[go: up one dir, main page]

CN116621417A - Method for rapid cleaning and dehydration of dredging sediment - Google Patents

Method for rapid cleaning and dehydration of dredging sediment Download PDF

Info

Publication number
CN116621417A
CN116621417A CN202310693675.8A CN202310693675A CN116621417A CN 116621417 A CN116621417 A CN 116621417A CN 202310693675 A CN202310693675 A CN 202310693675A CN 116621417 A CN116621417 A CN 116621417A
Authority
CN
China
Prior art keywords
molecular weight
mud
pipeline
dredging
cationic polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310693675.8A
Other languages
Chinese (zh)
Inventor
陆纯
徐祖信
董滨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongji University
Original Assignee
Tongji University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongji University filed Critical Tongji University
Priority to CN202310693675.8A priority Critical patent/CN116621417A/en
Publication of CN116621417A publication Critical patent/CN116621417A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C02F11/147Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using organic substances
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Treatment Of Sludge (AREA)

Abstract

本发明涉及底泥治理技术领域,具体为一种用于疏浚底泥快速清洁脱水的方法,其包括步骤:通过绞吸泵对河岸底泥进行切割、搅动形成泥浆,并通过泵力将泥浆输出;将输出的泥浆通过管道运输,在靠近河岸的管道上通过第一支路投加低分子量阳离子聚合物对泥浆进行一级絮凝;在靠近管道末端的位置通过第二支路投加高分子量絮凝剂对泥浆进行二级絮凝;将管道的末端与土工布袋相连,使从管道流出的絮体直接注入土工布袋中进行沉降过滤,过滤出的清水直接排出。本发明利用管道二级絮凝技术,显著提高了泥浆颗粒粒径,脱水效率及脱水速度大大提高,同时脱水液符合环保要求;该技术具有处理时间短、能耗低和脱水液水质稳定的优势。

The invention relates to the technical field of bottom mud control, in particular to a method for quickly cleaning and dehydrating dredged bottom mud, which includes the steps of: cutting and stirring the river bank bottom mud by a cutter suction pump to form mud, and outputting the mud by pumping force ;Transport the output mud through the pipeline, and add low molecular weight cationic polymer to the first branch of the pipeline near the river bank to perform primary flocculation of the mud; add high molecular weight flocculation through the second branch near the end of the pipeline Secondary flocculation of the mud with the agent; connect the end of the pipe to the geotextile bag, so that the flocs flowing out of the pipe are directly injected into the geotextile bag for sedimentation and filtration, and the filtered water is directly discharged. The invention utilizes the pipeline secondary flocculation technology to significantly increase the particle size of the mud particles, greatly improve the dehydration efficiency and dehydration speed, and at the same time the dehydration liquid meets the requirements of environmental protection; the technology has the advantages of short processing time, low energy consumption and stable water quality of the dehydration liquid.

Description

一种用于疏浚底泥快速清洁脱水的方法A method for rapid cleaning and dehydration of dredged sediment

技术领域technical field

本发明涉及底泥治理技术领域,特别涉及一种用于疏浚底泥快速清洁脱水的方法。The invention relates to the technical field of bottom mud treatment, in particular to a method for rapid cleaning and dehydration of dredged bottom mud.

背景技术Background technique

底泥是水体环境各种污染物质的最终储存场所,是影响水环境质量状况的重要因素。随着全球社会经济快速发展,工业污水、生活污水大量排放,污水泵站溢流排放,导致底泥中污染物质不断富集,底泥污染越发严重。Sediment is the ultimate storage place for various pollutants in the water environment, and is an important factor affecting the quality of the water environment. With the rapid development of the global social economy, large quantities of industrial sewage and domestic sewage are discharged, and the overflow discharge of sewage pumping stations leads to the continuous enrichment of pollutants in the sediment, and the pollution of the sediment is becoming more and more serious.

河道清淤是防治底泥污染和河道治理的重要措施之一,是水环境综合治理中的重要一环。清淤过程中会产生大量高含水率泥浆,这些疏浚底泥体积庞大,沉降性能差,且污染成分复杂,具有严重的生态风险。如何实现泥水快速分离,并降低污染物对环境的危害,是目前疏浚底泥处理领域亟需解决的难题之一。River channel dredging is one of the important measures to prevent and control sediment pollution and river channel management, and is an important part of comprehensive water environment management. A large amount of high water content mud will be produced during the dredging process. These dredged sediments are bulky, have poor settlement performance, and have complex pollution components, which pose serious ecological risks. How to realize the rapid separation of mud and water and reduce the harm of pollutants to the environment is one of the problems that need to be solved urgently in the field of dredging sediment treatment.

目前疏浚底泥的处理方法主要为通过环保绞吸将底泥抽吸出并输送到固定的泥浆处理站进行后期处理。清淤出的泥浆需要通过管道长距离输送,增加了输送成本,同时专门的泥浆处理站存在处理时间相对长、占地面积相对较大、设备投资占比大等不足。At present, the treatment method of dredging bottom sludge is mainly to suck out the bottom sludge through environmental protection cutter suction and transport it to a fixed mud treatment station for post-processing. The mud from dredging needs to be transported through long-distance pipelines, which increases the transportation cost. At the same time, the special mud treatment station has the disadvantages of relatively long processing time, relatively large floor area, and large proportion of equipment investment.

清淤出的泥浆沉降性能差,难以在自然条件下实现泥水分离,通常采用添加化学助滤药剂的方式提高泥水分离效果。现有的助滤药剂调理疏浚底泥时,药剂与泥浆所形成的絮体颗粒粒度较小,在过滤时易堵塞过滤介质和滤饼的空隙,导致机械脱水效率较低。此外,现有药剂处理后脱水液仍存在污染,需要专门的余水处理环节,大大增加了处理的成本和操作难度。The sedimentation performance of the dredged mud is poor, and it is difficult to achieve mud-water separation under natural conditions. The method of adding chemical filter aids is usually used to improve the mud-water separation effect. When the existing filter aids are used to condition the dredged sediment, the flocs formed by the agents and the mud have a small particle size, which easily blocks the gaps between the filter medium and the filter cake during filtration, resulting in low mechanical dehydration efficiency. In addition, the dehydration liquid is still polluted after the existing chemical treatment, and a special residual water treatment link is required, which greatly increases the cost of treatment and the difficulty of operation.

因此,现有技术还有待于改进和发展。Therefore, the prior art still needs to be improved and developed.

发明内容Contents of the invention

鉴于上述现有技术的不足,本发明的目的在于提供一种用于疏浚底泥快速清洁脱水的方法,以提升疏浚底泥脱水效率,缩短处理周期,提高余水水质。In view of the above deficiencies in the prior art, the purpose of the present invention is to provide a method for rapid cleaning and dehydration of dredged sediment, so as to improve the dehydration efficiency of dredged sediment, shorten the treatment cycle, and improve the quality of residual water.

本发明的技术方案如下:Technical scheme of the present invention is as follows:

一种用于疏浚底泥快速清洁脱水的方法,其中,包括步骤:A method for rapid cleaning and dehydration of dredged sediment, comprising the steps of:

通过绞吸泵对河岸底泥进行切割、搅动形成泥浆,并通过泵力将泥浆输出;Cutting and agitating the river bank bottom mud by cutter suction pump to form mud, and output the mud by pump force;

将输出的泥浆通过管道运输,在靠近河岸的管道上通过第一支路投加低分子量阳离子聚合物对泥浆进行一级絮凝,所述低分子量阳离子聚合物为聚电解质和多糖-甜菜碱阳离子聚合物的一种或多种;The output mud is transported through pipelines, and low molecular weight cationic polymers are added to the first branch of the pipeline near the river bank to perform primary flocculation of the mud. The low molecular weight cationic polymers are polyelectrolyte and polysaccharide-betaine cationic polymerization one or more of the

在靠近管道末端的位置通过第二支路投加高分子量絮凝剂对泥浆进行二级絮凝,所述高分子量絮凝剂为阳离子聚丙烯酰胺、阴离子聚丙烯酰胺和非离子型聚丙烯酰胺中的一种或多种;At the position close to the end of the pipeline, a high molecular weight flocculant is added through the second branch to carry out secondary flocculation of the mud, and the high molecular weight flocculant is one of cationic polyacrylamide, anionic polyacrylamide and nonionic polyacrylamide one or more kinds;

将管道的末端与土工布袋相连,使从管道流出的絮体直接注入土工布袋中进行沉降过滤,过滤出的清水直接排出。Connect the end of the pipe to the geotextile bag, so that the floc flowing out of the pipe is directly injected into the geotextile bag for sedimentation and filtration, and the filtered water is directly discharged.

所述用于疏浚底泥快速清洁脱水的方法,其中,所述低分子量阳离子聚合物的分子量小于28万。The method for rapid cleaning and dehydration of dredged sediment, wherein the molecular weight of the low molecular weight cationic polymer is less than 280,000.

所述用于疏浚底泥快速清洁脱水的方法,其中,所述低分子量阳离子聚合物的投加量为0.3-1.2g/kg。The method for rapid cleaning and dehydration of dredged sediment, wherein, the dosage of the low molecular weight cationic polymer is 0.3-1.2g/kg.

所述用于疏浚底泥快速清洁脱水的方法,其中,所述高分子量絮凝剂的分子量大于800万。The method for rapid cleaning and dehydration of dredged sediment, wherein the molecular weight of the high molecular weight flocculant is greater than 8 million.

所述用于疏浚底泥快速清洁脱水的方法,其中,所述高分子量絮凝剂的投加量为0.2-0.8g/kg。The method for rapid cleaning and dehydration of dredged sediment, wherein, the dosage of the high molecular weight flocculant is 0.2-0.8g/kg.

所述用于疏浚底泥快速清洁脱水的方法,其中,所述聚电解质为以二甲基二烯丙基氯化铵、甲基丙烯酰氧乙基三甲基氯化铵、丙烯酰胺氧乙基二甲基苄基氯化铵中的一种或多种为单体,通过均聚或共聚合得到的阳离子型聚合物;所述多糖-甜菜碱阳离子聚合物为以壳聚糖或淀粉为母体,通过与无水甜菜碱和甜菜碱酸盐中的至少一种发生酯化反应后得到的聚合物。The method for rapid cleaning and dehydration of dredged sediment, wherein the polyelectrolyte is based on dimethyl diallyl ammonium chloride, methacryloyloxyethyltrimethylammonium chloride, acrylamide oxyethylene One or more of the base dimethyl benzyl ammonium chloride is a monomer, a cationic polymer obtained by homopolymerization or copolymerization; the polysaccharide-betaine cationic polymer is based on chitosan or starch The matrix is a polymer obtained through an esterification reaction with at least one of anhydrous betaine and betaine acid salt.

所述用于疏浚底泥快速清洁脱水的方法,其中,所述第一支路到第二支路的距离设为S1,所述第二支路到管道末端的距离设为S2,所述S1和S2满足如下条件:The method for rapid cleaning and dehydration of dredged sediment, wherein, the distance from the first branch to the second branch is set as S 1 , and the distance from the second branch to the end of the pipeline is set as S 2 , so The above S1 and S2 meet the following conditions:

S1=S1混合+S1反应,其中,S1混合为低分子量阳离子聚合物与泥浆充分混合时间内管道泥浆流动的距离,S1反应为低分子量阳离子聚合物与泥浆进行絮凝反应时间内管道泥浆流动的距离;S 1 = S 1 mixing + S 1 reaction , wherein, S 1 mixing is the distance of pipeline mud flow within the time of sufficient mixing of low molecular weight cationic polymer and mud, and S 1 reaction is the flocculation reaction time of low molecular weight cationic polymer and mud The distance the pipeline mud flows;

S2=S2混合+S2反应,其中,S2混合为高分子量絮凝剂与泥浆充分混合时间内管道泥浆流动的距离,S2反应为高分子量絮凝剂与泥浆进行絮凝反应时间内管道泥浆流动的距离。S 2 = S 2 mixing + S 2 reaction , wherein, S 2 mixing is the distance of pipeline mud flow within the time when the high molecular weight flocculant and mud are fully mixed, and S 2 reaction is the pipeline mud within the flocculation reaction time of high molecular weight flocculant and mud flow distance.

所述用于疏浚底泥快速清洁脱水的方法,其中,泥浆经过S1的距离所需的时间为1-10min;泥浆经过S2的距离所需的时间为30s-5min。The method for rapid cleaning and dehydration of dredging bottom mud, wherein the time required for the mud to pass the distance of S1 is 1-10 minutes; the time required for the mud to pass the distance of S2 is 30s-5 minutes.

