CN116950661B - Deep sea mining plume suppression device and method based on carbon dioxide emulsion - Google Patents
Deep sea mining plume suppression device and method based on carbon dioxide emulsion Download PDFInfo
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 157
- 239000000839 emulsion Substances 0.000 title claims abstract description 132
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 90
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 90
- 238000005065 mining Methods 0.000 title claims abstract description 38
- 230000001629 suppression Effects 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 16
- 230000007246 mechanism Effects 0.000 claims abstract description 54
- 239000013535 sea water Substances 0.000 claims abstract description 38
- 238000003860 storage Methods 0.000 claims abstract description 34
- 239000013543 active substance Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 238000002347 injection Methods 0.000 claims abstract description 7
- 239000007924 injection Substances 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 22
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- 241000405070 Percophidae Species 0.000 claims 1
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- 238000003786 synthesis reaction Methods 0.000 claims 1
- 238000004945 emulsification Methods 0.000 abstract description 52
- 239000013049 sediment Substances 0.000 abstract description 12
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- 239000007921 spray Substances 0.000 abstract description 3
- 150000004677 hydrates Chemical class 0.000 abstract 1
- 210000003954 umbilical cord Anatomy 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000009919 sequestration Effects 0.000 description 4
- VTVVPPOHYJJIJR-UHFFFAOYSA-N carbon dioxide;hydrate Chemical compound O.O=C=O VTVVPPOHYJJIJR-UHFFFAOYSA-N 0.000 description 3
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
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- 239000000243 solution Substances 0.000 description 2
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- 206010003497 Asphyxia Diseases 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
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- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- CDIPRYKTRRRSEM-UHFFFAOYSA-M docosyl(trimethyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C CDIPRYKTRRRSEM-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21C—MINING OR QUARRYING
- E21C50/00—Obtaining minerals from underwater, not otherwise provided for
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- Mining & Mineral Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
本发明公开基于二氧化碳乳液的深海采矿羽流抑制装置及方法,包括二氧化碳存储单元、乳化单元、乳液喷射单元及电控单元,乳化单元包括增压机构、海水供入机构、活性剂供入机构和乳化容器,乳化容器内设有搅拌机构,二氧化碳存储单元通过增压机构与乳化容器相连。海水供入机构一端与外界相连,另一端与乳化容器相连,活性剂供入机构与乳化容器相连。乳液喷射单元包括乳液输送管和三组乳液喷嘴,乳液输送管与乳化容器相连,两组乳液喷嘴对称设在乳液输送管两侧,另外一组乳液喷嘴设在乳液输送管后侧。本发明使用二氧化碳包水型乳液形成覆盖层,压迫羽流快速沉降至深海海底,二氧化碳将与沉积物的孔隙水生成水合物,长期留置在海底。
The invention discloses a deep sea mining plume suppression device and method based on carbon dioxide emulsion, which includes a carbon dioxide storage unit, an emulsification unit, an emulsion injection unit and an electronic control unit. The emulsification unit includes a pressurization mechanism, a seawater supply mechanism, an active agent supply mechanism and The emulsification container is equipped with a stirring mechanism, and the carbon dioxide storage unit is connected to the emulsification container through a pressurizing mechanism. One end of the seawater supply mechanism is connected to the outside world, the other end is connected to the emulsification container, and the active agent supply mechanism is connected to the emulsification container. The emulsion spray unit includes an emulsion delivery pipe and three sets of emulsion nozzles. The emulsion delivery pipe is connected to the emulsification container. Two sets of emulsion nozzles are symmetrically located on both sides of the emulsion delivery pipe, and the other set of emulsion nozzles is located on the rear side of the emulsion delivery pipe. The invention uses a carbon dioxide water-in-water emulsion to form a covering layer, forcing the plume to rapidly sink to the deep sea bottom. The carbon dioxide will form hydrates with the pore water of the sediment and remain on the bottom of the sea for a long time.
Description
技术领域Technical field
本发明涉及海洋环境治理技术领域,具体涉及基于二氧化碳乳液的深海采矿羽流抑制装置及方法。The invention relates to the technical field of marine environment management, and in particular to a deep sea mining plume suppression device and method based on carbon dioxide emulsion.
背景技术Background technique
深海多金属结核是锰、钴、镍、锂等战略金属的重要来源,赋存于4000~6000米水深的海底表层沉积物中。多金属结核状如土豆,呈现面式分布规律,赋存地形为较平坦的海底平原或盆地,海底履带车是目前最具商业化前景的集矿装备。履带式集矿车作业过程中,水射流冲采矿石和车辆行走都会扰动海底稀软底质,使得沉积颗粒上浮扩散形成羽流。羽流一经形成,可扩散几千公里距离,羽流中携带的细小颗粒将导致海底生物窒息和大规模死亡,严重破坏生态系统。Deep-sea polymetallic nodules are an important source of strategic metals such as manganese, cobalt, nickel, and lithium, and are found in seafloor surface sediments at water depths of 4,000 to 6,000 meters. Polymetallic nodules are shaped like potatoes, showing a planar distribution pattern, and occur in relatively flat submarine plains or basins. Undersea crawler vehicles are currently the most commercially promising ore-gathering equipment. During the operation of the crawler-type mine collector, the water jet flushing the ore and the movement of the vehicle will disturb the thin and soft bottom of the seabed, causing the sediment particles to float up and spread to form a plume. Once a plume is formed, it can spread for thousands of kilometers. The fine particles carried in the plume will cause suffocation and mass death of seabed organisms, seriously damaging the ecosystem.
针对深海采矿羽流问题,中国专利CN215977448U公开了一种深海矿车扰动羽流抑制装置,包含颗粒物分离器、大吸力深海高压泵、羽状流抽吸口、管路,高压泵产生吸力将羽流吸入抽吸口,在颗粒物分离器内分离压实颗粒物后排放到海底。中国专利CN115653608B公开了一种基于二氧化碳的深海采矿羽流抑制封存装置及方法,包括羽流收集单元、泵吸管组、分离沉降单元及固化排放单元,工作时将羽流吸入固化沉淀仓,使用液态二氧化碳固化后排放至海底。现有的两项专利都采用抽吸方法将羽流引导至车体内部作进一步处理,但抽吸过程本身会引起海底流场改变,羽流影响范围可能会进一步扩大。因此,现有羽流抑制技术亟待进一步改进。In response to the problem of deep-sea mining plumes, Chinese patent CN215977448U discloses a deep-sea mine car disturbance plume suppression device, which includes a particle separator, a large-suction deep-sea high-pressure pump, a plume flow suction port, and pipelines. The high-pressure pump generates suction to remove the plume. The flow is sucked into the suction port, and the particles are separated and compacted in the particle separator and then discharged to the seabed. Chinese patent CN115653608B discloses a carbon dioxide-based deep sea mining plume suppression and storage device and method, which includes a plume collection unit, a pump suction pipe group, a separation and settlement unit and a solidification discharge unit. During operation, the plume is sucked into the solidification sedimentation bin, using liquid The carbon dioxide solidifies and is released to the seafloor. The two existing patents use a suction method to guide the plume into the interior of the vehicle body for further processing. However, the suction process itself will cause changes in the seafloor flow field, and the impact range of the plume may be further expanded. Therefore, existing plume suppression technology urgently needs further improvement.
发明内容Contents of the invention
针对上述现有技术的不足,本发明的一个目的在于提出基于二氧化碳乳液的深海采矿羽流抑制装置,解决集矿车在射流采集和行走过程中产生的羽状流,对海洋环境造成严重破坏,以及导致后续深海采矿作业无法进行的问题。In view of the shortcomings of the above-mentioned existing technologies, one purpose of the present invention is to propose a deep-sea mining plume suppression device based on carbon dioxide emulsion to solve the problem of plumes generated by mine trucks during jet collection and walking, which cause serious damage to the marine environment. and problems that make subsequent deep-sea mining operations impossible.
为了解决上述技术问题,本发明所采用的技术方案是:In order to solve the above technical problems, the technical solution adopted by the present invention is:
基于二氧化碳乳液的深海采矿羽流抑制装置,包括二氧化碳存储单元、乳化单元、乳液喷射单元及电控单元,所述二氧化碳存储单元包括设在采矿车上的中继仓和脐带管线,所述中继仓通过所述脐带管线能够与水面支持母船上的二氧化成制备单元相连。A deep sea mining plume suppression device based on carbon dioxide emulsion includes a carbon dioxide storage unit, an emulsification unit, an emulsion injection unit and an electronic control unit. The carbon dioxide storage unit includes a relay bin and an umbilical cord pipeline installed on the mining vehicle. The relay The warehouse can be connected to the dioxide production unit on the surface support mother ship through the umbilical cord pipeline.
乳化单元包括增压机构、海水供入机构、活性剂供入机构和乳化容器,乳化容器内部设有搅拌机构,中继仓的出口端通过所述增压机构与乳化容器的内部相连相通。The emulsification unit includes a pressurizing mechanism, a seawater supply mechanism, an active agent supplying mechanism and an emulsification container. A stirring mechanism is provided inside the emulsification container, and the outlet end of the relay bin is connected to the interior of the emulsification container through the pressurization mechanism.
海水供入机构位于乳化容器的一侧,其一端与外界相连,另一端与乳化容器的内部相连,能够将过滤后的海水送至乳化容器内。The seawater supply mechanism is located on one side of the emulsification container, with one end connected to the outside and the other end connected to the inside of the emulsification container, capable of sending filtered seawater into the emulsification container.
活性剂供入机构与乳化容器相连相通,将表面活性剂供入至乳化容器内。The active agent supply mechanism is connected with the emulsification container and supplies the surfactant into the emulsification container.
乳液喷射单元包括乳液输送管和三组乳液喷嘴,乳液输送管与乳化容器相连,包裹于矿石暂存箱的外侧,其左右两侧向外横向延伸形成延伸部分。The emulsion injection unit includes an emulsion delivery pipe and three sets of emulsion nozzles. The emulsion delivery pipe is connected to the emulsification container and wrapped around the outside of the ore temporary storage box. Its left and right sides extend outward laterally to form an extension part.
两组乳液喷嘴对称设置在乳液输送管的左右两侧,另外一组乳液喷嘴设置在乳液输送管的后侧,工作状态下,由乳化容器制备得到的二氧化碳包水型乳液经过乳液喷嘴向采矿车周边喷洒。Two sets of emulsion nozzles are symmetrically arranged on the left and right sides of the emulsion delivery pipe, and the other set of emulsion nozzles is set on the rear side of the emulsion delivery pipe. Under working conditions, the water-in-carbonate emulsion prepared from the emulsification container passes through the emulsion nozzles to the mining vehicle. Spray around.
进一步地,所述中继仓固定安装在矿石暂存箱内部,脐带管线的一端与中继仓的顶部相连,另一端连接水面支持母船上的二氧化成制备单元,中继仓通过脐带管线接收并存储来自水面支持母船的二氧化碳。Further, the relay warehouse is fixedly installed inside the ore temporary storage box. One end of the umbilical cord pipeline is connected to the top of the relay warehouse, and the other end is connected to the carbon dioxide preparation unit on the water surface support mother ship. The relay warehouse receives the umbilical cord pipeline. and store carbon dioxide from the surface support mother ship.
进一步地,增压机构包括增压泵和高压罐体,所述高压罐体设置在矿石暂存箱内部,通过第一管路与中继仓的出口端相连相通。Further, the boosting mechanism includes a boosting pump and a high-pressure tank. The high-pressure tank is arranged inside the ore temporary storage tank and is connected to the outlet end of the relay bin through the first pipeline.
增压泵设置在第一管路上,其信号端与电控单元通讯相连。The booster pump is arranged on the first pipeline, and its signal end is communicatively connected with the electronic control unit.
高压罐体与乳化容器管路相连,所述高压罐体和乳化容器之间设有流量阀一,流量阀一的信号端与电控单元通讯相连。The high-pressure tank is connected to the pipeline of the emulsification container. There is a flow valve one between the high-pressure tank and the emulsification container. The signal end of the flow valve one is communicatively connected to the electronic control unit.
进一步地,活性剂供入机构包括活性剂储存罐和星型送料阀,所述活性剂储存罐的入口与水面支持母船相连,其出口通过所述星型送料阀与乳化容器相连。Further, the active agent supply mechanism includes an active agent storage tank and a star-shaped feeding valve. The inlet of the active agent storage tank is connected to the water surface support mother ship, and its outlet is connected to the emulsification container through the star-shaped feeding valve.
星型送料阀配置有伺服电机,所述伺服电机的信号端与电控单元通讯相连。The star-shaped feeding valve is equipped with a servo motor, and the signal end of the servo motor is communicatively connected with the electronic control unit.
进一步地,海水供入机构包括输入管、抽吸泵及海水过滤器,输入管的一端与外界海水相通,另一端通过所述海水过滤器与乳化容器的中部相连。Further, the seawater supply mechanism includes an input pipe, a suction pump and a seawater filter. One end of the input pipe is connected to the external seawater, and the other end is connected to the middle part of the emulsification container through the seawater filter.
所述抽吸泵设置在输入管上,抽吸泵的信号端与电控单元通讯相连。The suction pump is arranged on the input pipe, and the signal end of the suction pump is communicatively connected to the electronic control unit.
进一步地,乳液输送管的主体部分为水平布置的U形结构,固定套设在矿石暂存箱外侧壁上,位于两侧的延伸部分别与主体部分前端左右两侧相连成一体结构。Further, the main part of the emulsion conveying pipe is a horizontally arranged U-shaped structure, which is fixedly sleeved on the outer wall of the ore temporary storage box, and the extensions on both sides are connected to the left and right sides of the front end of the main part to form an integrated structure.
每组乳液喷嘴均包括呈线性依次间隔排布的多个乳液喷嘴,各乳液喷嘴的前端与乳液输送管的后侧壁相连相通,其后端为线形开口的鸭嘴型结构。Each group of emulsion nozzles includes a plurality of emulsion nozzles arranged linearly at intervals. The front end of each emulsion nozzle is connected to the rear side wall of the emulsion delivery pipe, and its rear end is a duckbill-shaped structure with a linear opening.
进一步地,乳液输送管两侧的延伸部分左右对称分布,通过支架与采矿车固定相连,每侧的延伸部分均由水平段和倾斜段相连构成。Further, the extended portions on both sides of the emulsion conveying pipe are symmetrically distributed left and right, and are fixedly connected to the mining vehicle through brackets. The extended portions on each side are composed of horizontal sections and inclined sections.
各乳液喷嘴线形开口的长度延伸方向,均与其连接处的乳液输送管的轴线方向一致。The length extension direction of the linear opening of each emulsion nozzle is consistent with the axis direction of the emulsion delivery pipe at which it is connected.
本发明的另一个目的在于提出一种深海采矿羽流抑制方法。一种深海采矿羽流抑制方法,采用上述的基于二氧化碳乳液的深海采矿羽流抑制装置,包括如下步骤:Another object of the present invention is to propose a deep sea mining plume suppression method. A deep-sea mining plume suppression method, using the above-mentioned deep-sea mining plume suppression device based on carbon dioxide emulsion, includes the following steps:
步骤一,水面支持母船将表面活性剂通过脐带管线泵送活性剂供入机构内部储存,同时二氧化成制备单元将制得的气态二氧化碳通过脐带管线连续泵送至中继仓内,并在中继仓内部收集、暂存。Step 1: The surface support mother ship pumps the surfactant through the umbilical cord pipeline and supplies it to the internal storage of the institution. At the same time, the carbon dioxide preparation unit continuously pumps the produced gaseous carbon dioxide to the relay warehouse through the umbilical cord pipeline, and stores it in the intermediate warehouse. Internal collection and temporary storage in the warehouse.
步骤二,中继仓内的气态二氧化碳进入增压机构内,增压机构将气态二氧化碳加压至10MPa以上,使其成为液态二氧化碳,并进行暂存备用。Step 2: The gaseous carbon dioxide in the relay warehouse enters the supercharging mechanism. The supercharging mechanism pressurizes the gaseous carbon dioxide to above 10MPa, turning it into liquid carbon dioxide and temporarily storing it for later use.
步骤三,步骤二中的制得的液态二氧化碳进入乳化容器内,外部海水经过滤后泵送至乳化容器内。Step 3: The liquid carbon dioxide produced in Step 2 enters the emulsification container, and the external seawater is filtered and pumped into the emulsification container.
活性剂供入机构内部储存的表面活性剂通过管路进入乳化容器内,同时,向乳化容器内加入疏水颗粒,液态二氧化碳、海水、表面活性剂和疏水颗粒按照设定比例在乳化容器内充分搅拌,得到二氧化碳包水型乳液。The surfactant stored inside the active agent supply mechanism enters the emulsification container through the pipeline. At the same time, hydrophobic particles are added to the emulsification container. Liquid carbon dioxide, seawater, surfactant and hydrophobic particles are fully stirred in the emulsification container according to the set ratio. , to obtain a water-in-carbonate emulsion.
步骤四,二氧化碳包水型乳液经过乳液输送管到达各乳液喷嘴,通过乳液喷嘴以面洒的方式向外部喷射,在羽流的上方形成连续的乳液覆盖层。Step 4: The water-in-carbonate emulsion reaches each emulsion nozzle through the emulsion delivery pipe, and is sprayed to the outside through the emulsion nozzle in a surface spraying manner, forming a continuous emulsion covering layer above the plume.
步骤五,在重力作用下,乳液覆盖层向下沉降,二氧化碳包水型乳液吸附羽流中的颗粒,将羽流扑盖到海底,阻止羽流扩散。Step 5: Under the action of gravity, the emulsion covering layer settles downward. The water-in-carbon dioxide emulsion absorbs the particles in the plume and covers the plume to the seabed, preventing the plume from spreading.
进一步地,表面活性剂采用阳离子表面活性剂,步骤三中所述的液态二氧化碳、海水、表面活性剂和疏水颗粒按照体积配比依次为(70~90):(30~60):(4~9):(1~2)加入乳化容器内。搅拌机构采用螺旋搅拌桨,螺旋搅拌桨的转速为800rpm~1500rpm。Further, the surfactant uses a cationic surfactant. The liquid carbon dioxide, seawater, surfactant and hydrophobic particles described in step three are (70~90): (30~60): (4~ 9): (1~2) Add to the emulsification container. The stirring mechanism adopts a spiral stirring paddle, and the rotating speed of the spiral stirring paddle is 800rpm~1500rpm.
通过采用上述技术方案,本发明的有益技术效果是:By adopting the above technical solutions, the beneficial technical effects of the present invention are:
1、本发明使用二氧化碳包水型乳液形成覆盖层,密度较高的乳液覆盖层下压迫使羽流快速沉降,可有效抑制羽流外溢和扩散。1. The present invention uses a water-in-carbon dioxide emulsion to form a covering layer. The high-density emulsion covering layer presses down to cause the plume to settle rapidly, which can effectively inhibit the overflow and spread of the plume.
2、本发明采用阳离子型二氧化碳乳液,可吸附阴离子浓度较高的羽流颗粒,少部分逃逸羽流颗粒也将被电荷吸引,附着于乳液盖层表面并伴随乳液沉降。2. The present invention uses cationic carbon dioxide emulsion, which can adsorb plume particles with high anion concentration. A small number of escaped plume particles will also be attracted by electric charges, adhere to the surface of the emulsion cover layer, and settle with the emulsion.
3、本发明在利用二氧化碳乳液抑制羽流后,二氧化碳乳液将沉降至深海海底,在海水的长期溶解作用下,二氧化碳将与沉积物孔隙中的水结合发生化学反应,生成水合物后长期留置在海底,实现深海碳封存。3. After the present invention uses carbon dioxide emulsion to suppress the plume, the carbon dioxide emulsion will sink to the deep seabed. Under the long-term dissolution of seawater, carbon dioxide will combine with the water in the sediment pores to undergo a chemical reaction, and the hydrate will be formed and left for a long time. Undersea, realize deep sea carbon sequestration.
附图说明Description of the drawings
图1是本发明基于二氧化碳乳液的深海采矿羽流抑制装置的示意图。Figure 1 is a schematic diagram of the deep sea mining plume suppression device based on carbon dioxide emulsion of the present invention.
图2是本发明基于二氧化碳乳液的深海采矿羽流抑制装置的内部结构示意图。Figure 2 is a schematic diagram of the internal structure of the deep sea mining plume suppression device based on carbon dioxide emulsion of the present invention.
图3是图1本发明某一部分的结构示意图,示出的是乳液喷嘴。Figure 3 is a schematic structural diagram of a certain part of the invention of Figure 1, showing the emulsion nozzle.
图4是本发明一种深海采矿羽流抑制方法的流程图。Figure 4 is a flow chart of a deep sea mining plume suppression method of the present invention.
具体实施方式Detailed ways
下面结合附图对本发明进行详细说明:The present invention will be described in detail below in conjunction with the accompanying drawings:
实施例1,结合图1至图3,基于二氧化碳乳液的深海采矿羽流抑制装置,包括二氧化碳存储单元、乳化单元、乳液喷射单元及电控单元,所述二氧化碳存储单元包括设在采矿车上的中继仓11和脐带管线12,所述中继仓11固定安装在矿石暂存箱101内部,所述中继仓11通过所述脐带管线12能够与水面支持母船上的二氧化成制备单元相连。采矿车的前端设置有采集头103,其左右两侧具有对称布置的两个履带行走单元102,羽流来自于采矿车行走过程中,两个履带行走单元102激起的并向外部扩散,以及采集头103射流造成的。Embodiment 1, with reference to Figures 1 to 3, a deep sea mining plume suppression device based on carbon dioxide emulsion includes a carbon dioxide storage unit, an emulsification unit, an emulsion injection unit and an electronic control unit. The carbon dioxide storage unit includes a carbon dioxide storage unit installed on a mining vehicle. Relay warehouse 11 and umbilical cord pipeline 12. The relay warehouse 11 is fixedly installed inside the ore temporary storage box 101. The relay warehouse 11 can be connected to the carbon dioxide preparation unit on the surface support mother ship through the umbilical cord pipeline 12. . The front end of the mining vehicle is provided with a collection head 103, which has two symmetrically arranged crawler walking units 102 on its left and right sides. The plume comes from the two crawler walking units 102 that are stirred up and spread to the outside during the walking process of the mining vehicle, and The collection head 103 is caused by the jet.
脐带管线12的一端与中继仓11的顶部相连,另一端连接水面支持母船上的二氧化成制备单元,中继仓11通过脐带管线12接收并存储来自水面支持母船的二氧化碳。电控单元包括控制器,控制器采用现有技术已有的PLC控制器。One end of the umbilical cord pipeline 12 is connected to the top of the relay warehouse 11 , and the other end is connected to the carbon dioxide production unit on the surface support mother ship. The relay warehouse 11 receives and stores carbon dioxide from the surface support mother ship through the umbilical cord pipeline 12 . The electronic control unit includes a controller, and the controller adopts an existing PLC controller in the prior art.
乳化单元包括增压机构、海水供入机构、活性剂供入机构和乳化容器2,乳化容器2内部设有搅拌机构21,中继仓11的出口端通过所述增压机构与乳化容器2的内部相连相通。The emulsification unit includes a pressurizing mechanism, a seawater supply mechanism, an active agent supplying mechanism and an emulsification container 2. A stirring mechanism 21 is provided inside the emulsification container 2. The outlet end of the relay chamber 11 passes through the connection between the pressurization mechanism and the emulsification container 2. Internally connected.
