with large response deviation in the gas components, thereby realizing temperature compensation for the FTA detector and improving the measurement accuracy;
其中,样气管路3上设有第一过滤器6和第一阻火器7,第一过滤器6用来防止杂质进入FTA检测器1;第一阻火器7用来防止氢气火焰回火并保证安全性;The sample gas pipeline 3 is provided with a first filter 6 and a first flame arrester 7. The first filter 6 is used to prevent impurities from entering the FTA detector 1; the first flame arrester 7 is used to prevent hydrogen flame flashback and ensure safety;
具体的,FTA检测器1上连接有排气管路8,排气管路8上设有第二过滤器9和第二阻火器10。Specifically, the FTA detector 1 is connected to an exhaust pipeline 8 , and the exhaust pipeline 8 is provided with a second filter 9 and a second flame arrester 10 .
其中,FTA检测器后端设置有负压控制模块,通过负压控制模块对通过采样口4进入的样气进行抽取,具体的,负压控制模块包括限流孔板11,压力传感器12以及与出口连通的射流泵13,限流孔板11通过调节孔板直径来提供流路所需的真空度,压差传感器12能够发送压力信号至外部的控制平台,通过判断压力变化判断流路是否堵塞,压力传感器12通过压力变化反馈进样流量,超出范围则输出报警,FTA检测器1整体气密性好,且FTA检测器1进口及出口能够引出管路与压力传感器12及喷射泵13相连接,喷射泵13为FTA出口提供负压驱动力。Among them, a negative pressure control module is arranged at the rear end of the FTA detector, and the sample gas entering through the sampling port 4 is extracted by the negative pressure control module. Specifically, the negative pressure control module includes a flow limiting orifice 11, a pressure sensor 12 and a jet pump 13 connected to the outlet. The flow limiting orifice 11 provides the vacuum required for the flow path by adjusting the orifice diameter. The differential pressure sensor 12 can send a pressure signal to an external control platform, and judge whether the flow path is blocked by judging the pressure change. The pressure sensor 12 feeds back the sample flow rate through the pressure change, and outputs an alarm when it exceeds the range. The FTA detector 1 has good overall air tightness, and the inlet and outlet of the FTA detector 1 can lead out pipelines to be connected to the pressure sensor 12 and the jet pump 13. The jet pump 13 provides negative pressure driving force for the FTA outlet.
其中,第二过滤器9具有强大的过滤功能,用来防止杂质堵塞限流孔板11,第二阻火器10用来防止回火。The second filter 9 has a strong filtering function to prevent impurities from clogging the flow limiting orifice 11, and the second flame arrester 10 is used to prevent backfire.
在本发明中,该系统主要元器件都置于柱箱的高温区,可以保证样品进入系统后不失真能够得到更加准确的结果。In the present invention, the main components of the system are placed in the high temperature area of the column box, which can ensure that the sample is not distorted after entering the system and can obtain more accurate results.
在本发明中,FTA检测器1具有用于氢气和样气燃烧的喷嘴。In the present invention, the FTA detector 1 has a nozzle for combustion of hydrogen gas and sample gas.
在本发明中,氢气燃料通过流量传感器控制,避免因负压模块提供的压力对氢气流量产生波动影响。In the present invention, the hydrogen fuel is controlled by a flow sensor to avoid fluctuations in the hydrogen flow caused by the pressure provided by the negative pressure module.
在本发明中,通过采用FTA检测器1,实现了对所有的可燃性废气的LEL在线监测,增强了检测过程中的灵敏性和通用性并且压缩空气管路5克服了低氧浓度下火焰形态及火焰温度不稳定的问题,实现了低氧浓度下对可燃废气的LEL测量。In the present invention, by adopting the FTA detector 1, online LEL monitoring of all combustible exhaust gases is achieved, the sensitivity and versatility of the detection process are enhanced, and the compressed air pipeline 5 overcomes the problems of unstable flame morphology and flame temperature under low oxygen concentration, thereby realizing LEL measurement of combustible exhaust gases under low oxygen concentration.
具体的,FTA检测器1的出口处设置的负压控制模块能够对通过采样口4进入的样气进行抽取。Specifically, the negative pressure control module provided at the outlet of the FTA detector 1 can extract the sample gas entering through the sampling port 4 .
在本发明中,FTA检测器1具有火焰测温功能,测量工具涉及高精度温度测量元件。In the present invention, the FTA detector 1 has a flame temperature measurement function, and the measuring tool involves a high-precision temperature measuring element.
具体的,FTA检测器1通过高精度温度测量元件输出温度信号,通过对温度信号比例化处理后,可适用于不同气体的分析和监测。Specifically, the FTA detector 1 outputs a temperature signal through a high-precision temperature measuring element, and after proportional processing of the temperature signal, it can be applied to the analysis and monitoring of different gases.
具体的,高精度温度测量元件具备快速响应和快速输出的特点,满足系统所需的响应时间。Specifically, the high-precision temperature measurement element has the characteristics of fast response and fast output, meeting the response time required by the system.
具体的,为满足标准化,保证高精度温度测量元件和火焰形态的统一化。Specifically, to meet standardization, high-precision temperature measurement elements and flame morphology must be unified.
在本发明中,采用耐腐蚀不锈钢材料,首选哈氏合金,能够对工况更为复杂和具有腐蚀性的气体进行分析测试。In the present invention, corrosion-resistant stainless steel material is used, and Hastelloy is the preferred material, so that analysis and testing of gases with more complex working conditions and corrosiveness can be performed.
工作原理:working principle:
该可燃废气LEL在线监测系统在监测前,需要根据工况,计算压缩空气管路所需的补氧空气流量,并通过稀释比例来调节温度输出比例。Before monitoring, the combustible exhaust LEL online monitoring system needs to calculate the oxygen supplement air flow required for the compressed air pipeline according to the working conditions, and adjust the temperature output ratio by the dilution ratio.
随后根据工况以及计算的压缩空气路提供的空气流量大小,计算进样量范围。通过进样量的范围确定压力传感器12的报警范围。Then, the injection volume range is calculated according to the working conditions and the calculated air flow provided by the compressed air circuit, and the alarm range of the pressure sensor 12 is determined by the injection volume range.
随后确定限流孔板11大小和射流泵13所需的驱动气大小。Then, the size of the flow restriction orifice 11 and the driving gas size required by the jet pump 13 are determined.
随后氢气燃料通过氢气管路按一定流量进入到FTA检测器1中,此时采样管路通入零气和压缩空气,在一定时间下保持火焰的稳定。随后采样口通入样气。Then the hydrogen fuel enters the FTA detector 1 through the hydrogen pipeline at a certain flow rate, and at this time, zero gas and compressed air are introduced into the sampling pipeline to keep the flame stable for a certain period of time. Then the sample gas is introduced into the sampling port.
FTA检测器1具有温度测量功能,FTA检测器1收集温度信号后,按照比例化处理转化为气体的LEL值。The FTA detector 1 has a temperature measurement function. After collecting the temperature signal, the FTA detector 1 converts it into the LEL value of the gas according to proportional processing.
为保证测量结果的准确性,该可燃废气LEL在线监测系统在首次测样前及周期性运行使用一段时间后,应进行零点标定和量程标定,以保证测量值能够真实反应样品的实际情况。To ensure the accuracy of the measurement results, the combustible waste gas LEL online monitoring system should be calibrated for zero point and range before the first sample measurement and after a period of periodic operation to ensure that the measured value can truly reflect the actual situation of the sample.
在本发明中,零点标定为:使用除烃空气通过进样口4对系统进行零点标定,且应除去标定前期数据以保证样品残留对零点标定的影响。In the present invention, the zero point calibration is: using hydrocarbon-free air to perform zero point calibration on the system through the sampling port 4, and the pre-calibration data should be removed to ensure that the influence of sample residue on the zero point calibration is eliminated.
在本发明中,量程标定为:使用一定浓度的乙烯通过进样口4对系统进行量程标定,并且应当在零点标定之后进行量程标定,且应在零点标定之后进行量程标定,以保证样品残留对量程标定的影响。In the present invention, the range calibration is: using a certain concentration of ethylene to calibrate the system through the injection port 4, and the range calibration should be performed after the zero point calibration to ensure that the influence of sample residue on the range calibration is eliminated.
应说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照较佳实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的精神和范围,其均应涵盖在本发明的权利要求范围当中。It should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention rather than to limit it. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that the technical solutions of the present invention may be modified or replaced by equivalents without departing from the spirit and scope of the technical solutions of the present invention, which should all be included in the scope of the claims of the present invention.
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