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CN117304677A - A method for preparing highly breathable resin flower troughs for flower seedling breeding - Google Patents

A method for preparing highly breathable resin flower troughs for flower seedling breeding Download PDF

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Publication number
CN117304677A
CN117304677A CN202311258226.7A CN202311258226A CN117304677A CN 117304677 A CN117304677 A CN 117304677A CN 202311258226 A CN202311258226 A CN 202311258226A CN 117304677 A CN117304677 A CN 117304677A
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flower
resin
highly breathable
breathable
seedling breeding
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黄夏辉
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Foshan Zhongxingsheng New Material Technology Co ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/02Receptacles, e.g. flower-pots or boxes; Glasses for cultivating flowers
    • A01G9/029Receptacles for seedlings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/02Receptacles, e.g. flower-pots or boxes; Glasses for cultivating flowers
    • A01G9/021Pots formed in one piece; Materials used therefor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/06Coating with compositions not containing macromolecular substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/04Condensation polymers of aldehydes or ketones with phenols only
    • C08J2361/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2497/00Characterised by the use of lignin-containing materials
    • C08J2497/02Lignocellulosic material, e.g. wood, straw or bagasse

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Cultivation Receptacles Or Flower-Pots, Or Pots For Seedlings (AREA)

Abstract

本发明涉及树脂花槽制备技术领域,具体地说,涉及一种用于花苗育种的高透气树脂花槽的制备方法。其包括以下步骤:S1.1、准备成型器具;S1.2、将高透气性树脂材料和透气改性剂混合均匀;S1.3、添加植物营养素添加剂;S1.4、将混合好的液体树脂放入成型器具中;S1.5、固化和修整;S1.6、喷涂改性涂层。该用于花苗育种的高透气树脂花槽的制备方法中,通过采用高透气性树脂材料和透气改性剂,以及改性涂层的应用,使花槽具备良好的透气性,保证花苗的气体交换和呼吸,促进其健康生长;改性涂层中的二氧化硅溶胶与透气改性剂的二次反应增加了花槽的硬度和稳定性,减少结构变形和损坏,延长花槽的使用寿命。

The present invention relates to the technical field of resin flower trough preparation, and specifically to a method for preparing a highly breathable resin flower trough used for flower seedling breeding. It includes the following steps: S1.1, prepare molding equipment; S1.2, mix the highly breathable resin material and breathable modifier evenly; S1.3, add phytonutrient additives; S1.4, mix the liquid resin Put it into the molding tool; S1.5, curing and trimming; S1.6, spray modified coating. In the preparation method of the highly breathable resin flower trough used for flower seedling breeding, through the use of highly breathable resin materials and breathable modifiers, as well as the application of modified coatings, the flower trough has good air permeability and ensures the air permeability of the flower seedlings. Exchange and respiration to promote healthy growth; the secondary reaction between the silica sol in the modified coating and the breathable modifier increases the hardness and stability of the flower trough, reduces structural deformation and damage, and extends the service life of the flower trough. .

Description

一种用于花苗育种的高透气树脂花槽的制备方法A method for preparing highly breathable resin flower troughs for flower seedling breeding

技术领域Technical field

本发明涉及树脂花槽制备技术领域,具体地说,涉及一种用于花苗育种的高透气树脂花槽的制备方法。The present invention relates to the technical field of resin flower trough preparation, and specifically to a method for preparing a highly breathable resin flower trough used for flower seedling breeding.

背景技术Background technique

传统的花槽通常由一种塑料材料制成,这种材料对于根系的透气性能比较差。根系需要充足的氧气供应来促进花苗的生长和呼吸,而传统花槽的气体交换能力有限,无法满足根系的需求。此外,传统花槽在使用过程中容易发生变形、开裂等问题,降低了花槽的稳定性和使用寿命。Traditional planters are usually made of a plastic material that has poor air permeability for roots. The roots need sufficient oxygen supply to promote the growth and respiration of flower seedlings, but the gas exchange capacity of traditional planters is limited and cannot meet the needs of the roots. In addition, traditional flower troughs are prone to deformation, cracking and other problems during use, which reduces the stability and service life of the flower troughs.

具体的,现有技术不足之处如下:Specifically, the shortcomings of the existing technology are as follows:

(1)透气性差:传统花槽通常由一种密实的塑料材料制成,这种材料限制了氧气的透过性,导致根系无法获得充足的氧气供应。缺乏足够的氧气会影响花苗的生长和呼吸,从而降低其健康状况。(1) Poor air permeability: Traditional planters are usually made of a dense plastic material, which limits the permeability of oxygen, causing the roots to be unable to obtain sufficient oxygen supply. A lack of adequate oxygen affects the growth and respiration of flower seedlings, thereby reducing their health.

(2)结构不稳定:传统花槽在长期使用过程中容易发生变形、开裂等问题,降低了花槽的稳定性和使用寿命。花槽的不稳定性可能导致根系扭曲,影响花苗的根系发育和整体生长。(2) Structural instability: Traditional flower troughs are prone to deformation, cracking and other problems during long-term use, which reduces the stability and service life of the flower troughs. The instability of the flower trough may cause the root system to twist, affecting the root development and overall growth of the flower seedlings.

(3)缺乏营养补充:传统花槽本身并没有提供植物所需的营养元素。缺乏养分的供应会限制花苗的生长和发育,从而影响其健康状态和生命力。(3) Lack of nutritional supplements: Traditional planters themselves do not provide the nutrients needed by plants. Lack of nutrient supply will limit the growth and development of flower seedlings, thereby affecting their health and vitality.

