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CN116872593A - Mosquito-repellent textile and production method thereof - Google Patents

Mosquito-repellent textile and production method thereof Download PDF

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Publication number
CN116872593A
CN116872593A CN202310830644.2A CN202310830644A CN116872593A CN 116872593 A CN116872593 A CN 116872593A CN 202310830644 A CN202310830644 A CN 202310830644A CN 116872593 A CN116872593 A CN 116872593A
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mosquito
mosquito repellent
parts
repellent
emulsion
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Inventor
胡雪丽
王耀民
刘文博
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Shanghai Liangfeng Leading Technology Development Co ltd
Shanghai Liangfeng New Material Technology Co ltd
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Shanghai Liangfeng Leading Technology Development Co ltd
Shanghai Liangfeng New Material Technology Co ltd
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Priority to CN202310830644.2A priority Critical patent/CN116872593A/en
Publication of CN116872593A publication Critical patent/CN116872593A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M29/00Scaring or repelling devices, e.g. bird-scaring apparatus
    • A01M29/12Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/28Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/285Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyethers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/06Embossing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • B32B38/164Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Insects & Arthropods (AREA)
  • Toxicology (AREA)
  • Birds (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Textile Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

本发明属于功能性纺织品领域,公开了一种驱蚊纺织品及其生产方法,所述驱蚊纺织品的生产方法包括以下步骤:(1)、以含有化纤的面料为基材,将所述基材一个表面涂覆含有驱蚊剂的乳液,烘干;所述含有驱蚊剂的乳液包括如下重量份组分:100份驱蚊剂微胶囊;20‑50份驱蚊植物精油微胶囊;1‑5份二氧化硅气凝胶颗粒;2‑10份水性成膜剂;0.5‑2份增稠剂;0‑15份水;(2)、将步骤(1)烘干后的产物进行超声波粘合压花,使其经过乳液涂覆的表面粘合微孔膜,得到驱蚊纺织品。本发明生产得到的驱蚊纺织品具有持久的驱蚊效果,并且舒适度体验良好。The invention belongs to the field of functional textiles and discloses a mosquito-repellent textile and a production method thereof. The production method of the mosquito-repellent textile includes the following steps: (1) Using fabrics containing chemical fibers as a base material, One surface is coated with an emulsion containing mosquito repellent and dried; the emulsion containing mosquito repellent includes the following components by weight: 100 parts of mosquito repellent microcapsules; 20-50 parts of mosquito repellent plant essential oil microcapsules; 1- 5 parts of silica airgel particles; 2-10 parts of aqueous film-forming agent; 0.5-2 parts of thickening agent; 0-15 parts of water; (2), carry out ultrasonic bonding of the dried product of step (1) The mosquito-repellent textiles are obtained by combining and embossing them with an emulsion-coated surface-adhesive microporous film. The mosquito repellent textile produced by the invention has a long-lasting mosquito repellent effect and good comfort experience.

Description

一种驱蚊纺织品及其生产方法Mosquito repellent textile and production method thereof

技术领域Technical field

本发明涉及功能性纺织品技术领域,特别涉及一种驱蚊纺织品及其生产方法。The present invention relates to the technical field of functional textiles, and in particular to a mosquito repellent textile and a production method thereof.

背景技术Background technique

功能性纺织品是指纺织品除具有自身的基本使用价值外,还具有其他附加的特殊功能,如防水、防油污、抗菌、防蚊虫等功能。其中,驱蚊纺织品主要具有驱避蚊虫的功能。每到天气变暖,蚊子活动也增强,给人们徒增很多烦恼。蚊子不仅影响人们生活还传播疾病,扰乱大家生活。现有的纺织品用驱蚊方法繁多,例如印染后整理,纺丝加工法,其成分、效力有效时间、安环性参差不齐,防蚊效果也不一样。Functional textiles refer to textiles that, in addition to their own basic use value, also have other additional special functions, such as waterproof, oil-proof, antibacterial, mosquito-proof and other functions. Among them, mosquito repellent textiles mainly have the function of repelling mosquitoes. Every time the weather gets warmer, mosquito activity also increases, causing people a lot of trouble. Mosquitoes not only affect people's lives but also spread diseases and disrupt everyone's lives. There are many methods for repelling mosquitoes on textiles, such as finishing after printing and dyeing, and spinning processing methods. Their ingredients, effective time, safety and environmental properties are uneven, and the mosquito repellent effects are also different.

伊默宁(又叫驱蚊酯)是一种广谱、高效的昆虫驱避剂,对苍蝇、蚊子等都有良好的驱避效果;其具有毒性更低、刺激性更小、驱避时间更长等显著特点,可以制成溶液、乳剂、油膏、气雾剂、蚊香、微胶囊等专用驱避药剂。然而,伊默宁直接处理的纺织品,其驱蚊效力持续时间仅为4-8个小时,如何将伊默宁等驱蚊剂持久地固定在纺织品上,又不影响使用体验,成为现在纺织品防蚊技术研究的方向之一。Imonin (also called insect repellent) is a broad-spectrum, highly efficient insect repellent that has good repellent effects on flies, mosquitoes, etc.; it has lower toxicity, less irritation, and longer repellent time With its distinctive features such as longer length, it can be made into solutions, emulsions, ointments, aerosols, mosquito coils, microcapsules and other special repellent agents. However, the mosquito repellent effect of textiles directly treated by Imonin lasts only 4-8 hours. How to permanently fix mosquito repellents such as Imonin on textiles without affecting the use experience has become a problem for today's textile repellents. One of the directions of mosquito technology research.

发明内容Contents of the invention

鉴于以上现有技术的缺点,本发明的目的在于提供一种驱蚊纺织品及其生产方法,本发明生产得到的驱蚊纺织品具有持久的驱蚊效果,并且舒适度体验良好。In view of the above shortcomings of the prior art, the purpose of the present invention is to provide a mosquito repellent textile and a production method thereof. The mosquito repellent textile produced by the present invention has a long-lasting mosquito repellent effect and a good comfort experience.

本发明提供一种驱蚊纺织品的生产方法,包括以下步骤:The invention provides a production method of mosquito repellent textiles, which includes the following steps:

(1)、以含有化纤的面料为基材,将所述基材一个表面涂覆含有驱蚊剂的乳液,烘干;所述含有驱蚊剂的乳液包括如下重量份组分:(1). Use a fabric containing chemical fiber as a base material, coat one surface of the base material with an emulsion containing a mosquito repellent, and dry it; the emulsion containing a mosquito repellent includes the following components by weight:

100份驱蚊剂微胶囊;20-50份驱蚊植物精油微胶囊;1-5份二氧化硅气凝胶微粒;2-10份水性成膜剂;0.5-2份增稠剂;0-15份水;100 parts of mosquito repellent microcapsules; 20-50 parts of mosquito repellent plant essential oil microcapsules; 1-5 parts of silica aerogel particles; 2-10 parts of water-based film-forming agent; 0.5-2 parts of thickener; 0- 15 parts water;

(2)、将步骤(1)烘干后的产物进行超声波粘合压花,使其经过乳液涂覆的表面粘合上微孔膜,得到驱蚊纺织品。(2) The product dried in step (1) is subjected to ultrasonic bonding and embossing, and a microporous film is bonded to the emulsion-coated surface to obtain a mosquito repellent textile.

优选地,所述基材中的化纤材质为涤纶、尼龙、聚乙烯、聚乳酸和聚丙烯中的一种或多种;所述基材还含有纤维素纤维。Preferably, the chemical fiber material in the base material is one or more of polyester, nylon, polyethylene, polylactic acid and polypropylene; the base material also contains cellulose fibers.

优选地,所述涂覆为辊涂方式,所采用的涂饰辊目数为80-120目;涂饰量为4-10g/m2Preferably, the coating is a roller coating method, the mesh number of the coating roller used is 80-120 mesh, and the coating amount is 4-10g/m 2 .

优选地,所述驱蚊剂微胶囊的有效成分为驱蚊酯;所述驱蚊植物精油微胶囊中含有芦荟精油、桉树精油和尼姆树精油中的一种或多种。Preferably, the active ingredient of the mosquito repellent microcapsules is mosquito repellent; the mosquito repellent plant essential oil microcapsules contain one or more of aloe essential oil, eucalyptus essential oil and neem essential oil.

优选地,所述含有驱蚊剂的乳液固含量为20%~40%,室温粘度为80-120dPa.s。Preferably, the solid content of the emulsion containing mosquito repellent is 20% to 40%, and the room temperature viscosity is 80-120dPa.s.

优选地,所述烘干的温度为100-130℃,时间为2-10min。Preferably, the drying temperature is 100-130°C and the drying time is 2-10 minutes.

优选地,所述超声波粘合压花的图案为非实心的闭环图案,图案之间有间隙。Preferably, the ultrasonic bonding embossed pattern is a non-solid closed-loop pattern with gaps between the patterns.

优选地,所述超声波粘合压花的振动频率为20-30kHz,车速为4-6m/min。Preferably, the vibration frequency of the ultrasonic bonding embossing is 20-30kHz, and the vehicle speed is 4-6m/min.

优选地,所述微孔膜的平均孔径为0.3-0.5nm,厚度为0.3-0.5μm;所述微孔膜为聚氨酯微孔膜、聚四氟乙烯微孔膜、聚酯微孔膜或聚醚微孔膜。Preferably, the microporous membrane has an average pore diameter of 0.3-0.5 nm and a thickness of 0.3-0.5 μm; the microporous membrane is a polyurethane microporous membrane, a polytetrafluoroethylene microporous membrane, a polyester microporous membrane or a polyester microporous membrane. Ether microporous membrane.

优选地,所述涂覆方式可以为辊涂或刮涂。Preferably, the coating method can be roller coating or blade coating.

此外,本发明提供根据前文所述的生产方法得到的驱蚊纺织品。Furthermore, the present invention provides mosquito repellent textiles obtained according to the production method described above.

与现有技术相比,本发明实施例采用一定比例的驱蚊酯和天然驱蚊植物精油为驱蚊助剂,通过涂覆方式将有效成分附着到面料等纺织品表面;其中天然驱蚊植物精油可以协同驱蚊效果,植物中的抗菌成分还可以抑制纺织品上细菌的滋生;二氧化硅气凝胶微粒的加入,可以吸收乳液中的异味,改善驱蚊剂乳液的气味,减少纺织品的不适感。驱蚊剂虽然被粘合到纺织品上,但长期暴露在空气中散失也很快。本发明进一步采用超声波粘合技术,将透湿防水的微孔膜贴合在纺织品的反面,使其形成一个相对封闭的空间,驱蚊剂等助剂挥发性受到限制,相应的可以延长驱蚊时间。实验显示,本发明所得到的驱蚊纺织品具有持久的驱蚊效果,并且舒适度体验良好。Compared with the prior art, embodiments of the present invention use a certain proportion of mosquito repellent ester and natural mosquito repellent plant essential oils as mosquito repellent auxiliaries, and the active ingredients are attached to the surface of textiles such as fabrics through coating; among which, natural mosquito repellent plant essential oils It can synergize with the mosquito repellent effect, and the antibacterial ingredients in plants can also inhibit the growth of bacteria on textiles; the addition of silica airgel particles can absorb odors in lotions, improve the smell of mosquito repellent lotions, and reduce discomfort on textiles . Although mosquito repellent is bonded to textiles, it dissipates quickly when exposed to the air for a long time. The present invention further uses ultrasonic bonding technology to attach the moisture-permeable and waterproof microporous film to the reverse side of the textile to form a relatively closed space. The volatility of mosquito repellent and other additives is limited, and accordingly the mosquito repellent can be extended. time. Experiments show that the mosquito repellent textile obtained by the present invention has a long-lasting mosquito repellent effect and has good comfort experience.

此外,本发明选用超声波粘合技术,一是改善了传统针线粘合对微孔膜的破坏;二是超声波粘合可以实现连续的点状粘合,减少封闭空间的通道;三是通过点状粘合可以在纺织品表面形成图案,增加纺织品的美感。不同颜色的微孔膜可以形成多彩的图案,增加纺织品的童趣。该产品可以用于帐篷、地垫、推车,也可以用于床垫等产品,具有较好的实用性。In addition, the present invention uses ultrasonic bonding technology. First, it improves the damage to the microporous membrane caused by traditional needle thread bonding. Second, ultrasonic bonding can achieve continuous point bonding and reduce the passage of closed spaces. Third, through point-like bonding, Bonding can create patterns on the surface of textiles, adding to their beauty. Microporous films of different colors can form colorful patterns, adding to the childlike interest of textiles. This product can be used for tents, floor mats, carts, mattresses and other products, and has good practicality.

具体实施方式Detailed ways

下面对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。The technical solutions in the embodiments of the present application are clearly and completely described below. Obviously, the described embodiments are only some of the embodiments of the present application, rather than all the embodiments. Based on the embodiments in this application, all other embodiments obtained by those of ordinary skill in the art without creative efforts fall within the scope of protection of this application.

本发明提供了一种驱蚊纺织品的生产方法,包括以下步骤:The invention provides a production method of mosquito repellent textiles, which includes the following steps:

(1)、以含有化纤的面料为基材,将所述基材一个表面涂覆含有驱蚊剂的乳液,烘干;所述含有驱蚊剂的乳液包括如下重量份组分:(1). Use a fabric containing chemical fiber as a base material, coat one surface of the base material with an emulsion containing a mosquito repellent, and dry it; the emulsion containing a mosquito repellent includes the following components by weight:

100份驱蚊剂微胶囊;20-50份驱蚊植物精油微胶囊;1-5份二氧化硅气凝胶;2-10份水性成膜剂;0.5-2份增稠剂;0-15份水;100 parts of mosquito repellent microcapsules; 20-50 parts of mosquito repellent plant essential oil microcapsules; 1-5 parts of silica aerogel; 2-10 parts of water-based film-forming agent; 0.5-2 parts of thickener; 0-15 portion of water;

(2)、将步骤(1)烘干后的产物进行超声波粘合压花,使其经过乳液涂覆的表面粘合上微孔膜,得到驱蚊纺织品。(2) The product dried in step (1) is subjected to ultrasonic bonding and embossing, and a microporous film is bonded to the emulsion-coated surface to obtain a mosquito repellent textile.

本发明提供的生产方法得到使用体验良好的驱蚊纺织品,主要用于解决现有技术中纺织品驱蚊效果不持久的问题。The production method provided by the invention obtains mosquito repellent textiles with good user experience, and is mainly used to solve the problem in the prior art that the mosquito repellent effect of textiles is not long-lasting.

本发明实施例选用含有化纤的面料作为基材;所述基材中的化纤材质可以为涤纶、尼龙、聚乙烯、聚乳酸和聚丙烯中的一种或多种。所述基材的材质还含有纤维素纤维成分,如棉、竹纤维、粘胶纤维、莫代尔纤维、天丝等,以增加面料的吸湿透气性能。其中,莫代尔和天丝都属于再生纤维素纤维,分别是不同的商品名。本发明对所述基材的面料组织、规格等并无特殊限制,克重范围在40-100gsm。In the embodiment of the present invention, a fabric containing chemical fibers is selected as the base material; the chemical fiber material in the base material can be one or more of polyester, nylon, polyethylene, polylactic acid and polypropylene. The base material also contains cellulose fiber components, such as cotton, bamboo fiber, viscose fiber, modal fiber, Tencel, etc., to increase the moisture absorption and breathability of the fabric. Among them, Modal and Tencel are both regenerated cellulose fibers, and they have different trade names. The present invention has no special restrictions on the fabric structure, specifications, etc. of the base material, and the weight range is 40-100gsm.

在本发明的一些实施例中,可以选用涤棉梭织面料前处理布,面料规格为40S*40S130*90,经纬纱支为40S,经纱密度为130根/英寸,纬纱密度为90根/英寸,成分质量配比为:70%涤、30%棉。In some embodiments of the present invention, polyester-cotton woven fabric pre-treatment cloth can be used. The fabric specifications are 40S*40S130*90, the warp and weft yarn counts are 40S, the warp yarn density is 130 yarns/inch, and the weft yarn density is 90 yarns/inch. , the ingredient mass ratio is: 70% polyester, 30% cotton.

本发明实施例进行含有驱蚊剂的乳液的配制:可将一定比例的二氧化硅气凝胶微粒倒入水中,进行充分分散,再加入驱蚊剂微胶囊乳液、驱蚊植物精油微胶囊乳液、水性成膜剂,搅拌均匀后,再加入增稠剂搅拌,调节pH为6-7。上述各原料组分混合后形成所述的乳液,具体操作方法包括:将二氧化硅气凝胶微粒乳液倒入装水的配料桶中,在900转/min下搅拌13min,再将驱蚊剂微胶囊乳液、驱蚊植物精油微胶囊乳液、加入到配料桶中,搅拌均匀后,边加入增稠剂边搅拌,直到稠度适中,得到混合浆料,再用乙酸调节混合液的pH;最后将混合浆料通过80-120目滤网过滤,待用。In the embodiment of the present invention, an emulsion containing mosquito repellent is prepared: a certain proportion of silica airgel particles can be poured into water, fully dispersed, and then the mosquito repellent microcapsule emulsion and the mosquito repellent plant essential oil microcapsule emulsion are added. , water-based film-forming agent, stir evenly, then add thickener, stir, and adjust the pH to 6-7. The above-mentioned raw material components are mixed to form the emulsion. The specific operation method includes: pouring the silica airgel particle emulsion into an ingredient bucket filled with water, stirring at 900 rpm for 13 minutes, and then adding the mosquito repellent Microcapsule emulsion and mosquito repellent plant essential oil microcapsule emulsion are added to the ingredients bucket. After stirring evenly, add the thickener while stirring until the consistency is moderate to obtain a mixed slurry, and then use acetic acid to adjust the pH of the mixed solution; finally, Filter the mixed slurry through a 80-120 mesh filter and set aside.

其中,以上配制原料可采用微胶囊均匀分散在水中形成的乳液;所述驱蚊剂微胶囊乳液的有效成分为驱蚊酯,如市售的伊默宁。该微胶囊壁材结构成分包括二氧化硅、密胺树脂等,乳液固含量35-45%(固含量是微胶囊与水的质量比),粒径2-20微米。所述驱蚊植物精油微胶囊乳液有效成分为具有驱蚊效果的天然植物精油微胶囊,如桉树精油、尼姆树精油、芦荟精油,乳液固含量35-45%,粒径1.8-2.3微米;该微胶囊壁材结构成分包括聚丙烯酰胺、密胺树脂等。所述二氧化硅气凝胶微粒乳液的有效成分是二氧化硅气凝胶颗粒,具有多孔结构,可以吸附乳液中的异味,粒径1-5微米,乳液固含量10-20%。Among them, the above preparation raw materials can be an emulsion formed by uniformly dispersed microcapsules in water; the active ingredient of the mosquito repellent microcapsule emulsion is mosquito repellent ester, such as commercially available Immonin. The structural components of the microcapsule wall material include silica, melamine resin, etc., the solid content of the emulsion is 35-45% (the solid content is the mass ratio of the microcapsule to water), and the particle size is 2-20 microns. The active ingredients of the mosquito repellent plant essential oil microcapsule emulsion are natural plant essential oil microcapsules with mosquito repellent effect, such as eucalyptus essential oil, neem essential oil, and aloe vera essential oil. The emulsion has a solid content of 35-45% and a particle size of 1.8-2.3 microns; The structural components of the microcapsule wall material include polyacrylamide, melamine resin, etc. The active ingredient of the silica airgel particle emulsion is silica airgel particles, which have a porous structure and can absorb odors in the emulsion. The particle size is 1-5 microns, and the solid content of the emulsion is 10-20%.

并且,所述的2-10份水性成膜剂优选5-10质量份,其有效成分为水性丙烯酸树脂,如阴离子丙烯酸树脂乳液。所述增稠剂优选为乙基羟乙基纤维素成分,如中联邦增稠剂C-294,其质量份为0.5-2份;所述混合配制的乳液中还包含0-15份水。Moreover, the 2-10 parts of the aqueous film-forming agent is preferably 5-10 parts by mass, and its active ingredient is a water-based acrylic resin, such as anionic acrylic resin emulsion. The thickener is preferably an ethyl hydroxyethyl cellulose component, such as Zhongfeng Thickener C-294, and its mass part is 0.5-2 parts; the mixed and prepared emulsion also contains 0-15 parts of water.

作为优选,所述含有驱蚊剂的乳液质量固含量为20%~40%,室温粘度为80-120dPa.s,优选为90-100dPa.s。Preferably, the mass solid content of the mosquito repellent-containing emulsion is 20% to 40%, and the room temperature viscosity is 80-120dPa.s, preferably 90-100dPa.s.

得到含有驱蚊剂的浆料后,本发明实施例对所述的基材一个表面进行涂覆,可以为辊涂或刮涂,之后烘干,得到处理后的基材。After obtaining the slurry containing the mosquito repellent, in the embodiment of the present invention, one surface of the substrate is coated, which can be roller coating or blade coating, and then dried to obtain a treated substrate.

本申请一些实施例使用辊涂设备进行涂装(涂饰),所述辊涂采用的涂饰辊目数优选为80-120目,如100目(涂饰辊目数越大,则涂饰量大)。示例的,涂饰量优选为4-10g/m2。并且,所述烘干的温度优选为100-130℃,时间可为2-10min。优选地,所述涂覆方式可以为刮涂或辊涂,刮涂用于涂饰量大的面料,如10g/m2Some embodiments of the present application use roller coating equipment for coating (coating). The mesh number of the coating roller used in the roller coating is preferably 80-120 mesh, such as 100 mesh (the larger the mesh number of the coating roller, the larger the coating amount). For example, the coating amount is preferably 4-10g/m 2 . Moreover, the drying temperature is preferably 100-130°C, and the drying time can be 2-10 minutes. Preferably, the coating method can be blade coating or roller coating, and blade coating is used for fabrics with a large amount of coating, such as 10g/m 2 .

本发明实施例将烘干后的产物进行超声波粘合压花,使其经过乳液涂覆的表面粘合微孔膜和轻薄面料,得到驱蚊纺织品。In the embodiment of the present invention, the dried product is subjected to ultrasonic bonding and embossing, and the emulsion-coated surface is bonded to a microporous film and a light fabric to obtain a mosquito repellent textile.

超声波粘合压花工艺的工作原理是:利用高频率振荡(每秒两万周次)由焊头将声波传送至塑胶熔接面,瞬间使塑料分子产生摩擦,达到塑料熔点,迅速溶解,从而完成粘合。在超声波焊头的振动发热下,本发明实施例所述的微孔膜和轻薄面料熔化后贴合在面料上,形成保护层,将印有驱蚊剂的基布覆盖住。在本发明的实施例中,所述超声波粘合压花的图案为非实心的闭环图案,如圆形、三角形、梯形、星星等,图案之间有间隙;所述微孔膜覆盖面积占纺织品反面的100%,不同粘合图案为非连续的。The working principle of the ultrasonic bonding and embossing process is to use high-frequency oscillation (20,000 times per second) to transmit sound waves from the welding head to the plastic welding surface, which instantly causes friction between the plastic molecules, reaches the melting point of the plastic, and quickly dissolves to complete the process. bonding. Under the vibration and heating of the ultrasonic welding head, the microporous film and the light fabric described in the embodiment of the present invention are melted and attached to the fabric to form a protective layer to cover the base fabric printed with the mosquito repellent. In embodiments of the present invention, the pattern of the ultrasonic bonding embossing is a non-solid closed-loop pattern, such as circles, triangles, trapezoids, stars, etc., with gaps between the patterns; the microporous film coverage area accounts for 10% of the textile. 100% of the reverse side, the different bonding patterns are non-continuous.

在本发明的实施例中,所述微孔膜选用具有微孔结构的薄膜,可以防水、透湿气,微孔确保防蚊整理助剂可以挥发出来,又能防止水的渗入。作为优选,所述微孔膜的平均孔径为0.3-0.5nm,厚度为0.3-0.5μm。所述微孔膜可以是热塑性的聚氨酯(TPU)微孔膜、聚四氟乙烯微孔膜,也可以为聚酯微孔膜或聚醚微孔膜等热熔膜;其可以为素色或印花。具体地,所述微孔膜为微孔PU膜,其密度为1.1g/cm3,抗张强度≥30Mpa、撕裂强度≥80KN/m、伸长率≥800%、熔点为130-140℃。优选地,在防水透湿的微孔膜外侧可以同步超声波粘合轻薄面料,以增加对微孔膜的保护。优选地,轻薄面料可以为35-50gsm梭织布、涤纶或尼龙材质,如20D*20D、38gsm尼龙梭织布。In an embodiment of the present invention, the microporous film is a film with a microporous structure, which is waterproof and moisture-permeable. The micropores ensure that the anti-mosquito finishing aid can volatilize and prevent water from penetrating. Preferably, the microporous membrane has an average pore diameter of 0.3-0.5 nm and a thickness of 0.3-0.5 μm. The microporous film can be a thermoplastic polyurethane (TPU) microporous film, a polytetrafluoroethylene microporous film, or a hot melt film such as a polyester microporous film or a polyether microporous film; it can be plain or printing. Specifically, the microporous film is a microporous PU film with a density of 1.1g/cm 3 , a tensile strength of ≥30Mpa, a tear strength of ≥80KN/m, an elongation of ≥800%, and a melting point of 130-140°C. . Preferably, a thin fabric can be synchronously bonded with ultrasonic waves on the outside of the waterproof and moisture-permeable microporous membrane to increase the protection of the microporous membrane. Preferably, the light and thin fabric can be 35-50gsm woven fabric, polyester or nylon material, such as 20D*20D, 38gsm nylon woven fabric.

在本发明的实施例中,所述超声波粘合压花工艺在超声波粘合机上完成,例如在超声波绗缝机上对面料反面进行绗缝;所述超声波粘合压花的振动频率优选为20-30kHz,车速可为4-6m/min。作为优选,所述超声波焊接点(规则形状)的直径为1-3mm,间距为1-2mm。本发明实施例利用超声波粘合压花工艺,将具有微孔结构的微孔膜粘合在面料上;面料背面覆盖有微孔膜后,驱蚊剂等助剂挥发性受到限制,相应的可以延长驱蚊时间。In an embodiment of the present invention, the ultrasonic bonding and embossing process is completed on an ultrasonic bonding machine, for example, the reverse side of the fabric is quilted on an ultrasonic quilting machine; the vibration frequency of the ultrasonic bonding and embossing is preferably 20-20 30kHz, the vehicle speed can be 4-6m/min. Preferably, the diameter of the ultrasonic welding points (regular shape) is 1-3mm, and the spacing is 1-2mm. The embodiment of the present invention uses ultrasonic bonding and embossing technology to bond a microporous film with a microporous structure to the fabric; after the back of the fabric is covered with the microporous film, the volatility of auxiliary agents such as mosquito repellent is limited, and accordingly, the Extend mosquito repellent time.

本发明实施例提供了根据前文所述的生产方法得到的驱蚊纺织品,即采用至少包含一种化纤成分的基材(面料),经过涂覆防蚊整理剂(驱蚊剂等)、烘干、超声波粘合微孔薄膜后得到的纺织品,其驱蚊效果持久。Embodiments of the present invention provide mosquito repellent textiles obtained according to the production method described above, that is, using a base material (fabric) containing at least one chemical fiber component, coating with an anti-mosquito finishing agent (mosquito repellent, etc.), drying , the textile obtained after ultrasonic bonding of microporous films has a long-lasting mosquito repellent effect.

此外,所述的驱蚊纺织品表面可具有各种多彩的图案或不同颜色的纯色,气味舒适,提升了美感和舒适度,可用于帐篷、地垫、推车、床垫等产品,应用前景较好。In addition, the surface of the mosquito repellent textile can have a variety of colorful patterns or solid colors of different colors, with a comfortable smell, which improves the aesthetics and comfort. It can be used in products such as tents, floor mats, carts, mattresses, etc., and has promising application prospects. good.

为了更好理解本发明技术内容,下面提供具体实施例,对本发明做进一步的说明。在进一步描述本发明具体实施方式之前,应理解,本发明的保护范围不局限于下述特定的具体实施方案;还应当理解,本发明实施例中使用的术语是为了描述特定的具体实施方案,而不是为了限制本发明的保护范围。下列实施例中未注明具体条件的试验方法,通常按照常规条件,或者按照各制造商所建议的条件。In order to better understand the technical content of the present invention, specific examples are provided below to further illustrate the present invention. Before further describing the specific embodiments of the present invention, it should be understood that the protection scope of the present invention is not limited to the following specific specific embodiments; it should also be understood that the terms used in the embodiments of the present invention are for describing specific specific embodiments, It is not intended to limit the scope of the present invention. Test methods without specifying specific conditions in the following examples usually follow conventional conditions or conditions recommended by each manufacturer.

以下实施例中,含驱蚊剂的乳液制备如下:将二氧化硅气凝胶微粒乳液倒入装水的配料桶中,在900转/min下搅拌13min,再将驱蚊剂微胶囊、驱蚊植物微胶囊、加入到配料桶中,搅拌均匀后,边加入增稠剂边搅拌,直到稠度适中,得到混合浆料,再用乙酸调节混合液的pH;最后将混合浆料通过80-120目滤网过滤,待用。其固含量为20%~40%,室温粘度为80-120dPa.s。In the following examples, the emulsion containing mosquito repellent is prepared as follows: Pour the silica airgel particle emulsion into an ingredient bucket filled with water, stir for 13 minutes at 900 rpm, and then add the mosquito repellent microcapsules, repellent Mosquito plant microcapsules are added to the ingredient bucket. After stirring evenly, add the thickener while stirring until the consistency is moderate to obtain a mixed slurry. Then use acetic acid to adjust the pH of the mixed solution; finally, pass the mixed slurry through 80-120 Filter through mesh strainer and set aside. Its solid content is 20% to 40%, and its room temperature viscosity is 80-120dPa.s.

驱蚊酯选用谷桑化学的防虫整理剂HAB,乳液固含量35-45%,粒径2-20微米;驱蚊植物精油微胶囊选用芦荟精油微胶囊,含芦荟大黄素30%以上或桉树油微胶囊,含有24.7%桉叶油醇和26.3%葛绥醇,乳液固含量35-45%,粒径1.8-2.3微米。二氧化硅气凝胶微粒选用江苏安珈新材料的SiO2气凝胶乳液,粒径1-5微米,乳液固含量10-20%。水性成膜剂有效成分为羟甲基丙烯酰胺或丙烯酸环氧丙酯,如2,3-环氧丙基丙烯酸酯。增稠剂为乙基羟乙基纤维素成分,如中联邦增稠剂C-294。The insect repellent ester is selected from Gusang Chemical's insect repellent finishing agent HAB. The emulsion solid content is 35-45% and the particle size is 2-20 microns. The mosquito repellent plant essential oil microcapsules are aloe essential oil microcapsules, containing more than 30% of aloe-emodin or eucalyptus oil. Microcapsules contain 24.7% eucalyptol and 26.3% geranol, emulsion solid content 35-45%, particle size 1.8-2.3 microns. The silica airgel particles are selected from the SiO2 airgel emulsion of Jiangsu Anjia New Materials, with a particle size of 1-5 microns and a solid content of 10-20%. The active ingredients of the water-based film-forming agent are methylol acrylamide or glycidyl acrylate, such as 2,3-epoxypropyl acrylate. The thickener is ethyl hydroxyethyl cellulose, such as Zhongfeng Thickener C-294.

实施例1Example 1

选用涤棉面料前处理布,纱布规格为40S*40S 130*90 130gsm,成分为30%棉70%涤纶。Use polyester-cotton fabric pre-treatment cloth, the gauze specifications are 40S*40S 130*90 130gsm, and the composition is 30% cotton and 70% polyester.

在经过前处理后,辊涂含驱蚊剂的乳液。所述含有驱蚊剂的乳液(固含量为25%,室温粘度为110dPa.s)包括:100份市售驱蚊酯乳液、50份芦荟精油微胶囊、5份二氧化硅气凝胶微粒、10份水性成膜剂、0.5份增稠剂、2份水,pH为6,搅拌均匀后辊涂在面料上,涂饰量为5g/m2,在120℃下烘干。After pre-treatment, roll on a lotion containing mosquito repellent. The emulsion containing mosquito repellent (solid content is 25%, room temperature viscosity is 110dPa.s) includes: 100 parts of commercially available mosquito repellent emulsion, 50 parts of aloe essential oil microcapsules, 5 parts of silica aerogel particles, Mix 10 parts of water-based film-forming agent, 0.5 parts of thickening agent, and 2 parts of water with a pH of 6. Stir evenly and then apply it on the fabric with a roller. The coating amount is 5g/m 2 and dry at 120°C.

烘干后的产物进行超声波粘合压花,使其经过乳液涂覆的表面粘合上微孔膜,并在微孔膜外侧覆盖粘合38gsm的涤纶布,得到驱蚊纺织品。The dried product is subjected to ultrasonic bonding and embossing, so that the emulsion-coated surface is bonded with a microporous film, and the outside of the microporous film is covered with bonded 38gsm polyester cloth to obtain a mosquito repellent textile.

其中,选用圆形彩色TPU膜,膜孔径为0.4nm,厚度为0.4微米,密度为1.1g/cm3,抗张强度30Mpa、撕裂强度80KN/m、伸长率800%、熔点为130℃。在超声波绗缝机上对面料反面进行绗缝,绗缝图案直径为5CM,绗缝点直径为2mm,间距为2cm。反面TPU覆盖率为100%。超声波的振动频率为20kHz,车速为4m/min。Among them, a circular colored TPU film is selected, with a pore size of 0.4nm, a thickness of 0.4 microns, a density of 1.1g/cm 3 , a tensile strength of 30Mpa, a tear strength of 80KN/m, an elongation of 800%, and a melting point of 130°C. . Quilt the reverse side of the fabric on an ultrasonic quilting machine. The diameter of the quilting pattern is 5CM, the diameter of the quilting points is 2mm, and the spacing is 2cm. 100% TPU coverage on reverse side. The vibration frequency of ultrasonic waves is 20kHz, and the vehicle speed is 4m/min.

实施例2Example 2

选用涤粘胶梭织面料前处理布,面料规格为50gsm,成分为80%涤20%粘胶。Use polyester and viscose woven fabric pre-treatment cloth. The fabric specification is 50gsm and the composition is 80% polyester and 20% viscose.

在经过前处理后,喷涂含驱蚊剂的乳液。所述含有驱蚊剂的乳液(固含量为30%,室温粘度为90dPa.s)包括:100份驱蚊酯乳液、20份尼姆精油微胶囊、1份二氧化硅气凝胶微粒、2份水性成膜剂、0.5份增稠剂、2份水,pH为6,搅拌均匀后涂覆面料,涂饰量为10g/m2,在130℃下烘干。After pre-treatment, spray a lotion containing mosquito repellent. The emulsion containing mosquito repellent (solid content is 30%, room temperature viscosity is 90dPa.s) includes: 100 parts of mosquito repellent emulsion, 20 parts of neem essential oil microcapsules, 1 part of silica airgel particles, 2 Mix 10 parts of water-based film-forming agent, 0.5 parts of thickening agent, and 2 parts of water. The pH is 6. Stir evenly and then coat the fabric. The coating amount is 10g/m 2 and dry at 130°C.

烘干后的产物进行超声波粘合压花,使其经过乳液涂覆的表面粘合微孔膜和40gsm尼龙布,得到驱蚊纺织品。The dried product is subjected to ultrasonic bonding and embossing, and is passed through an emulsion-coated surface-bonded microporous film and 40gsm nylon cloth to obtain a mosquito repellent textile.

其中,选用聚四氟乙烯微孔膜,膜孔径为0.5nm,厚度为0.5微米,密度为1.2g/cm3,抗张强度40Mpa、撕裂强度80KN/m、伸长率900%、熔点为130℃。在超声波绗缝机上对面料反面进行绗缝,绗缝图案直径为3CM,绗缝点直径为2mm,间距为1.5cm。超声波的振动频率为30kHz,车速为4m/min。Among them, polytetrafluoroethylene microporous membrane is selected, with a pore size of 0.5nm, a thickness of 0.5 microns, a density of 1.2g/cm 3 , a tensile strength of 40Mpa, a tear strength of 80KN/m, an elongation of 900%, and a melting point of 130℃. Quilt the reverse side of the fabric on an ultrasonic quilting machine. The diameter of the quilting pattern is 3CM, the diameter of the quilting points is 2mm, and the spacing is 1.5cm. The vibration frequency of ultrasonic waves is 30kHz, and the vehicle speed is 4m/min.

对比例1Comparative example 1

选用涤粘胶梭织面料前处理布,面料规格为50gsm,成分为80%涤20%粘胶。Use polyester and viscose woven fabric pre-treatment cloth. The fabric specification is 50gsm and the composition is 80% polyester and 20% viscose.

在经过前处理后,喷涂含驱蚊剂的乳液。所述含有驱蚊剂的乳液(固含量为30%,室温粘度为90dPa.s)包括:100份驱蚊酯乳液、2份水性成膜剂、0.5份增稠剂、2份水,pH为6,搅拌均匀后涂覆面料,涂饰量为10g/m2,在130℃下烘干。After pre-treatment, spray a lotion containing mosquito repellent. The emulsion containing mosquito repellent (solid content is 30%, room temperature viscosity is 90dPa.s) includes: 100 parts of mosquito repellent emulsion, 2 parts of water-based film-forming agent, 0.5 parts of thickener, 2 parts of water, and the pH is 6. Stir evenly and then coat the fabric with a coating amount of 10g/m 2 and dry at 130°C.

烘干后的产物进行超声波粘合压花,使其经过乳液涂覆的表面粘合微孔膜、40gsm尼龙布,得到驱蚊纺织品。The dried product is subjected to ultrasonic bonding and embossing, and is passed through an emulsion-coated surface bonding microporous film and 40gsm nylon cloth to obtain a mosquito repellent textile.

其中,选用聚四氟乙烯微孔膜,膜孔径为0.5nm,厚度为0.5微米,密度为1.2g/cm3,抗张强度40Mpa、撕裂强度80KN/m、伸长率900%、熔点为130℃。在超声波绗缝机上对面料反面进行绗缝,绗缝图案直径为3CM,绗缝点直径为2mm,间距为1.5cm。超声波的振动频率为30kHz,车速为4m/min。Among them, polytetrafluoroethylene microporous membrane is selected, with a pore size of 0.5nm, a thickness of 0.5 microns, a density of 1.2g/cm 3 , a tensile strength of 40Mpa, a tear strength of 80KN/m, an elongation of 900%, and a melting point of 130℃. Quilt the reverse side of the fabric on an ultrasonic quilting machine. The diameter of the quilting pattern is 3CM, the diameter of the quilting points is 2mm, and the spacing is 1.5cm. The vibration frequency of ultrasonic waves is 30kHz, and the vehicle speed is 4m/min.

对比例2Comparative example 2

选用涤粘胶梭织面料前处理布,面料规格为50gsm,成分为80%涤20%粘胶。Use polyester and viscose woven fabric pre-treatment cloth. The fabric specification is 50gsm and the composition is 80% polyester and 20% viscose.

在经过前处理后,喷涂含驱蚊剂的乳液。所述含有驱蚊剂的乳液包括:100份驱蚊酯乳液、20份尼姆精油微胶囊、1份二氧化硅气凝胶微粒、2份水性成膜剂、0.5份增稠剂、2份水,pH为6,搅拌均匀后涂覆面料,涂饰量为10g/m2,在130℃下烘干。After pre-treatment, spray a lotion containing mosquito repellent. The emulsion containing mosquito repellent includes: 100 parts of mosquito repellent emulsion, 20 parts of neem essential oil microcapsules, 1 part of silica airgel particles, 2 parts of water-based film-forming agent, 0.5 parts of thickener, 2 parts Water, pH is 6, stir evenly and then coat the fabric with a coating amount of 10g/m 2 and dry at 130°C.

对比例3Comparative example 3

选用涤粘胶梭织面料前处理布,面料规格为50gsm,成分为80%涤20%粘胶。Use polyester and viscose woven fabric pre-treatment cloth. The fabric specification is 50gsm and the composition is 80% polyester and 20% viscose.

在经过前处理后,喷涂含驱蚊剂的乳液。所述含有驱蚊剂的乳液(固含量为30%,室温粘度为90dPa.s)包括:20份尼姆精油微胶囊、1份二氧化硅气凝胶微粒、2份水性成膜剂、0.5份增稠剂、2份水,pH为6,搅拌均匀后涂覆面料,涂饰量为10g/m2,在130℃下烘干。After pre-treatment, spray a lotion containing mosquito repellent. The emulsion containing mosquito repellent (solid content is 30%, room temperature viscosity is 90dPa.s) includes: 20 parts of neem essential oil microcapsules, 1 part of silica airgel particles, 2 parts of aqueous film-forming agent, 0.5 2 parts of thickener, 2 parts of water, pH is 6, stir evenly and then coat the fabric with a coating amount of 10g/m 2 and dry at 130°C.

烘干后的产物进行超声波粘合压花,使其经过乳液涂覆的表面粘合微孔膜和40gsm尼龙布,得到驱蚊纺织品。The dried product is subjected to ultrasonic bonding and embossing, and is passed through an emulsion-coated surface-bonded microporous film and 40gsm nylon cloth to obtain a mosquito repellent textile.

其中,选用聚四氟乙烯微孔膜,膜孔径为0.5nm,厚度为0.5微米,密度为1.2g/cm3,抗张强度40Mpa、撕裂强度80KN/m、伸长率900%、熔点为130℃。在超声波绗缝机上对面料反面进行绗缝,绗缝图案直径为3CM,绗缝点直径为2mm,间距为1.5cm。超声波的振动频率为30kHz,车速为4m/min。Among them, polytetrafluoroethylene microporous membrane is selected, with a pore size of 0.5nm, a thickness of 0.5 microns, a density of 1.2g/cm 3 , a tensile strength of 40Mpa, a tear strength of 80KN/m, an elongation of 900%, and a melting point of 130℃. Quilt the reverse side of the fabric on an ultrasonic quilting machine. The diameter of the quilting pattern is 3CM, the diameter of the quilting points is 2mm, and the spacing is 1.5cm. The vibration frequency of ultrasonic wave is 30kHz, and the vehicle speed is 4m/min.

按照《GB/T 30126-2013纺织品防蚊性能的检测和评价》测试纺织品的驱蚊性能。30%-50%为C级,具有驱避效果;50%-70%为B级,具有良好的驱避效果;>70%为A级,具有极强的驱避效果。The mosquito repellent performance of textiles was tested in accordance with "GB/T 30126-2013 Testing and Evaluation of Mosquito Repellent Performance of Textiles". 30%-50% is Class C, which has a repellent effect; 50%-70% is Class B, which has a good repellent effect; >70% is Class A, which has a strong repellent effect.

按照《GB 18401-2010国家纺织产品基本安全技术规范》测试纺织品的异味。Test the odor of textiles in accordance with "GB 18401-2010 National Basic Safety Technical Specifications for Textile Products".

按照ISO 0811:2018此时5次水洗后的静水压,单位mmH2O,数值越大,防水越好,大于3000mmH2O为有防水效果。According to ISO 0811:2018, the hydrostatic pressure after 5 times of washing is measured in mmH2O. The larger the value, the better the waterproofing. If it is greater than 3000mmH2O, it has a waterproof effect.

按照JIS L1099:B-1:2012测试面料透湿性能,数值越大,透湿性越好。The moisture permeability of the fabric is tested according to JIS L1099: B-1:2012. The larger the value, the better the moisture permeability.

结果如下:The result is as follows:

表1实施例的纺织品样品性能结果Table 1 Textile sample performance results of Examples

其中,实施例2样品试验组蚊停落数为3只,对照组(未处理的同款面料)蚊停落数为106只,故样品驱避率为97.17%(洗前)。该样品按标准方法机洗10次后,试验组蚊停落数为57只,对照组(未处理的同款面料)蚊停落数为102只,故样品机洗10次后的驱避率为44.12%。Among them, the number of mosquitoes falling in the test group of the sample of Example 2 was 3, and the number of mosquitoes falling in the control group (untreated fabric of the same style) was 106, so the repellent rate of the sample was 97.17% (before washing). After the sample was machine washed 10 times according to the standard method, the number of mosquitoes in the test group was 57, and the number of mosquitoes in the control group (untreated same fabric) was 102, so the repellent rate of the sample after machine washing 10 times is 44.12%.

依据标准评价,实施例中纺织品具有较为持久的驱蚊效果。并且,实施例中驱蚊纺织品没有异味,舒适度体验良好。According to standard evaluation, the textiles in the examples have a relatively long-lasting mosquito repellent effect. Moreover, the mosquito repellent textiles in the embodiments have no peculiar smell and provide good comfort experience.

需要说明的是,在本文中,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。It should be noted that, as used herein, the terms "include", "comprises" or any other variation thereof are intended to cover a non-exclusive inclusion, such that a process, method, article or device that includes a series of elements not only includes those elements, It also includes other elements not expressly listed or inherent in the process, method, article or equipment.

当实施例给出数值范围时,应理解,除非本发明另有说明,每个数值范围的两个端点以及两个端点之间任何一个数值均可选用。除非另外定义,本发明中使用的所有技术和科学术语与本技术领域技术人员通常理解的意义相同。除实施例中使用的具体方法、设备、材料外,根据本技术领域的技术人员对现有技术的掌握及本发明的记载,还可以使用与本发明实施例中所述的方法、设备、材料相似或等同的现有技术的任何方法、设备和材料来实现本发明。When the examples give numerical ranges, it should be understood that, unless otherwise stated in the present invention, both endpoints of each numerical range and any value between the two endpoints can be selected. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art. In addition to the specific methods, equipment, and materials used in the embodiments, those skilled in the art can also use methods, equipment, and materials described in the embodiments of the present invention based on their understanding of the prior art and the description of the present invention. Any methods, equipment and materials similar or equivalent to those in the prior art may be used to implement the present invention.

本文中应用了具体个例对本发明的原理及实施方式进行了阐述,以上实例的说明只是用于帮助理解本发明的方法及其核心思想。以上所述仅是本发明的优选实施方式,应当指出,由于文字表达的有限性,而客观上存在无限的具体结构,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进、润饰或变化,也可以将上述技术特征以适当的方式进行组合;这些改进润饰、变化或组合,或未经改进将发明的构思和技术方案直接应用于其它场合的,均应视为本发明的保护范围。This article uses specific examples to illustrate the principles and implementation methods of the present invention. The description of the above examples is only used to help understand the method and the core idea of the present invention. The above are only preferred embodiments of the present invention. It should be pointed out that due to the limitations of written expressions, there are objectively unlimited specific structures. For those of ordinary skill in the art, without departing from the principles of the present invention, Below, several improvements, modifications or changes can also be made, or the above technical features can be combined in an appropriate manner; these improvements, modifications or combinations, or the concepts and technical solutions of the invention can be directly applied to other situations without improvement. , should be regarded as the protection scope of the present invention.

Claims (10)

1. The production method of the mosquito-repellent textile is characterized by comprising the following steps of:
(1) Coating one surface of a base material with an emulsion containing a mosquito repellent by taking a chemical fiber-containing fabric as the base material, and drying; the mosquito repellent-containing emulsion comprises the following components in parts by weight:
100 parts of mosquito repellent microcapsule; 20-50 parts of mosquito-repellent plant essential oil microcapsule; 1-5 parts of silica aerogel; 2-10 parts of an aqueous film forming agent; 0.5-2 parts of thickener; 0-15 parts of water;
(2) And (3) carrying out ultrasonic bonding embossing on the dried product in the step (1) to bond a microporous membrane on the surface of the product coated by the emulsion, thereby obtaining the mosquito-repellent textile.
2. The method for producing mosquito-repellent textile according to claim 1, wherein the chemical fiber material in the base material is one or more of polyester, nylon, polyethylene, polylactic acid and polypropylene; the substrate also contains cellulosic fibers.
3. The method for producing mosquito repellent textile according to claim 1, wherein the coating is performed by roll coating, the number of coating rolls used is 80-120 mesh, and the coating amount is 4-10g/m 2
4. The method for producing a mosquito repellent textile according to claim 1, wherein the mosquito repellent microcapsule comprises an active ingredient of mosquito repellent ester; the mosquito-repellent plant essential oil microcapsule contains one or more of aloe essential oil, eucalyptus essential oil and nim tree essential oil.
5. The method for producing mosquito repellent textile according to claim 1, wherein the emulsion containing the mosquito repellent has a solid content of 20% to 40% and a room temperature viscosity of 80 to 120dpa.s.
6. The method for producing mosquito repellent textile according to claim 1, wherein the temperature of the drying is 100-130 ℃ for 2-10min.
7. The method of claim 1, wherein the pattern of ultrasonic bonding embossments is a non-solid closed loop pattern with gaps between the patterns.
8. The method for producing a mosquito repellent textile according to claim 1, wherein the ultrasonic bonding embossment has a vibration frequency of 20-30kHz and a vehicle speed of 4-6m/min.
9. The method for producing a mosquito repellent textile according to claim 1, wherein the microporous membrane has an average pore size of 0.3 to 0.5nm and a thickness of 0.3 to 0.5 μm; the microporous membrane is a polyurethane microporous membrane, a polytetrafluoroethylene microporous membrane, a polyester microporous membrane or a polyether microporous membrane.
10. Mosquito repellent textile obtainable by the production process according to any one of claims 1 to 9.
CN202310830644.2A 2023-07-07 2023-07-07 Mosquito-repellent textile and production method thereof Pending CN116872593A (en)

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