所述用于疏浚底泥快速清洁脱水的方法,其中,所述低分子量阳离子聚合物的质量浓度为0.1-1wt%,所述高分子量絮凝剂的质量浓度为0.1-0.3wt%。The method for rapid cleaning and dehydration of dredged sediment, wherein, the mass concentration of the low molecular weight cationic polymer is 0.1-1 wt%, and the mass concentration of the high molecular weight flocculant is 0.1-0.3 wt%.

所述用于疏浚底泥快速清洁脱水的方法,其中,所述土工布袋的等效孔径O95为0.5mm,渗透性Q50为25l/m2/s,宽条抗拉强度为90kN/m。The method for rapid cleaning and dehydration of dredged sediment, wherein the geotextile bag has an equivalent aperture O 95 of 0.5 mm, a permeability Q 50 of 25 l/m 2 /s, and a wide strip tensile strength of 90 kN/m .

有益效果:本发明提出的用于疏浚底泥快速清洁脱水的处理方法,利用管道二级絮凝技术,显著提高了泥浆颗粒粒径,脱水效率及脱水速度大大提高,同时脱水液符合环保要求。该技术具有处理时间短、现场可操作性强、设备费用低、能耗低和脱水液水质稳定的优势,在疏浚底泥脱水领域具有广阔的应用前景。Beneficial effects: The treatment method for rapid cleaning and dehydration of dredged sediment proposed by the present invention uses pipeline secondary flocculation technology to significantly increase the particle size of mud particles, greatly improve dehydration efficiency and dehydration speed, and at the same time, the dehydration liquid meets environmental protection requirements. This technology has the advantages of short processing time, strong on-site operability, low equipment cost, low energy consumption and stable water quality of dehydration liquid, and has broad application prospects in the field of dredging sediment dewatering.

附图说明Description of drawings

图1为本发明提供的一种用于疏浚底泥快速清洁脱水的方法流程图。Fig. 1 is a flow chart of a method for rapid cleaning and dehydration of dredged sediment provided by the present invention.

具体实施方式Detailed ways

本发明提供一种用于疏浚底泥快速清洁脱水的方法,为使本发明的目的、技术方案及效果更加清楚、明确,以下对本发明进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。The present invention provides a method for rapid cleaning and dehydration of dredged sediment. In order to make the purpose, technical solution and effect of the present invention clearer and clearer, the present invention will be further described in detail below. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.

请参阅图1,图1为本发明提供的一种用于疏浚底泥快速清洁脱水的方法流程图,如图所示,其包括步骤:Please refer to Fig. 1, Fig. 1 is a kind of flow chart of the method for dredging sediment fast cleaning dehydration provided by the present invention, as shown in the figure, it comprises steps:

S10、通过绞吸泵对河岸底泥进行切割、搅动形成泥浆,并通过泵力将泥浆输出;S10, cutting and agitating the bottom mud of the river bank through the cutter suction pump to form mud, and outputting the mud through pump force;

S20、将输出的泥浆通过管道运输,在靠近河岸的管道上通过第一支路投加低分子量阳离子聚合物对泥浆进行一级絮凝,所述低分子量阳离子聚合物为聚电解质和多糖-甜菜碱阳离子聚合物的一种或多种;S20, transport the output mud through the pipeline, and add low molecular weight cationic polymer to the first branch on the pipeline close to the river bank to perform primary flocculation of the mud, and the low molecular weight cationic polymer is polyelectrolyte and polysaccharide-betaine one or more cationic polymers;

S30、在靠近管道末端的位置通过第二支路投加高分子量絮凝剂对泥浆进行二级絮凝,所述高分子量絮凝剂为阳离子聚丙烯酰胺、阴离子聚丙烯酰胺和非离子型聚丙烯酰胺中的一种或多种;S30. Adding a high molecular weight flocculant at a position close to the end of the pipeline through the second branch to perform secondary flocculation of the mud. The high molecular weight flocculant is cationic polyacrylamide, anionic polyacrylamide and nonionic polyacrylamide one or more of

S40、将管道的末端与土工布袋相连,使从管道流出的絮体直接注入土工布袋中进行沉降过滤,过滤出的清水直接排出。S40. Connect the end of the pipe to the geotextile bag, so that the floc flowing out of the pipe is directly injected into the geotextile bag for sedimentation and filtration, and the filtered clear water is directly discharged.

具体来讲,本发明提出将泥浆的运输管道作为反应器,充分利用管道空间和水体流动产生的水力条件实现药剂对泥浆的调理,省去了后续加药混合反应过程,减少占地,节约处理时间;本发明还提出了管道二级絮凝技术,其包括低分子量阳离子聚合物的一级絮凝过程和高分子量絮凝剂的二级絮凝过程,与现有技术相比,本发明形成的絮体颗粒粒度增大了1.5-7倍,极大提高后续机械脱水效率,土工布袋过滤脱水速度可提高2-100倍,本发明技术中微絮体的产生是核心,即在一级絮凝过程中,低分子量阳离子聚合物通过电中和、弱架桥作用与泥浆形成悬浮的微絮体,该微絮体与高分子量的絮凝剂进一步发生二级絮凝过程,絮体间碰撞、聚集成团,迅速成长为粒径为50-300μm的粗大絮体;本发明提出的管道二级絮凝技术还可将水中污染物一起卷扫于微絮体内或吸附于微絮体表面以及微絮体所聚集形成的大聚集体内或吸附于大聚集体表面,可实现对水中细颗粒以及溶解性污染物的高效捕捉,与现有技术相比,该技术处理后无需再进行尾水处理,脱水液水质清澈,COD低于40mg/L,实现清洁脱水。Specifically, the present invention proposes to use the mud transportation pipeline as a reactor, and make full use of the pipeline space and the hydraulic conditions generated by the flow of water to realize the conditioning of the mud by medicines, eliminating the need for subsequent dosing and mixing reaction processes, reducing land occupation, and saving treatment Time; the present invention also proposes pipeline secondary flocculation technology, which includes the primary flocculation process of low-molecular-weight cationic polymers and the secondary flocculation process of high-molecular-weight flocculants. Compared with the prior art, the floc particles formed by the present invention The particle size is increased by 1.5-7 times, which greatly improves the subsequent mechanical dehydration efficiency, and the geotextile bag filtration and dehydration speed can be increased by 2-100 times. Molecular weight cationic polymers form suspended micro-flocs with mud through electrical neutralization and weak bridging. The micro-flocs and high-molecular-weight flocculants further undergo a secondary flocculation process, and the flocs collide and aggregate into groups and grow rapidly. It is a coarse floc with a particle size of 50-300 μm; the pipeline secondary flocculation technology proposed by the present invention can also sweep the pollutants in the water together into the microfloc or adsorb on the surface of the microfloc and the large floc formed by the aggregation of the microfloc In the aggregate or adsorbed on the surface of large aggregates, it can realize the efficient capture of fine particles and dissolved pollutants in water. Compared with the existing technology, this technology does not need to carry out tail water treatment after treatment, and the water quality of the dehydration liquid is clear and the COD is low. At 40mg/L, to achieve clean dehydration.

本发明提供的用于疏浚底泥快速清洁脱水的方法,脱水效率高,处理时间短,现场可操作性强,对过滤设备要求低,而且脱水液水质稳定,符合环保要求,在疏浚底泥脱水领域具有广阔的应用前景。The method for rapid cleaning and dehydration of dredged sediment provided by the present invention has high dehydration efficiency, short processing time, strong on-site operability, low requirements for filtering equipment, stable water quality of dehydration liquid, and meets environmental protection requirements. The field has broad application prospects.

在一些实施方式中,所述低分子量阳离子聚合物的分子量小于28万,所述低分子量阳离子聚合物的投加量为0.3-1.2g/kg。In some embodiments, the molecular weight of the low molecular weight cationic polymer is less than 280,000, and the dosage of the low molecular weight cationic polymer is 0.3-1.2 g/kg.

在本实施例中,分子量小于28万的低分子量阳离子聚合物可通过电中和、弱架桥作用与泥浆形成悬浮的微絮体,所述微絮体可将水中污染物进行吸附至其表面,从而可实现对泥浆水中细颗粒以及溶解性污染物的高效捕捉,即实现泥浆清洁脱水。在本实施例中,每1kg的泥浆中只需要投加0.3-1.2g的低分子量阳离子聚合物,就可完成泥浆的一级絮凝过程。In this example, the low-molecular-weight cationic polymer with a molecular weight of less than 280,000 can form suspended microflocs with mud through electrical neutralization and weak bridging, and the microflocs can adsorb pollutants in water to their surfaces , so that the efficient capture of fine particles and dissolved pollutants in mud water can be realized, that is, mud cleaning and dehydration can be realized. In this embodiment, only 0.3-1.2 g of low molecular weight cationic polymer needs to be added per 1 kg of mud to complete the first-stage flocculation process of the mud.

在一些实施方式中,所述低分子量阳离子聚合物为聚电解质和多糖-甜菜碱阳离子聚合物的一种或多种,其中,聚电解质为以二甲基二烯丙基氯化铵、甲基丙烯酰氧乙基三甲基氯化铵、丙烯酰胺氧乙基二甲基苄基氯化铵中的一种或多种为单体,通过均聚或共聚合得到的阳离子型聚合物;所述多糖-甜菜碱阳离子聚合物为以壳聚糖或淀粉为母体,通过与无水甜菜碱和甜菜碱酸盐中的至少一种发生酯化反应后得到的聚合物。In some embodiments, the low molecular weight cationic polymer is one or more of polyelectrolyte and polysaccharide-betaine cationic polymer, wherein the polyelectrolyte is based on dimethyl diallyl ammonium chloride, methyl One or more of acryloyloxyethyltrimethylammonium chloride and acrylamideoxyethyldimethylbenzylammonium chloride is a cationic polymer obtained by homopolymerization or copolymerization; The polysaccharide-betaine cationic polymer is a polymer obtained through esterification with at least one of anhydrous betaine and betaine acid salt, taking chitosan or starch as a matrix.

在一些实施方式中,所述高分子量絮凝剂的分子量大于800万,所述高分子量絮凝剂的投加量为0.2-0.8g/kg。In some embodiments, the molecular weight of the high molecular weight flocculant is greater than 8 million, and the dosage of the high molecular weight flocculant is 0.2-0.8 g/kg.

在本实施例中,分子量大于800万的高分子量絮凝剂可以与经过一级絮凝得到的微絮体进一步发生二级絮凝过程,微絮体间相互碰撞、聚集成团,迅速成长为粒径为50-300μm的粗大絮体。本实施例形成的絮体颗粒粒度相对微絮体增大了1.5-7倍,可极大提高后续机械脱水效率,布袋过滤脱水速度可提高2-100倍。在本实施例中,每1kg的泥浆中只需要投加0.2-0.8g的高分子量絮凝剂,就可完成泥浆的二级絮凝过程。In this example, the high-molecular-weight flocculant with a molecular weight greater than 8 million can further undergo a secondary flocculation process with the microflocs obtained through primary flocculation. Coarse flocs of 50-300μm. The particle size of the flocs formed in this embodiment is 1.5-7 times larger than that of the microflocs, which can greatly improve the efficiency of subsequent mechanical dehydration, and the dehydration speed of bag filtration can be increased by 2-100 times. In this embodiment, only 0.2-0.8 g of high molecular weight flocculant needs to be added per 1 kg of mud to complete the secondary flocculation process of mud.

在一些实施方式中,所述第一支路到第二支路的距离设为S1,所述第二支路到管道末端的距离设为S2,所述S1和S2满足如下条件:S1=S1混合+S1反应,其中,S1混合为低分子量阳离子聚合物与泥浆充分混合时间内管道泥浆流动的距离,S1反应为低分子量阳离子聚合物与泥浆进行絮凝反应时间内管道泥浆流动的距离;S2=S2混合+S2反应,其中,S2混合为高分子量絮凝剂与泥浆充分混合时间内管道泥浆流动的距离,S2反应为高分子量絮凝剂与泥浆进行絮凝反应时间内管道泥浆流动的距离。In some embodiments, the distance from the first branch to the second branch is set as S 1 , the distance from the second branch to the end of the pipeline is set as S 2 , and the S 1 and S 2 satisfy the following conditions : S 1 = S 1 mixing +S 1 reaction , wherein, S 1 mixing is the distance of pipeline mud flow in the time of sufficient mixing of low molecular weight cationic polymer and mud, and S 1 reaction is the flocculation reaction time of low molecular weight cationic polymer and mud The distance of mud flow in the inner pipeline; S 2 = S 2 mixing + S 2 reaction , wherein, S 2 mixing is the distance of pipeline mud flow within the time when the high molecular weight flocculant and mud are fully mixed, and S 2 reaction is the high molecular weight flocculant and mud flow distance The distance that pipeline mud flows during the flocculation reaction time.

在本实施例中,泥浆在管道中的流速V1固定,当泥浆经过S1的距离所耗时间t1为1-10min,则S1的距离=V1*t1,S1的距离应当满足泥浆与低分子量阳离子聚合物充分混合并完成一级絮凝反应;当泥浆经过S2的距离所耗时间t2为30s-5min,则S2的距离=V1*t2,S2的距离应当满足泥浆与高分子量絮凝剂充分混合并完成二级絮凝反应。In this embodiment, the flow velocity V 1 of the mud in the pipeline is fixed, and when the time t 1 that the mud passes through the distance of S 1 is 1-10min, then the distance of S 1 =V 1 *t 1 , the distance of S 1 should be Satisfied that the mud and the low molecular weight cationic polymer are fully mixed and complete the first-order flocculation reaction; when the time t 2 for the mud to pass through the distance of S 2 is 30s-5min, then the distance of S 2 = V 1 *t 2 , the distance of S 2 It should be satisfied that the mud and the high molecular weight flocculant are fully mixed and the secondary flocculation reaction is completed.

在一些实施方式中,所述低分子量阳离子聚合物的质量浓度为0.1-1wt%,所述高分子量絮凝剂的质量浓度为0.1-0.3wt%。In some embodiments, the mass concentration of the low molecular weight cationic polymer is 0.1-1 wt%, and the mass concentration of the high molecular weight flocculant is 0.1-0.3 wt%.

在一些实施方式中,所述土工布袋的等效孔径O95为0.5mm,渗透性Q50为25l/m2/s,宽条抗拉强度为90kN/m。采用本实施例选定参数的土工布袋能够对絮体进行有效脱水,所述土工布袋的过滤脱水速度可提高2-100倍。In some embodiments, the geotextile bag has an equivalent pore diameter O 95 of 0.5 mm, a permeability Q 50 of 25 l/m 2 /s, and a strip tensile strength of 90 kN/m. The geotextile bag with selected parameters in this embodiment can effectively dehydrate the flocs, and the filtration and dehydration speed of the geotextile bag can be increased by 2-100 times.

下面通过具体实施例对本发明做进一步的解释说明:The present invention is further explained below by specific embodiment:

实施例1Example 1

本实施例中采样的疏浚底泥为马鞍山洋河底泥,具体清洁脱水处理流程如下:The dredged sediment sampled in this example is the sediment of the Yanghe River in Ma'anshan. The specific cleaning and dehydration process is as follows:

S1-绞吸:通过绞吸泵从河底吸取底泥,管道直径0.2m,管道流速1.10m/s;S1-cutter suction: suck the sediment from the bottom of the river through the cutter suction pump, the diameter of the pipeline is 0.2m, and the flow rate of the pipeline is 1.10m/s;

S2-管道一级絮凝:步骤S1中输送出的泥浆含水率约为95%,通过加药泵将分子量为11.3万的聚二甲基二烯丙基氯化铵水溶液(1wt%)泵入管道,投加量为0.3g/kg,该段传输距离为70米,此时聚二甲基二烯丙基氯化铵通过电中和、弱架桥作用与泥浆形成悬浮的微絮体;S2-Pipeline primary flocculation: the moisture content of the mud delivered in step S1 is about 95%, and the polydimethyldiallylammonium chloride aqueous solution (1wt%) with a molecular weight of 113,000 is pumped into the pipeline through a dosing pump , the dosage is 0.3g/kg, and the transmission distance in this section is 70 meters. At this time, polydimethyldiallylammonium chloride forms suspended microflocs with the mud through electrical neutralization and weak bridging;

S3-管道二级絮凝:通过加药泵将分子量为1000万的阴离子型聚丙烯酰胺水溶液(0.3wt%)泵入管道,投加量为0.25g/kg,该段传输距离为30米,此时微絮体与高分子量的阴离子型聚丙烯酰胺发生二级絮凝过程,絮体间碰撞、聚集成团,迅速成长为粒径为50-300μm的粗大絮体;S3-Pipeline secondary flocculation: pump an anionic polyacrylamide aqueous solution (0.3wt%) with a molecular weight of 10 million into the pipeline through a dosing pump, the dosage is 0.25g/kg, and the transmission distance of this section is 30 meters. When micro-flocs and high-molecular-weight anionic polyacrylamide undergo a secondary flocculation process, the flocs collide and aggregate into clusters, and rapidly grow into coarse flocs with a particle size of 50-300 μm;

S4-管道末端与土工布袋相连,土工布袋为等效孔径O95为0.5mm的聚丙烯编织布,总过滤面积为36m2,步骤S3中输出的粗大絮体流经土工布袋,将过滤后的水液水质清澈,COD低于40mg/L,可实现清洁脱水。S4-pipe end is connected with geotextile bag, and geotextile bag is the polypropylene woven cloth of 0.5mm for equivalent aperture O95, and total filter area is 36m 2 , the coarse floc of output in step S3 flows through geotextile bag, filter after The water quality is clear, and the COD is lower than 40mg/L, which can realize clean dehydration.

实施例2Example 2

本实施例中采样的疏浚底泥为马鞍山洋河底泥,具体清洁脱水处理流程如下:The dredged sediment sampled in this example is the sediment of the Yanghe River in Ma'anshan. The specific cleaning and dehydration process is as follows:

S1-绞吸:通过绞吸泵从河底吸取底泥,管道直径0.2m,管道流速1.10m/s;S1-cutter suction: suck the sediment from the bottom of the river through the cutter suction pump, the diameter of the pipeline is 0.2m, and the flow rate of the pipeline is 1.10m/s;

S2-管道一级絮凝:步骤S1中输送出的泥浆含水率约为95%,通过加药泵将分子量为11.3万的聚二甲基二烯丙基氯化铵水溶液(1wt%),药剂投加量为0.75g/kg,该段传输距离为70米,此时聚二甲基二烯丙基氯化铵通过电中和、弱架桥作用与泥浆形成悬浮的微絮体;S2-Pipeline primary flocculation: the moisture content of the mud delivered in step S1 is about 95%, and the polydimethyldiallyl ammonium chloride aqueous solution (1wt%) with a molecular weight of 113,000 is injected by the dosing pump The dosage is 0.75g/kg, and the transmission distance in this section is 70 meters. At this time, polydimethyldiallylammonium chloride forms suspended microflocs with the mud through electrical neutralization and weak bridging;

S3-管道二级絮凝:通过加药泵将分子量为1000万的阴离子型聚丙烯酰胺水溶液(0.3wt%)泵入管道,投加量为0.25g/kg,该段传输距离为30米,此时微絮体与高分子量的阴离子型聚丙烯酰胺发生二级絮凝过程,絮体间碰撞、聚集成团,迅速成长为粒径为50-300μm的粗大絮体;S3-Pipeline secondary flocculation: pump an anionic polyacrylamide aqueous solution (0.3wt%) with a molecular weight of 10 million into the pipeline through a dosing pump, the dosage is 0.25g/kg, and the transmission distance of this section is 30 meters. When micro-flocs and high-molecular-weight anionic polyacrylamide undergo a secondary flocculation process, the flocs collide and aggregate into clusters, and rapidly grow into coarse flocs with a particle size of 50-300 μm;

S4-管道末端与土工布袋相连,土工布袋为等效孔径O95为0.5mm的聚丙烯编织布,步骤S3中输出的粗大絮体流经土工布袋,将过滤后的水液水质清澈,COD低于40mg/L,可实现清洁脱水。S4-pipe end is connected with geotextile bag, and geotextile bag is the polypropylene woven cloth of 0.5mm for equivalent aperture O95, and the coarse floc of output in step S3 flows through geotextile bag, and the aqueous liquid water quality after filtering is clear, and COD is low At 40mg/L, clean dehydration can be achieved.

实施例3Example 3

本实施例中采样的疏浚底泥为马鞍山洋河底泥,具体清洁脱水处理流程如下:The dredged sediment sampled in this example is the sediment of the Yanghe River in Ma'anshan. The specific cleaning and dehydration process is as follows:

S1-绞吸:通过绞吸泵从河底吸取底泥,管道直径0.2m,管道流速1.10m/s;S1-cutter suction: suck the sediment from the bottom of the river through the cutter suction pump, the diameter of the pipeline is 0.2m, and the flow rate of the pipeline is 1.10m/s;

S2-管道一级絮凝:步骤S1中输送出的泥浆含水率约为95%,通过加药泵将分子量为11.3万的聚二甲基二烯丙基氯化铵水溶液(1wt%),药剂投加量为1.2g/kg,该段传输距离为70米,此时聚二甲基二烯丙基氯化铵通过电中和、弱架桥作用与泥浆形成悬浮的微絮体;S2-Pipeline primary flocculation: the moisture content of the mud delivered in step S1 is about 95%, and the polydimethyldiallyl ammonium chloride aqueous solution (1wt%) with a molecular weight of 113,000 is injected by the dosing pump The dosage is 1.2g/kg, and the transmission distance in this section is 70 meters. At this time, polydimethyldiallylammonium chloride forms suspended microflocs with the mud through electrical neutralization and weak bridging;

S3-管道二级絮凝:通过加药泵将分子量为1000万的阴离子型聚丙烯酰胺水溶液(0.3wt%)泵入管道,投加量为0.25g/kg,该段传输距离为30米,此时微絮体与高分子量的阴离子型聚丙烯酰胺发生二级絮凝过程,絮体间碰撞、聚集成团,迅速成长为粒径为50-300μm的粗大絮体;S3-Pipeline secondary flocculation: pump an anionic polyacrylamide aqueous solution (0.3wt%) with a molecular weight of 10 million into the pipeline through a dosing pump, the dosage is 0.25g/kg, and the transmission distance of this section is 30 meters. When micro-flocs and high-molecular-weight anionic polyacrylamide undergo a secondary flocculation process, the flocs collide and aggregate into clusters, and rapidly grow into coarse flocs with a particle size of 50-300 μm;

S4-管道末端与土工布袋相连,土工布袋为等效孔径O95为0.5mm的聚丙烯编织布,步骤S3中输出的粗大絮体流经土工布袋,将过滤后的水液水质清澈,COD低于40mg/L,可实现清洁脱水。S4-pipe end is connected with geotextile bag, and geotextile bag is the polypropylene woven cloth of 0.5mm for equivalent aperture O95, and the coarse floc of output in step S3 flows through geotextile bag, and the aqueous liquid water quality after filtering is clear, and COD is low At 40mg/L, clean dehydration can be achieved.

实施例4Example 4

本实施例中采样的疏浚底泥为马鞍山洋河底泥,具体清洁脱水处理流程如下:The dredged sediment sampled in this example is the sediment of the Yanghe River in Ma'anshan. The specific cleaning and dehydration process is as follows:

S1-绞吸:通过绞吸泵从河底吸取底泥,管道直径0.2m,管道流速1.10m/s;S1-cutter suction: suck the sediment from the bottom of the river through the cutter suction pump, the diameter of the pipeline is 0.2m, and the flow rate of the pipeline is 1.10m/s;

S2-管道一级絮凝:步骤S1中输送出的泥浆含水率约为95%,通过加药泵将分子量为27.8万的淀粉-甜菜碱阳离子聚合物水溶液(0.6wt%),药剂为投加量为0.75g/kg,该段传输距离为70米,此时聚二甲基二烯丙基氯化铵通过电中和、弱架桥作用与泥浆形成悬浮的微絮体;S2-Pipeline primary flocculation: the moisture content of the mud delivered in step S1 is about 95%, and the starch-betaine cationic polymer aqueous solution (0.6wt%) with a molecular weight of 278,000 is added by the dosing pump, and the dosage is It is 0.75g/kg, and the transmission distance of this section is 70 meters. At this time, polydimethyldiallylammonium chloride forms suspended microflocs with mud through electrical neutralization and weak bridging;

S3-管道二级絮凝:通过加药泵将分子量为1000万的阴离子型聚丙烯酰胺水溶液(0.3wt%)泵入管道,投加量为0.25g/kg,该段传输距离为30米,此时微絮体与高分子量的阴离子型聚丙烯酰胺发生二级絮凝过程,絮体间碰撞、聚集成团,迅速成长为粒径为50-300μm的粗大絮体;S3-Pipeline secondary flocculation: pump an anionic polyacrylamide aqueous solution (0.3wt%) with a molecular weight of 10 million into the pipeline through a dosing pump, the dosage is 0.25g/kg, and the transmission distance of this section is 30 meters. When micro-flocs and high-molecular-weight anionic polyacrylamide undergo a secondary flocculation process, the flocs collide and aggregate into clusters, and rapidly grow into coarse flocs with a particle size of 50-300 μm;

S4-管道末端与土工布袋相连,土工布袋为等效孔径O95为0.5mm的聚丙烯编织布,步骤S3中输出的粗大絮体流经土工布袋,将过滤后的水液水质清澈,COD低于40mg/L,可实现清洁脱水。S4-pipe end is connected with geotextile bag, and geotextile bag is the polypropylene woven cloth of 0.5mm for equivalent aperture O95, and the coarse floc of output in step S3 flows through geotextile bag, and the aqueous liquid water quality after filtering is clear, and COD is low At 40mg/L, clean dehydration can be achieved.

对比例1Comparative example 1

本对比例1中采样的疏浚底泥为马鞍山洋河底泥,具体清洁脱水处理流程如下:对比例1在S-2管道一级絮凝投加的药剂和用量为空白,其他阶段过程同实施例2。The dredging bottom mud sampled in this comparative example 1 is the bottom mud of Ma'anshan Yanghe River, and the specific cleaning and dehydration treatment process is as follows: the medicament and dosage added in the first-level flocculation of the S-2 pipeline in comparative example 1 are blank, and the process of other stages is the same as that of the embodiment 2.

对比例2Comparative example 2

本对比例1中采样的疏浚底泥为马鞍山洋河底泥,具体清洁脱水处理流程如下:对比例2在S-3管道一级絮凝投加的药剂和用量为空白,其他阶段过程同实施例2。The dredged bottom mud sampled in this comparative example 1 is the bottom mud of Ma'anshan Yanghe River, and the specific cleaning and dehydration treatment process is as follows: the chemical agent and dosage added in the first-level flocculation of the S-3 pipeline in comparative example 2 are blank, and the process of other stages is the same as that of the embodiment 2.

对实施例1-4以及对比例1-2中的马鞍山洋河底泥清洁脱水过程进行性能评估,结果如表1所示。The performance evaluation of the cleaning and dewatering process of the Yanghe river sediment in Ma'anshan in Examples 1-4 and Comparative Examples 1-2 is shown in Table 1.

表1测试结果Table 1 Test results

从表1结果可以看出,本发明实施例1-4的过滤速度相比对比例1-2提高了10-100倍,且透过滤布的颗粒质量微乎其微。相比之下,对比例1-2的透过的颗粒质量较多,过滤效率较低。It can be seen from the results in Table 1 that the filtration speed of Example 1-4 of the present invention is 10-100 times higher than that of Comparative Example 1-2, and the quality of particles passing through the filter cloth is negligible. In contrast, Comparative Example 1-2 has a higher particle mass and a lower filtration efficiency.

造成过滤脱水速度差距较大的原因是本技术采用的二级絮凝工艺,利用电荷密度高而分子量相对较低的聚电解质或多糖-甜菜碱阳离子聚合物先与泥浆细颗粒形成微小絮体,该微絮体与高分子量的絮凝剂进一步絮凝架桥、网捕迅速成长为粗大絮体。由于絮体颗粒粗大,在过滤初始阶段迅速在滤布的网孔中形成滤饼层,且滤饼层孔隙率高,大量的水可以迅速通过滤饼层。而现有技术调理得到的絮团粒度小,在过滤时堵塞滤布以及滤饼层中的空隙,导致脱水速度缓慢。此外,实施例1-4的滤液的浊度和COD都较小,滤液清澈,而对比例1的滤液则相对较脏,对比例2虽然滤液较干净,但由于过滤初期透过的泥浆颗粒过多,这些透过的泥浆仍需回流处理,脱水效率降低。The reason for the large difference in filtration and dehydration speed is that the two-stage flocculation process adopted by this technology uses polyelectrolyte or polysaccharide-betaine cationic polymer with high charge density and relatively low molecular weight to form tiny flocs with mud fine particles first. The micro flocs and high molecular weight flocculants further flocculate and bridge, and the nets quickly grow into coarse flocs. Due to the coarse floc particles, a filter cake layer is quickly formed in the mesh of the filter cloth at the initial stage of filtration, and the filter cake layer has a high porosity, and a large amount of water can quickly pass through the filter cake layer. However, the particle size of the flocs obtained by conditioning in the prior art is small, which blocks the gaps in the filter cloth and the filter cake layer during filtration, resulting in a slow dehydration rate. In addition, the turbidity and COD of the filtrate of Examples 1-4 are all small, and the filtrate is clear, while the filtrate of Comparative Example 1 is relatively dirty. If there are too many, the permeated mud still needs to be refluxed, and the dehydration efficiency will be reduced.

应当理解的是,本发明的应用不限于上述的举例,对本领域普通技术人员来说,可以根据上述说明加以改进或变换,所有这些改进和变换都应属于本发明所附权利要求的保护范围。It should be understood that the application of the present invention is not limited to the above examples, and those skilled in the art can make improvements or changes according to the above descriptions, and all these improvements and changes should belong to the scope of protection of the appended claims of the present invention.

Claims (10)

1. A method for rapid clean dewatering of dredging substrate sludge, comprising the steps of:
cutting and stirring river bank sediment by a cutter suction pump to form mud, and outputting the mud by pump force;
transporting the output slurry through a pipeline, and adding a low molecular weight cationic polymer to perform primary flocculation on the slurry through a first branch on the pipeline close to the river bank, wherein the low molecular weight cationic polymer is one or more of polyelectrolyte and polysaccharide-betaine cationic polymer;
the method comprises the steps of (1) performing secondary flocculation on slurry at a position close to the tail end of a pipeline by adding a high molecular weight flocculant through a second branch, wherein the high molecular weight flocculant is one or more of cationic polyacrylamide, anionic polyacrylamide and nonionic polyacrylamide;
and connecting the tail end of the pipeline with the geotechnical cloth bag, directly injecting the flocs flowing out of the pipeline into the geotechnical cloth bag for sedimentation and filtration, and directly discharging the filtered clear water.
2. The method for rapid clean dewatering of dredging substrate sludge according to claim 1, wherein the low molecular weight cationic polymer has a molecular weight of less than 28 tens of thousands.
3. Method for rapid clean dewatering of dredging substrate sludge according to claim 2, characterized in that the low molecular weight cationic polymer is added in an amount of 0.3-1.2g/kg.
4. The method for rapid clean dewatering of dredging substrate sludge according to claim 1, wherein the high molecular weight flocculant has a molecular weight greater than 800 ten thousand.
5. The method for rapid clean dewatering of dredging substrate sludge according to claim 4, wherein the high molecular weight flocculant is added in an amount of 0.2-0.8g/kg.
6. The method for rapid clean dewatering of dredging sediment according to claim 1, wherein the polyelectrolyte is a cationic polymer obtained by homo-or copolymerization with one or more of dimethyl diallyl ammonium chloride, methacryloyloxyethyl trimethyl ammonium chloride, acrylamide oxyethyl dimethyl benzyl ammonium chloride as monomers; the polysaccharide-betaine cationic polymer is prepared by taking chitosan or starch as a matrix and carrying out esterification reaction with at least one of anhydrous betaine and betaine acid salt.
7. Method for rapid clean dewatering of dredging substrate sludge according to claim 1, characterized in that the distance from the first branch to the second branch is set to S 1 The distance from the second branch to the tail end of the pipeline is S 2 The S is 1 And S is 2 The following conditions are satisfied:
S 1 =S 1 mixing +S 1 reaction Wherein S is 1 mixing Is the distance of the pipeline slurry flow within the time of fully mixing the low molecular weight cationic polymer and the slurry, S 1 reaction Is a low molecular weight cationic polymerizationThe distance of pipeline mud flow in the flocculation reaction time of the material and the mud;
S 2 =S 2 mixing +S 2 reaction Wherein S is 2 mixing S is the distance of pipeline slurry flow in the time of fully mixing the high molecular weight flocculant with the slurry 2 reaction Is the distance that the pipeline slurry flows in the flocculation reaction time of the high molecular weight flocculant and the slurry.
8. Method for rapid clean dewatering of dredging substrate sludge according to claim 7, characterized in that the sludge is subjected to S 1 The distance of (2) is 1-10min; mud passing S 2 The time required for the distance of (2) is 30s-5min.
9. The method for rapid clean dewatering of dredging substrate sludge according to claim 1, wherein the mass concentration of the low molecular weight cationic polymer is 0.1-1wt% and the mass concentration of the high molecular weight flocculant is 0.1-0.3wt%.
10. Method for rapid clean dewatering of dredging substrate sludge according to claim 1, characterized in that the geotechnical cloth bag has equivalent pore diameter O 95 0.5mm, permeability Q 50 25l/m 2 And/s, the tensile strength of the wide strip is 90kN/m.
CN202310693675.8A 2023-06-13 2023-06-13 Method for rapid cleaning and dehydration of dredging sediment Pending CN116621417A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310693675.8A CN116621417A (en) 2023-06-13 2023-06-13 Method for rapid cleaning and dehydration of dredging sediment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310693675.8A CN116621417A (en) 2023-06-13 2023-06-13 Method for rapid cleaning and dehydration of dredging sediment

Publications (1)

Publication Number Publication Date
CN116621417A true CN116621417A (en) 2023-08-22

Family

ID=87617045

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310693675.8A Pending CN116621417A (en) 2023-06-13 2023-06-13 Method for rapid cleaning and dehydration of dredging sediment

Country Status (1)

Country Link
CN (1) CN116621417A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119241025A (en) * 2024-10-15 2025-01-03 广西中科立地工程科技有限公司 A mobile geotube bag slurry dehydration and solidification treatment method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119241025A (en) * 2024-10-15 2025-01-03 广西中科立地工程科技有限公司 A mobile geotube bag slurry dehydration and solidification treatment method

Similar Documents

Publication Publication Date Title
CN110902807B (en) A kind of powder strengthening method of biochemical water treatment
CN101863608B (en) Solid-liquid separation process for drilled pile waste mud
UA78436C2 (en) Method for rigidification of water suspensions
CN101306884A (en) A purification method for mixed water containing algae and sediment
JP3945541B2 (en) Physicochemical treatment method of runoff water for consumption, especially surface water
CN106830252A (en) The unified water treating apparatus of function are precipitated with ballasted flocculation
CN102939141A (en) Concentration of suspensions
CN110066097A (en) A kind of riverway sludge dehydrating and curing treatment process
CN204644016U (en) A kind of water treating equipment integrating clarification and filter
CN216946616U (en) Magnetic coagulation-flocculation reaction device and high-turbidity wastewater ultrafiltration treatment system
CN106219860B (en) River and lake pool gushes water reuse (treatment system more than polluted bed mud processing
CN116621417A (en) Method for rapid cleaning and dehydration of dredging sediment
CN115849662A (en) Flocculation combined plate-and-frame filter pressing enhanced high-water-content dredged sludge rapid dehydration method
CN102249515A (en) Dredged mud dewatering method for small suction cutter dredger
CN206680234U (en) Unified water treating apparatus with ballasted flocculation precipitation function
CN205933455U (en) Industrial waste water high -efficiency processing device
CN103351065B (en) The method of wastewater treatment of mixed type cast waste sand wet reclamation
CN104974454A (en) Flocculant and preparation method of same
CN112358116A (en) Efficient sludge backflow system and method for reinforcing magnetic coagulation separation process
CN107055926A (en) A kind of sludge water condition in waterworks water treatment facilities
CN113946142B (en) Automatic control treatment method for sludge water and sludge dewatering process of tap water plant
CN204779141U (en) Heavy metal wastewater retrieval and utilization treatment facility
CN114751597A (en) A water treatment process based on composite magnetic flocculant
CN115159811A (en) Zero-emission underground engineering slurry treatment construction method
CN208700854U (en) A kind of quick dystopy purification device of river water

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination