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CN117345553A - Web, manufacturing method of web, fan blade and wind generating set - Google Patents

Web, manufacturing method of web, fan blade and wind generating set Download PDF

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Publication number
CN117345553A
CN117345553A CN202210784896.1A CN202210784896A CN117345553A CN 117345553 A CN117345553 A CN 117345553A CN 202210784896 A CN202210784896 A CN 202210784896A CN 117345553 A CN117345553 A CN 117345553A
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China
Prior art keywords
resin
dicyclopentadiene
web
component
polydicyclopentadiene
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CN202210784896.1A
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Chinese (zh)
Inventor
刘宝锋
王超
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Jiangsu Goldwind Science and Technology Co Ltd
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Jiangsu Goldwind Science and Technology Co Ltd
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Priority to CN202210784896.1A priority Critical patent/CN117345553A/en
Publication of CN117345553A publication Critical patent/CN117345553A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F03MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
    • F03DWIND MOTORS
    • F03D80/00Details, components or accessories not provided for in groups F03D1/00 - F03D17/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
    • B29C70/70Completely encapsulating inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
    • B29C70/84Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks by moulding material on preformed parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/08Blades for rotors, stators, fans, turbines or the like, e.g. screw propellers
    • B29L2031/082Blades, e.g. for helicopters
    • B29L2031/085Wind turbine blades

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

本发明提供一种腹板、腹板的制造方法、风机叶片及风力发电机组。所述腹板包括芯材以及分别设置在所述芯材两侧的增强部,所述增强部包括聚双环戊二烯树脂基体以及设置在所述聚双环戊二烯树脂基体中的增强层。根据本发明的腹板,制造成本低、制造效率高且重量轻。

The invention provides a web, a web manufacturing method, a wind turbine blade and a wind power generator set. The web includes a core material and reinforcement portions respectively provided on both sides of the core material. The reinforcement portions include a polydicyclopentadiene resin matrix and a reinforcement layer provided in the polydicyclopentadiene resin matrix. The web according to the present invention has low manufacturing cost, high manufacturing efficiency and light weight.

Description

腹板、腹板的制造方法、风机叶片及风力发电机组Web, web manufacturing method, wind turbine blade and wind turbine

技术领域Technical field

本发明涉及风力发电技术领域,尤其设计一种腹板、腹板的制造方法、风机叶片及风力发电机组。The present invention relates to the technical field of wind power generation, and in particular designs a web, a web manufacturing method, a wind turbine blade and a wind power generator set.

背景技术Background technique

目前风力发电机组叶片的腹板主要由双组份环氧树脂体系灌注玻璃纤维织物与芯材组成的夹芯结构。At present, the web of wind turbine blades is mainly a sandwich structure composed of a two-component epoxy resin system infused with glass fiber fabric and core material.

环氧树脂是一种分子上含两个以上的环氧基团的聚合物,常见的由双酚A和环氧氯丙烷、多元醇等缩合聚合而成。由于制造环氧树脂的原料都大幅涨价,导致风机叶片的成本也大幅上涨。Epoxy resin is a polymer containing more than two epoxy groups in the molecule. It is commonly formed by the condensation polymerization of bisphenol A, epichlorohydrin, polyols, etc. As the raw materials for making epoxy resin have increased significantly in price, the cost of wind turbine blades has also increased significantly.

另外,由于环氧树脂室温下粘度较大(200cps-300cps),导致大厚度部件的灌注时间较长,从而使整个叶片腹板的灌注时间增加,在叶片腹板部件较厚的部位灌注时间较长,一般需要1-2个小时。此外,环氧树脂体系需要进行后固化,后固化周期为70℃下6-7h。因此,采用环氧树脂体系制造叶片腹板的生产效率低。In addition, due to the high viscosity of epoxy resin at room temperature (200cps-300cps), the infusion time of large-thickness parts is longer, which increases the infusion time of the entire blade web, and the infusion time is longer in thicker parts of the blade web parts. Long, usually takes 1-2 hours. In addition, the epoxy resin system needs to be post-cured, and the post-curing period is 6-7 hours at 70°C. Therefore, the production efficiency of manufacturing blade webs using epoxy resin systems is low.

发明内容Contents of the invention

本发明的目的在于提供一种制造成本低、制造效率高且重量轻的腹板。The object of the present invention is to provide a web with low manufacturing cost, high manufacturing efficiency and light weight.

本发明的另一目的在于提供一种能够解决在使用聚双环戊二烯树脂形成腹板时容易引起因浸润不良导致发白的工艺问题的腹板的制造方法。Another object of the present invention is to provide a method for manufacturing a web that can solve the process problem of whitening due to poor wetting when using polydicyclopentadiene resin to form the web.

根据本发明的一方面,提供一种腹板,所述腹板包括芯材以及分别设置在所述芯材两侧的增强部,所述增强部包括聚双环戊二烯树脂基体以及设置在所述聚双环戊二烯树脂基体中的增强层。According to an aspect of the present invention, a web is provided. The web includes a core material and reinforcing parts respectively provided on both sides of the core material. The reinforcing parts include a polydicyclopentadiene resin matrix and a reinforcing part provided on both sides of the core material. The reinforcing layer in the polydicyclopentadiene resin matrix.

可选地,所述增强层包括玻璃纤维、碳纤维、玄武岩纤维、芳纶纤维和亚麻纤维中的至少一种。Optionally, the reinforcing layer includes at least one of glass fiber, carbon fiber, basalt fiber, aramid fiber and flax fiber.

可选地,所述芯材包括孔和槽中的至少一种,所述聚双环戊二烯树脂基体延伸到所述孔和/或所述槽中。Optionally, the core material includes at least one of holes and grooves, and the polydicyclopentadiene resin matrix extends into the holes and/or grooves.

可选地,所述芯材包括第一芯材和第二芯材,所述第二芯材位于所述腹板的起吊点处,所述第二芯材的强度大于所述第一芯材的强度。Optionally, the core material includes a first core material and a second core material, the second core material is located at the lifting point of the web, and the strength of the second core material is greater than that of the first core material Strength of.

