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CN116282982A - Portland cement clinker and preparation method thereof - Google Patents

Portland cement clinker and preparation method thereof Download PDF

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Publication number
CN116282982A
CN116282982A CN202310122576.4A CN202310122576A CN116282982A CN 116282982 A CN116282982 A CN 116282982A CN 202310122576 A CN202310122576 A CN 202310122576A CN 116282982 A CN116282982 A CN 116282982A
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Prior art keywords
cement clinker
portland cement
clinker
preparation
firing
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CN202310122576.4A
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Chinese (zh)
Inventor
陈其联
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Guangxi Denggao Group Tiandong Cement Co ltd
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Guangxi Denggao Group Tiandong Cement Co ltd
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Priority to CN202310122576.4A priority Critical patent/CN116282982A/en
Publication of CN116282982A publication Critical patent/CN116282982A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • C04B7/147Metallurgical slag
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/43Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/44Burning; Melting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a silicate cement clinker and a preparation method thereof, which relate to the field of silicate cement clinker, and comprise the following components in parts by weight: 82% of lime raw material, 3% of coal oil slag, 10% of sandstone and 5% of steel slag. According to the invention, the particle size of the silicate cement clinker is reasonably proportioned and regulated, so that the abrasion degree of the silicate cement clinker to machinery caused by too small particles can be reduced under the condition of ensuring rapid hydration, the quality of the silicate cement clinker can be more intact under the condition of enough passing temperature and calcining time, the setting speed is more reasonable and rapid, the time for using cement can be provided, and the method is suitable for emergency processing.

Description

一种硅酸盐水泥熟料及其制备方法A kind of Portland cement clinker and preparation method thereof

技术领域technical field

本发明涉及硅酸盐水泥熟料领域,具体为一种硅酸盐水泥熟料及其制备方法。The invention relates to the field of Portland cement clinker, in particular to a Portland cement clinker and a preparation method thereof.

背景技术Background technique

硅酸盐水泥熟料是以石灰石和粘土为主要原料,经破碎、配料、磨细制成生料,继而将生料粉在水泥窑中经过1450℃煅烧而成的,经过硅酸盐水泥熟料与石膏进行磨细即可得到硅酸盐水泥。Portland cement clinker is made of limestone and clay as the main raw material, which is made into raw meal by crushing, batching, and grinding, and then the raw meal powder is calcined at 1450 ° C in a cement kiln. Portland cement can be obtained by grinding the material and gypsum.

硅酸盐水泥凝结硬化快,早期强度及后期强度高,适用于有早强要求的混凝土、冬季施工混凝土,地上、地下重要结构的高强混凝土和预应力混凝土工程,当需要紧急赶工时,因其凝结硬化快,硅酸盐水泥是人们较常使用的原料。Portland cement sets and hardens quickly, and has high early strength and late strength. It is suitable for concrete with early strength requirements, winter construction concrete, high-strength concrete and prestressed concrete projects for important structures above and below ground. Fast setting and hardening, Portland cement is a more commonly used raw material.

但硅酸盐水泥熟料在研磨过程中研磨出的颗粒越小,所产生的水泥颗粒越细,这就对机器的损耗太大,使得水泥在空气中硬化时收缩也增大,这样一来硅酸盐水泥熟料的凝固速度受到影响,在紧急加工下,为了追赶速度,导致水泥固化速度过快,如果来不及使用硅酸盐水泥熟料则会固化,无法使用,造成浪费,如何在合理的时间内加快初凝速度,且有足够的时间用来使用硅酸盐水泥熟料就成了一种问题,国标规定硅酸盐水泥的比表面积不小于300平方米/kg。However, the smaller the particles of Portland cement clinker are ground during the grinding process, the finer the cement particles produced, which will cause too much loss to the machine, and the shrinkage of the cement will also increase when it hardens in the air. The solidification speed of Portland cement clinker is affected. In emergency processing, in order to catch up with the speed, the cement solidification speed is too fast. If it is too late to use Portland cement clinker, it will solidify and cannot be used, resulting in waste. How to make it reasonable It becomes a problem to speed up the initial setting speed within a certain period of time and have enough time to use Portland cement clinker. The national standard stipulates that the specific surface area of Portland cement is not less than 300 square meters/kg.

发明内容Contents of the invention

基于此,本发明的目的是提供一种硅酸盐水泥熟料及其制备方法,以解决上述背景技术中所提到的技术问题。Based on this, the object of the present invention is to provide a Portland cement clinker and its preparation method, so as to solve the technical problems mentioned in the background art above.

为实现上述目的,本发明提供如下技术方案:一种硅酸盐水泥熟料及其制备方法,所述生产硅酸盐水泥熟料所需成分及其重量配比包括:82%的石灰质原料与3%的煤质油渣加10%的砂岩外加5%的钢渣配料。In order to achieve the above object, the present invention provides the following technical proposal: a portland cement clinker and its preparation method, the components required for the production of Portland cement clinker and their weight ratio include: 82% calcareous raw material and 3% coal-based oil residue plus 10% sandstone plus 5% steel slag ingredients.

本发明所述的一种硅酸盐水泥熟料及其制备方法,包括下述步骤:A kind of Portland cement clinker of the present invention and preparation method thereof, comprises the following steps:

S1:备料,将82%的石灰质原料与3%的煤质油渣加10%的砂岩外加5%的钢渣配料,按其重量配比放入微操研磨机进行研磨,可得到硅酸盐水泥的生料;S1: Prepare raw materials, mix 82% calcareous raw materials with 3% coal-based oil residue, 10% sandstone and 5% steel slag, put them into a micro-grinding machine according to their weight ratio, and grind them to get Portland cement raw material;

S2:烧制,将磨制完成的生料放入煅烧炉进行烧制,烧制完成后得到熟料,将其进行急冷处理,S2: Firing, put the ground raw material into the calciner for firing, after the firing is completed, the clinker is obtained, and it is subjected to quenching treatment,

上述将原料进行研磨后,保证其熟料颗粒度控制在5~15mm。After the above-mentioned raw materials are ground, it is ensured that the particle size of the clinker is controlled at 5-15 mm.

优选的,所述步骤2在烧制过程中,需保证生料煅烧温度达到1450℃,且煅烧时长为40minPreferably, in step 2, during the firing process, it is necessary to ensure that the raw meal calcining temperature reaches 1450°C, and the calcining time is 40 minutes

综上所述,本发明主要具有以下有益效果:In summary, the present invention mainly has the following beneficial effects:

本发明与现有技术相比,通过合理配比与调节硅酸盐水泥熟料的颗粒大小,在保证水化迅速的情况下,能够减少因颗粒过小而导致硅酸盐水泥熟料对机械造成的磨损度,且通过温度与煅烧时长足够的情况下,硅酸盐水泥熟料的质量能够更加完好,且凝固速度更加合理且快速,能提供时间用来使用水泥,适用于紧急加工。Compared with the prior art, the present invention can reduce the impact of Portland cement clinker on machinery due to too small particles by rationally proportioning and adjusting the particle size of Portland cement clinker while ensuring rapid hydration. The degree of wear caused by it, and the temperature and calcination time are sufficient, the quality of Portland cement clinker can be more intact, and the setting speed is more reasonable and fast, which can provide time for the use of cement and is suitable for emergency processing.

具体实施方式Detailed ways

下面将结合本发明实施例,对本发明实施例中的技术方案进行清楚、完整地描述。下面通过参考实施例是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention. The following examples are illustrative by referring to the examples, and are only used for explaining the present invention, and should not be construed as limiting the present invention.

下面根据本发明的整体结构,对其实施例进行说明。The embodiments of the present invention will be described below according to the overall structure of the present invention.

一种硅酸盐水泥熟料及其制备方法,一种硅酸盐水泥熟料及其制备方法,包括,其特征在于:生产硅酸盐水泥熟料所需成分及其重量配比包括:82%的石灰质原料与3%的煤质油渣加10%的砂岩外加5%的钢渣配料。A Portland cement clinker and a preparation method thereof, a Portland cement clinker and a preparation method thereof, comprising, characterized in that: the components required for the production of Portland cement clinker and their weight ratios include: 82 % calcareous raw material and 3% coal-based oil residue plus 10% sandstone plus 5% steel slag ingredients.

本硅酸盐水泥熟料及其制备方法包括下述步骤:This portland cement clinker and preparation method thereof comprise the following steps:

S1:备料,将82%的石灰质原料与3%的煤质油渣加10%的砂岩外加5%的钢渣配料,按其重量配比放入微操研磨机进行研磨,可得到硅酸盐水泥的生料;S1: Prepare raw materials, mix 82% calcareous raw materials with 3% coal-based oil residue, 10% sandstone and 5% steel slag, put them into a micro-grinding machine according to their weight ratio, and grind them to get Portland cement raw material;

S2:烧制,将磨制完成的生料放入煅烧炉进行烧制,烧制完成后得到熟料,将其进行急冷处理,可得到硅酸盐水泥熟料1。S2: Firing, putting the ground raw material into a calciner for firing, and clinker is obtained after firing, which is quenched to obtain Portland cement clinker 1 .

实施例2Example 2

将83%的石灰质原料与2.5%的煤质油渣加9%的砂岩外加4.5%的钢渣配料,按其重量配比放入微操研磨机进行研磨,可得到硅酸盐水泥的生料,将生料进行研磨后,保证其熟料颗粒度控制在5~15mm,将硅酸盐水泥熟料研磨后使其颗粒粒径不小于7mm且不大于10mm,继而进行烧制,将温度控制在1400℃,烧制45min得到硅酸盐水泥熟料2。Mixing 83% calcareous raw materials with 2.5% coal oil residue plus 9% sandstone plus 4.5% steel slag, put them into a micro-grinding machine according to their weight ratio for grinding, and the raw meal of Portland cement can be obtained. After grinding the raw meal, ensure that the particle size of the clinker is controlled at 5-15mm, grind the Portland cement clinker so that the particle size is not less than 7mm and not greater than 10mm, and then fire it, and control the temperature at Burn at 1400°C for 45 minutes to obtain Portland cement clinker 2.

实施例3Example 3

将85%的石灰质原料与1.5%的煤质油渣加9.5%的砂岩外加4%的钢渣配料,按其重量配比放入微操研磨机进行研磨,可得到硅酸盐水泥的生料,将生料进行研磨后,保证其熟料颗粒度控制在5~15mm,将硅酸盐水泥熟料研磨后使其颗粒粒径不小于10mm且不大于13mm,继而进行烧制,将温度控制在1500℃,烧制40min得到硅酸盐水泥熟料3。Mixing 85% calcareous raw materials with 1.5% coal oil residue, 9.5% sandstone and 4% steel slag, put them into a micro-grinding machine according to their weight ratio, and grind them to get the raw meal of Portland cement. After grinding the raw meal, ensure that the particle size of the clinker is controlled at 5-15mm, grind the Portland cement clinker so that the particle size is not less than 10mm and not greater than 13mm, and then fire it, and control the temperature at Burn at 1500°C for 40 minutes to obtain Portland cement clinker 3.

Figure SMS_1
Figure SMS_1

尽管已经示出和描述了本发明的实施例,但本具体实施例仅仅是对本发明的解释,其并不是对发明的限制,描述的具体特征、结构、材料或者特点可以在任何一个或多个实施例或示例中以合适的方式结合,本领域技术人员在阅读完本说明书后可在不脱离本发明的原理和宗旨的情况下,可以根据需要对实施例做出没有创造性贡献的修改、替换和变型等,但只要在本发明的权利要求范围内都受到专利法的保护。Although the embodiments of the present invention have been shown and described, this specific embodiment is only an explanation of the present invention, and it is not a limitation of the invention. The specific features, structures, materials or characteristics described can be in any one or more Combining the embodiments or examples in a suitable manner, those skilled in the art can make modifications and replacements without creative contributions to the embodiments as required without departing from the principle and purpose of the present invention after reading this specification and modifications, etc., but as long as they are within the scope of the claims of the present invention, they are all protected by the patent law.

Claims (4)

1. A Portland cement clinker and a preparation method thereof, comprising the Portland cement clinker, which is characterized in that: the components required by producing the silicate cement clinker and the weight ratio thereof comprise: 82% of lime raw material, 3% of coal oil slag, 10% of sandstone and 5% of steel slag.
2. The Portland cement clinker and the preparation method thereof according to claim 1, wherein: comprising the following steps:
s1: preparing materials, namely adding 10% of sandstone into 82% of calcareous raw materials and 3% of coal oil residues and 5% of steel slag ingredients, and putting the materials into a micro-operation grinding machine according to the weight ratio for grinding to obtain raw materials of Portland cement;
s2: and (3) firing, namely placing the ground raw materials into a calciner for firing, obtaining clinker after firing, and quenching the clinker.
3. The Portland cement clinker and the preparation method thereof according to claim 1, wherein: after the raw materials are ground, the granularity of clinker is controlled to be 5-15 mm.
4. The Portland cement clinker and the preparation method thereof according to claim 1, wherein: in the firing process, the calcination temperature of the raw material needs to be ensured to reach 1450 ℃, and the calcination time is 40min.
CN202310122576.4A 2023-02-16 2023-02-16 Portland cement clinker and preparation method thereof Pending CN116282982A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
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Country Status (1)

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