CN1167185A - Adhesive stick type long-effect light-reflection material for sign on road surface - Google Patents
Adhesive stick type long-effect light-reflection material for sign on road surface Download PDFInfo
- Publication number
- CN1167185A CN1167185A CN96107500A CN96107500A CN1167185A CN 1167185 A CN1167185 A CN 1167185A CN 96107500 A CN96107500 A CN 96107500A CN 96107500 A CN96107500 A CN 96107500A CN 1167185 A CN1167185 A CN 1167185A
- Authority
- CN
- China
- Prior art keywords
- sign
- road surface
- roller
- type long
- stick type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 55
- 239000000853 adhesive Substances 0.000 title claims abstract description 12
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 13
- -1 polypropylene Polymers 0.000 claims abstract description 13
- 239000004743 Polypropylene Substances 0.000 claims abstract description 10
- 229920001155 polypropylene Polymers 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 8
- 238000005096 rolling process Methods 0.000 claims abstract description 6
- 239000006004 Quartz sand Substances 0.000 claims abstract description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 4
- 239000011575 calcium Substances 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000003995 emulsifying agent Substances 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract 1
- 239000007822 coupling agent Substances 0.000 abstract 1
- 239000001038 titanium pigment Substances 0.000 abstract 1
- 238000003490 calendering Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 3
- 238000004026 adhesive bonding Methods 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002742 anti-folding effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Landscapes
- Road Signs Or Road Markings (AREA)
- Adhesive Tapes (AREA)
Abstract
The pavement long-acting reflecting sign material is made up by using polypropylene and TPR as base material, and mixing them with filling materials of quartz sand, quartz sand powder, light calcium powder, titanium pigment and coupling agent, and processed by colloid-forming and rolling so as to obtain a sheet material, i.e. the invented long-acting reflecting sign material with high elasticity, high deformationr esistance, high acid-proof and alkali-proof property and durable ageing resistance. The surface of said material contacted with pavement is coated with a layer adhesive which does not contaminate pavement and is easy to be spalled.
Description
The present invention relates to a kind of marking material that is used for the traffic administration on road surface.More particularly this marking material can directly stick on the road, and can be at noctilucence road surface long-acting reflecting table tape.---existing traffic administration pavement markers, as describing in United States Patent (USP) 92101175.X and 92103945.X two manuals, the former mainly is the adhesion strength that combines back raising traffic sign object self and road surface with polyorganosiloxane adhesive with pavement markers; The latter then mainly is a kind of ironed panel material of integral layer of road sign that can be reflective.Its surface has one deck polypropylene and can protect road sign pattern on the thin plate to avoid exposing to the weather and be compromised, thereby loses the effect of road sign sign.And the compound reflection traffic marking of narration in the Chinese patent 90108856.0 just adopts the plastics strip to make base, and glass microballoon is dissolved in the traffic tape of its surface as surface layer.Its defective is to have ignored the prerequisite tension of traffic tape self, anti-folding, and the reality of high tenacity and high-wearing feature needs.Disclosed in another Chinese utility model patent 90223988.0 then is a kind of geometrical layers body first class face colored belt of making raw material with pottery, the road surface that need dig up highway when this colored belt is constructed, after putting into ceramic grain of rice shape particle layer road surface signal belt then, use the road roller extrusion molding again, and the kraft adhesion coating of belt surface can't peel off at that time, wait for could slowly being demonstrated the colored belt that is covered by kraft after the continuous wearing and tearing of the vehicles.Its shortcoming is the construction trouble, and at following period of time colored belt cisco unity malfunction.
The present invention just can eliminate many deficiencies of above existing traffic sign thing.A kind of the wear-resisting, withstand voltage, corrosion-resistant of high strength degree that have is provided, and it is good to paste performance, and when changing colored belt, peels off easily and do not pollute the road surface, does not damage the road surface, the rational long-acting pavement reflecting marking material of reflective visibility.The present invention be on the basis of former patent of invention 92114966.2 by after the continuous practice, a kind of various indexs that former base material and batching and manufacture craft have all been done to obtain after the further improvement all are superior to the novel pavement marking material of original application stuck long-service marking line belt.
Inventive result of the present invention is by the modified PVC base material with former employing, has changed the TPR material into, and this TPR material be with carry out mixing a period of time through other batchings of high-speed mixing after, again through calendering, gluing, plant and obtain after pearl, the oven dry.For the high-intensity abrasion resistance that improves the colored belt sheet material, anti-aging and withstand voltage stability, the present invention has also added polypropylene in the TPR raw material, again at 160 ℃--in 300 ℃ the mill behind the heating plasticizing one time, add fill material that proportioning mixes again and carry out that calendering forms after mixing a period of time.
In accompanying drawing one, first procedure is batching required for the present invention: quartz sand, quartz powder, soft calcium powder, lithopone, titanium dioxide, antioxidant, glass microballoon, KH---550, and pigment, join temperature at 80 ℃--mix in-180 ℃ the high-speed mixer.Meanwhile, the temperature of mill is risen to 160 ℃---300 ℃, add polypropylene, TPR base material raw material again after roll spacing on the machine being transferred to the suitable distance of 1.0MM--5MM, in the mill that mixes up roll spacing, plastify.Might make the fused property of polypropylene and TPR like this after the plasticizing.The fill material that high temperature is mixed joins in the mill that is surrounded by the good polypropylene .TPR of plasticizing again, and after start was carried out mixing about 10---30 minute, discharging entered the multi-rolling mill calendering.Note, before the mixed packing material is sent into mill, the roll spacing between two rollers in the mill must be transferred to 2MM--6MM, in order to guarantee the equal thickness after the mixing glue laminated of sheet material one time.As a same reason, with the mixed material in the mill, send into multi-rolling mill before, should mix up the distance between several rollers in the calender earlier.Roller spacing between each roller should be transferred between 1MM--5MM.Generally speaking, (1), (2), the temperature of (30) roller should be transferred to 138 ℃ after the start--between 250 ℃, the temperature of (4) (or last) roller should transfer between 90 ℃-100 ℃.And should adopt the low speed reinforced rolling process of advancing during the calendering, roll.When raw material through (4) after (or last) roller calendering, along with the process of lowering the temperature while roll slowly, can guarantee the sheet material that rolls out at the gluing that and then carries out, plant
Can keep making the chlorinated rubber adhesive that newly is coated on the sheet material in the pearl operation, the bond properties that can not go down owing to the high temperature of sheet material, the high temperature of sheet material and make and to plant the glass microballoon fusion distortion that is placed on the sheet material thus.
Accompanying drawing two is stereograms of colored belt product of the present invention.Accompanying drawing three is finished product packing stereograms of the present invention.For the feasibility that manufactures a finished product of marking material of the present invention further is described, we further describe with embodiment.Pour in two rollers or the multiple roll mill load weighted polypropylene GRANULES is some, but should at first mix up each roller spacing before this between 1MM---5MM, then load weighted TPR particle is poured between two rollers, is made it 160 ℃ of temperature--the back plasticizing of plasticating under-300 ℃ the machine temperature adds after about 38 minutes again to be carried out mixing through the uniform quartz sand of high-speed mixing, quartz powder, light calcium powder, lithopone, titanium dioxide, antioxidant (1) glass microballoon (2) KH--550, pigment, supplement that proportioning is good.In mixing process, should be specifically noted that and avoid between roller and roller, producing a lot of gum deposits.The distance that according to circumstances suitably strengthens between two rollers keeps moderate gum deposit amount.For the fair mixing time that protects that guarantees sheet material should be grasped at 10-30 minute and is advisable.In sheet material mixing, also should render in the middle of the roller simultaneously in time with the sizing material at tapping knife correction roller two ends.In reinforced process, also should in time sweep in the adding machine from the various materials that fall down between roller, to guarantee the proportion speed degree of sheet material.With the sizing material that mixes, deliver to roll into the sheet material that thickness is 1MM--5MM in the four-roll calender after, send traction chamber traction to.And then just coat and plant pearl glue in the surface at sheet, sprinkling glass microballoon again, the HT--906 pressure sensitive adhesive is then coated at the sheet material back side again in the oven dry back, drying, encloses one deck barrier paper again, puts in storage through air-cooled, cut-parts, rolling, finished product then.
The characteristics of marking material of the present invention are:
1, base material good springiness, the permanent deformation degree is less, wear-resisting, acidproof acidity and lasting anti-aging;
2, the adhesive power cohesive strength of pressure sensitive adhesive is all very strong, three-waste free pollution in coating process, and can be at subzero 40 ℃--all have very strong bonding force in-100 ℃ of scopes;
3, the broad application temperature range of base material itself, selectivity is good arbitrarily.
Product inspection result of the present invention sees table:
Censorship odd numbers X-96029
| Assay | |||
| ??NO | Interventions Requested | Unit | Assay |
| ??1 | Hardness | Degree | ?????84.4 |
| ??2 | Breaking strength | ?????MPa | ?????1.70 |
| ??3 | Give as security long rate | ?????％ | ?????60 |
| ??4 | Permanent deformation | ?????％ | ?????2 |
| ??5 | 400 ℃ * 24h) breaking strength | ????MPa | ?????2.87 |
| ??6 | The warp-wise tearing strength | ????KN/m | ????15.2 |
| ??7 | Filling-tear resistance | ????KN/m | ????13.8 |
| ??8 | Wear-resisting | CM/1，61KM | ????4.59 |
Claims (7)
1, the present invention is a kind of adhesive stick type long-effect light-reflection material for sign on road surface that relates to traffic administration, and its feature is as follows:
Adopt polypropylene and TPR base material as this marking material;
Fill material through high temperature mixing homogeneous proportioning;
One deck can directly stick on marking material the HT-906 pressure sensitive adhesive of road surface;
2, the adhesive stick type long-effect light-reflection material for sign on road surface described in claim 1.It is characterized in that at 160 ℃--in-300 ℃ the mill polypropylene and TPR particle are plastified one time, the spacing of mill roller is 1.0MM-5MM;
3, the adhesive stick type long-effect light-reflection material for sign on road surface described in right 1.The inserts that it is characterized in that this marking material is quartz sand, quartz powder, light calcium powder, lithopone, titanium dioxide, antioxidant, glass microballoon, KH---550, pigment, and above inserts joined temperature at 80 ℃--mix in-180 ℃ the high-speed mixer;
4, the adhesive stick type long-effect light-reflection material for sign on road surface described in claim 1,2,3.It is characterized in that this marking material polypropylene and TPR and the various fillers that mix 160 ℃ of temperature--in 300 ℃ the mill mixing 10 minutes---15 minutes, and the spacing of mill roller transferred to 2MM---6MM;
5, the adhesive stick type long-effect light-reflection material for sign on road surface described in claim 1,2,3,4.The temperature that it is characterized in that making between each roller in the calender of this light-reflection material for sign is controlled at 138 ℃--and-250 ℃, and the temperature of last each roller of roller is controlled at 90 ℃-100 ℃, the spacing of individual roller can be 1MM-5MM;
6, adhesive stick type long-effect light-reflection material for sign on road surface as claimed in claim 5 is characterized in that making the calender of this reflectorized material, can be two-roll calendar, also can be multi-rolling mill;
7, HT one 906 pressure sensitive adhesives as claimed in claim 1 is characterized in that pressure sensitive adhesive is non-particle water and the emulsifier of waiting, acrylic acid, the rare and tackifying resin of acetic acid second, and plasticizing agent is formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96107500A CN1074486C (en) | 1996-06-05 | 1996-06-05 | Adhesive stick type long-effect light-reflection material for sign on road surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96107500A CN1074486C (en) | 1996-06-05 | 1996-06-05 | Adhesive stick type long-effect light-reflection material for sign on road surface |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1167185A true CN1167185A (en) | 1997-12-10 |
| CN1074486C CN1074486C (en) | 2001-11-07 |
Family
ID=5119616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96107500A Expired - Fee Related CN1074486C (en) | 1996-06-05 | 1996-06-05 | Adhesive stick type long-effect light-reflection material for sign on road surface |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1074486C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104710720A (en) * | 2015-03-31 | 2015-06-17 | 四川省江油市豫蜀夜视利反光材料有限公司 | Reflective marking belt base material, base material and method for manufacturing reflective marking belt |
| CN106498866A (en) * | 2016-11-24 | 2017-03-15 | 李德生 | Carbon fibre resin ceramic particle synthesizes offset plate |
| CN106752035A (en) * | 2016-11-22 | 2017-05-31 | 安徽雄峰实业有限公司 | A kind of rubber sleeve of automatic luminous and preparation method thereof |
| CN106758909A (en) * | 2016-11-24 | 2017-05-31 | 李德生 | Carbon fibre resin ceramic powders synthesize offset plate |
| CN107709668A (en) * | 2015-06-18 | 2018-02-16 | 3M创新有限公司 | Thermoplasticity pavement marker band |
-
1996
- 1996-06-05 CN CN96107500A patent/CN1074486C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104710720A (en) * | 2015-03-31 | 2015-06-17 | 四川省江油市豫蜀夜视利反光材料有限公司 | Reflective marking belt base material, base material and method for manufacturing reflective marking belt |
| CN104710720B (en) * | 2015-03-31 | 2017-03-29 | 四川省江油市豫蜀夜视利反光材料有限公司 | A kind of reflecting marking is with base material and base material, the manufacture method of reflecting marking band |
| CN107709668A (en) * | 2015-06-18 | 2018-02-16 | 3M创新有限公司 | Thermoplasticity pavement marker band |
| US10889947B2 (en) | 2015-06-18 | 2021-01-12 | 3M Innovative Properties Company | Thermoplastic pavement marking tapes |
| CN107709668B (en) * | 2015-06-18 | 2021-09-24 | 3M创新有限公司 | Thermoplastic pavement marking tape |
| CN106752035A (en) * | 2016-11-22 | 2017-05-31 | 安徽雄峰实业有限公司 | A kind of rubber sleeve of automatic luminous and preparation method thereof |
| CN106498866A (en) * | 2016-11-24 | 2017-03-15 | 李德生 | Carbon fibre resin ceramic particle synthesizes offset plate |
| CN106758909A (en) * | 2016-11-24 | 2017-05-31 | 李德生 | Carbon fibre resin ceramic powders synthesize offset plate |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1074486C (en) | 2001-11-07 |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yan Cuihua Inventor before: Yan Cuihua Inventor before: Xiao Sen Inventor before: Guo Yanwen Inventor before: Liu Zexin Inventor before: Yan Guosheng Inventor before: Yan Guoxiang Inventor before: Yan Guoping Inventor before: Yan Guoxun |
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| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: YAN CUIHUA; XIAO SEN; GUO YANWEN; LIU ZEXIN; YAN GUOSHENG; YAN GUOXIANG; YAN GUOPING; YAN GUOXUN TO: YAN CUIHUA |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |