CN117534199A - Biological retention filler, preparation method thereof and biological retention facility - Google Patents
Biological retention filler, preparation method thereof and biological retention facility Download PDFInfo
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- CN117534199A CN117534199A CN202410029925.2A CN202410029925A CN117534199A CN 117534199 A CN117534199 A CN 117534199A CN 202410029925 A CN202410029925 A CN 202410029925A CN 117534199 A CN117534199 A CN 117534199A
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- 239000000945 filler Substances 0.000 title claims abstract description 23
- 230000014759 maintenance of location Effects 0.000 title claims abstract description 7
- 238000002360 preparation method Methods 0.000 title abstract description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 77
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 59
- 239000010457 zeolite Substances 0.000 claims abstract description 59
- 238000009301 bioretention Methods 0.000 claims abstract description 50
- 241000894006 Bacteria Species 0.000 claims abstract description 45
- 230000001546 nitrifying effect Effects 0.000 claims abstract description 45
- 239000004927 clay Substances 0.000 claims abstract description 35
- 239000002689 soil Substances 0.000 claims abstract description 33
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000011159 matrix material Substances 0.000 claims abstract description 29
- 239000004746 geotextile Substances 0.000 claims abstract description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 10
- 239000010802 sludge Substances 0.000 claims abstract description 10
- 239000011780 sodium chloride Substances 0.000 claims abstract description 5
- 238000002791 soaking Methods 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 69
- 238000000034 method Methods 0.000 claims description 24
- 238000011081 inoculation Methods 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 8
- 229910001415 sodium ion Inorganic materials 0.000 claims description 7
- 230000007246 mechanism Effects 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000010304 firing Methods 0.000 claims 1
- 239000001301 oxygen Substances 0.000 abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 8
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 abstract description 6
- 238000001354 calcination Methods 0.000 abstract description 4
- 239000000243 solution Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 239000003344 environmental pollutant Substances 0.000 description 7
- 231100000719 pollutant Toxicity 0.000 description 7
- 230000004308 accommodation Effects 0.000 description 6
- 238000005342 ion exchange Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000005416 organic matter Substances 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 244000005700 microbiome Species 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 235000015097 nutrients Nutrition 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 241001148470 aerobic bacillus Species 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 230000001146 hypoxic effect Effects 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 230000033001 locomotion Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000002255 vaccination Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/10—Packings; Fillings; Grids
- C02F3/105—Characterized by the chemical composition
- C02F3/107—Inorganic materials, e.g. sand, silicates
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
- C02F3/2806—Anaerobic processes using solid supports for microorganisms
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/001—Runoff or storm water
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Biological Treatment Of Waste Water (AREA)
Abstract
Description
技术领域Technical field
本发明属于雨水处理技术领域,尤其与一种生物滞留填料及其制备方法、生物滞留设施有关。The invention belongs to the technical field of rainwater treatment, and is particularly related to a bioretention filler, a preparation method thereof, and bioretention facilities.
背景技术Background technique
城市降雨径流脱氮已逐渐成为重要的研究方向,硝化效率低是制约其处理效果的难点问题。随着城市污水处理设施革新及管理水平的升级,点源污染得到了有效控制,以降雨径流污染为代表的面源污染治理成为了城市水环境污染治理的重要方向。以生物滞留设施为代表的径流处理设施多数具有去除悬浮性污染物的功能,但对于氮的去除效果不佳。雨水径流中的氮主要以氨氮(约50%)和硝态氮为主,提高硝化效能是进一步提升总氮去除率的难点问题之一。该问题的主要原因是:生物滞留设施中无氧气补充措施,径流进入设施时,携带的氧气因好氧菌的呼吸代谢作用不断消耗,设施内部逐渐进入低溶解氧状态,传统的两步硝化菌群是严格好氧型微生物,在低溶解氧环境中硝化途径受阻,而好氧段的氧气量难以满足所有氨氮被硝化去除的需要,导致设施硝化效率进一步提升难度大。Nitrogen removal from urban rainfall runoff has gradually become an important research direction, and low nitrification efficiency is a difficult issue that restricts its treatment effect. With the innovation of urban sewage treatment facilities and the upgrading of management levels, point source pollution has been effectively controlled. Non-point source pollution control represented by rainfall runoff pollution has become an important direction in urban water environment pollution control. Most runoff treatment facilities, represented by bioretention facilities, have the function of removing suspended pollutants, but they are not effective in removing nitrogen. The nitrogen in rainwater runoff is mainly ammonia nitrogen (about 50%) and nitrate nitrogen. Improving nitrification efficiency is one of the difficult issues to further increase the total nitrogen removal rate. The main reason for this problem is: there is no oxygen supplementation measure in the bioretention facility. When the runoff enters the facility, the oxygen carried is continuously consumed due to the respiratory metabolism of aerobic bacteria, and the interior of the facility gradually enters a low dissolved oxygen state. Traditional two-step nitrifying bacteria The group is a strictly aerobic microorganism, and the nitrification pathway is blocked in a low dissolved oxygen environment. The amount of oxygen in the aerobic section cannot meet the needs of all ammonia nitrogen to be removed by nitrification, making it difficult to further improve the nitrification efficiency of the facility.
发明内容Contents of the invention
为了解决上述现有技术缺陷,本申请提供一种生物滞留填料及其制备方法、生物滞留设施,使得生物滞留设施在低氧环境下仍可将雨水中残留的氨氮转化为硝态氮,进而改善传统生物滞留设施脱氮效果不佳问题。In order to solve the above-mentioned deficiencies in the prior art, this application provides a bioretention filler, a preparation method thereof, and a bioretention facility, so that the bioretention facility can still convert residual ammonia nitrogen in rainwater into nitrate nitrogen in a low-oxygen environment, thereby improving The problem of poor nitrogen removal in traditional bioretention facilities.
为了实现上述目的,本发明采用以下技术:In order to achieve the above objects, the present invention adopts the following technologies:
生物滞留填料,其特征在于,包括:Bioretention filler is characterized by including:
沸石、粘土,应用时,粘土铺设于生物滞留设施的砾石层上方,且粘土内混合有有机物,应用时,沸石铺设于粘土的上方,沸石、粘土中均接种有全程硝化细菌,用于在缺氧环境下去除雨水中的氨氮,其中,沸石选择经过热处理和Na离子交换的改性沸石。Zeolite and clay. When used, the clay is laid on top of the gravel layer of the bioretention facility, and the clay is mixed with organic matter. When used, the zeolite is laid on top of the clay. The zeolite and clay are inoculated with full-scale nitrifying bacteria for use in deficiencies. To remove ammonia nitrogen from rainwater in an oxygen environment, the zeolite is modified zeolite that has undergone heat treatment and Na ion exchange.
生物滞留填料制备方法,用于制备上述的生物滞留填料,包括步骤:Bioretention filler preparation method, used to prepare the above-mentioned bioretention filler, includes the steps:
S100、将沸石进行焙烧;S100. Roast the zeolite;
S200、将焙烧后的沸石置于NaCl溶液中进行浸泡后,再将沸石进行干燥处理,得到改性沸石;S200. After soaking the roasted zeolite in a NaCl solution, the zeolite is dried to obtain modified zeolite;
S300、通过污泥富集全程硝化细菌;S300, enrich the whole process of nitrifying bacteria through sludge;
S400、将改性沸石进行全程硝化细菌接种;S400, inoculate the modified zeolite with nitrifying bacteria throughout the entire process;
S500、将粘土和有机物混合后进行全程硝化细菌接种。S500. Mix clay and organic matter and inoculate the entire process with nitrifying bacteria.
进一步的,步骤S200中的焙烧温度为500°C-550°C。Further, the calcination temperature in step S200 is 500°C-550°C.
进一步的,步骤S400、S500中,接种全程硝化细菌时,先将富集好全程硝化细菌的污泥用清水稀释到3000mg/L以上,再将其分多次淋入沸石和粘土。Further, in steps S400 and S500, when inoculating full-stage nitrifying bacteria, first dilute the sludge enriched with full-stage nitrifying bacteria with clean water to more than 3000 mg/L, and then pour it into zeolite and clay in multiple batches.
一种生物滞留设施,包括:A bioretention facility consisting of:
基质层,包括上述的生物滞留设施填料;The matrix layer, including the bioretention facility fill mentioned above;
砾石层,铺设于基质层下方,且砾石层与基质层通过第一透水土工布隔开;A gravel layer is laid below the matrix layer, and the gravel layer and the matrix layer are separated by a first permeable geotextile;
植土层,铺设于基质层上方,植土层和基质层之间通过第二透水土工布隔开;The planting soil layer is laid above the matrix layer, and the planting soil layer and the matrix layer are separated by a second permeable geotextile;
第三透水土工布,设于砾石层底部,并包覆砾石层、基质层、植土层的四周。The third permeable geotextile is located at the bottom of the gravel layer and covers the gravel layer, matrix layer, and planting soil layer.
进一步的,该设施还包括L型壳体,L型壳体内具有容置腔,容置腔内间隔设有多个L型支撑肋条,L型壳体的水平段设有多个竖向的通孔,且水平段设于粘土和沸石之间,L型壳体的竖向段设于第三透水土工布内,且设于植土层和沸石的一侧,且竖向段的顶部具有开口,竖向段延伸出植土层顶部。Further, the facility also includes an L-shaped shell, which has a receiving cavity. Multiple L-shaped supporting ribs are provided at intervals in the receiving cavity. The horizontal section of the L-shaped shell is provided with multiple vertical passages. hole, and the horizontal section is located between the clay and zeolite, the vertical section of the L-shaped shell is located in the third permeable geotextile, and is located on one side of the planting soil layer and zeolite, and the top of the vertical section has an opening , the vertical section extends out of the top of the planting soil layer.
进一步的,通孔的直径设置为小于沸石的粒径,用于防止沸石落入容置腔内。Further, the diameter of the through hole is set smaller than the particle size of the zeolite to prevent the zeolite from falling into the accommodation cavity.
进一步的,植土层顶部的两侧均设有一段轨道,轨道上方设有接种车,接种车包括两对轨道车轮和水箱,两对轨道车轮均转动连接于水箱的底部,轨道车轮通过固定于水箱的一个驱动机构驱动,且两对轨道车轮均卡设于轨道上,水箱底部设有第一出水管和第二出水管,第一出水管的出水口朝向竖向段的开口设置,第二出水管长度方向与轨道车轮的轴向相同,第二出水管底部开设有多个出水孔,且第一出水管、第二出水管的进水端均接入水箱内,并与一个电动阀连接。Further, a section of track is provided on both sides of the top of the planting soil layer, and an inoculation vehicle is provided above the track. The inoculation vehicle includes two pairs of rail wheels and a water tank. Both pairs of rail wheels are rotatably connected to the bottom of the water tank. The rail wheels are fixed on The water tank is driven by a driving mechanism, and two pairs of rail wheels are clamped on the track. A first water outlet pipe and a second water outlet pipe are provided at the bottom of the water tank. The water outlet of the first water outlet pipe is set toward the opening of the vertical section, and the second water outlet pipe is provided at the bottom of the water tank. The length direction of the water outlet pipe is the same as the axial direction of the rail wheel. There are multiple water outlet holes at the bottom of the second water outlet pipe. The water inlets of the first water outlet pipe and the second water outlet pipe are connected to the water tank and connected to an electric valve. .
进一步的,还包括溢流管,溢流管的顶部高出植土层预定高度,溢流管底部延伸至砾石层内与下水管道连接。Further, it also includes an overflow pipe, the top of the overflow pipe is higher than a predetermined height of the planting soil layer, and the bottom of the overflow pipe extends into the gravel layer and is connected to the sewer pipe.
本发明有益效果在于:The beneficial effects of the present invention are:
1、填料层选择的沸石氨氮的吸附量可达13.4 mg /g以上,能够有效吸附从植土层流下的雨水中的氨氮,且通过接种的全程硝化细菌在缺氧、富氧环境下均可将从植土层流下的雨水中的氨氮,以及沸石中吸附的氨氮转化为硝态氮,被微生物分解利用,防止沸石中吸附的氨氮达到饱和,且填料层选择经过热处理和Na离子交换的改性沸石,能够进一步提高沸石对氨氮的吸附和去除,提高雨水脱氮效果。1. The ammonia nitrogen adsorption capacity of the zeolite selected for the filler layer can reach more than 13.4 mg/g, which can effectively absorb ammonia nitrogen in rainwater flowing down from the planting soil layer, and the full-process nitrifying bacteria inoculated can operate in both hypoxic and oxygen-rich environments. The ammonia nitrogen in the rainwater flowing down from the planting soil layer and the ammonia nitrogen adsorbed in the zeolite are converted into nitrate nitrogen, which is decomposed and utilized by microorganisms to prevent the ammonia nitrogen adsorbed in the zeolite from reaching saturation. The filler layer is modified by heat treatment and Na ion exchange. It can further improve the adsorption and removal of ammonia nitrogen by zeolite and improve the denitrification effect of rainwater.
2、通过设置L型壳体,在生物滞留设施修建完成后,可从L型壳体顶部注入全程硝化细菌富集液,使全程硝化细菌富集液到达沸石和粘土之间,便于在后续生物滞留设施内全程硝化细菌减少的情况下,直接通过L型壳体向生物滞留设施内添加硝化细菌富集液,提高粘土层的接种效果。2. By setting up an L-shaped shell, after the construction of the bioretention facility is completed, the full-process nitrifying bacteria enrichment solution can be injected from the top of the L-shaped shell, so that the full-process nitrifying bacteria enrichment solution reaches between the zeolite and clay, which facilitates subsequent biological processes. When the nitrifying bacteria in the retention facility are reduced throughout the process, the nitrifying bacteria enrichment solution is directly added to the bioretention facility through the L-shaped shell to improve the inoculation effect of the clay layer.
3、植土层顶部的轨道、接种车的设置,结合L型壳体可以同时从植土层上方和基质层的粘土上方同时注入全程硝化细菌富集液,提高接种效率,以及接种的均匀性。3. The track on the top of the planting soil layer and the setting of the inoculation vehicle, combined with the L-shaped shell, can simultaneously inject the full-process nitrifying bacteria enrichment solution from above the planting soil layer and above the clay of the matrix layer, improving the inoculation efficiency and uniformity of inoculation. .
附图说明Description of drawings
图1为本申请实施例的生物滞留设施的整体结构立体图。Figure 1 is a perspective view of the overall structure of the bioretention facility according to the embodiment of the present application.
图2为本申请实施例的生物滞留设施的剖视图。Figure 2 is a cross-sectional view of a bioretention facility according to an embodiment of the present application.
图3为图2中A部放大视图。Figure 3 is an enlarged view of part A in Figure 2.
图4为本申请实施例的生物滞留设施的俯视图。Figure 4 is a top view of the bioretention facility according to the embodiment of the present application.
图5为图4中C部放大视图。Figure 5 is an enlarged view of part C in Figure 4.
图6为申请实施例的生物滞留设施中接种车的结构立体图。Figure 6 is a structural perspective view of the vaccination vehicle in the bioretention facility according to the application embodiment.
图7为图6中B部放大视图。Figure 7 is an enlarged view of part B in Figure 6.
附图标记:植土层-1,基质层-2,砾石层-3,第一透水土工布-4,第二透水土工布-5,第三透水土工布-6,L型壳体-7,轨道-8,轨道车轮-9,水箱-10,溢流管-11,沸石-201,粘土-202,L型支撑肋条-701,水平段-702,竖向段-703,开口-704,第一出水管-1001,第二出水管-1002,出水孔-1003。Reference signs: planting soil layer-1, matrix layer-2, gravel layer-3, first permeable geotextile-4, second permeable geotextile-5, third permeable geotextile-6, L-shaped shell-7 , track-8, track wheel-9, water tank-10, overflow pipe-11, zeolite-201, clay-202, L-shaped support rib-701, horizontal section-702, vertical section-703, opening-704, The first water outlet pipe-1001, the second water outlet pipe-1002, the water outlet hole-1003.
具体实施方式Detailed ways
为使本发明实施例的目的、技术方案和优点更加清楚,下面结合附图对本发明的实施方式进行详细说明,但本发明所描述的实施例是本发明一部分实施例,而不是全部的实施例。In order to make the purpose, technical solutions and advantages of the embodiments of the present invention clearer, the embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings. However, the described embodiments of the present invention are part of the embodiments of the present invention, not all of them. .
本申请实施例提供一种生物滞留填料,包括沸石201、粘土202,应用时,粘土202铺设于生物滞留设施的砾石层3上方,且粘土202内混合有有机物,作为营养物质供微生物生长,应用时,沸石201铺设于粘土202的上方,沸石201、粘土202中均接种有全程硝化细菌,用于在缺氧环境下去除雨水中的氨氮。The embodiment of the present application provides a bioretention filler, including zeolite 201 and clay 202. When used, the clay 202 is laid above the gravel layer 3 of the bioretention facility, and organic matter is mixed in the clay 202 as nutrients for the growth of microorganisms. Application At this time, zeolite 201 is laid on top of clay 202, and both zeolite 201 and clay 202 are inoculated with full-process nitrifying bacteria to remove ammonia nitrogen in rainwater in an anoxic environment.
因为沸石201具有多规律孔穴结构,其孔穴与一般物质的分子大小相当,直径约在0.3nm~1nm之间,其比表面积高达400m2/g~800m2/g,特殊的物理结构使沸石具有高效吸附性,能够有效吸附流经的雨水中的氨氮,同时,在缺氧、富氧环境下,被吸附的氨氮均会被沸石上接种的全程硝化细菌转化为硝态氮,后续再被微生物分解利用,可防止沸石201中吸附的氨氮达到饱和。Because zeolite 201 has a polyregular pore structure, its pores are about the same size as the molecules of ordinary substances, with diameters ranging from about 0.3nm to 1nm, and its specific surface area is as high as 400m 2 /g ~ 800m 2 /g. The special physical structure gives zeolite Highly efficient adsorption, it can effectively adsorb ammonia nitrogen in flowing rainwater. At the same time, in anoxic and oxygen-rich environments, the adsorbed ammonia nitrogen will be converted into nitrate nitrogen by the full-process nitrifying bacteria inoculated on the zeolite, and then be converted into nitrate nitrogen by microorganisms. Decomposition and utilization can prevent the ammonia nitrogen adsorbed in zeolite 201 from reaching saturation.
优选的,选择的沸石201为经过热处理和Na离子交换的改性沸石。沸石201经过热处理后,沸石201中的水逸去,形成疏松多孔的海绵体,可使吸附性能有效提高,沸石201经过Na离子交换后,得到更多的Na离子,能够进一步提高氨氮吸附效果。Preferably, the selected zeolite 201 is a modified zeolite that has undergone heat treatment and Na ion exchange. After zeolite 201 is heat treated, the water in zeolite 201 escapes to form a loose and porous sponge, which can effectively improve the adsorption performance. After zeolite 201 undergoes Na ion exchange, more Na ions are obtained, which can further improve the ammonia nitrogen adsorption effect.
填料的制备采用一种生物滞留填料制备方法,具体步骤为:将沸石201在进行焙烧;将焙烧后的沸石201置于NaCl溶液中进行浸泡后,再将沸石201进行干燥处理,得到改性沸石;通过污泥富集全程硝化细菌;将改性沸石进行全程硝化细菌接种;将粘土202和有机物混合后进行全程硝化细菌接种。The filler is prepared using a bioretention filler preparation method. The specific steps are: roasting zeolite 201; soaking the roasted zeolite 201 in a NaCl solution, and then drying the zeolite 201 to obtain modified zeolite ; Enrich nitrifying bacteria through sludge; inoculate modified zeolite with nitrifying bacteria; mix clay 202 with organic matter and inoculate nitrifying bacteria throughout the process.
具体的,富集全程硝化细菌方法为:先在5L连续流SBR反应器内种接种污水处理厂好氧段污泥1L,在不排水的情况下,连续缓慢输进不高于50mgN/L氨氮浓度的待处理水样。其中,反应器典型进水组成如下:每升含有26.745mg NH4Cl,50mg KH2PO4,75mg KCl,50mgMgSO4·7H2O,584mg NaCl,50mg CaCl2,1mL微量元素溶液。每升微量元素溶液组成如下:34.4mg MnSO4·1H2O,50mg H3BO3,70mg ZnCl2,72.6mg Na2MoO4·2H2O,2mg CuCl2·2H2O,24mg NiCl2·6H2O,80mg CoCl2·6H2O,1gFeSO4·6H2O。然后控制溶解氧浓度低于1.0mg/L,每个循环进水8h,进水速率为1.45mL/min;沉淀45min,以速率29mL/min出水,再闲置一定时间。最后定期监测反应器内氨氮浓度,当出水氨氮浓度低于0.05mgN/L时,即完成富集。Specifically, the method for enriching nitrifying bacteria throughout the process is: first inoculate 1L of sludge from the aerobic section of the sewage treatment plant in a 5L continuous flow SBR reactor, and continuously and slowly input no more than 50 mgN/L ammonia nitrogen without drainage. concentration of the water sample to be treated. Among them, the typical feed water composition of the reactor is as follows: each liter contains 26.745mg NH 4 Cl, 50mg KH 2 PO 4 , 75mg KCl, 50mgMgSO 4 ·7H 2 O, 584mg NaCl, 50mg CaCl 2 and 1mL trace element solution. The composition of trace element solution per liter is as follows: 34.4mg MnSO 4 ·1H 2 O, 50mg H 3 BO 3 , 70mg ZnCl 2 , 72.6mg Na 2 MoO 4 ·2H 2 O, 2mg CuCl 2 ·2H 2 O, 24mg NiCl 2 · 6H 2 O, 80 mg CoCl 2 ·6H 2 O, 1gFeSO 4 ·6H 2 O. Then control the dissolved oxygen concentration to be lower than 1.0mg/L, inject water for 8 hours in each cycle, and the water inlet rate is 1.45mL/min; precipitate for 45min, discharge water at a rate of 29mL/min, and then idle for a certain period of time. Finally, the ammonia nitrogen concentration in the reactor is regularly monitored. When the ammonia nitrogen concentration of the effluent is lower than 0.05mgN/L, the enrichment is completed.
具体的,焙烧沸石201时,设置焙烧温度为500℃-550℃。因为沸石201具有耐高温特性,但温度太高会破坏其结构使其失去离子交换功能。本实施例在500℃~550℃温度下对沸石201进行焙烧,可提高沸石201机械强度又可加大孔容,增加比表面积,还可增加阳离子的运动活性,使后续Na离子交换进行更充分。Specifically, when calcining zeolite 201, set the calcining temperature to 500°C-550°C. Zeolite 201 has high temperature resistance, but if the temperature is too high, its structure will be destroyed and it will lose its ion exchange function. In this embodiment, zeolite 201 is roasted at a temperature of 500°C to 550°C, which can improve the mechanical strength of zeolite 201, increase the pore volume, increase the specific surface area, and increase the movement activity of cations, so that subsequent Na ion exchange can be carried out more fully. .
具体的,接种全程硝化细菌时,先将富集好全程硝化细菌的污泥用清水稀释到3000mg/L以上,再将其分多次淋入沸石201和粘土202,可使全程硝化细菌随着清水逐步渗入沸石201和粘土202。Specifically, when inoculating full-stage nitrifying bacteria, first dilute the sludge enriched with full-stage nitrifying bacteria with clean water to above 3000 mg/L, and then pour it into zeolite 201 and clay 202 in multiple batches, so that the full-stage nitrifying bacteria can follow the inoculation. The clean water gradually penetrates into the zeolite 201 and clay 202.
另一方面,如图1-图7所示,本申请提供一种生物滞留设施,包括基质层2、砾石层3、植土层1等。On the other hand, as shown in Figures 1 to 7, this application provides a bioretention facility, including a matrix layer 2, a gravel layer 3, a planting soil layer 1, etc.
具体的,参阅图1、图2,基质层2包括上述的生物滞留填料,其中的粘土202铺设于生物滞留设施的砾石层3上方,沸石201铺设于粘土202及有机物的上方,砾石层3铺设于基质层2下方,且砾石层3与基质层2通过第一透水土工布4隔开,植土层1铺设于基质层2上方,植土层1和基质层2之间通过第二透水土工布5隔开,砾石层3底部设有第三透水土工布6,且第三透水土工布6包覆砾石层3、基质层2、植土层1的四周。Specifically, referring to Figures 1 and 2, the matrix layer 2 includes the above-mentioned bioretention filler, in which clay 202 is laid above the gravel layer 3 of the bioretention facility, zeolite 201 is laid above the clay 202 and organic matter, and the gravel layer 3 is laid Below the matrix layer 2, and the gravel layer 3 and the matrix layer 2 are separated by the first permeable geotextile 4, the planting soil layer 1 is laid above the matrix layer 2, and the planting soil layer 1 and the matrix layer 2 are separated by the second permeable geotextile. Separated by cloth 5 , a third permeable geotextile 6 is provided at the bottom of the gravel layer 3 , and the third permeable geotextile 6 covers the gravel layer 3 , the matrix layer 2 , and the planting soil layer 1 .
雨水流入该生物滞留设施时,先经过最顶层的植土层1进行初步过滤后,向下渗透进入基质层2内,基质层2内接种有全程硝化细菌的沸石201、粘土202会将雨水中的氨氮吸附、转化、分解,实现对雨水的脱氮,后续雨水继续往下流入砾石层3后排入下水管道。When rainwater flows into the bioretention facility, it first passes through the topmost soil layer 1 for preliminary filtration, and then penetrates downward into the matrix layer 2. Zeolite 201 and clay 202 inoculated with full-scale nitrifying bacteria in the matrix layer 2 will remove the rainwater. The ammonia nitrogen adsorbs, transforms and decomposes to achieve denitrification of rainwater, and subsequent rainwater continues to flow downward into the gravel layer 3 and then is discharged into the sewer pipe.
具体的,参阅图1、图4,该生物滞留设施还包括溢流管11,溢流管11的顶部高出植土层1预定高度,溢流管11底部延伸至砾石层3内与下水管道连接,当降雨量过多,生物滞留设施内超出最大蓄水高度时,过多的雨水可从溢流管11直接流入下水管道,防止路面被雨水淹没。Specifically, referring to Figures 1 and 4, the bioretention facility also includes an overflow pipe 11. The top of the overflow pipe 11 is higher than a predetermined height of the planting soil layer 1, and the bottom of the overflow pipe 11 extends into the gravel layer 3 and the sewer pipe. connection, when there is too much rainfall and the maximum water storage height is exceeded in the bioretention facility, the excess rainwater can directly flow into the sewer pipe from the overflow pipe 11 to prevent the road surface from being flooded by rainwater.
优选的,参阅图1-图2、图4-图5,该生物滞留设施还包括L型壳体7,L型壳体7内具有容置腔,容置腔内间隔设有多个L型支撑肋条701,L型支撑肋条701可用于支撑L型壳体7,防止上方的沸石201下压导致L型壳体7变形,水平段702的顶部和底部均设有多个通孔,具体的,通孔的直径设置为小于沸石201的粒径,用于防止沸石201落入容置腔内,且水平段702设于基质层2的粘土202和沸石201之间,L型壳体7的竖向段703设于第三透水土工布6内,且设于植土层1和沸石201的一侧,且竖向段703的顶部具有开口704,竖向段延伸出植土层1顶部,因为L型支撑肋条701可将容置腔分隔为多个L型的容置空间,从L型壳体7顶部注入全程硝化细菌的富集液后,接种液会被分隔于多个L型的容置空间,形成具有一定高度的水柱,缓慢的从的通孔向下流入粘土202。Preferably, referring to Figures 1-2 and 4-5, the bioretention facility also includes an L-shaped housing 7. The L-shaped housing 7 has a receiving chamber, and multiple L-shaped chambers are spaced in the receiving chamber. Support ribs 701, L-shaped support ribs 701 can be used to support the L-shaped shell 7 to prevent the zeolite 201 above from deforming the L-shaped shell 7 due to downward pressure. The top and bottom of the horizontal section 702 are provided with multiple through holes. Specifically, , the diameter of the through hole is set to be smaller than the particle size of the zeolite 201 to prevent the zeolite 201 from falling into the accommodation cavity, and the horizontal section 702 is provided between the clay 202 and the zeolite 201 of the matrix layer 2, and the L-shaped shell 7 The vertical section 703 is provided in the third water-permeable geotextile 6 and is provided on one side of the planting soil layer 1 and the zeolite 201. The top of the vertical section 703 has an opening 704, and the vertical section extends out of the top of the planting soil layer 1. Because the L-shaped support ribs 701 can divide the accommodation cavity into multiple L-shaped accommodation spaces, after injecting the full-process nitrifying bacteria enrichment solution from the top of the L-shaped housing 7, the inoculum solution will be divided into multiple L-shaped accommodation spaces. The accommodation space forms a water column with a certain height, which slowly flows downward into the clay 202 from the through hole.
接种全程硝化细菌的填料层在使用一段时间后,由于环境原因(例如生物滞留设施中营养物质减少,或者因为降雨较少,流入生物滞留设施内氨氮减少),其内的全程硝化细菌繁殖减缓,导致全程硝化细菌减少,此时需要再次接种全程硝化细菌提高雨水氨氮去除效果,较为直接的方式是直接从植土层1上方淋入全程硝化细菌的富集液,该种方式会使大部的带有全程硝化细菌的污泥粘附于植土层1和沸石201上,而粘土202内接种到的全程硝化细菌较少。设置L型壳体7后,可使全程硝化细菌的富集液直接通过L型壳体7的空腔均匀的流入粘土202内,提高接种的均匀性,提高雨水中氨氮的去除效果。After the filler layer inoculated with full-stage nitrifying bacteria is used for a period of time, due to environmental reasons (such as the reduction of nutrients in the bioretention facility, or the decrease in ammonia nitrogen flowing into the bioretention facility due to less rainfall), the reproduction of full-stage nitrifying bacteria in it slows down. As a result, the total nitrifying bacteria are reduced. At this time, it is necessary to inoculate the full-process nitrifying bacteria again to improve the ammonia nitrogen removal effect of rainwater. The more direct way is to directly pour the enriched solution of the full-process nitrifying bacteria from above the planting soil layer 1. This method will make most of the The sludge with full-stage nitrifying bacteria adheres to the planting soil layer 1 and zeolite 201, while the clay 202 is inoculated with less full-stage nitrifying bacteria. After the L-shaped shell 7 is installed, the enriched liquid of the whole-process nitrifying bacteria can flow directly into the clay 202 evenly through the cavity of the L-shaped shell 7, thereby improving the uniformity of inoculation and improving the removal effect of ammonia nitrogen in rainwater.
优选的,参阅图1、图2、图6、图7,植土层1顶部的两侧均设有一段轨道8,轨道8上方设有接种车,接种车包括两对轨道车轮9和水箱10,两对轨道车轮9均转动连接于水箱10底部,轨道车轮9通过固定于水箱10的一个驱动机构驱动,具体的,驱动机构可选择电机,两对轨道车轮9均卡设于轨道8上,水箱10底部设有第一出水管1001和第二出水管1002,第一出水管1001的出水口朝向竖向段703的开口704设置,第二出水管1002长度方向与轨道车轮9的轴向相同,第二出水管1002底部开设有多个出水孔1003,且第一出水管1001、第二出水管1002的进水端均接入水箱10内,并与一个电动阀连接。当需要在生物滞留设施内补充接种全程硝化细菌时,在水箱10内注入稀释得到的全程硝化细菌富集液,然后打开电动阀,同时控制驱动机构带动轨道车轮9转动即可将全程硝化细菌富集液同时注入植土层1上方,以及L型壳体7内,可有效提高接种效率,接种完成后,可通过防水布、防水胶条等方式材料盖住L型壳体7顶部,防止雨水从顶部流入其中即可。Preferably, referring to Figures 1, 2, 6, and 7, a section of track 8 is provided on both sides of the top of the planting soil layer 1, and an inoculation vehicle is provided above the track 8. The inoculation vehicle includes two pairs of rail wheels 9 and a water tank 10. , both pairs of rail wheels 9 are rotatably connected to the bottom of the water tank 10, and the rail wheels 9 are driven by a driving mechanism fixed to the water tank 10. Specifically, the driving mechanism can select a motor, and both pairs of rail wheels 9 are stuck on the track 8. A first water outlet pipe 1001 and a second water outlet pipe 1002 are provided at the bottom of the water tank 10. The water outlet of the first water outlet pipe 1001 is arranged toward the opening 704 of the vertical section 703. The length direction of the second water outlet pipe 1002 is the same as the axial direction of the rail wheel 9. , a plurality of water outlets 1003 are provided at the bottom of the second water outlet pipe 1002, and the water inlet ends of the first water outlet pipe 1001 and the second water outlet pipe 1002 are both connected to the water tank 10 and connected to an electric valve. When it is necessary to supplement the inoculation of full-stage nitrifying bacteria in the bioretention facility, inject the diluted full-stage nitrifying bacteria enrichment solution into the water tank 10, then open the electric valve, and control the driving mechanism to drive the rail wheel 9 to rotate to enrich the full-stage nitrifying bacteria. The collected liquid is injected above the planting soil layer 1 and into the L-shaped housing 7 at the same time, which can effectively improve the inoculation efficiency. After the inoculation is completed, the top of the L-shaped housing 7 can be covered with materials such as waterproof cloth and waterproof tape to prevent rainwater. Just flow into it from the top.
经过测试,该生物滞留设施稳定运行20天后,得到下表关于生物滞留设施污染物平均去除率。After testing, after the bioretention facility operated stably for 20 days, the following table was obtained regarding the average removal rate of pollutants in the bioretention facility.
经过测试,该生物滞留设施稳定运行50天后,又得到下表关于生物滞留设施污染物平均去除率。After testing, after the bioretention facility operated stably for 50 days, the following table was obtained regarding the average removal rate of pollutants in the bioretention facility.
具体的,测试方式为,先配置模拟雨水:在200升PE加药桶中加入180L自来水,静置至少24小时以减少余氯的影响。每次测试开始前搅拌曝气,模拟实际雨水高溶解氧特性。再投加配置好的污染物原液,定容到200L并顺时针搅拌15min。其中污染物主要成分来自以下物质,硝酸(KNO3),氯化铵(NH4Cl),磷酸二氢钾(KH2PO4),甘氨酸(C2H5NO2),乙酸钠(CH3COONa)。具体浓度污染物浓度选取参考实地检测的城市雨水径流溶解态营养物浓度,取这些研究中较高值并考虑实验室当中自来水自带的游离氮影响。本实验方法的污染物浓度选取为富集全程硝化细菌(Commammox)满负荷时氨氮浓度为28mg/L。Specifically, the test method is to first configure simulated rainwater: add 180L tap water to a 200L PE dosing barrel and let it sit for at least 24 hours to reduce the impact of residual chlorine. Stir and aerate before the start of each test to simulate the high dissolved oxygen characteristics of actual rainwater. Then add the prepared pollutant stock solution, adjust the volume to 200L and stir clockwise for 15 minutes. The main components of pollutants come from the following substances, nitric acid (KNO 3 ), ammonium chloride (NH 4 Cl), potassium dihydrogen phosphate (KH 2 PO 4 ), glycine (C 2 H 5 NO 2 ), sodium acetate (CH 3 COONa). The specific concentration of pollutants was selected with reference to the concentration of dissolved nutrients in urban rainwater runoff measured in the field. The higher value in these studies was taken and the influence of free nitrogen carried by the tap water in the laboratory was taken into consideration. The pollutant concentration for this experimental method was selected as the ammonia nitrogen concentration of 28 mg/L when the full load of enriched nitrifying bacteria (Commammox) is fully loaded.
最后,将配置好的模拟雨水通过蠕动泵缓慢蠕动泵运送到15孔布水喷头均匀布入该生物滞留设施上方,定期收集出水并监测水质出水水质即可。Finally, the configured simulated rainwater is slowly transported to the 15-hole water distribution nozzle through a peristaltic pump and evenly distributed over the bioretention facility. The effluent is collected regularly and the water quality is monitored.
显然与传统生物滞留设施氨氮去除率不足70%相比,该生物滞留设施可大幅增加生物滞留设施对雨水中的氨氮去除率。发明的这些修改和变型属于本发明权利要求及其同等技术的范围之内,则本发明也意图包含这些改动和变型在内。上述实施例或实施方式只是对本发明的举例说明,本发明也可以以其它的特定方式或其它的特定形式实施,而不偏离本发明的要旨或本质特征。Obviously, compared with the ammonia nitrogen removal rate of traditional bioretention facilities, which is less than 70%, this bioretention facility can significantly increase the ammonia nitrogen removal rate of bioretention facilities in rainwater. If these modifications and variations of the invention fall within the scope of the claims of the present invention and equivalent technologies, the present invention is also intended to include these modifications and variations. The above-mentioned examples or implementations are only examples of the present invention, and the present invention can also be implemented in other specific ways or other specific forms without departing from the gist or essential characteristics of the present invention.
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