因此,需要一种具有高透气性、结构稳定性和能够为植物提供营养元素的用于花苗育种的高透气树脂花槽的制备方法来改善现有技术的不足。Therefore, a method for preparing a highly breathable resin flower trough for flower seedling breeding that has high air permeability, structural stability and can provide nutrients to plants is needed to improve the shortcomings of the existing technology.

发明内容Contents of the invention

本发明的目的在于提供一种用于花苗育种的高透气树脂花槽的制备方法,以解决上述背景技术中提出的问题。The object of the present invention is to provide a method for preparing a highly breathable resin flower trough for flower seedling breeding, so as to solve the problems raised in the above background technology.

为实现上述目的,本发明提供一种用于花苗育种的高透气树脂花槽的制备方法,包括以下步骤:In order to achieve the above object, the present invention provides a method for preparing a highly breathable resin flower trough for flower seedling breeding, which includes the following steps:

S1.1、准备成型器具;S1.1. Prepare molding equipment;

S1.2、将高透气性树脂材料和透气改性剂混合均匀;S1.2. Mix the highly breathable resin material and breathable modifier evenly;

S1.3、添加植物营养素添加剂,制得液体树脂;S1.3. Add phytonutrient additives to prepare liquid resin;

S1.4、将混合好的液体树脂放入成型器具中;在材料未完全凝固之前,将多个小孔添加到树脂花槽的底部和侧面;S1.4. Put the mixed liquid resin into the molding device; before the material is completely solidified, add multiple small holes to the bottom and sides of the resin planter;

S1.5、确保树脂花槽表面光滑;等待树脂完全凝固和固化,将树脂花槽从成型器具中取出,并进行必要的修整,制得半成品花槽;S1.5. Ensure that the surface of the resin planter is smooth; wait for the resin to completely solidify and solidify, take the resin planter out of the molding tool, and perform necessary trimming to obtain a semi-finished planter;

S1.6、将改性涂层均匀的喷涂至半成品花槽内壁和外壁,并反复多次进行喷涂;将喷涂后的半成品花槽在通风环境中晾干,然后进行固化处理,即可制得高透气树脂花槽。S1.6. Spray the modified coating evenly on the inner and outer walls of the semi-finished flower trough, and spray repeatedly; dry the sprayed semi-finished flower trough in a ventilated environment, and then solidify it to obtain Highly breathable resin planters.

优选的,所述高透性树脂材料包括多孔陶瓷材料和高分子材料,两者体积比为1:3-5。Preferably, the highly permeable resin material includes porous ceramic material and polymer material, and the volume ratio of the two is 1:3-5.

高透气性树脂材料的多孔性能让根部能够得到充足的氧气供应,促进花苗生长和呼吸;还能够保持根部的稳定性,防止根系扭曲,有助于花苗的根系发育。The porous nature of the highly breathable resin material allows the roots to receive sufficient oxygen supply, promoting the growth and respiration of the flower seedlings; it can also maintain the stability of the roots, prevent root distortion, and contribute to the root development of the flower seedlings.

优选的,所述透气改性剂包括矿物材料、植物材料和增强材料,三者体积比为5-8:2-4:1。Preferably, the breathable modifier includes mineral materials, plant materials and reinforcing materials, and the volume ratio of the three is 5-8:2-4:1.

透气改性剂能够进一步增加花槽的透气性,改善根部的通气条件,促进花苗的气体交换;还可以增加树脂材料的硬度和稳定性,提高花槽的耐久性和使用寿命。The breathable modifier can further increase the breathability of the flower trough, improve the ventilation conditions of the roots, and promote gas exchange of the flower seedlings; it can also increase the hardness and stability of the resin material and improve the durability and service life of the flower trough.

优选的,所述矿物材料采用珍珠岩、蛭石和沸石中的至少一种。Preferably, the mineral material is at least one of perlite, vermiculite and zeolite.

优选的,所述植物材料采用植物秸秆、木屑和果皮中的至少一种。Preferably, the plant material is at least one of plant straw, sawdust and peel.

优选的,所述增强材料采用竹炭粉末。Preferably, the reinforcing material is bamboo charcoal powder.

优选的,所述透气改性剂的制备方法如下:Preferably, the preparation method of the breathable modifier is as follows:

S2.1、将矿物材料进行研磨或粉碎;S2.1. Grind or crush mineral materials;

S2.2、将废弃的植物材料进行粉碎或处理;S2.2. Crush or dispose of waste plant materials;

S2.3、将矿物材料和废弃的植物材料运用特定比例混合均匀;S2.3. Mix mineral materials and waste plant materials evenly in specific proportions;

S2.4、添加增强材料,并混合均匀。S2.4. Add reinforcing materials and mix evenly.

优选的,所述植物营养素添加剂包括有机肥料和微量元素。Preferably, the plant nutrient additives include organic fertilizers and trace elements.

优选的,所述改性涂层原料包括二氧化硅溶胶和溶剂。Preferably, the modified coating raw materials include silica sol and solvent.

改性涂层中二氧化硅溶胶具有非常小的孔隙结构,可以提供优异的透气性,保证花槽内部的气体交换;同时,二氧化硅溶胶具有出色的耐候性和耐化学性,能够保护花槽不受外界环境的影响。The silica sol in the modified coating has a very small pore structure, which can provide excellent air permeability and ensure gas exchange inside the flower trough; at the same time, the silica sol has excellent weather resistance and chemical resistance, which can protect the flowers. The tank is not affected by the external environment.

通过化学和物理反应,改性涂层中的二氧化硅溶胶与透气改性剂之间形成结合,增加了花槽的结构强度,使其更加坚固、耐久,并减少开裂或变形的风险;同时,改性涂层中的二氧化硅溶胶具有非常小的孔隙结构,通过与透气改性剂的反应,进一步增强了花槽的透气性,保证了花槽内部的气体交换,促进花苗的健康生长。Through chemical and physical reactions, a bond is formed between the silica sol in the modified coating and the breathable modifier, which increases the structural strength of the planter, making it stronger and more durable, and reducing the risk of cracking or deformation; at the same time , the silica sol in the modified coating has a very small pore structure. By reacting with the breathable modifier, it further enhances the breathability of the flower trough, ensures gas exchange inside the flower trough, and promotes the healthy growth of flower seedlings. .

优选的,所述溶剂采用乙醇。Preferably, the solvent is ethanol.

与现有技术相比,本发明的有益效果:Compared with the existing technology, the beneficial effects of the present invention are:

1、该用于花苗育种的高透气树脂花槽的制备方法中,通过采用高透气性树脂材料和透气改性剂,以及改性涂层的应用,使花槽具备良好的透气性,保证花苗的气体交换和呼吸,促进其健康生长;改性涂层中的二氧化硅溶胶与透气改性剂的二次反应增加了花槽的硬度和稳定性,减少结构变形和损坏,延长花槽的使用寿命;添加植物营养素添加剂,为花苗提供所需的营养元素,促进其健康生长和发育;改性涂层具有出色的耐候性和耐化学性,能够抵抗外界环境的侵蚀,保护花槽不受外界因素的影响。1. In the preparation method of the highly breathable resin flower trough used for flower seedling breeding, through the use of highly breathable resin materials and breathable modifiers, as well as the application of modified coatings, the flower trough has good air permeability and ensures that the flower seedlings Gas exchange and respiration promote healthy growth; the secondary reaction between the silica sol in the modified coating and the breathable modifier increases the hardness and stability of the flower trough, reduces structural deformation and damage, and prolongs the life of the flower trough. Long service life; phytonutrient additives are added to provide the necessary nutrients for flower seedlings and promote their healthy growth and development; the modified coating has excellent weather resistance and chemical resistance, and can resist the erosion of the external environment and protect the flower troughs from The influence of external factors.

2、该用于花苗育种的高透气树脂花槽的制备方法中,通过引入高透气性树脂材料、透气改性剂、植物营养素添加剂和改性涂层,本发明克服了传统花槽的不足,提供了更优异的透气性能、硬度和稳定性、营养补充以及耐候性和耐化学性,为花苗育种提供更理想的生长环境。2. In the preparation method of the highly breathable resin flower trough for flower seedling breeding, the present invention overcomes the shortcomings of traditional flower troughs by introducing highly breathable resin materials, breathable modifiers, phytonutrient additives and modified coatings. It provides better breathability, hardness and stability, nutritional supplementation, weather resistance and chemical resistance, providing a more ideal growth environment for flower seedling breeding.

附图说明Description of the drawings

图1为本发明的整体流程框图。Figure 1 is an overall flow chart of the present invention.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative efforts fall within the scope of protection of the present invention.

本发明提供了一种用于花苗育种的高透气树脂花槽,包括以下材料:高透性树脂材料、透气改性剂、植物营养素添加剂和改性涂层。The invention provides a highly breathable resin flower trough for flower seedling breeding, which includes the following materials: a highly permeable resin material, a breathable modifier, a plant nutrient additive and a modified coating.

高透气性树脂材料包括多孔陶瓷材料和高分子材料,两者按体积比为1:3-5,其中:多孔陶瓷材料采用陶瓷和多孔氧化铝;高分子材料采用聚合氨酯和酚醛树脂中的一种。高透气性树脂材料的多孔性能让根部能够得到充足的氧气供应,促进花苗生长和呼吸;还能够保持根部的稳定性,防止根系扭曲,有助于花苗的根系发育。Highly breathable resin materials include porous ceramic materials and polymer materials, with a volume ratio of 1:3-5. Among them: porous ceramic materials use ceramics and porous alumina; polymer materials use polyurethane and phenolic resin. A sort of. The porous nature of the highly breathable resin material allows the roots to receive sufficient oxygen supply, promoting the growth and respiration of the flower seedlings; it can also maintain the stability of the roots, prevent root distortion, and contribute to the root development of the flower seedlings.

透气改性剂包括矿物材料、植物材料和增强材料,矿物材料、植物材料和增强材料按体积比为5-8:2-4:1;其中:矿物材料采用珍珠岩、蛭石和沸石中的至少一种;植物材料采用植物秸秆、木屑和果皮中的至少一种;增强材料采用竹炭粉末。透气改性剂能够进一步增加花槽的透气性,改善根部的通气条件,促进花苗的气体交换;还可以增加树脂材料的硬度和稳定性,提高花槽的耐久性和使用寿命。Breathable modifiers include mineral materials, plant materials and reinforcing materials. The volume ratio of mineral materials, plant materials and reinforcing materials is 5-8:2-4:1; among which: the mineral materials use at least one of perlite, vermiculite and zeolite. One kind; the plant material adopts at least one of plant straw, sawdust and peel; the reinforcing material adopts bamboo charcoal powder. The breathable modifier can further increase the breathability of the flower trough, improve the ventilation conditions of the roots, and promote gas exchange of the flower seedlings; it can also increase the hardness and stability of the resin material and improve the durability and service life of the flower trough.

透气改性剂的制备方法如下:The preparation method of breathable modifier is as follows:

(1)将矿物材料进行研磨或粉碎;(1) Grind or crush mineral materials;

(2)将废弃的植物材料进行粉碎或处理;(2) Crushing or processing of discarded plant materials;

(3)将矿物材料和废弃的植物材料运用特定比例混合均匀;(3) Mix mineral materials and waste plant materials evenly using a specific ratio;

(4)添加增强材料,并混合均匀。(4) Add reinforcing materials and mix evenly.

植物营养素添加剂包括有机肥料和微量元素。植物营养素添加剂可以为花苗提供所需的养分,包括氮、磷、钾,促进其健康生长和发育。Phytonutrient additives include organic fertilizers and trace elements. Phytonutrient additives can provide flower seedlings with the nutrients they need, including nitrogen, phosphorus, and potassium, to promote healthy growth and development.

改性涂层原料包括二氧化硅溶胶和溶剂,溶剂采用乙醇;改性涂层是将二氧化硅溶胶加入至溶剂中,搅拌均匀制得。改性涂层中二氧化硅溶胶具有非常小的孔隙结构,可以提供优异的透气性,保证花槽内部的气体交换;同时,二氧化硅溶胶具有出色的耐候性和耐化学性,能够保护花槽不受外界环境的影响。The raw materials of the modified coating include silica sol and solvent, and the solvent is ethanol; the modified coating is prepared by adding silica sol to the solvent and stirring evenly. The silica sol in the modified coating has a very small pore structure, which can provide excellent air permeability and ensure gas exchange inside the flower trough; at the same time, the silica sol has excellent weather resistance and chemical resistance, which can protect the flowers. The tank is not affected by the external environment.

此外,改性涂层可以与花槽中的透气改性剂发生二次反应,增加花槽的硬度和稳定性;可以使花槽更加坚固,减少开裂或变形的风险;具体的:In addition, the modified coating can react secondary with the breathable modifier in the flower trough to increase the hardness and stability of the flower trough; it can make the flower trough stronger and reduce the risk of cracking or deformation; specifically:

二氧化硅溶胶中的羟基与透气改性剂中的官能团发生缩合反应或亲核取代反应;例如,二氧化硅溶胶中的羟基与透气改性剂中的羧基进行酯化反应或酰胺化反应。The hydroxyl groups in the silica sol undergo a condensation reaction or nucleophilic substitution reaction with the functional groups in the breathable modifier; for example, the hydroxyl groups in the silica sol undergo an esterification or amidation reaction with the carboxyl groups in the breathable modifier.

二氧化硅溶胶的表面和透气改性剂之间发生物理吸附或静电作用;例如,二氧化硅溶胶的表面可能吸附透气改性剂的分子,并通过氢键或范德华力等相互作用力形成结合。Physical adsorption or electrostatic interaction occurs between the surface of the silica sol and the breathable modifier; for example, the surface of the silica sol may adsorb molecules of the breathable modifier and form bonds through interaction forces such as hydrogen bonds or van der Waals forces. .

通过化学和物理反应,改性涂层中的二氧化硅溶胶与透气改性剂之间形成结合,增加了花槽的结构强度,使其更加坚固、耐久,并减少开裂或变形的风险;同时,改性涂层中的二氧化硅溶胶具有非常小的孔隙结构,通过与透气改性剂的反应,进一步增强了花槽的透气性,保证了花槽内部的气体交换,促进花苗的健康生长。Through chemical and physical reactions, a bond is formed between the silica sol in the modified coating and the breathable modifier, which increases the structural strength of the planter, making it stronger and more durable, and reducing the risk of cracking or deformation; at the same time , the silica sol in the modified coating has a very small pore structure. By reacting with the breathable modifier, it further enhances the breathability of the flower trough, ensures gas exchange inside the flower trough, and promotes the healthy growth of flower seedlings. .

根据图1所示,本发明还提供了一种用于花苗育种的高透气树脂花槽的制备方法,具体步骤如下:As shown in Figure 1, the present invention also provides a method for preparing a highly breathable resin flower trough for flower seedling breeding. The specific steps are as follows:

(1)准备成型器具,尺寸和形状根据需要进行调整。(1) Prepare the molding tool, and adjust the size and shape as needed.

(2)将高透气性树脂材料和透气改性剂按照比例混合均匀,确保透气改性剂均匀分布在树脂材料中。(2) Mix the highly breathable resin material and the breathable modifier evenly according to the proportion to ensure that the breathable modifier is evenly distributed in the resin material.

(3)添加植物营养素添加剂,提供植物所需的营养元素,制得液体树脂;(3) Add phytonutrient additives to provide the nutrients needed by plants to prepare liquid resin;

(4)将混合好的液体树脂放入成型器具中,确保材料充分填充成型器具的每个细节位置;在材料未完全凝固之前,将多个小孔添加到树脂花槽的底部和侧面,以增加气体的透过性;(4) Put the mixed liquid resin into the molding utensil, making sure that the material fully fills every detail of the molding utensil; before the material is completely solidified, add multiple small holes to the bottom and sides of the resin planter to Increase gas permeability;

(5)确保树脂花槽表面光滑,并在适当的位置上加入握把或其他便于携带和移动的装置;等待树脂完全凝固和固化,将树脂花槽从成型器具中取出,并进行必要的修整,如修剪边缘或去除多余的树脂,制得半成品花槽;(5) Make sure the surface of the resin planter is smooth, and add a handle or other device at the appropriate position to facilitate carrying and moving; wait for the resin to completely solidify and solidify, take the resin planter out of the molding device, and make necessary modifications , such as trimming the edges or removing excess resin to make semi-finished planters;

(6)将改性涂层均匀的喷涂至半成品花槽内壁和外壁,并反复多次进行喷涂;将喷涂后的半成品花槽在通风环境中晾干,然后进行固化处理,即可制得高透气树脂花槽。(6) Evenly spray the modified coating on the inner and outer walls of the semi-finished flower trough, and spray it repeatedly; dry the sprayed semi-finished flower trough in a ventilated environment, and then solidify it to make a high-quality Breathable resin planters.

本发明中,通过采用高透气性树脂材料和透气改性剂,以及改性涂层的应用,使花槽具备良好的透气性,保证花苗的气体交换和呼吸,促进其健康生长;改性涂层中的二氧化硅溶胶与透气改性剂的二次反应增加了花槽的硬度和稳定性,减少结构变形和损坏,延长花槽的使用寿命;添加植物营养素添加剂,为花苗提供所需的营养元素,促进其健康生长和发育;改性涂层具有出色的耐候性和耐化学性,能够抵抗外界环境的侵蚀,保护花槽不受外界因素的影响。In the present invention, through the use of highly breathable resin materials and breathable modifiers, as well as the application of modified coatings, the flower troughs have good air permeability, ensuring the gas exchange and breathing of the flower seedlings, and promoting their healthy growth; the modified coating The secondary reaction between the silica sol in the layer and the breathable modifier increases the hardness and stability of the flower trough, reduces structural deformation and damage, and extends the service life of the flower trough; phytonutrient additives are added to provide the flower seedlings with the necessary Nutrient elements promote healthy growth and development; the modified coating has excellent weather resistance and chemical resistance, can resist the erosion of the external environment, and protect the planter from external factors.

综上所述,通过引入高透气性树脂材料、透气改性剂、植物营养素添加剂和改性涂层,本发明克服了传统花槽的不足,提供了更优异的透气性能、硬度和稳定性、营养补充以及耐候性和耐化学性,为花苗育种提供更理想的生长环境。In summary, by introducing highly breathable resin materials, breathable modifiers, phytonutrient additives and modified coatings, the present invention overcomes the shortcomings of traditional flower troughs and provides more excellent breathability, hardness and stability. Nutritional supplementation, weather resistance and chemical resistance provide a more ideal growth environment for flower seedling breeding.

根据不同的原料用量,通过以下具体的实施例来对本发明提供的用于花苗育种的高透气树脂花槽的制备方法进一步说明。According to different amounts of raw materials, the preparation method of the highly breathable resin flower trough for flower seedling breeding provided by the present invention is further explained through the following specific examples.

实施例1Example 1

(1)准备成型器具,尺寸和形状根据需要进行调整。(1) Prepare the molding tool, and adjust the size and shape as needed.

(2)将多孔陶瓷材料和高分子材料,两者按体积比为1:3制得高透气性树脂材料;将矿物材料、植物材料和增强材料按体积比为5:2:1制得透气改性剂。(2) Combine porous ceramic materials and polymer materials at a volume ratio of 1:3 to produce a highly breathable resin material; combine mineral materials, plant materials and reinforcing materials at a volume ratio of 5:2:1 to produce a breathable resin material. Modifier.

(3)将60重量份的高透气性树脂材料和10重量份的透气改性剂混合均匀,确保透气改性剂均匀分布在树脂材料中。(3) Mix 60 parts by weight of highly breathable resin material and 10 parts by weight of breathable modifier evenly to ensure that the breathable modifier is evenly distributed in the resin material.

(4)添加3重量份的植物营养素添加剂,提供植物所需的营养元素,制得液体树脂;(4) Add 3 parts by weight of phytonutrient additives to provide the nutrients needed by plants to prepare liquid resin;

(5)将混合好的液体树脂放入成型器具中,确保材料充分填充成型器具的每个细节位置;在材料未完全凝固之前,将多个小孔添加到树脂花槽的底部和侧面,以增加气体的透过性;(5) Put the mixed liquid resin into the molding utensil, making sure that the material fully fills every detail of the molding utensil; before the material is completely solidified, add multiple small holes to the bottom and sides of the resin planter to Increase gas permeability;

(6)确保树脂花槽表面光滑,并在适当的位置上加入握把或其他便于携带和移动的装置;等待树脂完全凝固和固化,将树脂花槽从成型器具中取出,并进行必要的修整,如修剪边缘或去除多余的树脂,制得半成品花槽;(6) Make sure the surface of the resin planter is smooth, and add a handle or other device at the appropriate position to facilitate carrying and moving; wait for the resin to completely solidify and solidify, take the resin planter out of the molding device, and make necessary modifications , such as trimming the edges or removing excess resin to make semi-finished planters;

(7)将改性涂层均匀的喷涂至半成品花槽内壁和外壁,并反复多次进行喷涂;将喷涂后的半成品花槽在通风环境中晾干,然后进行固化处理,即可制得高透气树脂花槽。(7) Evenly spray the modified coating on the inner and outer walls of the semi-finished flower trough, and spray it repeatedly; dry the sprayed semi-finished flower trough in a ventilated environment, and then solidify it to make a high-quality Breathable resin planters.

实施例2Example 2

(1)准备成型器具,尺寸和形状根据需要进行调整。(1) Prepare the molding tool, and adjust the size and shape as needed.

(2)将多孔陶瓷材料和高分子材料,两者按体积比为1:4制得高透气性树脂材料;将矿物材料、植物材料和增强材料按体积比为6:3:1制得透气改性剂。(2) Combine porous ceramic materials and polymer materials at a volume ratio of 1:4 to produce a highly breathable resin material; combine mineral materials, plant materials and reinforcing materials at a volume ratio of 6:3:1 to produce a breathable resin material. Modifier.

(3)将50重量份的高透气性树脂材料和15重量份的透气改性剂混合均匀,确保透气改性剂均匀分布在树脂材料中。(3) Mix 50 parts by weight of highly breathable resin material and 15 parts by weight of breathable modifier evenly to ensure that the breathable modifier is evenly distributed in the resin material.

(4)添加2重量份的植物营养素添加剂,提供植物所需的营养元素,制得液体树脂;(4) Add 2 parts by weight of phytonutrient additives to provide the nutrients needed by plants to prepare liquid resin;

(5)将混合好的液体树脂放入成型器具中,确保材料充分填充成型器具的每个细节位置;在材料未完全凝固之前,将多个小孔添加到树脂花槽的底部和侧面,以增加气体的透过性;(5) Put the mixed liquid resin into the molding utensil, making sure that the material fully fills every detail of the molding utensil; before the material is completely solidified, add multiple small holes to the bottom and sides of the resin planter to Increase gas permeability;

(6)确保树脂花槽表面光滑,并在适当的位置上加入握把或其他便于携带和移动的装置;等待树脂完全凝固和固化,将树脂花槽从成型器具中取出,并进行必要的修整,如修剪边缘或去除多余的树脂,制得半成品花槽;(6) Make sure the surface of the resin planter is smooth, and add a handle or other device at the appropriate position to facilitate carrying and moving; wait for the resin to completely solidify and solidify, take the resin planter out of the molding device, and make necessary modifications , such as trimming the edges or removing excess resin to make semi-finished planters;

(7)将改性涂层均匀的喷涂至半成品花槽内壁和外壁,并反复多次进行喷涂;将喷涂后的半成品花槽在通风环境中晾干,然后进行固化处理,即可制得高透气树脂花槽。(7) Evenly spray the modified coating on the inner and outer walls of the semi-finished flower trough, and spray it repeatedly; dry the sprayed semi-finished flower trough in a ventilated environment, and then solidify it to make a high-quality Breathable resin planters.

实施例3Example 3

(1)准备成型器具,尺寸和形状根据需要进行调整。(1) Prepare the molding tool, and adjust the size and shape as needed.

(2)将多孔陶瓷材料和高分子材料,两者按体积比为1:5制得高透气性树脂材料;将矿物材料、植物材料和增强材料按体积比为8:4:1制得透气改性剂。(2) Combine porous ceramic materials and polymer materials at a volume ratio of 1:5 to produce a highly breathable resin material; combine mineral materials, plant materials and reinforcing materials at a volume ratio of 8:4:1 to produce a breathable resin material. Modifier.

(3)将40重量份的高透气性树脂材料和20重量份的透气改性剂混合均匀,确保透气改性剂均匀分布在树脂材料中。(3) Mix 40 parts by weight of highly breathable resin material and 20 parts by weight of breathable modifier evenly to ensure that the breathable modifier is evenly distributed in the resin material.

(4)添加1重量份的植物营养素添加剂,提供植物所需的营养元素,制得液体树脂;(4) Add 1 part by weight of phytonutrient additives to provide the nutrients needed by plants to prepare liquid resin;

(5)将混合好的液体树脂放入成型器具中,确保材料充分填充成型器具的每个细节位置;在材料未完全凝固之前,将多个小孔添加到树脂花槽的底部和侧面,以增加气体的透过性;(5) Put the mixed liquid resin into the molding utensil, making sure that the material fully fills every detail of the molding utensil; before the material is completely solidified, add multiple small holes to the bottom and sides of the resin planter to Increase gas permeability;

(6)确保树脂花槽表面光滑,并在适当的位置上加入握把或其他便于携带和移动的装置;等待树脂完全凝固和固化,将树脂花槽从成型器具中取出,并进行必要的修整,如修剪边缘或去除多余的树脂,制得半成品花槽;(6) Make sure the surface of the resin planter is smooth, and add a handle or other device at the appropriate position to facilitate carrying and moving; wait for the resin to completely solidify and solidify, take the resin planter out of the molding device, and make necessary modifications , such as trimming the edges or removing excess resin to make semi-finished planters;

(7)将改性涂层均匀的喷涂至半成品花槽内壁和外壁,并反复多次进行喷涂;将喷涂后的半成品花槽在通风环境中晾干,然后进行固化处理,即可制得高透气树脂花槽。(7) Evenly spray the modified coating on the inner and outer walls of the semi-finished flower trough, and spray it repeatedly; dry the sprayed semi-finished flower trough in a ventilated environment, and then solidify it to make a high-quality Breathable resin planters.

表1实施例1-3工艺参数Table 1 Embodiment 1-3 process parameters

为了验证本发明实施例制备的树脂花槽具有较好的透气性和结构稳定性,通过以下试验例来对本发明实施例提供的用于花苗育种的高透气树脂花槽的制备方法进行说明。In order to verify that the resin planters prepared in the embodiments of the present invention have better air permeability and structural stability, the following test examples are used to illustrate the preparation method of the highly breathable resin planters for flower seedling breeding provided by the embodiments of the present invention.

试验例Test example

本试验例目的在于比较高透气树脂花槽和传统塑料花槽的透气性和结构稳定性;The purpose of this test example is to compare the air permeability and structural stability of highly breathable resin planters and traditional plastic planters;

试验材料:试验组(A,B,C),为实施例1-3分别提供的树脂花槽;对照组,为传统塑料花槽;气泵;氧气浓度测量仪;结构稳定性测试装置。Test materials: The test group (A, B, C) is the resin planter provided in Examples 1-3 respectively; the control group is the traditional plastic planter; air pump; oxygen concentration measuring instrument; structural stability testing device.

试验方法:experiment method:

(1)准备相同尺寸和形状的高透气树脂花槽和传统塑料花槽。(1) Prepare highly breathable resin planters and traditional plastic planters of the same size and shape.

(2)连接气泵和各个花槽内部的小孔;打开气泵,提供稳定的氧气输送至花槽内。(2) Connect the air pump to the small holes inside each flower trough; turn on the air pump to provide stable oxygen delivery to the flower troughs.

(4)使用氧气浓度测量仪分别测量两种花槽内的氧气浓度,记录数据。(4) Use an oxygen concentration meter to measure the oxygen concentration in the two flower troughs and record the data.

(5)观察两种花槽内氧气的通透性,检查是否有氧气泄漏现象。(5) Observe the oxygen permeability in the two flower troughs and check whether there is oxygen leakage.

(6)使用结构稳定性测试装置分别对两种花槽进行结构稳定性测试,观察是否有变形、开裂等情况。(6) Use a structural stability testing device to test the structural stability of the two flower troughs to observe whether there are deformations, cracks, etc.

具体检测指标见表2。The specific detection indicators are shown in Table 2.

表2Table 2

试验组AExperimental group A 试验组BExperimental group B 试验组CExperimental group C 对照组control group 氧气浓度(%)Oxygen concentration (%) 24twenty four 2727 2626 1919 变形现象deformation phenomenon none none none 轻微变形slight deformation 开裂现象Cracking phenomenon none none none 出现细微开裂Minor cracks appear

根据表2所示,本发明提供的高透气树脂花槽在透气性和结构稳定性方面表现优于传统塑料花槽;高透气树脂花槽的氧气浓度稳定在室内空气水平,能够提供充足的氧气供应给花苗;同时,高透气树脂花槽表现出良好的结构稳定性,无变形和开裂现象;相比之下,传统塑料花槽在透气性和结构稳定性方面不如高透气树脂花。As shown in Table 2, the highly breathable resin planters provided by the present invention are better than traditional plastic planters in terms of air permeability and structural stability; the oxygen concentration of the highly breathable resin planters is stable at indoor air levels and can provide sufficient oxygen. Supply to flower seedlings; at the same time, highly breathable resin flower troughs show good structural stability without deformation and cracking; in comparison, traditional plastic flower troughs are not as good as highly breathable resin flowers in terms of air permeability and structural stability.

综上所述,采用本发明制备方法提供的树脂花槽具有较好的透气性能和结构稳定性。To sum up, the resin flower trough provided by the preparation method of the present invention has better air permeability and structural stability.

以上显示和描述了本发明的基本原理、主要特征和本发明的优点。本领域技术人员应该了解,本发明不受上述实施例的限制,上述实施例和说明书中描述的仅为本发明的优选例,并不用来限制本发明,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。The basic principles, main features and advantages of the present invention have been shown and described above. Those skilled in the art should understand that the present invention is not limited by the above-mentioned embodiments. The above-mentioned embodiments and descriptions are only preferred examples of the present invention and are not used to limit the present invention without departing from the spirit and scope of the present invention. There will also be various changes and improvements in the present invention, and these changes and improvements all fall within the scope of the claimed invention. The scope of protection of the present invention is defined by the appended claims and their equivalents.

Claims (10)

1.一种用于花苗育种的高透气树脂花槽的制备方法,其特征在于,包括以下步骤:1. A method for preparing highly breathable resin flower troughs for flower seedling breeding, which is characterized by comprising the following steps: S1.1、准备成型器具;S1.1. Prepare molding equipment; S1.2、将高透气性树脂材料和透气改性剂混合均匀;S1.2. Mix the highly breathable resin material and breathable modifier evenly; S1.3、添加植物营养素添加剂,制得液体树脂;S1.3. Add phytonutrient additives to prepare liquid resin; S1.4、将混合好的液体树脂放入成型器具中;在材料未完全凝固之前,将多个小孔添加到树脂花槽的底部和侧面;S1.4. Put the mixed liquid resin into the molding device; before the material is completely solidified, add multiple small holes to the bottom and sides of the resin planter; S1.5、确保树脂花槽表面光滑;等待树脂完全凝固和固化,将树脂花槽从成型器具中取出,并进行必要的修整,制得半成品花槽;S1.5. Ensure that the surface of the resin planter is smooth; wait for the resin to completely solidify and solidify, take the resin planter out of the molding tool, and perform necessary trimming to obtain a semi-finished planter; S1.6、将改性涂层均匀的喷涂至半成品花槽内壁和外壁,并反复多次进行喷涂;将喷涂后的半成品花槽在通风环境中晾干,然后进行固化处理,即可制得高透气树脂花槽。S1.6. Spray the modified coating evenly on the inner and outer walls of the semi-finished flower trough, and spray repeatedly; dry the sprayed semi-finished flower trough in a ventilated environment, and then solidify it to obtain Highly breathable resin planter. 2.根据权利要求1所述的用于花苗育种的高透气树脂花槽的制备方法,其特征在于:所述高透性树脂材料包括多孔陶瓷材料和高分子材料,两者体积比为1:3-5。2. The preparation method of a highly breathable resin flower trough for flower seedling breeding according to claim 1, characterized in that: the highly permeable resin material includes porous ceramic materials and polymer materials, and the volume ratio of the two is 1: 3-5. 3.根据权利要求1所述的用于花苗育种的高透气树脂花槽的制备方法,其特征在于:所述透气改性剂包括矿物材料、植物材料和增强材料,三者体积比为5-8:2-4:1。3. The preparation method of highly breathable resin flower troughs for flower seedling breeding according to claim 1, characterized in that: the breathable modifier includes mineral materials, plant materials and reinforcing materials, and the volume ratio of the three is 5- 8:2-4:1. 4.根据权利要求3所述的用于花苗育种的高透气树脂花槽的制备方法,其特征在于:所述矿物材料采用珍珠岩、蛭石和沸石中的至少一种。4. The method for preparing a highly breathable resin flower trough for flower seedling breeding according to claim 3, characterized in that the mineral material is at least one of perlite, vermiculite and zeolite. 5.根据权利要求3所述的用于花苗育种的高透气树脂花槽的制备方法,其特征在于:所述植物材料采用植物秸秆、木屑和果皮中的至少一种。5. The method for preparing a highly breathable resin flower trough for flower seedling breeding according to claim 3, wherein the plant material is at least one of plant straw, sawdust and peel. 6.根据权利要求3所述的用于花苗育种的高透气树脂花槽的制备方法,其特征在于:所述增强材料采用竹炭粉末。6. The method for preparing highly breathable resin flower troughs for flower seedling breeding according to claim 3, characterized in that: the reinforcing material adopts bamboo charcoal powder. 7.根据权利要求3所述的用于花苗育种的高透气树脂花槽的制备方法,其特征在于:所述透气改性剂的制备方法如下:7. The preparation method of highly breathable resin flower troughs for flower seedling breeding according to claim 3, characterized in that: the preparation method of the breathable modifier is as follows: S2.1、将矿物材料进行研磨或粉碎;S2.1. Grind or crush mineral materials; S2.2、将废弃的植物材料进行粉碎或处理;S2.2. Crush or dispose of waste plant materials; S2.3、将矿物材料和废弃的植物材料运用特定比例混合均匀;S2.3. Mix mineral materials and waste plant materials evenly in specific proportions; S2.4、添加增强材料,并混合均匀。S2.4. Add reinforcing materials and mix evenly. 8.根据权利要求1所述的用于花苗育种的高透气树脂花槽的制备方法,其特征在于:所述植物营养素添加剂包括有机肥料和微量元素。8. The method for preparing highly breathable resin flower troughs for flower seedling breeding according to claim 1, characterized in that: the plant nutrient additives include organic fertilizers and trace elements. 9.根据权利要求1所述的用于花苗育种的高透气树脂花槽的制备方法,其特征在于:所述改性涂层原料包括二氧化硅溶胶和溶剂。9. The method for preparing highly breathable resin flower troughs for flower seedling breeding according to claim 1, characterized in that: the modified coating raw materials include silica sol and solvent. 10.根据权利要求9所述的用于花苗育种的高透气树脂花槽的制备方法,其特征在于:所述溶剂采用乙醇。10. The method for preparing highly breathable resin flower troughs for flower seedling breeding according to claim 9, characterized in that: the solvent is ethanol.
CN202311258226.7A 2023-09-27 2023-09-27 A method for preparing highly breathable resin flower troughs for flower seedling breeding Pending CN117304677A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020071944A1 (en) * 1998-04-21 2002-06-13 Hugh C. Gardner Breathable composite and method therefor
CN102668917A (en) * 2012-06-07 2012-09-19 江素霞 Fast rooting flowerpot device and using method thereof
CN108849034A (en) * 2018-05-22 2018-11-23 万卓(武汉)新材料有限公司 A kind of ventilative damping flowerpot and preparation method thereof
CN214229059U (en) * 2021-01-05 2021-09-21 福建省德化鑫东宝瓷业有限公司 Air-permeable ceramic flowerpot
CN115926412A (en) * 2022-12-30 2023-04-07 江苏常阳科技有限公司 Molding compound for waterproof and breathable flowerpot and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020071944A1 (en) * 1998-04-21 2002-06-13 Hugh C. Gardner Breathable composite and method therefor
CN102668917A (en) * 2012-06-07 2012-09-19 江素霞 Fast rooting flowerpot device and using method thereof
CN108849034A (en) * 2018-05-22 2018-11-23 万卓(武汉)新材料有限公司 A kind of ventilative damping flowerpot and preparation method thereof
CN214229059U (en) * 2021-01-05 2021-09-21 福建省德化鑫东宝瓷业有限公司 Air-permeable ceramic flowerpot
CN115926412A (en) * 2022-12-30 2023-04-07 江苏常阳科技有限公司 Molding compound for waterproof and breathable flowerpot and preparation method thereof

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