增压机构包括增压泵32和高压罐体31,所述高压罐体31设置在矿石暂存箱101内部,通过第一管路33与中继仓11的出口端相连相通。增压泵32设置在第一管路33上,其信号端与电控单元通讯相连。高压罐体31与乳化容器2管路相连,所述高压罐体31和乳化容器2之间设有流量阀一34,流量阀一34的信号端与电控单元通讯相连。增压机构用于增加压强使二氧化碳从气态相变为液态The boosting mechanism includes a boosting pump 32 and a high-pressure tank 31. The high-pressure tank 31 is arranged inside the ore temporary storage tank 101 and is connected to the outlet end of the relay bin 11 through a first pipeline 33. The booster pump 32 is arranged on the first pipeline 33, and its signal end is communicatively connected with the electronic control unit. The high-pressure tank 31 is connected to the emulsification container 2 through pipelines. A flow valve 34 is provided between the high-pressure tank 31 and the emulsification container 2. The signal end of the flow valve 34 is connected to the electronic control unit for communication. The booster mechanism is used to increase the pressure to change the phase of carbon dioxide from gaseous to liquid.
海水供入机构位于乳化容器2的一侧,其一端与外界相连,另一端与乳化容器2的内部相连,能够将过滤后的海水送至乳化容器2内。具体地,海水供入机构包括输入管41、抽吸泵及海水过滤器42,输入管41的一端与外界海水相通,另一端通过所述海水过滤器42与乳化容器2的中部相连。所述抽吸泵设置在输入管41上,抽吸泵的信号端与电控单元通讯相连。The seawater supply mechanism is located on one side of the emulsification container 2, with one end connected to the outside and the other end connected to the inside of the emulsification container 2, capable of sending filtered seawater into the emulsification container 2. Specifically, the seawater supply mechanism includes an input pipe 41, a suction pump and a seawater filter 42. One end of the input pipe 41 is connected to the external seawater, and the other end is connected to the middle of the emulsification container 2 through the seawater filter 42. The suction pump is arranged on the input pipe 41, and the signal end of the suction pump is communicatively connected to the electronic control unit.
活性剂供入机构与乳化容器2相连相通,将表面活性剂供入至乳化容器2内。活性剂供入机构包括活性剂储存罐51和星型送料阀52,所述活性剂储存罐51的入口与水面支持母船相连,其出口通过所述星型送料阀52与乳化容器2相连。星型送料阀52配置有伺服电机,所述伺服电机的信号端与电控单元通讯相连。The active agent supply mechanism is connected with the emulsification container 2 and supplies surfactant into the emulsification container 2 . The active agent supply mechanism includes an active agent storage tank 51 and a star-shaped feeding valve 52. The inlet of the active agent storage tank 51 is connected to the water surface support mother ship, and its outlet is connected to the emulsification container 2 through the star-shaped feeding valve 52. The star-shaped feeding valve 52 is equipped with a servo motor, and the signal end of the servo motor is communicatively connected with the electronic control unit.
乳液喷射单元包括乳液输送管61和三组乳液喷嘴62,乳液输送管61与乳化容器2相连,包裹于矿石暂存箱101的外侧,其左右两侧向外横向延伸形成延伸部分。乳液输送管61的主体部分为水平布置的U形结构,固定套设在矿石暂存箱101外侧壁上,位于两侧的延伸部分别与主体部分前端左右两侧相连成一体结构。The emulsion injection unit includes an emulsion delivery pipe 61 and three sets of emulsion nozzles 62. The emulsion delivery pipe 61 is connected to the emulsification container 2 and wrapped around the outside of the ore temporary storage box 101. Its left and right sides extend outward and laterally to form an extension part. The main part of the emulsion conveying pipe 61 is a horizontally arranged U-shaped structure, which is fixedly sleeved on the outer wall of the ore temporary storage box 101. The extensions on both sides are respectively connected to the left and right sides of the front end of the main part to form an integrated structure.
每组乳液喷嘴62均包括呈线性依次间隔排布的多个乳液喷嘴62,各乳液喷嘴62的前端与乳液输送管61的后侧壁相连相通,其后端为线形开口的鸭嘴型结构。Each group of emulsion nozzles 62 includes a plurality of emulsion nozzles 62 arranged linearly and sequentially at intervals. The front end of each emulsion nozzle 62 is connected to the rear side wall of the emulsion delivery pipe 61 , and its rear end is a duckbill-shaped structure with a linear opening.
两组乳液喷嘴62对称设置在乳液输送管61的左右两侧,另外一组乳液喷嘴62设置在乳液输送管61的后侧,工作状态下,由乳化容器2制备得到的二氧化碳包水型乳液经过乳液喷嘴62向采矿车周边喷洒。Two groups of emulsion nozzles 62 are symmetrically arranged on the left and right sides of the emulsion delivery pipe 61, and another set of emulsion nozzles 62 are arranged on the rear side of the emulsion delivery pipe 61. Under working conditions, the water-in-carbonate emulsion prepared by the emulsification container 2 passes through The emulsion nozzle 62 sprays around the mining vehicle.
乳液输送管61两侧的延伸部分左右对称分布,通过支架与采矿车固定相连,每侧的延伸部分均由水平段和倾斜段相连构成。各乳液喷嘴62线形开口的长度延伸方向,均与其连接处的乳液输送管61的轴线方向一致。The extended portions on both sides of the emulsion conveying pipe 61 are symmetrically distributed left and right, and are fixedly connected to the mining vehicle through brackets. The extended portions on each side are composed of horizontal sections and inclined sections. The length extension direction of the linear opening of each emulsion nozzle 62 is consistent with the axial direction of the emulsion delivery pipe 61 at the connection point.
实施例2,结合图1至图4,一种深海采矿羽流抑制方法,采用上述的基于二氧化碳乳液的深海采矿羽流抑制装置,包括如下步骤:Embodiment 2, with reference to Figures 1 to 4, a deep sea mining plume suppression method, using the above deep sea mining plume suppression device based on carbon dioxide emulsion, includes the following steps:
步骤一,水面支持母船将表面活性剂通过脐带管线12泵送活性剂供入机构内部储存,同时二氧化成制备单元将制得的气态二氧化碳通过脐带管线12连续泵送至中继仓11内,并在中继仓11内部收集、暂存。Step 1: The surface support mother ship pumps the surfactant through the umbilical line 12 and supplies the active agent to the internal storage of the mechanism. At the same time, the carbon dioxide production unit continuously pumps the produced gaseous carbon dioxide to the relay warehouse 11 through the umbilical line 12. And it is collected and temporarily stored in the relay warehouse 11.
步骤二,中继仓11内的气态二氧化碳进入增压机构内,增压机构将气态二氧化碳加压至10MPa以上,使其成为液态二氧化碳,并进行暂存备用。Step 2: The gaseous carbon dioxide in the relay warehouse 11 enters the supercharging mechanism. The supercharging mechanism pressurizes the gaseous carbon dioxide to above 10 MPa, turning it into liquid carbon dioxide and temporarily storing it for later use.
步骤三,步骤二中的制得的液态二氧化碳进入乳化容器2内,外部海水经过滤后泵送至乳化容器2内。Step 3: The liquid carbon dioxide produced in Step 2 enters the emulsification container 2 , and the external seawater is filtered and pumped into the emulsification container 2 .
活性剂供入机构内部储存的表面活性剂通过管路进入乳化容器2内,同时,向乳化容器2内加入疏水颗粒,液态二氧化碳、海水、表面活性剂和疏水颗粒按照设定比例在乳化容器2内充分搅拌,使用搅拌桨进行搅拌加速液态二氧化碳乳化过程,得到二氧化碳包水型阳离子乳液。The surfactant stored inside the active agent supply mechanism enters the emulsification container 2 through the pipeline. At the same time, hydrophobic particles are added to the emulsification container 2. Liquid carbon dioxide, seawater, surfactant and hydrophobic particles are added to the emulsification container 2 in a set ratio. Stir thoroughly inside, and use a stirring paddle to stir to accelerate the emulsification process of liquid carbon dioxide to obtain a water-in-carbon dioxide cationic emulsion.
具体地,表面活性剂采用阳离子表面活性剂,优选二十二烷基三甲基溴化铵、十六烷基三甲基溴化铵。Specifically, the surfactant is a cationic surfactant, preferably behenyltrimethylammonium bromide and cetyltrimethylammonium bromide.
步骤三中所述的液态二氧化碳、海水、表面活性剂和疏水颗粒按照体积配比依次为(70~90):(30~60):(4~9):(1~2)加入乳化容器2内。搅拌机构21采用螺旋搅拌桨,螺旋搅拌桨的转速为800rpm~1500rpm。The liquid carbon dioxide, seawater, surfactant and hydrophobic particles described in step three are (70~90) according to the volume ratio: (30~60): (4~9): (1~2) Add emulsification container 2 Inside. The stirring mechanism 21 adopts a spiral stirring paddle, and the rotating speed of the spiral stirring paddle is 800rpm to 1500rpm.
步骤四,二氧化碳包水型阳离子乳液经过乳液输送管61到达各乳液喷嘴62,通过乳液喷嘴62以面洒的方式向外部喷射,在羽流的上方形成连续的乳液覆盖层。Step 4: The water-in-carbon dioxide cationic emulsion reaches each emulsion nozzle 62 through the emulsion delivery pipe 61, and is sprayed to the outside through the emulsion nozzle 62 in a surface spraying manner, forming a continuous emulsion covering layer above the plume.
步骤五,在重力作用下,乳液覆盖层向下沉降,二氧化碳包水型乳液吸附羽流中的颗粒,将羽流扑盖到海底,阻止羽流扩散。利用二氧化碳阳离子乳液密度较高特性以及电荷吸附性,一方面形成连续盖层向下压迫羽流使其沉降,一方面吸附羽流颗粒抑制羽流扩散Step 5: Under the action of gravity, the emulsion covering layer settles downward. The water-in-carbon dioxide emulsion absorbs the particles in the plume and covers the plume to the seabed, preventing the plume from spreading. Taking advantage of the high density and charge adsorption properties of carbon dioxide cationic emulsion, on the one hand, a continuous cover layer is formed to press the plume downward to cause it to settle, and on the other hand, the plume particles are absorbed to inhibit the plume diffusion.
二氧化碳乳液释放至海水中,吸附羽流颗粒沉降至海底,短暂停留在海底沉积物表面。在乳液结构中,二氧化碳包裹于水分子外层。在海水的长期溶解作用下,乳液结构逐渐被破坏,位于外层的二氧化碳分子将直接接触海底沉积物。根据二氧化碳水合物性质,二氧化碳将抢夺沉积物孔隙中的强结合水,并通过化学反应生成二氧化碳水合物。在反应过程中,二氧化碳水合物将侵蚀进入海底沉积物孔隙,取代水分子填充孔隙并胶结沉积物颗粒。The emulsion of carbon dioxide is released into seawater, and the adsorbed plume particles sink to the seafloor, where they briefly remain on the surface of seafloor sediments. In an emulsion structure, carbon dioxide is wrapped around water molecules. Under the long-term dissolution of seawater, the emulsion structure is gradually destroyed, and the carbon dioxide molecules in the outer layer will directly contact the seabed sediments. According to the properties of carbon dioxide hydrate, carbon dioxide will rob the strongly bound water in the sediment pores and generate carbon dioxide hydrate through chemical reactions. During the reaction, carbon dioxide hydrate will erode into seafloor sediment pores, displacing water molecules to fill the pores and cement sediment particles.
本发明中碳封存方式主要利用二氧化碳乳液密度较高特性以及二氧化碳沉积物中溶解特性。在深海4000~6000米水深环境中,液态二氧化碳及二氧化碳乳液密度比当地海水更高,在重力作用下呈现下沉趋势,碳封存泄露风险很小。所述二氧化碳乳液为二氧化碳包水型乳液,乳液沉降至海底后,停留在海水-沉积物交界面上,位于二氧化碳包水型乳液结构外层的二氧化碳会逐渐溶解,并渗入到沉积物中与沉积物颗粒稳定胶结,实现深海长期碳封存。The carbon sequestration method in the present invention mainly utilizes the high density characteristics of carbon dioxide emulsion and the dissolution characteristics of carbon dioxide sediments. In a deep sea environment with a water depth of 4,000 to 6,000 meters, liquid carbon dioxide and carbon dioxide emulsions have a higher density than local seawater, and tend to sink under the influence of gravity, so the risk of carbon sequestration leakage is very small. The carbon dioxide emulsion is a water-in-carbon dioxide emulsion. After the emulsion settles to the seabed, it stays at the seawater-sediment interface. The carbon dioxide located in the outer layer of the water-in-carbon dioxide emulsion structure will gradually dissolve and penetrate into the sediment and deposit. The solid particles are stably cemented to achieve long-term carbon sequestration in the deep sea.
本发明中未述及的部分采用或借鉴已有技术即可实现。Parts not described in the present invention can be realized by adopting or drawing on existing technologies.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性。In addition, the terms "first" and "second" are used for descriptive purposes only and are not to be understood as indicating or implying relative importance.
在本发明的描述中,需要理解的是,术语“上”、“下”、“前”、“后”、“左”、“右”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be understood that the orientation or positional relationship indicated by the terms "upper", "lower", "front", "back", "left", "right", etc. are based on those shown in the accompanying drawings. The orientation or positional relationship is only for the convenience of describing the present invention and simplifying the description. It does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation of the present invention.
当然,上述说明并非是对本发明的限制,本发明也并不仅限于上述举例,本技术领域的技术人员在本发明的实质范围内所做出的变化、改型、添加或替换,也应属于本发明的保护范围。Of course, the above description is not a limitation of the present invention, and the present invention is not limited to the above examples. Changes, modifications, additions or substitutions made by those skilled in the art within the essential scope of the present invention should also fall within the scope of the present invention. protection scope of the invention.
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