CN116730689A - Basalt fiber reinforced coral sand concrete and preparation method thereof - Google Patents
Basalt fiber reinforced coral sand concrete and preparation method thereof Download PDFInfo
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- 239000004567 concrete Substances 0.000 title claims abstract description 136
- 239000004576 sand Substances 0.000 title claims abstract description 119
- 235000014653 Carica parviflora Nutrition 0.000 title claims abstract description 111
- 241000243321 Cnidaria Species 0.000 title claims abstract description 109
- 229920002748 Basalt fiber Polymers 0.000 title claims abstract description 93
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000013535 sea water Substances 0.000 claims abstract description 53
- 238000003756 stirring Methods 0.000 claims abstract description 49
- 239000000463 material Substances 0.000 claims abstract description 40
- 239000010881 fly ash Substances 0.000 claims abstract description 28
- 239000004568 cement Substances 0.000 claims abstract description 27
- 239000000843 powder Substances 0.000 claims abstract description 26
- 239000002893 slag Substances 0.000 claims abstract description 26
- 229920005646 polycarboxylate Polymers 0.000 claims abstract description 25
- 239000002002 slurry Substances 0.000 claims abstract description 21
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 12
- 239000011398 Portland cement Substances 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 3
- 238000010257 thawing Methods 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 101
- 238000012360 testing method Methods 0.000 description 17
- 229920000049 Carbon (fiber) Polymers 0.000 description 11
- 239000004917 carbon fiber Substances 0.000 description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 11
- 239000011159 matrix material Substances 0.000 description 10
- 238000001878 scanning electron micrograph Methods 0.000 description 8
- 230000006835 compression Effects 0.000 description 7
- 238000007906 compression Methods 0.000 description 7
- 238000010276 construction Methods 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- 230000003068 static effect Effects 0.000 description 7
- 239000008030 superplasticizer Substances 0.000 description 7
- 238000012669 compression test Methods 0.000 description 6
- 239000004566 building material Substances 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 230000003628 erosive effect Effects 0.000 description 4
- 238000006703 hydration reaction Methods 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- 230000036571 hydration Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 244000132059 Carica parviflora Species 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011374 ultra-high-performance concrete Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011210 fiber-reinforced concrete Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000009440 infrastructure construction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000010220 ion permeability Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/24—Sea water resistance
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
技术领域Technical field
本发明涉及一种混凝土技术领域,具体涉及一种玄武岩纤维增强珊瑚砂混凝土及其制备方法。The invention relates to the technical field of concrete, and in particular to a basalt fiber reinforced coral sand concrete and a preparation method thereof.
背景技术Background technique
自我国提出相关海洋战略以来,岛礁工程建设如火如荼,在基础设施建设、海洋岛礁工程等领域得到了迅速的发展,所需的建筑材料也不断的逐年增加。然而,运输大量的原材料需要花费巨大的成本,南海岛礁对我国的政治、经济和文化有着重要影响,为进一步发展海洋经济,南海岛礁建设需要稳步推进。南海岛礁区域的构筑物会受到海水的侵蚀,海浪的冲击以及海风的剥蚀,因此在南海岛礁工程建设中所使用的建筑材料(如混凝土),需要具备比普通建筑材料更强的力学性能(特别是抗冲击性能)、抗渗透能力与耐腐蚀能力,也需考虑建筑材料动态力学性能。在南海岛礁工程建设中,使用海水制备珊瑚砂水泥基复合材料,能较大程度降低工程成本,减少对建筑材料的依赖,具有重要的工程实用价值,但是,由于珊瑚砂脆性大,对混凝土强度会造成消极影响。Since my country proposed relevant marine strategies, the construction of island and reef projects has been in full swing. Rapid development has been achieved in the fields of infrastructure construction, marine island and reef projects, etc., and the required building materials have also continued to increase year by year. However, transporting a large amount of raw materials requires huge costs. The South China Sea islands and reefs have an important impact on my country's politics, economy and culture. In order to further develop the marine economy, the construction of the South China Sea islands and reefs needs to be steadily advanced. Structures in the South China Sea islands and reefs will be eroded by seawater, impacted by waves and denuded by sea winds. Therefore, the building materials (such as concrete) used in the construction of South China Sea islands and reefs need to have stronger mechanical properties than ordinary building materials ( Especially impact resistance), penetration resistance and corrosion resistance, the dynamic mechanical properties of building materials also need to be considered. In the construction of islands and reefs in the South China Sea, using seawater to prepare coral sand cement-based composite materials can greatly reduce project costs and reduce dependence on building materials. It has important engineering practical value. However, due to the high brittleness of coral sand, it has great impact on concrete. Intensity can have a negative impact.
为充分利用海水海砂资源,大量学者对海水海砂混凝土进行了研究,其粗骨料为普通碎石,研究表明海水、海砂中含有较多氯盐,会影响水泥的水化过程,对混凝土的强度、工作性能和耐久性等都有影响,海水海砂混凝土的力学性能与普通混凝土的力学性能不同。Alhozaimy等制备聚丙烯纤维增强混凝土,并研究其弯曲韧性与抗冲击力学性能。试验结果表明,掺加聚丙烯纤维,对混凝土抗压强度与抗折强度影响较小。Soroushian等对不同碳纤维含量与不同骨料含量制备的碳纤维增强水泥基复合材料进行冻融耐久性试验,试验结果发现随着碳纤维掺量与骨料含量的不断增加,复合材料冻融耐久性表现出先增加后降低的规律,当碳纤维掺量与骨料含量增加到一定程度后,对复合材料耐久性会产生负面效应。此外朱德举等通过试验分析了未掺加粗骨料的海水海砂超高性能混凝土的力学性能影响因素,发现钢纤维对海水海砂超高性能混凝土的力学性能的提升效果较显著,但其只提高了抗压强度影响,其抗冲击韧性、耐腐蚀性、延性、耐久性效果还有待探讨。In order to make full use of seawater and sand resources, a large number of scholars have conducted research on seawater and sea-sand concrete. The coarse aggregate is ordinary gravel. Studies have shown that seawater and sea sand contain more chlorine salts, which will affect the hydration process of cement. The strength, working performance and durability of concrete all have an impact. The mechanical properties of seawater and sea sand concrete are different from those of ordinary concrete. Alhozaimy et al. prepared polypropylene fiber reinforced concrete and studied its flexural toughness and impact resistance mechanical properties. The test results show that adding polypropylene fiber has little effect on the compressive strength and flexural strength of concrete. Soroushian et al. conducted freeze-thaw durability tests on carbon fiber reinforced cement-based composite materials prepared with different carbon fiber contents and different aggregate contents. The test results found that as the carbon fiber content and aggregate content continued to increase, the freeze-thaw durability of the composite materials showed an improvement. According to the law of increase and then decrease, when the carbon fiber content and aggregate content increase to a certain level, it will have a negative effect on the durability of the composite material. In addition, Zhu Deju et al. conducted experiments to analyze the influencing factors on the mechanical properties of seawater and sea sand ultra-high performance concrete without coarse aggregate, and found that steel fiber has a significant improvement effect on the mechanical properties of sea water and sea sand ultra-high performance concrete, but its It only improves the impact of compressive strength, and its impact toughness, corrosion resistance, ductility, and durability effects have yet to be explored.
发明内容Contents of the invention
本发明要解决的技术问题是克服现有技术的不足,提供一种可提高混凝土的抗冲击韧性、抗冻融侵蚀能力、耐腐蚀性、有效延长混凝土使用寿命、提高混凝土在海洋环境下的耐久性的玄武岩纤维增强珊瑚砂混凝土及其制备方法。The technical problem to be solved by the present invention is to overcome the shortcomings of the existing technology and provide a method that can improve the impact toughness, freeze-thaw erosion resistance, and corrosion resistance of concrete, effectively extend the service life of concrete, and improve the durability of concrete in the marine environment. Properties of basalt fiber reinforced coral sand concrete and preparation method thereof.
为解决上述技术问题,本发明提出如下方案。In order to solve the above technical problems, the present invention proposes the following solutions.
一种玄武岩纤维增强珊瑚砂混凝土,由以下原料制备而成:按质量份计,水泥220份~260份,粉煤灰182份~202份,矿渣粉38份~58份,珊瑚砂518份~538份,海水114.8份~134.8份,聚羧酸减水剂0.40份~1.2份,玄武岩纤维2.11份~8.44份。A kind of basalt fiber reinforced coral sand concrete is prepared from the following raw materials: in terms of mass parts, 220 to 260 parts of cement, 182 to 202 parts of fly ash, 38 to 58 parts of slag powder, and 518 to 518 parts of coral sand. 538 parts, seawater 114.8 to 134.8 parts, polycarboxylate water reducing agent 0.40 to 1.2 parts, basalt fiber 2.11 to 8.44 parts.
上述的玄武岩纤维增强珊瑚砂混凝土,优选的,所述珊瑚砂的颗粒粒径为0.15mm~2.36mm,所述珊瑚砂的细度模数1.88~2.03。For the above-mentioned basalt fiber reinforced coral sand concrete, preferably, the particle size of the coral sand is 0.15 mm to 2.36 mm, and the fineness modulus of the coral sand is 1.88 to 2.03.
上述的玄武岩纤维增强珊瑚砂混凝土,优选的,所述玄武岩纤维的弹性模量为91GPa~110GPa,公称长度为10mm,密度为2.63g/cm3~2.65g/cm3,单丝直径7μm~15μm,断裂强度>2000MPa。For the above-mentioned basalt fiber reinforced coral sand concrete, preferably, the elastic modulus of the basalt fiber is 91GPa~110GPa, the nominal length is 10mm, the density is 2.63g/ cm3 ~2.65g/ cm3 , and the single filament diameter is 7μm~15μm , breaking strength>2000MPa.
上述的玄武岩纤维增强珊瑚砂混凝土,优选的,所述聚羧酸减水剂的固含量为50%,减水率为28%,所述聚羧酸减水剂的质量为水泥、粉煤灰和矿渣粉总质量的0.2%。For the above-mentioned basalt fiber reinforced coral sand concrete, preferably, the solid content of the polycarboxylate water-reducing agent is 50%, the water-reducing rate is 28%, and the quality of the polycarboxylate water-reducing agent is cement, fly ash and 0.2% of the total mass of slag powder.
上述的玄武岩纤维增强珊瑚砂混凝土,优选的,所述水泥为硅酸盐水泥,所述粉煤灰为比表面积1300m2/kg、烧失量2.8%、密度2.55g/cm3、SiO2含量45.1%、含水量0.85%、细度16%的粉煤灰,所述矿渣粉为比表面积628m2/kg、密度2.93g/cm3、烧失量0.96%、含水量0.4%的矿渣粉。For the above-mentioned basalt fiber reinforced coral sand concrete, preferably, the cement is Portland cement, the fly ash has a specific surface area of 1300m 2 /kg, a loss on ignition of 2.8%, a density of 2.55g/cm 3 and a SiO 2 content 45.1% fly ash, moisture content 0.85%, fineness 16%. The slag powder has a specific surface area of 628m 2 /kg, a density of 2.93g/cm 3 , a loss on ignition of 0.96%, and a moisture content of 0.4%.
上述的玄武岩纤维增强珊瑚砂混凝土,优选的,所述海水为人工海水,所述人工海水包括NaCl、MgCl2·6H2O、Na2SO4、CaCl2、KCl、NaHCO3、KBr和水。For the above-mentioned basalt fiber reinforced coral sand concrete, preferably, the seawater is artificial seawater, and the artificial seawater includes NaCl, MgCl 2 ·6H 2 O, Na 2 SO 4 , CaCl 2 , KCl, NaHCO 3 , KBr and water.
作为一个总的发明构思,本发明还提供一种上述的玄武岩纤维增强珊瑚砂混凝土的制备方法,包括以下步骤:As a general inventive concept, the present invention also provides a method for preparing the above-mentioned basalt fiber reinforced coral sand concrete, which includes the following steps:
(1)将水泥、粉煤灰和矿渣粉混合并搅拌,得到胶凝材料;(1) Mix and stir cement, fly ash and slag powder to obtain cementitious material;
(2)先将胶凝材料与2/3海水进行混合并搅拌,然后添加聚羧酸减水剂与1/3海水继续搅拌,得到胶凝状浆体;(2) First mix the gelling material with 2/3 seawater and stir, then add polycarboxylate water-reducing agent and 1/3 seawater and continue stirring to obtain a gelled slurry;
(3)将玄武岩纤维与珊瑚砂混合并搅拌均匀,使玄武岩纤维在珊瑚砂中均匀分散,得到混合物,然后将混合物充分融入步骤(2)所得胶凝状浆体中搅拌,得到混凝土材料;(3) Mix the basalt fiber and coral sand and stir evenly so that the basalt fiber is evenly dispersed in the coral sand to obtain a mixture, and then fully integrate the mixture into the gelled slurry obtained in step (2) and stir to obtain a concrete material;
(4)将所得混凝土材料浇筑入模,进行养护,得到玄武岩纤维增强珊瑚砂混凝土。(4) Pour the obtained concrete material into the mold and perform curing to obtain basalt fiber reinforced coral sand concrete.
上述的玄武岩纤维增强珊瑚砂混凝土的制备方法,优选的,步骤(1)中,所述搅拌的时间为1min~3min;步骤(2)中,所述搅拌的时间为2min~3min,所述继续搅拌的时间为2min~3min;步骤(3)中,所述搅拌的时间为3min~4min。For the above preparation method of basalt fiber reinforced coral sand concrete, preferably, in step (1), the stirring time is 1 min to 3 min; in step (2), the stirring time is 2 min to 3 min, and the continuing The stirring time is 2 to 3 minutes; in step (3), the stirring time is 3 to 4 minutes.
上述的玄武岩纤维增强珊瑚砂混凝土的制备方法,优选的,步骤(3)中,所述珊瑚砂在混合前先进行预润湿。In the above preparation method of basalt fiber reinforced coral sand concrete, preferably, in step (3), the coral sand is pre-wetted before mixing.
作为一个总的发明构思,本发明还提供一种上述的玄武岩纤维增强珊瑚砂混凝土或者上述的制备方法制得的玄武岩纤维增强珊瑚砂混凝土在海洋工程领域(优选南海海洋工程领域)的应用。As a general inventive concept, the present invention also provides an application of the above-mentioned basalt fiber-reinforced coral sand concrete or the basalt fiber-reinforced coral sand concrete prepared by the above-mentioned preparation method in the field of marine engineering (preferably the field of South China Sea marine engineering).
本发明中,水胶比为海水与胶凝材料的质量比。In the present invention, the water-cement ratio is the mass ratio of seawater to cementitious materials.
与现有技术相比,本发明的优点在于:Compared with the prior art, the advantages of the present invention are:
1、本发明的玄武岩纤维增强珊瑚砂混凝土将玄武岩纤维、珊瑚砂、聚羧酸减水剂等原料及其配比进行协同,有效提高了混凝土的抗冲击韧性、抗冻融侵蚀能力、耐腐蚀性,还可延长混凝土的使用寿命,并且能够提高混凝土在海洋环境下的耐久性,拓展其在海洋领域的应用范围。本发明以海水中的珊瑚砂作为原材料,在海洋工程的建设过程中可就地取材,不仅降低了原材料的成本,也减少了从内陆运输淡水和砂的成本,但是,使用珊瑚砂作为细骨料会导致试块内微裂纹与微空洞等缺陷较多,使抗拉强度、抗冲击强度低、性质脆,对于混凝土而言,其破坏、脆弱区域往往为水泥浆体与骨料之间的界面过渡区,申请人发现,掺入玄武岩纤维可以改善界面过渡区微结构的强度,减少混凝土内部的缺陷,还可提高混凝土的密实度和整体性,显著提升混凝土的抗冲击韧性,解决了由于珊瑚砂脆性大对混凝土强度造成的不良影响,使所得混凝土具有良好工作性的同时能够保证建筑结构的安全性和可靠性。不同玄武岩纤维掺量对混凝土动态冲击特性有明显影响,合适的玄武岩纤维掺入量可有效减小混凝土的损伤劣化。珊瑚砂、玄武岩纤维的协同还能够显著提高腐蚀条件下混凝土的抗冻融侵蚀能力,有效延长其使用寿命。1. The basalt fiber reinforced coral sand concrete of the present invention combines basalt fiber, coral sand, polycarboxylate superplasticizer and other raw materials and their proportions to effectively improve the impact toughness, freeze-thaw erosion resistance, and corrosion resistance of the concrete. It can also extend the service life of concrete, improve the durability of concrete in the marine environment, and expand its application scope in the marine field. The present invention uses coral sand in seawater as raw material, which can be obtained locally during the construction process of marine projects. It not only reduces the cost of raw materials, but also reduces the cost of transporting fresh water and sand from the inland. However, using coral sand as fine material Aggregate will cause many defects such as micro-cracks and micro-voids in the test block, making the tensile strength and impact strength low and brittle. For concrete, the damaged and fragile areas are often between the cement slurry and the aggregate. In the interface transition zone, the applicant found that incorporating basalt fiber can improve the strength of the microstructure of the interface transition zone, reduce defects within the concrete, improve the compactness and integrity of the concrete, and significantly improve the impact resistance toughness of the concrete, solving the problem Due to the adverse effects of the brittleness of coral sand on the strength of concrete, the resulting concrete has good workability while ensuring the safety and reliability of the building structure. Different basalt fiber content has a significant impact on the dynamic impact characteristics of concrete. Appropriate basalt fiber content can effectively reduce the damage and deterioration of concrete. The synergy of coral sand and basalt fiber can also significantly improve the freeze-thaw erosion resistance of concrete under corrosive conditions and effectively extend its service life.
2、本发明的玄武岩纤维增强珊瑚砂混凝土中采用聚羧酸减水剂,可以保证在极低的水胶比的情况下(普通混凝土水胶比通常在0.35-0.6之间,本发明的水胶比在0.22-0.3之间),使拌合物具有良好的工作性能,得到满足结构要求的力学性能、延性、耐久性优异的混凝土。2. The polycarboxylate water-reducing agent used in the basalt fiber reinforced coral sand concrete of the present invention can ensure a very low water-cement ratio (the water-cement ratio of ordinary concrete is usually between 0.35-0.6, and the water-cement ratio of the present invention is The glue ratio is between 0.22-0.3), so that the mixture has good working performance and obtains concrete with excellent mechanical properties, ductility and durability that meets the structural requirements.
3、本发明的玄武岩纤维增强珊瑚砂混凝土中还加入了矿渣粉、粉煤灰等胶凝材料,可以在一定程度上改善界面过渡区微结构的强度,增强混凝土的耐久性和长期强度,同时剔除了现有混凝土材料中常用的碎石等粗骨料,采用珊瑚砂作为细骨料,掺入玄武岩纤维后提高了混凝土的密实度和整体性,减少了混凝土内部的缺陷,因此多原料协同可显著提高混凝土的强度和耐久性,可使混凝土更适应海洋环境。3. The basalt fiber reinforced coral sand concrete of the present invention also adds slag powder, fly ash and other cementitious materials, which can improve the strength of the microstructure of the interface transition zone to a certain extent, enhance the durability and long-term strength of the concrete, and at the same time The coarse aggregates such as gravel commonly used in existing concrete materials are eliminated, and coral sand is used as fine aggregate. After adding basalt fiber, the density and integrity of the concrete are improved, and the internal defects of the concrete are reduced. Therefore, multiple raw materials are synergistic. It can significantly improve the strength and durability of concrete and make concrete more adaptable to the marine environment.
4、本发明的制备方法通过对原材料的筛选与配比控制、施工工艺的优化控制,合理掺加优质矿物掺合料或复合掺合料,使用珊瑚砂细骨料可就地取材、降低成本,但会导致试块内微裂纹与微空洞等缺陷较多,通过掺入玄武岩纤维改善界面过渡区微结构的强度,可显著提升混凝土的抗冲击韧性,解决了珊瑚砂水泥基材料抗拉强度低、性质脆的问题,采用聚羧酸减水剂可以保证在极低的水胶比的情况下,使拌合物具有良好的工作性能,得到满足结构所要求的力学性能、延性、耐久性优异的混凝土。本发明采用纤维后掺法,促进了纤维在混凝土中分散得更加均匀。4. The preparation method of the present invention rationally adds high-quality mineral admixtures or composite admixtures through the selection and proportion control of raw materials and the optimization control of construction processes. The use of coral sand fine aggregate can obtain local materials and reduce costs. , but it will lead to many defects such as micro-cracks and micro-voids in the test block. Improving the strength of the microstructure in the interface transition zone by incorporating basalt fiber can significantly improve the impact toughness of concrete and solve the problem of tensile strength of coral sand cement-based materials. To solve the problem of low water-binder ratio and brittle nature, the use of polycarboxylate water-reducing agent can ensure that the mixture has good working performance at an extremely low water-binder ratio and obtains the mechanical properties, ductility, and durability required by the structure. Excellent concrete. The present invention adopts the fiber post-mixing method to promote the fibers to be dispersed more evenly in the concrete.
5、本发明的玄武岩纤维增强珊瑚砂混凝土可应用于海洋工程领域,解决了普通混凝土在海洋环境下抗冲击韧性的难题,在海洋工程中具有较高的经济效益。5. The basalt fiber reinforced coral sand concrete of the present invention can be used in the field of marine engineering, solves the problem of impact resistance and toughness of ordinary concrete in marine environments, and has high economic benefits in marine engineering.
附图说明Description of drawings
图1为实施例2的玄武岩纤维增强珊瑚砂混凝土中珊瑚砂与混凝土基体连接的SEM图。Figure 1 is an SEM image of the connection between the coral sand and the concrete matrix in the basalt fiber reinforced coral sand concrete of Example 2.
图2为实施例2的玄武岩纤维增强珊瑚砂混凝土中玄武岩纤维端部与混凝土基体连接的SEM图。Figure 2 is an SEM image of the connection between the end of the basalt fiber and the concrete matrix in the basalt fiber reinforced coral sand concrete of Example 2.
图3为实施例2的玄武岩纤维增强珊瑚砂混凝土中玄武岩纤维的三维骨架桥接的SEM图。Figure 3 is an SEM image of the three-dimensional skeleton bridge of basalt fiber in the basalt fiber reinforced coral sand concrete of Example 2.
图4为实施例2的玄武岩纤维增强珊瑚砂混凝土中玄武岩纤维断裂的SEM图。Figure 4 is an SEM image of the fracture of basalt fibers in the basalt fiber reinforced coral sand concrete of Example 2.
具体实施方式Detailed ways
以下结合说明书附图和具体优选的实施例对本发明作进一步描述,但并不因此而限制本发明的保护范围。以下实施例中所采用的材料和仪器均为市售。The present invention will be further described below in conjunction with the accompanying drawings and specific preferred embodiments of the specification, but the protection scope of the present invention will not be limited thereby. The materials and instruments used in the following examples are all commercially available.
以下各实施例中:In the following examples:
水泥为诸城市杨春山水水泥有限公司生产的PO42.5硅酸盐水泥,粉煤灰为比表面积1300m2/kg、烧失量2.8%、密度2.55g/cm3、SiO2含量45.1%、含水量0.85%、细度16%的粉煤灰,矿渣粉为比表面积628m2/kg、密度2.93g/cm3、烧失量0.96%、含水量0.4%的矿渣粉。The cement is PO42.5 Portland cement produced by Zhucheng Yangchun Shanshui Cement Co., Ltd. The fly ash has a specific surface area of 1300m2 /kg, a loss on ignition of 2.8%, a density of 2.55g/ cm3 , and a SiO2 content of 45.1%. The fly ash has a moisture content of 0.85% and a fineness of 16%. The slag powder has a specific surface area of 628m 2 /kg, a density of 2.93g/cm 3 , a loss on ignition of 0.96%, and a moisture content of 0.4%.
珊瑚砂作为混凝土的细骨料,珊瑚砂的颗粒粒径为0.15mm~2.36mm,细度模数1.88~2.03,分类为细砂。Coral sand is used as the fine aggregate of concrete. The particle size of coral sand is 0.15mm~2.36mm, the fineness modulus is 1.88~2.03, and it is classified as fine sand.
玄武岩纤维的弹性模量为91~110GPa,公称长度为10mm,密度为2.64g/cm3(2.63g/cm3~2.65g/cm3均可),单丝直径7μm~15μm,断裂强度>2000MPa。本发明利用玄武岩纤维作为增强材料,可有效提高混凝土的抗压强度,改善混凝土的抗压、抗裂性能,同时增加珊瑚砂混凝土延性及耐久性。The elastic modulus of basalt fiber is 91~110GPa, the nominal length is 10mm, the density is 2.64g/cm 3 (2.63g/cm 3 ~ 2.65g/cm 3 is acceptable), the single filament diameter is 7μm~15μm, and the breaking strength is >2000MPa . The present invention uses basalt fiber as reinforcing material, which can effectively increase the compressive strength of concrete, improve the compression and crack resistance of concrete, and at the same time increase the ductility and durability of coral sand concrete.
聚羧酸减水剂的固含量为50%,减水率为28%,聚羧酸减水剂的质量为水泥、粉煤灰和矿渣粉总质量的0.2%。本发明利用聚羧酸减水剂提高混凝土的施工性能和硬化性能,节约水泥,降低能耗,提高混凝土的致密性,而致密性的提高能够有效阻止氯离子的侵蚀,进而增强混凝土的抗氯离子渗透性能,同时致密性的提高还能够提高混凝土的力学性能。The solid content of the polycarboxylate water-reducing agent is 50%, the water-reducing rate is 28%, and the mass of the polycarboxylate water-reducing agent is 0.2% of the total mass of cement, fly ash and slag powder. The present invention uses polycarboxylate water-reducing agent to improve the construction performance and hardening performance of concrete, save cement, reduce energy consumption, and improve the density of concrete. The improvement in density can effectively prevent the erosion of chloride ions, thereby enhancing the chlorine resistance of concrete. Ion permeability, while increasing density can also improve the mechanical properties of concrete.
海水作为水化反应用水,为按比例配置的人工海水,人工海水包含水和如表1所示的化学组成。Seawater, used as water for hydration reaction, is artificial seawater configured in proportion. Artificial seawater contains water and the chemical composition shown in Table 1.
表1 人工海水的化学组成表Table 1 Chemical composition of artificial seawater
实施例1Example 1
一种本发明的玄武岩纤维增强珊瑚砂混凝土,按质量份计,由以下组分组成:硅酸盐水泥240份、粉煤灰192份、矿渣粉48份、珊瑚砂528份、海水124.8份、聚羧酸减水剂0.96份、玄武岩纤维为2.11份。A kind of basalt fiber reinforced coral sand concrete of the present invention is composed of the following components in terms of parts by mass: 240 parts of Portland cement, 192 parts of fly ash, 48 parts of slag powder, 528 parts of coral sand, 124.8 parts of seawater, The polycarboxylate water-reducing agent is 0.96 parts and the basalt fiber is 2.11 parts.
一种本实施例的玄武岩纤维增强珊瑚砂混凝土的制备方法,包括以下步骤:A method for preparing the basalt fiber reinforced coral sand concrete of this embodiment includes the following steps:
(1)将搅拌桶壁润湿,加入水泥、粉煤灰和矿渣粉,搅拌1min至均匀,得到胶凝材料;人工海水可提前制备。(1) Wet the wall of the mixing barrel, add cement, fly ash and slag powder, stir for 1 minute until uniform, and obtain the cementitious material; artificial seawater can be prepared in advance.
(2)加入2/3海水至搅拌桶中,与胶凝材料混合搅拌约2min,随后添加聚羧酸减水剂与1/3海水搅拌约2 min,得到具有一定流动性的胶凝状浆体。(2) Add 2/3 seawater into the mixing barrel, mix with the gelling material and stir for about 2 minutes, then add polycarboxylate superplasticizer and 1/3 seawater and stir for about 2 minutes to obtain a gelled slurry with certain fluidity body.
(3)将玄武岩纤维与珊瑚砂提前搅拌均匀,使玄武岩纤维在珊瑚砂中均匀分散,得到混合物,将珊瑚砂与玄武岩纤维的混合物充分融入胶凝状浆体中,搅拌3min,得到混凝土材料。(3) Stir the basalt fiber and coral sand evenly in advance so that the basalt fiber is evenly dispersed in the coral sand to obtain a mixture. Fully integrate the mixture of coral sand and basalt fiber into the gelled slurry and stir for 3 minutes to obtain concrete material.
(4)将混凝土材料浇筑入模,进行振捣1min,24小时后,拆模再进行标准养护至28d龄期,得到玄武岩纤维增强珊瑚砂混凝土。(4) Pour the concrete material into the mold and vibrate for 1 minute. After 24 hours, remove the mold and perform standard curing to 28 days to obtain basalt fiber reinforced coral sand concrete.
将养护好的混凝土试块进行静态抗压试验以及动态冲击压缩SHPB试验进行研究,结果如表2所示。The cured concrete test blocks were subjected to static compression tests and dynamic impact compression SHPB tests. The results are shown in Table 2.
实施例2Example 2
一种本发明的玄武岩纤维增强珊瑚砂混凝土,按质量份计,由以下组分组成:硅酸盐水泥240份、粉煤灰192份、矿渣粉48份、珊瑚砂528份、海水124.8份、聚羧酸减水剂0.96份、玄武岩纤维4.22份。A kind of basalt fiber reinforced coral sand concrete of the present invention is composed of the following components in terms of parts by mass: 240 parts of Portland cement, 192 parts of fly ash, 48 parts of slag powder, 528 parts of coral sand, 124.8 parts of sea water, 0.96 parts of polycarboxylate water-reducing agent and 4.22 parts of basalt fiber.
一种本实施例的玄武岩纤维增强珊瑚砂混凝土的制备方法,包括以下步骤:A method for preparing the basalt fiber reinforced coral sand concrete of this embodiment includes the following steps:
(1)将搅拌桶壁润湿,加入水泥、粉煤灰和矿渣粉,搅拌1min至均匀,得到胶凝材料;人工海水可提前制备。(1) Wet the wall of the mixing barrel, add cement, fly ash and slag powder, stir for 1 minute until uniform, and obtain the cementitious material; artificial seawater can be prepared in advance.
(2)加入2/3海水至搅拌桶中,与胶凝材料混合搅拌约2min,随后添加聚羧酸减水剂与1/3海水量搅拌约2 min,得到具有一定流动性的胶凝状浆体。(2) Add 2/3 of the seawater into the mixing barrel, mix with the gelling material and stir for about 2 minutes, then add polycarboxylate superplasticizer and 1/3 of the seawater and stir for about 2 minutes to obtain a gelatinous material with certain fluidity. slurry.
(3)将玄武岩纤维与珊瑚砂提前搅拌均匀,使玄武岩纤维在珊瑚砂中均匀分散,得到混合物,将珊瑚砂与玄武岩纤维的混合物充分融入胶凝状浆体中,搅拌3min,得到混凝土材料。(3) Stir the basalt fiber and coral sand evenly in advance so that the basalt fiber is evenly dispersed in the coral sand to obtain a mixture. Fully integrate the mixture of coral sand and basalt fiber into the gelled slurry and stir for 3 minutes to obtain concrete material.
(4)将混凝土材料浇筑入模,进行振捣1min,24小时后,拆模再进行标准养护至28d龄期,得到玄武岩纤维增强珊瑚砂混凝土。(4) Pour the concrete material into the mold and vibrate for 1 minute. After 24 hours, remove the mold and perform standard curing to 28 days to obtain basalt fiber reinforced coral sand concrete.
将养护好的混凝土试块进行静态抗压试验以及动态冲击压缩SHPB试验进行研究,结果如表2所示。The cured concrete test blocks were subjected to static compression tests and dynamic impact compression SHPB tests. The results are shown in Table 2.
图1为本实施例的玄武岩纤维增强珊瑚砂混凝土中珊瑚砂与混凝土基体连接的SEM图。从图中可以看出,珊瑚砂呈现出多孔内部结构疏松的现象,在外力下更易发生破碎。Figure 1 is an SEM image of the connection between the coral sand and the concrete matrix in the basalt fiber reinforced coral sand concrete of this embodiment. It can be seen from the figure that coral sand has a porous internal structure and is more likely to break under external force.
图2为本实施例的玄武岩纤维增强珊瑚砂混凝土中玄武岩纤维端部与混凝土基体连接的SEM图。从图中可以看出,玄武岩纤维增强珊瑚砂混凝土的孔洞内部存在水化产物的填充,且玄武岩纤维基体被水泥颗粒包裹,纤维表面和纤维根部与混凝土基体连接处有着较多的水化产物生成。Figure 2 is an SEM image of the connection between the end of the basalt fiber and the concrete matrix in the basalt fiber reinforced coral sand concrete of this embodiment. It can be seen from the figure that the holes of basalt fiber reinforced coral sand concrete are filled with hydration products, and the basalt fiber matrix is wrapped by cement particles. There are more hydration products generated at the connection between the fiber surface and fiber roots and the concrete matrix. .
图3为本实施例的玄武岩纤维增强珊瑚砂混凝土中玄武岩纤维的三维骨架桥接的SEM图。从图中可以看出,玄武岩纤维在混凝土基体中形成一个三维骨架网络系统,其在混凝土基体中较为稳定,使混凝土材料的变形受到约束,这说明玄武岩纤维可以增强混凝土的强度。Figure 3 is an SEM image of the three-dimensional skeleton bridge of basalt fiber in the basalt fiber reinforced coral sand concrete of this embodiment. It can be seen from the figure that basalt fiber forms a three-dimensional skeleton network system in the concrete matrix, which is relatively stable in the concrete matrix and restrains the deformation of the concrete material. This shows that basalt fiber can enhance the strength of concrete.
图4为本实施例的玄武岩纤维增强珊瑚砂混凝土中玄武岩纤维断裂的SEM图。图中可以看出纤维断裂处呈现出交叉撕裂状,这说明玄武岩纤维与混凝土基体的粘结性能较好,也说明了玄武岩纤维在混凝土基体破坏的过程中起到了很好的约束作用。Figure 4 is an SEM image of the fracture of basalt fibers in the basalt fiber reinforced coral sand concrete of this embodiment. It can be seen in the figure that the fiber fractures show a cross-tear shape, which shows that the bonding performance between the basalt fiber and the concrete matrix is good, and also shows that the basalt fiber plays a very good restraint role in the destruction of the concrete matrix.
实施例3Example 3
一种本发明的玄武岩纤维增强珊瑚砂混凝土,按质量份计,由以下组分组成:硅酸盐水泥240份、粉煤灰192份、矿渣粉48份、珊瑚砂528份、海水124.8份、聚羧酸减水剂0.96份、玄武岩纤维8.44份。A kind of basalt fiber reinforced coral sand concrete of the present invention is composed of the following components in terms of parts by mass: 240 parts of Portland cement, 192 parts of fly ash, 48 parts of slag powder, 528 parts of coral sand, 124.8 parts of seawater, Polycarboxylate water-reducing agent 0.96 parts, basalt fiber 8.44 parts.
一种本实施例的玄武岩纤维增强珊瑚砂混凝土的制备方法,包括以下步骤:A method for preparing the basalt fiber reinforced coral sand concrete of this embodiment includes the following steps:
(1)将搅拌桶壁润湿,加入水泥、粉煤灰和矿渣粉,搅拌1min至均匀,得到胶凝材料;人工海水可提前制备。(1) Wet the wall of the mixing barrel, add cement, fly ash and slag powder, stir for 1 minute until uniform, and obtain the cementitious material; artificial seawater can be prepared in advance.
(2)加入2/3海水至搅拌桶中,与胶凝材料混合搅拌约2min,随后添加聚羧酸减水剂与1/3海水量搅拌约2 min,得到具有一定流动性的胶凝状浆体。(2) Add 2/3 of the seawater into the mixing barrel, mix with the gelling material and stir for about 2 minutes, then add polycarboxylate superplasticizer and 1/3 of the seawater and stir for about 2 minutes to obtain a gelatinous material with certain fluidity. slurry.
(3)将玄武岩纤维与珊瑚砂提前搅拌均匀,使玄武岩纤维在珊瑚砂中均匀分散,得到混合物,将珊瑚砂与玄武岩纤维的混合物充分融入胶凝状浆体中,搅拌3min,得到混凝土材料。(3) Stir the basalt fiber and coral sand evenly in advance so that the basalt fiber is evenly dispersed in the coral sand to obtain a mixture. Fully integrate the mixture of coral sand and basalt fiber into the gelled slurry and stir for 3 minutes to obtain concrete material.
(4)将混凝土材料浇筑入模,进行振捣1min,24小时后,拆模再进行标准养护至28d龄期,得到玄武岩纤维增强珊瑚砂混凝土。(4) Pour the concrete material into the mold and vibrate for 1 minute. After 24 hours, remove the mold and perform standard curing to 28 days to obtain basalt fiber reinforced coral sand concrete.
将养护好的混凝土试块进行静态抗压试验以及动态冲击压缩SHPB试验进行研究,结果如表2所示。The cured concrete test blocks were subjected to static compression tests and dynamic impact compression SHPB tests. The results are shown in Table 2.
对比例1Comparative example 1
一种玄武岩纤维增强珊瑚砂混凝土,按质量份计,由以下组分组成:硅酸盐水泥240份、粉煤灰192份、矿渣粉48份、珊瑚砂528份、海水124.8份、聚羧酸减水剂0.96份、玄武岩纤维4.22份。A kind of basalt fiber reinforced coral sand concrete consists of the following components in terms of parts by mass: 240 parts of Portland cement, 192 parts of fly ash, 48 parts of slag powder, 528 parts of coral sand, 124.8 parts of seawater, polycarboxylic acid 0.96 parts of water reducing agent and 4.22 parts of basalt fiber.
一种玄武岩纤维增强珊瑚砂混凝土的制备方法,包括以下步骤:A preparation method of basalt fiber reinforced coral sand concrete, including the following steps:
(1)将搅拌桶壁润湿,加入水泥、粉煤灰和矿渣粉,搅拌1min至均匀,得到胶凝材料;人工海水可提前制备。(1) Wet the wall of the mixing barrel, add cement, fly ash and slag powder, stir for 1 minute until uniform, and obtain the cementitious material; artificial seawater can be prepared in advance.
(2)加入2/3海水至搅拌桶中,与胶凝材料混合搅拌约2min,随后添加聚羧酸减水剂与1/3海水量搅拌约2 min,得到具有一定流动性的胶凝状浆体。(2) Add 2/3 of the seawater into the mixing barrel, mix with the gelling material and stir for about 2 minutes, then add polycarboxylate superplasticizer and 1/3 of the seawater and stir for about 2 minutes to obtain a gelatinous material with certain fluidity. slurry.
(3)将胶凝状浆体中加入珊瑚砂,搅拌至珊瑚砂充分融入胶凝状浆体中,得到材料拌合物。(3) Add coral sand to the gelled slurry and stir until the coral sand is fully integrated into the gelled slurry to obtain a material mixture.
(4)将玄武岩纤维掺进材料拌合物中,使其均匀分散,得到混凝土材料。(4) Mix basalt fiber into the material mixture and disperse it evenly to obtain concrete material.
(5)将混凝土材料浇筑入模,进行振捣1min,24小时后,拆模再进行标准养护至28d龄期,得到玄武岩纤维增强珊瑚砂高延性混凝土。(5) Pour the concrete material into the mold and vibrate for 1 minute. After 24 hours, remove the mold and perform standard curing to 28 days to obtain basalt fiber reinforced coral sand high ductility concrete.
将养护好的混凝土试块进行静态抗压试验以及动态冲击压缩SHPB试验进行研究,结果如表2所示。The cured concrete test blocks were subjected to static compression tests and dynamic impact compression SHPB tests. The results are shown in Table 2.
对比例2Comparative example 2
一种碳纤维增强珊瑚砂混凝土,按质量份计,由以下组分组成:硅酸盐水泥240份、粉煤灰192份、矿渣粉48份、珊瑚砂528份、海水124.8份、聚羧酸减水剂0.96份、碳纤维8.44份。A kind of carbon fiber reinforced coral sand concrete consists of the following components in terms of parts by mass: 240 parts of Portland cement, 192 parts of fly ash, 48 parts of slag powder, 528 parts of coral sand, 124.8 parts of seawater, polycarboxylic acid-reduced 0.96 parts of water agent and 8.44 parts of carbon fiber.
一种碳纤维增强珊瑚砂混凝土的制备方法,包括以下步骤:A preparation method of carbon fiber reinforced coral sand concrete, including the following steps:
(1)在制备之前提前24小时预润湿珊瑚砂至饱和,提前人工制备海水。(1) Pre-wet the coral sand to saturation 24 hours in advance before preparation, and prepare seawater artificially in advance.
(2)先将硅酸盐水泥、粉煤灰和矿渣粉搅拌均匀,加2/3海水量搅拌约2 min,随后添加聚羧酸减水剂与1/3海水量搅拌约2 min,得到具有一定流动性的胶凝状浆体。(2) First stir the Portland cement, fly ash and slag powder evenly, add 2/3 of the seawater and stir for about 2 minutes, then add the polycarboxylate superplasticizer and 1/3 of the seawater and stir for about 2 minutes to get A gel-like slurry with certain fluidity.
(3)将碳纤维与珊瑚砂提前搅拌均匀,使碳纤维在珊瑚砂中均匀分散,得到混合物,将珊瑚砂和碳纤维的混合物充分融入胶凝状浆体中,搅拌3min,得到混凝土材料。(3) Stir the carbon fiber and coral sand evenly in advance so that the carbon fiber is evenly dispersed in the coral sand to obtain a mixture. Fully integrate the mixture of coral sand and carbon fiber into the gelled slurry and stir for 3 minutes to obtain concrete material.
(4)将混凝土材料浇筑入模,进行振捣1min,24小时后,拆模再进行标准养护至28d龄期,得到碳纤维增强珊瑚砂混凝土。(4) Pour the concrete material into the mold and vibrate for 1 minute. After 24 hours, remove the mold and perform standard curing to 28 days to obtain carbon fiber reinforced coral sand concrete.
将养护好的混凝土试块进行静态抗压试验以及动态冲击压缩SHPB试验进行研究,结果如表2所示。The cured concrete test blocks were subjected to static compression tests and dynamic impact compression SHPB tests. The results are shown in Table 2.
对比例3Comparative example 3
不加玄武岩纤维的珊瑚砂混凝土,即空白组,具体如下:Coral sand concrete without basalt fiber, that is, the blank group, is as follows:
一种珊瑚砂混凝土,按质量份计,由以下组分组成:硅酸盐水泥240份、粉煤灰192份、矿渣粉48份、珊瑚砂528份、海水124.8份、聚羧酸减水剂0.96份。A kind of coral sand concrete consists of the following components in terms of parts by mass: 240 parts of Portland cement, 192 parts of fly ash, 48 parts of slag powder, 528 parts of coral sand, 124.8 parts of seawater, and polycarboxylate water-reducing agent 0.96 servings.
一种珊瑚砂混凝土的制备方法,包括以下步骤:A preparation method of coral sand concrete includes the following steps:
(1)在制备之前提前24小时预润湿珊瑚砂至饱和,提前人工制备海水。(1) Pre-wet the coral sand to saturation 24 hours in advance before preparation, and prepare seawater artificially in advance.
(2)先将硅酸盐水泥、粉煤灰和矿渣粉搅拌均匀,加2/3海水量搅拌约2 min,随后添加聚羧酸减水剂与1/3海水量搅拌约2 min,得到具有一定流动性的胶凝状浆体。(2) First stir the Portland cement, fly ash and slag powder evenly, add 2/3 of the seawater and stir for about 2 minutes, then add the polycarboxylate superplasticizer and 1/3 of the seawater and stir for about 2 minutes to get A gel-like slurry with certain fluidity.
(3)在胶凝状浆体中加入珊瑚砂,搅拌至珊瑚砂充分融入胶凝状浆体中,得到混凝土材料。(3) Add coral sand to the gelled slurry and stir until the coral sand is fully integrated into the gelled slurry to obtain concrete material.
(4)将混凝土材料浇筑入模,进行振捣1min,24小时后,拆模再进行标准养护至28d龄期,得到珊瑚砂混凝土。(4) Pour the concrete material into the mold and vibrate it for 1 minute. After 24 hours, remove the mold and perform standard curing to 28 days to obtain coral sand concrete.
养护好的混凝土试块进行静态抗压试验以及动态冲击压缩SHPB试验进行研究,结果如表2所示。The cured concrete test blocks were subjected to static compression tests and dynamic impact compression SHPB tests. The results are shown in Table 2.
表2 实施例1-3、对比例1-3的混凝土静动态抗压强度表Table 2 Static and dynamic compressive strength of concrete in Examples 1-3 and Comparative Examples 1-3
以上所述,仅是本发明的较佳实施例而已,并非对本发明作任何形式上的限制。虽然本发明已以较佳实施例揭示如上,然而并非用以限定本发明。任何熟悉本领域的技术人员,在不脱离本发明的精神实质和技术方案的情况下,都可利用上述揭示的方法和技术内容对本发明技术方案做出许多可能的变动和修饰,或修改为等同变化的等效实施例。因此,凡是未脱离本发明技术方案的内容,依据本发明的技术实质对以上实施例所做的任何简单修改、等同替换、等效变化及修饰,均仍属于本发明技术方案保护的范围内。The above descriptions are only preferred embodiments of the present invention and do not limit the present invention in any form. Although the present invention has been disclosed above in terms of preferred embodiments, this is not intended to limit the present invention. Any person familiar with the art can make many possible changes and modifications to the technical solution of the present invention using the methods and technical content disclosed above without departing from the spirit and technical solution of the present invention, or modify it to be equivalent. Varied equivalent embodiments. Therefore, any simple modifications, equivalent substitutions, equivalent changes and modifications made to the above embodiments based on the technical essence of the present invention without departing from the content of the technical solution of the present invention still fall within the scope of protection of the technical solution of the present invention.
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