CN116395965A - Glaze with imitation marble light sensation and application of glaze in preparation of ceramic tile with imitation marble light sensation with high fidelity - Google Patents

Abstract

The invention discloses a glaze with a marble-like light sensation and application thereof in preparing a ceramic tile with a high fidelity marble-like light sensation, wherein the glaze comprises the following raw materials: potassium feldspar, quartz, talcum powder, calcium borate, modified kaolin and composite matt material; the specific formula comprises the following raw materials: 20-50 parts of potassium feldspar, 20-50 parts of quartz, 5-10 parts of talcum powder, 5-10 parts of calcium borate, 10-20 parts of modified kaolin and 8-15 parts of composite matt material; the dispersibility of the kaolin in the glaze is improved after the modification treatment of stearic acid and octadecyl trimethyl ammonium bromide, so that the connection strength between the components of the glaze is enhanced, and the glaze prepared under a specific proportion improves the glossiness of the glaze, achieves the purposes of smooth and fine glaze and low glossiness, and ensures better wear resistance and light sensation.

Description

A kind of glaze material with imitation marble light feeling and its application in the preparation of high fidelity imitation marble The application of stone light-sensitive ceramic tiles

technical field

The invention relates to the technical field of ceramic tile glazes, in particular to a glaze with a marble-imitating light effect and its application in preparing high-fidelity marble-imitating light-sensitive ceramic tiles.

Background technique

The glaze applied to imitation marble tiles is generally made of natural ore. After grinding and adding water, it is coated on the surface of the green body and melted by roasting at a certain temperature. When the temperature drops, a glassy thin layer on the ceramic surface is formed. It increases the mechanical strength, thermal stability, and dielectric strength of ceramics and prevents liquid and gas erosion, and also increases the appearance of ceramic tiles, facilitates cleaning, and is not stained by dust;

The natural minerals used in the existing marble-like glazes are non-renewable resources. Long-term large-scale mining is not conducive to long-term development, and the glazes either have a rough surface with low gloss or a smooth glaze with high gloss. Good imitation marble glaze. On the basis of the original ordinary matte glaze, they add soft polishing equipment to polish the glaze softly. Although this soft polishing has low gloss, it greatly increases the production cost. Soft glaze with low-gloss ink sprayed on the glaze. Although this process is simple to operate, the light perception on the surface of the tile is uneven.

Contents of the invention

Aiming at the defects of the prior art, the purpose of the present invention is to provide a glaze material with imitation marble light effect and its application in the preparation of high-fidelity marble imitation light effect ceramic tiles, so as to solve the problems raised in the above-mentioned background technology.

The present invention solves technical problem and adopts following technical scheme:

The invention provides a kind of glaze material with imitation marble light feeling, comprising following raw materials:

Potassium feldspar, quartz, talc powder, calcium borate, modified kaolin, composite matte material;

Its specific formula includes the following raw materials: 20-50 parts of potassium feldspar, 20-50 parts of quartz, 5-10 parts of talcum powder, 5-10 parts of calcium borate, 10-20 parts of modified kaolin, 8-15 parts of composite matte material share.

Preferably, the glaze with imitation marble light perception comprises the following raw materials:

30 parts of potassium feldspar, 35 parts of quartz, 8 parts of talc powder, 8 parts of calcium borate, 16 parts of modified kaolin, 12 parts of composite matte material.

Preferably, the preparation of the modified kaolin comprises the following steps:

S1. Grinding the kaolin into granules, then ball milling with water to pass through a 200-300 mesh sieve, and air drying to obtain kaolin powder;

S2. Add 10-15 parts of stearic acid and 20-30 parts of octadecyltrimethylammonium bromide to 100-150 parts of kaolin micropowder in parts by mass, and ultrasonically vibrate for 10-15 minutes to obtain an ultrasonic mixture ;

S3. Raise the temperature of the ultrasonic mixture to 70-80°C, then sequentially add 3-4 parts of tin crystal material, 1-2 parts of white glass, 2-4 parts of magnesium oxide, and 1-3 parts of calcium carbonate, and stir for 60-80 minutes. Heat preservation reaction for 1-2 hours, and finally obtain modified kaolin after suction filtration, washing and drying.

Preferably, the mass of water added during the ball milling is 8-10% of the kaolin, and the particle size of the kaolin after grinding is 0.1-0.3 μm.

Preferably, the mass percentage of silicon dioxide in the kaolin is 45-65%, and the mass percentage of aluminum oxide is 35-55%.

Preferably, the water content of the modified kaolin is less than 2%, and the content of particles with a particle size of 0.25-0.3 μm does not exceed 50%.

Preferably, the preparation method of the composite matte material comprises the following steps:

(1) Add barium oxide and manganese oxide to deionized water and disperse evenly at 2400 rpm to prepare a mixed solution with a mass concentration of 25%. Add sodium hydroxide solution dropwise to the mixed solution under stirring conditions, and react After obtaining mixture A;

(2) Add the mixture A into a constant temperature magnetic stirring water bath, heat up to 75°C, and then disperse and react at a high speed for 10 hours, add methanol and precipitate, dry and grind to obtain a composite matte material.

Preferably, the composite matt material includes the following raw materials in mass fractions: 20-30 parts of barium oxide, 10-30 parts of manganese oxide, 5-10 parts of methanol, and 100-200 parts of deionized water.

Preferably, the preparation of the imitation marble photosensitive glaze comprises the following steps:

Step 1. Grinding potassium feldspar, quartz, talcum powder, calcium borate, modified kaolin, and composite matte material and mixing evenly to obtain a dry powder glaze;

Step 2, mixing the dry powder glaze and water in a weight ratio of 100:40-50 to obtain a marble-like glaze with a concentration of 40-50%;

Step 3: firing the glaze at 135-1500° C. for 8-10 hours to finally obtain a marble-like glaze.

The marble-imitating light-sensitive glaze prepared by the present invention and its application in preparing high-fidelity marble-like light-sensitive ceramic tiles, the kaolin in the glaze is modified by stearic acid and octadecyltrimethylammonium bromide The dispersibility after the anti-aging treatment is improved, thereby enhancing the connection strength between the glaze components, so that the hardness of the prepared marble-like light-sensitive tiles is better.

Compared with prior art and prior art, the present invention has the following beneficial effects:

The present invention uses natural minerals as a matrix and mixes them with modified kaolin and composite matting materials. The glaze prepared under a specific ratio can improve the gloss of the glazed surface and achieve a smooth and delicate glazed surface with low glossiness. The purpose is to ensure that its wear resistance and light perception are better.

Detailed ways

The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with specific embodiments. Apparently, the described embodiments are only some of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.

The present invention of the present embodiment provides a kind of glaze material with imitation marble light feeling, comprises following raw material:

Potassium feldspar, quartz, talc powder, calcium borate, modified kaolin, composite matte material;

Its specific formula includes the following raw materials: 20-50 parts of potassium feldspar, 20-50 parts of quartz, 5-10 parts of talcum powder, 5-10 parts of calcium borate, 10-20 parts of modified kaolin, 8-15 parts of composite matte material share.

The glaze material with imitation marble light feeling of the present embodiment comprises following raw material:

30 parts of potassium feldspar, 35 parts of quartz, 8 parts of talc powder, 8 parts of calcium borate, 16 parts of modified kaolin, 12 parts of composite matte material.

The preparation of the modified kaolin of the present embodiment comprises the following steps:

S1. Grinding the kaolin into granules, then ball milling with water to pass through a 200-300 mesh sieve, and air drying to obtain kaolin powder;

S2. Add 10-15 parts of stearic acid and 20-30 parts of octadecyltrimethylammonium bromide to 100-150 parts of kaolin micropowder in parts by mass, and ultrasonically vibrate for 10-15 minutes to obtain an ultrasonic mixture ;

S3. Raise the temperature of the ultrasonic mixture to 70-80°C, then sequentially add 3-4 parts of tin crystal material, 1-2 parts of white glass, 2-4 parts of magnesium oxide, and 1-3 parts of calcium carbonate, and stir for 60-80 minutes. Heat preservation reaction for 1-2 hours, and finally obtain modified kaolin after suction filtration, washing and drying.

The mass of water added during ball milling in this embodiment is 8-10% of the kaolin, and the particle size of the kaolin after grinding is 0.1-0.3 μm.

The mass percentage of silicon dioxide in the kaolin of this embodiment is 45-65%, and the mass percentage of aluminum oxide is 35-55%.

