CN1164699C - High performance decorative printing ink and its preparation method - Google Patents
High performance decorative printing ink and its preparation method Download PDFInfo
- Publication number
- CN1164699C CN1164699C CNB021520127A CN02152012A CN1164699C CN 1164699 C CN1164699 C CN 1164699C CN B021520127 A CNB021520127 A CN B021520127A CN 02152012 A CN02152012 A CN 02152012A CN 1164699 C CN1164699 C CN 1164699C
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- performance
- high performance
- printing ink
- decorative ink
- wetting dispersing
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- Expired - Fee Related
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Abstract
The present invention discloses decorative printing ink with high performance, which has components by weight: 20 to 75% of inorganic polymer composite materials with high performance, 5 to 30% of organic polymer materials, 5 to 50% of pigment, 1 to 30% of filler, 0.1 to 15% of auxiliary agent and 10 to 50% of solvent. The present invention also discloses a method for preparing the decorative printing ink with high performance. The decorative printing ink with high performance of the present invention has the characteristics of brilliant and smooth coating layer, excellent adhesive force, good weatherability, abrasion resistance and chemical resistance, etc. The present invention can be used together with silver paste for screening and printing silver paste patterns on printing ink. The thickness is moderate, lines are integral, and no bubble exists.
Description
Technical field
The present invention relates to a kind of decorative ink, the invention still further relates to a kind of preparation method of decorative ink.
Background technology
The front windshield of automobile, back glass, side door glass and lampshade all are flat in the past, therefore can be installed on the car body easily.But along with widening of people's aesthetic standard, the glass that particularly high-grade car uses now all has certain radian, for ease of installing, uses the high polyurethane sealant of bonding strength, makes glass and car body directly bonding.This mounting means does not have obvious frame, can directly glass be installed on the car body, has both improved work efficiency, has increased somewhat attractive in appearance for automobile again.But novel process has also brought seal gum to subject to the defective that connects up in ultraviolet radiation destruction and the exposed window, so decorative ink just arises at the historic moment.For preventing on vehicle glass, condense fog or frosting, come demist or defrosting with electrically heated method usually again.When the coating top sieve seal silver slurry pattern at common decorative ink, the goods that make like this tend to occur silver-colored lines broken string or bubble are arranged, and silver slurry coat-thickness can not be up to standard, influence the electrically heated demist, the efficient of defrosting also influences outward appearance, causes the qualification rate of product low.
Summary of the invention
The object of the present invention is to provide a kind of high-performance decorative ink, this decorative ink has excellent sticking power, good weathering resistance, wear resistance and chemical resistant properties are being starched and the time spent with silver, at the silver slurry pattern of decorative ink top sieve seal, thickness is moderate, and the lines complete sum does not have bubble.
Another object of the present invention is to provide a kind of preparation method of high-performance decorative ink.
High-performance decorative ink provided by the invention, its component and weight content are:
Inorganic macromolecular composite material 20～75%, described inorganic macromolecular composite material is made up of the following weight proportion raw material: PbO 20～65%, SiO
210～40%, Al
2O
30.5～10%, TiO
21～8%, ZrO
21～8%, Cr
2O
31～9%, CuO 1～10%, Li
2O 0.5～8%, Fe
2O
30.5～5%, Na
2CO
30.5～8%, Ca
3(PO
4)
20.5～3%, Na
2SiF
61～8%;
Organic polymer material 5～30%, described organic polymer material is selected from one or more in ethyl cellulose, Resins, epoxy and the silicone resin;
Pigment 5～50%;
Filler 1～30%, described filler is selected from one or more in silicon-dioxide, alchlor, kaolin and the wilkinite;
Auxiliary agent 0.1～15%, described auxiliary agent are selected from one or more in 902 and 910 wetting dispersing agents and antisettling agent, WETZFS453 wetting dispersing agent, DA-168 wetting dispersing agent and the HX-4010 wetting dispersing agent;
Solvent 10～50%, described solvent is selected from one or more in vegetables oil, tridecanol, pine tar and the α-terpinol.
The preparation method of above-mentioned high-performance decorative ink provided by the invention may further comprise the steps:
(1) each raw material that will form the inorganic macromolecular composite material is mixed in proportion, be evenly to stir under 1200～1400 ℃ the condition in temperature, after cooling, make the high-performance inorganic polymer composite powder of particle diameter≤10 μ m with common pulverizing, grinding technics;
(2) be ground to particle diameter≤10 μ m after above-mentioned inorganic macromolecular composite material powder and organic polymer material, auxiliary agent, solvent, pigment and filler are mixed in proportion, promptly get high-performance decorative ink of the present invention.
The coating light of high-performance decorative ink of the present invention is level and smooth, has excellent sticking power, good weathering resistance, and characteristics such as wear resistance and chemical resistant properties can be starched and usefulness with silver, and at printing ink top sieve seal silver slurry pattern, thickness is moderate, and the lines complete sum does not have bubble.
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1
(1) preparation high-performance inorganic polymer composite
With PbO 56 grams, SiO
224 grams, Al
2O
33.5 gram, TiO
22.5 gram, ZrO
22.5 gram, Cr
2O
33 grams, CuO 2 grams, Li
2O 1.5 grams, Fe
2O
31.5 gram, Na
2CO
32 grams, Ca
3(PO
4)
22 gram and Na
2SiF
6Behind the 4 gram mixings, be contained in the ceramic crucible, at stove internal heating to 1300 ℃, after material is molten, take out, cool to room temperature is pulverized, and is ground to the powder of particle diameter≤10Llm.
(2) preparation high-performance decorative ink
Get above-mentioned high-performance inorganic polymer composite powder 47 grams, black pigment 28 grams, superfine silicon dioxide 1.5 grams, brilliant alcoholic solution 22 grams of the o-terpene of 30% ethyl cellulose and silicone resin (weight ratio is 1: 1), after 910 wetting dispersing agents, 1.5 grams mix, when being ground to particle diameter≤10Llm, obtain decorative ink of the present invention.
Embodiment 2
(1) preparation high-performance inorganic polymer composite
With PbO 49 grams, SiO
224 grams, Al
2O
33 grams, TiO
22.5 gram, ZrO
23 grams, Cr
2O
35 grams, CuO 3.5 grams, Li
2O 3.5 grams, Fe
2O
31.5 gram, Na
2CO
34 grams, Ca
3(PO
4)
22 gram and Na
2SiF
6Behind the 5 gram mixings, be contained in the ceramic crucible, at stove internal heating to 1400 ℃, after material is molten, take out, cool to room temperature is pulverized, and is ground to the powder of particle diameter≤10 μ m.
(2) preparation high-performance decorative ink
Get above-mentioned high-performance inorganic polymer composite powder 50 grams, black pigment 28 grams, kaolin 1.5 grams, vegetable oil solution 22.5 grams of 30% ethyl cellulose, after HX-4010 dispersion agent 1 gram mixes, when being ground to particle diameter≤10 μ m, obtain decorative ink of the present invention.
Decorative ink sieve is printed on the sheet glass, after the ink dries, be put into temperature and be and burn till in 650 ℃ the stove or after ink dries, republish layer of metal slip (silver slurry), after waiting to do, be put into temperature and be in 800 ℃ the stove and burn till.The performance of ink coating sees the following form.
The decorative ink performance relatively
| Project | Embodiment 1 | Embodiment 2 | Commercially available decorative ink | |
| 650 ℃ of firing temperatures | In outward appearance on glass | Light is level and smooth | Light is level and smooth | Light is level and smooth |
| With glass cementation | Excellent (can not scraping any more) with pocket knife | Excellent (can not scraping any more) with pocket knife | Excellent (can not scraping any more) with pocket knife | |
| 800 ℃ of firing temperatures | In outward appearance on glass | Light is level and smooth | Light is level and smooth | Light is level and smooth |
| With glass cementation | Excellent (can not scraping any more) with pocket knife | Excellent (can not scraping any more) with pocket knife | Excellent (can not scraping any more) with pocket knife | |
| Silver slurry and printing ink cementability | The silver lines are complete, no bubble, and silver-colored lines thickness is moderate | The silver lines are complete, no bubble, and silver-colored lines thickness is moderate | Silver lines broken string has bubble, silver-colored lines thin thickness |
Claims (2)
1, a kind of high-performance decorative ink, its component and weight content are:
Inorganic macromolecular composite material 20～75%, described inorganic macromolecular composite material is made up of the following weight proportion raw material: PbO 20～65%, SiO
210～40%, Al
2O
30.5～10%, TiO
21～8%, ZrO
21～8%, Cr
2O
31～9%, CuO 1～10%, Li
2O 0.5～8%, Fe
2O
30.5～5%, Na
2CO
30.5～8%, Ca
3(PO
4)
20.5～3%, Na
2SiF
61～8%;
Organic polymer material 5～30%, described organic polymer material is selected from one or more in ethyl cellulose, Resins, epoxy and the silicone resin;
Pigment 5～50%;
Filler 1～30%, described filler is selected from one or more in silicon-dioxide, alchlor, kaolin and the wilkinite;
Auxiliary agent 0.1～15%, described auxiliary agent are selected from one or more in 902 and 910 wetting dispersing agents and antisettling agent, WETZFS453 wetting dispersing agent, DA-168 wetting dispersing agent and the HX-4010 wetting dispersing agent;
Solvent 10～50%, described solvent is selected from one or more in vegetables oil, tridecanol, pine tar and the α-terpinol.
2, the preparation method of the described high-performance decorative ink of claim 1 may further comprise the steps:
(1) each raw material that will form the inorganic macromolecular composite material is mixed in proportion, be evenly to stir under 1200～1400 ℃ the condition in temperature, after cooling, make the high-performance inorganic polymer composite powder of particle diameter≤10 μ m with common pulverizing, grinding technics;
(2) be ground to particle diameter≤10 μ m after above-mentioned inorganic macromolecular composite material powder and organic polymer material, auxiliary agent, solvent, pigment and filler are mixed in proportion, promptly get high-performance decorative ink of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021520127A CN1164699C (en) | 2002-11-20 | 2002-11-20 | High performance decorative printing ink and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021520127A CN1164699C (en) | 2002-11-20 | 2002-11-20 | High performance decorative printing ink and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1410494A CN1410494A (en) | 2003-04-16 |
| CN1164699C true CN1164699C (en) | 2004-09-01 |
Family
ID=4752075
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021520127A Expired - Fee Related CN1164699C (en) | 2002-11-20 | 2002-11-20 | High performance decorative printing ink and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1164699C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101088947B (en) * | 2006-06-13 | 2010-10-27 | 上海宝银电子材料有限公司 | Heat resistant antisticking no-lead black glaze for automobile glass and its prepn process |
| CN101157810B (en) * | 2007-11-13 | 2010-06-30 | 上海Dic油墨有限公司 | Gravure alcohol ester argentine-soluble ink and method for making same |
| CN102702842B (en) * | 2012-05-21 | 2014-08-20 | 深圳Tcl新技术有限公司 | Mirror silver ink and preparation method thereof |
| JP5797716B2 (en) * | 2013-10-16 | 2015-10-21 | 台湾太陽油▲墨▼股▲分▼有限公司 | Thermosetting resin composition, cured product thereof, and display member using the same |
-
2002
- 2002-11-20 CN CNB021520127A patent/CN1164699C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1410494A (en) | 2003-04-16 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |