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CN116219293A - Super-thick and super-high-power steel for hydroelectric engineering and manufacturing method thereof - Google Patents

Super-thick and super-high-power steel for hydroelectric engineering and manufacturing method thereof Download PDF

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CN116219293A
CN116219293A CN202310167174.6A CN202310167174A CN116219293A CN 116219293 A CN116219293 A CN 116219293A CN 202310167174 A CN202310167174 A CN 202310167174A CN 116219293 A CN116219293 A CN 116219293A
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胡海洋
隋轶
孙殿东
王勇
韩严法
陈捷
胡昕明
颜秉宇
王爽
高天宇
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Angang Steel Co Ltd
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Abstract

本发明涉及一种超厚超高强大型水电工程用钢及其制造方法,钢中化学成分为C:0.10%~0.15%;Si:0.06%~0.10%;Mn:0.90%~1.50%;P≤0.008%;S≤0.001%;Ni:1.75%~2.4%;Cr:0.55%~0.75%;Mo:0.75%~1.2%;Ti:0.07%~0.11%;N:0.015%~0.025%;CeO2:0.10%~0.20%;Al:0.02%~0.04%;[H]≤1.5ppm;[O]≤8ppm;余量为Fe和杂质。采用低碳、低锰、Ni+Cr+Mo+Ti低合金化成分设计,配合电渣重熔+轧制+离线调质热处理工艺,利用高熔点Ti(CN)、CeO2细化晶粒的作用,实现了大厚度电渣坯的高渗透轧制生产,最终获得晶粒度为7.5级及以上、110~160mm厚1000MPa级超厚超高强钢板。

Figure 202310167174

The invention relates to an ultra-thick, ultra-high-power and large-scale steel for hydropower engineering and a manufacturing method thereof. The chemical composition in the steel is C: 0.10%-0.15%; Si: 0.06%-0.10%; Mn: 0.90%-1.50%; P≤ 0.008%; S≤0.001%; Ni: 1.75%~2.4%; Cr: 0.55%~0.75%; Mo: 0.75%~1.2%; Ti: 0.07%~0.11%; N: 0.015%~ 0.025 %; : 0.10%~0.20%; Al: 0.02%~0.04%; [H]≤1.5ppm; [O]≤8ppm; the balance is Fe and impurities. Adopt low carbon, low manganese, Ni+Cr+Mo+Ti low alloying composition design, cooperate with electroslag remelting + rolling + off-line quenching and tempering heat treatment process, and use high melting point Ti(CN) and CeO2 to refine the grain , realized the high penetration rolling production of large-thickness electroslag blanks, and finally obtained ultra-thick and ultra-high-strength steel plates with a grain size of 7.5 and above, 110-160mm thick and 1000MPa grade.

Figure 202310167174

Description

一种超厚超高强大型水电工程用钢及其制造方法An ultra-thick, ultra-high-strength, large-scale hydropower engineering steel and its manufacturing method

技术领域technical field

本发明涉及水电用钢制造技术领域,尤其涉及一种超厚超高强大型水电工程用钢及其制造方法。The invention relates to the technical field of steel manufacturing for hydropower, in particular to an ultra-thick, super-high-strength large-scale steel for hydropower engineering and a manufacturing method thereof.

背景技术Background technique

随着水电工程的大型化发展趋势,水电用钢的强度级别将进一步提高,与此同时,钢板的使用厚度也将突破100mm。钢板厚度的增加会带来Z向性能降低、组织不均匀、生产成本高等一系列问题,再加上水电用钢对性能要求的特殊性,生产难度将进一步增大。With the development trend of large-scale hydropower projects, the strength level of steel for hydropower will be further improved, and at the same time, the thickness of steel plates will also exceed 100mm. The increase in the thickness of the steel plate will bring about a series of problems such as reduced Z-direction performance, uneven structure, and high production costs. Coupled with the particularity of performance requirements for steel for hydropower, the production difficulty will further increase.

国内现有关于1000MPa强度级别钢的生产方法主要集中在100mm以下厚度规格,且成分设计和工艺设计均与本发明有较大的区别。The existing domestic production methods for steel with a strength level of 1000 MPa mainly focus on thickness specifications below 100 mm, and the composition design and process design are quite different from the present invention.

公开号为CN108385034A的中国专利申请公开了“一种不大于100mm厚1000MPa级水电用钢板的LGB-QT生产方法”,该钢板的化学成分:C0.12~0.21%,Si0.30~0.80%,Mn0.95~1.65%,P≤0.01%,S≤0.002%,Ni≤4.50%,Cr0.20~0.90%,Cu≤0.20%,Alt≤0.10%,Nb≤0.15%,Mo≤0.50%,V≤0.20%,Ti≤0.08%,B≤0.005%,余量为Fe。该钢板的LGB-Q&T制备方法:按照设定的成分冶炼与连铸,加热后进行两阶段控制轧制,之后控制冷却至室温,最后进行调质处理。其生产的钢板厚度不大于100mm,且采用Ni+Cr+Mo低合金成分设计,并利用Nb、V、Ti进行控轧控冷生产,和本发明成分和生产工艺均不相同。The Chinese patent application with the publication number CN108385034A discloses "a method for producing LGB-QT of a 1000MPa-grade steel plate for hydropower not greater than 100 mm in thickness". The chemical composition of the steel plate is: C0.12-0.21%, Si0.30-0.80%, Mn0.95~1.65%, P≤0.01%, S≤0.002%, Ni≤4.50%, Cr0.20~0.90%, Cu≤0.20%, Alt≤0.10%, Nb≤0.15%, Mo≤0.50%, V ≤0.20%, Ti≤0.08%, B≤0.005%, and the balance is Fe. The LGB-Q&T preparation method of the steel plate: smelting and continuous casting according to the set composition, two-stage controlled rolling after heating, then controlled cooling to room temperature, and finally quenching and tempering treatment. The thickness of the steel plate produced by it is not more than 100mm, and the low alloy composition design of Ni+Cr+Mo is adopted, and Nb, V, Ti are used for controlled rolling and controlled cooling production, which is different from the composition and production process of the present invention.

公开号为CN113399948A的中国专利申请公开了“一种生产厚度100mm以上规格1000MPa水电钢的方法”,采用两块250-350mm厚的连铸坯经焊接组坯后进行轧制和热处理,具体包括对连铸坯尺寸和复合面进行相应加工后进行组坯焊接、抽真空、轧制和热处理等工序;其属于轧制复合厚板制造技术领域,所采用铸坯成分也与本发明不同,并且不涉及钢板Z向性能,对于100mm以上复合板来说,性能安全性较低。The Chinese patent application with the publication number CN113399948A discloses "a method for producing 1000MPa hydropower steel with a thickness of 100mm or more", which uses two continuous casting slabs with a thickness of 250-350mm to be rolled and heat-treated after welding. The size of the continuous casting slab and the composite surface are processed accordingly, and then the processes such as billet welding, vacuuming, rolling and heat treatment are carried out; it belongs to the technical field of rolling composite thick plate manufacturing, and the components of the cast slab used are also different from those of the present invention, and are not It involves the Z-direction performance of the steel plate. For the composite plate over 100mm, the performance safety is low.

公开号为CN108504960A的中国专利申请公开了“一种大型水电工程用1000MPa级低裂纹水电钢板及其生产方法”,包括如下质量百分比的化学成分:C:0.06~0.17%、Si:≤0.15%、Mn:0.8~2.0%、P:≤0.010%、S:≤0.003%、Ni:1.0~2.0%、Cu:0.10~0.25%、Cr:0.3~1.5%、Mo:0.4~0.7%、V+Nb+Ti:≤0.1%、Als:0.015~0.045%、Ce≤0.020%、CEV≤0.64%、Pcm≤0.28%,其它为Fe和残留元素。产品具有高强度、高韧性、低裂纹敏感性、表面质量好、良好的焊接性等优点,但其所生产的钢板厚度仅为10~50mm。The Chinese patent application with the publication number CN108504960A discloses "a 1000MPa low-crack hydropower steel plate for large-scale hydropower projects and its production method", including the following chemical components in mass percentages: C: 0.06-0.17%, Si: ≤0.15%, Mn: 0.8~2.0%, P: ≤0.010%, S: ≤0.003%, Ni: 1.0~2.0%, Cu: 0.10~0.25%, Cr: 0.3~1.5%, Mo: 0.4~0.7%, V+Nb +Ti: ≤0.1%, Als: 0.015-0.045%, Ce≤0.020%, CEV≤0.64%, Pcm≤0.28%, others are Fe and residual elements. The product has the advantages of high strength, high toughness, low crack sensitivity, good surface quality, good weldability, etc., but the thickness of the steel plate it produces is only 10-50mm.

授权公告号为CN103451562B的中国发明专利公开了一种“水电用调质型大厚度易焊接Z向高强度钢板及其生产方法”,包含冶炼、连铸、电渣重熔、加热、轧制、轧后水冷、热堆垛、热处理工序,由以下质量百分比的组分熔炼而成,C≤0.18%,Si≤0.60%,Mn≤1.80%,P≤0.012%,S≤0.005%,Ni≤2.00%,Mo≤0.70%,Cr≤1.5%,Cu≤0.5%,Nb≤0.060%,Al≥0.020%,V≤0.12%,Ti≤0.05%,B≤0.004%,N≤0.015%,余量为Fe和不可避免的杂质。本发明与该发明相比,钢的化学成分设计不同,生产工艺也不同。该发明所述钢板采用控轧控冷+调质热处理的工艺生产,加热时间更是长达30h,整个生产工序繁琐,生产节奏较慢,生产成本较高。另外,该发明所生产钢板的室温抗拉强度仅为542-621MPa,与本发明钢板的强度相差较大;该发明所述钢板-20℃冲击功从78J到300J均有分布,可见冲击性能波动较大,而本发明在-40℃下,板厚1/4和1/2处均具有稳定的冲击性能。The Chinese invention patent with the authorized notification number CN103451562B discloses a "quenched and tempered large-thickness easy-to-weld Z-direction high-strength steel plate for hydropower and its production method", including smelting, continuous casting, electroslag remelting, heating, rolling, After rolling, water cooling, hot stacking, and heat treatment processes are smelted from the following components in mass percentages, C≤0.18%, Si≤0.60%, Mn≤1.80%, P≤0.012%, S≤0.005%, Ni≤2.00 %, Mo≤0.70%, Cr≤1.5%, Cu≤0.5%, Nb≤0.060%, Al≥0.020%, V≤0.12%, Ti≤0.05%, B≤0.004%, N≤0.015%, the balance is Fe and unavoidable impurities. Compared with the present invention, the chemical composition design of the steel is different, and the production process is also different. The steel plate described in this invention is produced by the process of controlled rolling and controlled cooling + quenching and tempering heat treatment, and the heating time is as long as 30 hours. The whole production process is cumbersome, the production rhythm is slow, and the production cost is high. In addition, the room temperature tensile strength of the steel plate produced by this invention is only 542-621MPa, which is quite different from the strength of the steel plate of the present invention; the impact energy of the steel plate in this invention at -20°C is distributed from 78J to 300J, which shows that the impact performance fluctuates Larger, but the present invention has stable impact performance at -40°C at 1/4 and 1/2 of the plate thickness.

发明内容Contents of the invention

本发明提供了一种超厚超高强大型水电工程用钢及其制造方法,采用低碳、低锰、Ni+Cr+Mo+Ti低合金化成分设计,配合电渣重熔+轧制+离线调质热处理工艺,利用高熔点Ti(CN)、CeO2细化晶粒的作用,实现了大厚度电渣坯的高渗透轧制生产,最终获得晶粒度为7.5级及以上、110~160mm厚1000MPa级超厚超高强钢板。The invention provides an ultra-thick, ultra-high-strength, large-scale steel for hydropower engineering and its manufacturing method. It adopts low-carbon, low-manganese, Ni+Cr+Mo+Ti low-alloying composition design, and cooperates with electroslag remelting + rolling + off-line Quenching and tempering heat treatment process, using the effect of high melting point Ti(CN) and CeO2 to refine the grain, realized the high penetration rolling production of large thickness electroslag blank, and finally obtained the grain size of 7.5 grade and above, 110 ~ 160mm Thick 1000MPa class ultra-thick ultra-high-strength steel plate.

为了达到上述目的,本发明采用以下技术方案实现:In order to achieve the above object, the present invention adopts the following technical solutions to realize:

一种超厚超高强大型水电工程用钢,钢中化学成分按重量百分比计为C:0.10%~0.15%;Si:0.06%~0.10%;Mn:0.90%~1.50%;P≤0.008%;S≤0.001%;Ni:1.75%~2.4%;Cr:0.55%~0.75%;Mo:0.75%~1.2%;Ti:0.07%~0.11%;N:0.015%~0.025%;CeO2:0.10%~0.20%;Al:0.02%~0.04%;[H]≤1.5ppm;[O]≤8ppm;余量为Fe和不可避免的杂质。An ultra-thick, ultra-high-strength, and large-scale steel for hydropower engineering. The chemical composition in the steel is C: 0.10%-0.15%; Si: 0.06%-0.10%; Mn: 0.90%-1.50%; P≤0.008%; S≤0.001%; Ni: 1.75%~2.4%; Cr: 0.55%~0.75%; Mo: 0.75%~1.2%; Ti: 0.07%~0.11%; N: 0.015%~0.025%; CeO 2 : 0.10% ~0.20%; Al: 0.02%~0.04%; [H]≤1.5ppm; [O]≤8ppm; the balance is Fe and unavoidable impurities.

进一步的,成品钢板室温拉伸的抗拉强度≥950MPa,屈服强度≥885MPa,断后伸长率≥15%;-40℃冲击吸收能量>150J;Z向断面收缩率>55%;无延性转变温度TNDT≤-45℃。Further, the tensile strength of the finished steel plate at room temperature is ≥ 950MPa, the yield strength is ≥ 885MPa, and the elongation after fracture is ≥ 15%; the impact energy absorbed at -40°C is > 150J; the Z-direction section shrinkage rate is > 55%; there is no ductility transition temperature TNDT≤-45°C.

一种超厚超高强大型水电工程用钢的制造方法,钢板制造工艺包括钢坯电渣重熔、电渣坯退火、加热、轧制、离线调质热处理;控制工艺过程如下:A method for manufacturing ultra-thick, ultra-high-strength, and large-scale steel for hydropower projects. The steel plate manufacturing process includes electroslag remelting of steel billets, electroslag billet annealing, heating, rolling, and off-line quenching and tempering heat treatment; the control process is as follows:

1)钢坯电渣重熔:重熔前向结晶器内吹氩气15~20min,氩气流量为7~9m3/h;重熔时熔速控制在560~620kg/h,结晶器冷却水量为55~65m3/h,水温控制在26~33℃;化渣阶段电流设定值为16000~22000A,补缩阶段电流设定值为8000~12000A并保持10~15min;1) Billet electroslag remelting: before remelting, blow argon gas into the crystallizer for 15-20 minutes, and the flow rate of argon gas is 7-9m 3 /h; 55~65m 3 /h, the water temperature is controlled at 26~33℃; the current setting value in the slag melting stage is 16000~22000A, and the feeding stage current setting value is 8000~12000A and kept for 10~15min;

2)电渣坯退火;电渣坯脱模后进行缓冷,缓冷坑预热至400~500℃,电渣坯的保温时间为15h以上,缓冷至室温;2) Electroslag billet annealing; slow cooling after electroslag billet demoulding, slow cooling pit preheated to 400-500°C, holding time of electroslag billet for more than 15h, and slow cooling to room temperature;

3)加热;电渣坯加热保温温度为1250~1300℃,保温时间为3~5h;3) Heating; the heating and holding temperature of the electroslag billet is 1250-1300°C, and the holding time is 3-5h;

4)轧制;开轧温度为1180~1220℃,前4个轧制道次的总变形量≥45mm,最后一个轧制道次中前2个道次的压下率≥10%;轧后钢板下线缓冷,缓冷时间不少于30小时;4) Rolling; the starting rolling temperature is 1180-1220°C, the total deformation of the first 4 rolling passes is ≥ 45mm, and the reduction ratio of the first 2 passes in the last rolling pass is ≥ 10%; after rolling The steel plate is slowly cooled off the production line, and the slow cooling time is not less than 30 hours;

5)离线调质热处理;淬火温度为880~950℃,保温时间为2~5min/mm,淬火冷速为20~25℃/s;回火保温温度为560~620℃,保温时间为4~8min/mm。5) Off-line quenching and tempering heat treatment; quenching temperature is 880-950°C, holding time is 2-5min/mm, quenching cooling rate is 20-25°C/s; tempering holding temperature is 560-620°C, holding time is 4-5 8min/mm.

进一步的,所述电渣坯的厚度为500~700mm;成品钢板厚度为110~160mm。Further, the thickness of the electroslag billet is 500-700 mm; the thickness of the finished steel plate is 110-160 mm.

进一步的,所述电渣坯出加热炉后采用高压水除鳞1~3min,除鳞水压为28~33MPa。Further, after the electroslag billet leaves the heating furnace, high-pressure water is used to descale for 1-3 minutes, and the water pressure for descaling is 28-33 MPa.

与现有技术相比,本发明的有益效果是:Compared with prior art, the beneficial effect of the present invention is:

1)采用低碳、低锰、Ni+Cr+Mo+Ti低合金化成分设计,并利用高熔点Ti(CN)、CeO2细化晶粒的作用,实现大厚度电渣坯的高渗透轧制生产,最终获得晶粒度为7.5级及以上(更细)的超厚超高强钢板;1) It is designed with low carbon, low manganese, Ni+Cr+Mo+Ti low alloying composition, and utilizes the effect of high melting point Ti(CN) and CeO2 to refine the grains to realize high penetration rolling of large thickness electroslag blanks production, and finally obtain ultra-thick ultra-high-strength steel plates with a grain size of 7.5 and above (finer);

2)采用电渣重熔工艺生产,钢质纯净度高,非金属夹杂物≤0.5级,无中心疏松和中心偏析;2) Produced by electroslag remelting process, the steel has high purity, non-metallic inclusions ≤ 0.5 grade, no center porosity and center segregation;

3)采用500~700mm厚电渣坯,高温大压下直接轧制成品钢板,并利用精准的离线调质热处理工艺,实现110~160mm厚1000MPa级水电工程用钢的制造;生产工艺相对简单、稳定,生产效率较高;3) Using 500-700mm thick electroslag billet, directly rolling the finished steel plate under high temperature and high pressure, and using precise off-line quenching and tempering heat treatment process to realize the manufacture of 110-160mm thick 1000MPa grade steel for hydropower engineering; the production process is relatively simple, Stable, high production efficiency;

4)通过化学成分和工艺的创新设计,实现了一种大厚度、均质化高强钢板的生产制造,钢板厚度1/4处和1/2处力学性能基本一致,具有良好的性能均匀性;4) Through the innovative design of chemical composition and process, the production and manufacture of a large-thickness, homogeneous high-strength steel plate has been realized. The mechanical properties of 1/4 and 1/2 of the thickness of the steel plate are basically the same, with good performance uniformity;

5)成品钢板室温拉伸的抗拉强度≥950MPa,屈服强度≥885MPa,断后伸长率≥15%;-40℃冲击吸收能量>150J;Z向断面收编率>55%;无延性转变温度TNDT≤-45℃,具有优异的低温韧性、抗层状撕裂性能以及抗脆断性能,完全满足大型水电工程对超厚超高强钢的使用要求。5) The tensile strength of the finished steel plate at room temperature is ≥ 950MPa, the yield strength is ≥ 885MPa, and the elongation after fracture is ≥ 15%; -40°C impact absorption energy > 150J; Z-direction section acceptance rate > 55%; no ductility transition temperature TNDT ≤-45°C, with excellent low-temperature toughness, lamellar tear resistance and brittle fracture resistance, fully meeting the requirements of large-scale hydropower projects for ultra-thick and ultra-high-strength steel.

附图说明Description of drawings

图1是本发明所述一种超厚超高强大型水电工程用钢的典型金相组织照片。Fig. 1 is a typical metallographic structure photo of a kind of ultra-thick, ultra-high-power and large-scale hydropower engineering steel according to the present invention.

具体实施方式Detailed ways

本发明所述一种超厚超高强大型水电工程用钢,钢中化学成分按重量百分比计为C:0.10%~0.15%;Si:0.06%~0.10%;Mn:0.90%~1.50%;P≤0.008%;S≤0.001%;Ni:1.75%~2.4%;Cr:0.55%~0.75%;Mo:0.75%~1.2%;Ti:0.07%~0.11%;N:0.015%~0.025%;CeO2:0.10%~0.20%;Al:0.02%~0.04%;[H]≤1.5ppm;[O]≤8ppm;余量为Fe和不可避免的杂质。The super-thick, ultra-high-power and large-scale hydropower engineering steel of the present invention, the chemical composition in the steel is C: 0.10%-0.15%; Si: 0.06%-0.10%; Mn: 0.90%-1.50%; P ≤0.008%; S≤0.001%; Ni: 1.75%~2.4%; Cr: 0.55%~0.75%; Mo: 0.75%~1.2%; Ti: 0.07%~0.11%; N: 0.015%~0.025%; CeO 2 : 0.10%~0.20%; Al: 0.02%~0.04%; [H]≤1.5ppm; [O]≤8ppm; the balance is Fe and unavoidable impurities.

进一步的,成品钢板室温拉伸的抗拉强度≥950MPa,屈服强度≥885MPa,断后伸长率≥15%;-40℃冲击吸收能量>150J;Z向断面收缩率>55%;无延性转变温度TNDT≤-45℃。Further, the tensile strength of the finished steel plate at room temperature is ≥ 950MPa, the yield strength is ≥ 885MPa, and the elongation after fracture is ≥ 15%; the impact energy absorbed at -40°C is > 150J; the Z-direction section shrinkage rate is > 55%; there is no ductility transition temperature TNDT≤-45°C.

本发明所述一种超厚超高强大型水电工程用钢的制造方法,钢板制造工艺包括钢坯电渣重熔、电渣坯退火、加热、轧制、离线调质热处理;控制工艺过程如下:According to the present invention, a method for manufacturing super-thick, super-high-power and large-scale steel for hydropower engineering, the steel plate manufacturing process includes billet electroslag remelting, electroslag billet annealing, heating, rolling, off-line quenching and tempering heat treatment; the control process is as follows:

1)钢坯电渣重熔:重熔前向结晶器内吹氩气15~20min,氩气流量为7~9m3/h;重熔时熔速控制在560~620kg/h,结晶器冷却水量为55~65m3/h,水温控制在26~33℃;化渣阶段电流设定值为16000~22000A,补缩阶段电流设定值为8000~12000A并保持10~15min;1) Billet electroslag remelting: before remelting, blow argon gas into the crystallizer for 15-20 minutes, and the flow rate of argon gas is 7-9m 3 /h; 55~65m 3 /h, the water temperature is controlled at 26~33℃; the current setting value in the slag melting stage is 16000~22000A, and the feeding stage current setting value is 8000~12000A and kept for 10~15min;

2)电渣坯退火;电渣坯脱模后进行缓冷,缓冷坑预热至400~500℃,电渣坯的保温时间为15h以上,缓冷至室温;2) Electroslag billet annealing; slow cooling after electroslag billet demoulding, slow cooling pit preheated to 400-500°C, holding time of electroslag billet for more than 15h, and slow cooling to room temperature;

3)加热;电渣坯加热保温温度为1250~1300℃,保温时间为3~5h;3) Heating; the heating and holding temperature of the electroslag billet is 1250-1300°C, and the holding time is 3-5h;

4)轧制;开轧温度为1180~1220℃,前4个轧制道次的总变形量≥45mm,最后一个轧制道次中前2个道次的压下率≥10%;轧后钢板下线缓冷,缓冷时间不少于30小时;4) Rolling; the starting rolling temperature is 1180-1220°C, the total deformation of the first 4 rolling passes is ≥ 45mm, and the reduction ratio of the first 2 passes in the last rolling pass is ≥ 10%; after rolling The steel plate is slowly cooled off the production line, and the slow cooling time is not less than 30 hours;

5)离线调质热处理;淬火温度为880~950℃,保温时间为2~5min/mm,淬火冷速为20~25℃/s;回火保温温度为560~620℃,保温时间为4~8min/mm。5) Off-line quenching and tempering heat treatment; quenching temperature is 880-950°C, holding time is 2-5min/mm, quenching cooling rate is 20-25°C/s; tempering holding temperature is 560-620°C, holding time is 4-5 8min/mm.

进一步的,所述电渣坯的厚度为500~700mm;成品钢板厚度为110~160mm。Further, the thickness of the electroslag billet is 500-700 mm; the thickness of the finished steel plate is 110-160 mm.

进一步的,所述电渣坯出加热炉后采用高压水除鳞1~3min,除鳞水压为28~33MPa。Further, after the electroslag billet leaves the heating furnace, high-pressure water is used to descale for 1-3 minutes, and the water pressure for descaling is 28-33 MPa.

本发明所述一种超厚超高强大型水电工程用钢的成分设计理由如下:The compositional design reason of a kind of ultra-thick ultra-high-power large-scale hydropower project steel of the present invention is as follows:

(1)C:碳溶解在钢中形成间隙固溶体,起固溶强化的作用,可以与Ti元素形成细小的碳化物,起沉淀强化作用,还可以提高钢的淬透性。但碳含量的增加会损害钢的焊接性能和低温韧性,因此本发明C含量控制在0.10%~0.15%。(1) C: Carbon dissolves in steel to form interstitial solid solution, which acts as solid solution strengthening, and can form fine carbides with Ti element, which acts as precipitation strengthening, and can also improve the hardenability of steel. However, the increase of carbon content will damage the weldability and low-temperature toughness of steel, so the content of C in the present invention is controlled at 0.10%-0.15%.

(2)Si:用于还原剂和脱氧剂,并起一定的固溶强化作用。Si含量过高,会降低钢的塑性和焊接性能,所以本发明钢中Si含量控制在0.06%~0.10%。(2) Si: It is used as a reducing agent and deoxidizer, and plays a certain role in solid solution strengthening. If the Si content is too high, the plasticity and weldability of the steel will be reduced, so the Si content in the steel of the present invention is controlled at 0.06%-0.10%.

(3)Mn:钢中良好的脱氧剂和脱硫剂;在钢中具有一定的固溶强化作用,能提高钢板的强度和淬透性。但过多的锰易造成偏析,恶化钢板的韧性。因此本发明控制Mn含量为0.90%~1.50%。(3) Mn: a good deoxidizer and desulfurizer in steel; it has a certain solid solution strengthening effect in steel and can improve the strength and hardenability of steel plates. However, too much manganese can easily cause segregation and deteriorate the toughness of the steel plate. Therefore, the present invention controls the Mn content to be 0.90%-1.50%.

(4)P、S:均为有害元素,P会引起钢的冷脆,S会造成钢的热脆,且易偏析,对钢的低温韧性和焊接性能均有明显的不利影响,因此两者含量越低越好,本发明控制钢中P≤0.008%、S≤0.001%。(4) P and S: Both are harmful elements, P will cause cold brittleness of steel, S will cause hot brittleness of steel, and is easy to segregate, which has obvious adverse effects on low temperature toughness and welding performance of steel, so both The lower the content, the better, and the present invention controls P≤0.008% and S≤0.001% in the steel.

(5)Ni:在本发明中的作用主要有:1)降低临近转变温度,提高钢板的淬透性;2)起固溶强化的作用,提高钢板低温韧性;3)促进细小板条马氏体的形成;4)与Cr、Mo配合使用,使钢板在调质热处理后获得强度和韧性配合良好的综合力学性能。本发明控制Ni含量为1.75%~2.4%。(5) Ni: The functions in the present invention mainly include: 1) reduce the near transition temperature and improve the hardenability of the steel plate; 2) play the role of solid solution strengthening and improve the low temperature toughness of the steel plate; 4) It is used in conjunction with Cr and Mo to make the steel plate obtain comprehensive mechanical properties with good strength and toughness after quenching and tempering heat treatment. The present invention controls the Ni content to be 1.75% to 2.4%.

(6)Cr:铬可以与碳生成细小弥散的碳化物,提高钢板的强度和韧性;淬火时,可以降低获得马氏体组织的最小冷却速度,更易获得马氏体组织;降低残余奥氏体的含量,从而在回火时获得良好的回火组织,改善钢板的强韧性;提高钢中回火析出(FeCr)3C等合金渗透体的热力学稳定性,降低回火过程中碳化物的聚集速度;与Mo等搭配使用,使钢板在调质热处理后具有良好的综合性能。但Cr含量过高会降低钢的焊接性能,因此本发明控制Cr含量为0.55%~0.75%。(6) Cr: Chromium can form fine and dispersed carbides with carbon to improve the strength and toughness of the steel plate; during quenching, it can reduce the minimum cooling rate to obtain martensite structure, and it is easier to obtain martensite structure; reduce retained austenite content, so that a good tempered structure can be obtained during tempering, and the strength and toughness of the steel plate can be improved; the thermodynamic stability of alloy infiltration bodies such as (FeCr)3C and other alloys precipitated in steel can be improved, and the aggregation speed of carbides can be reduced during tempering. ; Used in conjunction with Mo, etc., the steel plate has good comprehensive properties after quenching and tempering heat treatment. However, if the Cr content is too high, the weldability of the steel will be reduced, so the present invention controls the Cr content to be 0.55%-0.75%.

(7)Mo:可以固溶于铁素体、奥氏体和碳化物中,起固溶强化的作用;可以提高钢的淬透性;提高碳化物的稳定性,抑制回火过程中渗透体的聚集长大;与Cr、Mn配合使用,降低或抑制其它元素造成的回火脆性,保证钢板热处理后具有稳定的高强韧性。本发明控制Mo含量为0.75%~1.2%。(7) Mo: It can be dissolved in ferrite, austenite and carbide, and plays a role of solid solution strengthening; it can improve the hardenability of steel; improve the stability of carbide, and inhibit the infiltration during tempering Agglomeration and growth; used in conjunction with Cr and Mn to reduce or inhibit temper brittleness caused by other elements, and ensure stable high-strength toughness of the steel plate after heat treatment. The present invention controls the Mo content to be 0.75% to 1.2%.

(8)Ti:可以形成大量细小弥散的碳氮化物,既可以细化铸态组织,也可以在高温加热、轧制过程中阻止奥氏体晶粒长大,细化晶粒;Ti能变质钢中的硫化物,形成大量纳米尺寸硫化物粒子并弥散分布,从而减轻硫化物对钢性能的不利影响;固溶Ti既起固溶强化作用,又可以提高钢板的淬透性;高熔点的TiN可以阻止焊接热影响区晶粒粗化,提高钢板的焊接性能。因此本发明中Ti含量控制为0.07%~0.11%。(8) Ti: It can form a large number of fine and dispersed carbonitrides, which can not only refine the as-cast structure, but also prevent the growth of austenite grains and refine the grains during high temperature heating and rolling; Ti can deteriorate The sulfides in the steel form a large number of nano-sized sulfide particles and distribute them in a dispersed manner, thereby reducing the adverse effects of sulfides on the properties of the steel; solid solution Ti can not only play a solid solution strengthening role, but also improve the hardenability of the steel plate; high melting point TiN can prevent grain coarsening in the welding heat-affected zone and improve the welding performance of the steel plate. Therefore, the content of Ti in the present invention is controlled to be 0.07%-0.11%.

(9)N:氮在本发明中的作用主要有:1)起固溶强化的作用;2)扩大奥氏体相区,形成和稳定奥氏体;3)与Ti形成细小的TiN粒子,改善铸态组织,阻止加热中奥氏体晶粒粗化;4)与Al形成AlN,细化晶粒。本发明控制N含量为0.015%~0.025%。(9) N: The role of nitrogen in the present invention mainly includes: 1) play the role of solid solution strengthening; 2) expand the austenite phase region, form and stabilize austenite; 3) form fine TiN particles with Ti, Improve the as-cast structure and prevent the coarsening of austenite grains during heating; 4) form AlN with Al to refine the grains. The present invention controls the N content to be 0.015% to 0.025%.

(10)CeO2:在钢液中加入高熔点CeO2粉剂,增加形核核心,促进钢液凝固,细化铸态组织;细化Ti(CN)粒子,并促进弥散分布;可以提高晶界对位错运动的阻力,提高钢板的强韧性。本发明加入CeO2含量为0.10%~0.20%。(10) CeO 2 : Add high melting point CeO 2 powder to the molten steel to increase the nucleation core, promote the solidification of the molten steel, and refine the as-cast structure; refine the Ti(CN) particles and promote the dispersion distribution; it can improve the grain boundary The resistance to dislocation movement improves the strength and toughness of the steel plate. The content of CeO2 added in the present invention is 0.10%-0.20%.

(11)Al:起到一定的脱氧作用,并细化晶粒。本发明Al含量控制为0.02%~0.04%。(11) Al: It plays a certain role in deoxidation and refines the grains. In the present invention, the Al content is controlled at 0.02% to 0.04%.

(12)H和O:H和O对钢板的性能都会产生不利的影响,本发明控制[H]≤1.5ppm,[O]≤8ppm。(12) H and O: Both H and O will have adverse effects on the performance of the steel plate. The present invention controls [H]≤1.5ppm and [O]≤8ppm.

本发明所述一种超厚超高强大型水电工程用钢的制造工艺为:钢坯电渣重熔—电渣坯退火—加热—轧制—离线调质热处理—超声波探伤—性能检验,主要控制过程如下:The manufacturing process of an ultra-thick, ultra-high-power and large-scale steel for hydropower projects described in the present invention is: billet electroslag remelting-electroslag billet annealing-heating-rolling-off-line quenching and tempering heat treatment-ultrasonic flaw detection-performance inspection, the main control process as follows:

1、为保证钢坯与钢板的压缩比大于3,从而有效控制钢板的抗层状撕裂性能以及沿厚度截面的组织性能均匀性,本发明采用厚度为500~700mm的电渣坯进行钢板的轧制生产。电渣重熔属于二次精炼方法,具有深度洁净化钢质、改善钢坯结晶组织、消除中心疏松和中心偏析以及均质化钢板组织性能等优点,非常适合本发明所述钢的生产。1. In order to ensure that the compression ratio between the steel billet and the steel plate is greater than 3, so as to effectively control the lamellar tear resistance of the steel plate and the uniformity of the structure and performance along the thickness section, the present invention uses an electroslag billet with a thickness of 500-700mm for rolling of the steel plate production. Electroslag remelting belongs to the secondary refining method, which has the advantages of deep cleaning of steel quality, improvement of slab crystal structure, elimination of center porosity and center segregation, and homogenization of steel plate structure and performance, and is very suitable for the production of steel described in the present invention.

电渣重熔自耗电极采用符合本发明化学成分要求的钢坯,电渣重熔过程中严格控制电力制度、渣系和渣量以及充填比。重熔前向结晶器内吹氩气15~20min,氩气流量为7~9m3/h;重熔时熔速控制在560~620kg/h,结晶器冷却水量为55~65m3/h,水温控制在26~33℃;化渣阶段电流设定值为16000~22000A,补缩阶段电流设定值为8000~12000A并保持10~15min。电渣坯脱模后需进入缓冷坑缓冷,缓冷坑预先预热至400~500℃,电渣坯在该温度下保温15h以上,然后缓冷至室温出坑。长时退火的目的是为了消除电渣坯的热应力和组织应力,改善铸态组织,弥散分布析出物。The electroslag remelting consumable electrode adopts the steel billet meeting the chemical composition requirements of the present invention, and the electric power system, slag system, slag amount and filling ratio are strictly controlled during the electroslag remelting process. Before remelting, blow argon gas into the crystallizer for 15-20 minutes, the flow rate of argon gas is 7-9m3/h; during re-melting, the melting speed is controlled at 560-620kg/h, the cooling water volume of the crystallizer is 55-65m3/h, and the water temperature is controlled At 26-33°C; the setting value of the current in the slag removal stage is 16000-22000A, and the current setting value in the feeding stage is 8000-12000A and keep it for 10-15min. After demoulding, the electroslag billet needs to enter the slow cooling pit for slow cooling. The slow cooling pit is preheated to 400-500°C, and the electroslag billet is kept at this temperature for more than 15 hours, and then slowly cooled to room temperature to exit the pit. The purpose of long-term annealing is to eliminate the thermal stress and structural stress of the electroslag billet, improve the as-cast structure, and disperse the precipitates.

2、电渣坯加热保温温度为1250~1300℃,保温时间为3~5h。由于钢中含有大量弥散分布的高熔点TiN和CeO2粒子,在高温长时间加热过程中可以有效阻止奥氏体晶粒的粗化。因此本发明适当提高了加热温度,在保证电渣坯内外温度一致、奥氏体化充分均匀的同时,缩短大厚度电渣坯的加热时间,提高生产效率。2. The heating and holding temperature of the electroslag billet is 1250-1300°C, and the holding time is 3-5 hours. Since the steel contains a large number of dispersed TiN and CeO2 particles with high melting point, it can effectively prevent the coarsening of austenite grains during high temperature and long heating process. Therefore, the present invention appropriately increases the heating temperature, and while ensuring consistent internal and external temperatures of the electroslag billet and sufficiently uniform austenitization, shortens the heating time of the large-thickness electroslag billet and improves production efficiency.

电渣坯出炉后采用高压水除鳞1~3min,除鳞水压为28~33MPa,目的是去除表面氧化铁皮,保证钢板良好的表面质量。After the electroslag billet is out of the furnace, high-pressure water is used to descale for 1-3 minutes, and the descaling water pressure is 28-33MPa. The purpose is to remove the surface oxide scale and ensure the good surface quality of the steel plate.

3、电渣坯除鳞后进行轧制,开轧温度为1180~1220℃,前4个轧制道次的变形量≥45mm,并控制最后一个轧制道次的前2个道次压下率≥10%,轧制中,各道次间隔应尽可能短,直至轧制至成品钢板厚度(110~160mm)。高温大压下的多道次轧制,使电渣坯厚度截面均获得一定的轧制渗透,提高了大厚度钢坯的变形一致性,有利于提高组织和性能均匀性。并通过促进奥氏体反复再结晶,细化晶粒,均匀化组织。因为坯料较厚,高温轧制也降低了轧机负荷,保证了钢板的稳定生产。3. The electroslag billet is rolled after descaling, the rolling start temperature is 1180-1220°C, the deformation of the first 4 rolling passes is ≥ 45mm, and the first 2 passes of the last rolling pass are controlled. Ratio ≥ 10%. During rolling, the interval between each pass should be as short as possible until the thickness of the finished steel plate (110-160mm) is reached. The multi-pass rolling under high temperature and high pressure makes the thickness section of the electroslag billet obtain a certain rolling penetration, improves the deformation consistency of the large thickness billet, and is conducive to improving the uniformity of structure and performance. And by promoting repeated recrystallization of austenite, the grains are refined and the structure is homogenized. Because the billet is thicker, high-temperature rolling also reduces the load on the rolling mill and ensures stable production of steel plates.

钢板轧后下线进缓冷坑缓冷,缓冷时间不小于30小时,充分消除钢板内应力,降低钢板表面和中心温差,使轧制组织进一步均匀化,并脱除钢板中的氢,改善钢板的内部质量。After the steel plate is rolled, it goes off-line and enters the slow cooling pit for slow cooling. The slow cooling time is not less than 30 hours, fully eliminates the internal stress of the steel plate, reduces the temperature difference between the surface and the center of the steel plate, further homogenizes the rolling structure, and removes the hydrogen in the steel plate, improving The internal quality of the steel plate.

4、钢板缓冷后采用离线调质热处理工艺,其中淬火温度为880~950℃,保温时间为2~5min/mm,淬火冷速为20~25℃/s;回火保温温度为560~620℃,保温时间为4~8min/mm。合理的调质热处理工艺,保证了本发明成品钢板获得均匀细小的回火索氏体组织和优异的性能。4. After the steel plate is slowly cooled, the off-line quenching and tempering heat treatment process is adopted, wherein the quenching temperature is 880-950°C, the holding time is 2-5min/mm, the quenching cooling rate is 20-25°C/s; the tempering and holding temperature is 560-620 ℃, the holding time is 4~8min/mm. Reasonable quenching and tempering heat treatment process ensures that the finished steel plate of the present invention obtains uniform and fine tempered sorbite structure and excellent performance.

本发明所述一种超厚超高强大型水电工程用钢的典型金相组织照片如图1所示,组织为回火索氏体。A photo of a typical metallographic structure of an ultra-thick, ultra-high-strength, large-scale hydropower engineering steel according to the present invention is shown in Figure 1, and the structure is tempered sorbite.

以下实施例在以本发明技术方案为前提下进行实施,给出了详细的实施方式和具体的操作过程,但本发明的保护范围不限于下述的实施例。The following examples are carried out on the premise of the technical solutions of the present invention, and detailed implementation methods and specific operation processes are provided, but the protection scope of the present invention is not limited to the following examples.

【实施例】【Example】

各实施例钢的化学成分如表1所示,各实施例的电渣重溶工艺参数如表2所示,加热及轧制工艺参数如表3所示,各实施例的离线调质热处理工艺参数如表4所示,各实施例成品钢板的性能如表5所示。The chemical composition of each embodiment steel is shown in Table 1, the electroslag remelting process parameters of each embodiment are shown in Table 2, the heating and rolling process parameters are shown in Table 3, and the off-line quenching and tempering heat treatment process of each embodiment The parameters are shown in Table 4, and the properties of the finished steel plates of each embodiment are shown in Table 5.

表1钢的化学成分(%)Table 1 Chemical Composition of Steel (%)

Figure BDA0004096272940000071
Figure BDA0004096272940000071

Figure BDA0004096272940000081
Figure BDA0004096272940000081

表2电渣重熔工艺参数Table 2 Electroslag remelting process parameters

Figure BDA0004096272940000082
Figure BDA0004096272940000082

表3加热及轧制工艺参数Table 3 heating and rolling process parameters

Figure BDA0004096272940000091
Figure BDA0004096272940000091

表4离线调质热处理工艺参数Table 4 off-line quenching and tempering heat treatment process parameters

Figure BDA0004096272940000092
Figure BDA0004096272940000092

表5钢板调质态力学性能Table 5 Mechanical properties of steel plate in quenched and tempered state

Figure BDA0004096272940000101
Figure BDA0004096272940000101

以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above is only a preferred embodiment of the present invention, but the scope of protection of the present invention is not limited thereto, any person familiar with the technical field within the technical scope disclosed in the present invention, according to the technical solution of the present invention Any equivalent replacement or change of the inventive concepts thereof shall fall within the protection scope of the present invention.

Claims (5)

1.一种超厚超高强大型水电工程用钢,其特征在于,钢中化学成分按重量百分比计为C:0.10%~0.15%;Si:0.06%~0.10%;Mn:0.90%~1.50%;P≤0.008%;S≤0.001%;Ni:1.75%~2.4%;Cr:0.55%~0.75%;Mo:0.75%~1.2%;Ti:0.07%~0.11%;N:0.015%~0.025%;CeO2:0.10%~0.20%;Al:0.02%~0.04%;[H]≤1.5ppm;[O]≤8ppm;余量为Fe和不可避免的杂质。1. An ultra-thick, ultra-high-strength, large-scale steel for hydropower engineering, characterized in that the chemical composition in the steel is calculated by weight percentage as C: 0.10%-0.15%; Si: 0.06%-0.10%; Mn: 0.90%-1.50% ; P≤0.008%; S≤0.001%; Ni: 1.75% ~ 2.4%; Cr: 0.55% ~ 0.75%; ; CeO 2 : 0.10%-0.20%; Al: 0.02%-0.04%; [H]≤1.5ppm; [O]≤8ppm; the balance is Fe and unavoidable impurities. 2.根据权利要求1所述的一种超厚超高强大型水电工程用钢,其特征在于,成品钢板室温拉伸的抗拉强度≥950MPa,屈服强度≥885MPa,断后伸长率≥15%;-40℃冲击吸收能量>150J;Z向断面收缩率>55%;无延性转变温度TNDT≤-45℃。2. A super-thick, ultra-high-power and large-scale steel for hydropower engineering according to claim 1, characterized in that the tensile strength of the finished steel plate at room temperature is ≥ 950 MPa, the yield strength is ≥ 885 MPa, and the elongation after fracture is ≥ 15%; Impact absorption energy at -40°C > 150J; Z-direction area reduction > 55%; non-ductile transition temperature TNDT ≤ -45°C. 3.如权利要求1或2所述一种超厚超高强大型水电工程用钢的制造方法,其特征在于,钢板制造工艺包括钢坯电渣重熔、电渣坯退火、加热、轧制、离线调质热处理;控制工艺过程如下:3. A method for manufacturing ultra-thick, ultra-high-power, large-scale hydropower engineering steel as claimed in claim 1 or 2, wherein the steel plate manufacturing process includes electroslag remelting of steel billets, electroslag billet annealing, heating, rolling, off-line Quenching and tempering heat treatment; the control process is as follows: 1)钢坯电渣重熔:重熔前向结晶器内吹氩气15~20min,氩气流量为7~9m3/h;重熔时熔速控制在560~620kg/h,结晶器冷却水量为55~65m3/h,水温控制在26~33℃;化渣阶段电流设定值为16000~22000A,补缩阶段电流设定值为8000~12000A并保持10~15min;1) Billet electroslag remelting: before remelting, blow argon gas into the crystallizer for 15-20 minutes, and the flow rate of argon gas is 7-9m 3 /h; 55~65m 3 /h, the water temperature is controlled at 26~33℃; the current setting value in the slag melting stage is 16000~22000A, and the feeding stage current setting value is 8000~12000A and kept for 10~15min; 2)电渣坯退火;电渣坯脱模后进行缓冷,缓冷坑预热至400~500℃,电渣坯的保温时间为15h以上,缓冷至室温;2) Electroslag billet annealing; slow cooling after electroslag billet demoulding, slow cooling pit preheated to 400-500°C, holding time of electroslag billet for more than 15h, and slow cooling to room temperature; 3)加热;电渣坯加热保温温度为1250~1300℃,保温时间为3~5h;3) Heating; the heating and holding temperature of the electroslag billet is 1250-1300°C, and the holding time is 3-5h; 4)轧制;开轧温度为1180~1220℃,前4个轧制道次的各道次变形量≥45mm,最后一个轧制道次之前的2个道次总压下率≥10%;轧后钢板下线缓冷,缓冷时间不少于30小时;4) Rolling; the rolling start temperature is 1180-1220°C, the deformation of each pass in the first 4 rolling passes is ≥45mm, and the total reduction rate of the 2 passes before the last rolling pass is ≥10%; After rolling, the steel plate is slowly cooled off the production line, and the slow cooling time is not less than 30 hours; 5)离线调质热处理;淬火温度为880~950℃,保温时间为2~5min/mm,淬火冷速为20~25℃/s;回火保温温度为560~620℃,保温时间为4~8min/mm。5) Off-line quenching and tempering heat treatment; quenching temperature is 880-950°C, holding time is 2-5min/mm, quenching cooling rate is 20-25°C/s; tempering holding temperature is 560-620°C, holding time is 4-5 8min/mm. 4.根据权利要求3所述的一种超厚超高强大型水电工程用钢的制造方法,其特征在于,所述电渣坯的厚度为500~700mm;成品钢板厚度为110~160mm。4 . The method for manufacturing ultra-thick, ultra-high-power and large-scale steel for hydropower engineering according to claim 3, characterized in that, the thickness of the electroslag billet is 500-700 mm; the thickness of the finished steel plate is 110-160 mm. 5.根据权利要求3所述的一种超厚超高强大型水电工程用钢的制造方法,其特征在于,所述电渣坯出加热炉后采用高压水除鳞1~3min,除鳞水压为28~33MPa。5. A method for manufacturing ultra-thick, ultra-high-power, large-scale hydropower engineering steel according to claim 3, characterized in that, after the electroslag billet leaves the heating furnace, high-pressure water is used for descaling for 1 to 3 minutes, and the water pressure for descaling is 1-3 minutes. It is 28 ~ 33MPa.
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