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CN117855877A - Tunable THz absorber capable of realizing dual-band spin selective absorption - Google Patents

Tunable THz absorber capable of realizing dual-band spin selective absorption Download PDF

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CN117855877A
CN117855877A CN202410164139.3A CN202410164139A CN117855877A CN 117855877 A CN117855877 A CN 117855877A CN 202410164139 A CN202410164139 A CN 202410164139A CN 117855877 A CN117855877 A CN 117855877A
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CN117855877B (en
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王英华
孙鑫悦
刘广强
高旭珍
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Qufu Normal University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q17/00Devices for absorbing waves radiated from an antenna; Combinations of such devices with active antenna elements or systems
    • H01Q17/008Devices for absorbing waves radiated from an antenna; Combinations of such devices with active antenna elements or systems with a particular shape
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/003Light absorbing elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/0006Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices
    • H01Q15/0086Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices said selective devices having materials with a synthesized negative refractive index, e.g. metamaterials or left-handed materials

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  • Optics & Photonics (AREA)
  • Optical Modulation, Optical Deflection, Nonlinear Optics, Optical Demodulation, Optical Logic Elements (AREA)

Abstract

本发明公开了一种能够实现双波段自旋选择吸收的可调谐THz吸收器,属于THz波段金属与石墨烯相结合的光学超材料技术领域,该可调谐THz吸收器由若干个在XY平面上呈周期性排列的结构单元组成,取所述结构单元的几何中心为O点,过该点的沿水平和竖直方向的两条相互垂直的边为OX轴和OY轴,且垂直于两条边的为OZ轴,每个所述结构单元均由下层的金属板、中间衬底层以及附着在所述中间衬底层上的两条石墨烯片和位于上层的L型金属单元组成。本发明采用上述的一种能够实现双波段自旋选择吸收的可调谐THz吸收器,具有制作简单,可调谐,双波段范围,自旋选择吸收效率高,应用场景广泛等优点。

The present invention discloses a tunable THz absorber capable of realizing dual-band spin-selective absorption, belonging to the technical field of optical metamaterials combining THz band metals and graphene. The tunable THz absorber is composed of a number of structural units arranged periodically on the XY plane, the geometric center of the structural unit is taken as point O, the two mutually perpendicular sides passing through the point in the horizontal and vertical directions are the OX axis and the OY axis, and the axis perpendicular to the two sides is the OZ axis, each of the structural units is composed of a metal plate in the lower layer, an intermediate substrate layer, two graphene sheets attached to the intermediate substrate layer, and an L-shaped metal unit located in the upper layer. The present invention adopts the above-mentioned tunable THz absorber capable of realizing dual-band spin-selective absorption, which has the advantages of simple manufacture, tunability, dual-band range, high spin-selective absorption efficiency, and wide application scenarios.

Description

一种能够实现双波段自旋选择吸收的可调谐THz吸收器A tunable THz absorber capable of dual-band spin-selective absorption

技术领域Technical Field

本发明涉及THz波段金属与石墨烯相结合的光学超材料技术领域,尤其是涉及一种能够实现双波段自旋选择吸收的可调谐THz吸收器。The present invention relates to the technical field of optical metamaterials combining THz band metal and graphene, and in particular to a tunable THz absorber capable of realizing dual-band spin selective absorption.

背景技术Background technique

太赫兹(THz)波(0.1-10THz)位于微波和红外光波之间,具有光子能量低、穿透性强、带宽宽、成像分辨率高等优点,引起了研究人员的极大兴趣。在20世纪80年代中期以前,由于缺乏有效的产生和检测方法,人们对该波段的电磁性质的研究是有限的,因此被称为“太赫兹空隙”,随着超快激光技术和新材料的迅速发展,使太赫兹的产生和探测问题得到了有效的解决,太赫兹科学技术得到了蓬勃的发展,在检测、成像和无线通信等多个应用领域取得了丰硕成果。其中吸收器在太赫兹应用设备中扮演着重要角色,但传统天然材料对太赫兹波的电磁响应较弱,很难实现对太赫兹波的高效吸收。超材料(Metamaterials)的出现解决了这一问题。2008年,Tao等人提出了第一代太赫兹超材料吸收器,该吸收器在1.3THz时的谐振吸收率高达70%。随后,双波段、多波段和宽带超材料吸收器相继问世,为太赫兹超材料吸收器的发展开辟了广阔的前景。Terahertz (THz) waves (0.1-10THz) are located between microwaves and infrared light waves. They have the advantages of low photon energy, strong penetration, wide bandwidth, and high imaging resolution, which have aroused great interest among researchers. Before the mid-1980s, due to the lack of effective generation and detection methods, research on the electromagnetic properties of this band was limited, so it was called the "THz gap". With the rapid development of ultrafast laser technology and new materials, the generation and detection problems of THz have been effectively solved. THz science and technology has been vigorously developed, and fruitful results have been achieved in many application fields such as detection, imaging, and wireless communications. Among them, absorbers play an important role in THz application devices, but traditional natural materials have weak electromagnetic response to THz waves, making it difficult to achieve efficient absorption of THz waves. The emergence of metamaterials solves this problem. In 2008, Tao et al. proposed the first generation of THz metamaterial absorbers, which had a resonant absorption rate of up to 70% at 1.3THz. Subsequently, dual-band, multi-band and broadband metamaterial absorbers came out one after another, opening up broad prospects for the development of terahertz metamaterial absorbers.

超材料是人工制造的亚波长周期性结构,这里的“亚波长”是指其结构尺寸小于外部光刺激的波长。1999年Walser首次提出了超材料,在超材料研究初期,主要是在微波区域实现一些电磁特性,如负折射率和完美透镜等。在第一个位于微波区的完美超材料吸收器被Landy等人提出后,用于电磁波吸收的超材料因此备受关注,但是所设计的大多数超材料吸收器只适用于线性偏振波,很少适用于圆偏振波。随着超材料的发展,具有手性特征的超材料引起了人们的注意,因为具有手性特征的超材料不仅能操纵线性偏振波还能操纵圆偏振波。手性指的是一个物体缺乏镜面对称性,不能通过平移或旋转与其镜像结构重合。通过人工设计将手性引入到超材料吸收器结构的设计中就能够获得缺乏镜像对称性的手性超材料吸收器。由于手性超材料吸收器对右旋圆偏光(RCP)与左旋圆偏振光(LCP)的吸收率不同,因此可以实现对圆偏振光的选择性吸收即自旋选择吸收。同时自旋选择吸收效应可以用圆二色性(CD)值来表示,圆二色性值被定义为右旋圆偏振光与左旋圆偏振光的吸收差值。近年来,人们在从微波到光学区域的频谱范围内提出了各种手性超材料吸收器。2016年,Wang等人通过结合两层各向异性超材料结构,设计出了一种工作在中红外区域的圆二色性超镜,这种超镜对左旋圆偏振光表现出完美的反射率,而不反转其偏振方向,同时它完全吸收右旋圆偏振光。2017年,Tang等人提出了一种η型超材料结构,这种结构能够在可见光频段实现双带自旋选择吸收,最大吸收率超过了80%且圆二色性值约为0.5。2018年,OuYang等人提出了一种近红外手性等离子体超表面吸收器,它能够在单一频带内实现对右旋圆偏振光的吸收,它的镜像结构能够实现在单一频带内对左旋圆偏振光的吸收,最大吸收率为87%,最大圆二色性值约为70%。2019年,Wang等人提出了一种I型手性选择性超材料吸收器,在两个共振频段内能够对左旋圆偏振光实现强烈的吸收,吸收率分别达到95.18%和91.77%,但在两个频段内几乎不吸收右旋圆偏振光,从而产生了显著的圆二色性。2022年,Tang等人设计并演示了具有双波段选择性吸收的中红外手性超表面吸收器,其对圆偏振光吸收的可调谐性是通过顶部金属层的两个耦合矩形条的独特设计实现的,可以通过调整垂直矩形条的宽度和长度来控制和翻转每个波段的圆二色性符号。2022年,Tao等人提出了两种工作在太赫兹区域并且具有强圆二色性的双波段自旋选择吸收超表面,第一种可以在两个波段吸收圆偏振波的相同自旋态,第二种在第一个波段吸收圆偏振波的一种自旋态,在第二个波段吸收与第一个波段自旋态正交的自旋态。从手性超材料吸收器的研究中可以看出,太赫兹手性超材料吸收器尚未得到广泛研究。因此,研究设计能够在太赫兹范围内实现圆偏振波选择和传播控制的自旋选择吸收超材料结构对于许多应用是至关重要的,例如全息成像、生物分子检测和CD光谱。Metamaterials are artificially manufactured subwavelength periodic structures, where "subwavelength" means that the size of the structure is smaller than the wavelength of external light stimulation. Metamaterials were first proposed by Walser in 1999. In the early stage of metamaterial research, some electromagnetic properties, such as negative refractive index and perfect lens, were mainly realized in the microwave region. After the first perfect metamaterial absorber in the microwave region was proposed by Landy et al., metamaterials for electromagnetic wave absorption have attracted much attention. However, most of the designed metamaterial absorbers are only suitable for linearly polarized waves, and rarely for circularly polarized waves. With the development of metamaterials, metamaterials with chiral characteristics have attracted people's attention, because metamaterials with chiral characteristics can manipulate not only linearly polarized waves but also circularly polarized waves. Chirality refers to the lack of mirror symmetry of an object, which cannot be overlapped with its mirror structure by translation or rotation. By introducing chirality into the design of the metamaterial absorber structure through artificial design, a chiral metamaterial absorber lacking mirror symmetry can be obtained. Since the chiral metamaterial absorber has different absorption rates for right-handed circularly polarized light (RCP) and left-handed circularly polarized light (LCP), it can achieve selective absorption of circularly polarized light, namely spin-selective absorption. At the same time, the spin-selective absorption effect can be expressed by the circular dichroism (CD) value, which is defined as the absorption difference between right-handed circularly polarized light and left-handed circularly polarized light. In recent years, various chiral metamaterial absorbers have been proposed in the spectrum range from microwave to optical regions. In 2016, Wang et al. designed a circular dichroism supermirror working in the mid-infrared region by combining two layers of anisotropic metamaterial structures. This supermirror shows perfect reflectivity for left-handed circularly polarized light without reversing its polarization direction, and it completely absorbs right-handed circularly polarized light. In 2017, Tang et al. proposed an η-type metamaterial structure that can achieve dual-band spin-selective absorption in the visible light band, with a maximum absorption rate of more than 80% and a circular dichroism value of about 0.5. In 2018, OuYang et al. proposed a near-infrared chiral plasma metasurface absorber that can absorb right-handed circularly polarized light in a single band, and its mirror structure can absorb left-handed circularly polarized light in a single band, with a maximum absorption rate of 87% and a maximum circular dichroism value of about 70%. In 2019, Wang et al. proposed a type I chiral selective metamaterial absorber that can strongly absorb left-handed circularly polarized light in two resonant frequency bands, with absorption rates of 95.18% and 91.77% respectively, but almost no right-handed circularly polarized light is absorbed in the two frequency bands, resulting in significant circular dichroism. In 2022, Tang et al. designed and demonstrated a mid-infrared chiral metasurface absorber with dual-band selective absorption. The tunability of its absorption of circularly polarized light is achieved through the unique design of two coupled rectangular strips on the top metal layer. The circular dichroism sign of each band can be controlled and flipped by adjusting the width and length of the vertical rectangular strips. In 2022, Tao et al. proposed two dual-band spin-selective absorption metasurfaces working in the terahertz region and with strong circular dichroism. The first can absorb the same spin state of circularly polarized waves in two bands, and the second absorbs one spin state of circularly polarized waves in the first band and absorbs the spin state orthogonal to the spin state of the first band in the second band. It can be seen from the research on chiral metamaterial absorbers that terahertz chiral metamaterial absorbers have not been widely studied. Therefore, the research and design of spin-selective absorption metamaterial structures that can achieve circularly polarized wave selection and propagation control in the terahertz range is crucial for many applications, such as holographic imaging, biomolecule detection, and CD spectroscopy.

上述提出的手性超材料只能通过调整结构的大小来调节吸收,这降低了实际应用的适用性。为了实现可调谐吸收,一种新型材料石墨烯被引入到了超材料的设计中。石墨烯是由紧密排列的扁平单层碳原子组成的一种二维蜂窝状晶格,于2004年首次通过石墨剥离获得,偏压或光激发石墨烯的电磁特性由自由载流子的Drude式电响应以及狄拉克锥的低带和高带之间的带间跃迁决定,通过控制费米能级这两者都是可调的,从而使这种材料制成的电磁结构具有前所未有的可调性。最近,人们报道了不同的基于石墨烯的可调谐超材料。He等人提出了一种石墨烯超材料,并对其在太赫兹区域的电磁诱导透明(EIT)窗口的主动调谐进行了数值演示。Yuan等人报道了一种全石墨烯介质太赫兹超材料吸收器/反射器,其吸收带宽和吸收率可以通过施加偏置电压调节图案化石墨烯的费米能级来调节。Tao等人介绍了一种具有强圆二色性的可调谐双波段太赫兹非对称传输(AT)超表面,它可以在太赫兹频段实现双波段AT效应,并具有很强的CD效应,在两个波段中偏振波能够被转化为它的交叉偏振波。因此,石墨烯是可调谐器件的良好候选材料,在设计的手性超材料结构上附加上石墨烯层就能够实现具有可调性的自旋选择超材料吸收器,这种具有可调性自旋选择吸收器的研究可能会为手性传感、成像、信息加密和隐藏等新兴太赫兹技术中的各种手性相关应用提供广阔的发展前景。The chiral metamaterials proposed above can only adjust the absorption by adjusting the size of the structure, which reduces the applicability of practical applications. In order to achieve tunable absorption, a new material, graphene, has been introduced into the design of metamaterials. Graphene is a two-dimensional honeycomb lattice composed of tightly packed flat monolayer carbon atoms. It was first obtained by graphite exfoliation in 2004. The electromagnetic properties of biased or photoexcited graphene are determined by the Drude-like electrical response of free carriers and the interband transition between the low and high bands of the Dirac cone. Both are tunable by controlling the Fermi level, which makes the electromagnetic structure made of this material have unprecedented tunability. Recently, different graphene-based tunable metamaterials have been reported. He et al. proposed a graphene metamaterial and numerically demonstrated the active tuning of its electromagnetic induced transparency (EIT) window in the terahertz region. Yuan et al. reported an all-graphene dielectric terahertz metamaterial absorber/reflector, whose absorption bandwidth and absorptivity can be adjusted by applying a bias voltage to adjust the Fermi level of the patterned graphene. Tao et al. introduced a tunable dual-band terahertz asymmetric transmission (AT) metasurface with strong circular dichroism, which can realize dual-band AT effect in the terahertz band and has a strong CD effect, and polarized waves in two bands can be converted into their cross-polarized waves. Therefore, graphene is a good candidate material for tunable devices. Adding a graphene layer to the designed chiral metamaterial structure can realize a tunable spin-selective metamaterial absorber. The research on this tunable spin-selective absorber may provide broad development prospects for various chirality-related applications in emerging terahertz technologies such as chiral sensing, imaging, information encryption and hiding.

发明内容Summary of the invention

本发明的目的是提供一种能够实现双波段自旋选择吸收的可调谐THz吸收器,具有制作简单,可调谐,双波段范围,自旋选择吸收效率高,应用场景广泛等优点。The purpose of the present invention is to provide a tunable THz absorber capable of realizing dual-band spin-selective absorption, which has the advantages of simple manufacture, tunability, dual-band range, high spin-selective absorption efficiency, and wide application scenarios.

为实现上述目的,本发明提供了一种能够实现双波段自旋选择吸收的可调谐THz吸收器,该可调谐THz吸收器由若干个在XY平面上呈周期性排列的结构单元组成,取所述结构单元的几何中心为O点,过该点的沿水平和竖直方向的两条相互垂直的边为OX轴和OY轴,且垂直于两条边的为OZ轴,每个所述结构单元均由下层的金属板、中间衬底层以及附着在所述中间衬底层上的两条石墨烯片和位于上层的L型金属单元组成,所述的双波段自旋选择吸收是指能够在两个频段内分别实现对右旋圆偏振光与左旋圆偏振光的选择性吸收,其中右旋圆偏振光与左旋圆偏振光属于圆偏振光的两种自旋态,所述附着的石墨烯片使得在不改变结构参数的情况下实现了对自旋选择吸收效率的调控。To achieve the above-mentioned purpose, the present invention provides a tunable THz absorber capable of realizing dual-band spin-selective absorption. The tunable THz absorber is composed of a plurality of structural units arranged periodically on an XY plane. The geometric center of the structural unit is taken as point O, and two mutually perpendicular sides passing through the point in the horizontal and vertical directions are the OX axis and the OY axis, and the axis perpendicular to the two sides is the OZ axis. Each of the structural units is composed of a metal plate in a lower layer, an intermediate substrate layer, two graphene sheets attached to the intermediate substrate layer, and an L-shaped metal unit in an upper layer. The dual-band spin-selective absorption refers to the ability to realize selective absorption of right-handed circularly polarized light and left-handed circularly polarized light in two frequency bands, respectively, wherein right-handed circularly polarized light and left-handed circularly polarized light belong to two spin states of circularly polarized light, and the attached graphene sheets enable the spin-selective absorption efficiency to be regulated without changing the structural parameters.

优选的,在所述结构单元的两侧附加有与所述石墨烯片的两端相连的电极。Preferably, electrodes connected to two ends of the graphene sheet are attached to both sides of the structural unit.

优选的,所述L型金属单元由沿OX轴方向分布的三组金属棒组合构成,三组金属棒组合的长度都不相同,但厚度和宽度都相同;Preferably, the L-shaped metal unit is composed of three groups of metal rods distributed along the OX axis, and the lengths of the three groups of metal rods are different, but the thickness and width are the same;

第一组金属棒组合由第一金属棒与第二金属棒组成,第二组金属棒组合由第三金属棒与第四金属棒组成,第三组金属棒组合由第五金属棒与第六金属棒组成;每一组金属棒组合中的金属棒都是相互垂直的,所述第一组金属棒组合与第二组金属棒组合绕OZ轴旋转的角度一致,所述第三组金属棒组合与第一、二组金属棒组合绕OZ轴旋转的角度不一致;所述L型金属单元的所述第二组金属棒组合中的第四金属棒与第三组金属棒组合中的第五金属棒的夹角记为θ。The first group of metal rod combinations consists of the first metal rod and the second metal rod, the second group of metal rod combinations consists of the third metal rod and the fourth metal rod, and the third group of metal rod combinations consists of the fifth metal rod and the sixth metal rod; the metal rods in each group of metal rod combinations are perpendicular to each other, the first group of metal rod combinations and the second group of metal rod combinations rotate at the same angle around the OZ axis, and the third group of metal rod combinations rotate at an angle different from the first and second groups of metal rod combinations around the OZ axis; the angle between the fourth metal rod in the second group of metal rod combinations and the fifth metal rod in the third group of metal rod combinations of the L-shaped metal unit is recorded as θ.

优选的,所述夹角θ的调节范围为92°-112°。Preferably, the adjustment range of the angle θ is 92°-112°.

优选的,所述θ=102°。Preferably, θ=102°.

优选的,所述金属板与中间衬底层的长和宽分别为px=py=310um,所述金属板的厚度t=18um,所述中间衬底层的厚度d=75um,所述L型金属单元的宽度w=12um,厚度h=18um;其中,所述第一组金属棒组合中的所述第一金属棒的长度L1=185um、所述第二金属棒的长度L2=149um,所述第二组金属棒组合中的所述第三金属棒的长度L3=155um、所述第四金属棒的长度L4=157um,所述第三组金属棒组合中的所述第五金属棒的长度L5=147um、所述第六金属棒的长度L6=170um,所述第一组金属棒组合和第二组金属棒组合的间距m=37um,两条所述石墨烯片的宽度wg=5um,它们之间的间距b=35um。Preferably, the length and width of the metal plate and the intermediate substrate layer are px = py =310um respectively, the thickness of the metal plate is t=18um, the thickness of the intermediate substrate layer is d=75um, the width of the L-shaped metal unit is w=12um, and the thickness is h=18um; wherein, the length of the first metal rod in the first group of metal rods is L1 =185um, the length of the second metal rod is L2 =149um, the length of the third metal rod in the second group of metal rods is L3 =155um, the length of the fourth metal rod is L4 =157um, the length of the fifth metal rod in the third group of metal rods is L5 =147um, the length of the sixth metal rod is L6 =170um, the spacing between the first group of metal rods and the second group of metal rods is m=37um, the width of the two graphene sheets is wg =5um, and the spacing between them is b=35um.

优选的,所述中间衬底层为二氧化硅衬底。Preferably, the intermediate substrate layer is a silicon dioxide substrate.

优选的,所述L型金属单元与金属板均为金质材质。Preferably, the L-shaped metal unit and the metal plate are both made of gold.

优选的,所述结构单元具有手性特征。Preferably, the structural unit has chiral characteristics.

因此,本发明采用上述一种能够实现双波段自旋选择吸收的可调谐THz吸收器的有益效果如下:Therefore, the beneficial effects of the present invention using the above-mentioned tunable THz absorber capable of realizing dual-band spin selective absorption are as follows:

(1)该THz吸收器能够实现对圆偏振光双波段完美自旋选择吸收,即在0.28THz波段,圆偏振光沿OZ轴正方向射入该材料时,RCP能够被完美吸收,但几乎不吸收LCP;在0.35THz波段,圆偏振光沿OZ轴正方向射入该材料时,LCP能够被完美吸收,但几乎不吸收RCP。(1) The THz absorber can achieve perfect dual-band spin-selective absorption of circularly polarized light, that is, in the 0.28 THz band, when circularly polarized light is incident on the material along the positive direction of the OZ axis, RCP can be perfectly absorbed, but LCP is almost not absorbed; in the 0.35 THz band, when circularly polarized light is incident on the material along the positive direction of the OZ axis, LCP can be perfectly absorbed, but RCP is almost not absorbed.

(2)该THz吸收器具备可调谐性,通过改变石墨烯的费米能级能够在不改变结构参数的情况下实现对自旋选择吸收效率的调控。(2) The THz absorber is tunable. By changing the Fermi level of graphene, the spin-selective absorption efficiency can be regulated without changing the structural parameters.

(3)通过改变每组金属棒组合中金属棒的长度、宽度、厚度以及二氧化硅衬底的厚度和金属棒的旋转角度,能够满足不同环境下实际应用中对自旋选择吸收的效率以及波段等的要求,应用场景广泛。(3) By changing the length, width, thickness of the metal rods in each group of metal rods, the thickness of the silicon dioxide substrate, and the rotation angle of the metal rods, the requirements for the efficiency and band of spin-selective absorption in practical applications under different environments can be met, and the application scenarios are wide.

下面通过附图和实施例,对本发明的技术方案做进一步的详细描述。The technical solution of the present invention is further described in detail below through the accompanying drawings and embodiments.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

图1为本实施例中可调谐THz吸收器的三维结构示意图;FIG1 is a schematic diagram of the three-dimensional structure of a tunable THz absorber in this embodiment;

图2为本实施例中结构单元的三维结构示意图;FIG2 is a schematic diagram of the three-dimensional structure of the structural unit in this embodiment;

图3为结构单元的主视图;Fig. 3 is a front view of the structural unit;

图4(a)和(b)分别为本实施例中圆偏振光沿OZ轴正方向入射到THz吸收器时得到的反射谱图和吸收谱图;4(a) and (b) are respectively the reflection spectrum and absorption spectrum obtained when circularly polarized light is incident on the THz absorber along the positive direction of the OZ axis in this embodiment;

图5(a)和(b)分别为本实施例中随石墨烯费米能级变化的RCP吸收谱和RCP峰值、峰频率的变化图;5(a) and (b) are respectively diagrams showing the RCP absorption spectrum and the changes in the RCP peak value and peak frequency as the Fermi level of graphene changes in this embodiment;

图6(a)和(b)分别为本实施例中随石墨烯费米能级变化的LCP吸收谱和LCP峰值、峰频率的变化图;6(a) and (b) are respectively diagrams showing the changes in the LCP absorption spectrum and the LCP peak value and peak frequency as the Fermi level of graphene changes in this embodiment;

图7(a)和(b)分别为本实施例中圆偏振光沿OZ轴正方向入射到THz吸收器时得到的CD谱和随石墨烯费米能级变化的CD谱;7(a) and (b) are respectively the CD spectrum obtained when circularly polarized light is incident on the THz absorber along the positive direction of the OZ axis and the CD spectrum changing with the Fermi level of graphene in this embodiment;

图8(a)和(b)分别为本实施例中夹角θ变化时THz吸收器对RCP和LCP的吸收谱。FIG8 (a) and (b) are absorption spectra of the THz absorber to RCP and LCP when the angle θ varies in this embodiment, respectively.

附图标记Reference numerals

1、金属板;2、中间衬底层;3、石墨烯片;4、L型金属单元;5、电极;6、第一金属棒;7、第二金属棒;8、第三金属棒;9、第四金属棒;10、第五金属棒;11、第六金属棒。1. Metal plate; 2. Intermediate substrate layer; 3. Graphene sheet; 4. L-shaped metal unit; 5. Electrode; 6. First metal rod; 7. Second metal rod; 8. Third metal rod; 9. Fourth metal rod; 10. Fifth metal rod; 11. Sixth metal rod.

具体实施方式Detailed ways

以下通过附图和实施例对本发明的技术方案作进一步说明。The technical solution of the present invention is further described below through the accompanying drawings and embodiments.

除非另外定义,本发明使用的技术术语或者科学术语应当为本发明所属领域内具有一般技能的人士所理解的通常意义。本发明中使用的“第一”、“第二”以及类似的词语并不表示任何顺序、数量或者重要性,而只是用来区分不同的组成部分。“包括”或者“包含”等类似的词语意指出现该词前面的元件或者物件涵盖出现在该词后面列举的元件或者物件及其等同,而不排除其他元件或者物件。“连接”或者“相连”等类似的词语并非限定于物理的或者机械的连接,而是可以包括电性的连接,不管是直接的还是间接的。“上”、“下”、“左”、“右”等仅用于表示相对位置关系,当被描述对象的绝对位置改变后,则该相对位置关系也可能相应地改变。Unless otherwise defined, the technical terms or scientific terms used in the present invention should be understood by people with ordinary skills in the field to which the present invention belongs. "First", "second" and similar words used in the present invention do not indicate any order, quantity or importance, but are only used to distinguish different components. "Include" or "comprise" and similar words mean that the elements or objects appearing before the word include the elements or objects listed after the word and their equivalents, without excluding other elements or objects. "Connect" or "connected" and similar words are not limited to physical or mechanical connections, but may include electrical connections, whether direct or indirect. "Up", "down", "left", "right" and the like are only used to indicate relative positional relationships. When the absolute position of the described object changes, the relative positional relationship may also change accordingly.

实施例一Embodiment 1

如图1所示,本发明提供了一种能够实现双波段自旋选择吸收的可调谐THz吸收器,该可调谐THz吸收器由若干个在XY平面上呈周期性排列的结构单元组成,取结构单元的几何中心为O点,过该点的沿水平和竖直方向的两条相互垂直的边为OX轴和OY轴,且垂直于两条边的为OZ轴。结构单元具有手性特征,每个结构单元均由下层的金属板1、中间衬底层2以及附着在中间衬底层2上的两条石墨烯片3和位于上层的L型金属单元4组成,在周期性结构单元两侧附加两片电极5与石墨烯片3的两端相连。As shown in FIG1 , the present invention provides a tunable THz absorber capable of realizing dual-band spin selective absorption, the tunable THz absorber is composed of a plurality of structural units arranged periodically on the XY plane, the geometric center of the structural unit is taken as point O, the two mutually perpendicular sides passing through the point in the horizontal and vertical directions are the OX axis and the OY axis, and the axis perpendicular to the two sides is the OZ axis. The structural unit has chiral characteristics, each structural unit is composed of a metal plate 1 in the lower layer, an intermediate substrate layer 2, two graphene sheets 3 attached to the intermediate substrate layer 2, and an L-shaped metal unit 4 in the upper layer, and two electrodes 5 are attached on both sides of the periodic structural unit to connect the two ends of the graphene sheet 3.

如图2所示,L型金属单元4由沿OX轴方向分布的三组金属棒组合构成,三组金属棒组合的长度都不相同,但厚度和宽度都相同。其中,第一组金属棒组合由一根第一金属棒6与一根第二金属棒7组成,第二组金属棒组合由一根第三金属棒8与一根第四金属棒9组成,第三组金属棒组合由一根第五金属棒10与一根第六金属棒11组成,且每一组金属棒组合中的两根金属棒都是相互垂直的。As shown in FIG. 2 , the L-shaped metal unit 4 is composed of three groups of metal rods distributed along the OX axis, and the lengths of the three groups of metal rods are different, but the thickness and width are the same. Among them, the first group of metal rods is composed of a first metal rod 6 and a second metal rod 7, the second group of metal rods is composed of a third metal rod 8 and a fourth metal rod 9, and the third group of metal rods is composed of a fifth metal rod 10 and a sixth metal rod 11, and the two metal rods in each group of metal rods are perpendicular to each other.

第一组金属棒组合与第二组金属棒组合绕OZ轴旋转的角度一致,第三组金属棒组合与第一、二组金属棒组合绕OZ轴旋转的角度不一致。L型金属单元4的所述第二组金属棒组合中的第四金属棒9与第三组金属棒组合中的第五金属棒10的夹角记为θ。旋转第三组金属棒组合,夹角θ的调节范围为92°-112°。当夹角θ=102°时,对圆偏振光的自旋选择吸收率是最优的。The first group of metal rods and the second group of metal rods rotate at the same angle around the OZ axis, and the third group of metal rods rotates at the same angle around the OZ axis as the first and second groups of metal rods. The angle between the fourth metal rod 9 in the second group of metal rods of the L-shaped metal unit 4 and the fifth metal rod 10 in the third group of metal rods is denoted as θ. The third group of metal rods rotates, and the adjustment range of the angle θ is 92°-112°. When the angle θ=102°, the spin-selective absorption rate of circularly polarized light is optimal.

需要说明的是,结合图2,结构单元中,中间衬底层2为二氧化硅衬底,二氧化硅衬底介于上层的L型金属单元4与下层的金属板1之间,且L型金属单元4与金属板1均为金质材质。It should be noted that, in conjunction with FIG. 2 , in the structural unit, the middle substrate layer 2 is a silicon dioxide substrate, the silicon dioxide substrate is between the upper L-shaped metal unit 4 and the lower metal plate 1 , and both the L-shaped metal unit 4 and the metal plate 1 are made of gold.

本实施例中,结合图2与图3,结构单元中金属板1与中间衬底层2的长和宽分别为px=py=310um,金属板1的厚度t=18um,中间衬底层2的厚度d=75um,L型金属单元4的宽度w=12um,厚度h=18um。其中,第一组金属棒组合中的第一金属棒6的长度L1=185um、第二金属棒7的长度L2=149um,第二组金属棒组合中的第三金属棒8的长度L3=155um、第四金属棒9的长度L4=157um,第三组金属棒组合中的第五金属棒10的长度L5=147um、第六金属棒11的长度L6=170um,第一组金属棒组合和第二组金属棒组合的间距m=37um,两条石墨烯片3的宽度wg=5um,它们之间的间距b=35um。In this embodiment, in combination with FIG. 2 and FIG. 3 , the length and width of the metal plate 1 and the intermediate substrate layer 2 in the structural unit are respectively p x = p y = 310 um, the thickness of the metal plate 1 is t = 18 um, the thickness of the intermediate substrate layer 2 is d = 75 um, the width of the L-shaped metal unit 4 is w = 12 um, and the thickness is h = 18 um. Among them, the length of the first metal rod 6 in the first group of metal rods is L 1 = 185 um, the length of the second metal rod 7 is L 2 = 149 um, the length of the third metal rod 8 in the second group of metal rods is L 3 = 155 um, the length of the fourth metal rod 9 is L 4 = 157 um, the length of the fifth metal rod 10 in the third group of metal rods is L 5 = 147 um, the length of the sixth metal rod 11 is L 6 = 170 um, the spacing between the first group of metal rods and the second group of metal rods is m = 37 um, the width of the two graphene sheets 3 is w g = 5 um, and the spacing between them is b = 35 um.

进一步的,本发明可采用微纳加工技术(如电子束曝光,聚焦离子束等方法)进行制备。聚焦离子束技术(FIB)能够利用具有聚焦功能的透镜将离子束加速聚焦成很小尺寸的光斑,使离子束具有非常高的能量并与固体发生碰撞,将组成固体的原子层溅射剥离。利用聚焦离子束技术可以实现成像,刻蚀,沉积薄膜,离子束注入,透射电镜样品的制备等功能。以聚焦离子束刻蚀为例,在二氧化硅衬底2的上层和下层沉积金属薄膜,在上层依次刻蚀出第一组金属棒组合的第一金属棒6和第二金属棒7、第二组金属棒组合的第三金属棒8和第四金属棒9、第三组金属棒组合的第五金属棒10和第六金属棒11,形成上层的L型金属单元4,在下层沉积的金属薄膜形成金属板1。Further, the present invention can be prepared by micro-nano processing technology (such as electron beam exposure, focused ion beam and other methods). Focused ion beam technology (FIB) can accelerate and focus the ion beam into a very small size spot using a lens with a focusing function, so that the ion beam has very high energy and collides with the solid, and sputters and peels off the atomic layer that constitutes the solid. The focused ion beam technology can be used to achieve imaging, etching, thin film deposition, ion beam injection, and preparation of transmission electron microscope samples. Taking focused ion beam etching as an example, a metal film is deposited on the upper and lower layers of the silicon dioxide substrate 2, and the first metal rod 6 and the second metal rod 7 of the first group of metal rods are sequentially etched in the upper layer, and the third metal rod 8 and the fourth metal rod 9 of the second group of metal rods are combined, and the fifth metal rod 10 and the sixth metal rod 11 of the third group of metal rods are combined to form an L-shaped metal unit 4 on the upper layer, and the metal film deposited on the lower layer forms a metal plate 1.

另外,本发明的THz吸收器能够在两个频段内分别实现对右旋圆偏振光与左旋圆偏振光的完美选择性吸收,即实现双波段完美自旋选择吸收。由于沿着OZ轴正方向入射的圆偏振光入射到L型金属单元4时能够引起局域表面的强磁耦合共振效应,并且在共振频率下反射谱表现为共振谷。为了实现THz吸收器对圆偏振光的自旋选择性吸收,将这种THz吸收器设置为L型金属单元4构成的周期性结构。即当RCP和LCP沿+Z方向入射时,入射光首先与上层的L型金属单元4相互作用,其中RCP与L型金属单元4相互作用时,引起最右侧的第二组金属棒组合与第三组金属棒组合之间的强磁耦合共振表现为反射谷,而LCP与L型金属单元4相互作用时,引起最左侧的第一组金属棒组合与第二组金属棒组合之间的强磁耦合共振表现为反射谷,并且由于下层金属板1的存在,入射光不能透过该结构,因此透射率为0,即T=0,又根据吸收与透反射之间的关系A=1-R-T进一步得出A=1-R。结合图4(a)的模拟实验结果得出的反射谱,再根据右旋圆偏振光的吸收公式ARCP=1-rRR 2-rLR 2和左旋圆偏振光的吸收公式ALCP=1-rLL 2-rRL 2计算得出的吸收谱如图4(b)所示,在0.28THz波段RCP被完美吸收,而LCP几乎不被吸收,而在0.35THz波段LCP被完美吸收,RCP几乎不被吸收,从而在0.28THz和0.35THz两个波段实现了对圆偏振光的完美自旋选择吸收。In addition, the THz absorber of the present invention can achieve perfect selective absorption of right-handed circularly polarized light and left-handed circularly polarized light in two frequency bands, that is, dual-band perfect spin selective absorption. Since the circularly polarized light incident along the positive direction of the OZ axis can cause a strong magnetic coupling resonance effect on the local surface when incident on the L-type metal unit 4, and the reflection spectrum shows a resonance valley at the resonance frequency. In order to achieve spin selective absorption of circularly polarized light by the THz absorber, the THz absorber is set as a periodic structure composed of L-type metal units 4. That is, when RCP and LCP are incident along the +Z direction, the incident light first interacts with the upper L-shaped metal unit 4, wherein when RCP interacts with the L-shaped metal unit 4, a strong magnetic coupling resonance is caused between the second group of metal rods and the third group of metal rods on the rightmost side, which manifests as a reflection valley; and when LCP interacts with the L-shaped metal unit 4, a strong magnetic coupling resonance is caused between the first group of metal rods and the second group of metal rods on the leftmost side, which manifests as a reflection valley. Due to the existence of the lower metal plate 1, the incident light cannot penetrate the structure, so the transmittance is 0, that is, T=0, and according to the relationship between absorption and transflection A=1-RT, A=1-R is further derived. Combined with the reflection spectrum obtained from the simulation experimental results of Figure 4(a), the absorption spectrum calculated according to the absorption formula of right-handed circularly polarized light A RCP =1-r RR 2 -r LR 2 and the absorption formula of left-handed circularly polarized light A LCP =1-r LL 2 -r RL 2 is shown in Figure 4(b). In the 0.28 THz band, RCP is perfectly absorbed, while LCP is almost not absorbed, and in the 0.35 THz band, LCP is perfectly absorbed, and RCP is almost not absorbed, thereby achieving perfect spin-selective absorption of circularly polarized light in the two bands of 0.28 THz and 0.35 THz.

为了更好地适用于实际应用,发明人在THz吸收器结构的中间层二氧化硅衬底上方附接了两条平行于X轴的石墨烯片3,通过改变外加电压Vg调控石墨烯的费米能级来调谐自旋选择吸收的效率,结合图5和图6可以看出,随着石墨烯的费米能级从0eV增大到0.8eV,吸收效率峰值从0.99降低到0.7左右,吸收峰频率基本保持不变或变化很小。该发明中THz吸收器的结构设置,不仅实现了对圆偏振光的自旋选择吸收,还能够对自旋选择吸收率进行调谐。该THz吸收器具有制作简单,可调谐,双波段范围,自旋选择吸收效率高,应用场景广泛等优点。In order to better suit practical applications, the inventor attached two graphene sheets 3 parallel to the X-axis above the silicon dioxide substrate in the middle layer of the THz absorber structure, and tuned the efficiency of spin-selective absorption by adjusting the Fermi level of graphene by changing the applied voltage Vg . It can be seen from Figures 5 and 6 that as the Fermi level of graphene increases from 0eV to 0.8eV, the absorption efficiency peak decreases from 0.99 to about 0.7, and the absorption peak frequency remains basically unchanged or changes very little. The structural setting of the THz absorber in this invention not only realizes the spin-selective absorption of circularly polarized light, but also can tune the spin-selective absorption rate. The THz absorber has the advantages of simple manufacture, tunability, dual-band range, high spin-selective absorption efficiency, and a wide range of application scenarios.

本实施例中,为了更好地了解沿+Z方向入射的圆偏振光自旋选择吸收的情况,图7给出了圆二色性值:CD=ARCP-ALCP。结合图7(a),经过计算得出,在0.28THz波段,圆二色性值约为0.85,在0.35THz波段圆二色性值约为-0.86,具有显著的圆二色性。结合图7(b),通过调控石墨烯的费米能级也可以调控圆二色性的值,随着石墨烯的费米能级从0eV增大到0.8eV,圆二色性的绝对值从0.8降低到0.26左右。In this embodiment, in order to better understand the spin-selective absorption of circularly polarized light incident along the +Z direction, FIG. 7 shows the circular dichroism value: CD = A RCP - A LCP . Combined with FIG. 7 (a), it is calculated that in the 0.28THz band, the circular dichroism value is about 0.85, and in the 0.35THz band, the circular dichroism value is about -0.86, which has significant circular dichroism. Combined with FIG. 7 (b), the circular dichroism value can also be adjusted by adjusting the Fermi level of graphene. As the Fermi level of graphene increases from 0eV to 0.8eV, the absolute value of the circular dichroism decreases from 0.8 to about 0.26.

本实施例中,取上层L型金属单元4中的三组金属棒组合沿OX轴方向布置,首先让第一组金属棒组合沿OZ轴逆时针旋转40°,再沿OX轴负方向平移142um;其次让第二组金属棒组合沿OZ轴逆时针旋转40°,再沿OX轴负方向平移105um;最后,让第三组金属棒组合沿OZ轴顺时针方向旋转38°,再沿OX轴正方向平移142um。此时,第二组金属棒组合的第四金属棒和第三组金属棒组合的第五金属棒之间的夹角θ=102°,THz吸收器达到的自旋选择吸收效果是最优的。结合图8可以看出,当改变第三组金属棒组合的旋转角度时,THz吸收器对圆偏振光的自旋选择吸收效果会发生很大的变化,尤其是当夹角θ=92°即第三组金属棒绕OZ轴顺时针旋转48°时,在两个共振波段内都表现出对LCP的强烈吸收,几乎不吸收RCP,当夹角θ=97°时,在0.28THz共振波段处,出现了对RCP和LCP的不同程度的吸收,在0.35THz共振波段,仅出现了对LCP的强烈吸收。当夹角θ从102°变化到112°时,第一个共振波段频率出现了轻微的蓝移,且RCP吸收峰值略微下降,第二个共振波段频率保持不变,且LCP吸收峰值基本保持不变。因此,通过调整第三组金属棒组合绕OZ轴的旋转角度可以在两个共振波段下得到不同的自旋选择吸收效果,能够满足实际应用中对自旋选择吸收的圆偏振光的偏振态要求。In this embodiment, the three groups of metal rods in the upper L-shaped metal unit 4 are arranged along the OX axis. First, the first group of metal rods is rotated 40° counterclockwise along the OZ axis, and then translated 142um along the negative direction of the OX axis; secondly, the second group of metal rods is rotated 40° counterclockwise along the OZ axis, and then translated 105um along the negative direction of the OX axis; finally, the third group of metal rods is rotated 38° clockwise along the OZ axis, and then translated 142um along the positive direction of the OX axis. At this time, the angle θ between the fourth metal rod of the second group of metal rods and the fifth metal rod of the third group of metal rods is 102°, and the spin selective absorption effect achieved by the THz absorber is optimal. Combined with Figure 8, it can be seen that when the rotation angle of the third group of metal rods is changed, the spin-selective absorption effect of the THz absorber on circularly polarized light will change greatly, especially when the angle θ=92°, that is, when the third group of metal rods rotates 48° clockwise around the OZ axis, it shows strong absorption of LCP in both resonance bands, and almost no absorption of RCP. When the angle θ=97°, at the 0.28THz resonance band, different degrees of absorption of RCP and LCP appear, and at the 0.35THz resonance band, only strong absorption of LCP appears. When the angle θ changes from 102° to 112°, the frequency of the first resonance band has a slight blue shift, and the RCP absorption peak decreases slightly, while the frequency of the second resonance band remains unchanged, and the LCP absorption peak remains basically unchanged. Therefore, by adjusting the rotation angle of the third group of metal rods around the OZ axis, different spin-selective absorption effects can be obtained in the two resonance bands, which can meet the polarization state requirements of circularly polarized light for spin-selective absorption in practical applications.

因此,本发明采用上述一种能够实现双波段自旋选择吸收的可调谐THz吸收器,具有制作简单,可调谐,双波段范围,自旋选择吸收效率高,应用场景广泛等优点。Therefore, the present invention adopts the above-mentioned tunable THz absorber capable of realizing dual-band spin-selective absorption, which has the advantages of simple manufacture, tunability, dual-band range, high spin-selective absorption efficiency, and wide application scenarios.

最后应说明的是:以上实施例仅用以说明本发明的技术方案而非对其进行限制,尽管参照较佳实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对本发明的技术方案进行修改或者等同替换,而这些修改或者等同替换亦不能使修改后的技术方案脱离本发明技术方案的精神和范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention rather than to limit it. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that they can still modify or replace the technical solution of the present invention with equivalents, and these modifications or equivalent replacements cannot cause the modified technical solution to deviate from the spirit and scope of the technical solution of the present invention.

Claims (9)

1. The tunable THz absorber capable of realizing dual-band spin selective absorption consists of a plurality of structural units which are periodically arranged on an XY plane, wherein the geometric center of the structural units is taken as an O point, two sides which are perpendicular to each other and pass through the O point along the horizontal direction and the vertical direction are taken as an OX axis and an OY axis, and the two sides which are perpendicular to the O point are taken as the OZ axis, and the tunable THz absorber is characterized in that: each structural unit consists of a lower metal plate (1), an intermediate substrate layer (2), two graphene sheets (3) attached to the intermediate substrate layer and an upper L-shaped metal unit (4).
2. A tunable THz absorber capable of dual band spin selective absorption according to claim 1, wherein: electrodes (5) connected with two ends of the graphene sheet (3) are attached to two sides of the structural unit.
3. A tunable THz absorber capable of dual band spin selective absorption according to claim 1, wherein: the L-shaped metal unit (4) is formed by combining three groups of metal rods distributed along the OX axis direction, wherein the lengths of the three groups of metal rods are different, but the thickness and the width are the same;
the first group of metal rod combinations consists of a first metal rod (6) and a second metal rod (7), the second group of metal rod combinations consists of a third metal rod (8) and a fourth metal rod (9), and the third group of metal rod combinations consists of a fifth metal rod (10) and a sixth metal rod (11); the metal bars in each group of metal bar combinations are mutually perpendicular, the rotation angles of the first group of metal bar combinations and the second group of metal bar combinations around the OZ axis are consistent, and the rotation angles of the third group of metal bar combinations and the first group of metal bar combinations and the second group of metal bar combinations around the OZ axis are inconsistent; and the included angle between a fourth metal rod (9) in the second group of metal rod combinations and a fifth metal rod (10) in the third group of metal rod combinations of the L-shaped metal units (4) is marked as theta.
4. A tunable THz absorber capable of dual band spin selective absorption according to claim 3, wherein: the adjustment range of the included angle theta is 92-112 degrees.
5. A tunable THz absorber capable of dual band spin selective absorption according to claim 4, wherein: the angle θ=102° optimal for the spin-selective absorption of circularly polarized light.
6. A tunable THz absorber capable of dual band spin selective absorption according to claim 3, wherein: the length and the width of the metal plate (1) and the middle substrate layer (2) are p respectively x =p y =310 um, the thickness t=18 um of the metal plate (1), the thickness d=75 um of the intermediate substrate layer (2), the width w=12 um of the L-shaped metal unit (4), and the thickness h=18 um; wherein the length L of the first metal bar (6) in the first group of metal bar combinations 1 Length L of the second metal rod (7) =185 um 2 Length L of the third metal bar (8) in the second group of metal bar combinations =149 um 3 Length L of the fourth metal bar (9) =155 um 4 =157 um, length L of the fifth metal bar (10) in the third group of metal bar combinations 5 Length L of the sixth metal bar (11) =147 um 6 The first group of metal bar combinations and the second group of metal bar combinations have a distance m=37um, and the width w of the two graphene sheets is equal to 170um g =5 um, and the spacing between them b=35 um.
7. A tunable THz absorber capable of dual band spin selective absorption according to claim 1, wherein: the intermediate substrate layer (2) is a silicon dioxide substrate.
8. A tunable THz absorber capable of dual band spin selective absorption according to claim 1, wherein: the L-shaped metal units (4) and the metal plates (1) are made of gold materials.
9. A tunable THz absorber capable of dual band spin selective absorption according to claim 1, wherein: the structural unit has chiral characteristics.
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