根据本发明的另一方面,提供一种腹板的制造方法,所述制造方法包括:在腹板模具中铺设芯材和增强层,所述增强层设置在所述芯材两侧;灌注树脂,所述树脂为聚双环戊二烯树脂体系;使所述树脂固化。According to another aspect of the present invention, a method for manufacturing a web is provided. The manufacturing method includes: laying a core material and a reinforcement layer in a web mold, with the reinforcement layer being provided on both sides of the core material; and injecting resin. , the resin is a polydicyclopentadiene resin system; the resin is cured.

可选地,灌注所述树脂的步骤包括:在所述腹板模具的外侧布置真空系统;抽真空并在抽真空后灌注树脂,其中,树脂灌注温度为25℃-35℃。Optionally, the step of injecting the resin includes: arranging a vacuum system outside the web mold; evacuation and injecting the resin after evacuation, wherein the resin infusion temperature is 25°C-35°C.

可选地,使所述树脂固化的步骤包括:在40-60℃下保温1-2小时再升温至80-85℃保温3-4小时。Optionally, the step of curing the resin includes: maintaining the temperature at 40-60°C for 1-2 hours and then raising the temperature to 80-85°C and maintaining the temperature for 3-4 hours.

可选地,所述抽真空的步骤包括:在所述树脂的灌注量达到一半之前,将真空度设置为0.5-0.8个大气压。Optionally, the step of vacuuming includes: setting the vacuum degree to 0.5-0.8 atmospheres before the resin filling amount reaches half.

可选地,灌注所述树脂的管体直径为5-20mm。Optionally, the diameter of the tube into which the resin is poured is 5-20 mm.

可选地,在灌注所述树脂时,逐步增大所述树脂的灌注速率。Optionally, when injecting the resin, the infusion rate of the resin is gradually increased.

可选地,所述聚双环戊二烯树脂体系包括双环戊二烯或双环戊二烯预聚体,所述聚双环戊二烯树脂体系还包括催化剂,基于100重量份的双环戊二烯或双环戊二烯预聚体,催化剂的含量为0.01-5重量份。Optionally, the polydicyclopentadiene resin system includes dicyclopentadiene or dicyclopentadiene prepolymer, and the polydicyclopentadiene resin system further includes a catalyst, based on 100 parts by weight of dicyclopentadiene or Dicyclopentadiene prepolymer, the catalyst content is 0.01-5 parts by weight.

可选地,所述双环戊二烯预聚体由双环戊二烯和弹性体形成,弹性体与双环戊二烯的重量比为0.01-0.7。Optionally, the dicyclopentadiene prepolymer is formed from dicyclopentadiene and an elastomer, and the weight ratio of the elastomer to dicyclopentadiene is 0.01-0.7.

可选地,催化剂包括钌催化剂、经典双组分催化剂、钼酚类化合物或者钨-三苯基膦系列配合物,弹性体包括热塑性弹性体。Optionally, the catalyst includes a ruthenium catalyst, a classic two-component catalyst, a molybdenum phenolic compound or a tungsten-triphenylphosphine series complex, and the elastomer includes a thermoplastic elastomer.

可选地,所述聚双环戊二烯树脂体系的制造方法包括:在灌注树脂之前,将双环戊二烯或双环戊二烯预聚体和催化剂分成A组分和B组分,所述A组分为双环戊二烯或双环戊二烯预聚体且所述B组分为催化剂,或者所述A组分为双环戊二烯或双环戊二烯预聚体的一部分且所述B组分为催化剂以及双环戊二烯或双环戊二烯预聚体的其余部分;分别对所述A组分和所述B组分进行脱泡,然后混合。Optionally, the manufacturing method of the polydicyclopentadiene resin system includes: before injecting the resin, dividing dicyclopentadiene or dicyclopentadiene prepolymer and catalyst into component A and component B, said A The component is dicyclopentadiene or dicyclopentadiene prepolymer and the B component is a catalyst, or the A component is a part of dicyclopentadiene or dicyclopentadiene prepolymer and the B component Separate into the catalyst and the remainder of dicyclopentadiene or dicyclopentadiene prepolymer; degas the A component and the B component respectively, and then mix.

根据本发明的另一方面,提供一种风机叶片,所述风机叶片包括如上所述的腹板。According to another aspect of the invention, a wind turbine blade is provided, the wind turbine blade comprising a web as described above.

根据本发明的还一方面,提供一种风力发电机组,所述风力发电机组包括如上所述的风机叶片。According to yet another aspect of the present invention, a wind power generator set is provided, which wind power generator set includes the wind turbine blade as described above.

根据本发明,用于聚双环戊二烯树脂基体的聚双环戊二烯树脂体系(组合料)的成本比环氧树脂体系便宜30%以上,每支叶片腹板可节省1-3万元人民币,降本效果明显。According to the present invention, the cost of the polydicyclopentadiene resin system (assembly) used for the polydicyclopentadiene resin matrix is more than 30% cheaper than the epoxy resin system, and each blade web can save 10,000 to 30,000 yuan. , the cost reduction effect is obvious.

根据本发明,采用聚双环戊二烯树脂体系灌注增强层和芯材制作腹板,由于聚双环戊二烯树脂体系室温下粘度小,只有10~100cps,因此其灌注速度非常快,可以缩短腹板的灌注时间约0.5-1.5个小时。According to the present invention, the polydicyclopentadiene resin system is used to infuse the reinforcement layer and core material to make the web. Since the polydicyclopentadiene resin system has a low viscosity at room temperature, only 10 to 100 cps, the infusion speed is very fast and the web can be shortened. The plate perfusion time is approximately 0.5-1.5 hours.

根据本发明,聚双环戊二烯树脂无需后固化,固化时间短,可以使生产效率大幅提高。According to the present invention, the polydicyclopentadiene resin does not require post-curing, the curing time is short, and the production efficiency can be greatly improved.

根据本发明,聚双环戊二烯树脂体系(组合料)的密度为1.03-1.05g/cm3,固化后的密度比环氧树脂体系固化后的密度小,制得的腹板重量轻3-5%,从而可实现叶片的轻量化。According to the present invention, the density of the polydicyclopentadiene resin system (assembly) is 1.03-1.05g/cm 3 , the density after curing is smaller than the density after curing of the epoxy resin system, and the web is 3-3 light in weight 5%, thus achieving lightweight blades.

另外,根据本发明,提供了一种能够解决在使用聚双环戊二烯树脂形成腹板时容易引起因浸润不良导致发白的工艺问题。In addition, according to the present invention, a method is provided that can solve the process problem of whitening caused by poor wetting when using polydicyclopentadiene resin to form a web.

附图说明Description of drawings

通过下面结合附图进行的详细描述,本发明的上述和其它目的、特点和优点将会变得更加清楚,其中:The above and other objects, features and advantages of the present invention will become more apparent from the following detailed description taken in conjunction with the accompanying drawings, in which:

图1是根据本发明的实施例的叶片的一部分的分解示意性;Figure 1 is an exploded schematic diagram of a portion of a blade according to an embodiment of the invention;

图2是根据本发明的实施例的主梁和腹板的示意图;Figure 2 is a schematic diagram of main beams and webs according to an embodiment of the present invention;

图3是根据本发明的实施例的腹板的示意图;Figure 3 is a schematic diagram of a web according to an embodiment of the invention;

图4是沿图3的A-A线截取的截面图;Figure 4 is a cross-sectional view taken along line A-A of Figure 3;

图5是示出根据本发明的实施例的腹板的制造方法的示意图。FIG. 5 is a schematic diagram illustrating a method of manufacturing a web according to an embodiment of the present invention.

在附图中:101为第一壳体,102为第二壳体,10为腹板,20为主梁,11为增强部,12为芯材,12a为第一芯材,12b为第二芯材,31为一体灌注系统,32为真空系统,33为腹板模具,34为第一阀门,35为第二阀门,36为温度传感器。In the drawings: 101 is the first shell, 102 is the second shell, 10 is the web, 20 is the main beam, 11 is the reinforcement, 12 is the core material, 12a is the first core material, 12b is the second For the core material, 31 is an integrated perfusion system, 32 is a vacuum system, 33 is a web mold, 34 is a first valve, 35 is a second valve, and 36 is a temperature sensor.

具体实施方式Detailed ways

以下,将参照图1至图5描述根据本发明的实施例的腹板、腹板的制造方法、风机叶片及风力发电机组。Hereinafter, a web, a web manufacturing method, a wind turbine blade and a wind turbine set according to embodiments of the present invention will be described with reference to FIGS. 1 to 5 .

图1是根据本发明的实施例的叶片的一部分的分解示意性。如图1所示,叶片可包括第一壳体101和第二壳体102。在安装好的叶片中,第一壳体101和第二壳体102可彼此结合以形成完整的壳体,提供气流通过的几何翼型。Figure 1 is an exploded schematic representation of a portion of a blade according to an embodiment of the invention. As shown in FIG. 1 , the blade may include a first housing 101 and a second housing 102 . In the installed blade, the first shell 101 and the second shell 102 can be combined with each other to form a complete shell, providing a geometric airfoil through which the airflow passes.

根据本发明的实施例,叶片可包括腹板10。腹板10可支撑在第一壳体101和第二壳体102之间,用于承受剪力和弯曲力矩。可选地,叶片可包括两个腹板10,两个腹板10彼此分开。然而,腹板10的数量不受具体限制。According to embodiments of the invention, the blade may include a web 10 . The web 10 may be supported between the first shell 101 and the second shell 102 for bearing shear forces and bending moments. Alternatively, the blade may comprise two webs 10 separated from each other. However, the number of webs 10 is not particularly limited.

据本发明的实施例,叶片还可包括主梁20。主梁20可设置在第一壳体101和第二壳体102中以作为承力部件。叶片可包括分别设置在第一壳体101和第二壳体102中的两个主梁20。According to embodiments of the present invention, the blade may further include a main beam 20 . The main beam 20 may be provided in the first housing 101 and the second housing 102 as a load-bearing component. The blade may include two main beams 20 provided in the first housing 101 and the second housing 102 respectively.

图2是根据本发明的实施例的主梁和腹板的示意图。如图2所示,两个主梁20在叶片的厚度方向上彼此相对,两个腹板10在叶片的弦向上彼此相对并支撑两个主梁20。Figure 2 is a schematic diagram of main beams and webs according to an embodiment of the present invention. As shown in FIG. 2 , the two main beams 20 are opposite to each other in the thickness direction of the blade, and the two webs 10 are opposite to each other in the chord direction of the blade and support the two main beams 20 .

以下,将参照图3和图4来描述根据本发明的实施例的腹板。图3是根据本发明的实施例的腹板的示意图,图4是沿图3的A-A线截取的截面图。Hereinafter, a web according to an embodiment of the present invention will be described with reference to FIGS. 3 and 4 . 3 is a schematic diagram of a web according to an embodiment of the present invention, and FIG. 4 is a cross-sectional view taken along line A-A of FIG. 3 .

如图3和图4所示,根据本发明的实施例的腹板10可包括芯材12以及分别设置在芯材12两侧的增强部11。As shown in FIGS. 3 and 4 , the web 10 according to the embodiment of the present invention may include a core material 12 and reinforcement portions 11 respectively provided on both sides of the core material 12 .

根据本发明的实施例,设置在芯材12两侧的增强部11在芯材12的两端结合到一起并翻转形成粘接法兰,使得腹板10形成类似于C型或T型的结构,以提供叶片的强度和刚度。然而,腹板10的形状不受具体限制。According to an embodiment of the present invention, the reinforcing parts 11 provided on both sides of the core material 12 are combined together at both ends of the core material 12 and turned over to form a bonding flange, so that the web 10 forms a structure similar to a C-shape or a T-shape. , to provide blade strength and stiffness. However, the shape of the web 10 is not particularly limited.

根据本发明的实施例,增强部11可包括聚双环戊二烯树脂基体以及设置在聚双环戊二烯树脂基体中的增强层。根据本发明,通过在增强部11中应用聚双环戊二烯树脂基体,可实现以下技术效果中的至少一项技术效果:1、聚双环戊二烯树脂体系(组合料)(聚双环戊二烯树脂在灌注并固化后形成聚双环戊二烯树脂基体)的成本比环氧树脂体系便宜30%以上,每支叶片腹板可节省1-3万元人民币,降本效果明显;2、在利用聚双环戊二烯树脂体系(组合料)灌注增强层和芯材制作腹板时,由于聚双环戊二烯树脂体系(组合料)室温下粘度小,只有10~100cps,因此其灌注速度非常快,可以缩短腹板的灌注时间约0.5-1.5个小时;3、聚双环戊二烯树脂无需后固化,固化时间短,可以使生产效率大幅提高;4、聚双环戊二烯树脂体系(组合料)的密度为1.03-1.05g/cm3,固化后的密度比环氧树脂体系固化后的密度小,制得的腹板重量轻3-5%,从而可实现叶片的轻量化。According to an embodiment of the present invention, the reinforcing part 11 may include a polydicyclopentadiene resin matrix and a reinforcing layer disposed in the polydicyclopentadiene resin matrix. According to the present invention, by applying a polydicyclopentadiene resin matrix in the reinforced part 11, at least one of the following technical effects can be achieved: 1. Polydicyclopentadiene resin system (composite material) (polydicyclopentadiene resin system) The cost of polyethylene resin, which forms a polydicyclopentadiene resin matrix after infusion and solidification, is more than 30% cheaper than the epoxy resin system. Each blade web can save 10,000 to 30,000 yuan, and the cost reduction effect is obvious; 2. When using the polydicyclopentadiene resin system (composite material) to infuse the reinforcement layer and core material to make the web, the polydicyclopentadiene resin system (composition material) has a low viscosity at room temperature, only 10 to 100 cps, so the infusion speed is very It is fast and can shorten the infusion time of the web by about 0.5-1.5 hours; 3. Polydicyclopentadiene resin does not require post-curing, and the curing time is short, which can greatly improve production efficiency; 4. Polydicyclopentadiene resin system (combination The density of the material) is 1.03-1.05g/cm 3 , and the density after curing is smaller than the density after curing of the epoxy resin system. The weight of the web produced is 3-5% lighter, thereby achieving lightweight blades.

根据本发明的实施例,聚双环戊二烯树脂基体可利用聚双环戊二烯树脂体系(组合料)制成。聚双环戊二烯(PDCPD)树脂体系是由催化剂、双环戊二烯(DCPD)或双环戊二烯(DCPD)预聚体共聚而成的高分子IPN合金材料,具有密度小、韧性好、易灌注、固化速度快等特点。According to embodiments of the present invention, the polydicyclopentadiene resin matrix can be made using a polydicyclopentadiene resin system (composition). Polydicyclopentadiene (PDCPD) resin system is a polymer IPN alloy material copolymerized by catalyst, dicyclopentadiene (DCPD) or dicyclopentadiene (DCPD) prepolymer. It has low density, good toughness, and ease of use. It has the characteristics of fast filling and curing speed.

根据本发明的实施例,聚双环戊二烯树脂体系可包括双环戊二烯或双环戊二烯预聚体。通过利用弹性体对双环戊二烯进行改性,形成双环戊二烯预聚体。通过对双环戊二烯进行改性,可提高分子量,改善性能。According to embodiments of the present invention, the polydicyclopentadiene resin system may include dicyclopentadiene or dicyclopentadiene prepolymer. Dicyclopentadiene prepolymer is formed by modifying dicyclopentadiene with an elastomer. By modifying dicyclopentadiene, the molecular weight can be increased and performance improved.

根据本发明的实施例,弹性体与双环戊二烯的重量比为0.01-0.7。当弹性体与双环戊二烯的重量比小于0.01时,弹性体的添加量过小,对双环戊二烯进行改性的作用不明显。当弹性体与双环戊二烯的重量比达到0.7时,对双环戊二烯进行改性的作用已经很显著,而当弹性体与双环戊二烯的重量比超过0.7时,对双环戊二烯进行改性的作用不再明显提高,相反还会影响双环戊二烯的量,因此影响作为主剂的双环戊二烯的性能。According to embodiments of the present invention, the weight ratio of elastomer to dicyclopentadiene is 0.01-0.7. When the weight ratio of the elastomer to dicyclopentadiene is less than 0.01, the added amount of the elastomer is too small, and the effect of modifying dicyclopentadiene is not obvious. When the weight ratio of elastomer to dicyclopentadiene reaches 0.7, the effect of modifying dicyclopentadiene is already significant, and when the weight ratio of elastomer to dicyclopentadiene exceeds 0.7, the effect of modifying dicyclopentadiene The effect of modification is no longer significantly improved, but will instead affect the amount of dicyclopentadiene, thus affecting the performance of dicyclopentadiene as the main agent.

根据本发明的实施例,弹性体可以为热塑性弹性体(TPE或TPR)。可选地,弹性体可以为SBS(苯乙烯系热塑性弹性体)、SEBS(饱和型SBS)、PS(聚苯乙烯)、TPS(苯乙烯类热塑弹性体)、TPV(热塑性三元乙丙动态硫化弹性体)、TPEE(热塑性聚酯弹性体)和TPU(主热塑性聚氨酯弹性体橡胶)中的任意一种。According to embodiments of the present invention, the elastomer may be a thermoplastic elastomer (TPE or TPR). Alternatively, the elastomer may be SBS (styrenic thermoplastic elastomer), SEBS (saturated SBS), PS (polystyrene), TPS (styrenic thermoplastic elastomer), TPV (thermoplastic ethylene propylene diene monomer) Any one of dynamic vulcanized elastomer), TPEE (thermoplastic polyester elastomer) and TPU (main thermoplastic polyurethane elastomer rubber).

根据本发明的实施例,聚双环戊二烯树脂体系还可包括催化剂。基于100重量份的双环戊二烯或双环戊二烯预聚体,催化剂的含量为0.01-5重量份。根据本发明,通过在双环戊二烯预聚体中加入催化剂,可在双环戊二烯预聚体的聚合反应中起到催化聚合的作用。According to embodiments of the present invention, the polydicyclopentadiene resin system may further include a catalyst. The content of the catalyst is 0.01-5 parts by weight based on 100 parts by weight of dicyclopentadiene or dicyclopentadiene prepolymer. According to the present invention, by adding a catalyst to the dicyclopentadiene prepolymer, it can play a catalytic polymerization role in the polymerization reaction of the dicyclopentadiene prepolymer.

当基于100重量份的双环戊二烯或双环戊二烯预聚体,催化剂的添加量小于0.01重量份时,催化剂的添加量过小,无法充分发挥对双环戊二烯或双环戊二烯预聚体的催化聚合的作用。当基于100重量份的双环戊二烯或双环戊二烯预聚体,催化剂的添加量大于5重量份时,对双环戊二烯或双环戊二烯预聚体的催化聚合的作用不再明显提高,相反还会影响双环戊二烯或双环戊二烯预聚体的量,因此影响作为主剂的双环戊二烯或双环戊二烯预聚体的性能。When the added amount of catalyst is less than 0.01 parts by weight based on 100 parts by weight of dicyclopentadiene or dicyclopentadiene prepolymer, the added amount of catalyst is too small and cannot fully exert its effect on dicyclopentadiene or dicyclopentadiene prepolymer. catalytic polymerization of polymers. When the addition amount of the catalyst is greater than 5 parts by weight based on 100 parts by weight of dicyclopentadiene or dicyclopentadiene prepolymer, the effect on the catalytic polymerization of dicyclopentadiene or dicyclopentadiene prepolymer is no longer obvious. Increasing the amount will, on the contrary, affect the amount of dicyclopentadiene or dicyclopentadiene prepolymer, thus affecting the performance of dicyclopentadiene or dicyclopentadiene prepolymer as the main agent.

根据本发明的实施例,催化剂可包括钌催化剂、经典双组分催化剂、钼酚类化合物或者钨-三苯基膦系列配合物等。钌催化剂可以是Grubbs一代或Grubbs二代。经典双组分催化剂中的第一组份(主催化剂)为W、Mo、Ru、Ti、Re等的配合物,第二组份为Al、Mg、Sn、Zn、Si等的金属有机化合物。钼酚类化合物可以为例如三对甲基苯氧基二氯化钼、三(2,4-二叔丁基-6-甲基酚氧基)二氯化钼、三壬基苯氧基二氧化钼等。According to embodiments of the present invention, the catalyst may include a ruthenium catalyst, a classic two-component catalyst, a molybdenum phenolic compound, or a tungsten-triphenylphosphine series complex, etc. The ruthenium catalyst can be Grubbs first generation or Grubbs second generation. The first component (main catalyst) in a classic two-component catalyst is a complex of W, Mo, Ru, Ti, Re, etc., and the second component is a metal organic compound such as Al, Mg, Sn, Zn, Si, etc. The molybdenum phenolic compound may be, for example, tris-p-methylphenoxymolybdenum dichloride, tris(2,4-di-tert-butyl-6-methylphenoxy)molybdenum dichloride, trinonylphenoxydichloride Molybdenum oxide, etc.

根据本发明的实施例,增强部11还可包括设置在聚双环戊二烯树脂基体中的增强层,以提高腹板10的强度和刚度。根据本发明的实施例,增强层可包括玻璃纤维、碳纤维、玄武岩纤维、芳纶纤维和亚麻纤维中的至少一种。According to embodiments of the present invention, the reinforcing part 11 may further include a reinforcing layer disposed in a polydicyclopentadiene resin matrix to improve the strength and stiffness of the web 10 . According to embodiments of the present invention, the reinforcing layer may include at least one of glass fiber, carbon fiber, basalt fiber, aramid fiber and flax fiber.

作为示例,增强层可采用以下纤维中的至少一种:玻璃纤维(包括克重为800-1200g/m2的双轴向织物),双轴向碳纤维织物(包括克重为的100g/m2-2000g/m2多轴向织物)、碳-玻混杂织物(包括层内混杂和层间混杂织物,克重为100g/m2-2000g/m2,碳纤维的混杂重量比为1%-99%)、玄武岩纤维织物(包括克重为100g/m2-2000g/m2的双轴向织物和多轴向织物)、芳纶纤维织物(包括克重为100g/m2-2000g/m2的双轴向织物和多轴向织物)、亚麻等天然纤维织物(包括克重为100g/m2-2000g/m2的双轴向织物和多轴向织物)。As an example, the reinforcing layer may use at least one of the following fibers: glass fiber (including biaxial fabrics with a weight of 800-1200g/ m2 ), biaxial carbon fiber fabrics (including biaxial fabrics with a weight of 100g/ m2) -2000g/m 2 multi-axial fabric), carbon-glass hybrid fabric (including intra-layer hybrid and inter-layer hybrid fabrics, gram weight is 100g/m 2 -2000g/m 2 , carbon fiber hybrid weight ratio is 1%-99 %), basalt fiber fabrics (including biaxial fabrics and multiaxial fabrics with a weight of 100g/ m2-2000g / m2 ), aramid fiber fabrics (including biaxial fabrics with a weight of 100g/ m2-2000g / m2 biaxial fabrics and multiaxial fabrics), linen and other natural fiber fabrics (including biaxial fabrics and multiaxial fabrics with a weight of 100g/ m2-2000g / m2 ).

根据本发明的实施例的腹板10可包括夹在增强部11之间的芯材12。为了提高芯材12与增强部11之间的结合强度,芯材12可包括孔和槽中的至少一种。在灌注聚双环戊二烯树脂体系(用于形成聚双环戊二烯树脂基体)时,聚双环戊二烯树脂体系会流入孔和/或槽中并在后续固化工艺中固化。因此,根据本发明的聚双环戊二烯树脂基体可延伸到孔和/或槽中,形成类似锚栓的结构,提高芯材12与增强部11之间的结合强度。作为示例,槽可以为一字型或十字型,然而,槽的形式不限于此。The web 10 according to embodiments of the present invention may include a core 12 sandwiched between reinforcements 11 . In order to improve the bonding strength between the core material 12 and the reinforcement 11 , the core material 12 may include at least one of holes and grooves. When infusing the polydicyclopentadiene resin system (used to form the polydicyclopentadiene resin matrix), the polydicyclopentadiene resin system flows into the holes and/or grooves and solidifies during the subsequent curing process. Therefore, the polydicyclopentadiene resin matrix according to the present invention can extend into the holes and/or grooves to form an anchor-like structure to improve the bonding strength between the core material 12 and the reinforcement 11 . As an example, the groove may be in a straight shape or a cross shape, however, the form of the groove is not limited thereto.

根据本发明的实施例,芯材12可以为PET泡沫、HPE泡沫、PVC泡沫、SAN泡沫和轻木中的至少一种。PET泡沫主要成分是聚对苯二甲酸乙二醇酯,俗称涤纶树脂,具有良好的耐热性、力学强度及环保性能。HPE泡沫是指双环戊二烯和聚醚共混发泡形成的具有互穿聚合物网络的新型硬质泡沫,泡孔尺寸小,吸胶量低,环保可回收,韧性好,具有突出的抗疲劳性能。PVC泡沫是指以聚氯乙烯树脂为主体,加入发泡剂及其它添加剂制成,是一种使用较早的泡沫塑料,分为硬质和软质。本发明中使用的PVC泡沫可以为交联型硬质PVC泡沫。According to embodiments of the present invention, the core material 12 may be at least one of PET foam, HPE foam, PVC foam, SAN foam and balsa wood. The main component of PET foam is polyethylene terephthalate, commonly known as polyester resin, which has good heat resistance, mechanical strength and environmental protection performance. HPE foam refers to a new type of rigid foam with an interpenetrating polymer network formed by blending and foaming dicyclopentadiene and polyether. It has small cell size, low glue absorption, is environmentally friendly and recyclable, has good toughness, and has outstanding anti-resistance properties. Fatigue performance. PVC foam is made of polyvinyl chloride resin as the main body, adding foaming agent and other additives. It is an early-used foam plastic and is divided into hard and soft. The PVC foam used in the present invention may be cross-linked rigid PVC foam.

根据本发明的实施例,优选地,可使用PET泡沫和HPE泡沫作为腹板10的芯材,以最大限度地降低叶片成本。According to embodiments of the present invention, preferably, PET foam and HPE foam may be used as the core material of the web 10 to minimize blade costs.

根据本发明的实施例,如图3所示,芯材12可包括第一芯材12a和第二芯材12b。第二芯材12b位于腹板10的起吊点处,第二芯材12b的强度大于第一芯材12a的强度。腹板10的起吊点是吊装腹板10时的主要受力点,根据本发明,通过使第二芯材12b的强度大于第一芯材12a的强度,可提高局部结构承载力,避免在吊装腹板10时对腹板10造成损坏。According to an embodiment of the present invention, as shown in FIG. 3 , the core material 12 may include a first core material 12a and a second core material 12b. The second core material 12b is located at the lifting point of the web 10, and the strength of the second core material 12b is greater than the strength of the first core material 12a. The lifting point of the web 10 is the main force-bearing point when hoisting the web 10. According to the present invention, by making the strength of the second core material 12b greater than the strength of the first core material 12a, the local structural bearing capacity can be improved, and the lifting capacity can be avoided. The web 10 is damaged when the web 10 is removed.

根据本发明的实施例,第一芯材12a可采用PET泡沫,第二芯材可采用轻木,例如,密度为135-176Kg/m3的轻木。According to an embodiment of the present invention, the first core material 12a may be PET foam, and the second core material may be balsa wood, for example, balsa wood with a density of 135-176Kg/ m3 .

图5是示出根据本发明的实施例的腹板的制造方法的示意图。以下,将参照图5描述根据本发明的实施例的腹板的制造方法。为了避免冗余,将省略与以上描述重复的描述。FIG. 5 is a schematic diagram illustrating a method of manufacturing a web according to an embodiment of the present invention. Hereinafter, a method of manufacturing a web according to an embodiment of the present invention will be described with reference to FIG. 5 . To avoid redundancy, descriptions that are repeated with the above descriptions will be omitted.

如图5所示,根据本发明的实施例的腹板的制造方法包括:在腹板模具33中铺设芯材12和增强层,增强层设置在芯材12两侧;灌注树脂,树脂为聚双环戊二烯树脂体系;使树脂固化。As shown in Figure 5, the manufacturing method of the web according to the embodiment of the present invention includes: laying the core material 12 and the reinforcement layer in the web mold 33, with the reinforcement layer being provided on both sides of the core material 12; pouring resin, and the resin is polyethylene. Dicyclopentadiene resin system; cures the resin.

首先,可在腹板模具33中铺设芯材12和增强层。具体地,可首先在腹板模具33上铺设位于芯材12一侧的增强层。然后,可铺设芯材12。最后,可在芯材12的另一侧铺设增强层。First, the core material 12 and reinforcement layers can be laid in the web mold 33 . Specifically, the reinforcement layer located on one side of the core material 12 can be laid on the web mold 33 first. The core material 12 can then be laid. Finally, a reinforcement layer can be laid on the other side of the core 12 .

接下来,可向芯材12和增强层灌注聚双环戊二烯树脂体系,聚双环戊二烯树脂体系在固化后形成以上描述的聚双环戊二烯树脂基体。根据本发明的实施例,聚双环戊二烯树脂体系可包括双环戊二烯或双环戊二烯预聚体和催化剂。双环戊二烯预聚体由双环戊二烯以及对双环戊二烯进行共聚改性的弹性体形成。以上已经对双环戊二烯预聚体和催化剂等进行了描述,在此将省略详细描述。Next, the core material 12 and the reinforcing layer may be infused with a polydicyclopentadiene resin system, which upon curing forms the polydicyclopentadiene resin matrix described above. According to embodiments of the present invention, the polydicyclopentadiene resin system may include dicyclopentadiene or dicyclopentadiene prepolymer and a catalyst. The dicyclopentadiene prepolymer is formed from dicyclopentadiene and an elastomer that copolymerizes dicyclopentadiene. The dicyclopentadiene prepolymer, catalyst, and the like have been described above, and detailed description will be omitted here.

根据本发明的实施例,在灌注树脂之前,可将双环戊二烯或预聚体和催化剂分成A组分和B组分。A组分为双环戊二烯或预聚体,B组分为催化剂。或者,A组分为双环戊二烯或预聚体的一部分,B组分为催化剂以及双环戊二烯或预聚体的其余部分。可分别对A组分和B组分进行脱泡,混合后进行灌注。A组分和B组分的重量比可以为100∶0.1~5。由于一体灌注系统31不需要预先对树脂进行单独的脱泡工序,避免了混合后脱泡造成的树脂温度上升,也减少了反复倾倒树脂所引入的大量气泡,减少了树脂中气泡带来的灌注发白,提高了灌注质量。According to embodiments of the present invention, before injecting the resin, dicyclopentadiene or prepolymer and catalyst may be divided into A component and B component. Component A is dicyclopentadiene or prepolymer, and component B is catalyst. Alternatively, component A is part of the dicyclopentadiene or prepolymer, component B is the catalyst and the remainder of the dicyclopentadiene or prepolymer. Component A and component B can be degassed separately, mixed and then poured. The weight ratio of component A and component B can be 100:0.1~5. Since the integrated pouring system 31 does not require a separate degassing process for the resin in advance, it avoids the temperature rise of the resin caused by degassing after mixing, and also reduces the large number of bubbles introduced by repeatedly pouring the resin, and reduces the pouring caused by the bubbles in the resin. Whitening improves the quality of perfusion.

根据本发明的实施例,在灌注树脂时,可利用真空系统32来抽真空并利用一体灌注系统31来灌注树脂。According to an embodiment of the present invention, when injecting resin, the vacuum system 32 may be used to evacuate and the integrated infusion system 31 may be used to inject resin.

可在腹板模具33的外侧布置真空系统32,通过调节第二阀门35,可设置真空度等级。由于聚双环戊二烯树脂体系的粘度低,如果在灌注过程中将真空度设置的较大,则灌注的聚双环戊二烯树脂很容易被抽走。根据本发明的实施例,可在树脂的灌注量达到一半之前,将真空度设置为0.5-0.8个大气压,以避免聚双环戊二烯树脂被抽走。A vacuum system 32 can be arranged outside the web mold 33, and by adjusting the second valve 35, the vacuum level can be set. Due to the low viscosity of the polydicyclopentadiene resin system, if the vacuum degree is set to a large value during the infusion process, the infused polydicyclopentadiene resin can be easily pumped away. According to embodiments of the present invention, the vacuum degree can be set to 0.5-0.8 atmospheres before the resin infusion volume reaches half to prevent the polydicyclopentadiene resin from being pumped away.

根据本发明的实施例,在抽真空后,可利用一体灌注系统31来灌注树脂。According to an embodiment of the present invention, after vacuuming, the integrated infusion system 31 can be used to inject resin.

根据本发明的实施例,在灌注树脂时,可逐步增大树脂的灌注速率。如上所述,由于聚双环戊二烯树脂体系的粘度低,因此其流动性好。在灌注初期,树脂的灌注速率不宜过大,以防止树脂被抽走。可通过逐步增大树脂的灌注速率,来保证树脂灌注的稳定性。According to embodiments of the present invention, when injecting resin, the infusion rate of the resin can be gradually increased. As mentioned above, the polydicyclopentadiene resin system has good fluidity due to its low viscosity. In the early stages of infusion, the resin infusion rate should not be too high to prevent the resin from being pumped away. The stability of resin infusion can be ensured by gradually increasing the resin infusion rate.

根据本发明的实施例,可通过控制第一阀门34来调节树脂的灌注速率,在灌注树脂时,可逐步增大第一阀门34的开度。According to an embodiment of the present invention, the resin infusion rate can be adjusted by controlling the first valve 34, and when injecting the resin, the opening of the first valve 34 can be gradually increased.

根据本发明的实施例,考虑到聚双环戊二烯树脂体系的粘度低流动性好,灌注树脂的管体直径可以为5mm-20mm。According to embodiments of the present invention, considering that the polydicyclopentadiene resin system has low viscosity and good fluidity, the diameter of the resin-infused tube may be 5 mm to 20 mm.

根据本发明的实施例,树脂灌注的温度可以为25℃-35℃。可通过温度传感器36来监测树脂灌注的温度。当树脂灌注的温度小于25℃时,聚双环戊二烯树脂的流动性下降,当树脂灌注的温度高于35℃,会导致聚双环戊二烯树脂不稳定。According to embodiments of the present invention, the temperature of resin infusion may be 25°C-35°C. The temperature of the resin infusion may be monitored by a temperature sensor 36 . When the resin infusion temperature is less than 25°C, the fluidity of the polydicyclopentadiene resin decreases. When the resin infusion temperature is higher than 35°C, the polydicyclopentadiene resin will become unstable.

根据本发明的实施例,在灌注结束后,树脂进入固化阶段。作为示例,可使树脂在40-60℃下保温1-2小时再升温至80-85℃保温3-4小时。According to embodiments of the present invention, after the infusion is completed, the resin enters the curing stage. As an example, the resin can be kept at 40-60°C for 1-2 hours and then heated to 80-85°C for 3-4 hours.

具体地,可将腹板模具33的模具加热程序设置40-60℃下保温1-2小时(预固化),再升至80-85℃加热3-4个小时。在固化过程中,可在真空袋表面加盖保温棉,表面超过60℃时需移除,进行散热,放热峰过后重新加盖。另外,在预固化过程中,灌注树脂的管体和灌注口应避免覆盖保温棉,以利于散热。Specifically, the mold heating program of the web mold 33 can be set to 40-60°C for 1-2 hours (pre-curing), and then raised to 80-85°C for 3-4 hours. During the curing process, the surface of the vacuum bag can be covered with thermal insulation cotton. When the surface exceeds 60°C, it needs to be removed to dissipate heat. After the exothermic peak, the bag must be re-covered. In addition, during the pre-curing process, the resin-filled pipe body and filling port should avoid being covered with insulation cotton to facilitate heat dissipation.

可选地,待温度自然降温至50℃以下后,进行脱模,获得根据本发明的实施例的腹板10。Optionally, after the temperature naturally cools down to below 50° C., demoulding is performed to obtain the web 10 according to the embodiment of the present invention.

本发明的一方面还可提供一种包括如上所述的腹板10的风机叶片。One aspect of the present invention may also provide a wind turbine blade including the web 10 as described above.

本发明的一个实施例还可提供一种包括如上所述的风机叶片的风力发电机组。An embodiment of the present invention may further provide a wind power generator including the wind turbine blades as described above.

如上所述,根据本发明可实现以下技术效果中的至少一项技术效果。As described above, at least one of the following technical effects can be achieved according to the present invention.

根据本发明,用于聚双环戊二烯树脂基体的聚双环戊二烯树脂体系(组合料)的成本比环氧树脂体系便宜30%以上,每支叶片腹板可节省1-3万元人民币,降本效果明显。According to the present invention, the cost of the polydicyclopentadiene resin system (assembly) used for the polydicyclopentadiene resin matrix is more than 30% cheaper than the epoxy resin system, and each blade web can save 10,000 to 30,000 yuan. , the cost reduction effect is obvious.

根据本发明,在用聚双环戊二烯树脂体系(组合料)灌注增强层和芯材制作腹板时,由于聚双环戊二烯树脂体系(组合料)室温下粘度小,只有10~100cps,因此其灌注速度非常快,可以缩短腹板的灌注时间约0.5-1.5个小时。According to the present invention, when the polydicyclopentadiene resin system (assembly) is used to infuse the reinforcement layer and the core material to make the web, the viscosity of the polydicyclopentadiene resin system (assembly) at room temperature is small, only 10 to 100 cps. Therefore, its perfusion speed is very fast and can shorten the perfusion time of the web by about 0.5-1.5 hours.

根据本发明,聚双环戊二烯树脂无需后固化,固化时间短,可以使生产效率大幅提高。According to the present invention, the polydicyclopentadiene resin does not require post-curing, the curing time is short, and the production efficiency can be greatly improved.

根据本发明,聚双环戊二烯树脂体系(组合料)的密度为1.03-1.05g/cm3,固化后的密度比环氧树脂体系固化后的密度小,制得的腹板重量轻3-5%,从而可实现叶片的轻量化。According to the present invention, the density of the polydicyclopentadiene resin system (assembly) is 1.03-1.05g/cm 3 , the density after curing is smaller than the density after curing of the epoxy resin system, and the web is 3-3 light in weight 5%, thus achieving lightweight blades.

另外,根据本发明,提供了一种能够解决在使用聚双环戊二烯树脂形成腹板时容易引起因浸润不良导致发白的工艺问题。In addition, according to the present invention, a method is provided that can solve the process problem of whitening caused by poor wetting when using polydicyclopentadiene resin to form a web.

尽管已经参照其示例性实施例具体描述了本发明的示例性实施例,但是本领域的技术人员应该理解,在不脱离权利要求所限定的本发明的精神和范围的情况下,可以对其进行形式和细节上的各种改变。Although exemplary embodiments of the present invention have been described in detail with reference to the exemplary embodiments thereof, those skilled in the art will understand that they may be modified without departing from the spirit and scope of the invention as defined by the appended claims. Various changes in form and detail.

Claims (16)

1. The web plate is characterized in that the web plate (10) comprises a core material and reinforcing parts (11) respectively arranged at two sides of the core material (12), and the reinforcing parts (11) comprise a polydicyclopentadiene resin matrix and reinforcing layers arranged in the polydicyclopentadiene resin matrix.
2. The web of claim 1, wherein the reinforcing layer comprises at least one of glass fibers, carbon fibers, basalt fibers, aramid fibers, and flax fibers.
3. The web according to claim 1, wherein the core material (12) comprises at least one of holes and grooves into which the polydicyclopentadiene resin matrix extends.
4. The web according to claim 1, wherein the core (12) comprises a first core (12 a) and a second core (12 b), the second core (12 b) being located at a lifting point of the web, the second core (12 b) having a strength that is greater than the strength of the first core (12 a).
5. A method of manufacturing a web, the method comprising:
paving a core material and reinforcing layers in a web plate mould, wherein the reinforcing layers are arranged on two sides of the core material;
pouring resin, wherein the resin is polydicyclopentadiene resin system;
the resin is cured.
6. The method of manufacturing according to claim 5, wherein the step of impregnating the resin includes:
disposing a vacuum system outside of the web mold;
vacuumizing and pouring resin after vacuumizing, wherein the pouring temperature of the resin is 25-35 ℃.
7. The method of manufacturing according to claim 5, wherein the step of curing the resin comprises: preserving heat at 40-60deg.C for 1-2 hr, and heating to 80-85deg.C for 3-4 hr.
8. The method of manufacturing according to claim 6, wherein the step of evacuating comprises: the vacuum was set to 0.5-0.8 atm before the resin infusion reached half.
9. The method according to claim 5, wherein the resin-impregnated tube has a diameter of 5 to 20mm.
10. The manufacturing method according to claim 9, wherein the infusion rate of the resin is gradually increased while the resin is infused.
11. The method according to claim 5, wherein the polydicyclopentadiene resin system comprises dicyclopentadiene or a dicyclopentadiene prepolymer, and the polydicyclopentadiene resin system further comprises a catalyst in an amount of 0.01 to 5 parts by weight based on 100 parts by weight of dicyclopentadiene or a dicyclopentadiene prepolymer.
12. The method of claim 11, wherein the dicyclopentadiene prepolymer is formed from dicyclopentadiene and an elastomer, and wherein the weight ratio of the elastomer to dicyclopentadiene is from 0.01 to 0.7.
13. The method of manufacture of claim 12 wherein the catalyst comprises a ruthenium catalyst, a classical two-component catalyst, a molybdenum phenolic compound or a tungsten-triphenylphosphine complex and the elastomer comprises a thermoplastic elastomer.
14. The method of manufacturing according to claim 11, wherein the method of manufacturing the polydicyclopentadiene resin system comprises:
before infusing a resin, separating dicyclopentadiene or a dicyclopentadiene prepolymer and a catalyst into an A component and a B component, wherein the A component is dicyclopentadiene or a dicyclopentadiene prepolymer and the B component is a catalyst, or the A component is a part of dicyclopentadiene or a dicyclopentadiene prepolymer and the B component is the catalyst and the rest of the dicyclopentadiene resin or prepolymer;
and respectively defoaming the component A and the component B, and then mixing.
15. A fan blade, characterized in that it comprises a web (10) according to any one of claims 1-4.
16. A wind power plant, characterized in that it comprises a wind turbine blade according to claim 15.
CN202210784896.1A 2022-06-29 2022-06-29 Web, manufacturing method of web, fan blade and wind generating set Pending CN117345553A (en)

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CN101705922A (en) * 2009-11-30 2010-05-12 株洲时代新材料科技股份有限公司 Large-scale composite material wind-power blade and preparation method thereof
US20190039337A1 (en) * 2016-02-23 2019-02-07 Lm Wp Patent Holding A/S Method of manufacturing a composite laminate structure
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