CN117417789A - 一种再生ibc吨桶绿色清洗溶剂 - Google Patents
一种再生ibc吨桶绿色清洗溶剂 Download PDFInfo
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- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- C—CHEMISTRY; METALLURGY
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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Abstract
本发明属于吨桶绿色清洗剂领域，具体公开了一种再生IBC吨桶绿色清洗溶剂，按重量份包括以下原料：葡萄糖酸钠15‑25份、偏硅酸钠5‑15份、碳酸钠4‑8份、海藻糖脂3‑6份、柠檬酸钠5‑10份、二乙二醇单丁醚6‑12份、乳化剂4‑10份、硅油3‑8份、有机碱2‑5份、缓蚀剂2‑4份、去离子水100份。本发明所述的清洗剂，制备方法简单，污染小，清洗条件温和，清洗效果好，特别适用于高密度聚乙烯HDPE材质吨桶中硫酸残余的清洗，对HDPE吨桶的损伤小。
Description
技术领域
本发明属于吨桶绿色清洗剂领域，具体公开了一种再生IBC吨桶绿色清洗溶剂。
背景技术
IBC吨桶是指IBC中型散装容器。是现代仓储、运输液体产品的必备工具。集装桶由内容器和金属框架组合而成，内容器采用高分子量高密度聚乙烯吹塑成型。采用集装桶包装，可以大副降低生产、储存、运输、操作成本。节省大量的人力、物力。储存相比传统包装可节省35％的空间，装卸可使用叉车作业，减少了人工搬运的诸多麻烦。灌装：1个吨桶＝5个200L桶，灌装过程中减少了多次重复操作的麻烦，同时避免灌装过程中漏料、遗洒等浪费。综上所述，集装桶使用方便、经济耐用，随着国际化发展，集装桶逐渐成为液体包装的主流产品。可盛装Ⅱ、Ⅲ类危险品，盛装Ⅱ类危险品的液体密度最大为1.5g/cm3，盛装Ⅲ类危险品的液体密度为1.8g/cm3。产品结构合理，牢固结实，可用叉车直接装卸，并可以码垛储存。产品底部装有排液阀门，液体排放方便、迅速、彻底、安全，便于清洗，可多次周转使用，节约能源，利于环境保护。
IBC吨桶可以采用PE再生料进行制备，绿色环保，但是再生的HDPE具有以下缺陷，吸湿性小,易发生融体破裂,长期与热金属接触易分解，收缩范围及收缩值大,易发生缩孔.凹痕,变形。因此对于现有的存放98％硫酸的再生IBC吨桶也需要使用针对性的清洗剂清洗才能最大限度的延长IBC吨桶寿命，以及提升清洗效果。
发明内容
为了解决上述问题，本发明公开了一种再生IBC吨桶绿色清洗溶剂，制备方法简单，污染小，清洗条件温和，清洗效果好。
本发明包括以下技术方案：
一种再生IBC吨桶绿色清洗溶剂，按重量份包括以下原料：
进一步的，上述一种再生IBC吨桶绿色清洗溶剂，所述乳化剂选自失水山梨醇单油酸酯、山梨醇酐单油酸酯或蔗糖脂肪酸酯中的一种。
进一步的，上述一种再生IBC吨桶绿色清洗溶剂，所述硅油选自聚硅氧烷或端羟基聚硅氧烷。
进一步的，上述一种再生IBC吨桶绿色清洗溶剂，所述有机碱选自三乙胺、三乙烯二胺或吡啶中的一种。
进一步的，上述一种再生IBC吨桶绿色清洗溶剂，所述缓蚀剂选自3，7，11-三甲基十二炔-3-醇、聚天冬氨酸或3，5-二甲基-1-己炔-3-醇中的一种。
进一步的，上述一种再生IBC吨桶绿色清洗溶剂，所述IBC吨桶为高密度聚乙烯吨桶。
进一步的，上述再生IBC吨桶绿色清洗溶剂的制备方法，包括以下步骤：
将葡萄糖酸钠、偏硅酸钠、碳酸钠、海藻糖脂、柠檬酸钠、二乙二醇单丁醚和去离子水混合形成均一的溶液体系，搅拌，放置在室温中静置；
(2)在上述溶液体系中加入乳化剂、硅油、有机碱和缓蚀剂，并搅拌均匀，静置后得到水性清洗剂。
进一步的，上述再生IBC吨桶绿色清洗溶剂的用途，其特征在于，所述绿色清洗溶剂用于清洗储存98％浓硫酸的IBC吨桶。
进一步的，上述再生IBC吨桶绿色清洗溶剂的用途，所述清洗过程中温度保持在20-30℃。
相比现有技术，本发明具有如下有益效果:
本发明提供了一种再生IBC吨桶绿色清洗溶剂，所述清洗剂的原料基本无毒或者低毒，环境污染小，绿色环保，制备流程短，成本低，制备条件温和。本发明所述的清洗剂特别针对再生的高密度聚乙烯吨桶设计，针对再生高密度聚乙烯材料易发生融体破裂,长期与热金属接触易分解，收缩范围及收缩值大,易发生缩孔.凹痕,变形的缺陷，加入葡萄糖酸钠和海藻糖脂成分，保护高密度聚乙烯吨桶内壁，同时利用有机碱和碳酸钠等成分对吨桶残留的浓硫酸进行彻底的中和和清洗。
附图说明
图1为测试例中实施例1-3以及对比例1-4的污垢残留率％；
图2为测试例中实施例1-3以及对比例1-4的IBC吨桶寿命(模拟加速老化测试)天数。
具体实施方式
下面对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
一种再生IBC吨桶绿色清洗溶剂，按重量份包括以下原料：
所述乳化剂选自失水山梨醇单油酸酯、山梨醇酐单油酸酯或蔗糖脂肪酸酯中的一种；
所述硅油选自聚硅氧烷或端羟基聚硅氧烷；
所述有机碱选自三乙胺、三乙烯二胺或吡啶中的一种；
所述缓蚀剂选自3，7，11-三甲基十二炔-3-醇、聚天冬氨酸或3，5-二甲基-1-己炔-3-醇中的一种；
所述IBC吨桶为高密度聚乙烯吨桶；
上述再生IBC吨桶绿色清洗溶剂的制备方法，包括以下步骤：
将葡萄糖酸钠、偏硅酸钠、碳酸钠、海藻糖脂、柠檬酸钠、二乙二醇单丁醚和去离子水混合形成均一的溶液体系，搅拌，放置在室温中静置；
(2)在上述溶液体系中加入乳化剂、硅油、有机碱和缓蚀剂，并搅拌均匀，静置后得到水性清洗剂。
实施例1
一种再生IBC吨桶绿色清洗溶剂，按重量份包括以下原料：
所述乳化剂为失水山梨醇单油酸酯；
所述硅油为聚硅氧烷；
所述有机碱为三乙胺；
所述缓蚀剂为3，7，11-三甲基十二炔-3-醇；
所述IBC吨桶为高密度聚乙烯吨桶；
上述再生IBC吨桶绿色清洗溶剂的制备方法，包括以下步骤：
将葡萄糖酸钠、偏硅酸钠、碳酸钠、海藻糖脂、柠檬酸钠、二乙二醇单丁醚和去离子水混合形成均一的溶液体系，搅拌，放置在室温中静置；
(2)在上述溶液体系中加入乳化剂、硅油、有机碱和缓蚀剂，并搅拌均匀，静置后得到水性清洗剂。
实施例2
一种再生IBC吨桶绿色清洗溶剂，按重量份包括以下原料：
所述乳化剂为山梨醇酐单油酸酯或；
所述硅油为端羟基聚硅氧烷；
所述有机碱为三乙烯二胺；
所述缓蚀剂为聚天冬氨酸；
所述IBC吨桶为高密度聚乙烯吨桶；
上述再生IBC吨桶绿色清洗溶剂的制备方法，包括以下步骤：
将葡萄糖酸钠、偏硅酸钠、碳酸钠、海藻糖脂、柠檬酸钠、二乙二醇单丁醚和去离子水混合形成均一的溶液体系，搅拌，放置在室温中静置；
(2)在上述溶液体系中加入乳化剂、硅油、有机碱和缓蚀剂，并搅拌均匀，静置后得到水性清洗剂。
实施例3
一种再生IBC吨桶绿色清洗溶剂，按重量份包括以下原料：
所述乳化剂为蔗糖脂肪酸酯；
所述硅油为端羟基聚硅氧烷；
所述有机碱为吡啶；
所述缓蚀剂为3，5-二甲基-1-己炔-3-醇；
所述IBC吨桶为高密度聚乙烯吨桶；
上述再生IBC吨桶绿色清洗溶剂的制备方法，包括以下步骤：
将葡萄糖酸钠、偏硅酸钠、碳酸钠、海藻糖脂、柠檬酸钠、二乙二醇单丁醚和去离子水混合形成均一的溶液体系，搅拌，放置在室温中静置；
(2)在上述溶液体系中加入乳化剂、硅油、有机碱和缓蚀剂，并搅拌均匀，静置后得到水性清洗剂。
对比例1
一种再生IBC吨桶绿色清洗溶剂，按重量份包括以下原料：
所述乳化剂为山梨醇酐单油酸酯或；
所述硅油为端羟基聚硅氧烷；
所述有机碱为三乙烯二胺；
所述缓蚀剂为聚天冬氨酸；
所述IBC吨桶为高密度聚乙烯吨桶；
上述再生IBC吨桶绿色清洗溶剂的制备方法，包括以下步骤：
将葡萄糖酸钠、偏硅酸钠、碳酸钠、海藻糖脂、柠檬酸钠、二乙二醇单丁醚和去离子水混合形成均一的溶液体系，搅拌，放置在室温中静置；
(2)在上述溶液体系中加入乳化剂、硅油、有机碱和缓蚀剂，并搅拌均匀，静置后得到水性清洗剂。
本对比例1相比实施例2，不包括葡萄糖酸钠10份，其他均相同。
对比例2
一种再生IBC吨桶绿色清洗溶剂，按重量份包括以下原料：
所述乳化剂为山梨醇酐单油酸酯或；
所述硅油为端羟基聚硅氧烷；
所述有机碱为三乙烯二胺；
所述缓蚀剂为聚天冬氨酸；
所述IBC吨桶为高密度聚乙烯吨桶；
上述再生IBC吨桶绿色清洗溶剂的制备方法，包括以下步骤：
将葡萄糖酸钠、偏硅酸钠、碳酸钠、海藻糖脂、柠檬酸钠、二乙二醇单丁醚和去离子水混合形成均一的溶液体系，搅拌，放置在室温中静置；
(2)在上述溶液体系中加入乳化剂、硅油、有机碱和缓蚀剂，并搅拌均匀，静置后得到水性清洗剂。
本对比例1相比实施例2，不包括海藻糖脂4.5份，其他均相同。
对比例3
一种再生IBC吨桶绿色清洗溶剂，按重量份包括以下原料：
所述乳化剂为山梨醇酐单油酸酯或；
所述硅油为端羟基聚硅氧烷；
所述有机碱为三乙烯二胺；
所述缓蚀剂为聚天冬氨酸；
所述IBC吨桶为高密度聚乙烯吨桶；
上述再生IBC吨桶绿色清洗溶剂的制备方法，包括以下步骤：
将葡萄糖酸钠、偏硅酸钠、碳酸钠、海藻糖脂、柠檬酸钠、二乙二醇单丁醚和去离子水混合形成均一的溶液体系，搅拌，放置在室温中静置；
(2)在上述溶液体系中加入乳化剂、硅油、有机碱和缓蚀剂，并搅拌均匀，静置后得到水性清洗剂。
本对比例1相比实施例2，不包括葡萄糖酸钠10份和海藻糖脂4.5份，其他均相同。
对比例4
商业购入硫酸氢钠清洗剂。
测试例
对以上实施例1-3以及对比例1-3制备得到的清洗溶剂进行实际的清洗测试，所述绿色清洗溶剂用于清洗储存98％浓硫酸的IBC吨桶，所述清洗过程中温度保持在20-30℃。结果如表1和图1和图2所示。
表1性能测试
由以上表1和图1和图2可以看出，本发明所述的清洗剂特别针对再生的高密度聚乙烯吨桶设计，针对再生高密度聚乙烯材料易发生融体破裂,长期与热金属接触易分解，收缩范围及收缩值大,易发生缩孔.凹痕,变形的缺陷，加入葡萄糖酸钠和海藻糖脂成分，保护高密度聚乙烯吨桶内壁，同时利用有机碱和碳酸钠等成分对吨桶残留的浓硫酸进行彻底的中和和清洗。
上述实施例为本发明的有限几种优选实施方式，其描述较为具体和详细，但并不能因此而理解为对本发明发明范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。
Claims (9)
1.一种再生IBC吨桶绿色清洗溶剂，其特征在于，按重量份包括以下原料：
葡萄糖酸钠 15-25份
偏硅酸钠 5-15份
碳酸钠 4-8份
海藻糖脂 3-6份
柠檬酸钠 5-10份
二乙二醇单丁醚 6-12份
乳化剂 4-10份
硅油 3-8份
有机碱 2-5份
缓蚀剂 2-4份
去离子水 100份。
2.根据权利要求1所述的一种再生IBC吨桶绿色清洗溶剂，其特征在于，所述乳化剂选自失水山梨醇单油酸酯、山梨醇酐单油酸酯或蔗糖脂肪酸酯中的一种。
3.根据权利要求1所述的一种再生IBC吨桶绿色清洗溶剂，其特征在于，所述硅油选自聚硅氧烷或端羟基聚硅氧烷。
4.根据权利要求1所述的一种再生IBC吨桶绿色清洗溶剂，其特征在于，所述有机碱选自三乙胺、三乙烯二胺或吡啶中的一种。
5.根据权利要求1所述的一种再生IBC吨桶绿色清洗溶剂，其特征在于，所述缓蚀剂选自3，7，11-三甲基十二炔-3-醇、聚天冬氨酸或3，5-二甲基-1-己炔-3-醇中的一种。
6.根据权利要求1所述的一种再生IBC吨桶绿色清洗溶剂，其特征在于，所述IBC吨桶为高密度聚乙烯吨桶。
7.如权利要求1-6任一项所述的再生IBC吨桶绿色清洗溶剂的制备方法，其特征在于，包括以下步骤：
将葡萄糖酸钠、偏硅酸钠 、碳酸钠 、海藻糖脂、柠檬酸钠、二乙二醇单丁醚和去离子水混合形成均一的溶液体系，搅拌，放置在室温中静置；
（2）在上述溶液体系中加入乳化剂、硅油、有机碱和缓蚀剂，并搅拌均匀，静置后得到水性清洗剂。
8.如权利要求1-6任一项所述的再生IBC吨桶绿色清洗溶剂的用途，其特征在于，所述绿色清洗溶剂用于清洗储存98%浓硫酸的IBC吨桶。
9.根据权利要求8所述的用途，其特征在于，所述清洗过程中温度保持在20-30℃。
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