CN116145133B - A method for laser epitaxial growth of nickel-based single crystal high-temperature alloy - Google Patents
A method for laser epitaxial growth of nickel-based single crystal high-temperature alloy Download PDFInfo
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Abstract
Description
技术领域Technical Field
本发明属于镍基单晶材料结构修复技术领域,涉及一种镍基单晶高温合金的激光外延生长方法。The invention belongs to the technical field of nickel-based single crystal material structure repair, and relates to a laser epitaxial growth method of a nickel-based single crystal high-temperature alloy.
背景技术Background Art
镍基单晶高温合金涡轮叶片由于没有晶界,材料的抗蠕变和热疲劳性能大大提高,最高工作温度可达1100℃,已被广泛应用于航空发动机等领域。Nickel-based single crystal high-temperature alloy turbine blades have no grain boundaries, so the creep and thermal fatigue resistance of the material is greatly improved. The maximum operating temperature can reach 1100°C, and they have been widely used in aero engines and other fields.
尽管如此,由于工作环境恶劣,单晶叶片在工作一段时间后,还是会产生裂纹等表面缺陷,导致发动机失效。目前的一般情况是一旦发现裂纹等缺陷就要更换,但是镍基单晶高温合金叶片造价昂贵,更换成本很高。因此,对镍基单晶高温合金叶片进行修复成为了目前各国的研究热点。Despite this, due to the harsh working environment, single crystal blades will still have surface defects such as cracks after working for a period of time, causing engine failure. At present, the general situation is that once cracks and other defects are found, they must be replaced, but nickel-based single crystal high-temperature alloy blades are expensive and the replacement cost is very high. Therefore, repairing nickel-based single crystal high-temperature alloy blades has become a research hotspot in various countries.
理想的镍基单晶高温合金叶片修复技术,应该是使修复后材料的结晶结构等同于晶体的单晶结构,从而保证修复叶片的服役周期与可靠性。The ideal nickel-based single-crystal high-temperature alloy blade repair technology should be to make the crystal structure of the repaired material equivalent to the single crystal structure of the crystal, thereby ensuring the service life and reliability of the repaired blade.
激光熔覆具有精确的能量输入,更高的温度梯度和更好的可控性,适合于实现结构复杂的涡轮叶片的晶粒外延生长。Laser cladding has precise energy input, higher temperature gradient and better controllability, and is suitable for achieving grain epitaxial growth of turbine blades with complex structures.
近些年,研究者们研究了激光熔覆技术在镍基单晶高温合金修复领域的应用,通过控制激光工艺,实现了镍基单晶合金的激光修复,但是通过激光进行精确修复单晶合金还是具有许多问题。In recent years, researchers have studied the application of laser cladding technology in the field of nickel-based single crystal high-temperature alloy repair. By controlling the laser process, laser repair of nickel-based single crystal alloys has been achieved. However, there are still many problems in accurately repairing single crystal alloys by laser.
本发明提出一种通过理论模型精确控制枝晶外延生长,利用MATLAB和仿真软件进行计算和仿真,以达到精确修复单晶高温合金的方法,可以弥补激光熔覆技术修复单晶合金的理论空白。The present invention proposes a method for accurately repairing single crystal high-temperature alloys by accurately controlling the epitaxial growth of dendrites through a theoretical model and performing calculations and simulations using MATLAB and simulation software, which can fill the theoretical gap in repairing single crystal alloys using laser cladding technology.
发明内容Summary of the invention
本发明的目的是提供一种利用激光熔覆技术实现的镍基单晶高温合金激光外延生长方法,通过使用MATLAB和仿真软件进行计算和仿真,以筛选得到适合的激光工艺参数控制激光定向熔覆镍基单晶沿着合适的方向进行外延生长,解决镍基单晶高温合金激光精密修复中的技术问题。The purpose of the present invention is to provide a method for laser epitaxial growth of nickel-based single crystal high-temperature alloys using laser cladding technology. By using MATLAB and simulation software for calculation and simulation, suitable laser process parameters are screened to control the laser directional cladding of nickel-based single crystals to grow epitaxially along a suitable direction, thereby solving the technical problems in laser precision repair of nickel-based single crystal high-temperature alloys.
为实现上述发明目的,本发明提供的镍基单晶高温合金激光外延生长方法包括:To achieve the above-mentioned purpose of the invention, the laser epitaxial growth method of nickel-based single crystal high-temperature alloy provided by the present invention comprises:
1)、建立激光熔覆模型,加载高斯移动热源模型,计算得到激光熔覆熔池的大小及温度梯度分布,具体包括:1) Establish a laser cladding model, load the Gaussian moving heat source model, and calculate the size of the laser cladding molten pool and the temperature gradient distribution, including:
a)、将所需修复镍基单晶高温合金的材料成分输入在JMatPro材料性能模拟软件中,计算得到镍基单晶高温合金的材料特性参数特性熔化温度T、导热系数k、比热容Cp、密度ρ和融化潜热L,并将所述材料特性参数导出,定义在Ansys仿真软件中;a) Input the material composition of the nickel-based single crystal high-temperature alloy to be repaired into the JMatPro material performance simulation software, calculate the material characteristic parameters of the nickel-based single crystal high-temperature alloy, the melting temperature T, thermal conductivity k, specific heat capacity Cp, density ρ and melting latent heat L, and export the material characteristic parameters and define them in the Ansys simulation software;
b)、按照高斯移动热源模型计算公式输入激光工艺参数建立高斯移动热源,通过编写ANSYS APDL命令流,将所述高斯移动热源加载在Ansys仿真软件中,利用高斯移动热源实现激光加工的仿真模拟,b) According to the calculation formula of Gauss moving heat source model Input laser process parameters to establish Gaussian moving heat source, load the Gaussian moving heat source into Ansys simulation software by writing ANSYS APDL command stream, and use Gaussian moving heat source to realize laser processing simulation.
其中:in:
R为反射率,%;R is reflectivity, %;
P为激光输出功率,W;P is the laser output power, W;
ω为入射激光光斑半径,mm;ω is the incident laser spot radius, mm;
r为横向柱坐标;r is the transverse cylindrical coordinate;
c)、利用Design Modeler软件建立激光熔覆模型,设定激光沿X轴进行扫过,Z轴正方向为镍基单晶高温合金的[001]方向;c) Use Design Modeler software to establish a laser cladding model, set the laser to scan along the X-axis, and the positive direction of the Z-axis is the [001] direction of the nickel-based single crystal high-temperature alloy;
d)、将JMatPro软件导出的镍基单晶高温合金的材料特性参数分别赋予所建立的激光熔覆模型中的基板材料和熔覆层材料;d) assigning the material characteristic parameters of the nickel-based single crystal high-temperature alloy derived from the JMatPro software to the substrate material and the cladding layer material in the established laser cladding model;
e)、设定激光熔覆熔池仿真的边界条件,包括初始温度T0、对流换热条件以及表面热辐射条件;e) Setting boundary conditions for laser cladding molten pool simulation, including initial temperature T 0 , convection heat transfer conditions, and surface thermal radiation conditions;
f)、进行模型求解,得到激光熔覆熔池的大小,导出温度梯度分布及其在X、Y、Z轴方向上的分量Gx、Gy、Gz。f) Solve the model to obtain the size of the laser cladding molten pool, and derive the temperature gradient distribution and its components G x , G y , and G z in the X, Y, and Z axis directions.
其中,所述步骤b)中具体是将高斯移动热源加载到Ansys仿真软件中激光熔覆模型基板的上表面。Wherein, the step b) specifically involves loading a Gaussian moving heat source onto the upper surface of the laser cladding model substrate in the Ansys simulation software.
进而,由于所述高斯移动热源是沿X轴进行激光扫描的,因此:Furthermore, since the Gaussian moving heat source performs laser scanning along the X-axis, therefore:
r=[(x-v·t)2+y2]0.5 r=[(xv·t) 2 +y 2 ] 0.5
其中:in:
v是激光扫描速度,mm/s;v is the laser scanning speed, mm/s;
t为扫描时间,s。t is the scanning time, s.
2)、通过Hunt模型和矢量化计算模型,进行枝晶生长方向的计算,求解得出枝晶生长方向,以及激光熔覆熔池内任意一点的温度梯度矢量,具体包括:2) The growth direction of the dendrite is calculated by using the Hunt model and the vectorized calculation model, and the growth direction of the dendrite and the temperature gradient vector at any point in the laser cladding molten pool are obtained. Specifically, the following are the results:
a)、Hunt模型中,凝固界面前沿生长速度与激光热源移动速度之间满足关系:a) In the Hunt model, the growth rate of the solidification interface front The laser heat source moving speed Satisfying relationship between:
而枝晶生长速度与凝固界面前沿生长速度之间满足关系:The dendrite growth rate The growth rate of the solidification interface front Satisfying relationship between:
将上述两式联立,则可以得到枝晶生长速度与激光热源移动速度之间的关系:Combining the above two equations, we can get the relationship between the dendrite growth rate and the laser heat source moving speed:
其中:in:
θ为法线与激光移动方向的夹角;θ is the normal Angle with the laser moving direction;
为法线与晶体学方向[hkl]的夹角; Normal Angle with the crystallographic direction [hkl];
b)、通过Ansys模型求解得到的熔池内部在X、Y、Z轴方向上的分量Gx、Gy、Gz通过与之平行的温度梯度的方向来确定凝固界面前沿的推进方向,即法线方向,进而得到凝固界面推进方向与枝晶生长方向之间的夹角 b) The components Gx , Gy , and Gz in the X, Y, and Z directions of the molten pool obtained by solving the Ansys model are used to determine the advancement direction of the solidification interface front, that is, the normal direction, through the direction of the temperature gradient parallel to it, and then the angle between the advancement direction of the solidification interface and the dendrite growth direction is obtained.
c)、建立矢量化计算模型,设定激光沿[h1k1l1]晶向在(h3k3l3)的基材表面扫过,因此,晶体学取向中X、Y、Z轴则分别对应于[h1k1l1],[h2k2l2],[h3k3l3],其中[h2k2l2]可以通过[h1k1l1]与[h3k3l3]的叉乘获得:c) Establish a vectorized calculation model and set the laser to scan along the [h 1 k 1 l 1 ] crystal direction on the substrate surface of (h 3 k 3 l 3 ). Therefore, the X, Y, and Z axes in the crystallographic orientation correspond to [h 1 k 1 l 1 ], [h 2 k 2 l 2 ], and [h 3 k 3 l 3 ], respectively, where [h 2 k 2 l 2 ] can be obtained by the cross product of [h 1 k 1 l 1 ] and [h 3 k 3 l 3 ]:
[h2k2l2]=[h1k1l1]×[h3k3l3][h 2 k 2 l 2 ]=[h 1 k 1 l 1 ]×[h 3 k 3 l 3 ]
任意一点在X、Y、Z三个方向上的温度梯度矢量为:Temperature gradient vector of any point in the X, Y, and Z directions for:
利用MATLAB软件将所述矢量化计算,求解得到熔池内任意一点在X、Y、Z三个方向上的温度梯度矢量 The vector calculation is performed using MATLAB software to obtain the temperature gradient vector of any point in the molten pool in the X, Y, and Z directions.
3)、判断熔池内任意一点在X、Y、Z三个方向上的温度梯度与枝晶生长速度是否可发生CET转变,并判断是否可实现基板的枝晶外延生长,通过其枝晶生长的范围确定最优激光工艺参数3) Determine whether the temperature gradient and dendrite growth rate in the X, Y, and Z directions at any point in the molten pool can undergo CET transformation, and determine whether the dendrite epitaxial growth of the substrate can be achieved, and determine the optimal laser process parameters based on the range of dendrite growth.
CET转变即柱状晶—等轴晶转变。当发生CET转变,即Gn/V<KCET时,柱状晶就会转变成等轴晶,形成没有方向性的组织;因此,并不希望发生CET转变,而是希望上述计算得到的Gn/Vhkl>KCET。CET transformation is the transformation from columnar crystal to equiaxed crystal. When CET transformation occurs, that is, Gn /V< KCET , the columnar crystal will transform into equiaxed crystal, forming a non-directional structure; therefore, CET transformation is not desired, but Gn / Vhkl > KCET calculated above is desired.
上述判断公式中:In the above judgment formula:
G是凝固前沿的温度梯度;G is the temperature gradient at the solidification front;
Vhkl是柱状枝晶沿[hkl]晶向的生长速度;V hkl is the growth velocity of columnar dendrites along the [hkl] crystal direction;
KCET是CET转变临界值,为与材料相关的常数,本发明镍基单晶高温合金的KCET取值为2.7×1028;K CET is the CET transition critical value, which is a constant related to the material. The K CET value of the nickel-based single crystal high-temperature alloy of the present invention is 2.7×10 28 ;
n是材料参数,本发明镍基单晶高温合金的材料参数取值为3.4。n is a material parameter, and the material parameter of the nickel-based single crystal high-temperature alloy of the present invention is 3.4.
通过上述公式的计算可以判断枝晶是否外延生长成为单晶。The calculation of the above formula can determine whether the dendrite grows epitaxially into a single crystal.
只要当某一分量的Gn/Vhkl比值满足大于临界值KCET时,就可以实现单晶生长,即实现枝晶外延生长;对于多个分量的Gn/Vhkl比值都满足大于临界值KCET时,柱状枝晶则优先沿温度梯度最大的方向进行生长。As long as the Gn / Vhkl ratio of a certain component satisfies the critical value KCET , single crystal growth can be achieved, that is, dendrite epitaxial growth can be achieved; when the Gn / Vhkl ratios of multiple components all meet the critical value KCET , columnar dendrites preferentially grow along the direction with the largest temperature gradient.
进一步地,继续判断所述生长方向是否为基板取向,并将所有可以实现基板取向的枝晶外延生长的激光工艺参数筛选出来。Furthermore, it is continued to be determined whether the growth direction is substrate-oriented, and all laser process parameters that can achieve substrate-oriented dendrite epitaxial growth are screened out.
更进一步的,本发明对于可以实现枝晶外延生长的激光工艺参数,通过判断其枝晶外延生长的范围,将其中最大范围对应的工艺参数设定为最优激光工艺参数。Furthermore, for laser process parameters that can achieve epitaxial growth of dendrites, the present invention determines the range of epitaxial growth of dendrites and sets the process parameters corresponding to the maximum range as the optimal laser process parameters.
4)、运用筛选出的激光工艺参数,在镍基单晶高温合金基板表面激光熔覆熔覆层,在基板表面实现枝晶外延定向生长。4) Using the selected laser process parameters, a cladding layer is laser clad on the surface of a nickel-based single crystal high-temperature alloy substrate to achieve directional epitaxial growth of dendrites on the substrate surface.
具体地,是根据MATLAB预测结果,设定最优的激光工艺参数,确定打印方案;根据打印方案调节激光熔覆所采用的激光输出功率、激光扫描速度、送粉速率、入射激光光斑直径,采用同轴送粉的方式,并利用氩气保护基板表面,进行激光熔覆。Specifically, the optimal laser process parameters are set and the printing plan is determined based on the MATLAB prediction results. The laser output power, laser scanning speed, powder feeding rate, and incident laser spot diameter used in laser cladding are adjusted according to the printing plan. The coaxial powder feeding method is adopted, and argon gas is used to protect the substrate surface for laser cladding.
更具体地,在激光熔覆的加工过程中,激光每扫描一次,都会对基板加热一次,所以在熔覆过程中应适当调整激光输出功率,以保证在激光熔覆过程中保持稳定的温度梯度,确保枝晶外延生长的条件。More specifically, during the laser cladding process, the substrate is heated every time the laser scans, so the laser output power should be adjusted appropriately during the cladding process to ensure a stable temperature gradient during the laser cladding process and ensure the conditions for epitaxial growth of dendrites.
本发明提供的镍基单晶高温合金激光外延生长方法可以在激光熔覆之前,通过理论模型准确预测得到枝晶外延生长的方向和范围,从而通过控制和优化激光工艺参数,实现对晶粒外延定向生长的影响,达到精确控制枝晶外延生长,使得熔覆层的微观组织能够形成连续外延生长的镍基单晶组织,为镍基单晶高温合金叶片的修复提供理论指导。The nickel-based single crystal high-temperature alloy laser epitaxial growth method provided by the present invention can accurately predict the direction and range of dendrite epitaxial growth through a theoretical model before laser cladding, thereby controlling and optimizing the laser process parameters to influence the directional epitaxial growth of grains, thereby achieving precise control of dendrite epitaxial growth, so that the microstructure of the cladding layer can form a continuously epitaxially grown nickel-based single crystal structure, and provide theoretical guidance for the repair of nickel-based single crystal high-temperature alloy blades.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是本发明中激光熔覆示意图。FIG. 1 is a schematic diagram of laser cladding in the present invention.
图2是本发明中熔池的三位示意图,其中α、β、γ为镍基单晶高温合金中枝晶的最优生长方向[100]、[010]、[001]与熔池内任一点法向的夹角。FIG2 is a three-dimensional schematic diagram of the molten pool in the present invention, wherein α, β, and γ are the angles between the optimal growth directions [100], [010], and [001] of dendrites in a nickel-based single crystal high-temperature alloy and the normal direction of any point in the molten pool.
图3是实施例1的金相组织图像。FIG. 3 is a metallographic structure image of Example 1.
图4是实施例2的金相组织图像。FIG. 4 is a metallographic structure image of Example 2.
图5是比较例1的金相组织图像。FIG. 5 is a metallographic structure image of Comparative Example 1.
实施方式Implementation
下面结合附图和实施例对本发明的具体实施方式作进一步的详细描述。以下实施例仅用于更加清楚地说明本发明的技术方案,从而使本领域技术人员能很好地理解和利用本发明,而不是限制本发明的保护范围。The specific implementation of the present invention is further described in detail below in conjunction with the accompanying drawings and examples. The following examples are only used to more clearly illustrate the technical solution of the present invention so that those skilled in the art can well understand and utilize the present invention, rather than limiting the scope of protection of the present invention.
本发明实施例和对比例中涉及到的生产工艺、实验方法或检测方法,若无特别说明,均为现有技术中的常规方法,且其名称和/或简称均属于本领域内的常规名称,在相关用途领域内均非常清楚明确,本领域内技术人员能够根据该名称理解常规工艺步骤并应用相应的设备,按照常规条件或制造商建议的条件进行实施。The production processes, experimental methods or detection methods involved in the embodiments and comparative examples of the present invention are all conventional methods in the prior art unless otherwise specified, and their names and/or abbreviations are all conventional names in the field and are very clear and unambiguous in the relevant application fields. Technicians in the field can understand the conventional process steps based on the names and apply the corresponding equipment to implement them according to conventional conditions or the conditions recommended by the manufacturer.
本发明实施例中使用的各种仪器、设备、原料或试剂,并没有来源上的特殊限制,均为可以通过正规商业途径购买获得的常规产品,也可以按照本领域技术人员熟知的常规方法进行制备。本发明中其他未尽事宜为公知技术。The various instruments, equipment, raw materials or reagents used in the embodiments of the present invention are not particularly limited in terms of their sources, and are all conventional products that can be purchased through regular commercial channels, or can be prepared according to conventional methods well known to those skilled in the art. Other matters not covered in the present invention are known technologies.
本发明以下实施例采用DD6镍基单晶高温合金作为待修复的基板材料,以GH738镍基高温合金作为熔覆层材料,按照图1所示的激光熔覆方式对基板进行修复。The following embodiments of the present invention use DD6 nickel-based single crystal high-temperature alloy as the substrate material to be repaired and GH738 nickel-based high-temperature alloy as the cladding layer material, and repair the substrate according to the laser cladding method shown in FIG. 1 .
在激光熔覆过程中,将镍基单晶高温合金中枝晶的最优生长方向[100]、[010]和[001]与熔池内任一点的法向矢量的夹角分别定义为α、β和γ,熔池模拟图如图2所示。During the laser cladding process, the optimal growth directions of dendrites [100], [010] and [001] in nickel-based single crystal superalloys are aligned with the normal vector of any point in the molten pool. The angles are defined as α, β and γ respectively, and the molten pool simulation diagram is shown in Figure 2.
由于DD6与GH738两种材料的成分相差不大,为了模拟结果更容易收敛,以下实施例中具体使用同一材料的热物性参数进行模拟。Since the compositions of DD6 and GH738 are similar, in order to make the simulation results more easily convergent, the thermophysical property parameters of the same material are used for simulation in the following embodiments.
实施例Example
实施例1Example 1
1)、在Design Modeler软件中建立激光熔覆模型,设定激光沿X轴进行扫过,Z轴正方向为镍基单晶高温合金的[001]方向。所建立激光熔覆模型的基体尺寸为20×10×5mm,熔覆层尺寸为20×1×0.5mm。1) Establish a laser cladding model in the Design Modeler software, set the laser to scan along the X-axis, and set the positive direction of the Z-axis to the [001] direction of the nickel-based single crystal high-temperature alloy. The substrate size of the established laser cladding model is 20×10×5mm, and the cladding layer size is 20×1×0.5mm.
2)、采用均匀的六面体网格划分结构单元,通过JmatPro软件求解得到DD6镍基单晶高温合金的下述热物性参数:特性熔化温度1615K,导热系数0.0332kj/(m·s·K),比热容0.773kj/(kg·K),密度8780kg/m3,融化潜热99kj/kg,并将其分别赋予基体材料和熔覆层材料。2) The structural unit is divided by uniform hexahedral grid, and the following thermophysical parameters of DD6 nickel-based single crystal high-temperature alloy are obtained by solving with JmatPro software: characteristic melting temperature 1615K, thermal conductivity 0.0332kj/(m·s·K), specific heat capacity 0.773kj/(kg·K), density 8780kg/m 3 , melting latent heat 99kj/kg, and they are assigned to the base material and the cladding layer material respectively.
3)、设置激光熔覆模型的表面初始温度为22℃,与空气进行对流换热,并将换热通过软件加载在模型表面,设置激光加载面具有热辐射,辐射系数0.8。3) Set the initial surface temperature of the laser cladding model to 22°C, conduct convective heat exchange with the air, and load the heat exchange on the model surface through software. Set the laser loading surface to have thermal radiation, and the radiation coefficient is 0.8.
4)、建立正交实验,分别采用激光功率200W、400W、800W,扫描速度5mm/s、10mm/s、20mm/s,送粉量10g/min,光斑直径4mm,激光反射率50%,利用ANSYS APDL加载高斯移动热源命令流,进行Ansys仿真求解,求得激光工艺参数对熔池的影响以及熔池内部温度梯度分布。4) Establish an orthogonal experiment, using laser powers of 200W, 400W, and 800W, scanning speeds of 5mm/s, 10mm/s, and 20mm/s, a powder feeding rate of 10g/min, a spot diameter of 4mm, and a laser reflectivity of 50%. Use ANSYS APDL to load the Gaussian moving heat source command flow and perform ANSYS simulation to obtain the influence of laser process parameters on the molten pool and the temperature gradient distribution inside the molten pool.
5)、通过MATLAB软件将仿真求得的不同温度梯度分布结果带入到枝晶矢量化计算模型中,对枝晶优先生长方向及速度进行预测。5) The different temperature gradient distribution results obtained by simulation are brought into the dendrite vectorization calculation model through MATLAB software to predict the preferred growth direction and speed of the dendrite.
最终可以得到在激光工艺参数为激光功率800W,扫描速度10mm/s时,熔池底部Z轴上的Gn/Vhkl比值为3.08×1028,大于临界值KCET,并且生长面积占熔池面积的70.5%,面积最大,熔覆层可以实现枝晶外延生长且生长区域最大。Finally, it can be obtained that when the laser process parameters are laser power 800W and scanning speed 10mm/s, the Gn / Vhkl ratio on the Z axis at the bottom of the molten pool is 3.08× 1028 , which is greater than the critical value KCET , and the growth area accounts for 70.5% of the molten pool area, the largest area, and the cladding layer can achieve dendrite epitaxial growth with the largest growth area.
6)、取基板材料为DD6的镍基单晶高温合金,使用无损探伤方法查找修复部位,确定好基体取向并对修复部位进行切割,并在激光熔覆修复前进行预处理,将待修复部位打磨、抛光后,使用丙酮、酒精清洗待修复合金表面。6) Take the nickel-based single crystal high-temperature alloy with the substrate material of DD6, use the non-destructive testing method to find the repair part, determine the substrate orientation and cut the repair part, and perform pretreatment before laser cladding repair. After grinding and polishing the part to be repaired, use acetone and alcohol to clean the surface of the alloy to be repaired.
7)、按照上述预测结果得到的枝晶预测范围确定打印方案,调整激光工艺参数,保证激光加工工程中保持稳定的温度梯度,使激光热流方向保持垂直,使用GH738粉末对DD6镍基单晶进行修复。7) Determine the printing plan according to the dendrite prediction range obtained from the above prediction results, adjust the laser process parameters, ensure a stable temperature gradient during the laser processing, keep the laser heat flow direction vertical, and use GH738 powder to repair the DD6 nickel-based single crystal.
第一层激光熔覆扫描设定的工艺参数如下:激光功率800W,扫描速度10mm/s,送粉量10g/min,光斑直径4mm,保护气氩气出气量15ml/min,采用同轴送粉的方式进行激光熔覆。The process parameters set for the first layer of laser cladding scanning are as follows: laser power 800W, scanning speed 10mm/s, powder feeding amount 10g/min, spot diameter 4mm, protective gas argon gas output 15ml/min, and coaxial powder feeding method is used for laser cladding.
因为激光每扫过一次,都会对基板加热一次,所以在后续扫描过程中适当减少激光功率,减小热输入,保证枝晶的外延生长。Because the substrate is heated every time the laser scans, the laser power should be appropriately reduced in the subsequent scanning process to reduce the heat input and ensure the epitaxial growth of the dendrite.
8)、在激光熔覆修复结束后,对基板材料进行去除残余热应力处理,并进行缺陷和损伤检测。8) After the laser cladding repair is completed, the substrate material is treated to remove residual thermal stress and defect and damage detection is performed.
修复完成后的叶片金相组织如图3所示,其中左图为待修复基板的金相图片,右图为修复层的金相图片。可以看出,修复后已经实现了枝晶的外延生长,形成比基板更为细小的枝晶组织。The metallographic structure of the blade after repair is shown in Figure 3, where the left picture is the metallographic picture of the substrate to be repaired, and the right picture is the metallographic picture of the repair layer. It can be seen that epitaxial growth of dendrites has been achieved after repair, forming a dendrite structure that is finer than the substrate.
实施例2Example 2
在实际的激光熔覆修复过程中,为了降低激光熔覆过程所产生的残余应力,避免开裂,一般是在激光熔覆过程中采用原位预热工艺。因此与实施例1不同,本实施例设置激光熔覆过程中镍基单晶高温叶片DD6基板的低温区预热温度约为950℃。In the actual laser cladding repair process, in order to reduce the residual stress generated by the laser cladding process and avoid cracking, an in-situ preheating process is generally used during the laser cladding process. Therefore, unlike Example 1, this embodiment sets the low temperature zone preheating temperature of the nickel-based single crystal high temperature blade DD6 substrate during the laser cladding process to be about 950°C.
1)、设置激光熔覆模型的表面初始温度为950℃,与空气进行对流换热,并将换热通过软件加载在模型表面,设置激光加载面具有热辐射,辐射系数0.8。1) Set the initial surface temperature of the laser cladding model to 950°C, conduct convection heat exchange with the air, and load the heat exchange on the model surface through software. Set the laser loading surface to have thermal radiation, and the radiation coefficient is 0.8.
2)、建立正交实验,分别采用激光功率500W,1000W,1500W,扫描速度5mm/s,10mm/s,20mm/s,送粉量10g/min,光斑直径4mm,激光反射率50%,利用ANSYS APDL加载高斯移动热源命令流,进行Ansys仿真求解,求得激光工艺参数对熔池的影响以及熔池内部温度梯度分布。2) Establish an orthogonal experiment, using laser powers of 500W, 1000W, and 1500W, scanning speeds of 5mm/s, 10mm/s, and 20mm/s, powder feeding rate of 10g/min, spot diameter of 4mm, and laser reflectivity of 50%. Use ANSYS APDL to load the Gaussian moving heat source command flow and perform Ansys simulation to obtain the influence of laser process parameters on the molten pool and the temperature gradient distribution inside the molten pool.
3)、同样的,通过MATLAB软件将仿真求得的不同温度梯度结果带入到枝晶矢量化计算模型中,对枝晶优先生长方向及速度进行预测。3) Similarly, the different temperature gradient results obtained by simulation are brought into the dendrite vectorization calculation model through MATLAB software to predict the preferred growth direction and speed of the dendrite.
最终得到在激光工艺参数为激光功率1500W,扫描速度10mm/s时,熔池底部Z轴上的Gn/Vhkl比值为2.91×1028,大于临界值KCET,并且生长面积占熔池面积的58.2%,面积最大,熔覆层可以实现枝晶外延生长且生长区域最大。Finally, when the laser process parameters are laser power 1500W and scanning speed 10mm/s, the Gn / Vhkl ratio on the Z axis at the bottom of the molten pool is 2.91× 1028 , which is greater than the critical value KCET , and the growth area accounts for 58.2% of the molten pool area, the largest area. The cladding layer can achieve dendrite epitaxial growth and the growth area is the largest.
4)、将基板预热至950℃,根据枝晶预测范围确定打印方案,调整激光工艺参数,保证激光加工工程中保持稳定的温度梯度,使激光热流方向保持垂直,使用GH738粉末对DD6镍基单晶进行修复。4) Preheat the substrate to 950°C, determine the printing plan according to the predicted range of dendrites, adjust the laser process parameters, ensure a stable temperature gradient during the laser processing, keep the laser heat flow direction vertical, and use GH738 powder to repair the DD6 nickel-based single crystal.
第一层设定工艺参数如下:激光功率1500W,光斑直径4mm,扫描速度10mm/s,送粉速率10g/min,保护气氩气出气量15ml/min,采用同轴送粉的方式进行熔覆。每扫过一次,适当减少激光功率,减小热输入,保证枝晶的外延生长。The process parameters for the first layer are as follows: laser power 1500W, spot diameter 4mm, scanning speed 10mm/s, powder feeding rate 10g/min, protective gas argon gas output 15ml/min, and coaxial powder feeding for cladding. After each scan, the laser power is appropriately reduced to reduce heat input and ensure epitaxial growth of dendrites.
5)、为了服役的稳定性,对修复后的单晶合金进行标准固溶处理(1300℃、4h)。5) In order to ensure service stability, the repaired single crystal alloy is subjected to standard solution treatment (1300°C, 4h).
修复完成后的叶片修复层金相组织如图4中(a)所示,图4中(b)为经过固溶处理后的金相图片。可以看出,本实施例已经实现了枝晶的外延生长,并且在经过标准固溶处理后也没有发生再结晶现象。因此,较高的预热温度是降低激光成形高温合金样品中残余应力的有效手段。The metallographic structure of the blade repair layer after repair is shown in Figure 4 (a), and Figure 4 (b) is the metallographic picture after solution treatment. It can be seen that the epitaxial growth of dendrites has been achieved in this embodiment, and no recrystallization has occurred after standard solution treatment. Therefore, a higher preheating temperature is an effective means to reduce residual stress in laser formed high-temperature alloy samples.
比较例1Comparative Example 1
将镍基单晶高温合金DD6基板的低温区预热温度设置为700℃,其他激光工艺参数同实施例2,设置激光功率1500W,光斑直径4mm,扫描速度10mm/s,送粉速率10g/min,保护气氩气出气量15ml/min,采用同轴送粉的方式进行激光熔覆。The low temperature zone preheating temperature of the nickel-based single crystal high temperature alloy DD6 substrate is set to 700°C, and the other laser process parameters are the same as in Example 2, with the laser power of 1500W, the spot diameter of 4mm, the scanning speed of 10mm/s, the powder feeding rate of 10g/min, the protective gas argon gas output of 15ml/min, and the coaxial powder feeding method is used for laser cladding.
对修复后的单晶合金进行标准固溶处理(1300℃、4h)。The repaired single crystal alloy was subjected to standard solution treatment (1300°C, 4h).
修复完成后的叶片修复层金相组织如图5中(a)所示,图5中(b)为经过固溶处理后的金相图片。可以看出,本比较例虽然也实现了枝晶的外延生长,但是在标准固溶处理后发生了严重的再结晶,破坏了单晶取向一致性。因此,为了减少激光加工过程中残余应力的产生,需要对镍基单晶合金基板进行预热,预热温度超过700℃。The metallographic structure of the blade repair layer after repair is shown in Figure 5 (a), and Figure 5 (b) is the metallographic picture after solution treatment. It can be seen that although the epitaxial growth of dendrites is also achieved in this comparative example, severe recrystallization occurs after the standard solution treatment, destroying the consistency of single crystal orientation. Therefore, in order to reduce the generation of residual stress during laser processing, the nickel-based single crystal alloy substrate needs to be preheated, and the preheating temperature exceeds 700°C.
本发明以上实施例并没有详尽叙述所有的细节,也不限制本发明仅为以上所述实施例。本领域普通技术人员在不脱离本发明原理和宗旨的情况下,针对这些实施例进行的各种变化、修改、替换和变型,均应包含在本发明的保护范围之内。The above embodiments of the present invention do not describe all the details in detail, nor limit the present invention to the above embodiments. Various changes, modifications, substitutions and variations made by ordinary technicians in this field without departing from the principles and purpose of the present invention should be included in the protection scope of the present invention.
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