CN116177917A - Electrolytic manganese slag treatment method and active micro powder material - Google Patents
Electrolytic manganese slag treatment method and active micro powder material Download PDFInfo
- Publication number
- CN116177917A CN116177917A CN202310467901.0A CN202310467901A CN116177917A CN 116177917 A CN116177917 A CN 116177917A CN 202310467901 A CN202310467901 A CN 202310467901A CN 116177917 A CN116177917 A CN 116177917A
- Authority
- CN
- China
- Prior art keywords
- slag
- electrolytic manganese
- treatment
- manganese slag
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002893 slag Substances 0.000 title claims abstract description 195
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 102
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 101
- 239000011572 manganese Substances 0.000 title claims abstract description 101
- 239000000463 material Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000000843 powder Substances 0.000 title claims abstract description 23
- 239000011521 glass Substances 0.000 claims abstract description 43
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 38
- 230000000694 effects Effects 0.000 claims abstract description 34
- 238000000227 grinding Methods 0.000 claims abstract description 32
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000003607 modifier Substances 0.000 claims abstract description 24
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 22
- 229910052742 iron Inorganic materials 0.000 claims abstract description 21
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003546 flue gas Substances 0.000 claims abstract description 19
- 239000000292 calcium oxide Substances 0.000 claims abstract description 16
- 235000012255 calcium oxide Nutrition 0.000 claims abstract description 16
- 230000008569 process Effects 0.000 claims abstract description 13
- 235000019738 Limestone Nutrition 0.000 claims abstract description 11
- 239000010440 gypsum Substances 0.000 claims abstract description 11
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 11
- 239000006028 limestone Substances 0.000 claims abstract description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 11
- 238000003723 Smelting Methods 0.000 claims abstract description 10
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 10
- 238000007885 magnetic separation Methods 0.000 claims abstract description 9
- 238000010791 quenching Methods 0.000 claims abstract description 9
- 230000000171 quenching effect Effects 0.000 claims abstract description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000012298 atmosphere Substances 0.000 claims abstract description 8
- 239000010459 dolomite Substances 0.000 claims abstract description 8
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 6
- 239000006227 byproduct Substances 0.000 claims abstract description 6
- 239000010453 quartz Substances 0.000 claims abstract description 6
- 239000010959 steel Substances 0.000 claims abstract description 6
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000010436 fluorite Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 17
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 16
- 239000012535 impurity Substances 0.000 claims description 15
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000012744 reinforcing agent Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000002023 wood Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- 239000002956 ash Substances 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 229940044172 calcium formate Drugs 0.000 claims description 3
- 239000004281 calcium formate Substances 0.000 claims description 3
- 235000019255 calcium formate Nutrition 0.000 claims description 3
- 239000003518 caustics Substances 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000010881 fly ash Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 238000009837 dry grinding Methods 0.000 claims 3
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 239000000047 product Substances 0.000 abstract description 10
- 238000003672 processing method Methods 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000006703 hydration reaction Methods 0.000 description 8
- 235000017550 sodium carbonate Nutrition 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- 239000004568 cement Substances 0.000 description 7
- 230000036571 hydration Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 239000004566 building material Substances 0.000 description 5
- 235000011132 calcium sulphate Nutrition 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000003837 high-temperature calcination Methods 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- -1 sodium fatty acid Chemical class 0.000 description 2
- 235000019794 sodium silicate Nutrition 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 229910000616 Ferromanganese Inorganic materials 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- CQBLUJRVOKGWCF-UHFFFAOYSA-N [O].[AlH3] Chemical compound [O].[AlH3] CQBLUJRVOKGWCF-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000037081 physical activity Effects 0.000 description 1
- 230000003334 potential effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
- C04B40/0042—Powdery mixtures
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Metallurgy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention provides a treatment method of electrolytic manganese slag and an active micro powder material. The processing method comprises the following steps: and adding a modifier and a regulator into the electrolytic manganese slag for smelting to obtain flue gas and slag. And carrying out quenching treatment on the slag to obtain glass slag. And carrying out magnetic separation treatment on the glass slag to obtain metallic iron and iron-removing glass slag. Mixing the deironing glass slag and the activity excitant in hot flue gas atmosphere to perform grinding treatment, thus obtaining the active micro powder material. Wherein, the modifier is one or more of quicklime, limestone, dolomite, industrial by-product gypsum, steel slag, quartz or tailings; the regulator is one or more of fluorite, sodium carbonate, potassium carbonate or sodium bicarbonate. Based on the method, the electrolytic manganese slag can be fully utilized, the added value of manganese slag products is higher, the market consumption is larger, and the treatment process flow is shorter.
Description
Technical Field
The invention relates to the field of electrolytic manganese slag, in particular to a treatment method of electrolytic manganese slag and an active micro powder material.
Background
The electrolytic (leached) manganese slag is industrial slag which is discharged by taking manganese ore as a raw material, grinding the manganese ore, leaching the manganese ore with sulfuric acid solution, and then carrying out filter pressing and water draining, wherein the water content of the industrial slag is generally about 20%. The electrolytic manganese slag is a fine-particle black brown solid waste, is acidic or weak acid and has a density of 2-3 g/cm 3 Between them. After the water is directly discharged, the water content is higher due to the storage of rainwater, and the water is in a pasty state. The air-dried electrolytic manganese slag particles can be clustered together, and have certain mud plasticity. According to different ore grades and production processes, the amount of the discharged manganese slag is 6-9 tons on average per 1 ton of electrolytic manganese metal produced, so that the yield of the electrolytic manganese slag is high, and a large amount of land resources are occupied. In addition, the electrolytic manganese slag contains soluble sulfate, heavy metal, residual acid and other toxic and harmful substances, and serious ecological influence is caused on local and peripheral soil and groundwater, so that harmless and recycling treatment of the electrolytic manganese slag is a trend at present.
At present, because electrolytic manganese slag contains high sulfate such as calcium sulfate, manganese sulfate, ferric sulfate and the like, most of the prior art mainly uses the electrolytic manganese slag to replace gypsum to manufacture cement retarder, produce cement concrete, wall materials and other building materials. The invention patent CN110467365A uses electrolytic manganese slag to prepare cement, the CN108585721A uses electrolytic manganese slag and steel slag tailing mud to produce autoclaved aerated blocks, and the CN109482624A uses electrolytic manganese slag to produce sintered lightweight aggregate and the like.
Of course, besides being used for manufacturing building materials, the electrolytic manganese slag also has the characteristic of high sulfur element in the manganese slag in the prior art, industrial sulfuric acid is prepared through high-temperature calcination or roasting treatment, such as the patent CN105217580B and the patent CN110482612A, the recycling of the sulfur element in the manganese slag is realized, and the added value of the product is higher. However, due to the characteristics of low activity of the mixed material after high-temperature calcination or roasting treatment, high residual sulfur content and the like, the mixing amount of the mixed material in cement is still low, the product value is low, and the process economy is poor.
In addition, aiming at the characteristic that the manganese slag is rich in iron and manganese elements, a roasting and magnetic separation process is adopted to separate metal oxides in the manganese slag, such as patent CN106755950B. Besides, manganese ore is added to prepare ferromanganese alloy in an electric furnace smelting mode, such as patent CN 105624438B, and recovery of valuable metal elements in electrolytic manganese slag is realized.
To sum up, the prior art processes electrolytic manganese slag, which is mainly developed and extracted for a certain valuable component (such as iron, manganese, sulfur, ammonia, etc.) of electrolytic manganese slag, and finally the residual low-value components (main components are CaO and SiO) 2 、Al 2 O 3 MgO, etc.) for use in building materials. The field focuses on the aspect of valuable component extraction, the development of the value of the residual components is often focused on the defect of insufficient research, so that the residual components are mostly directly used as low-value building materials for application, the added value of the product is very low, the market competitiveness is insufficient, and policy subsidy is often required to help to be barely generated. In addition, domestic electrolytic manganese enterprises are mostly concentrated in southwest areas such as Yun Guian and the like with rich manganese ores, and have more mountainous regions, less plain and inconvenient traffic. The residual low-value components after simple development and extraction cannot be widely applied to building material raw materials in each row, the sales range and market consumption of products are affected, and the economic income is also insufficient.
Therefore, it is necessary to provide a new electrolytic manganese slag treatment method, especially for electrolytic manganese slag after extracting valuable components such as sulfur, iron and the like, so that the electrolytic manganese slag can be fully recycled, and recycling is better.
Disclosure of Invention
The invention mainly aims to provide a treatment method of electrolytic manganese slag and an active micro powder material, which are used for solving the problem that the electrolytic manganese slag with extracted valuable components cannot be effectively utilized in the prior art.
In order to achieve the above object, according to one aspect of the present invention, there is provided a method for treating electrolytic manganese slag, comprising the steps of: adding a modifier and a regulator into electrolytic manganese slag to perform smelting at 1300-1450 ℃ to obtain flue gas and slag; the flue gas is used for preparing acid; quenching the slag to obtain glass slag; carrying out magnetic separation treatment on the glass slag to obtain iron-removing glass slag; mixing the deironing glass slag and the active exciting agent in hot flue gas atmosphere to perform drying and grinding treatment to obtain an active micro powder material; wherein, the modifier is one or more of quicklime, limestone, dolomite, industrial by-product gypsum, steel slag, quartz or tailings; the regulator is one or more of fluorite, sodium carbonate, potassium carbonate or sodium bicarbonate.
Further, the slag comprises the following components: caO 22-45wt%, siO 2 26~52wt%，Al 2 O 3 3-10wt% of MgO, 1-9wt% of FeO, 0.2-2wt% of MnO, 1-5wt% of MnO and the balance of impurities; preferably, the electrolytic manganese slag comprises the following components: caO 3-16wt%, siO 2 20~40wt%，Al 2 O 3 1~3wt%，MgO 1~3wt%，Fe 2 O 3 5~12wt%，MnO 4~11wt%、SO 3 28-33 wt% and the balance of impurities.
Further, the weight ratio of the modifier to the slag is (10-35): 100; preferably, the weight ratio of the regulator to the slag is (1-5): 100.
further, the weight ratio of the iron-removing glass slag to the activity excitant is 100: (5-20); preferably, the active excitant comprises a main material, auxiliary materials and an enhancer; the main materials are untreated electrolytic manganese slag and/or electrolytic manganese slag after low-temperature roasting treatment; preferably, the temperature of the low-temperature roasting treatment is 300-500 ℃; one or more of quicklime, limestone, calcined dolomite, volcanic ash, clinker or industrial gypsum as auxiliary materials; the reinforcing agent is one or more of caustic alkali, sodium carbonate, calcium sulfate, sodium silicate or sodium sulfate.
Further, the weight ratio of the main materials to the auxiliary materials to the reinforcing agents is (65-90): (10-25): (1-8).
Further, the temperature of the slag is 1250-1400 ℃, the slag is cooled to 300-500 ℃ within 2-8 s, and quenching treatment is completed.
Further, in the process of drying and grinding, the treatment temperature is 110-160 ℃ and the treatment time is 1-3 h.
Further, the raw materials in the process of drying and grinding treatment also comprise grinding aids; preferably, the grinding aid is one or more of triethanolamine, fly ash, industrial salt, triisopropanolamine, ethylene glycol, propylene glycol, glycerol, sodium fatty acid, calcium chloride, sodium acetate, aluminum sulfate, calcium formate, wood calcium or wood sodium; the consumption of the grinding aid is preferably 0.02-1% of the weight of the iron glass slag; preferably, the grinding treatment is carried out in a ball mill, a vertical mill or a roller mill.
In order to achieve the above object, according to one aspect of the present invention, there is provided an active fine powder material obtained by the aforementioned electrolytic manganese slag treatment method.
Further, the specific surface area of the active micro powder material is more than or equal to 350m 2 /kg。
Based on the method, the electrolytic manganese slag can be fully utilized, and the developed manganese slag products such as metallic iron, active micro powder and the like have higher added value, larger market consumption and shorter treatment process flow. Particularly, based on the treatment method, the harmless, reduction and recycling treatment of the electrolytic manganese slag can be realized more effectively, the potential utilization value of the manganese slag is fully excavated, and the characteristics of different properties of the electrolytic manganese slag before and after calcination are fully utilized.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the invention. In the drawings:
FIG. 1 shows a schematic flow chart of a method for treating electrolytic manganese slag in an embodiment of the invention.
Detailed Description
It should be noted that, in the case of no conflict, the embodiments and features in the embodiments may be combined with each other. The invention will be described in detail below with reference to the drawings in connection with embodiments.
As described in the background and part of the invention, the prior art has the problem that the electrolytic manganese slag after extracting valuable components cannot be effectively utilized. In order to solve the problem, the invention provides a treatment method of electrolytic manganese slag, as shown in fig. 1, comprising the following steps: adding a modifier and a regulator into electrolytic manganese slag for smelting (the modification deconstructing treatment is realized in a smelting mode, namely, the chemical components and the mineral phase composition of the original electrolytic manganese slag are changed), so as to obtain flue gas and slag. Wherein the flue gas is used for preparing acid. And carrying out quenching treatment on the slag to obtain glass slag. And carrying out magnetic separation treatment on the glass slag to obtain metallic iron and iron-removing glass slag. Mixing the deironing glass slag and the activity excitant in hot flue gas atmosphere to perform drying and grinding treatment to obtain the active micro powder material. Wherein, the modifier is one or more of quicklime, limestone, dolomite, industrial by-product gypsum, steel slag, quartz or tailings; the regulator is one or more of fluorite, sodium carbonate, potassium carbonate or sodium bicarbonate.
The electrolytic manganese slag disclosed by the invention is molten electrolytic manganese slag subjected to melting treatment (1250-1400 ℃), wherein valuable metal elements (such as iron and manganese), sulfur-containing compounds (such as calcium sulfate) and water are separated, and the residual main components are calcium oxide, silicon oxide, aluminum oxide, magnesium oxide and the like. According to the invention, the electrolytic manganese slag, the modifier and the regulator are mixed to carry out modification and deconstruction treatment at 1300-1450 ℃ so as to obtain slag and flue gas (the flue gas is sent to an acid making system to prepare concentrated sulfuric acid and the like). And then quenching the slag to obtain glass slag (amorphous). And then carrying out magnetic separation treatment on the glass slag so as to further remove metal iron mixed in the glass slag and obtain the iron-removing glass slag. Finally, the deironing glass slag and the activity excitant are mixed in hot flue gas atmosphere to carry out grinding treatment, so that the materials can be ground while being dried, and the active micro powder material is obtained efficiently. Wherein, the modifier is one or more of fluorite, sodium carbonate, potassium carbonate or sodium bicarbonate, which can further reduce the viscosity of slag on the basis of better fluxing property. The modifier is one or more of quicklime, limestone, dolomite, industrial by-product gypsum, steel slag, quartz or tailings, and can further effectively reduce the connection degree of silicon-oxygen and aluminum-oxygen networks in the slag. The smelting temperature is lower than 1300 ℃, and the activity index of the obtained micro powder material is lower in the subsequent application process; the application performance of the micro powder material is not increased in a breakthrough way when the temperature is higher than 1450 ℃, but the damage of the kiln refractory is promoted to be quicker, the energy consumption is higher, the overall cost is higher, and the economical efficiency is poorer.
The active micro powder material obtained by the treatment method can change the chemical components and the mineral phase composition of the original electrolytic manganese slag (the raw slag has poor hydration activity), has excellent potential hydration activity (the potential hydration activity is that the material can generate complex hydration reaction under the alkaline solution environment to generate hydration products with cementing property), can be directly used as an active admixture for being sold to production enterprises such as concrete, cement products and the like, has excellent hydration activity under corresponding conditions (such as alkaline conditions), replaces partial cement raw materials to be used, and reduces the cost.
In a word, the invention can fully utilize the electrolytic manganese slag, the added value of the manganese slag product is higher, the market consumption is larger, and the treatment process flow is shorter. In particular, based on the treatment method, the harmless, reduction and recycling treatment of the electrolytic manganese slag can be realized more effectively, and the characteristics of different properties of the electrolytic manganese slag before and after calcination are fully utilized.
In an alternative embodiment, the glass slag is subjected to a magnetic separation treatment by passing it through a magnetic separation drum or other iron removal device, on the basis of which the metals entrained in the glass slag can be ferromagnetically separated and sold as iron raw material.
The electrolytic manganese slag disclosed by the invention is molten electrolytic manganese slag subjected to melting treatment (1250-1400 ℃), wherein valuable metal elements (such as iron and manganese), sulfur-containing compounds (such as calcium sulfate) and water are separated, and the residual main components are calcium oxide, silicon oxide, aluminum oxide, magnesium oxide and the like. Specifically, the electrolytic manganese slag comprises the following components: caO 3-16wt%, siO 2 20~40wt%，Al 2 O 3 1~3wt%，MgO 1~3wt%，Fe 2 O 3 5~12wt%，MnO 4~11wt%、SO 3 28 to 33wt% and the balance of impurities (e.g. NaO) 2 、K 2 O、BaO、P 2 O 5 NH and NH 4+ Etc.). The mineral phase composition of the electrolytic manganese slag is as follows: quartz, gypsum, iron vitriol, hematite, feldspar, mica, calcite, chlorite, and the like.
In a preferred embodiment, the slag comprises the following components: caO 22-45wt%, siO 2 26~52wt%，Al 2 O 3 3-10wt% of MgO, 1-9wt% of FeO, 0.2-2wt% of MnO, 1-5wt% of MnO and the balance of impurities. The mineral phase of the slag is mainly a glassy phase. In order to further improve the effect of the modification and deconstruction treatment, the weight ratio of the modifier to the slag is preferably (10 to 35): 100, which may be, for example, 10:100, 15:100, 20:100, 25:100, 30:100 or 35:100; the weight ratio of the regulator to the slag is (1-5): 100, for example, may be 1:100, 2:100, 3:100, 4:100, or 5:100. Based on the method, the synergistic effect of the modifier and the regulator is better, so that the reagent and the electrolytic manganese slag can be promoted to fully react, the effect of modification and deconstruction treatment can be promoted to be better, more electrolytic manganese slag can be subjected to effective treatment, and the performance of the subsequently obtained active micro powder material is better. Wherein, the micro powder material with excellent activity can not be obtained by too little modifier; and too much amount of the catalyst has larger influence on the physical and chemical properties of the slag, so that the melting temperature and the viscosity of the slag are increased, and the temperature is required to be increased, which brings about problems caused by the temperature increase, and has poorer cost and economy.
In a preferred embodiment, the active activator comprises a main ingredient, an auxiliary ingredient and a reinforcing agent. The main materials are untreated electrolytic manganese slag and/or electrolytic manganese slag after low-temperature roasting treatment; the temperature of the low-temperature roasting treatment is preferably 300-500 ℃. Based on the method, the treatment method not only adopts a modification and activation process route which takes molten electrolytic manganese slag as a main body cementing material, but also adopts a manganese slag double-main-body utilization route which takes electrolytic manganese slag which is in an original state or is subjected to low-temperature roasting and activation treatment as a main body activity excitant, fully utilizes the performance characteristics of the manganese slag at different temperatures, improves the comprehensive resource utilization rate of the manganese slag, develops a novel manganese slag-based activity excitant which takes the manganese slag as the main body material of the activity excitant, can effectively improve the potential activity of the molten manganese slag, and reduces the manufacturing cost of the activity excitant material.
In order to further increase the excitation effect of the activity excitant, one or more of quicklime, limestone, calcined dolomite, volcanic ash, clinker or industrial gypsum (for example, industrial solid waste such as industrial byproduct gypsum) is preferably selected as auxiliary materials; preferably the strengthening agent is one or more of caustic, sodium carbonate, calcium sulphate, sodium silicate or sodium sulphate. Based on the above, the main materials, auxiliary materials and the reinforcing agent have better synergistic effect. Further preferably, the weight ratio of the main material to the auxiliary material to the reinforcing agent is (65-90): (10-25): (1-8), for example, may be 65:10:1, 70:12:2, 75:14:3, 80:15:4, 85:20:6, or 90:25:8.
In a preferred embodiment, the weight ratio of the iron-removing glass slag to the activity excitant is 100: (5-20), for example, may be 100:5, 100:10, 100:15 or 100:20. Based on the method, the excitation effect of the iron-removing glass slag is better, so that the activity of the active micro powder material is better, and the utilization value is higher.
In order to further improve the morphological effect of the glass slag, the temperature of the slag is 1250-1400 ℃, the temperature of the slag is reduced to 300-500 ℃ within 2-8 seconds, and quenching treatment is completed. Based on this, amorphous glassy residues can be obtained more smoothly and efficiently.
In a preferred embodiment, the iron-removing glass slag and the activity excitant are mixed under the hot flue gas atmosphere (110-160 ℃) to carry out drying and grinding treatment, wherein the treatment temperature is 110-160 ℃ and the treatment time is 1-3 hours in the grinding treatment process. When the temperature is too low, the drying time is long, the production efficiency is low, and when the temperature is too high, the energy consumption is increased. In the concrete operation, the flue gas from the kiln can be utilized by the person skilled in the art to provide hot flue gas atmosphere for grinding treatment, the heat release can be further generated by the severe movement friction of the glass slag, the consumption of dry flue gas is reduced, meanwhile, water stored by solid slag is released by mutual collision among particles, and the grinding effect is better.
In order to further improve the grinding effect, so that the active micro powder material is promoted to have better application specific surface area, preferably, the raw materials in the grinding treatment process also comprise grinding aids; more preferably, the grinding aid is one or more of triethanolamine, fly ash, industrial salt, triisopropanolamine, ethylene glycol, propylene glycol, glycerol, sodium fatty acid, calcium chloride, sodium acetate, aluminum sulfate, calcium formate, wood calcium or wood sodium; the consumption of the grinding aid is 0.02-1% of the weight of the dry glass slag. The above-described grinding treatment of the present invention is carried out in a ball mill, a vertical mill or a roll mill.
The invention also provides an active micro powder material which is obtained by the treatment method of the electrolytic manganese slag.
Based on the reasons, the active micro powder material obtained by the treatment method has potential hydration activity and better activity. The material can be used as an active mixed material by virtue of better hydration activity, and can be directly used as an active admixture for being sold to production enterprises such as concrete, cement products and the like. The specific surface area of the active micropowder material is not less than 350m 2 /kg。
The present application is described in further detail below in conjunction with specific embodiments, which should not be construed as limiting the scope of the claims.
Example 1
Electrolytic manganese slag components: caO 7wt%, siO 2 30wt%、MnO4wt%、Fe 2 O 3 6wt%、Al 2 O 3 2.5wt%、MgO 2.4wt%、SO 3 30wt% and the balance impurities.
The electrolytic manganese slag, the modifier (limestone) and the regulator (sodium carbonate) are mixed according to the weight ratio of 86:12:2, and then are put into a melting furnace and are smelted at 1400 ℃ to obtain slag. The slag comprises the following components: 25wt% of CaO and SiO 2 55wt%，Al 2 O 3 4.5wt percent of MgO 5.6wt percent, feO 1.0wt percent, mnO 1.4wt percent and the balance of impurities.
Wherein the weight ratio of the modifier to the slag is 26:100; the weight ratio of the regulator to the slag is 2:100.
the slag enters a cooler through a chute, and is cooled to 350 ℃ in 6s in a water spray cooling mode, so that quenching is completed, and glass slag is obtained. And carrying out magnetic separation on the glass slag to remove iron to obtain iron-removed glass slag. Removal ofAfter iron glass slag is doped with an activity excitant (the weight ratio of electrolytic manganese slag, quicklime and sodium silicate which are subjected to oxidation roasting treatment at 400 ℃ is 80:15:4) and grinding aid (triethanolamine), grinding is carried out in a ball mill (under the atmosphere of hot flue gas at 160 ℃) for 2 hours to a specific surface area of 410m 2 And (3) per kg, preparing the active micro powder material. Wherein, the weight ratio of the iron-removing glass slag to the activity excitant is 100:10; the consumption of the grinding aid is 0.1 percent of the weight of the iron-removing glass slag.
Example 2
The only difference from example 1 is that:
the electrolytic manganese slag, the modifier (limestone) and the regulator (sodium carbonate) are mixed according to the weight ratio of 100:10:1, and then are put into a melting furnace and are smelted at 1350 ℃ to obtain slag. The slag comprises the following components: caO 22.3wt%, siO 2 57.3wt%，Al 2 O 3 4.7wt percent of MgO 5.5wt percent, feO 1.0wt percent, mnO 1.5wt percent and the balance of impurities.
Wherein the weight ratio of the modifier to the slag is 19:100; the weight ratio of the regulator to the slag is 1.9:100. the weight ratio of the iron-removing glass slag to the activity excitant is 100:5, a step of; the consumption of the grinding aid is 0.05 percent of the weight of the iron glass slag. Grinding to specific surface area of 380m 2 /kg。
Example 3
The only difference from example 1 is that:
the electrolytic manganese slag, the modifier (limestone) and the regulator (sodium carbonate) are mixed according to the weight ratio of 100:35:5, and then are put into a melting furnace and are smelted at 1400 ℃ to obtain slag. The slag comprises the following components: caO 34.1wt%, siO 2 44.3wt%，Al 2 O 3 3.6wt percent of MgO 5.9wt percent, 0.8wt percent of FeO, 1.2wt percent of MnO and the balance of impurities.
Wherein the weight ratio of the modifier to the slag is 50:100; the weight ratio of the regulator to the slag is 7:100.
the weight ratio of the iron-removing glass slag to the activity excitant is 100:18; the consumption of the grinding aid is 1% of the weight of the iron glass slag. Grinding to specific surface area of 450m 2 /kg。
Example 4
The only difference from example 1 is that: smelting is carried out at 1300 ℃.
The slag comprises the following components: 25wt% of CaO and SiO 2 55wt%，Al 2 O 3 4.5wt percent of MgO 5.6wt percent, feO 1.0wt percent, mnO 1.4wt percent and the balance of impurities.
Example 5
The only difference from example 1 is that: smelting is carried out at 1450 ℃.
The slag comprises the following components: 25wt% of CaO and SiO 2 55wt%，Al 2 O 3 4.5wt percent of MgO 5.6wt percent, feO 1.0wt percent, mnO 1.4wt percent and the balance of impurities.
Example 6
The only difference from example 1 is that: smelting is carried out at 1200 ℃.
The slag comprises the following components of CaO 25wt percent and SiO 2 55wt%，Al 2 O 3 4.5wt percent of MgO 5.6wt percent, feO 1.0wt percent, mnO 1.4wt percent and the balance of impurities.
Example 7
The only difference from example 1 is that: the weight ratio of the modifier to the slag is 10:100.
the slag comprises the following components: caO 18.8wt%, siO 2 60.5wt%，Al 2 O 3 5wt%, mgO 5.3wt%, feO 1.1wt%, mnO 4.0wt% and the balance of impurities.
Example 8
The only difference from example 1 is that: the weight ratio of the modifier to the slag is 35:100.
the slag comprises the following components: caO 28.6wt%, siO 2 51.7wt%，Al 2 O 3 4.2wt percent of MgO, 5.8wt percent of FeO, 0.9wt percent of MnO, 1.4wt percent and the balance of impurities.
Characterization of the properties:
activity index test: the test is performed with reference to GB/T18046-2017.
TABLE 1
The above is only a preferred embodiment of the present invention, and is not intended to limit the present invention, but various modifications and variations can be made to the present invention by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (10)
1. The method for treating the electrolytic manganese slag is characterized by comprising the following steps of:
adding a modifier and a regulator into the electrolytic manganese slag to perform smelting at 1300-1450 ℃ to obtain flue gas and slag;
the flue gas is used for preparing acid;
quenching the slag to obtain glass slag;
carrying out magnetic separation treatment on the glass slag to obtain iron-removing glass slag;
mixing the deironing glass slag and the activity excitant in hot flue gas atmosphere to perform drying grinding treatment to obtain an active micro powder material;
wherein the modifier is one or more of quicklime, limestone, dolomite, industrial by-product gypsum, steel slag, quartz or tailings; the regulator is one or more of fluorite, sodium carbonate, potassium carbonate or sodium bicarbonate.
2. The method for treating electrolytic manganese slag according to claim 1, wherein the slag comprises the following components: caO 22-45wt%, siO 2 26~52wt%，Al 2 O 3 3-10wt% of MgO, 1-9wt% of FeO, 0.2-2wt% of MnO, 1-5wt% of MnO and the balance of impurities;
the electrolytic manganese slag comprises the following components: caO 3-16wt%, siO 2 20~40wt%，Al 2 O 3 1~3wt%，MgO 1~3wt%，Fe 2 O 3 5~12wt%，MnO 4~11wt%、SO 3 28-33 wt% and the balance of impurities.
3. The method for treating electrolytic manganese slag according to claim 1 or 2, wherein the weight ratio of the modifier to the slag is (10 to 35): 100;
the weight ratio of the regulator to the slag is (1-5): 100.
4. the method for treating electrolytic manganese slag according to claim 1 or 2, wherein the weight ratio of the iron-removing glass slag to the activity excitant is 100: (5-20);
the active excitant comprises main materials, auxiliary materials and reinforcing agents;
the main material is the electrolytic manganese slag and/or the electrolytic manganese slag after low-temperature roasting treatment; the temperature of the low-temperature roasting treatment is 300-500 ℃;
the auxiliary materials are one or more of quicklime, limestone, calcined dolomite, volcanic ash, clinker or industrial gypsum;
the reinforcing agent is one or more of caustic alkali, sodium carbonate, calcium sulfate, sodium silicate or sodium sulfate.
5. The method for treating electrolytic manganese slag according to claim 4, wherein the weight ratio of the main material, the auxiliary material and the reinforcing agent is (65-90): (10-25): (1-8).
6. The method for treating electrolytic manganese slag according to claim 1 or 2, wherein the temperature of the slag is 1250-1400 ℃, the slag is cooled to 300-500 ℃ within 2-8 seconds, and the quenching treatment is completed.
7. The method for treating electrolytic manganese slag according to claim 1, wherein in the dry grinding treatment process, the treatment temperature is 110-160 ℃ and the treatment time is 1-3 h.
8. The method for treating electrolytic manganese slag according to claim 7, wherein the raw materials in the dry grinding treatment process further comprise grinding aids;
the grinding aid is one or more of triethanolamine, fly ash, industrial salt, triisopropanolamine, ethylene glycol, propylene glycol, glycerol, fatty acid sodium, calcium chloride, sodium acetate, aluminum sulfate, calcium formate, wood calcium or wood sodium;
the consumption of the grinding aid is 0.02-1% of the weight of the iron glass slag;
the dry grinding treatment is carried out in a ball mill, a vertical mill or a roller mill.
9. An active micropowder material, characterized in that it is obtained by the method for treating electrolytic manganese slag according to any one of claims 1 to 8.
10. The active micropowder material according to claim 9, characterized in that the specific surface area of the active micropowder material is not less than 350m 2 /kg。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310467901.0A CN116177917B (en) | 2023-04-27 | 2023-04-27 | Electrolytic manganese slag treatment method and active micro powder material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310467901.0A CN116177917B (en) | 2023-04-27 | 2023-04-27 | Electrolytic manganese slag treatment method and active micro powder material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN116177917A true CN116177917A (en) | 2023-05-30 |
| CN116177917B CN116177917B (en) | 2023-08-11 |
Family
ID=86449322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310467901.0A Active CN116177917B (en) | 2023-04-27 | 2023-04-27 | Electrolytic manganese slag treatment method and active micro powder material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116177917B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118162447A (en) * | 2024-05-13 | 2024-06-11 | 中国恩菲工程技术有限公司 | Treatment method of electrolytic manganese slag |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109133761A (en) * | 2018-07-17 | 2019-01-04 | 枞阳县天筑新型建筑材料有限公司 | It is a kind of to prepare non-burning brick technique using iron tailings-Quadratic aluminum dust slag-acidleach manganese slag |
| CN109369020A (en) * | 2018-10-09 | 2019-02-22 | 交城义望铁合金有限责任公司 | A kind of calendering technology method producing devitrified glass or stone slab using liquid manganese slag |
| CN115093146A (en) * | 2022-05-09 | 2022-09-23 | 中国恩菲工程技术有限公司 | Composite excitant and preparation method and application thereof |
| KR102487469B1 (en) * | 2022-11-16 | 2023-01-11 | 합자회사성주개발 | Concrete composition using manganese slag |
| KR102487478B1 (en) * | 2022-11-16 | 2023-01-11 | 합자회사성주개발 | A ready-mixed concrete composition containing manganese slag and a method of producing ready-mixed concrete using the composition |
| CN115636607A (en) * | 2022-11-17 | 2023-01-24 | 中国恩菲工程技术有限公司 | Method and system for cooperatively treating high-iron red mud and electrolytic manganese slag |
-
2023
- 2023-04-27 CN CN202310467901.0A patent/CN116177917B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109133761A (en) * | 2018-07-17 | 2019-01-04 | 枞阳县天筑新型建筑材料有限公司 | It is a kind of to prepare non-burning brick technique using iron tailings-Quadratic aluminum dust slag-acidleach manganese slag |
| CN109369020A (en) * | 2018-10-09 | 2019-02-22 | 交城义望铁合金有限责任公司 | A kind of calendering technology method producing devitrified glass or stone slab using liquid manganese slag |
| CN115093146A (en) * | 2022-05-09 | 2022-09-23 | 中国恩菲工程技术有限公司 | Composite excitant and preparation method and application thereof |
| KR102487469B1 (en) * | 2022-11-16 | 2023-01-11 | 합자회사성주개발 | Concrete composition using manganese slag |
| KR102487478B1 (en) * | 2022-11-16 | 2023-01-11 | 합자회사성주개발 | A ready-mixed concrete composition containing manganese slag and a method of producing ready-mixed concrete using the composition |
| CN115636607A (en) * | 2022-11-17 | 2023-01-24 | 中国恩菲工程技术有限公司 | Method and system for cooperatively treating high-iron red mud and electrolytic manganese slag |
Non-Patent Citations (3)
| Title |
|---|
| 文光远: "《铁冶金学》", 重庆大学出版社, pages: 64 * |
| 王志强, 马春, 韩趁涛: "碳铬渣、硅锰渣微晶玻璃的研制", 玻璃与搪瓷, no. 06, pages 64 * |
| 赵虎腾;李远霞;谭德斌;张杰;张东方;宋谋胜;: "电解锰渣的理化特性与物相转变研究", 广东化工, no. 07 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118162447A (en) * | 2024-05-13 | 2024-06-11 | 中国恩菲工程技术有限公司 | Treatment method of electrolytic manganese slag |
Also Published As
| Publication number | Publication date |
|---|---|
| CN116177917B (en) | 2023-08-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101805827B (en) | Sludge oxidized pellet and its preparation method | |
| KR101903438B1 (en) | Non-roasting Pellet Composition Prepared By Using Melted Iron slags and Melted Iron Process By-products, and Pellet Preparation Method | |
| CN105271327B (en) | A kind of aluminum ash harmless treatment the method for recycling | |
| CN110106312B (en) | Process for producing LF (ladle furnace) slagging agent by using electrolytic aluminum carbon slag | |
| EP3535429A1 (en) | Process for the recovery of lithium | |
| CN105861845B (en) | A kind of method of Combined Treatment copper ashes and slag | |
| CN112063834B (en) | A method for returning stainless steel pickling sludge to rotary kiln-submerged arc furnace process utilization | |
| CN116177917B (en) | Electrolytic manganese slag treatment method and active micro powder material | |
| CN108950212B (en) | A kind of method for comprehensively recovering sodium, aluminum and iron from red mud | |
| RU2634831C2 (en) | Titan containing filler, method for its manufacturing and its application | |
| CN111101002A (en) | Production process for magnesium smelting and cement co-production by Pidgeon process | |
| CN115354156B (en) | A method for removing alkali metals from vanadium extraction tailings by calcination roasting-leaching | |
| US10703675B2 (en) | Method for processing steel slag and hydraulic mineral binder | |
| Wang et al. | A novel method of extracting iron from high-iron red mud and preparing low-carbon cement clinker from tailings | |
| CN105543484A (en) | Method for treating waste lead-acid battery colloid sludge through zinc hydrometallurgy residues to recover lead and silver | |
| Li et al. | Review on comprehensive recovery valuable metals and utilization of copper slag | |
| CN113463134B (en) | Process method for producing electrolytic manganese metal by using silicomanganese slag | |
| CN105483381A (en) | Comprehensive utilization method of nickel and iron slags | |
| CN109402386B (en) | Composite additive for promoting recovery of iron and aluminum in red mud and preparation and use methods thereof | |
| CN106282583A (en) | A kind of recovery non-ferrous metal, rare precious metal and method of iron powder from ironmaking dust | |
| CN109913604B (en) | Method for extracting iron from high-iron red mud and directly cementing | |
| CN108330289B (en) | A kind of processing method of copper smelting by pyrometallurgy clinker | |
| CN108970621B (en) | Method for preparing water body COD degradation catalyst by using laterite-nickel ore smelting waste residues and application of water body COD degradation catalyst in ozone degradation | |
| CN114990330B (en) | Chromium slag harmless recycling treatment method, active micro powder material composition and active micro powder material | |
| CN107858476B (en) | Composite slag modifier for converter steelmaking |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |