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CN116891778A - Elevator traction machine lubricating oil and preparation method and application thereof - Google Patents

Elevator traction machine lubricating oil and preparation method and application thereof Download PDF

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Publication number
CN116891778A
CN116891778A CN202310868654.5A CN202310868654A CN116891778A CN 116891778 A CN116891778 A CN 116891778A CN 202310868654 A CN202310868654 A CN 202310868654A CN 116891778 A CN116891778 A CN 116891778A
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traction machine
elevator traction
lubricating oil
oil
agent
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CN116891778B (en
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周峰
梁依经
蔡美荣
于强亮
张明
王新刚
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Lanzhou Institute of Chemical Physics LICP of CAS
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    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
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Abstract

本发明提供了一种电梯曳引机润滑油及其制备方法和应用,属于电梯曳引机润滑技术领域。本发明中电梯曳引机润滑油包括基体材料与抗泡剂,所述抗泡剂的质量为所述基体材料质量的0.001~0.02%;所述基体材料包括以下质量百分含量的组分:水溶性聚亚烷基二醇87.7~96.1%,油溶性聚醚3.0~10.0%,抗氧剂0.3~0.8%,金属钝化剂0.05~0.1%,极压抗磨剂0.3~0.8%,减摩剂0.2~0.5%,防锈剂0.05~0.1%;所述极压抗磨剂为三‑十二烷基十二烷基季膦盐多库酯离子液体与二辛基磷酸酯十二胺盐;所述减摩剂为非活性硼酸酯和油溶性有机钼盐。本发明提供的电梯曳引机润滑油具有优异的综合性能。The invention provides an elevator traction machine lubricating oil and its preparation method and application, belonging to the technical field of elevator traction machine lubrication. In the present invention, the elevator traction machine lubricating oil includes a base material and an anti-foaming agent. The mass of the anti-foaming agent is 0.001 to 0.02% of the mass of the base material; the base material includes the following components in mass percentage: Water-soluble polyalkylene glycol 87.7~96.1%, oil-soluble polyether 3.0~10.0%, antioxidant 0.3~0.8%, metal passivator 0.05~0.1%, extreme pressure anti-wear agent 0.3~0.8%, minus Friction agent 0.2~0.5%, rust inhibitor 0.05~0.1%; the extreme pressure anti-wear agent is tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid and dioctyl phosphate dodecylamine Salt; the friction reducing agent is an inactive borate ester and an oil-soluble organic molybdenum salt. The elevator traction machine lubricating oil provided by the invention has excellent comprehensive performance.

Description

一种电梯曳引机润滑油及其制备方法和应用Elevator traction machine lubricating oil and its preparation method and application

技术领域Technical field

本发明涉及电梯曳引机润滑技术领域,尤其涉及一种电梯曳引机润滑油及其制备方法和应用。The present invention relates to the technical field of elevator traction machine lubrication, and in particular to an elevator traction machine lubricating oil and its preparation method and application.

背景技术Background technique

电梯分为升降电梯和自动扶梯两大类。各类电梯通常都包括八大组成部分:曳引系统、导向系统、轿厢、门系统、重量平衡系统、电力拖动系统、电气控制系统、安全保护系统。Elevators are divided into two categories: lifts and escalators. All types of elevators usually include eight major components: traction system, guidance system, car, door system, weight balance system, electric drive system, electrical control system, and safety protection system.

对于有齿曳引式电梯,其曳引系统减速齿轮箱的作用是降低曳引机输出转速,增大输出扭矩。曳引系统减速齿轮箱结构有多种,常用的有蜗轮蜗杆式、伞齿轮式和行星齿轮式。蜗轮蜗杆式曳引机的蜗轮大多采用耐磨青铜,蜗杆采用表面渗碳淬火的合金钢,蜗杆传动齿面间的滑动较大,齿面接触时间较长,摩擦磨损情况突出。For toothed traction elevators, the function of the reduction gearbox of the traction system is to reduce the output speed of the traction machine and increase the output torque. There are many types of reduction gearbox structures for traction systems, the commonly used ones are worm gear type, bevel gear type and planetary gear type. The worm gears of worm gear traction machines are mostly made of wear-resistant bronze, and the worms are made of surface carburized and quenched alloy steel. The sliding between the worm transmission tooth surfaces is large, the tooth surface contact time is long, and the friction and wear are prominent.

80年代以前电梯行业的整体用油水平不高,大量普通齿轮油、机械油等都被使用在蜗轮蜗杆副曳引机中。随着电梯技术的发展,曳引机齿轮箱结构日趋紧凑,梯速不断提高,载荷也越来越大,这些油品已明显不能满足新的润滑要求,由此也出现了一些曳引机蜗轮蜗杆副磨损,甚至发生胶合、抱杆等事故。到80年代后期,国内研制成功了普通蜗轮蜗杆油及极压型蜗轮蜗杆油,在一定程度上满足了冶金系统的用油需要,也缓解了电梯曳引机润滑油紧缺的矛盾,因此被电梯行业大量采用,但当时这种油品的研制是为了满足冶金系统引进的大型轧机压下系统蜗轮蜗杆副的润滑,并未充分考虑到电梯曳引机的实际工况以及材质、载荷参数等因素,因此在使用中暴露出一些不适应于电梯曳引机的问题,如腐蚀、传动效率低、承载能力不足等。为了改变这一状况,一些企业在极压蜗轮蜗杆油的基础上均研制出了矿物型电梯专用油,具有较好的油性,比一般极压蜗轮蜗杆油提高了传动效率,且最大限度地减少了对铜部件蜗轮的腐蚀,可使曳引机蜗轮蜗杆寿命大大延长,质量达到国外同类产品水平,目前正在国内普遍使用。Before the 1980s, the overall oil consumption level in the elevator industry was not high, and a large amount of ordinary gear oil, mechanical oil, etc. were used in worm gear traction machines. With the development of elevator technology, the structure of traction machine gearboxes has become increasingly compact, the elevator speed has continued to increase, and the load has become larger and larger. These oils can no longer meet the new lubrication requirements. As a result, some traction machine worm gears have also appeared. The worm pair is worn, and accidents such as gluing and rod holding may even occur. By the late 1980s, ordinary worm gear oil and extreme pressure worm gear oil were successfully developed in China, which met the oil needs of the metallurgical system to a certain extent and also alleviated the shortage of lubricating oil for elevator traction machines. Therefore, they were used by elevators. It is widely used in the industry, but the development of this oil at that time was to meet the lubrication of the worm gear pair of the large-scale rolling mill reduction system introduced by the metallurgical system. The actual working conditions of the elevator traction machine as well as the material, load parameters and other factors were not fully considered. , so some problems that are not suitable for elevator traction machines are exposed during use, such as corrosion, low transmission efficiency, insufficient load-bearing capacity, etc. In order to change this situation, some companies have developed mineral-type elevator special oil based on extreme pressure worm gear oil. It has better oil properties, improves transmission efficiency than general extreme pressure worm gear oil, and minimizes By eliminating the corrosion of the copper parts of the worm gear, the life of the traction machine worm gear can be greatly extended, and the quality reaches the level of similar foreign products. It is currently widely used in China.

随着电梯曳引机技术的不断更新,市场中的电梯曳引机润滑油产品也不断的升级换代。目前,电梯曳引机用油已完成了从矿物型向合成型的转化,按基础油类型不同,合成型电梯油包括聚α烯烃(PAO)型润滑油和聚亚烷基二醇(PAG)型润滑油,其中聚亚烷基二醇型润滑油由于黏度指数更高,高温性能更好,所以应用更为普遍。但目前聚亚烷基二醇(PAG)型电梯曳引机用油的氧化安定性、防锈性及减摩性能仍有待提高。With the continuous updating of elevator traction machine technology, elevator traction machine lubricating oil products in the market are also constantly being upgraded. At present, the oil used in elevator traction machines has completed the transformation from mineral type to synthetic type. According to the type of base oil, synthetic elevator oil includes polyalpha olefin (PAO) lubricating oil and polyalkylene glycol (PAG). Type lubricants, among which polyalkylene glycol type lubricants are more commonly used due to their higher viscosity index and better high temperature performance. However, the oxidation stability, rust prevention and friction reducing properties of polyalkylene glycol (PAG) elevator traction machine oils still need to be improved.

发明内容Contents of the invention

本发明的目的在于提供一种电梯曳引机润滑油及其制备方法和应用,本发明提供的电梯曳引机润滑油综合性能优异,既具有优异的氧化安定性、防锈性和减摩性能,同时还具有优异的黏温性能和极压抗磨性。The object of the present invention is to provide an elevator traction machine lubricating oil and its preparation method and application. The elevator traction machine lubricating oil provided by the invention has excellent comprehensive properties, including excellent oxidation stability, rust prevention and friction reducing properties. , and also has excellent viscosity-temperature properties and extreme pressure and wear resistance.

为了实现上述发明目的,本发明提供以下技术方案:In order to achieve the above-mentioned object of the invention, the present invention provides the following technical solutions:

本发明提供了一种电梯曳引机润滑油,包括基体材料与抗泡剂,所述抗泡剂的质量为所述基体材料质量的0.001~0.02%;The invention provides an elevator traction machine lubricating oil, which includes a base material and an anti-foaming agent, and the mass of the anti-foaming agent is 0.001 to 0.02% of the mass of the base material;

所述基体材料包括以下质量百分含量的组分:The matrix material includes the following components in mass percentage:

水溶性聚亚烷基二醇87.7~96.1%,油溶性聚醚3.0~10.0%,抗氧剂0.3~0.8%,金属钝化剂0.05~0.1%,极压抗磨剂0.3~0.8%,减摩剂0.2~0.5%,防锈剂0.05~0.1%;Water-soluble polyalkylene glycol 87.7~96.1%, oil-soluble polyether 3.0~10.0%, antioxidant 0.3~0.8%, metal passivator 0.05~0.1%, extreme pressure anti-wear agent 0.3~0.8%, minus Friction agent 0.2~0.5%, rust inhibitor 0.05~0.1%;

所述极压抗磨剂为三-十二烷基十二烷基季膦盐多库酯离子液体与二辛基磷酸酯十二胺盐;The extreme pressure anti-wear agent is tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid and dioctyl phosphate dodecaamine salt;

所述减摩剂为非活性硼酸酯和油溶性有机钼盐。The friction reducer is an inactive borate ester and an oil-soluble organic molybdenum salt.

优选地,所述三-十二烷基十二烷基季膦盐多库酯离子液体与二辛基磷酸酯十二胺盐的质量比为1~3:1。Preferably, the mass ratio of the tri-dodecyl dodecyl quaternary phosphonium salt docusate ionic liquid and the dioctyl phosphate dodecylamine salt is 1 to 3:1.

优选地,所述非活性硼酸酯为硼酰胺配合物,所述油溶性有机钼盐为二烷基二硫代氨基甲酸钼。Preferably, the inactive borate ester is a boron amide complex, and the oil-soluble organic molybdenum salt is molybdenum dialkyldithiocarbamate.

优选地,所述非活性硼酸酯与二烷基二硫代氨基甲酸钼的质量比为1.0~1.5:1.0。Preferably, the mass ratio of the inactive borate ester to molybdenum dialkyldithiocarbamate is 1.0-1.5:1.0.

优选地,所述水溶性聚亚烷基二醇包括合成油SDM-03C和合成油SDM-08D;所述水溶性聚亚烷基二醇的40℃运动黏度为40~2200mm2/s。Preferably, the water-soluble polyalkylene glycol includes synthetic oil SDM-03C and synthetic oil SDM-08D; the 40°C kinematic viscosity of the water-soluble polyalkylene glycol is 40 to 2200 mm 2 /s.

优选地,所述油溶性聚醚的40℃运动黏度为15~250mm2/s;所述油溶性聚醚的制备原料包括单体与引发剂,所述单体包括环氧丁烷与环氧丙烷,所述引发剂为醇类化合物。Preferably, the 40°C kinematic viscosity of the oil-soluble polyether is 15 to 250 mm 2 /s; the raw materials for preparing the oil-soluble polyether include monomers and initiators, and the monomers include butylene oxide and epoxy. Propane, the initiator is an alcohol compound.

优选地,所述抗氧剂为烷基酚和烷基苯胺,所述烷基酚和烷基苯胺的质量比为1~3:1。Preferably, the antioxidant is alkylphenol and alkylaniline, and the mass ratio of the alkylphenol to alkylaniline is 1 to 3:1.

优选地,所述金属钝化剂为苯三唑衍生物;所述防锈剂为十七烯基咪唑啉烯基丁二酸盐;所述抗泡剂为硅型抗泡剂与非硅型抗泡剂。Preferably, the metal passivating agent is a benzene triazole derivative; the rust inhibitor is heptadecenyl imidazolinyl succinate; the anti-foaming agent is a silicone-type antifoaming agent and a non-silicon-type antifoaming agent. Antifoaming agent.

本发明提供了上述技术方案所述电梯曳引机润滑油的制备方法,包括以下步骤:The present invention provides a method for preparing lubricating oil for elevator traction machines described in the above technical solution, which includes the following steps:

将水溶性聚亚烷基二醇、油溶性聚醚、抗氧剂、金属钝化剂、极压抗磨剂、减摩剂、防锈剂与抗泡剂混合,得到电梯曳引机润滑油。Mix water-soluble polyalkylene glycol, oil-soluble polyether, antioxidant, metal passivator, extreme pressure anti-wear agent, friction reducer, anti-rust agent and anti-foaming agent to obtain elevator traction machine lubricating oil .

本发明提供了上述技术方案所述电梯曳引机润滑油或上述技术方案所述制备方法制备得到的电梯曳引机润滑油在电梯曳引机蜗轮蜗杆副传动系统润滑中的应用。The present invention provides the application of the elevator traction machine lubricating oil described in the above technical solution or the elevator traction machine lubricating oil prepared by the preparation method described in the above technical solution in the lubrication of the worm gear pair transmission system of the elevator traction machine.

本发明提供了一种电梯曳引机润滑油,包括基体材料与抗泡剂,所述抗泡剂的质量为所述基体材料质量的0.001~0.02%;所述基体材料包括以下质量百分含量的组分:水溶性聚亚烷基二醇87.7~96.1%,油溶性聚醚3.0~10.0%,抗氧剂0.3~0.8%,金属钝化剂0.05~0.1%,极压抗磨剂0.3~0.8%,减摩剂0.2~0.5%,防锈剂0.05~0.1%;所述极压抗磨剂为三-十二烷基十二烷基季膦盐多库酯离子液体与二辛基磷酸酯十二胺盐;所述减摩剂为非活性硼酸酯和油溶性有机钼盐。本发明采用水溶性聚亚烷基二醇和油溶性聚醚作为基础油组分,在充分利用聚亚烷基二醇优异黏温性能、导热性能和热氧化稳定性的同时,又改善了单独使用聚亚烷基二醇时密封材料相容性差以及对其它各添加剂溶解性差的弊端,使得基础油组分保持了良好的综合性能。本发明采用三-十二烷基十二烷基季膦盐多库酯离子液体与二辛基磷酸酯十二胺盐作为极压抗磨剂,减少活性硫的使用有利于保护电梯曳引机铜部件,解决了润滑油极压性和抗腐蚀性之间的矛盾。本发明采用非活性硼酸酯和油溶性有机钼作为减摩剂,能够降低润滑油摩擦系数和牵引系数从而提高传动效率。本发明引入抗氧剂、金属钝化剂、极压抗磨剂、减摩剂、防锈剂以及抗泡剂多种功能添加剂,不同添加剂之间存在极其复杂的相互作用,通过控制各添加剂合适的加入量,使得润滑油具有优异的黏温性能和极佳的热氧化稳定性,能够防止油泥的形成,而且还具有优异的抗磨损保护性能,摩擦系数和牵引系数低,防腐蚀、防锈性能极佳,同时具有导热性能高和低倾点的特点。本发明提供的电梯曳引机润滑油能够用于电梯曳引机蜗轮蜗杆副传动系统的润滑,原料配伍合理,制备方法简单,适用范围广。The invention provides an elevator traction machine lubricating oil, which includes a base material and an anti-foaming agent. The mass of the anti-foaming agent is 0.001 to 0.02% of the mass of the base material; the base material includes the following mass percentages Components: water-soluble polyalkylene glycol 87.7~96.1%, oil-soluble polyether 3.0~10.0%, antioxidant 0.3~0.8%, metal passivator 0.05~0.1%, extreme pressure anti-wear agent 0.3~ 0.8%, friction reducing agent 0.2~0.5%, rust inhibitor 0.05~0.1%; the extreme pressure anti-wear agent is tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid and dioctyl phosphoric acid Ester dodecamine salt; the friction reducing agent is an inactive borate ester and an oil-soluble organic molybdenum salt. The present invention uses water-soluble polyalkylene glycol and oil-soluble polyether as base oil components. While making full use of the excellent viscosity-temperature properties, thermal conductivity and thermal oxidation stability of polyalkylene glycol, it also improves the performance when used alone. The disadvantages of polyalkylene glycol include poor compatibility of sealing materials and poor solubility of other additives make the base oil components maintain good comprehensive properties. The present invention uses tri-dodecyl dodecyl quaternary phosphonium salt docusate ionic liquid and dioctyl phosphate dodecylamine salt as extreme pressure anti-wear agents, which reduces the use of active sulfur and is beneficial to protecting the elevator traction machine. Copper parts solve the contradiction between the extreme pressure properties and corrosion resistance of lubricating oil. The invention uses inactive borate ester and oil-soluble organic molybdenum as friction reducing agents, which can reduce the friction coefficient and traction coefficient of lubricating oil and thereby improve transmission efficiency. The invention introduces multiple functional additives such as antioxidants, metal passivators, extreme pressure anti-wear agents, friction reducers, anti-rust agents and anti-foaming agents. There are extremely complex interactions between different additives. By controlling the appropriateness of each additive The addition amount makes the lubricating oil have excellent viscosity-temperature properties and excellent thermal oxidation stability, which can prevent the formation of sludge. It also has excellent anti-wear protection properties, low friction coefficient and traction coefficient, and is anti-corrosion and anti-rust. Excellent performance, combined with high thermal conductivity and low pour point. The elevator traction machine lubricating oil provided by the invention can be used for the lubrication of the worm gear transmission system of the elevator traction machine. It has reasonable raw material compatibility, simple preparation method and wide application range.

具体实施方式Detailed ways

本发明提供了一种电梯曳引机润滑油,包括基体材料与抗泡剂,所述抗泡剂的质量为所述基体材料质量的0.001~0.02%;The invention provides an elevator traction machine lubricating oil, which includes a base material and an anti-foaming agent, and the mass of the anti-foaming agent is 0.001 to 0.02% of the mass of the base material;

所述基体材料包括以下质量百分含量的组分:The matrix material includes the following components in mass percentage:

水溶性聚亚烷基二醇87.7~96.1%,油溶性聚醚3.0~10.0%,抗氧剂0.3~0.8%,金属钝化剂0.05~0.1%,极压抗磨剂0.3~0.8%,减摩剂0.2~0.5%,防锈剂0.05~0.1%;Water-soluble polyalkylene glycol 87.7~96.1%, oil-soluble polyether 3.0~10.0%, antioxidant 0.3~0.8%, metal passivator 0.05~0.1%, extreme pressure anti-wear agent 0.3~0.8%, minus Friction agent 0.2~0.5%, rust inhibitor 0.05~0.1%;

所述极压抗磨剂为三-十二烷基十二烷基季膦盐多库酯离子液体与二辛基磷酸酯十二胺盐;The extreme pressure anti-wear agent is tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid and dioctyl phosphate dodecaamine salt;

所述减摩剂为非活性硼酸酯和油溶性有机钼盐。The friction reducer is an inactive borate ester and an oil-soluble organic molybdenum salt.

在本发明中,若无特殊说明,所用制备原料均为本领域技术人员熟知的市售商品或采用本领域技术人员熟知的方法制备得到即可。In the present invention, unless otherwise specified, all preparation raw materials used are commercially available products well known to those skilled in the art or can be prepared by methods well known to those skilled in the art.

本发明提供的电梯曳引机润滑油包括基体材料与抗泡剂,按质量百分含量计,本发明所述电梯曳引机润滑油中基体材料包括水溶性聚亚烷基二醇(PAG)87.7~96.1%,优选为90.0~95.0%,更优选为92.0~93.0%。在本发明中,所述水溶性聚亚烷基二醇的40℃运动黏度优选为40~2200mm2/s,更优选为50~1500mm2/s,进一步优选为90~1150mm2/s,再进一步优选为99.08~1042mm2/s。在本发明中,所述水溶性聚亚烷基二醇的制备原料优选包括环氧乙烷与环氧丙烷,所述环氧乙烷与环氧丙烷的摩尔比优选为50~70:30~50。在本发明中,所述水溶性聚亚烷基二醇优选包括合成油SDM-03C和合成油SDM-08D,所述合成油SDM-03C与合成油SDM-08D的质量比优选为1:1.2~7.6,更优选为1:2.0~5.0,进一步优选为1:2.9~3.3。在本发明的实施例中,所述合成油SDM-03C和合成油SDM-08D购自南京威尔化工有限公司。The elevator traction machine lubricating oil provided by the present invention includes a base material and an anti-foaming agent. In terms of mass percentage, the base material in the elevator traction machine lubricating oil includes water-soluble polyalkylene glycol (PAG). 87.7 to 96.1%, preferably 90.0 to 95.0%, more preferably 92.0 to 93.0%. In the present invention, the 40°C kinematic viscosity of the water-soluble polyalkylene glycol is preferably 40 to 2200 mm 2 /s, more preferably 50 to 1500 mm 2 /s, further preferably 90 to 1150 mm 2 /s, and then More preferably, it is 99.08-1042mm2 /s. In the present invention, the raw materials for preparing the water-soluble polyalkylene glycol preferably include ethylene oxide and propylene oxide, and the molar ratio of the ethylene oxide and propylene oxide is preferably 50-70:30- 50. In the present invention, the water-soluble polyalkylene glycol preferably includes synthetic oil SDM-03C and synthetic oil SDM-08D, and the mass ratio of the synthetic oil SDM-03C to synthetic oil SDM-08D is preferably 1:1.2 ~7.6, more preferably 1:2.0~5.0, even more preferably 1:2.9~3.3. In the embodiment of the present invention, the synthetic oil SDM-03C and synthetic oil SDM-08D were purchased from Nanjing Weir Chemical Co., Ltd.

按质量百分含量计,本发明所述电梯曳引机润滑油中基体材料包括油溶性聚醚(OSP)3.0~10.0%,优选为4.0~8.0%,进一步优选为5.0~6.0%。在本发明中,所述油溶性聚醚的40℃运动黏度优选为15~250mm2/s,更优选为20~50mm2/s,进一步优选为29~35mm2/s。在本发明中,所述油溶性聚醚的制备原料优选包括单体与引发剂;所述单体优选包括环氧丁烷与环氧丙烷,所述环氧丁烷与环氧丙烷的摩尔比优选为40~60:40~60;所述引发剂优选为醇类化合物,更优选为正丁醇。在本发明中,所述油溶性聚醚优选为合成油OSP32。在本发明的实施例中,所述合成油OSP32购自南京古田化工有限公司,40℃运动黏度为31.35mm2/s。In terms of mass percentage, the base material in the elevator traction machine lubricating oil of the present invention includes 3.0 to 10.0% of oil-soluble polyether (OSP), preferably 4.0 to 8.0%, and further preferably 5.0 to 6.0%. In the present invention, the 40°C kinematic viscosity of the oil-soluble polyether is preferably 15 to 250 mm 2 /s, more preferably 20 to 50 mm 2 /s, and further preferably 29 to 35 mm 2 /s. In the present invention, the raw materials for preparing the oil-soluble polyether preferably include monomers and initiators; the monomers preferably include butylene oxide and propylene oxide, and the molar ratio of the butylene oxide to propylene oxide The ratio is preferably 40 to 60: 40 to 60; the initiator is preferably an alcohol compound, and more preferably n-butanol. In the present invention, the oil-soluble polyether is preferably synthetic oil OSP32. In the embodiment of the present invention, the synthetic oil OSP32 was purchased from Nanjing Gutian Chemical Co., Ltd., and its kinematic viscosity at 40°C was 31.35mm 2 /s.

本发明采用水溶性聚亚烷基二醇和油溶性聚醚作为基础油组分,二者均为合成油,在充分利用聚亚烷基二醇优异黏温性能、导热性能和热氧化稳定性的同时,又改善了单独使用聚亚烷基二醇时密封材料相容性差以及对其它各添加剂溶解性差的弊端,使得基础油组分保持了良好的综合性能。The present invention uses water-soluble polyalkylene glycol and oil-soluble polyether as base oil components, both of which are synthetic oils. It makes full use of the excellent viscosity-temperature properties, thermal conductivity properties and thermal oxidation stability of polyalkylene glycol. At the same time, it also improves the disadvantages of poor compatibility of sealing materials and poor solubility of other additives when polyalkylene glycol is used alone, so that the base oil component maintains good overall performance.

按质量百分含量计,本发明所述电梯曳引机润滑油中基体材料包括抗氧剂0.3~0.8%,优选为0.50~0.75%。在本发明中,所述抗氧剂优选为烷基酚和烷基苯胺;所述烷基酚和烷基苯胺的质量比优选为1~3:1,更优选为1.5~2:1。在本发明中,所述烷基酚优选为2,6-二叔丁基对甲酚;所述烷基苯胺优选为丁辛基二苯胺。在本发明中,所述2,6-二叔丁基对甲酚优选为锦州康泰润滑油添加剂股份有限公司的T501,所述丁辛基二苯胺优选为BASF公司的IRGANOX L57。本发明优选采用2,6-二叔丁基对甲酚和丁辛基二苯胺作为抗氧剂,二者协同能够提升润滑油的抗氧化性能,防止过早氧化衰退,延长了换油周期和使用寿命。In terms of mass percentage, the base material in the elevator traction machine lubricating oil of the present invention includes 0.3% to 0.8% of antioxidants, preferably 0.50% to 0.75%. In the present invention, the antioxidant is preferably alkylphenol and alkylaniline; the mass ratio of the alkylphenol and alkylaniline is preferably 1 to 3:1, and more preferably 1.5 to 2:1. In the present invention, the alkyl phenol is preferably 2,6-di-tert-butyl-p-cresol; the alkyl aniline is preferably butyl octyl diphenylamine. In the present invention, the 2,6-di-tert-butyl p-cresol is preferably T501 from Jinzhou Kangtai Lubricating Oil Additive Co., Ltd., and the butoctyl diphenylamine is preferably IRGANOX L57 from BASF Company. The present invention preferably uses 2,6-di-tert-butyl-p-cresol and butyloctyl diphenylamine as antioxidants. The synergy between the two can improve the antioxidant performance of lubricating oil, prevent premature oxidation decline, and extend the oil change cycle and service life.

按质量百分含量计,本发明所述电梯曳引机润滑油中基体材料包括金属钝化剂0.05~0.1%,优选为0.06~0.09%,更优选为0.07~0.08%。在本发明中,所述金属钝化剂优选为苯三唑衍生物,所述苯三唑衍生物优选为N,N-双(2-乙基己基)-4-甲基-苯并三唑-1-甲胺。在本发明中,所述N,N-双(2-乙基己基)-4-甲基-苯并三唑-1-甲胺优选为BASF公司的Irgamet 39。本发明优选采用苯三唑衍生物作为金属钝化剂,能够提升润滑油对电梯曳引机蜗轮蜗杆副铜部件的防腐蚀保护。In terms of mass percentage, the base material in the elevator traction machine lubricating oil of the present invention includes 0.05% to 0.1% of metal passivating agent, preferably 0.06% to 0.09%, and more preferably 0.07% to 0.08%. In the present invention, the metal passivating agent is preferably a benzotriazole derivative, and the benzotriazole derivative is preferably N,N-bis(2-ethylhexyl)-4-methyl-benzotriazole. -1-Methylamine. In the present invention, the N,N-bis(2-ethylhexyl)-4-methyl-benzotriazole-1-methylamine is preferably Irgamet 39 from BASF Company. The present invention preferably uses benzene triazole derivatives as metal passivators, which can improve the anti-corrosion protection of lubricating oil on the copper components of the worm gear and worm gear of the elevator traction machine.

按质量百分含量计,本发明所述电梯曳引机润滑油中基体材料包括极压抗磨剂0.3~0.8%,优选为0.50~0.75%。在本发明中,所述极压抗磨剂为三-十二烷基十二烷基季膦盐多库酯离子液体与二辛基磷酸酯十二胺盐,所述三-十二烷基十二烷基季膦盐多库酯离子液体与二辛基磷酸酯十二胺盐的质量比优选为1~3:1,更优选为1.5~2:1。在本发明中,所述二辛基磷酸酯十二胺盐优选为BASF公司的Irgalube 349。本发明对所述三-十二烷基十二烷基季膦盐多库酯离子液体的来源没有特殊限定,采用本领域技术人员熟知的方法制备得到即可(Fan Mingjin,Yang Desuo,Wang Xiaoling,et al.DOSS-Based QAILs:AsBoth Neat Lubricants and Lubricant Additives with ExcellentTribologicalProperties and Good Detergency.Industrial&Engineering Chemistry Research,2014,53(46):17952-17960)。本发明采用三-十二烷基十二烷基季膦盐多库酯离子液体与二辛基磷酸酯十二胺盐作为极压抗磨剂,二者相互之间具有较好的正协同作用,极大提升了极压抗磨性能,且不含有活性硫成分,有利于保护电梯曳引机铜部件,解决了极压性和抗腐蚀性之间的矛盾。In terms of mass percentage, the base material in the elevator traction machine lubricating oil of the present invention includes 0.3% to 0.8% of extreme pressure anti-wear agent, preferably 0.50% to 0.75%. In the present invention, the extreme pressure anti-wear agent is tri-dodecyl dodecyl quaternary phosphonium salt docusate ionic liquid and dioctyl phosphate dodecylamine salt. The mass ratio of the dodecyl quaternary phosphonium salt docusate ionic liquid and the dioctyl phosphate dodecylamine salt is preferably 1 to 3:1, and more preferably 1.5 to 2:1. In the present invention, the dioctyl phosphate dodecaamine salt is preferably Irgalube 349 from BASF Company. The present invention has no special restrictions on the source of the tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid, which can be prepared by methods well known to those skilled in the art (Fan Mingjin, Yang Desuo, Wang Xiaoling ,et al.DOSS-Based QAILs:AsBoth Neat Lubricants and Lubricant Additives with ExcellentTribologicalProperties and Good Detergency.Industrial&Engineering Chemistry Research,2014,53(46):17952-17960). The present invention uses tri-dodecyl dodecyl quaternary phosphonium salt docusate ionic liquid and dioctyl phosphate dodecylamine salt as extreme pressure anti-wear agents, and the two have a good positive synergistic effect with each other. , greatly improves the extreme pressure and anti-wear performance, and does not contain active sulfur components, which is beneficial to protecting the copper parts of the elevator traction machine and solving the contradiction between extreme pressure and corrosion resistance.

按质量百分含量计,本发明所述电梯曳引机润滑油中基体材料包括减摩剂0.2~0.5%,优选为0.30~0.45%。在本发明中,所述减摩剂为非活性硼酸酯和油溶性有机钼盐;所述非活性硼酸酯和油溶性有机钼盐的质量比优选为1.0~1.5:1.0,更优选为1.00~1.25:1.00。在本发明中,所述非活性硼酸酯优选为硼酰胺配合物;在本发明的实施例中,所述非活性硼酸酯具体为Vanderbilt公司的Vanlube 289。在本发明中,所述油溶性有机钼盐优选为二烷基二硫代氨基甲酸钼;在本发明的实施例中,所述二烷基二硫代氨基甲酸钼优选为ADEKA公司的SAKURA-LUBE 525。本发明采用非活性硼酸酯和油溶性有机钼作为减摩剂,具有较好的减摩性能,能降低润滑油的摩擦系数和牵引系数,在实际应用中能够提高电梯曳引机的传动效率,而且与其它添加剂具有较好的配伍性。In terms of mass percentage, the base material in the elevator traction machine lubricating oil of the present invention includes 0.2% to 0.5% of friction reducer, preferably 0.30% to 0.45%. In the present invention, the friction reducing agent is an inactive borate ester and an oil-soluble organic molybdenum salt; the mass ratio of the inactive borate ester and the oil-soluble organic molybdenum salt is preferably 1.0 to 1.5:1.0, and more preferably 1.00~1.25: 1.00. In the present invention, the inactive boric acid ester is preferably a boron amide complex; in the embodiment of the present invention, the inactive boric acid ester is specifically Vanlube 289 of Vanderbilt Company. In the present invention, the oil-soluble organic molybdenum salt is preferably molybdenum dialkyldithiocarbamate; in the embodiment of the present invention, the molybdenum dialkyldithiocarbamate is preferably SAKURA-Dialkyldithiocarbamate from ADEKA. LUBE 525. The invention uses inactive borate ester and oil-soluble organic molybdenum as friction reducing agent, has good friction reducing performance, can reduce the friction coefficient and traction coefficient of lubricating oil, and can improve the transmission efficiency of the elevator traction machine in practical applications. , and has good compatibility with other additives.

按质量百分含量计,本发明所述电梯曳引机润滑油中基体材料包括防锈剂0.05~0.1%,优选为0.06~0.08%。在本发明中,所述防锈剂优选为十七烯基咪唑啉烯基丁二酸盐;在本发明的实施例中,所述十七烯基咪唑啉烯基丁二酸盐具体为上海米德加尔德化工有限公司的T703。本发明优选采用十七烯基咪唑啉烯基丁二酸盐作为防锈剂,不仅具有较好的防锈性能,而且与其它添加剂具有较好的配伍性。In terms of mass percentage, the base material in the elevator traction machine lubricating oil of the present invention includes 0.05% to 0.1% of rust inhibitor, preferably 0.06% to 0.08%. In the present invention, the rust preventive agent is preferably heptadecene imidazolinyl succinate; in the embodiment of the present invention, the heptadecene imidazolinyl succinate is specifically Shanghai T703 from Midgard Chemical Co., Ltd. The present invention preferably uses heptadecenyl imidazolinyl succinate as the anti-rust agent, which not only has good anti-rust performance, but also has good compatibility with other additives.

本发明所述电梯曳引机润滑油包括抗泡剂,所述抗泡剂的质量为所述基体材料质量的0.001~0.02%,优选为0.005~0.01%。在本发明中,所述抗泡剂优选为硅型抗泡剂和非硅型抗泡剂;所述硅型抗泡剂优选为聚甲基硅油;所述非硅型抗泡剂优选为聚丙烯酸酯。在本发明中,所述硅型抗泡剂和非硅型抗泡剂的质量比优选为1~3:1~3,更优选为1~2:1~2。在本发明中,所述硅型抗泡剂聚甲基硅油优选为上海申浦精细化工厂的T901,所述非硅型抗泡剂聚丙烯酸酯优选为上海申浦精细化工厂的T912。本发明限定抗泡剂的用量在上述范围,能够保持一定的泡沫特性,避免润滑油在使用过程中出现因气泡而使油膜破坏造成的干摩擦现象发生。The elevator traction machine lubricating oil of the present invention includes an anti-foaming agent, and the mass of the anti-foaming agent is 0.001 to 0.02% of the mass of the base material, preferably 0.005 to 0.01%. In the present invention, the anti-foaming agent is preferably a silicone-type antifoaming agent and a non-silicon-type antifoaming agent; the silicone-type antifoaming agent is preferably polymethyl silicone oil; the non-silicon-type antifoaming agent is preferably polymethyl silicone oil. Acrylate. In the present invention, the mass ratio of the silicone antifoam agent and the non-silicon antifoam agent is preferably 1 to 3:1 to 3, and more preferably 1 to 2:1 to 2. In the present invention, the silicone antifoaming agent polymethyl silicone oil is preferably T901 from Shanghai Shenpu Fine Chemical Factory, and the non-silicon antifoaming agent polyacrylate is preferably T912 from Shanghai Shenpu Fine Chemical Factory. The present invention limits the amount of anti-foaming agent to the above range, which can maintain a certain foam characteristic and avoid dry friction caused by bubbles in the lubricating oil during use, causing the oil film to be destroyed.

本发明提供了上述技术方案所述电梯曳引机润滑油的制备方法,包括以下步骤:The present invention provides a method for preparing lubricating oil for elevator traction machines described in the above technical solution, which includes the following steps:

将水溶性聚亚烷基二醇、油溶性聚醚、抗氧剂、金属钝化剂、极压抗磨剂、减摩剂、防锈剂与抗泡剂混合,得到电梯曳引机润滑油。Mix water-soluble polyalkylene glycol, oil-soluble polyether, antioxidant, metal passivator, extreme pressure anti-wear agent, friction reducer, anti-rust agent and anti-foaming agent to obtain elevator traction machine lubricating oil .

本发明优选将水溶性聚亚烷基二醇、油溶性聚醚混合,得到基础油组分;在60~80℃且搅拌条件下向所述基础油组分中加入所述抗氧剂、金属钝化剂、极压抗磨剂、减摩剂、防锈剂与抗泡剂,加料完毕后继续在60~80℃条件下搅拌3~5h使所得混合物料均匀透明,冷却后得到电梯曳引机润滑油。在本发明的实施例中,所述混合优选在带搅拌器的不锈钢调合釜内进行。In the present invention, it is preferred to mix water-soluble polyalkylene glycol and oil-soluble polyether to obtain a base oil component; add the antioxidant, metal to the base oil component under stirring conditions at 60-80°C After adding the passivating agent, extreme pressure anti-wear agent, anti-friction agent, anti-rust agent and anti-foaming agent, continue to stir at 60-80°C for 3-5 hours to make the resulting mixture uniform and transparent. After cooling, the elevator traction is obtained Machine lubricant. In the embodiment of the present invention, the mixing is preferably performed in a stainless steel blending kettle with a stirrer.

本发明提供了上述技术方案所述电梯曳引机润滑油或上述技术方案所述制备方法制备得到的电梯曳引机润滑油在电梯曳引机蜗轮蜗杆副传动系统润滑中的应用。The present invention provides the application of the elevator traction machine lubricating oil described in the above technical solution or the elevator traction machine lubricating oil prepared by the preparation method described in the above technical solution in the lubrication of the worm gear pair transmission system of the elevator traction machine.

下面将结合本发明中的实施例,对本发明中的技术方案进行清楚、完整地描述。显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the present invention will be clearly and completely described below with reference to the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts fall within the scope of protection of the present invention.

以下实施例以及对比例中涉及的部分制备原料来源包括:Some of the raw material sources involved in the following examples and comparative examples include:

水溶性聚亚烷基二醇包括合成油SDM-03C和合成油SDM-08D,均购自南京威尔化工有限公司,其中合成油SDM-03C的40℃运动黏度为99.08mm2/s,合成油SDM-08D的40℃运动黏度为1042mm2/s;Water-soluble polyalkylene glycol includes synthetic oil SDM-03C and synthetic oil SDM-08D, both purchased from Nanjing Weil Chemical Co., Ltd. The 40°C kinematic viscosity of synthetic oil SDM-03C is 99.08mm 2 /s. The 40°C kinematic viscosity of oil SDM-08D is 1042mm 2 /s;

油溶性聚醚(OSP)合成油OSP32购自南京古田化工有限公司,40℃运动黏度为31.35mm2/s;Oil-soluble polyether (OSP) synthetic oil OSP32 was purchased from Nanjing Gutian Chemical Co., Ltd., with a kinematic viscosity of 31.35mm 2 /s at 40°C;

2,6-二叔丁基对甲酚为锦州康泰润滑油添加剂股份有限公司的T501;2,6-di-tert-butyl-p-cresol is T501 from Jinzhou Kangtai Lubricating Oil Additive Co., Ltd.;

丁辛基二苯胺为BASF公司的IRGANOX L57;Butyl octyl diphenylamine is IRGANOX L57 from BASF;

N,N-双(2-乙基己基)-4-甲基-苯并三唑-1-甲胺为BASF公司的Irgamet 39;N,N-bis(2-ethylhexyl)-4-methyl-benzotriazole-1-methylamine is Irgamet 39 from BASF;

二辛基磷酸酯十二胺盐为BASF公司的Irgalube 349;The dioctyl phosphate dodecaamine salt is Irgalube 349 from BASF;

非活性硼酸酯为Vanderbilt公司的Vanlube 289;The inactive borate ester is Vanlube 289 from Vanderbilt Company;

二烷基二硫代氨基甲酸钼为ADEKA公司的SAKURA-LUBE 525;Molybdenum dialkyldithiocarbamate is SAKURA-LUBE 525 from ADEKA;

十七烯基咪唑啉烯基丁二酸盐为上海米德加尔德化工有限公司的T703;Heptadecenyl imidazolinyl succinate is T703 from Shanghai Midgard Chemical Co., Ltd.;

硅型抗泡剂聚甲基硅油为上海申浦精细化工厂的T901;The silicone anti-foaming agent polymethyl silicone oil is T901 from Shanghai Shenpu Fine Chemical Factory;

非硅型抗泡剂聚丙烯酸酯为上海申浦精细化工厂的T912;The non-silicon anti-foaming agent polyacrylate is T912 from Shanghai Shenpu Fine Chemical Factory;

三-十二烷基十二烷基季膦盐多库酯离子液体的制备方法如下:The preparation method of tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid is as follows:

在三口圆底烧瓶中加入等摩尔量的三-十二烷基磷和溴代十二烷并加入乙腈作为溶剂,在惰性气体中于70℃条件下反应8h,反应结束后旋蒸去除溶剂,得到亮黄色油状粘稠液体,记为P12121212Br;在三口圆底烧瓶中加入等摩尔量的P12121212Br和磷酸二异辛酯钠,并加无水乙醇将所述P12121212Br和磷酸二异辛酯钠完全溶解,在50℃条件下充分搅拌反应8h,反应结束后加入二氯甲烷溶解所得产物体系,用蒸馏水洗涤,之后用无水硫酸钠干燥,过滤,将滤液进行减压蒸馏去除溶剂,得到的淡黄色透明油状液体即为三-十二烷基十二烷基季膦盐多库酯离子液体。Add an equal molar amount of tri-dodecylphosphorus and dodecyl bromide to a three-necked round-bottom flask and add acetonitrile as the solvent. React in an inert gas at 70°C for 8 hours. After the reaction is completed, the solvent is removed by rotary evaporation. Obtain a bright yellow oily viscous liquid, recorded as P 12121212Br ; add an equimolar amount of P 12121212Br and sodium diisooctyl phosphate into a three-necked round-bottomed flask, and add absolute ethanol to dissolve the P 12121212Br and diisooctyl phosphate. The sodium is completely dissolved, and the reaction is fully stirred at 50°C for 8 hours. After the reaction is completed, dichloromethane is added to dissolve the resulting product system, washed with distilled water, then dried with anhydrous sodium sulfate, filtered, and the filtrate is distilled under reduced pressure to remove the solvent to obtain The light yellow transparent oily liquid is tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid.

以下实施例以及对比例中电梯曳引机润滑油均在带搅拌器的不锈钢调合釜中制备。The elevator traction machine lubricating oil in the following examples and comparative examples was prepared in a stainless steel blending kettle with a stirrer.

实施例1Example 1

向27.6g水溶性聚亚烷基二醇合成油SDM-03C中加入60.1g水溶性聚亚烷基二醇合成油SDM-08D和10.0g油溶性聚醚合成油OSP32,升温至70±5℃并进行搅拌,再加入0.60g的2,6-二叔丁基对甲酚、0.20g的丁辛基二苯胺、0.1g的N,N-双(2-乙基己基)-4-甲基-苯并三唑-1-甲胺、0.60g的三-十二烷基十二烷基季膦盐多库酯离子液体、0.20g的二辛基磷酸酯十二胺盐、0.30g的非活性硼酸酯、0.20g的二烷基二硫代氨基甲酸钼、0.1g的十七烯基咪唑啉烯基丁二酸盐、0.0133g的硅型抗泡剂聚甲基硅油和0.0067g非硅型抗泡剂聚丙烯酸酯,在70±5℃条件下搅拌3h,冷却至室温(25℃)即得电梯曳引机润滑油。Add 60.1g water-soluble polyalkylene glycol synthetic oil SDM-08D and 10.0g oil-soluble polyether synthetic oil OSP32 to 27.6g water-soluble polyalkylene glycol synthetic oil SDM-03C, and raise the temperature to 70±5℃ And stir, then add 0.60g of 2,6-di-tert-butyl-p-cresol, 0.20g of butoctyldiphenylamine, and 0.1g of N,N-bis(2-ethylhexyl)-4-methyl - Benzotriazole-1-methylamine, 0.60g of tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid, 0.20g of dioctylphosphate dodecaamine salt, 0.30g of non- Active borate ester, 0.20g of molybdenum dialkyldithiocarbamate, 0.1g of heptadecenyl imidazolinyl succinate, 0.0133g of silicone antifoam agent polymethyl silicone oil and 0.0067g of non- Stir the silicone anti-foaming agent polyacrylate for 3 hours at 70±5°C and cool to room temperature (25°C) to obtain the elevator traction machine lubricating oil.

实施例2Example 2

向21.8g水溶性聚亚烷基二醇合成油SDM-03C中加入71.1g水溶性聚亚烷基二醇合成油SDM-08D和5.0g油溶性聚醚合成油OSP32,升温至70±5℃并进行搅拌,再加入0.50g的2,6-二叔丁基对甲酚、0.25g的丁辛基二苯胺、0.07g的N,N-双(2-乙基己基)-4-甲基-苯并三唑-1-甲胺、0.50g的三-十二烷基十二烷基季膦盐多库酯离子液体、0.25g的二辛基磷酸酯十二胺盐、0.25g的非活性硼酸酯、0.20g的二烷基二硫代氨基甲酸钼、0.08g的十七烯基咪唑啉烯基丁二酸盐、0.005g的硅型抗泡剂聚甲基硅油和0.005g非硅型抗泡剂聚丙烯酸酯,在70±5℃条件下搅拌3h,冷却至室温(25℃)即得电梯曳引机润滑油。Add 71.1g water-soluble polyalkylene glycol synthetic oil SDM-08D and 5.0g oil-soluble polyether synthetic oil OSP32 to 21.8g water-soluble polyalkylene glycol synthetic oil SDM-03C, and raise the temperature to 70±5℃ And stir, then add 0.50g of 2,6-di-tert-butyl-p-cresol, 0.25g of butoctyldiphenylamine, and 0.07g of N,N-bis(2-ethylhexyl)-4-methyl - Benzotriazole-1-methylamine, 0.50g of tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid, 0.25g of dioctylphosphate dodecamine salt, 0.25g of non- Active borate ester, 0.20g molybdenum dialkyldithiocarbamate, 0.08g heptadecenyl imidazolinyl succinate, 0.005g silicone antifoam agent polymethyl silicone oil and 0.005g non- Stir the silicone anti-foaming agent polyacrylate for 3 hours at 70±5°C and cool to room temperature (25°C) to obtain the elevator traction machine lubricating oil.

实施例3Example 3

向24.5g水溶性聚亚烷基二醇合成油SDM-03C中加入71.6g水溶性聚亚烷基二醇合成油SDM-08D和3.0g油溶性聚醚合成油OSP32,升温至70±5℃并进行搅拌,再加入0.15g的2,6-二叔丁基对甲酚、0.15g的丁辛基二苯胺、0.05g的N,N-双(2-乙基己基)-4-甲基-苯并三唑-1-甲胺、0.15g的三-十二烷基十二烷基季膦盐多库酯离子液体、0.15g的二辛基磷酸酯十二胺盐、0.10g的非活性硼酸酯、0.10g的二烷基二硫代氨基甲酸钼、0.05g的十七烯基咪唑啉烯基丁二酸盐、0.0003g的硅型抗泡剂聚甲基硅油和0.0007g非硅型抗泡剂聚丙烯酸酯,在70±5℃条件下搅拌3h,冷却至室温(25℃)即得电梯曳引机润滑油。Add 71.6g water-soluble polyalkylene glycol synthetic oil SDM-08D and 3.0g oil-soluble polyether synthetic oil OSP32 to 24.5g water-soluble polyalkylene glycol synthetic oil SDM-03C, and raise the temperature to 70±5℃ And stir, then add 0.15g of 2,6-di-tert-butyl-p-cresol, 0.15g of butoctyldiphenylamine, and 0.05g of N,N-bis(2-ethylhexyl)-4-methyl - Benzotriazole-1-methylamine, 0.15g of tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid, 0.15g of dioctylphosphate dodecaamine salt, 0.10g of non- Active borate ester, 0.10g of molybdenum dialkyldithiocarbamate, 0.05g of heptadecenyl imidazolinyl succinate, 0.0003g of silicone antifoam agent polymethyl silicone oil and 0.0007g of non- Stir the silicone anti-foaming agent polyacrylate for 3 hours at 70±5°C and cool to room temperature (25°C) to obtain the elevator traction machine lubricating oil.

对比例1Comparative example 1

按照实施例3制备电梯曳引机润滑油,不同之处仅在于将0.15g的三-十二烷基十二烷基季膦盐多库酯离子液体和0.15g的二辛基磷酸酯十二胺盐,替换成0.30g的二辛基磷酸酯十二胺盐。Elevator traction machine lubricating oil was prepared according to Example 3, except that 0.15g of tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid and 0.15g of dioctyl phosphate dodecyl phosphate were mixed. Amine salt, replaced with 0.30 g of dioctyl phosphate dodecaamine salt.

对比例2Comparative example 2

按照实施例3制备电梯曳引机润滑油,不同之处仅在于将0.10g的非活性硼酸酯和0.10g的二烷基二硫代氨基甲酸钼,替换成0.20g的二烷基二硫代氨基甲酸钼。Elevator traction machine lubricating oil was prepared according to Example 3, except that 0.10 g of inactive borate ester and 0.10 g of molybdenum dialkyldithiocarbamate were replaced with 0.20 g of dialkyl disulfide. Substitute molybdenum carbamate.

对比例3Comparative example 3

按照实施例3制备电梯曳引机润滑油,不同之处仅在于将0.15g的三-十二烷基十二烷基季膦盐多库酯离子液体和0.15g的二辛基磷酸酯十二胺盐,替换成0.15g的三-十二烷基甲基季铵盐多库酯离子液体和0.15g的二辛基磷酸酯十八胺盐。Elevator traction machine lubricating oil was prepared according to Example 3, except that 0.15g of tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid and 0.15g of dioctyl phosphate dodecyl phosphate were mixed. The amine salt was replaced with 0.15g of tri-dodecylmethyl quaternary ammonium salt docusate ionic liquid and 0.15g of dioctyl phosphate stearylamine salt.

对实施例与对比例制备的电梯曳引机润滑油进行性能测试,结果见表1。Performance tests were conducted on the elevator traction machine lubricants prepared in the Examples and Comparative Examples. The results are shown in Table 1.

表1实施例以及对比例制备的电梯曳引机润滑油的性能测试结果Table 1 Performance test results of elevator traction machine lubricants prepared in Examples and Comparative Examples

由表1可知,本发明提供的电梯曳引机润滑油具有优异的黏温性能和极佳的热氧化稳定性,能够有效防止油泥的形成,而且具有优异的抗磨损保护性能,摩擦系数低,防腐蚀、防锈性能极佳,同时具有低倾点的特点,并具有良好的抗泡性能和橡胶相容性。同时,与对比例1相比,实施例3制备的电梯曳引机润滑油极压抗磨性能优异,说明本发明采用三-十二烷基十二烷基季膦盐多库酯离子液体和二辛基磷酸酯十二胺盐复配能够产生较好的正协同效果,极大提升润滑油的极压抗磨性能;与对比例2相比,实施例3制备的电梯曳引机润滑油减摩性能优异,说明本发明采用非活性硼酸酯和二烷基二硫代氨基甲酸钼复配,二者产生很好的协同效应,能够降低润滑油的摩擦系数。As can be seen from Table 1, the elevator traction machine lubricating oil provided by the present invention has excellent viscosity-temperature properties and excellent thermal oxidation stability, can effectively prevent the formation of sludge, and has excellent anti-wear protection performance and low friction coefficient. It has excellent anti-corrosion and anti-rust properties, has a low pour point, and has good anti-foaming properties and rubber compatibility. At the same time, compared with Comparative Example 1, the elevator traction machine lubricating oil prepared in Example 3 has excellent extreme pressure and anti-wear properties, indicating that the present invention uses tri-dodecyldodecyl quaternary phosphonium salt docusate ionic liquid and The compounding of dioctyl phosphate dodecaamine salt can produce a better positive synergistic effect and greatly improve the extreme pressure and anti-wear performance of lubricating oil; compared with Comparative Example 2, the elevator traction machine lubricating oil prepared in Example 3 The excellent friction reducing performance shows that the present invention uses a compound of inactive borate ester and molybdenum dialkyldithiocarbamate, which produces a good synergistic effect and can reduce the friction coefficient of lubricating oil.

以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above are only preferred embodiments of the present invention. It should be noted that those skilled in the art can make several improvements and modifications without departing from the principles of the present invention. These improvements and modifications can also be made. should be regarded as the protection scope of the present invention.

Claims (10)

1. The elevator traction machine lubricating oil comprises a base material and an anti-foaming agent, wherein the mass of the anti-foaming agent is 0.001-0.02% of the mass of the base material;
the matrix material comprises the following components in percentage by mass:
87.7 to 96.1 percent of water-soluble polyalkylene glycol, 3.0 to 10.0 percent of oil-soluble polyether, 0.3 to 0.8 percent of antioxidant, 0.05 to 0.1 percent of metal passivating agent, 0.3 to 0.8 percent of extreme pressure antiwear agent, 0.2 to 0.5 percent of antifriction agent and 0.05 to 0.1 percent of antirust agent;
the extreme pressure antiwear agent is tri-dodecyl quaternary phosphonium salt docusate ionic liquid and dioctyl phosphate dodecyl amine salt;
the friction reducer is inactive borate and oil-soluble organic molybdenum salt.
2. The elevator traction machine lubricating oil according to claim 1, wherein the mass ratio of the tri-dodecyl quaternary phosphonium salt multi-base ester ionic liquid to dioctyl phosphate dodecyl amine salt is 1-3: 1.
3. the elevator traction machine lubricating oil of claim 1, wherein the inactive borate ester is a boroamide complex and the oil-soluble organic molybdenum salt is molybdenum dialkyldithiocarbamate.
4. The elevator traction machine lubricating oil according to claim 3, wherein the mass ratio of the inactive boric acid ester to the molybdenum dialkyldithiocarbamate is 1.0 to 1.5:1.0.
5. the elevator traction machine lubricating oil of claim 1, wherein the water-soluble polyalkylene glycol comprises synthetic oil SDM-03C and synthetic oil SDM-08D; the kinematic viscosity of the water-soluble polyalkylene glycol at 40 ℃ is 40-2200 mm 2 /s。
6. The elevator traction machine lubricating oil according to claim 1, wherein the oil-soluble polyether has an kinematic viscosity at 40 ℃ of 15 to 250mm 2 S; the preparation raw materials of the oil-soluble polyether comprise monomers and an initiator, wherein the monomers comprise epoxybutane and epoxypropane, and the initiator is an alcohol compound.
7. The elevator traction machine lubricating oil according to claim 1, wherein the antioxidant is alkylphenol and alkylaniline, and the mass ratio of the alkylphenol to the alkylaniline is 1-3: 1.
8. the elevator traction machine lubricating oil according to claim 1, wherein the metal deactivator is a benzotriazole derivative; the antirust agent is heptadecenyl imidazoline alkenyl succinate; the anti-foaming agent is a silicon type anti-foaming agent and a non-silicon type anti-foaming agent.
9. The method for producing the elevator traction machine lubricating oil according to any one of claims 1 to 8, comprising the steps of:
mixing water-soluble polyalkylene glycol, oil-soluble polyether, an antioxidant, a metal passivating agent, an extreme pressure antiwear agent, a friction reducer, an antirust agent and an antifoaming agent to obtain the elevator traction machine lubricating oil.
10. Use of the elevator traction machine lubricating oil according to any one of claims 1 to 8 or the elevator traction machine lubricating oil prepared by the preparation method according to claim 9 in lubrication of an elevator traction machine worm gear pair transmission system.
CN202310868654.5A 2023-07-17 2023-07-17 Elevator traction machine lubricating oil and preparation method and application thereof Active CN116891778B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403741A (en) * 2014-10-17 2015-03-11 中国石油化工股份有限公司 Worm wheel worm rod lubricating oil composition and preparation method thereof
CN109233960A (en) * 2018-10-26 2019-01-18 辽宁海华科技股份有限公司 A kind of industrial robot precision speed reduction device lubricant oil composite
CN114606043A (en) * 2022-03-18 2022-06-10 中国科学院兰州化学物理研究所 Synthetic open gear lubricating oil and preparation method and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104403741A (en) * 2014-10-17 2015-03-11 中国石油化工股份有限公司 Worm wheel worm rod lubricating oil composition and preparation method thereof
CN109233960A (en) * 2018-10-26 2019-01-18 辽宁海华科技股份有限公司 A kind of industrial robot precision speed reduction device lubricant oil composite
CN114606043A (en) * 2022-03-18 2022-06-10 中国科学院兰州化学物理研究所 Synthetic open gear lubricating oil and preparation method and application thereof

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