The water content of the modified kaolin in this embodiment is less than 2%, and the content of particles with a particle diameter of 0.25-0.3 μm does not exceed 50%.

The preparation method of the composite matte material of the present embodiment comprises the following steps:

(1) Add barium oxide, manganese oxide and zinc oxide into deionized water and disperse evenly at 2400 rpm to prepare a mixed solution with a mass concentration of 25%, and add sodium hydroxide solution dropwise to the mixed solution under stirring conditions In, the mixture A is obtained after the reaction;

(2) Add the mixture A into a constant temperature magnetic stirring water bath, heat up to 75°C, and then disperse and react at a high speed for 10 hours, add methanol and precipitate, dry and grind to obtain a composite matte material.

The composite matte material of this embodiment includes the following raw materials in mass fractions: 20-30 parts of barium oxide, 10-30 parts of manganese oxide, 10-20 parts of zinc oxide, 5-10 parts of methanol, and 100-200 parts of deionized water.

The preparation of the imitation marble photosensitive glaze of the present embodiment comprises the steps:

Step 1. Grinding potassium feldspar, quartz, talcum powder, calcium borate, modified kaolin, and composite matte material and mixing evenly to obtain a dry powder glaze;

Step 2, mixing the dry powder glaze and water in a weight ratio of 100:40-50 to obtain a marble-like glaze with a concentration of 40-50%;

Step 3: firing the glaze material at 1350° C.-1500° C. for 8-10 hours to finally obtain a marble-imitating glaze.

Example 1.

The present invention of the present embodiment provides a kind of glaze material with imitation marble light feeling, comprises following raw material:

Potassium feldspar, quartz, talc powder, calcium borate, modified kaolin, composite matte material;

Its specific formula includes the following raw materials: 20 parts of potassium feldspar, 20 parts of quartz, 5 parts of talcum powder, 5 parts of calcium borate, 10 parts of modified kaolin, and 8 parts of composite matte material.

The preparation of the modified kaolin of the present embodiment comprises the following steps:

S1, pulverizing the kaolin into granules, then adding water and ball milling to pass through a 200-mesh sieve, and obtaining kaolin micropowder after air-drying;

S2. Add 10 parts of stearic acid and 20 parts of octadecyltrimethylammonium bromide to 100 parts of kaolin micropowder in parts by mass, and ultrasonically vibrate for 10 minutes to obtain an ultrasonic mixture;

S3. Raise the temperature of the ultrasonic mixture to 70°C, then sequentially add 3 parts of tin crystal material, 1 part of white glass, 2 parts of magnesium oxide, and 1 part of calcium carbonate and stir for 60 minutes, keep the temperature for 1 hour, and finally filter, wash and dry Then get modified kaolin.

The mass of water added during ball milling in this embodiment is 8% of the kaolin, and the particle size of the kaolin after grinding is 0.1 μm.

The mass percentage of silicon dioxide in the kaolin of this embodiment is 45%, and the mass percentage of aluminum oxide is 35%.

The water content of the modified kaolin in this embodiment is less than 2%, and the content of particles with a particle size of 0.25 μm does not exceed 50%.

The preparation method of the composite matte material of the present embodiment comprises the following steps:

(1) Add barium oxide, manganese oxide and zinc oxide into deionized water and disperse evenly at 2400 rpm to prepare a mixed solution with a mass concentration of 25%, and add sodium hydroxide solution dropwise to the mixed solution under stirring conditions In, the mixture A is obtained after the reaction;

(2) Add the mixture A into a constant temperature magnetic stirring water bath, heat up to 75°C, and then disperse and react at a high speed for 10 hours, add methanol and precipitate, dry and grind to obtain a composite matte material.

The composite matte material of this embodiment includes the following raw materials in mass fractions: 20 parts of barium oxide, 10 parts of manganese oxide, 10 parts of zinc oxide, 5 parts of methanol, and 100 parts of deionized water.

The preparation of the imitation marble photosensitive glaze of the present embodiment comprises the steps:

Step 1. Grinding potassium feldspar, quartz, talcum powder, calcium borate, modified kaolin, and composite matte material and mixing evenly to obtain a dry powder glaze;

Step 2, mixing the dry powder glaze and water at a weight ratio of 100:40 to obtain a marble-like glaze with a concentration of 40%;

Step 3: firing the glaze at 1350° C. for 8 hours to finally obtain a marble-like glaze.

Example 2.

The present invention of the present embodiment provides a kind of glaze material with imitation marble light feeling, comprises following raw material:

Potassium feldspar, quartz, talc powder, calcium borate, modified kaolin, composite matte material;

Its specific formula includes the following raw materials: 33 parts of potassium feldspar, 35 parts of quartz, 8 parts of talcum powder, 8 parts of calcium borate, 16 parts of modified kaolin, and 12 parts of composite matte material.

The preparation of the modified kaolin of the present embodiment comprises the following steps:

S1, pulverizing the kaolin into granules, then adding water and ball milling to pass through a 260-mesh sieve, and obtaining kaolin micropowder after air-drying;

S2. Add 113 parts of stearic acid and 25 parts of octadecyltrimethylammonium bromide to 130 parts of kaolin micropowder in parts by mass, and ultrasonically vibrate for 12 minutes to obtain an ultrasonic mixture;

S3. Raise the temperature of the ultrasonic mixture to 76°C, then sequentially add 3 parts of tin crystal material, 1 part of white glass, 3 parts of magnesium oxide, and 2 parts of calcium carbonate and stir for 70 minutes, keep the temperature for 1.5 hours, and finally filter, wash, Modified kaolin is obtained after drying.

The mass of water added during ball milling in this embodiment is 9% of the kaolin, and the particle size of the kaolin after grinding is 0.2 μm.

The mass percent content of silicon dioxide in the kaolin of this embodiment is 50%, and the mass percent content of aluminum oxide is 45%.

The water content of the modified kaolin in this embodiment is less than 2%, and the content of particles with a particle size of 0.27 μm does not exceed 50%.

The preparation method of the composite matte material of the present embodiment comprises the following steps:

(1) Add barium oxide, manganese oxide and zinc oxide into deionized water and disperse evenly at 2400 rpm to prepare a mixed solution with a mass concentration of 25%, and add sodium hydroxide solution dropwise to the mixed solution under stirring conditions In, the mixture A is obtained after the reaction;

(2) Add the mixture A into a constant temperature magnetic stirring water bath, heat up to 75°C, and then disperse and react at a high speed for 10 hours, add methanol and precipitate, dry and grind to obtain a composite matte material.

The composite matte material of this embodiment includes the following raw materials in mass fractions: 25 parts of barium oxide, 20 parts of manganese oxide, 15 parts of zinc oxide, 8 parts of methanol, and 150 parts of deionized water.

The preparation of the imitation marble photosensitive glaze of the present embodiment comprises the steps:

Step 1. Grinding potassium feldspar, quartz, talcum powder, calcium borate, modified kaolin, and composite matte material and mixing evenly to obtain a dry powder glaze;

Step 2, mixing the dry powder glaze and water at a weight ratio of 100:45 to obtain a marble-like glaze with a concentration of 45%;

Step 3: firing the glaze material at 1400° C. for 9 hours to finally obtain a marble-like glaze.

Example 3.

The present invention of the present embodiment provides a kind of glaze material with imitation marble light feeling, comprises following raw material:

Potassium feldspar, quartz, talc powder, calcium borate, modified kaolin, composite matte material;

The specific formula includes the following raw materials: 50 parts of potassium feldspar, 50 parts of quartz, 10 parts of talcum powder, 10 parts of calcium borate, 20 parts of modified kaolin, and 15 parts of composite matte material.

The preparation of the modified kaolin of the present embodiment comprises the following steps:

S1, pulverizing the kaolin into granules, then adding water and ball milling to pass through a 300-mesh sieve, and obtaining kaolin micropowder after air-drying;

S2. Add 15 parts of stearic acid and 30 parts of octadecyltrimethylammonium bromide to 150 parts of kaolin micropowder in parts by mass, and ultrasonically vibrate for 15 minutes to obtain an ultrasonic mixture;

S3. Raise the temperature of the ultrasonic mixture to 80°C, then sequentially add 4 parts of tin crystal material, 2 parts of white glass, 4 parts of magnesium oxide, and 3 parts of calcium carbonate and stir for 80 minutes, keep warm for 2 hours, and finally filter, wash and dry Then get modified kaolin.

The mass of water added during ball milling in this embodiment is 10% of the kaolin, and the particle size of the kaolin after grinding is 0.3 μm.

The mass percent content of silicon dioxide in the kaolin of this embodiment is 65%, and the mass percent content of aluminum oxide is 55%.

The water content of the modified kaolin in this embodiment is less than 2%, and the content of particles with a particle size of 0.3 μm does not exceed 50%.

The preparation method of the composite matte material of the present embodiment comprises the following steps:

(1) Add barium oxide, manganese oxide and zinc oxide into deionized water and disperse evenly at 2400 rpm to prepare a mixed solution with a mass concentration of 25%, and add sodium hydroxide solution dropwise to the mixed solution under stirring conditions In, the mixture A is obtained after the reaction;

(2) Add the mixture A into a constant temperature magnetic stirring water bath, heat up to 75°C, and then disperse and react at a high speed for 10 hours, add methanol and precipitate, dry and grind to obtain a composite matte material.

The composite matte material of this embodiment includes the following raw materials in mass fractions: 30 parts of barium oxide, 30 parts of manganese oxide, 20 parts of zinc oxide, 10 parts of methanol, and 200 parts of deionized water.

The preparation of the imitation marble photosensitive glaze of the present embodiment comprises the steps:

Step 1. Grinding potassium feldspar, quartz, talcum powder, calcium borate, modified kaolin, and composite matte material and mixing evenly to obtain a dry powder glaze;

Step 2, mixing the dry powder glaze and water in a weight ratio of 100:50 to obtain a marble-like glaze with a concentration of 50%;

Step 3: firing the glaze material at 1500° C. for 10 hours to finally obtain a marble-imitating glaze.

Comparative example 1.

The difference from Example 3 is that the kaolin is not modified.

Comparative example 2.

The difference from Example 3 is that no composite matting material is added during the preparation of the glaze.

Comparative example 3.

The difference from Example 3 is that barium oxide and manganese oxide are added in excess in the composite matt material.

Carry out performance test with embodiment 1-3 and comparative example 1-3 product;

Make 30 glaze samples, each group of 5 is divided into 6 groups, each group corresponds to Example 1-3 and Comparative Example 1-3 and is numbered as A/B/C/D/E/F, the glaze Coated on the surface of ceramic tiles, after firing at high temperature, the glaze samples of A/B/C/D/E/F groups were tested respectively, and the test results are shown in the table below.

Can find out from embodiment 1-3; Use the glaze that the present invention makes with imitation marble light feeling and its application in the ceramic tile of imitation marble light feeling of preparation high fidelity take natural mineral as matrix, and modified kaolin It is prepared by mixing with compound matte material, and the glaze prepared under a specific ratio can improve the gloss of the glaze surface and achieve the purpose of smooth and delicate glaze surface with low gloss.

From Comparative Example 1 and Example 3, it can be seen that the dispersibility of kaolin in the glaze is improved after stearic acid and octadecyltrimethylammonium bromide modification treatment, thereby enhancing the interaction between the glaze components. The connection strength increases the hardness of the glaze;

In addition, it is found from Comparative Examples 2-3 that in the preparation of glazes with imitation marble light perception and its application in the preparation of high-fidelity marble-like light perception tiles, the barium oxide and manganese oxide in its composite matt material Excessive addition reduces the transparency of the glaze, distorts the texture of the glaze surface, and the gloss of the glaze is high.

The innovation point of the present invention is:

The present invention uses natural minerals as a matrix and mixes them with modified kaolin and composite matting materials. The glaze prepared under a specific ratio can improve the gloss of the glazed surface and achieve a smooth and delicate glazed surface with low glossiness. The purpose is to ensure that its wear resistance and light perception are good, and at the same time, the dispersibility of kaolin in the glaze is improved after being modified by stearic acid and octadecyltrimethylammonium bromide, so as to enhance the relationship between glaze components. Excellent connection strength, so that the hardness of the prepared marble-like light-sensitive tiles is better.

It will be apparent to those skilled in the art that the invention is not limited to the details of the above-described exemplary embodiments, but that the invention can be embodied in other specific forms without departing from the spirit or essential characteristics of the invention. Accordingly, the embodiments should be regarded in all points of view as exemplary and not restrictive, the scope of the invention being defined by the appended claims rather than the foregoing description, and it is therefore intended that the scope of the invention be defined by the appended claims rather than by the foregoing description. All changes within the meaning and range of equivalents of the elements are embraced in the present invention.

In addition, it should be understood that although this specification is described according to implementation modes, not each implementation mode only includes an independent technical solution, and this description in the specification is only for clarity, and those skilled in the art should take the specification as a whole , the technical solutions in the various embodiments can also be properly combined to form other implementations that can be understood by those skilled in the art.

Claims (10)

1. The glaze with the marble-like light sensation is characterized by comprising the following raw materials: potassium feldspar, quartz, talcum powder, calcium borate, modified kaolin and composite matt material;

the specific formula comprises the following raw materials: 20-50 parts of potassium feldspar, 20-50 parts of quartz, 5-10 parts of talcum powder, 5-10 parts of calcium borate, 10-20 parts of modified kaolin and 8-15 parts of composite matt material.

2. The glaze with marble-like light sensation according to claim 1, comprising the following raw materials:

30 parts of potassium feldspar, 35 parts of quartz, 8 parts of talcum powder, 8 parts of calcium borate, 16 parts of modified kaolin and 12 parts of composite matt material.

3. The glaze with a marbled light sensation according to claim 1, wherein the preparation of the modified kaolin comprises the steps of:

s1, crushing kaolin into particles, adding water, ball milling to pass through a 200-300 mesh sieve, and carrying out pneumatic drying to obtain kaolin micropowder;

s2, adding 10-15 parts of stearic acid and 20-30 parts of octadecyl trimethyl ammonium bromide into 100-150 parts of kaolin micropowder according to parts by weight, and carrying out ultrasonic vibration for 10-15min to obtain an ultrasonic mixed solution;

and S3, heating the ultrasonic mixed solution to 70-80 ℃, sequentially adding 3-4 parts of tin crystal material, 1-2 parts of white glass, 2-4 parts of magnesium oxide and 1-3 parts of calcium carbonate, stirring for 60-80min, carrying out heat preservation reaction for 1-2h, and finally carrying out suction filtration, washing and drying to obtain the modified kaolin.

4. A marbled light-sensitive glaze according to claim 3, wherein the mass of water added during ball milling is 8-10% of kaolin, and the particle size of the kaolin after grinding is 0.1-0.3 μm.

5. A marbleized glaze according to claim 3, wherein the silica content in the kaolin is 45-65% by mass and the alumina content is 35-55% by mass.

6. A marbleized glaze according to claim 3, wherein said kaolin modified has a moisture content of less than 2% and wherein the particle content of 0.25 to 0.3 μm is not more than 50%.

7. The glaze with a marbled light sensation according to claim 1, wherein the preparation method of the composite matt material comprises the following steps:

(1) Adding barium oxide and manganese oxide into deionized water, uniformly dispersing at 2400 rpm to obtain a mixed solution with the mass concentration of 25%, dropwise adding sodium hydroxide solution into the mixed solution under the stirring condition, and reacting to obtain a mixture A;

(2) Adding the mixture A into a constant-temperature magnetic stirring water bath kettle, heating to 75 ℃, performing high-speed dispersion reaction for 10 hours, adding methanol, precipitating, drying, and grinding to obtain the composite matt material.

8. The glaze with marble-like light sensation according to claim 7, wherein the composite matt material comprises the following raw materials in mass fraction: 20-30 parts of barium oxide, 10-30 parts of manganese oxide, 5-10 parts of methanol and 100-200 parts of deionized water.

9. The glaze material with a marbled light sensation according to claim 1, wherein the preparation of the marbled light sensation glaze material comprises the following steps:

grinding potassium feldspar, quartz, talcum powder, calcium borate, modified kaolin and a composite matt material, and uniformly mixing to obtain a dry powder glaze;

step two, dry powder glaze and water are mixed according to the weight ratio of 100: 40-50% of the raw materials are mixed to obtain the marble-like light-sensitive glaze with the concentration of 40-50%;

and thirdly, firing the glaze at 135-1500 ℃ for 8-10 hours to finally obtain the marble-like light-sensitive glaze.

10. A glaze having a marbleized light sensation as claimed in any one of claims 1 to 9 and its use in the preparation of high fidelity marbleized light sensation tiles.