CN116200949A - Wear-resistant elastic rib fabric and preparation method thereof - Google Patents
Wear-resistant elastic rib fabric and preparation method thereof Download PDFInfo
- Publication number
- CN116200949A CN116200949A CN202310071844.4A CN202310071844A CN116200949A CN 116200949 A CN116200949 A CN 116200949A CN 202310071844 A CN202310071844 A CN 202310071844A CN 116200949 A CN116200949 A CN 116200949A
- Authority
- CN
- China
- Prior art keywords
- modified
- wear
- parts
- nano
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 102
- 238000002360 preparation method Methods 0.000 title claims abstract description 46
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000002131 composite material Substances 0.000 claims abstract description 78
- 239000002105 nanoparticle Substances 0.000 claims abstract description 58
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical class O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims abstract description 55
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 46
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 46
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 46
- 239000000839 emulsion Substances 0.000 claims abstract description 43
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229920005989 resin Polymers 0.000 claims abstract description 40
- 239000011347 resin Substances 0.000 claims abstract description 40
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 40
- 239000010703 silicon Substances 0.000 claims abstract description 40
- 239000002904 solvent Substances 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000006185 dispersion Substances 0.000 claims description 63
- 238000002156 mixing Methods 0.000 claims description 49
- 229920001046 Nanocellulose Polymers 0.000 claims description 47
- 239000007788 liquid Substances 0.000 claims description 47
- 239000010445 mica Substances 0.000 claims description 47
- 229910052618 mica group Inorganic materials 0.000 claims description 47
- 238000003756 stirring Methods 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical class [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims description 28
- 239000011521 glass Substances 0.000 claims description 28
- 239000011259 mixed solution Substances 0.000 claims description 28
- 239000000843 powder Substances 0.000 claims description 27
- 229920000858 Cyclodextrin Polymers 0.000 claims description 24
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 24
- 239000008367 deionised water Substances 0.000 claims description 22
- 229910021641 deionized water Inorganic materials 0.000 claims description 22
- 239000000243 solution Substances 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- 239000002202 Polyethylene glycol Substances 0.000 claims description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims description 14
- 238000009210 therapy by ultrasound Methods 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 13
- ZDXPYRJPNDTMRX-UHFFFAOYSA-N glutamine Natural products OC(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-N 0.000 claims description 8
- FGZFESWHQXSPJU-UHFFFAOYSA-N 2-methyl-2-(3,3,3-trifluoropropyl)-1,3,5,2,4,6-trioxatrisilinane Chemical compound FC(F)(F)CC[Si]1(C)O[SiH2]O[SiH2]O1 FGZFESWHQXSPJU-UHFFFAOYSA-N 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000001116 FEMA 4028 Substances 0.000 claims description 7
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 7
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 7
- 229960004853 betadex Drugs 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 7
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 230000001105 regulatory effect Effects 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 229920002050 silicone resin Polymers 0.000 claims 1
- 230000009471 action Effects 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 40
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 20
- 239000000835 fiber Substances 0.000 description 19
- 238000000034 method Methods 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 229920002334 Spandex Polymers 0.000 description 6
- 239000004759 spandex Substances 0.000 description 6
- 230000004580 weight loss Effects 0.000 description 6
- 239000005543 nano-size silicon particle Substances 0.000 description 5
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 238000001132 ultrasonic dispersion Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 241000842962 Apoda limacodes Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006306 polyurethane fiber Polymers 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1685—Wear resistance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a wear-resistant elastic fabric and a preparation method thereof, and relates to the technical field of fabrics, wherein the wear-resistant elastic fabric comprises a base cloth layer and a wear-resistant layer, the base cloth layer is an elastic fabric, and the wear-resistant layer comprises the following components in parts by weight: 5-10 parts of modified polytetrafluoroethylene wax emulsion, 10-30 parts of modified cyclodextrin/nanoparticle composite material, 5-10 parts of modified organic silicon resin and 10-50 parts of solvent. The invention has the beneficial effects that the wear-resistant material consisting of the modified polytetrafluoroethylene wax, the modified cyclodextrin/nanoparticle composite material, the modified organic silicon resin and the solvent is formed on the elastic florida fabric base cloth layer, and the wear resistance and the antibacterial property of the fabric can be greatly improved through the combined action of the components in the wear-resistant material, so that the wear-resistant fabric has excellent wear resistance and low wear rate, and the mechanical property and the thermal stability are greatly improved.
Description
Technical Field
The invention relates to the technical field of fabrics, in particular to a wear-resistant elastic rib fabric and a preparation method thereof.
Background
The traditional fabric is usually woven by adopting natural fibers such as cotton, hemp and silk, and the natural fibers have the advantages of moisture absorption, ventilation, no harm to the body and the like, but the natural fibers are easy to wrinkle, deform and wear. The artificial fiber is prepared with polymer as material and through chemical treatment and mechanical processing. The artificial fiber has similar performance to natural fiber, excellent hydroscopicity, air permeability and dyeing property, soft hand feeling and glossy and is one kind of important textile material.
In general fabrics and complex fabrics, all the warp yarns are arranged in parallel, but in leno fabrics, due to the use of special heddles (doup heddles), special draw methods and special reed methods, the two warp yarns (ground warp, leno warp) are twisted with each other. The voids formed at the two warp twist points are referred to as "sand holes". In a leno weave, the warp pair ground warp is a weave in which each weft yarn is twisted once, and the warp pair ground warp is a weave in which each weft yarn is twisted once, two or more weft yarns are woven Luo Zuzhi. In recent years, as new raw materials for weaving are continuously increased, the production range of leno fabrics is increasingly enlarged, patterns are continuously renovated, so that the twisting method of the leno fabrics is also greatly changed, and a plurality of different twisting methods are often combined together for weaving, so that the formed fabrics are commonly called as fancy leno fabrics. Elastic festoon is usually obtained by adding elastic fiber such as spandex to natural fiber.
Since the main component of the floret fabric is natural fiber, and the natural fiber is easy to deform and abrade in use, in order to improve the defect of the natural fiber in performance, the following modes can be adopted: firstly, blending natural fibers and artificial fibers; secondly, compounding artificial fiber fabric on the natural fiber fabric; thirdly, attaching a protective layer on the natural fiber fabric.
In the prior art, chinese patent CN 114277493B discloses blending modified polyurethane fiber, modified polyamide fiber, nano ceramic fiber and cotton fiber fibrilia and acetate fiber, namely the first method is adopted; chinese patent CN 113802370B discloses that the third method is adopted to form an abrasion-resistant layer composed of aqueous urethane acrylate, reactive diluent, modified nano silica, dispersant, photoinitiator and deionized water on the base fabric layer; although the method can improve the wear resistance of the natural fiber, the wear resistance effect is general, so that a new wear-resistant elastic rib fabric needs to be developed.
Disclosure of Invention
The invention aims to at least solve one of the technical problems in the prior art and provides a wear-resistant elastic rib fabric and a preparation method thereof.
The technical scheme of the invention is as follows:
the first aspect of the invention provides a wear-resistant elastic fabric, which comprises a base cloth layer and a wear-resistant layer, wherein the base cloth layer is an elastic fabric, and the wear-resistant layer comprises the following components in parts by weight:
5-10 parts of modified polytetrafluoroethylene wax emulsion, 10-30 parts of modified cyclodextrin/nanoparticle composite material, 5-10 parts of modified organic silicon resin and 10-50 parts of solvent.
Preferably, the wear-resistant layer comprises the following components in parts by weight:
6-9 parts of modified polytetrafluoroethylene wax emulsion, 15-25 parts of modified cyclodextrin/nanoparticle composite material, 6-9 parts of modified organic silicon resin and 20-40 parts of solvent.
Preferably, the preparation method of the modified polytetrafluoroethylene wax emulsion comprises the following steps: adding vinyl triethoxysilane into the polytetrafluoroethylene wax emulsion, continuously adding the modified nano mica sheet/nano cellulose composite material, dispersing for 2-8 hours at the temperature of 65-75 ℃, and cooling to obtain the modified polytetrafluoroethylene wax emulsion.
Preferably, the preparation method of the modified nano mica sheet/nano cellulose composite material comprises the following steps: adding the nano mica sheets into deionized water, and performing ultrasonic treatment to form nano mica sheet dispersion liquid; adding the nanocellulose into deionized water, and performing ultrasonic treatment to form nanocellulose dispersion; uniformly mixing the nano mica sheet dispersion liquid, the nano cellulose dispersion liquid and the silane coupling agent to obtain the modified nano mica sheet/nano cellulose composite material.
Preferably, the preparation method of the modified cyclodextrin/nanoparticle composite material comprises the following steps: dissolving beta-cyclodextrin in water, adding polyethylene glycol, and stirring for 2-4 hours to obtain cyclodextrin dispersion; adding the nano particles into an ethanol water solution, regulating the pH of the solution to 5-5.5, then adding a silane coupling agent, and stirring for 2-8 hours at 55-65 ℃ to obtain a nano particle dispersion liquid; and mixing the cyclodextrin dispersion liquid, the nanoparticle dispersion liquid and the aqueous glutamine solution, and reacting for 4-10 hours at 50-65 ℃ to obtain the modified cyclodextrin/nanoparticle composite material.
Preferably, the nanoparticle is one or more of nano silica, nano titania, nano zinc oxide, nano alumina and nano calcium carbonate.
Preferably, the preparation method of the modified organic silicon resin comprises the following steps: adding the organic silicon resin into a solvent, continuously adding the trifluoropropyl methyl cyclotrisiloxane, uniformly stirring, adding the modified potassium titanate whisker/glass powder composite material, heating to 55-65 ℃ for dispersion treatment for 4-10 hours, and cooling to obtain the modified organic silicon resin.
Preferably, the preparation method of the modified potassium titanate whisker/glass powder composite material comprises the following steps: mixing potassium titanate whisker, glass powder and absolute ethyl alcohol, adding fatty acid polyethylene glycol ester, dispersing for 10-30 min by ultrasonic wave, continuously adding a silane coupling agent, stirring for 10-30 min at 60-80 ℃, and drying to obtain the modified potassium titanate whisker/glass powder composite material.
The second aspect of the invention provides a method for preparing wear-resistant elastic rib fabric, comprising the following steps:
s1, adding a modified cyclodextrin/nanoparticle composite material into deionized water, and uniformly stirring to obtain a first mixed solution; adding the modified organic silicon resin into a solvent, uniformly mixing, continuously adding the modified polytetrafluoroethylene wax emulsion, uniformly mixing to obtain a mixed solution II, mixing the mixed solution I and the mixed solution II, and stirring at 60-70 ℃ for 20-40 min to obtain a wear-resistant material;
s2, coating the wear-resistant material on the surface of the base cloth layer to obtain the wear-resistant elastic rib fabric.
