CN116925435B - Preparation process of wear-resistant and anti-skid golf sole - Google Patents
Preparation process of wear-resistant and anti-skid golf sole Download PDFInfo
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- CN116925435B CN116925435B CN202311182348.2A CN202311182348A CN116925435B CN 116925435 B CN116925435 B CN 116925435B CN 202311182348 A CN202311182348 A CN 202311182348A CN 116925435 B CN116925435 B CN 116925435B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 52
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 28
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 23
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 22
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 22
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 22
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 22
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 22
- 229920001194 natural rubber Polymers 0.000 claims abstract description 22
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 22
- 229920001971 elastomer Polymers 0.000 claims abstract description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000006229 carbon black Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000000314 lubricant Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000004073 vulcanization Methods 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 239000011259 mixed solution Substances 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 20
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 14
- VMAWODUEPLAHOE-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O[Si](C)(C=C)O1 VMAWODUEPLAHOE-UHFFFAOYSA-N 0.000 claims description 12
- ZPFCAYLALUOUSI-UHFFFAOYSA-N 2,5-dimethyl-1,4-dithiane-2-thiol Chemical compound CC1(SCC(SC1)C)S ZPFCAYLALUOUSI-UHFFFAOYSA-N 0.000 claims description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 10
- 239000003960 organic solvent Substances 0.000 claims description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- 238000002390 rotary evaporation Methods 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 6
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 230000009471 action Effects 0.000 claims description 5
- 238000000748 compression moulding Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000003760 magnetic stirring Methods 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 239000012044 organic layer Substances 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- 238000009966 trimming Methods 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- 244000028419 Styrax benzoin Species 0.000 claims description 3
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 3
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- 229960002130 benzoin Drugs 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 235000019382 gum benzoic Nutrition 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- OTKCEEWUXHVZQI-UHFFFAOYSA-N 1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(=O)CC1=CC=CC=C1 OTKCEEWUXHVZQI-UHFFFAOYSA-N 0.000 claims description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 210000002683 foot Anatomy 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 125000000101 thioether group Chemical group 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
- LOZWAPSEEHRYPG-UHFFFAOYSA-N 1,4-dithiane Chemical group C1CSCCS1 LOZWAPSEEHRYPG-UHFFFAOYSA-N 0.000 description 1
- JSMAHLVRXDDDAA-UHFFFAOYSA-N 2,5-bis(methylsulfanyl)-1,4-dithiane Chemical compound CSC1CSC(SC)CS1 JSMAHLVRXDDDAA-UHFFFAOYSA-N 0.000 description 1
- 210000003423 ankle Anatomy 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 150000004759 cyclic silanes Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- -1 thiophene compound Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a preparation process of a wear-resistant and anti-slip golf sole, which comprises the following raw material components in parts by weight: 70-90 parts of natural rubber, 11-19 parts of styrene-butadiene-styrene block copolymer, 10-15 parts of ethylene-vinyl acetate copolymer, 5.2-8.7 parts of reinforcing agent, 14-20 parts of white carbon black, 3.3-4.6 parts of antioxidant, 2.4-3 parts of lubricant, 1.5-3 parts of vulcanizing agent and 2-4 parts of vulcanization accelerator. The invention provides a preparation process of a rubber material used in soles, and the prepared rubber material not only has the effects of high strength, skid resistance, water resistance and portability, but also has the advantages of wear resistance, aging resistance and high strength, so that the rubber material can easily cope with most ball sports, especially in golf balls with higher sole quality.
Description
Technical Field
The invention relates to the field of elastic soles, in particular to a preparation process of a wear-resistant and anti-slip golf sole.
Background
Golf is not a very intense sport and the playing rhythm is not very jerky, and although the feet do not bear very great impacts at all times, a distance of about six kilometers is typically required to complete an 18 hole. In this process, the whole body weight is placed on both feet, so that a comfortable pair of shoes is selected, and the method is a good method for protecting both feet, neither for amateurs nor professionals, from suffering from bitter taste, nor from injury to ankles.
The shape, material, structure and fittings of the golf sole are different from those of the common shoes. In particular, the sole nail ensures that the player stands stably, has a feeling of stepping on the ground, and helps to walk and slip on uneven road surfaces. The soles of the general golf shoes are provided with a plurality of short nails made of rubber, so that the soles can be prevented from slipping, grass can be walked more stably, the body can be kept balanced during the swing, meanwhile, the turf is protected, and the golf shoes are more specialized in appearance.
The golf shoe sole is required to have anti-slip, waterproof and lightweight effects to more stably walk on grass and to better alleviate the fatigue of several hours of golf. However, the rubber studs of the soles of many golf shoes in the prior art have lower strength and cannot play a good role in preventing water and skid, so that the soles cannot play a role in strongly grabbing the ground when a player swings to play a ball, thereby causing the conditions of unstable center of gravity, easy injury and the like,
disclosure of Invention
Aiming at the problems existing in the prior art, the invention aims to provide a preparation process of a wear-resistant and anti-skid golf sole.
The aim of the invention is realized by adopting the following technical scheme:
a preparation process of wear-resistant and anti-slip golf sole comprises the following steps:
step 1, weighing natural rubber, a styrene-butadiene-styrene block copolymer and an ethylene-vinyl acetate copolymer, drying, mixing into an internal mixer, and banburying for 10-20min at 120-130 ℃ to form a first banburying material;
step 2, sequentially adding the following components including a reinforcing agent, white carbon black, an antioxidant and a lubricant into the first banburying material, banburying for 1-2min after each component is added, adding the next component, cooling to 100-110 ℃ after all the components are added, and banburying for 10-20min to form a second banburying material;
step 3, placing the second banburying material in a vulcanizing tank, adding a vulcanizing agent and a vulcanizing accelerator into the vulcanizing tank, controlling the temperature of the vulcanizing tank to be 150-160 ℃ and the vulcanizing time to be 1-2h to form a vulcanizing material;
and 4, placing the vulcanized material at room temperature for at least 24 hours, transferring the vulcanized material into a mold, and performing compression molding and trimming to obtain the golf sole.
Preferably, the raw material components added in the preparation process of the wear-resistant and anti-slip golf sole comprise the following components in parts by weight:
70-90 parts of natural rubber, 11-19 parts of styrene-butadiene-styrene block copolymer, 10-15 parts of ethylene-vinyl acetate copolymer, 5.2-8.7 parts of reinforcing agent, 14-20 parts of white carbon black, 3.3-4.6 parts of antioxidant, 2.4-3 parts of lubricant, 1.5-3 parts of vulcanizing agent and 2-4 parts of vulcanization accelerator.
Preferably, in the step 1, the Natural Rubber (NR) is one of standard rubber SVR3L, standard rubber SVR10 and standard rubber SVR 20; more preferably standard gum SVR3L, and Vietnam is produced.
Preferably, in the step 1, the styrene-butadiene-styrene block copolymer (SBS) is one of Baling petrochemical YH-791, baling petrochemical YH-792 and Baling petrochemical YH-796; more preferably Baling petrochemical YH-792.
Preferably, in said step 1, the ethylene-vinyl acetate copolymer (EVA) has a vinyl acetate content of 40wt.%, and a melt index of 52g/10min at 190℃and 2.16 kg.
Preferably, in the step 2, the white carbon black is any one of the types of Desolid R972, desolid R974, desolid R106, desolid R202 and Desolid R812; more preferably Desolid R974, nitrogen adsorption specific surface area of 170+ -20m 2 And/g, the grain diameter is 10-15nm.
Preferably, in the step 2, the antioxidant is a hindered phenol antioxidant, including any one or a combination of more of an antioxidant 1035, an antioxidant 1076 and an antioxidant 1010; more preferably an antioxidant 1035.
Preferably, in the step 2, the lubricant is any one or a combination of more than one of stearic acid, zinc stearate and calcium stearate; more preferably zinc stearate.
Preferably, in the step 2, the preparation method of the reinforcing agent includes:
s1, weighing 2, 5-dimethyl mercapto-1, 4-dithiane and tetramethyl tetravinyl cyclotetrasiloxane, mixing into an organic solvent, and uniformly stirring under magnetic stirring to form a reaction mixed solution;
s2, adding the photoinitiator into the reaction mixed solution, carrying out irradiation treatment on the reaction mixed solution under the action of an ultraviolet light source irradiation machine, continuously stirring, and after the reaction is finished, sequentially carrying out operations of solvent removal, extraction and drying to obtain the reinforcing agent.
Preferably, in S1, the organic solvent includes one of tetrahydrofuran, toluene, 1, 4-dioxane, and ethyl acetate.
Preferably, in the S1, the mass ratio of the 2, 5-dimethyl mercapto-1, 4-dithiane, the tetramethyl tetravinyl cyclotetrasiloxane and the organic solvent is 0.42-0.84:0.34-0.68:6-10.
Preferably, in the step S1, the stirring speed is 250-350r/min.
Preferably, in the step S2, the photoinitiator is one of benzoin dimethyl ether, diphenyl ketone and alpha-hydroxyalkyl benzophenone.
Preferably, in the step S2, the wavelength of the ultraviolet light source is 365-405nm, the temperature of the irradiation reaction is 25-35 ℃, and the stirring speed is 400-600r/min.
Preferably, in the step S2, the mass ratio of the photoinitiator to the reaction mixed solution is 0.1-0.5:100.
Preferably, in S2, the solvent is removed by spin evaporation; the extraction is to dissolve the product after solvent removal in dichloromethane, and then extract the product at least twice by using a mixed solution of acetone and water in a volume ratio of 1:1; the drying is to dry the extracted organic layer by rotary evaporation.
Preferably, in the step 3, the vulcanizing agent is sulfur, and the vulcanization accelerator is 2,2' -dithiodibenzothiazyl.
The beneficial effects of the invention are as follows:
1. the invention provides a preparation process of a rubber material used in soles, and the prepared rubber material not only has the effects of skid resistance, water resistance and portability, but also has the advantages of wear resistance, high toughness and high strength, so that the rubber material can easily cope with most ball sports, especially in golf balls with higher sole quality.
2. The main raw materials of the rubber material prepared by the invention comprise natural rubber, styrene-butadiene-styrene block copolymer and ethylene-vinyl acetate copolymer; the natural rubber has excellent elasticity and high elongation, the ethylene-vinyl acetate copolymer is light and wear-resistant, and the SBS has high water resistance, so that the material has certain elasticity, portability, water resistance and wear resistance. In addition, the invention also adds white carbon black as a filling material to play a role in reinforcing, wear-resisting and skid-proof; the reinforcing agent is added to serve as an auxiliary reinforcing material, so that the compatibility of all raw materials can be enhanced, the performance of the rubber material is further improved, the addition amount of the white carbon black can be reduced by adding the reinforcing agent, and the defect that a large amount of white carbon black is easy to agglomerate is avoided.
3. The reinforcing agent is prepared by using tetramethyl tetravinyl cyclotetrasiloxane and 2, 5-dimethyl mercapto-1, 4-dithiane to generate Click chemistry reaction (Click chemistry) of double bonds and mercapto. Tetramethyl tetravinyl cyclosiloxane is a compound containing a polyvinyl cyclic silane, 2, 5-dimethyl mercapto-1, 4-dithiane is a thiophene compound containing double-end mercapto groups, and mercapto groups and double bonds generate thioether groups in the reaction process, so that the obtained reinforcing agent is a compound containing both thioether groups and thiophene groups. The thioether group has stronger compatibility and flexibility, and the 1, 4-dithiane group has stronger stability and compatibility, so that the obtained reinforcing agent has better improvement on the compatibility of rubber materials, and has improved performances on all aspects of the rubber materials, and the reinforcing agent is mainly characterized in the aspects of mechanical strength, flexibility, wear resistance and the like.
Detailed Description
The technical scheme of the invention is described below through specific examples. It is to be understood that the mention of one or more method steps of the present invention does not exclude the presence of other method steps before and after the combination step or that other method steps may be interposed between these explicitly mentioned steps; it should also be understood that these examples are illustrative of the present invention and are not intended to limit the scope of the present invention. Moreover, unless otherwise indicated, the numbering of the method steps is merely a convenient tool for identifying the method steps and is not intended to limit the order of arrangement of the method steps or to limit the scope of the invention in which the invention may be practiced, as such changes or modifications in their relative relationships may be regarded as within the scope of the invention without substantial modification to the technical matter.
In order to better understand the above technical solution, exemplary embodiments of the present invention are described in more detail below. While exemplary embodiments of the invention are shown, it should be understood that the invention may be embodied in various forms and should not be limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art.
The invention is further described with reference to the following examples.
Example 1
A preparation process of wear-resistant and anti-slip golf sole comprises the following steps:
step 1, weighing natural rubber, a styrene-butadiene-styrene block copolymer and an ethylene-vinyl acetate copolymer, drying, mixing into an internal mixer, and banburying for 15min at 125 ℃ to form a first banburying material;
step 2, sequentially adding the following components including a reinforcing agent, white carbon black, an antioxidant and a lubricant into the first banburying material, banburying for 1min after each component is added, adding the next component, cooling to 100 ℃ after all the components are added, and banburying for 15min to form a second banburying material;
step 3, placing the second banburying material in a vulcanizing tank, adding a vulcanizing agent and a vulcanizing accelerator into the vulcanizing tank, controlling the temperature of the vulcanizing tank to be 155 ℃ and the vulcanizing time to be 1.5 hours, so as to form a vulcanizing material;
and 4, placing the vulcanized material at room temperature for at least 24 hours, transferring the vulcanized material into a mold, and performing compression molding and trimming to obtain the golf sole.
The raw material components added in the preparation process of the wear-resistant and anti-slip golf sole comprise the following components in parts by weight:
80 parts of natural rubber, 15 parts of styrene-butadiene-styrene block copolymer, 12 parts of ethylene-vinyl acetate copolymer, 7.8 parts of reinforcing agent, 18 parts of white carbon black, 4.1 parts of antioxidant, 2.8 parts of lubricant, 2.3 parts of vulcanizing agent and 3 parts of vulcanization accelerator.
Of the above, natural Rubber (NR) was a standard rubber SVR3L, the place of production was Vietnam, the brand of styrene-butadiene-styrene block copolymer (SBS) was Baling petrochemical YH-792, the vinyl acetate content of ethylene-vinyl acetate copolymer (EVA) was 40wt.%, and the melt index was 52g/10min at 190℃and 2.16 kg. The model of the white carbon black is Degusse R974, and the nitrogen adsorption specific surface area is 170+/-20 m 2 And/g, the grain diameter is 10-15nm. The antioxidant is antioxidant 1035. The lubricant is zinc stearate. The vulcanizing agent is sulfur, and the vulcanizing accelerator is 2,2' -dithiodibenzothiazyl.
In the above, the preparation method of the reinforcing agent comprises the following steps:
s1, weighing 2, 5-dimethyl mercapto-1, 4-dithiane and tetramethyl tetravinyl cyclotetrasiloxane, mixing into tetrahydrofuran, and uniformly stirring under magnetic stirring at a stirring speed of 300r/min to form a reaction mixed solution; wherein the mass ratio of the 2, 5-dimethyl mercapto-1, 4-dithiane, the tetramethyl tetravinyl cyclotetrasiloxane and the tetrahydrofuran is 0.42-0.84:0.34-0.68:6-10.
S2, adding a photoinitiator into the reaction mixed solution, carrying out irradiation treatment on the reaction mixed solution under the action of an ultraviolet light source irradiation machine, continuously stirring, removing an organic solvent in a rotary evaporation mode after the reaction is finished, dissolving a solvent-removed product into dichloromethane, extracting at least twice by using a mixed solution of acetone and water in a volume ratio of 1:1, and carrying out rotary evaporation drying on an extracted organic layer to obtain an enhancer; wherein the photoinitiator is benzoin dimethyl ether; the wavelength of the ultraviolet light source is 365nm, the temperature of the irradiation reaction is 30 ℃, and the stirring speed is 500r/min; the mass ratio of the photoinitiator to the reaction mixture was 0.3:100.
Example 2
A preparation process of wear-resistant and anti-slip golf sole comprises the following steps:
step 1, weighing natural rubber, a styrene-butadiene-styrene block copolymer and an ethylene-vinyl acetate copolymer, drying, mixing into an internal mixer, and banburying for 10min at 120 ℃ to form a first banburying material;
step 2, sequentially adding the following components including a reinforcing agent, white carbon black, an antioxidant and a lubricant into the first banburying material, banburying for 1min after each component is added, adding the next component, cooling to 100 ℃ after all the components are added, and banburying for 10min to form a second banburying material;
step 3, placing the second banburying material in a vulcanizing tank, adding a vulcanizing agent and a vulcanizing accelerator into the vulcanizing tank, controlling the temperature of the vulcanizing tank to be 150 ℃ and the vulcanizing time to be 1h, and forming a vulcanizing material;
and 4, placing the vulcanized material at room temperature for at least 24 hours, transferring the vulcanized material into a mold, and performing compression molding and trimming to obtain the golf sole.
The raw material components added in the preparation process of the wear-resistant and anti-slip golf sole comprise the following components in parts by weight:
70 parts of natural rubber, 11 parts of styrene-butadiene-styrene block copolymer, 10 parts of ethylene-vinyl acetate copolymer, 5.2 parts of reinforcing agent, 14 parts of white carbon black, 3.3 parts of antioxidant, 2.4 parts of lubricant, 1.5 parts of vulcanizing agent and 2 parts of vulcanization accelerator.
Of the above, natural Rubber (NR) is standard rubber SVR10. The styrene-butadiene-styrene block copolymer (SBS) is identified by the brand name Baling petrochemical YH-791. Ethylene vinyl acetate copolymer (EVA) had a vinyl acetate content of 40wt.%, and a melt index of 52g/10min at 190℃and 2.16 kg. The model of the white carbon black is Degusse R972. The antioxidant is antioxidant 1076. The lubricant is stearic acid. The vulcanizing agent is sulfur, and the vulcanizing accelerator is 2,2' -dithiodibenzothiazyl.
In the step 2, the preparation method of the reinforcing agent comprises the following steps:
s1, weighing 2, 5-dimethyl mercapto-1, 4-dithiane and tetramethyl tetravinyl cyclotetrasiloxane, mixing into toluene, and stirring uniformly under magnetic stirring at the stirring speed of 250r/min to form a reaction mixed solution; wherein the mass ratio of the 2, 5-dimethyl mercapto-1, 4-dithiane, the tetramethyl tetravinyl cyclotetrasiloxane and the toluene is 0.42:0.34:6.
S2, adding a photoinitiator into the reaction mixed solution, carrying out irradiation treatment on the reaction mixed solution under the action of an ultraviolet light source irradiation machine, continuously stirring, removing an organic solvent in a rotary evaporation mode after the reaction is finished, dissolving a solvent-removed product into dichloromethane, extracting at least twice by using a mixed solution of acetone and water in a volume ratio of 1:1, and carrying out rotary evaporation drying on an extracted organic layer to obtain an enhancer; wherein the photoinitiator is diphenyl ethanone; the wavelength of the ultraviolet light source is 365nm, the temperature of the irradiation reaction is 25 ℃, and the stirring speed is 400r/min; the mass ratio of the photoinitiator to the reaction mixture was 0.1:100.
Example 3
A preparation process of wear-resistant and anti-slip golf sole comprises the following steps:
step 1, weighing natural rubber, a styrene-butadiene-styrene block copolymer and an ethylene-vinyl acetate copolymer, drying, mixing into an internal mixer, and banburying for 20min at 130 ℃ to form a first banburying material;
step 2, sequentially adding the following components including a reinforcing agent, white carbon black, an antioxidant and a lubricant into the first banburying material, banburying for 2min after each component is added, adding the next component, cooling to 110 ℃ after all the components are added, and banburying for 20min to form a second banburying material;
step 3, placing the second banburying material in a vulcanizing tank, adding a vulcanizing agent and a vulcanizing accelerator into the vulcanizing tank, controlling the temperature of the vulcanizing tank to 160 ℃ and the vulcanizing time to 2 hours to form a vulcanizing material;
and 4, placing the vulcanized material at room temperature for at least 24 hours, transferring the vulcanized material into a mold, and performing compression molding and trimming to obtain the golf sole.
The raw material components added in the preparation process of the wear-resistant and anti-slip golf sole comprise the following components in parts by weight:
90 parts of natural rubber, 19 parts of a styrene-butadiene-styrene block copolymer, 15 parts of an ethylene-vinyl acetate copolymer, 8.7 parts of a reinforcing agent, 20 parts of white carbon black, 4.6 parts of an antioxidant, 3 parts of a lubricant, 3 parts of a vulcanizing agent and 4 parts of a vulcanization accelerator.
Of the above, natural Rubber (NR) is standard rubber SVR20. The styrene-butadiene-styrene block copolymer (SBS) is identified by the brand name Baling petrochemical YH-796. Ethylene vinyl acetate copolymer (EVA) had a vinyl acetate content of 40wt.%, and a melt index of 52g/10min at 190℃and 2.16 kg. The model of the white carbon black is Degusse R812. The antioxidant is antioxidant 1010. The lubricant is calcium stearate. The vulcanizing agent is sulfur, and the vulcanizing accelerator is 2,2' -dithiodibenzothiazyl.
In the step 2, the preparation method of the reinforcing agent comprises the following steps:
s1, weighing 2, 5-dimethyl mercapto-1, 4-dithiane and tetramethyl tetravinyl cyclotetrasiloxane, mixing into ethyl acetate, and uniformly stirring under magnetic stirring at a stirring speed of 350r/min to form a reaction mixed solution; wherein the mass ratio of the 2, 5-dimethyl mercapto-1, 4-dithiane, the tetramethyl tetravinyl cyclotetrasiloxane and the ethyl acetate is 0.42-0.84:0.34-0.68:6-10.
S2, adding a photoinitiator into the reaction mixed solution, carrying out irradiation treatment on the reaction mixed solution under the action of an ultraviolet light source irradiation machine, continuously stirring, removing the organic solvent by a rotary evaporation mode after the reaction is finished, dissolving the product after the solvent removal into dichloromethane, extracting at least twice by using a mixed solution of acetone and water in a volume ratio of 1:1, and carrying out rotary evaporation drying on the extracted organic layer to obtain the reinforcing agent. Wherein the photoinitiator is alpha-hydroxyalkyl benzophenone; the wavelength of the ultraviolet light source is 405nm, the temperature of the irradiation reaction is 35 ℃, and the stirring speed is 600r/min; the mass ratio of the photoinitiator to the reaction mixture was 0.5:100.
Comparative example 1
A process for preparing a sole was the same as in example 1, except that no reinforcing agent was added during the preparation.
Comparative example 2
A process for preparing a sole of shoe is the same as in example 1, except that the reinforcing agent added during the preparation is tetramethyl tetravinyl cyclotetrasiloxane.
Comparative example 3
A process for preparing a sole of shoe is the same as in example 1, except that the reinforcing agent added during the preparation is 2, 5-dimethylmercapto-1, 4-dithiane.
Experimental detection
The sole materials prepared in example 1 and comparative examples 1 to 3 were compared in terms of performance tests including: tensile strength (GB/T528-2009), tear strength (GB/T529-2008), rebound resilience (GB/T6670-2008), hardness (Shore durometer GS-706G), water repellency (7 days of immersion in water without water), coefficient of friction (GB/T10006-1988) and the like, and the detection results are shown in Table 1.
As can be seen from Table 1, the sole material prepared in the embodiment 1 of the invention has the characteristics of high strength and high toughness, also has good wear resistance and skid resistance, is very suitable for being used on golf soles at higher ends, is comfortable to wear, can avoid the problem of sole cracking in the process of movement to a large extent, and has the strong ground grabbing property so that the possibility of skidding is greatly reduced and the stability of movement is enhanced.
In the description of the present specification, a description referring to terms "one embodiment," "some embodiments," "examples," "specific examples," or "some examples," etc., means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms should not be understood as necessarily being directed to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Further, one skilled in the art can engage and combine the different embodiments or examples described in this specification.
While embodiments of the present invention have been shown and described above, it will be understood that the above embodiments are illustrative and not to be construed as limiting the invention, and that variations, modifications, alternatives and variations may be made to the above embodiments by one of ordinary skill in the art within the scope of the invention.
Claims (10)
1. The preparation process of the wear-resistant and anti-slip golf sole is characterized by comprising the following steps of:
step 1, weighing natural rubber, a styrene-butadiene-styrene block copolymer and an ethylene-vinyl acetate copolymer, drying, mixing into an internal mixer, and banburying for 10-20min at 120-130 ℃ to form a first banburying material;
step 2, sequentially adding the following components including a reinforcing agent, white carbon black, an antioxidant and a lubricant into the first banburying material, banburying for 1-2min after each component is added, adding the next component, cooling to 100-110 ℃ after all the components are added, and banburying for 10-20min to form a second banburying material;
step 3, placing the second banburying material in a vulcanizing tank, adding a vulcanizing agent and a vulcanizing accelerator into the vulcanizing tank, controlling the temperature of the vulcanizing tank to be 150-160 ℃ and the vulcanizing time to be 1-2h to form a vulcanizing material;
step 4, placing the vulcanized material at room temperature for at least 24 hours, transferring the vulcanized material into a mold, and performing compression molding and trimming to obtain the golf sole;
in the step 2, the preparation method of the reinforcing agent comprises the following steps:
s1, weighing 2, 5-dimethyl mercapto-1, 4-dithiane and tetramethyl tetravinyl cyclotetrasiloxane, mixing into an organic solvent, and uniformly stirring under magnetic stirring to form a reaction mixed solution;
s2, adding the photoinitiator into the reaction mixed solution, carrying out irradiation treatment on the reaction mixed solution under the action of an ultraviolet light source irradiation machine, continuously stirring, and after the reaction is finished, sequentially carrying out operations of solvent removal, extraction and drying to obtain the reinforcing agent.
2. The process for preparing the wear-resistant and anti-slip golf sole according to claim 1, wherein the raw material components added in the process for preparing the wear-resistant and anti-slip golf sole comprise the following components in parts by weight:
70-90 parts of natural rubber, 11-19 parts of styrene-butadiene-styrene block copolymer, 10-15 parts of ethylene-vinyl acetate copolymer, 5.2-8.7 parts of reinforcing agent, 14-20 parts of white carbon black, 3.3-4.6 parts of antioxidant, 2.4-3 parts of lubricant, 1.5-3 parts of vulcanizing agent and 2-4 parts of vulcanization accelerator.
3. The process for preparing a wear-resistant and anti-slip golf sole according to claim 1, wherein in the step 1, the natural rubber is one of standard rubber SVR3L, standard rubber SVR10 and standard rubber SVR20.
4. The process for preparing a wear-resistant and skid-resistant golf sole according to claim 1, wherein in the step 1, the styrene-butadiene-styrene block copolymer (SBS) is one of the brands of baling petrochemical YH-791, baling petrochemical YH-792 and baling petrochemical YH-796.
5. The process for preparing a wear-resistant and skid-resistant golf sole according to claim 1, wherein in the step 1, the ethylene-vinyl acetate copolymer has a vinyl acetate content of 40wt.% and a melt index of 52g/10min at 190 ℃ under 2.16 kg; the white carbon black is any one of Desolid R972, desolid R974, desolid R106, desolid R202 and Desolid R812.
6. The process for preparing a wear-resistant and anti-slip golf sole according to claim 1, wherein in the step 2, the antioxidant is a hindered phenol antioxidant, and comprises any one or more of an antioxidant 1035, an antioxidant 1076 and an antioxidant 1010; the lubricant is one or more of stearic acid, zinc stearate and calcium stearate.
7. The process for preparing the wear-resistant and anti-slip golf sole according to claim 1, wherein in the step S1, the organic solvent comprises one of tetrahydrofuran, toluene, 1, 4-dioxane and ethyl acetate; the mass ratio of the 2, 5-dimethyl mercapto-1, 4-dithiane, the tetramethyl tetravinyl cyclotetrasiloxane and the organic solvent is 0.42-0.84:0.34-0.68:6-10; the stirring speed is 250-350r/min.
8. The process for preparing a wear-resistant and anti-slip golf sole according to claim 1, wherein in S2, the photoinitiator is one of benzoin dimethyl ether, diphenyl ethanone and alpha-hydroxyalkyl benzophenone; the wavelength of the ultraviolet light source is 365-405nm, the temperature of the irradiation reaction is 25-35 ℃, and the stirring speed is 400-600r/min; the mass ratio of the photoinitiator to the reaction mixed solution is 0.1-0.5:100.
9. The process for preparing a wear-resistant and anti-slip golf sole according to claim 1, wherein in S2, the solvent is removed by spin-evaporation; the extraction is to dissolve the product after solvent removal in dichloromethane, and then extract the product at least twice by using a mixed solution of acetone and water in a volume ratio of 1:1; the drying is to dry the extracted organic layer by rotary evaporation.
10. The process for preparing a wear-resistant and skid-proof golf sole according to claim 1, wherein in the step 3, the vulcanizing agent is sulfur and the vulcanizing accelerator is 2,2' -dithiodibenzothiazyl.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB757644A (en) * | 1954-04-15 | 1956-09-19 | Dunlop Rubber Co | Improvements relating to rubbery compositions |
| CN108276543A (en) * | 2017-02-03 | 2018-07-13 | Skc株式会社 | Glass lens polythiol compositions |
| WO2022041930A1 (en) * | 2020-08-27 | 2022-03-03 | 茂泰(福建)鞋材有限公司 | Leather scrap-modified rubber outsole and preparation method therefor |
| CN114891177A (en) * | 2022-05-06 | 2022-08-12 | 盛鼎高新材料有限公司 | Chain extender and application thereof in polyurethane elastomer |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB757644A (en) * | 1954-04-15 | 1956-09-19 | Dunlop Rubber Co | Improvements relating to rubbery compositions |
| CN108276543A (en) * | 2017-02-03 | 2018-07-13 | Skc株式会社 | Glass lens polythiol compositions |
| WO2022041930A1 (en) * | 2020-08-27 | 2022-03-03 | 茂泰(福建)鞋材有限公司 | Leather scrap-modified rubber outsole and preparation method therefor |
| CN114891177A (en) * | 2022-05-06 | 2022-08-12 | 盛鼎高新材料有限公司 | Chain extender and application thereof in polyurethane elastomer |
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