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CN116264909A - A method for preparing tobacco pyrolysis products based on the principle of dialysis, tobacco pyrolysis products and applications - Google Patents

A method for preparing tobacco pyrolysis products based on the principle of dialysis, tobacco pyrolysis products and applications Download PDF

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CN116264909A
CN116264909A CN202111550025.5A CN202111550025A CN116264909A CN 116264909 A CN116264909 A CN 116264909A CN 202111550025 A CN202111550025 A CN 202111550025A CN 116264909 A CN116264909 A CN 116264909A
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tobacco
pyrolysis
dialysis
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张博
尹新强
王志国
邓昌健
赵国玲
彭新辉
龚淑果
梁秋菊
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China Tobacco Hunan Industrial Co Ltd
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/22Treatment of tobacco products or tobacco substitutes by application of electric or wave energy or particle radiation
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/24Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
    • A24B15/26Use of organic solvents for extraction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

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Abstract

本发明公开了一种基于透析原理制备烟草热解产物的方法及烟草热解产物和应用。烟草热解产物的制备方法如下:将烟草原料进行磨粉,得到烟草粉末;将烟草粉末通过溶剂提取,得到烟草浸膏;将烟草浸膏通过透析处理,得到除杂烟草浸膏;将除杂烟草浸膏进行热解处理,得到热解产物。该方法利用透析技术可定向除去浸膏中对抽吸品质有负面影响的物质,如蛋白质、多糖等,同时对感官特征有重要作用的小分子和易挥发成分进行富集,有利于烟草浸膏质量的稳定性。

Figure 202111550025

The invention discloses a method for preparing tobacco pyrolysis products based on the principle of dialysis, tobacco pyrolysis products and applications. The preparation method of the tobacco pyrolysis product is as follows: the tobacco raw material is ground into powder to obtain tobacco powder; the tobacco powder is extracted by solvent to obtain tobacco extract; the tobacco extract is subjected to dialysis to obtain impurity-removed tobacco extract; The tobacco extract is subjected to pyrolysis treatment to obtain pyrolysis products. This method uses dialysis technology to remove substances in the extract that have a negative impact on smoking quality, such as proteins and polysaccharides. At the same time, it enriches small molecules and volatile components that play an important role in sensory characteristics, which is beneficial to tobacco extract. Quality stability.

Figure 202111550025

Description

一种基于透析原理制备烟草热解产物的方法及烟草热解产物 和应用A method for preparing tobacco pyrolysis products based on the principle of dialysis and tobacco pyrolysis products and application

技术领域technical field

本发明涉及一种烟草热解产物及其制备方法和应用,具体涉及一种基于透析原理制备烟草热解产物的方法,还涉及该方法制备的烟草热解产物及其在加热不燃烧烟草制品中的应用,属于新型烟草制品技术领域。The present invention relates to a tobacco pyrolysis product and its preparation method and application, in particular to a method for preparing a tobacco pyrolysis product based on the principle of dialysis, and also to the tobacco pyrolysis product prepared by the method and its use in heat-not-burn tobacco products The application belongs to the technical field of new tobacco products.

背景技术Background technique

根据欧睿国际的推算数据,2020年,除中国外全球其他市场销售卷烟5528 万箱,较上年下降5.2%,创下近五年来最大降幅。从销售额看,除中国之外全球市场共实现销售额196.2亿美元,较上年增长4.3%;加热卷烟实现销售额177.8亿美元,较上年增长15.8%。世界范围内,加热卷烟已经成为烟草销售额的主要上涨动力。According to the calculation data of Euromonitor International, in 2020, 55.28 million boxes of cigarettes will be sold in other markets around the world except China, a decrease of 5.2% from the previous year, the largest decline in the past five years. In terms of sales, the global market excluding China achieved a total sales of US$19.62 billion, an increase of 4.3% over the previous year; sales of heated cigarettes were US$17.78 billion, an increase of 15.8% over the previous year. Worldwide, heated cigarettes have become the main driving force for tobacco sales.

烟支在燃吸过程中从炭线附近900℃左右至近滤嘴段50℃左右,存在三个温度区间,即高温燃烧区、热解蒸馏区、冷凝区。新型烟草制品与现有卷烟相比,加热温度波动性较小,相同温度下裂解或挥发出的香气物质丰富性明显不足。目前,市面上主流的加热卷烟产品大部分为烟草口味,然而新型烟草制品均仍存在烟香不足等缺陷,与卷烟燃吸时感官质量相差较大。此外,烟草提取物中存在对感官质量有负面作用的大分子物质如蛋白质等,定向的去除此类大分子物质对改善加热卷烟抽吸品质具有重要作用。目前,分离的手段主要采用膜分离技术,然而在工业化生产过程中,膜分离技术时常发生堵膜现象,严重影响生产的进度。During the burning and smoking process of cigarettes, there are three temperature ranges from about 900 °C near the charcoal line to about 50 °C near the filter tip, namely, the high-temperature combustion zone, the pyrolysis distillation zone, and the condensation zone. Compared with existing cigarettes, new tobacco products have less fluctuation in heating temperature, and the richness of aroma substances cracked or volatilized at the same temperature is obviously insufficient. At present, most of the mainstream heated cigarette products on the market are tobacco-flavored. However, new tobacco products still have defects such as insufficient smoke flavor, which is quite different from the sensory quality of cigarettes when they are burned and smoked. In addition, there are macromolecular substances such as proteins in tobacco extracts that have negative effects on sensory quality, and targeted removal of such macromolecular substances plays an important role in improving the smoking quality of heated cigarettes. At present, membrane separation technology is mainly used as the means of separation. However, in the process of industrial production, membrane clogging often occurs in membrane separation technology, which seriously affects the progress of production.

基于此,河南中烟陈泽少等(发明专利公布号CN 110236232 A)在烟叶浸膏中加入美拉德反应物进行微波裂解,并采用有机溶剂对热解油进行萃取,旋转蒸发后加入电子烟液中,此方法可明显增强电子烟香气质,增强电子烟烘烤气息;然而有可能存在不足,即烟叶浸膏中含有大量的可溶性蛋白质及多糖等对感官质量存在负面影响的物质;此外,郑建宇等发表的论文中,采用超滤膜技术可有效去除烟草提取物中对感官质量存在负面影响的大分子物质,并且经分离与富集技术,可降低烟草提取物对烟草原料的依赖程度,提高质量的稳定性。Based on this, Henan China Tobacco Chen Zeshao et al. (invention patent publication number CN 110236232 A) added Maillard reactants to the tobacco leaf extract for microwave cracking, and used an organic solvent to extract the pyrolysis oil, and added electrons after rotary evaporation. In the smoke liquid, this method can significantly enhance the aroma of electronic cigarettes and enhance the baking smell of electronic cigarettes; however, there may be shortcomings, that is, the tobacco leaf extract contains a large amount of soluble proteins and polysaccharides that have a negative impact on sensory quality; in addition , in papers published by Zheng Jianyu et al., the use of ultrafiltration membrane technology can effectively remove macromolecular substances that have a negative impact on sensory quality in tobacco extracts, and the separation and enrichment technology can reduce the dependence of tobacco extracts on tobacco raw materials , improve quality stability.

发明内容Contents of the invention

针对现有技术的不足,本发明的第一个目的是在于提供一种烟草热解产物,该烟草热解产物用于加热不燃烧卷烟新型烟草制品中,能显著增强烟草制品烟熏香气,增强烟气的丰富性,从而更逼真卷烟的抽吸感受,具有较好的实用价值。Aiming at the deficiencies of the prior art, the first object of the present invention is to provide a tobacco pyrolysis product, which can be used in new tobacco products of heat-not-burn cigarettes, which can significantly enhance the smoky aroma of tobacco products, enhance The richness of the smoke makes the smoking experience of cigarettes more realistic and has good practical value.

本发明的第二个目的是在于提供一种基于透析原理制备烟草热解产物的方法,该方法通过采用透析技术能够在制备烟草浸膏过程中定向除去烟草中对感官品质存在负面影响的大分子物质,并通过对浸膏分子量及热解温度进行控制以获得烟草热解产物,既可以增强新型烟草制品烟草本香,又可以对香气成分进行分离与富集,降低烟草原料对烟草提取物的质量波动影响。The second object of the present invention is to provide a method for preparing tobacco pyrolysis products based on the principle of dialysis, which can directionally remove macromolecules in tobacco that have a negative impact on sensory quality during the preparation of tobacco extract by using dialysis technology Substances, and by controlling the molecular weight and pyrolysis temperature of the extract to obtain tobacco pyrolysis products, it can not only enhance the tobacco aroma of new tobacco products, but also separate and enrich the aroma components, and reduce the influence of tobacco raw materials on tobacco extracts. quality fluctuations.

本发明的第三个目的是在于提供一种烟草热解产物的应用,该烟草热解产物用于加热不燃烧卷烟新型烟草制品中,能显著增强烟草制品的烟熏香气,增强烟气的丰富性,从而更逼真卷烟的抽吸感受,具有较好的实用价值。The third object of the present invention is to provide an application of a tobacco pyrolysis product, which is used in a new type of tobacco product of a heat-not-burn cigarette, which can significantly enhance the smoky aroma of the tobacco product and enhance the richness of the smoke Sex, so that the smoking experience of cigarettes is more realistic, and it has good practical value.

为了实现上述技术目的,本发明提供了一种基于透析原理制备烟草热解产物的方法,其包括以下步骤:In order to achieve the above technical purpose, the present invention provides a method for preparing tobacco pyrolysis products based on the principle of dialysis, which comprises the following steps:

1)将烟草原料进行磨粉,得到烟草粉末;1) Grinding the tobacco raw material to obtain tobacco powder;

2)将烟草粉末通过溶剂提取,得到烟草浸膏;2) Extracting the tobacco powder by a solvent to obtain a tobacco extract;

3)将烟草浸膏通过透析处理,得到除杂烟草浸膏;3) The tobacco extract is processed by dialysis to obtain the tobacco extract for removing impurities;

4)将除杂烟草浸膏进行热解处理,得到烟草热解产物。4) Pyrolyzing the impurity-removing tobacco extract to obtain a tobacco pyrolysis product.

本发明技术方案的关键是在于对烟草浸膏进行透析处理,在透析处理过程中可以根据不同的烟草原料以及烟草原料中包含的对感官质量存在负面影响的大分子物质种类来选择合适孔径的透析袋,能够有效脱除这些大分子物质。The key to the technical solution of the present invention is to perform dialysis treatment on the tobacco extract. During the dialysis treatment, the dialysis with a suitable pore size can be selected according to different tobacco raw materials and the types of macromolecular substances contained in the tobacco raw materials that have a negative impact on the sensory quality. Bags can effectively remove these macromolecules.

作为一个优选的方案,所述烟草原料包括烤烟、白肋烟、香料烟、雪茄烟、晒黄烟、烟草花、烟草秸秆中至少一种。现有技术中常见的烟草原料,都适应于本发明技术方案。As a preferred solution, the tobacco raw material includes at least one of flue-cured tobacco, burley tobacco, oriental tobacco, cigar tobacco, sun-cured tobacco, tobacco flowers, and tobacco stalks. Common tobacco raw materials in the prior art are all suitable for the technical solution of the present invention.

作为一个优选的方案,所述烟草原料磨粉至100~300目。将烟草原料磨粉至适当粒径有利于对烟草原料中的有用成分的高效提取。As a preferred solution, the tobacco raw material is ground to 100-300 mesh. Grinding the tobacco raw material to an appropriate particle size is beneficial to the efficient extraction of useful components in the tobacco raw material.

作为一个优选的方案,所述溶剂提取的过程为:将烟草粉末置于溶剂中进行加热回流提取,所得提取液通过减压蒸馏回收溶剂,再进行冷冻干燥,得到烟草浸膏。As a preferred solution, the solvent extraction process is as follows: the tobacco powder is placed in a solvent for heating and reflux extraction, the obtained extract is distilled under reduced pressure to recover the solvent, and then freeze-dried to obtain tobacco extract.

作为一个优选的方案,烟草粉末与溶剂的固液比为1g:2~10mL,回流温度为70~90℃。As a preferred solution, the solid-to-liquid ratio of the tobacco powder to the solvent is 1g:2-10mL, and the reflux temperature is 70-90°C.

作为一个优选的方案,所述溶剂为乙醇、水、石油醚、乙酸乙酯中至少一种;As a preferred solution, the solvent is at least one of ethanol, water, petroleum ether, and ethyl acetate;

作为一个优选的方案,所述减压蒸馏温度为40~65℃。As a preferred solution, the vacuum distillation temperature is 40-65°C.

作为一个优选的方案,所述透析处理过程中采用的透析袋截留分子量大小为0.3KD~30KD。由表1中可以看出,通过不同截留分子量的透析袋截留得到的烟草浸膏其主要成分的含量是完全不同的,综合考虑烟草浸膏中本身包含的有用成分含量和不利杂质含量以及热解产物中有用成分的含量等,透析袋截留分子量大小较优选为20KD~10KD。As a preferred solution, the molecular weight cut-off of the dialysis bag used in the dialysis treatment process is 0.3KD-30KD. As can be seen from Table 1, the content of the main components of the tobacco extract obtained by dialysis bags with different molecular weight cut-offs is completely different. Considering the content of useful components and unfavorable impurities contained in the tobacco extract itself and the content of pyrolysis The content of useful ingredients in the product, etc., the molecular weight cut-off of the dialysis bag is more preferably 20KD-10KD.

作为一个优选的方案,所述透析处理过程中采用的透析液为质量百分比浓度为5~25%的乙醇水溶液,透析次数为2~4次,每次透析时间为5~7h,烟草浸膏与透析液的质量体积比为1g:50~100mL。As a preferred solution, the dialysate used in the dialysis treatment process is an aqueous ethanol solution with a mass percent concentration of 5-25%, the number of dialysis times is 2-4 times, and the dialysis time is 5-7 hours each time. Tobacco extract and The mass volume ratio of the dialysate is 1g:50-100mL.

作为一个优选的方案,所述采用微波加热热解方式,热解处理过程中热解温度控制在200℃~1000℃温度区域内。As a preferred solution, microwave heating and pyrolysis is adopted, and the pyrolysis temperature is controlled within a temperature range of 200° C. to 1000° C. during the pyrolysis treatment.

作为一个较优选的方案,所述热解处理的过程中将除杂烟草浸膏在 200℃~1000℃温度区域内任意温度下进行热解,得到烟草热解产物,或者,将除杂烟草浸膏在200℃~350℃、>350℃且≤450℃、>450℃且≤550℃、>550℃且≤650℃、>650℃且≤750℃、>750℃且≤850℃或>850℃且≤1000℃温度区域内进行热解,将任意两个以上温度区域内所得热解产物混合,得到烟草热解产物。进一步优选,将除杂烟草浸膏在200℃~350℃、>350℃且≤450℃、>450℃且≤550℃、>550℃且≤650℃、>650℃且≤750℃、>750℃且≤850℃或>850℃且≤1000℃温度区域内进行热解,将任意三个或四个温度区域内所得热解产物混合,得到烟草热解产物。更进一步优选,将除杂烟草浸膏分成若干份,且分别在 200℃~350℃、>350℃且≤450℃、>450℃且≤550℃、>550℃且≤650℃、> 650℃且≤750℃、>750℃且≤850℃和>850℃且≤1000℃温度区域内进行热解,将200℃~350℃、>350℃且≤450℃、>450℃且≤550℃和>550℃且≤650℃四个温度区域内所得热解产物按照质量比1~3:0.5~1.5:1:1~3混合得到烟草热解产物;或者,将200℃~350℃、>350℃且≤450℃和>450℃且≤550℃三个温度区域内所得热解产物按照质量比0.5~1.5:0.5~1.5:1混合得到烟草热解产物;或者,将650℃~750℃、>750℃且≤850℃和>850℃且≤1000℃三个温度区域内所得热解产物按照质量比0.5~1.5:0.5~1.5:1混合,得到烟草热解产物。除杂烟草浸膏在不同温度下热解所得烟草热解产物的成分是存在差异的,将多个不同温度下的烟草热解产物进行复合,可以更好地还原和增强烟草本香。As a more preferred solution, during the pyrolysis treatment, the impurity-removing tobacco extract is pyrolyzed at any temperature in the temperature range of 200°C to 1000°C to obtain tobacco pyrolysis products, or the impurity-removing tobacco extract Paste at 200°C to 350°C, >350°C and ≤450°C, >450°C and ≤550°C, >550°C and ≤650°C, >650°C and ≤750°C, >750°C and ≤850°C or >850°C ℃ and ≤ 1000 ℃ for pyrolysis, and the pyrolysis products obtained in any two or more temperature regions are mixed to obtain tobacco pyrolysis products. More preferably, the impurity-removing tobacco extract is heated at 200°C to 350°C, >350°C and ≤450°C, >450°C and ≤550°C, >550°C and ≤650°C, >650°C and ≤750°C, >750°C ℃ and ≤ 850 ℃ or > 850 ℃ and ≤ 1000 ℃ for pyrolysis, and mixing pyrolysis products obtained in any three or four temperature regions to obtain tobacco pyrolysis products. Even more preferably, the impurity-removing tobacco extract is divided into several parts, and respectively at 200°C to 350°C, >350°C and ≤450°C, >450°C and ≤550°C, >550°C and ≤650°C, >650°C And ≤750°C, >750°C and ≤850°C and >850°C and ≤1000°C temperature range for pyrolysis, 200°C to 350°C, >350°C and ≤450°C, >450°C and ≤550°C and The pyrolysis products obtained in the four temperature regions of >550°C and ≤650°C are mixed according to the mass ratio of 1~3:0.5~1.5:1:1~3 to obtain tobacco pyrolysis products; or, 200°C~350°C, >350°C ℃ and ≤ 450 ℃ and > 450 ℃ and ≤ 550 ℃ the pyrolysis products obtained in the three temperature zones are mixed according to the mass ratio of 0.5-1.5:0.5-1.5:1 to obtain tobacco pyrolysis products; or, 650 ℃ ~ 750 ℃, The pyrolysis products obtained in the three temperature regions of >750°C and ≤850°C and >850°C and ≤1000°C are mixed according to the mass ratio of 0.5-1.5:0.5-1.5:1 to obtain tobacco pyrolysis products. There are differences in the composition of the tobacco pyrolysis products obtained by pyrolyzing the impurity-removing tobacco extract at different temperatures. Combining multiple tobacco pyrolysis products at different temperatures can better restore and enhance the original aroma of tobacco.

作为一个优选的方案,所述热解过程中产生的热解气采用冷阱进行捕集,产生的热解油采用冷阱中用于捕集热解气的吸收液进行溶解吸收。作为一个较优选的方案,所述热解气采用冷阱进行捕集时,以液氮作为冷阱剂,以乙醇作为吸收液,除杂烟草浸膏的质量与吸收液的体积比为1g:5~20mL。溶解吸收过程中可以采用超声或振荡辅助加速溶解。As a preferred solution, the pyrolysis gas produced during the pyrolysis process is captured by a cold trap, and the pyrolysis oil produced is dissolved and absorbed by the absorption liquid used to capture the pyrolysis gas in the cold trap. As a preferred scheme, when the pyrolysis gas is captured by a cold trap, liquid nitrogen is used as the cold trap agent, and ethanol is used as the absorption liquid, and the volume ratio of the quality of the impurity-removing tobacco extract to the absorption liquid is 1g: 5~20mL. During the dissolution and absorption process, ultrasound or vibration can be used to assist in accelerating the dissolution.

作为一个优选的方案,所述热解过程中产生的热解气采用吸附材料进行捕集,产生的热解油与用于捕集热解气的吸附材料混合采用溶剂溶解萃取。作为一个较优选的方案,所述热解气采用吸附材料捕集时,以XAD-2吸附管作为吸附材料。采用的溶剂为乙醇,相对除杂烟草浸膏的质量与乙醇的体积比为1g:5~20mL。溶解萃取过程中可以采用超声或振荡辅助加速溶解。As a preferred solution, the pyrolysis gas generated during the pyrolysis process is captured by an adsorption material, and the generated pyrolysis oil is mixed with the adsorption material used to capture the pyrolysis gas and extracted by solvent dissolution. As a preferred solution, when the pyrolysis gas is captured by an adsorption material, XAD-2 adsorption tube is used as the adsorption material. The solvent used is ethanol, and the volume ratio of the mass of the impurity-removing tobacco extract to the ethanol is 1g:5-20mL. During the dissolution extraction process, ultrasound or vibration can be used to assist in accelerating the dissolution.

本发明还提供了一种烟草热解产物,其由所述制备方法得到。The invention also provides a tobacco pyrolysis product obtained by the preparation method.

本发明还提供了一种烟草热解产物的应用,其应用于加热不燃烧卷烟。由于不同孔径透析袋及不同热解温度下得到的烟草热解产物包含的主要成分存在差异,将其用于加热不燃烧卷烟表现出不同的应用效果。本发明技术方案通过优选透析袋截留分子量大小为20KD~10KD,定向除去烟草中对感官品质存在负面影响的大分子物质,再将除杂烟草浸膏分别几个不同温度下进行热解,在各温度下的热解产物再按适当的比例复配成混合热解产物,在不燃烧卷烟中表现出较佳的应用效果。The invention also provides an application of tobacco pyrolysis product, which is applied to heat-not-burn cigarettes. Due to the differences in the main components contained in the tobacco pyrolysis products obtained under different pore diameters and different pyrolysis temperatures, the use of the dialysis bags in heat-not-burn cigarettes shows different application effects. The technical scheme of the present invention optimizes the molecular weight cut-off of the dialysis bag to be 20KD~10KD, removes macromolecular substances in tobacco that have a negative impact on the sensory quality, and then pyrolyzes the impurity-removing tobacco extract at several different temperatures. The pyrolysis products at high temperature are then compounded into a mixed pyrolysis product in an appropriate proportion, which shows a better application effect in non-burning cigarettes.

作为一个优选的方案,烟草热解产物在加热不燃烧卷烟中的添加量按照 1~20mg/支添加。As a preferred solution, the amount of tobacco pyrolysis products added to heat-not-burn cigarettes is 1-20 mg/cigarette.

本发明提供了一种烟草热解产物的制备方法,采用如下步骤制备获得:The invention provides a method for preparing a tobacco pyrolysis product, which is obtained through the following steps:

(1)烟草磨成烟草粉末(1) Tobacco is ground into tobacco powder

将烟草原料平衡(温度22±2℃,相对湿度60±5%)24小时后进行磨粉处理,磨粉后烟末的直径约为200目;烟草原料包括但不限于烤烟、白肋烟、香料烟、雪茄烟、晒黄烟、烟草花、烟草秸秆中一种或多种的混合物;Balance the tobacco raw material (temperature 22 ± 2 ° C, relative humidity 60 ± 5%) for 24 hours before grinding, the diameter of the powder after grinding is about 200 mesh; tobacco raw material includes but not limited to flue-cured tobacco, Burley tobacco, A mixture of one or more of oriental tobacco, cigar tobacco, sun-dried tobacco, tobacco flower, and tobacco straw;

(2)烟草浸膏的制备(2) Preparation of Tobacco Extract

采用溶剂加热回流的方式进行提取,将提取液减压蒸干后,进行冷冻干燥,即得烟草浸膏;所述溶剂包括但不限于乙醇、水、石油醚、乙酸乙酯及其混合物;烟末与溶剂的比例=1g:2~10mL;加热方式优先选择水浴加热,加热温度优先选择70~90℃;减压蒸馏装置中水温为40~65℃,蒸馏至无液体滴出;The solvent is heated and refluxed for extraction, the extract is evaporated to dryness under reduced pressure, and then freeze-dried to obtain tobacco extract; the solvent includes but is not limited to ethanol, water, petroleum ether, ethyl acetate and mixtures thereof; The ratio of powder to solvent = 1g: 2~10mL; the heating method is preferably water bath heating, and the heating temperature is preferably 70~90°C; the water temperature in the vacuum distillation device is 40~65°C, distill until no liquid drips out;

(3)除杂烟草浸膏的制备(3) preparation of impurity-removing tobacco extract

将制备的烟草浸膏装入透析袋中,用透析夹密封后,进行进行透析除杂;所述透析袋可选择分子量为0.3KD~30KD之间,亦可次优选择膜分离技术进行筛分,然而膜分离技术暂无法实现工业化生产;透析液优选5~25%乙醇水溶液;进行三次透析,每次透析时间为6h,烟草浸膏与透析液的比例优选为1g:100mL。透析后进行旋转蒸发得到不同分子量的烟草浸膏。Put the prepared tobacco extract into a dialysis bag, seal it with a dialysis clip, and then carry out dialysis to remove impurities; the dialysis bag can be selected with a molecular weight between 0.3KD and 30KD, and can also be screened by suboptimal membrane separation technology However, membrane separation technology cannot realize industrialized production for the time being; the preferred 5-25% ethanol aqueous solution for dialysate; carry out three dialysis, each dialysis time is 6h, the ratio of tobacco extract and dialysate is preferably 1g:100mL. Rotary evaporation was performed after dialysis to obtain tobacco extracts with different molecular weights.

(4)对除杂烟草浸膏进行热解;(4) pyrolyzing the tobacco extract for removing impurities;

对除杂烟草浸膏进行热解,热解产物中包含热解气和热解油两部分。采用溶液-冷阱捕集的方法吸收热解气,热解完毕后将热解油转移至吸收热解气的冷阱溶液中,进行充分溶解吸收;所述热解方式包括但不限于微波加热热解、红外加热热解、电磁加热热解或电阻丝加热热解;所述热解温度在200℃~1000℃间,热解过程可以将除杂烟草浸膏分别在200℃~1000℃温度范围内的在多个温度区域内进行热解,再将各温度区域内热解所得热解产物进行复合,如将除杂烟草浸膏在200℃~350℃、>350℃且≤450℃、>450℃且≤550℃、>550℃且≤650℃、>650℃且≤750℃、>750℃且≤850℃或>850℃且≤1000℃温度区域内进行热解,将任意两个以上温度区域内所得热解产物混合,得到烟草热解产物;所述热解气优先选择冷阱捕集方法,冷阱装置包括但不限于采用液氮作为冷阱剂;冷阱吸收液包括但不限于乙醇;除杂烟草浸膏质量与冷阱中吸收液体积的比例=1g: 5~20mL,溶解吸收过程可以选择超声溶解或振荡溶解的方式。若热解装置不支持安装冷阱装置,次优选择具有功能的吸附材料捕集热解气,如XAD-2吸附管,捕集了热解气的吸附材料与热解油混合采用溶剂溶解萃取,溶剂为乙醇,除杂烟草浸膏质量与溶剂的体积比例=1g:5~20mL。The impurity-removed tobacco extract is pyrolyzed, and the pyrolysis product includes pyrolysis gas and pyrolysis oil. The pyrolysis gas is absorbed by the method of solution-cold trap capture. After the pyrolysis is completed, the pyrolysis oil is transferred to the cold trap solution for absorbing the pyrolysis gas, and fully dissolved and absorbed; the pyrolysis method includes but is not limited to microwave heating Pyrolysis, infrared heating pyrolysis, electromagnetic heating pyrolysis or resistance wire heating pyrolysis; the pyrolysis temperature is between 200°C and 1000°C, and the pyrolysis process can remove impurities from the tobacco extract at a temperature of 200°C to 1000°C Within the range, pyrolysis is carried out in multiple temperature regions, and then the pyrolysis products obtained by pyrolysis in each temperature region are compounded, such as removing impurities from tobacco extract at 200°C to 350°C, >350°C and ≤450°C, >450°C and ≤550°C, >550°C and ≤650°C, >650°C and ≤750°C, >750°C and ≤850°C or >850°C and ≤1000°C, any two The pyrolysis products obtained in the above temperature range are mixed to obtain tobacco pyrolysis products; the pyrolysis gas is preferably collected by a cold trap, and the cold trap device includes but is not limited to the use of liquid nitrogen as a cold trap agent; the cold trap absorption liquid includes but Not limited to ethanol; the ratio of the mass of impurity-removing tobacco extract to the volume of the absorption liquid in the cold trap = 1g: 5-20mL, and the dissolution and absorption process can be done by ultrasonic or vibrational dissolution. If the pyrolysis device does not support the installation of a cold trap device, it is sub-optimal to choose a functional adsorption material to capture the pyrolysis gas, such as XAD-2 adsorption tube. The adsorption material that captures the pyrolysis gas is mixed with the pyrolysis oil and extracted by solvent dissolution , the solvent is ethanol, and the volume ratio of the impurity-removing tobacco extract quality to the solvent=1g:5~20mL.

(5)将烟草热解产物应用于加热不燃烧新型烟草制品中;(5) Apply tobacco pyrolysis products to new heat-not-burn tobacco products;

将烟草热解产物注射至加热卷烟中,待溶剂蒸发后,即可进行抽吸。The pyrolysis product of tobacco is injected into the heated cigarette, and after the solvent evaporates, it can be smoked.

相对现有技术,本发明技术方案带来的有益技术效果:Compared with the prior art, the beneficial technical effect brought by the technical solution of the present invention:

本发明提供了一种烟草热解产物,用于新型烟草制品,能显著增强新型烟草制品烟熏香气,增强烟气的丰富性,从而更逼真卷烟的抽吸感受,具有较好的实用价值。The invention provides a tobacco pyrolysis product, which is used in new-type tobacco products, can significantly enhance the smoky aroma of the new-type tobacco products, enhance the richness of the smoke, thereby more realistically smoking the cigarette, and has good practical value.

本发明的提供了一种基于透析原理制备烟草热解产物的方法,该方法通过采用透析技术能够在制备烟草浸膏过程中定向除去烟草中对感官品质存在负面影响的大分子物质,并通过对浸膏分子量及热解温度进行控制以获得烟草热解产物,既可以增强新型烟草制品烟草本香,又可以对香气成分进行分离与富集,降低烟草原料对烟草提取物的质量波动影响。The present invention provides a method for preparing tobacco pyrolysis products based on the principle of dialysis, which can directionally remove macromolecular substances in tobacco that have a negative impact on sensory quality in the process of preparing tobacco extract by using dialysis technology, and by using dialysis technology The molecular weight of the extract and the pyrolysis temperature are controlled to obtain tobacco pyrolysis products, which can not only enhance the tobacco aroma of new tobacco products, but also separate and enrich the aroma components, and reduce the influence of tobacco raw materials on the quality fluctuation of tobacco extracts.

附图说明Description of drawings

图1为小于30KD的烟草浸膏在400℃的气相色谱总离子流图。Figure 1 is a gas chromatographic total ion chromatogram of tobacco extract less than 30KD at 400°C.

图2为小于15KD的烟草浸膏在400℃的气相色谱总离子流图。Figure 2 is a gas chromatographic total ion chromatogram of tobacco extract less than 15KD at 400°C.

图3为小于10KD的烟草浸膏在400℃的气相色谱总离子流图。Figure 3 is a gas chromatographic total ion chromatogram of tobacco extract less than 10KD at 400°C.

具体实施方式Detailed ways

下面结合具体实施例对本发明作进一步描述。以下实施例旨在说明本发明而不是对本发明的进一步限定。The present invention will be further described below in conjunction with specific embodiments. The following examples are intended to illustrate the present invention without further limiting the invention.

实施例1Example 1

选择烤烟烟叶原料,平衡24h后进行磨粉处理,烟末粒度约为200目。采用热回流的方式制备烟草浸膏,水浴温度80℃,溶剂采用乙醇:水体积比=1:1,烟末与溶剂的比例=1g:5mL,加热回流时间3小时。将萃取液旋转蒸干后进行冷冻干燥处理,冷冻干燥时间48小时,制备烟草浸膏;将所得烟草浸膏转移至15KD 的透析袋中,进行透析处理,透析液选择20%乙醇水溶液,透析三次,每次透析时间为6h,烟草浸膏与透析液的比例为1g:100mL。取经透析后的烟叶浸膏三份,每份约10g,分别在300℃、400℃、500℃三个温度点进行微波热解,冷阱中吸收液为50mL,吸收液选择乙醇,热解油采用吸收热解气的吸收液进行超声辅助溶解。三个温度下的裂解产物按照质量比M300℃浸膏:M400℃浸膏:M500℃浸膏=1: 1:1的方式加入到加热卷烟中,添加量为10mg/支,并与常规烟草浸膏热解产物 (按照实施例1制备,只是不经过透析处理)按照相同的复配比例进行感官质量对比评价,结果如表2所示。感官总体评价,透析后烟草浸膏热解产物复配的加热卷烟烟气更细腻,香气透发性更好,余味更加干净。The raw material of flue-cured tobacco leaves is selected, and after equilibrating for 24 hours, it is pulverized, and the particle size of the tobacco powder is about 200 mesh. Tobacco extract was prepared by heat reflux, the water bath temperature was 80°C, the solvent was ethanol: water volume ratio = 1:1, the ratio of tobacco powder to solvent = 1g: 5mL, and the heating and reflux time was 3 hours. Rotate the extract to dryness and then freeze-dry it for 48 hours to prepare tobacco extract; transfer the obtained tobacco extract to a 15KD dialysis bag for dialysis treatment, choose 20% ethanol aqueous solution as the dialysate, and dialyze three times , each dialysis time is 6h, the ratio of tobacco extract and dialysate is 1g: 100mL. Take three parts of tobacco leaf extract after dialysis, about 10g each, and carry out microwave pyrolysis at three temperature points of 300°C, 400°C, and 500°C respectively. The absorption liquid in the cold trap is 50mL. Ultrasonic-assisted dissolution is performed using an absorption liquid that absorbs pyrolysis gas. The pyrolysis products at the three temperatures were added to heated cigarettes according to the mass ratio of M 300 °C extract: M 400 °C extract: M 500 °C extract = 1: 1: 1, the addition amount was 10mg/stick, and was mixed with Conventional tobacco extract pyrolysis products (prepared according to Example 1, but without dialysis treatment) were subjected to sensory quality comparative evaluation according to the same compounding ratio, and the results are shown in Table 2. According to the overall sensory evaluation, the smoke of the heated cigarette compounded with the pyrolysis product of tobacco extract after dialysis is more delicate, the aroma is more transparent, and the aftertaste is cleaner.

将实施例1中的透析袋替换为30KD和10KD,在相同制备的除杂烟草浸膏,在400℃的气相色谱总离子流图如图1~图3所述。The dialysis bag in Example 1 was replaced with 30KD and 10KD, and the impurity-removing tobacco extract prepared in the same way, the gas chromatographic total ion chromatogram at 400°C is as shown in Figures 1-3.

表1.为实施例1中30KD、15KD、10KD三种不同透析袋所得除杂烟草浸膏在 400℃条件下热解产物的香气成分测定结果Table 1. is 30KD, 15KD, 10KD in embodiment 1 three kinds of different dialysis bag gained impurity-removing tobacco extracts under the condition of 400 DEG C of the aroma component determination result of the pyrolysis product

Figure BDA0003416916430000071
Figure BDA0003416916430000071

Figure BDA0003416916430000081
Figure BDA0003416916430000081

实施例2Example 2

选择白肋烟叶原料,平衡24h后进行磨粉处理,烟末粒度约为200目。采用热回流的方式制备烟草浸膏,水浴温度80℃,溶剂采用乙醇:水体积比=8:2,烟末与溶剂的比例=1g:7mL,加热回流时间3小时。将萃取液旋转蒸干后进行冷冻干燥处理,冷冻干燥时间48小时,制备烟草浸膏;将所得烟草浸膏转移至10KD 的透析袋中,进行透析处理,透析液选择20%乙醇水溶液,透析三次,每次透析时间为6h,烟草浸膏与透析液的比例为1g:100mL。取经透析后的烟叶浸膏三份,每份约10g,分别在400℃、500℃、600℃三个温度点进行微波热解,冷阱中吸收液为100mL,吸收液选择乙醇,热解油采用吸收热解气的吸收液进行超声辅助溶解。三个温度下的裂解产物按照质量比M400℃浸膏:M500℃浸膏:M600℃浸膏=1: 1:1的方式复配加入到加热卷烟中,添加量为10mg/支,并与常规烟草浸膏热解产物(按照实施例2制备,只是不经过透析处理)按照相同的复配比例进行感官质量对比评价,结果如表2所示。感官总体评价,透析后烟草浸膏热解产物复配的加热卷烟烟气更飘逸细腻,香气透发性更好。The raw material of Burley tobacco leaves was selected, and after 24 hours of equilibration, it was milled, and the particle size of the tobacco powder was about 200 mesh. Tobacco extract was prepared by heat reflux, the water bath temperature was 80°C, the solvent was ethanol:water volume ratio=8:2, the ratio of tobacco powder to solvent=1g:7mL, and the heating and reflux time was 3 hours. Rotate the extract to dryness and freeze-dry it for 48 hours to prepare tobacco extract; transfer the obtained tobacco extract to a dialysis bag of 10KD for dialysis treatment, select 20% ethanol aqueous solution as the dialysate, and dialyze three times , each dialysis time is 6h, the ratio of tobacco extract and dialysate is 1g:100mL. Take three parts of tobacco leaf extract after dialysis, about 10g each, and carry out microwave pyrolysis at three temperature points of 400°C, 500°C, and 600°C respectively. The absorption liquid in the cold trap is 100mL. Ultrasonic-assisted dissolution is performed using an absorption liquid that absorbs pyrolysis gas. The pyrolysis products at the three temperatures are compounded and added to heated cigarettes according to the mass ratio of M 400 °C extract: M 500 °C extract: M 600 °C extract = 1: 1: 1, the addition amount is 10mg/stick, And compare and evaluate the sensory quality with the conventional tobacco extract pyrolysis product (prepared according to Example 2, but without dialysis treatment) according to the same compounding ratio, and the results are shown in Table 2. According to the overall sensory evaluation, the smoke of the heated cigarette compounded with the pyrolysis product of tobacco extract after dialysis is more elegant and delicate, and the aroma permeability is better.

实施例3Example 3

选择香料烟叶原料,平衡24h后进行磨粉处理,烟末粒度约为200目。采用热回流的方式制备烟草浸膏,水浴温度80℃,溶剂采用乙醇:水体积比=3:1,烟末与溶剂的比例=1g:7mL,加热回流时间3小时。将萃取液旋转蒸干后进行冷冻干燥处理,冷冻干燥时间48小时,制备烟草浸膏;将所得烟草浸膏转移至20KD 的透析袋中,进行透析处理,透析液选择20%乙醇水溶液,透析三次,每次透析时间为6h,烟草浸膏与透析液的比例为1g:100mL。取经透析后的烟叶浸膏三份,每份约10g,分别在700℃、800℃、900℃三个温度点进行微波热解,冷阱中吸收液为100mL,吸收液选择乙醇,热解油采用吸收热解气的吸收液进行超声辅助溶解。三个温度下的裂解产物按照质量比M700℃浸膏:M800℃浸膏:M900℃浸膏=1: 1:1的方式复配加入到加热卷烟中,添加量为10mg/支,并与无复配,单独采用 700℃裂解产物进行感官质量对比评价,结果如表2所示。感官总体评价,透析后烟草浸膏热解产物复配的加热卷烟烟气丰富度大幅度提高。The raw material of oriental tobacco leaves was selected, and after equilibrating for 24 hours, it was milled, and the particle size of the tobacco powder was about 200 mesh. Tobacco extract was prepared by heat reflux, the water bath temperature was 80°C, the solvent was ethanol:water volume ratio=3:1, the ratio of tobacco powder to solvent=1g:7mL, and the heating and reflux time was 3 hours. Rotate the extract to dryness and freeze-dry it for 48 hours to prepare tobacco extract; transfer the obtained tobacco extract to a 20KD dialysis bag for dialysis treatment, select 20% ethanol aqueous solution as the dialysate, and dialyze three times , each dialysis time is 6h, the ratio of tobacco extract and dialysate is 1g:100mL. Take three parts of tobacco leaf extract after dialysis, about 10g each, and carry out microwave pyrolysis at three temperature points of 700°C, 800°C, and 900°C respectively. The absorption liquid in the cold trap is 100mL. Ultrasonic-assisted dissolution is performed using an absorption liquid that absorbs pyrolysis gas. The pyrolysis products at the three temperatures are compounded and added to heated cigarettes according to the mass ratio of M 700 °C extract: M 800 °C extract: M 900 °C extract = 1: 1: 1, and the added amount is 10mg/stick. And with no compounding, the pyrolysis product at 700°C was used alone for sensory quality comparison evaluation, and the results are shown in Table 2. According to the overall sensory evaluation, the smoke richness of heated cigarettes compounded with pyrolysis products of tobacco extract after dialysis is greatly improved.

表2实施例1~3烟草浸膏热解产物感官评价结果Table 2 Sensory evaluation results of tobacco extract pyrolysis products of Examples 1-3

Figure BDA0003416916430000091
Figure BDA0003416916430000091

Figure BDA0003416916430000101
Figure BDA0003416916430000101

Claims (14)

1.一种基于透析原理制备烟草热解产物的方法,其特征在于:包括以下步骤:1. A method for preparing tobacco pyrolysis products based on the principle of dialysis, characterized in that: comprising the following steps: 1)将烟草原料进行磨粉,得到烟草粉末;1) Grinding the tobacco raw material to obtain tobacco powder; 2)将烟草粉末通过溶剂提取,得到烟草浸膏;2) Extracting the tobacco powder by a solvent to obtain a tobacco extract; 3)将烟草浸膏通过透析处理,得到除杂烟草浸膏;3) The tobacco extract is processed by dialysis to obtain the tobacco extract for removing impurities; 4)将除杂烟草浸膏进行热解处理,得到烟草热解产物。4) Pyrolyzing the impurity-removing tobacco extract to obtain a tobacco pyrolysis product. 2.根据权利要求1所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述烟草原料包括烤烟、白肋烟、香料烟、雪茄烟、晒黄烟、烟草花、烟草秸秆中至少一种。2. A method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 1, characterized in that: the tobacco raw materials include flue-cured tobacco, burley tobacco, oriental tobacco, cigar tobacco, sun-dried tobacco, tobacco flower, tobacco At least one kind of straw. 3.根据权利要求1所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述烟草原料磨粉至100~300目。3 . The method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 1 , characterized in that: the tobacco raw material is ground to 100-300 mesh. 4.根据权利要求1所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述溶剂提取的过程为:将烟草粉末置于溶剂中进行加热回流提取,所得提取液通过减压蒸馏回收溶剂,再进行冷冻干燥,得到烟草浸膏。4. A method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 1, characterized in that: the solvent extraction process is: placing the tobacco powder in a solvent for heating and reflux extraction, and the obtained extract is passed through The solvent is recovered by distillation under reduced pressure, and then freeze-dried to obtain tobacco extract. 5.根据权利要求4所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:5. A method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 4, characterized in that: 烟草粉末与溶剂的固液比为1g:2~10mL,回流温度为70~90℃;The solid-to-liquid ratio of tobacco powder to solvent is 1g:2-10mL, and the reflux temperature is 70-90°C; 所述溶剂为乙醇、水、石油醚、乙酸乙酯中至少一种;Described solvent is at least one in ethanol, water, sherwood oil, ethyl acetate; 所述减压蒸馏温度为40~65℃。The temperature of the vacuum distillation is 40-65°C. 6.根据权利要求1所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述透析处理过程中采用的透析袋截留分子量大小为0.3KD~30KD。6 . The method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 1 , characterized in that: the molecular weight cut-off of the dialysis bag used in the dialysis process is 0.3KD-30KD. 7.根据权利要求1所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述透析处理过程中采用的透析液为质量百分比浓度为5~25%的乙醇水溶液,透析次数为2~4次,每次透析时间为5~7h,烟草浸膏与透析液的质量体积比为1g:50~100mL。7. A method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 1, characterized in that: the dialysate used in the dialysis treatment process is an aqueous ethanol solution with a concentration of 5% to 25% by mass, and the dialysis The frequency is 2 to 4 times, each dialysis time is 5 to 7 hours, and the mass volume ratio of tobacco extract to dialysate is 1g:50 to 100mL. 8.根据权利要求1所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述热解处理采用微波加热热解方式,热解处理过程中热解温度控制在200℃~1000℃温度区域内。8. A method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 1, characterized in that: the pyrolysis treatment adopts a microwave heating pyrolysis method, and the pyrolysis temperature is controlled at 200°C during the pyrolysis treatment process ~1000℃ temperature range. 9.根据权利要求1或8所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述热解处理过程中将除杂烟草浸膏在200℃~1000℃温度区域内任意温度下进行热解,得到烟草热解产物,或者,将除杂烟草浸膏在200℃~350℃、>350℃且≤450℃、>450℃且≤550℃、>550℃且≤650℃、>650℃且≤750℃、>750℃且≤850℃或>850℃且≤1000℃温度区域内进行热解,将任意两个以上温度区域内所得热解产物混合,得到烟草热解产物。9. A method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 1 or 8, characterized in that: during the pyrolysis process, the impurity-removed tobacco extract is placed in the temperature range of 200°C to 1000°C Carry out pyrolysis at any temperature to obtain tobacco pyrolysis products, or, remove impurities from tobacco extract at 200°C to 350°C, >350°C and ≤450°C, >450°C and ≤550°C, >550°C and ≤650°C ℃, >650°C and ≤750°C, >750°C and ≤850°C, or >850°C and ≤1000°C temperature range for pyrolysis, mixing pyrolysis products obtained in any two or more temperature ranges to obtain tobacco pyrolysis product. 10.根据权利要求1所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述热解过程中产生的热解气采用冷阱进行捕集,产生的热解油采用冷阱中用于捕集热解气的吸收液进行溶解吸收;或者,所述热解过程中产生的热解气采用吸附材料进行捕集,产生的热解油与用于捕集热解气的吸附材料混合采用溶剂溶解萃取。10. A method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 1, characterized in that: the pyrolysis gas produced in the pyrolysis process is captured by a cold trap, and the pyrolysis oil produced is The absorption liquid used to capture the pyrolysis gas in the cold trap is dissolved and absorbed; or, the pyrolysis gas generated during the pyrolysis process is captured by an adsorption material, and the generated pyrolysis oil is used to capture the pyrolysis gas. The adsorbent material mixture is extracted by solvent dissolution. 11.根据权利要求10所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述热解气采用冷阱进行捕集时,以液氮作为冷阱剂,以乙醇作为吸收液,除杂烟草浸膏的质量与吸收液的体积比为1g:5~20mL。11. A method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 10, characterized in that: when the pyrolysis gas is captured by a cold trap, liquid nitrogen is used as the cold trap agent, and ethanol is used as the cold trap agent. Absorbing liquid, the volume ratio of the mass of the impurity-removing tobacco extract to the absorbing liquid is 1g:5-20mL. 12.根据权利要求10所述的一种基于透析原理制备烟草热解产物的方法,其特征在于:所述热解气采用吸附材料捕集时,以XAD-2吸附管作为吸附材料。12. A method for preparing tobacco pyrolysis products based on the principle of dialysis according to claim 10, characterized in that: when the pyrolysis gas is captured by an adsorption material, an XAD-2 adsorption tube is used as the adsorption material. 13.一种烟草热解产物,其特征在于:由权利要求1~12任一项所述制备方法得到。13. A tobacco pyrolysis product, characterized in that it is obtained by the preparation method described in any one of claims 1-12. 14.权利要求13所述的一种烟草热解产物的应用,其特征在于:应用于加热不燃烧卷烟。14. The application of a tobacco pyrolysis product according to claim 13, characterized in that it is applied to heat-not-burn cigarettes.
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