The invention has at least one of the following beneficial effects:
1. according to the invention, the wear-resistant material consisting of the modified polytetrafluoroethylene wax emulsion, the modified cyclodextrin/nanoparticle composite material, the modified organic silicon resin and the solvent is formed on the elastic florida fabric base cloth layer, and the wear resistance of the fabric can be greatly improved through the combined action of the components in the wear-resistant material, so that the wear-resistant fabric has excellent wear resistance and low wear rate, and the mechanical property and the thermal stability are greatly improved, and also has a certain antibacterial property.
2. The modified polytetrafluoroethylene wax emulsion can greatly improve the wear resistance of the fabric and has a certain waterproof effect, and by modifying the nano mica sheet and the nano cellulose, not only is the dispersibility of the nano mica sheet and the nano cellulose in polytetrafluoroethylene wax improved, but also the nano mica sheet has better wear resistance and corrosion resistance, the nano cellulose has high mechanical strength, the nano mica sheet and the nano cellulose form a lamellar structure, and the nano mica sheet and the polytetrafluoroethylene wax and the nano cellulose float on the surface of the wear-resistant layer, so that the wear resistance and the thermal stability of the fabric can be improved. According to the invention, the cyclodextrin is modified to form hydroxyl on the surface, the silane coupling agent is hydrolyzed under an acidic condition to generate an active hydroxyl functional group, then the active hydroxyl functional group is dehydrated and condensed with the hydroxyl on the surfaces of the nano particles and the modified cyclodextrin, the grafting of the silane coupling agent on the surfaces of the nano particles and the modified cyclodextrin is realized, and the epoxy end of the silane coupling agent is subjected to ring opening reaction with the active carboxyl on the amino acid molecular chain, so that the glutamine is grafted on the surfaces of the nano particles and the cyclodextrin, and the dispersibility of the nano particles and the cyclodextrin is improved. The organic silicon resin structure contains both an organic group and an inorganic structure, and the special composition and the molecular structure integrate the characteristics of organic matters and the functions of inorganic matters.
Description of the embodiments
The present invention will be described in further detail with reference to the following specific examples, but the present invention is not limited to the following specific examples.
Examples
A wear-resistant elastic rib fabric comprises a base cloth layer and a wear-resistant layer,
the base cloth layer is an elastic festooned fabric, and in the embodiment, yarns used by the elastic festooned fabric are obtained by blending cotton fibers and spandex fibers according to a mass ratio of 10:2;
the wear-resistant layer comprises the following components in parts by weight:
5 parts of modified polytetrafluoroethylene wax emulsion, 10 parts of modified cyclodextrin/nanoparticle composite material, 5 parts of modified organic silicon resin and 10 parts of n-butanol solvent.
The preparation method of the modified polytetrafluoroethylene wax emulsion comprises the following steps: adding 4 parts of vinyl triethoxysilane into 10 parts of polytetrafluoroethylene wax emulsion, continuously adding 2 parts of modified nano mica sheet/nano cellulose composite material, dispersing for 8 hours at 65 ℃, and cooling to obtain the modified polytetrafluoroethylene wax emulsion.
The preparation method of the modified nano mica sheet/nano cellulose composite material comprises the following steps: adding 1 part of nano mica sheet into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nano mica sheet dispersion liquid; adding 0.5 part of nanocellulose into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nanocellulose dispersion liquid; uniformly mixing the nano mica sheet dispersion liquid, the nano cellulose dispersion liquid and the silane coupling agent to obtain the modified nano mica sheet/nano cellulose composite material.
The preparation method of the modified cyclodextrin/nanoparticle composite material comprises the following steps: dissolving 2 parts of beta-cyclodextrin in water at 50 ℃, adding 20 parts of polyethylene glycol, and stirring for 4 hours to obtain cyclodextrin dispersion; adding 1 part of nano silicon dioxide, 1 part of nano titanium dioxide and 1 part of nano zinc oxide into 50 parts of ethanol water solution with the concentration of 25%, regulating the pH value of the solution to 5.5, then adding 0.3 part of silane coupling agent KH560, and stirring for 8 hours at 55 ℃ to obtain nanoparticle dispersion liquid; and mixing the cyclodextrin dispersion liquid, the nanoparticle dispersion liquid and the aqueous glutamine solution, and reacting for 10 hours at 50 ℃ to obtain the modified cyclodextrin/nanoparticle composite material.
The preparation method of the modified organic silicon resin comprises the following steps: adding 5 parts of organic silicon resin into 1 part of n-butanol solvent, continuously adding 1 part of trifluoropropyl methyl cyclotrisiloxane, uniformly stirring, adding 1 part of modified potassium titanate whisker/glass powder composite material, heating to 55 ℃ for dispersion treatment for 10 hours, and cooling to obtain the modified organic silicon resin.
The preparation method of the modified potassium titanate whisker/glass powder composite material comprises the following steps: mixing 1 part of potassium titanate whisker, 0.5 part of glass powder and 5 parts of absolute ethyl alcohol, adding 5 parts of fatty acid polyethylene glycol ester, dispersing for 10min by 200kW ultrasonic waves, continuously adding 0.5 part of silane coupling agent KH560, stirring for 30min at 60 ℃, and drying to obtain the modified potassium titanate whisker/glass powder composite material.
The preparation method of the wear-resistant elastic rib fabric comprises the following steps:
s1, adding a modified cyclodextrin/nanoparticle composite material into deionized water, and uniformly stirring to obtain a first mixed solution; adding the modified organic silicon resin into a solvent, uniformly mixing, continuously adding the modified polytetrafluoroethylene wax emulsion, uniformly mixing to obtain a mixed solution II, mixing the mixed solution I and the mixed solution II, and stirring at 60 ℃ for 40min to obtain a wear-resistant material;
s2, coating the wear-resistant material on the surface of the base cloth layer to obtain the wear-resistant elastic rib fabric.
Examples
A wear-resistant elastic rib fabric comprises a base cloth layer and a wear-resistant layer,
the base cloth layer is an elastic festooned fabric, and in the embodiment, yarns used by the elastic festooned fabric are obtained by blending cotton fibers and spandex fibers according to a mass ratio of 10:2;
the wear-resistant layer comprises the following components in parts by weight:
6 parts of modified polytetrafluoroethylene wax emulsion, 15 parts of modified cyclodextrin/nanoparticle composite material, 6 parts of modified organic silicon resin and 20 parts of n-butanol solvent.
The preparation method of the modified polytetrafluoroethylene wax emulsion comprises the following steps: adding 5 parts of vinyl triethoxysilane into 12 parts of polytetrafluoroethylene wax emulsion, continuously adding 2.5 parts of modified nano mica sheet/nano cellulose composite material, dispersing for 6 hours at the temperature of 68 ℃, and cooling to obtain the modified polytetrafluoroethylene wax emulsion.
The preparation method of the modified nano mica sheet/nano cellulose composite material comprises the following steps: adding 1 part of nano mica sheet into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nano mica sheet dispersion liquid; adding 0.5 part of nanocellulose into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nanocellulose dispersion liquid; uniformly mixing the nano mica sheet dispersion liquid, the nano cellulose dispersion liquid and the silane coupling agent to obtain the modified nano mica sheet/nano cellulose composite material.
The preparation method of the modified cyclodextrin/nanoparticle composite material comprises the following steps: dissolving 2 parts of beta-cyclodextrin in water at 50 ℃, adding 20 parts of polyethylene glycol, and stirring for 3 hours to obtain cyclodextrin dispersion; adding 1 part of nano silicon dioxide, 1 part of nano titanium dioxide and 1 part of nano zinc oxide into 50 parts of ethanol water solution with the concentration of 25%, regulating the pH value of the solution to 5.5, then adding 0.3 part of silane coupling agent KH560, and stirring for 4 hours at 60 ℃ to obtain nanoparticle dispersion liquid; and mixing the cyclodextrin dispersion liquid, the nanoparticle dispersion liquid and the aqueous glutamine solution, and reacting for 7 hours at 55 ℃ to obtain the modified cyclodextrin/nanoparticle composite material.
The preparation method of the modified organic silicon resin comprises the following steps: adding 5 parts of organic silicon resin into 1 part of n-butanol solvent, continuously adding 1 part of trifluoropropyl methyl cyclotrisiloxane, uniformly stirring, adding 1 part of modified potassium titanate whisker/glass powder composite material, heating to 60 ℃ for dispersion treatment for 7 hours, and cooling to obtain the modified organic silicon resin.
The preparation method of the modified potassium titanate whisker/glass powder composite material comprises the following steps: mixing 1 part of potassium titanate whisker, 0.5 part of glass powder and 5 parts of absolute ethyl alcohol, adding 5 parts of fatty acid polyethylene glycol ester, performing 200kW power ultrasonic dispersion for 20min, continuously adding 0.5 part of silane coupling agent KH560, stirring for 20min at 70 ℃, and drying to obtain the modified potassium titanate whisker/glass powder composite material.
The preparation method of the wear-resistant elastic rib fabric comprises the following steps:
s1, adding a modified cyclodextrin/nanoparticle composite material into deionized water, and uniformly stirring to obtain a first mixed solution; adding the modified organic silicon resin into a solvent, uniformly mixing, continuously adding the modified polytetrafluoroethylene wax emulsion, uniformly mixing to obtain a mixed solution II, mixing the mixed solution I and the mixed solution II, and stirring at 62 ℃ for 35min to obtain a wear-resistant material;
s2, coating the wear-resistant material on the surface of the base cloth layer to obtain the wear-resistant elastic rib fabric.
Examples
A wear-resistant elastic rib fabric comprises a base cloth layer and a wear-resistant layer,
the base cloth layer is an elastic festooned fabric, and in the embodiment, yarns used by the elastic festooned fabric are obtained by blending cotton fibers and spandex fibers according to a mass ratio of 10:2;
the wear-resistant layer comprises the following components in parts by weight:
7.5 parts of modified polytetrafluoroethylene wax emulsion, 20 parts of modified cyclodextrin/nanoparticle composite material, 7.5 parts of modified organic silicon resin and 30 parts of n-butanol solvent.
The preparation method of the modified polytetrafluoroethylene wax emulsion comprises the following steps: adding 6 parts of vinyl triethoxysilane into 15 parts of polytetrafluoroethylene wax emulsion, continuously adding 3 parts of modified nano mica sheet/nano cellulose composite material, dispersing for 4 hours at the temperature of 70 ℃, and cooling to obtain the modified polytetrafluoroethylene wax emulsion.
The preparation method of the modified nano mica sheet/nano cellulose composite material comprises the following steps: adding 1 part of nano mica sheet into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nano mica sheet dispersion liquid; adding 0.5 part of nanocellulose into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nanocellulose dispersion liquid; uniformly mixing the nano mica sheet dispersion liquid, the nano cellulose dispersion liquid and the silane coupling agent to obtain the modified nano mica sheet/nano cellulose composite material.
The preparation method of the modified cyclodextrin/nanoparticle composite material comprises the following steps: dissolving 2 parts of beta-cyclodextrin in water at 50 ℃, adding 20 parts of polyethylene glycol, and stirring for 3 hours to obtain cyclodextrin dispersion; adding 1 part of nano silicon dioxide, 1 part of nano titanium dioxide and 1 part of nano zinc oxide into 50 parts of ethanol water solution with the concentration of 25%, regulating the pH value of the solution to 5.5, then adding 0.3 part of silane coupling agent KH560, and stirring for 5 hours at 60 ℃ to obtain nanoparticle dispersion liquid; and mixing the cyclodextrin dispersion liquid, the nanoparticle dispersion liquid and the aqueous glutamine solution, and reacting for 7 hours at 57 ℃ to obtain the modified cyclodextrin/nanoparticle composite material.
The preparation method of the modified organic silicon resin comprises the following steps: adding 5 parts of organic silicon resin into 1 part of n-butanol solvent, continuously adding 1 part of trifluoropropyl methyl cyclotrisiloxane, uniformly stirring, adding 1 part of modified potassium titanate whisker/glass powder composite material, heating to 60 ℃ for dispersion treatment for 7 hours, and cooling to obtain the modified organic silicon resin.
The preparation method of the modified potassium titanate whisker/glass powder composite material comprises the following steps: mixing 1 part of potassium titanate whisker, 0.5 part of glass powder and 5 parts of absolute ethyl alcohol, adding 5 parts of fatty acid polyethylene glycol ester, performing ultrasonic dispersion for 20min under 200kW power, continuously adding 0.5 part of silane coupling agent KH560, stirring for 20min at 70 ℃, and drying to obtain the modified potassium titanate whisker/glass powder composite material.
The preparation method of the wear-resistant elastic rib fabric comprises the following steps:
s1, adding a modified cyclodextrin/nanoparticle composite material into deionized water, and uniformly stirring to obtain a first mixed solution; adding the modified organic silicon resin into a solvent, uniformly mixing, continuously adding the modified polytetrafluoroethylene wax emulsion, uniformly mixing to obtain a mixed solution II, mixing the mixed solution I and the mixed solution II, and stirring for 30min at 65 ℃ to obtain a wear-resistant material;
s2, coating the wear-resistant material on the surface of the base cloth layer to obtain the wear-resistant elastic rib fabric.
Examples
A wear-resistant elastic rib fabric comprises a base cloth layer and a wear-resistant layer,
the base cloth layer is an elastic festooned fabric, and in the embodiment, yarns used by the elastic festooned fabric are obtained by blending cotton fibers and spandex fibers according to a mass ratio of 10:2;
the wear-resistant layer comprises the following components in parts by weight:
9 parts of modified polytetrafluoroethylene wax emulsion, 25 parts of modified cyclodextrin/nanoparticle composite material, 9 parts of modified organic silicon resin and 40 parts of n-butanol solvent.
The preparation method of the modified polytetrafluoroethylene wax emulsion comprises the following steps: adding 7 parts of vinyl triethoxysilane into 18 parts of polytetrafluoroethylene wax emulsion, continuously adding 3.5 parts of modified nano mica sheet/nano cellulose composite material, dispersing for 3 hours at the temperature of 72 ℃, and cooling to obtain the modified polytetrafluoroethylene wax emulsion.
The preparation method of the modified nano mica sheet/nano cellulose composite material comprises the following steps: adding 1 part of nano mica sheet into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nano mica sheet dispersion liquid; adding 0.5 part of nanocellulose into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nanocellulose dispersion liquid; uniformly mixing the nano mica sheet dispersion liquid, the nano cellulose dispersion liquid and the silane coupling agent to obtain the modified nano mica sheet/nano cellulose composite material.
The preparation method of the modified cyclodextrin/nanoparticle composite material comprises the following steps: dissolving 2 parts of beta-cyclodextrin in water at 50 ℃, adding 20 parts of polyethylene glycol, and stirring for 4 hours to obtain cyclodextrin dispersion; adding 1 part of nano silicon dioxide, 1 part of nano titanium dioxide and 1 part of nano zinc oxide into 50 parts of ethanol water solution with the concentration of 25%, regulating the pH value of the solution to 5.5, then adding 0.3 part of silane coupling agent KH560, and stirring for 2 hours at 65 ℃ to obtain nanoparticle dispersion liquid; and mixing the cyclodextrin dispersion liquid, the nanoparticle dispersion liquid and the aqueous glutamine solution, and reacting for 4 hours at 65 ℃ to obtain the modified cyclodextrin/nanoparticle composite material.
The preparation method of the modified organic silicon resin comprises the following steps: adding 5 parts of organic silicon resin into 1 part of n-butanol solvent, continuously adding 1 part of trifluoropropyl methyl cyclotrisiloxane, uniformly stirring, adding 1 part of modified potassium titanate whisker/glass powder composite material, heating to 60 ℃ for dispersion treatment for 5 hours, and cooling to obtain the modified organic silicon resin.
The preparation method of the modified potassium titanate whisker/glass powder composite material comprises the following steps: mixing 1 part of potassium titanate whisker, 0.5 part of glass powder and 5 parts of absolute ethyl alcohol, adding 5 parts of fatty acid polyethylene glycol ester, performing ultrasonic dispersion for 15min under 200kW power, continuously adding 0.5 part of silane coupling agent KH560, stirring for 20min at 70 ℃, and drying to obtain the modified potassium titanate whisker/glass powder composite material.
The preparation method of the wear-resistant elastic rib fabric comprises the following steps:
s1, adding a modified cyclodextrin/nanoparticle composite material into deionized water, and uniformly stirring to obtain a first mixed solution; adding the modified organic silicon resin into a solvent, uniformly mixing, continuously adding the modified polytetrafluoroethylene wax emulsion, uniformly mixing to obtain a mixed solution II, mixing the mixed solution I and the mixed solution II, and stirring at 68 ℃ for 30min to obtain a wear-resistant material;
s2, coating the wear-resistant material on the surface of the base cloth layer to obtain the wear-resistant elastic rib fabric.
Examples
A wear-resistant elastic rib fabric comprises a base cloth layer and a wear-resistant layer,
the base cloth layer is an elastic festooned fabric, and in the embodiment, yarns used by the elastic festooned fabric are obtained by blending cotton fibers and spandex fibers according to a mass ratio of 10:2;
the wear-resistant layer comprises the following components in parts by weight:
10 parts of modified polytetrafluoroethylene wax emulsion, 30 parts of modified cyclodextrin/nanoparticle composite material, 10 parts of modified organic silicon resin and 50 parts of n-butanol solvent.
The preparation method of the modified polytetrafluoroethylene wax emulsion comprises the following steps: 8 parts of vinyl triethoxysilane is added into 20 parts of polytetrafluoroethylene wax emulsion, 4 parts of modified nano mica sheet/nano cellulose composite material is continuously added, the mixture is dispersed for 2 hours at the temperature of 75 ℃, and the mixture is cooled to obtain the modified polytetrafluoroethylene wax emulsion.
The preparation method of the modified nano mica sheet/nano cellulose composite material comprises the following steps: adding 1 part of nano mica sheet into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nano mica sheet dispersion liquid; adding 0.5 part of nanocellulose into 5 parts of deionized water, and performing ultrasonic treatment for 30min under 200kW power to form nanocellulose dispersion liquid; uniformly mixing the nano mica sheet dispersion liquid, the nano cellulose dispersion liquid and the silane coupling agent to obtain the modified nano mica sheet/nano cellulose composite material.
The preparation method of the modified cyclodextrin/nanoparticle composite material comprises the following steps: dissolving 2 parts of beta-cyclodextrin in water at 50 ℃, adding 20 parts of polyethylene glycol, and stirring for 2 hours to obtain cyclodextrin dispersion; adding 1 part of nano silicon dioxide, 1 part of nano titanium dioxide and 1 part of nano zinc oxide into 50 parts of ethanol water solution with the concentration of 25%, regulating the pH value of the solution to 5.5, then adding 0.3 part of silane coupling agent KH560, and stirring for 2 hours at 65 ℃ to obtain nanoparticle dispersion liquid; and mixing the cyclodextrin dispersion liquid, the nanoparticle dispersion liquid and the aqueous glutamine solution, and reacting for 4 hours at 65 ℃ to obtain the modified cyclodextrin/nanoparticle composite material.
The preparation method of the modified organic silicon resin comprises the following steps: adding 5 parts of organic silicon resin into 1 part of n-butanol solvent, continuously adding 1 part of trifluoropropyl methyl cyclotrisiloxane, uniformly stirring, adding 1 part of modified potassium titanate whisker/glass powder composite material, heating to 65 ℃ for dispersion treatment for 4 hours, and cooling to obtain the modified organic silicon resin.
The preparation method of the modified potassium titanate whisker/glass powder composite material comprises the following steps: mixing 1 part of potassium titanate whisker, 0.5 part of glass powder and 5 parts of absolute ethyl alcohol, adding 5 parts of fatty acid polyethylene glycol ester, performing ultrasonic dispersion for 30min under 200kW power, continuously adding 0.5 part of silane coupling agent KH560, stirring for 10min at 80 ℃, and drying to obtain the modified potassium titanate whisker/glass powder composite material.
The preparation method of the wear-resistant elastic rib fabric comprises the following steps:
s1, adding a modified cyclodextrin/nanoparticle composite material into deionized water, and uniformly stirring to obtain a first mixed solution; adding the modified organic silicon resin into a solvent, uniformly mixing, continuously adding the modified polytetrafluoroethylene wax emulsion, uniformly mixing to obtain a mixed solution II, mixing the mixed solution I and the mixed solution II, and stirring at 70 ℃ for 20min to obtain a wear-resistant material;
s2, coating the wear-resistant material on the surface of the base cloth layer to obtain the wear-resistant elastic rib fabric.
The difference from example 1 is that: the wear layer did not include the modified polytetrafluoroethylene wax emulsion, otherwise as in example 1.
The difference from example 1 is that: the wear layer does not include a modified cyclodextrin/nanoparticle composite, otherwise as in example 1.
Abrasion resistance tests were performed on the abrasion resistant elastic rib fabric prepared in examples 1 to 5 and comparative examples 1 to 2.
The wear resistance index is generally expressed according to the physical property changes of the fabric such as strength, thickness, weight and the like after the fabric is subjected to certain wear. The fabric weight loss rate after abrasion was assessed using the German standard DIN 53863.2.
Experimental conditions: five samples were prepared for each variety.
Number of experimental rubs: 300 turns.
Experimental principle: the fabric sample plane is worn by friction with the abrasive at a constant pressure.
Units: weight loss percentage%.
The test results are shown in Table 1.
| Weight loss rate | |
| Example 1 | 0.259% |
| Example 2 | 0.231% |
| Example 3 | 0.209% |
| Example 4 | 0.198% |
| Example 5 | 0.212% |
| Comparative example 1 | 1.158% |
| Comparative example 2 | 1.062% |
As can be seen from the above test, the weight loss rate of examples 1 to 5 is only about 0.2%, thus demonstrating that examples 1 to 5 have very high wear resistance.
Comparing examples 1-5 with comparative example 1 (the wear-resistant layer does not comprise modified polytetrafluoroethylene wax emulsion) and comparative example 2 (the wear-resistant layer does not comprise modified cyclodextrin/nanoparticle composite material), the weight loss rate of comparative examples 1-2 is about 1.1%, and the weight loss rate of examples 1-5 is obviously smaller than that of comparative examples 1-2, so that whether the wear-resistant layer is added with polytetrafluoroethylene wax emulsion and modified cyclodextrin/nanoparticle composite material can influence the wear resistance of the fabric.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should make equivalent substitutions or modifications according to the technical scheme of the present invention and the inventive concept thereof, and should be covered by the scope of the present invention.
Claims (9)
1. The wear-resistant elastic fabric is characterized by comprising a base cloth layer and a wear-resistant layer, wherein the base cloth layer is an elastic festooned fabric, and the wear-resistant layer comprises the following components in parts by weight:
5-10 parts of modified polytetrafluoroethylene wax emulsion, 10-30 parts of modified cyclodextrin/nanoparticle composite material, 5-10 parts of modified organic silicon resin and 10-50 parts of solvent.
2. The wear-resistant elastic rib fabric according to claim 1, wherein the wear-resistant layer comprises the following components in parts by weight:
6-9 parts of modified polytetrafluoroethylene wax emulsion, 15-25 parts of modified cyclodextrin/nanoparticle composite material, 6-9 parts of modified organic silicon resin and 20-40 parts of solvent.
3. The wear-resistant elastic rib fabric according to claim 1, wherein the preparation method of the modified polytetrafluoroethylene wax emulsion comprises the following steps: adding vinyl triethoxysilane into the polytetrafluoroethylene wax emulsion, continuously adding the modified nano mica sheet/nano cellulose composite material, dispersing for 2-8 hours at the temperature of 65-75 ℃, and cooling to obtain the modified polytetrafluoroethylene wax emulsion.
4. A wear resistant elastic rib fabric according to claim 3, wherein the preparation method of the modified nano mica sheet/nano cellulose composite material comprises the following steps: adding the nano mica sheets into deionized water, and performing ultrasonic treatment to form nano mica sheet dispersion liquid; adding the nanocellulose into deionized water, and performing ultrasonic treatment to form nanocellulose dispersion; uniformly mixing the nano mica sheet dispersion liquid, the nano cellulose dispersion liquid and the silane coupling agent to obtain the modified nano mica sheet/nano cellulose composite material.
5. The wear-resistant elastic rib fabric according to claim 1, wherein the preparation method of the modified cyclodextrin/nanoparticle composite material comprises the following steps: dissolving beta-cyclodextrin in water, adding polyethylene glycol, and stirring for 2-4 hours to obtain cyclodextrin dispersion; adding the nano particles into an ethanol water solution, regulating the pH of the solution to 5-5.5, then adding a silane coupling agent, and stirring for 2-8 hours at 55-65 ℃ to obtain a nano particle dispersion liquid; and mixing the cyclodextrin dispersion liquid, the nanoparticle dispersion liquid and the aqueous glutamine solution, and reacting for 4-10 hours at 50-65 ℃ to obtain the modified cyclodextrin/nanoparticle composite material.
6. The wear resistant stretch fabric of claim 5, wherein the nanoparticles are one or more of nano silica, nano titania, nano zinc oxide, nano alumina, and nano calcium carbonate.
7. The wear-resistant elastic rib fabric according to claim 1, wherein the preparation method of the modified silicone resin comprises the following steps: adding the organic silicon resin into a solvent, continuously adding the trifluoropropyl methyl cyclotrisiloxane, uniformly stirring, adding the modified potassium titanate whisker/glass powder composite material, heating to 55-65 ℃ for dispersion treatment for 4-10 hours, and cooling to obtain the modified organic silicon resin.
8. The wear-resistant elastic rib fabric according to claim 7, wherein the preparation method of the modified potassium titanate whisker/glass frit composite material comprises the following steps: mixing potassium titanate whisker, glass powder and absolute ethyl alcohol, adding fatty acid polyethylene glycol ester, dispersing for 10-30 min by ultrasonic wave, continuously adding a silane coupling agent, stirring for 10-30 min at 60-80 ℃, and drying to obtain the modified potassium titanate whisker/glass powder composite material.
9. The preparation method of the wear-resistant elastic rib fabric is characterized by comprising the following steps of:
s1, adding a modified cyclodextrin/nanoparticle composite material into deionized water, and uniformly stirring to obtain a first mixed solution; adding the modified organic silicon resin into a solvent, uniformly mixing, continuously adding the modified polytetrafluoroethylene wax emulsion, uniformly mixing to obtain a mixed solution II, mixing the mixed solution I and the mixed solution II, and stirring at 60-70 ℃ for 20-40 min to obtain a wear-resistant material;
s2, coating the wear-resistant material on the surface of the base cloth layer to obtain the wear-resistant elastic rib fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310071844.4A CN116200949A (en) | 2023-02-07 | 2023-02-07 | Wear-resistant elastic rib fabric and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310071844.4A CN116200949A (en) | 2023-02-07 | 2023-02-07 | Wear-resistant elastic rib fabric and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116200949A true CN116200949A (en) | 2023-06-02 |
Family
ID=86514099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310071844.4A Pending CN116200949A (en) | 2023-02-07 | 2023-02-07 | Wear-resistant elastic rib fabric and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116200949A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016132760A (en) * | 2015-01-22 | 2016-07-25 | 株式会社大阪ソーダ | Titanium oxide dispersion |
| CN109610184A (en) * | 2018-12-15 | 2019-04-12 | 深圳市仁义和兴塑胶五金制品有限公司 | A kind of organic silicon cloth of waterproof antiwear and processing technology |
| US20200232156A1 (en) * | 2017-07-20 | 2020-07-23 | Jiangnan University | Multifunctional high-strength composite fabric coating agent, coating, method for preparing the same, and application thereof |
| CN113802370A (en) * | 2021-10-14 | 2021-12-17 | 江苏三盛纺织有限公司 | Composite wear-resistant fabric |
| US20220119631A1 (en) * | 2019-01-11 | 2022-04-21 | Adeka Corporation | Additive composition, thermoplastic resin composition containing same, and molded article of said thermoplastic resin composition |
| WO2022110593A1 (en) * | 2020-11-25 | 2022-06-02 | 胡森川 | Wear-resistant and aging-resistant furniture plastic particle and preparation method therefor |
| CN114669199A (en) * | 2022-03-15 | 2022-06-28 | 山东大学 | Modified mica sheet-nanocellulose composite nanofiltration membrane and preparation method thereof |
-
2023
- 2023-02-07 CN CN202310071844.4A patent/CN116200949A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016132760A (en) * | 2015-01-22 | 2016-07-25 | 株式会社大阪ソーダ | Titanium oxide dispersion |
| US20200232156A1 (en) * | 2017-07-20 | 2020-07-23 | Jiangnan University | Multifunctional high-strength composite fabric coating agent, coating, method for preparing the same, and application thereof |
| CN109610184A (en) * | 2018-12-15 | 2019-04-12 | 深圳市仁义和兴塑胶五金制品有限公司 | A kind of organic silicon cloth of waterproof antiwear and processing technology |
| US20220119631A1 (en) * | 2019-01-11 | 2022-04-21 | Adeka Corporation | Additive composition, thermoplastic resin composition containing same, and molded article of said thermoplastic resin composition |
| WO2022110593A1 (en) * | 2020-11-25 | 2022-06-02 | 胡森川 | Wear-resistant and aging-resistant furniture plastic particle and preparation method therefor |
| CN113802370A (en) * | 2021-10-14 | 2021-12-17 | 江苏三盛纺织有限公司 | Composite wear-resistant fabric |
| CN114669199A (en) * | 2022-03-15 | 2022-06-28 | 山东大学 | Modified mica sheet-nanocellulose composite nanofiltration membrane and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 倪礼忠等: "《聚合物基复合材料》", vol. 2, 31 January 2022, 华东理工大学出版社, pages: 169 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109610183B (en) | Aqueous polyurethane coating adhesive for textiles and fabric treatment method | |
| CN113290971B (en) | Nano antifouling and antibacterial textile fabric and preparation method thereof | |
| CN113389049A (en) | Composite cotton fiber fabric easy to dye and preparation method thereof | |
| CN110356059B (en) | Antibacterial ultraviolet-proof fabric | |
| CN113914104A (en) | Antibacterial anti-wrinkle cotton and linen fabric and preparation method thereof | |
| CN109722884A (en) | A kind of preparation method of wear-resisting high resiliency linen-cotton fabric | |
| CN110528158B (en) | Long-acting anti-fouling fabric based on nanogel treatment and preparation method thereof | |
| CN115874304A (en) | Preparation method of antistatic textile fabric | |
| CN116200949A (en) | Wear-resistant elastic rib fabric and preparation method thereof | |
| CN112176746B (en) | Preparation method of natural fiber graphene composite material | |
| CN107904960B (en) | Preparation method of smooth artificial synthetic leather | |
| CN118029134A (en) | Preparation method and application of stable aqueous anti-ultraviolet yarn finishing agent | |
| CN116100899A (en) | Wear-resistant, tear-resistant and antistatic fabric and preparation process thereof | |
| CN115354502A (en) | Wear-resistant and water-resistant composite fabric and preparation method thereof | |
| CN114808435B (en) | Alkaline finishing method of low-gram-weight polyester colored gauze | |
| CN111809271A (en) | High-performance nano ceramic uvioresistant high-thermal insulation fiber and preparation method thereof | |
| CN114438785B (en) | Anti-cracking coating finishing liquid, preparation method and treatment method thereof and jean fabric | |
| CN118498085B (en) | Flexible high-strength composite fabric and preparation method thereof | |
| CN111472169A (en) | Preparation method of all-cotton anti-pilling super-soft sanded fabric | |
| CN117127403B (en) | Production process of crease-resistant knitted fabric | |
| CN112140661A (en) | Antifouling and water-repellent textile fabric | |
| CN118205273B (en) | Functional fabric with radiation-proof antibacterial effect and production method thereof | |
| CN110820331A (en) | Preparation method of high-strength anti-wrinkle finishing agent material for natural fiber fabric | |
| CN118958008B (en) | Ultraviolet-resistant bamboo fiber fabric and preparation process thereof | |
| CN118727234B (en) | Environment-friendly breathable elastic fabric and processing technology thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |