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CN116143073A - A device for sliding arc plasma assisted diesel reforming - Google Patents

A device for sliding arc plasma assisted diesel reforming Download PDF

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CN116143073A
CN116143073A CN202211711112.9A CN202211711112A CN116143073A CN 116143073 A CN116143073 A CN 116143073A CN 202211711112 A CN202211711112 A CN 202211711112A CN 116143073 A CN116143073 A CN 116143073A
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reforming
arc plasma
reaction
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plasma torch
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CN116143073B (en
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郭萌
邓清东
李锐
刘岩
杨广元
朱刚
胡明超
芮珍珍
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Anhui East China Institute of Optoelectronic Technology
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
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Abstract

本发明涉及能源技术领域,具体来说是一种滑动弧等离子体辅助柴油重整的重整装置,包括电弧等离子体炬和与所述电弧等离子体炬相连接的重整反应机构,所述电弧等离子体炬用于产生处理柴油的非热电弧等离子体,所述重整反应腔用于柴油的进料和重整;本发明公开了一种滑动弧等离子体辅助柴油重整的重整装置;本发明公开的重整装置,可以实现柴油在非平衡等离子体高温、高化学活性的环境中发生裂解,并进行部分氧化重整与水蒸气重整反应,同时释放热量,在重整反应腔中形成高温区域;裂解产物和重整产物经过内导管在二次反应腔内进一步停留,进行二次裂解和重整,从而实现柴油的高转化率重整制氢。

Figure 202211711112

The invention relates to the field of energy technology, in particular to a reforming device for sliding arc plasma-assisted reforming of diesel oil, comprising an arc plasma torch and a reforming reaction mechanism connected with the arc plasma torch, the arc The plasma torch is used to generate non-thermal arc plasma for processing diesel oil, and the reforming reaction chamber is used for feeding and reforming diesel oil; the invention discloses a reforming device for sliding arc plasma-assisted reforming of diesel oil; The reforming device disclosed in the present invention can realize the pyrolysis of diesel oil in the environment of non-equilibrium plasma high temperature and high chemical activity, and carry out partial oxidation reforming and steam reforming reactions, and release heat at the same time, in the reforming reaction chamber A high-temperature area is formed; the cracked product and reformed product pass through the inner conduit and stay in the secondary reaction chamber for secondary cracking and reforming, so as to realize hydrogen production by reforming with high conversion rate of diesel.

Figure 202211711112

Description

一种滑动弧等离子体辅助柴油重整的装置A device for sliding arc plasma assisted diesel reforming

技术领域technical field

本发明涉及能源技术领域,具体来说是一种滑动弧等离子体辅助柴油重整的装置。The invention relates to the field of energy technology, in particular to a sliding arc plasma-assisted diesel reforming device.

背景技术Background technique

氢能是一种清洁能源,有望成为未来社会的支柱能源,近年,氢能已开始应用于汽车工业、能源发电、航空航天等多个行业,如掺氢发动机、燃料电池等。Hydrogen energy is a kind of clean energy and is expected to become the pillar energy of the future society. In recent years, hydrogen energy has begun to be used in many industries such as the automobile industry, energy power generation, and aerospace, such as hydrogen-doped engines and fuel cells.

氢能的应用很大程度上依靠于氢制取、携带与储运技术的发展状况,安全、成本等问题正制约着氢能的进一步扩展应用。The application of hydrogen energy depends largely on the development of hydrogen production, carrying, storage and transportation technologies. Issues such as safety and cost are restricting the further expansion and application of hydrogen energy.

因此,世界各国均已开始烃类燃料重整制氢技术研究,为中小规模、分散式场景下氢能的安全应用提供支持。Therefore, countries all over the world have begun research on hydrogen production technology by reforming hydrocarbon fuels to provide support for the safe application of hydrogen energy in small and medium-scale and decentralized scenarios.

传统的柴油重整技术主要通过催化重整的方式,此技术已相对成熟但仍存在固有缺陷,如催化剂制备成本高、易失活等问题。而等离子体是物质第四态,具有高温度高化学活性的特点,拥有一定的催化能力,是现今燃料重整技术研究中的热点。The traditional diesel reforming technology is mainly through catalytic reforming. This technology is relatively mature but still has inherent defects, such as high cost of catalyst preparation and easy deactivation. Plasma is the fourth state of matter. It has the characteristics of high temperature and high chemical activity, and has a certain catalytic ability. It is a hot spot in the research of fuel reforming technology today.

现有等离子体重整装置多针对醇类燃料,应用于柴油等重烃类燃料时转化率相对较低,在柴油流量较大时,难以保证重整过程可靠运行,装置难以实现小型化。Existing plasma reforming devices are mostly aimed at alcohol fuels. When applied to heavy hydrocarbon fuels such as diesel, the conversion rate is relatively low. When the diesel flow rate is large, it is difficult to ensure reliable operation of the reforming process and the miniaturization of the device is difficult.

因此,急需要提供一种非热电弧等离子体重整柴油装置及提高燃料转化率的率方法。Therefore, there is an urgent need to provide a non-thermal arc plasma reforming diesel device and a method for improving the fuel conversion rate.

发明内容Contents of the invention

本发明的目的提供一种非热滑动弧等离子体重整柴油装置。The object of the present invention is to provide a non-thermal sliding arc plasma reforming diesel device.

为了实现上述目的,本发明采用的技术方案为:In order to achieve the above object, the technical scheme adopted in the present invention is:

一种滑动弧等离子体辅助柴油重整的装置,包括电弧等离子体炬和与所述电弧等离子体炬相连接的重整反应机构,所述重整反应机构包括重整反应腔;所述电弧等离子体炬上端伸入重整反应腔;所述电弧等离子体炬用于产生处理柴油的非热电弧等离子体,所述重整反应腔用于柴油的进料和重整。A device for sliding arc plasma assisted reforming of diesel oil, comprising an arc plasma torch and a reforming reaction mechanism connected to the arc plasma torch, the reforming reaction mechanism including a reforming reaction chamber; the arc plasma The upper end of the body torch extends into the reforming reaction chamber; the arc plasma torch is used to generate non-thermal arc plasma for treating diesel, and the reforming reaction chamber is used for feeding and reforming diesel.

所述电弧等离子体炬包括壳体组件,所述壳体组件内布置有电极组件;The arc plasma torch includes a housing assembly within which an electrode assembly is disposed;

所述壳体组件包括连接壳体;所述连接壳体上设有放电气管口;The housing assembly includes a connection housing; the connection housing is provided with a discharge pipe port;

所述电极组件包括高压电极,所述高压电极连接有电极支杆。The electrode assembly includes a high-voltage electrode, and the high-voltage electrode is connected with an electrode support rod.

所述连接壳体远离重整反应机构一端设有连接套筒;所述电极支杆布置在连接套筒内侧。A connecting sleeve is provided at the end of the connecting housing away from the reforming reaction mechanism; the electrode pole is arranged inside the connecting sleeve.

所述连接套筒内设有绝缘件;所述绝缘件上设有穿接孔,所述电极支杆通过穿接孔穿过绝缘件布置。The connecting sleeve is provided with an insulator; the insulator is provided with a piercing hole, and the electrode support rod is arranged through the insulator through the piercing hole.

所述绝缘件的穿接孔内设有固定套筒,所述电极支杆端部连接有接线柱。A fixing sleeve is provided in the penetration hole of the insulator, and a terminal is connected to the end of the electrode pole.

所述绝缘件外侧设有限位沉槽,所述连接套筒嵌入在绝缘件的限位沉槽内。A limit sinking groove is provided on the outer side of the insulating member, and the connecting sleeve is embedded in the limit sinking groove of the insulating member.

所述壳体靠近重整反应机构一端设有阳极盖;所述阳极盖上设有顶部通孔。An anode cover is provided at the end of the casing close to the reforming reaction mechanism; a top through hole is provided on the anode cover.

所述连接套筒上设有固定螺母,所述固定螺母处于连接套筒与壳体的连接处。The connecting sleeve is provided with a fixing nut, and the fixing nut is located at the joint of the connecting sleeve and the housing.

所述重整反应机构包括一次反应机构和二次反应机构;The reforming reaction mechanism includes a primary reaction mechanism and a secondary reaction mechanism;

电弧等离子体炬通过一次反应机构与二次反应机构相连接;The arc plasma torch is connected with the secondary reaction mechanism through the primary reaction mechanism;

所述一次反应机构包括一次反应壳体,所述一次反应壳体内部中空形成一次反应腔;The primary reaction mechanism includes a primary reaction housing, and the interior of the primary reaction housing is hollow to form a primary reaction chamber;

所述二次反应机构包括二次反应壳体,所述二次反应壳体内部中空形成二次反应腔;The secondary reaction mechanism includes a secondary reaction shell, and the secondary reaction shell is hollow inside to form a secondary reaction chamber;

所述一次反应腔与第二次反应腔通过内导管相连通;The primary reaction chamber communicates with the second reaction chamber through an inner conduit;

所述二次反应壳体上设有出气管,所述出气管内设有合成气出气口;所述合成气出气口与二次反应腔相连通;An outlet pipe is provided on the secondary reaction shell, and a synthesis gas outlet is arranged in the outlet pipe; the synthesis gas outlet communicates with the secondary reaction chamber;

所述一次反应壳体上设有进料口;所述进料口与一次反应腔相连通。The primary reaction shell is provided with a feed port; the feed port communicates with the primary reaction chamber.

所述一次反应壳体与二次反应壳体通过上法兰组件相连接;所述一次反应壳体通过下法兰组件与电弧等离子体炬。The primary reaction shell is connected with the secondary reaction shell through the upper flange assembly; the primary reaction shell is connected with the arc plasma torch through the lower flange assembly.

本发明的优点在于:The advantages of the present invention are:

本发明公开了一种滑动弧等离子体辅助柴油重整的重整装置;本发明公开的重整装置,可以实现柴油在非平衡等离子体高温、高化学活性的环境中发生裂解,并进行部分氧化重整与水蒸气重整反应,同时释放热量,在重整反应腔中形成高温区域;裂解产物和重整产物经过内导管在二次反应腔内进一步停留,进行二次裂解和重整,从而实现柴油的高转化率重整制氢。The invention discloses a reforming device for sliding arc plasma-assisted reforming of diesel oil; the reforming device disclosed in the invention can realize the cracking and partial oxidation of diesel oil in an environment of non-equilibrium plasma high temperature and high chemical activity Reforming and steam reforming react and release heat at the same time, forming a high-temperature area in the reforming reaction chamber; the cracked product and reformed product stay in the secondary reaction chamber through the inner conduit for secondary cracking and reforming, thereby Realize high conversion rate reforming of diesel to produce hydrogen.

附图说明Description of drawings

下面对本发明说明书各幅附图表达的内容及图中的标记作简要说明:The content expressed in each accompanying drawing of the description of the present invention and the marks in the figure are briefly described below:

图1为本发明的结构示意图。Fig. 1 is a structural schematic diagram of the present invention.

附图标记说明:Explanation of reference signs:

1、二次反应腔,2、合成气出气口,3、上连接法兰;4、进料口;5、内导管,6、一次反应腔,8、连接壳体,9、放电气管口,10、阳极盖,11、高压电极,12、电极支杆,13、固定螺母,14、连接套筒,15、绝缘件,16、固定套筒,17、接线柱。1. Secondary reaction chamber, 2. Syngas outlet, 3. Upper connecting flange; 4. Feed inlet; 5. Inner conduit, 6. Primary reaction chamber, 8. Connecting shell, 9. Discharge gas pipe port, 10. Anode cover, 11. High voltage electrode, 12. Electrode support rod, 13. Fixing nut, 14. Connecting sleeve, 15. Insulator, 16. Fixing sleeve, 17. Terminal post.

具体实施方式Detailed ways

下面对照附图,通过对最优实施例的描述,对本发明的具体实施方式作进一步详细的说明。The specific implementation manner of the present invention will be described in further detail below by describing the best embodiment with reference to the accompanying drawings.

一种滑动弧等离子体辅助柴油重整的装置,包括电弧等离子体炬1-2和与所述电弧等离子体炬1-2相连接的重整反应机构1-1,所述重整反应机构1-1包括重整反应腔;所述电弧等离子体炬1-2伸入重整反应腔;所述电弧等离子体炬1-2用于产生处理柴油的非热电弧等离子体,所述重整反应腔用于柴油的进料和重整;本发明公开了一种滑动弧等离子体辅助柴油重整的装置;本发明公开的重整装置,可以实现柴油在非平衡等离子体高温、高化学活性的环境中发生裂解,并进行部分氧化重整与水蒸气重整反应。A device for sliding arc plasma assisted reforming of diesel oil, comprising an arc plasma torch 1-2 and a reforming reaction mechanism 1-1 connected to the arc plasma torch 1-2, the reforming reaction mechanism 1 -1 includes a reforming reaction chamber; the arc plasma torch 1-2 extends into the reforming reaction chamber; the arc plasma torch 1-2 is used to generate non-thermal arc plasma for processing diesel, and the reforming reaction The cavity is used for feeding and reforming of diesel; the invention discloses a device for sliding arc plasma-assisted reforming of diesel; the reforming device disclosed in the invention can realize the high temperature and high chemical activity of diesel in non-equilibrium plasma Cracking occurs in the environment, and partial oxidation reforming and steam reforming reactions are carried out.

本发明公开的重整装置主要是提供场所实现柴油进行重整反应。The reforming device disclosed in the present invention mainly provides a place to realize the reforming reaction of diesel oil.

本发明公开的重整装置主要包括电弧等离子体炬1-2和重整反应机构1-1,所述电弧等离子体炬1-2用于产生处理柴油的非热电弧等离子体,所述重整反应腔用于柴油的进料和重整;具体,本发明公开的所述电弧等离子体炬1-2包括壳体组件,所述壳体组件内布置有电极组件;壳体组件起到很好的防护作用,避免电极组件的外露,而电极组件的设置,主要是为了形成非热电弧等离子体;方便后续柴油重整反应;另外,在本发明中所述壳体组件包括连接壳体8;所述连接壳体8上设有放电气管口9;连接壳体8为一个圆筒结构,方便后续电极组件以及后续其他部件的安放布置,同时在连接壳体8内部设有所述电极组件包括高压电极11,所述高压电极11连接有电极支杆12;高压电极11连接有电极支杆12,高压电极11通电后,与阳极盖上端面之间最小缝隙处产生电弧,然后电弧被放电气吹动,加长并快速旋转,形成等离子体区域;后续使用时,通过非热电弧等离子体对柴油提供重整能量;另外,在本发明中所述重整反应机构1-1包括一次反应机构和二次反应机构;通过设置两个反应机构可以实现一次裂解产物和重整产物在二次反应腔1内可以进一步停留,进行二次裂解和重整,从而实现柴油的高转化率重整制氢。The reforming device disclosed in the present invention mainly includes an arc plasma torch 1-2 and a reforming reaction mechanism 1-1. The arc plasma torch 1-2 is used to generate non-thermal arc plasma for processing diesel oil. The reforming The reaction chamber is used for feeding and reforming diesel oil; specifically, the arc plasma torch 1-2 disclosed in the present invention includes a shell assembly, and an electrode assembly is arranged inside the shell assembly; the shell assembly plays a very good role. Protective effect, avoiding the exposure of the electrode assembly, and the setting of the electrode assembly is mainly to form a non-thermal arc plasma; facilitate the subsequent diesel reforming reaction; in addition, the housing assembly in the present invention includes a connecting housing 8; The connection housing 8 is provided with a discharge gas pipe port 9; the connection housing 8 is a cylindrical structure, which is convenient for the placement and arrangement of the subsequent electrode assembly and other subsequent components, and the electrode assembly is provided inside the connection housing 8. High-voltage electrode 11, the high-voltage electrode 11 is connected with an electrode support rod 12; the high-voltage electrode 11 is connected with an electrode support rod 12, after the high-voltage electrode 11 is energized, an arc is generated at the smallest gap between the high-voltage electrode 11 and the upper end surface of the anode cover, and then the arc is discharged. Blow, elongate and rotate rapidly to form a plasma region; during subsequent use, reforming energy is provided to diesel through non-thermal arc plasma; in addition, the reforming reaction mechanism 1-1 in the present invention includes a primary reaction mechanism and Secondary reaction mechanism: by setting up two reaction mechanisms, the primary cracking product and the reformed product can further stay in the secondary reaction chamber 1 for secondary cracking and reforming, so as to realize hydrogen production by reforming with high conversion rate of diesel oil .

具体,在本发明中电弧等离子体炬1-2通过一次反应机构与二次反应机构相连接;这样的设置,方便电弧等离子体炬1-2中的高压电极11伸入一次反应腔6;方便柴油在非平衡等离子体高温、高化学活性的环境中发生裂解,并进行部分氧化重整与水蒸气重整反应;另外,在本发明中所述一次反应机构包括一次反应壳体,所述一次反应壳体内部中空形成一次反应腔6;所述二次反应机构包括二次反应壳体,所述二次反应壳体内部中空形成二次反应腔1;这样的设置,可以更好的实现上述两次裂解和重整反应。Specifically, in the present invention, the arc plasma torch 1-2 is connected with the secondary reaction mechanism through the primary reaction mechanism; such arrangement facilitates the high-voltage electrode 11 in the arc plasma torch 1-2 to stretch into the primary reaction chamber 6; it is convenient Diesel is cracked in an environment of non-equilibrium plasma high temperature and high chemical activity, and undergoes partial oxidation reforming and steam reforming reactions; in addition, the primary reaction mechanism in the present invention includes a primary reaction shell, and the primary The interior of the reaction housing is hollow to form a primary reaction chamber 6; the secondary reaction mechanism includes a secondary reaction housing, and the interior of the secondary reaction housing is hollow to form a secondary reaction chamber 1; such an arrangement can better realize the above-mentioned Two cleavage and reformation reactions.

同时,在本发明中所述一次反应腔6与第二次反应腔1通过内导管5相连通;内导管5起到很好的连通作用,方便一次反应腔6内的柴油产生的裂解产物和重整产物经过内导管5进入二次反应腔1。Simultaneously, in the present invention, described primary reaction cavity 6 is communicated with secondary reaction cavity 1 by inner conduit 5; The reformed product enters the secondary reaction chamber 1 through the inner conduit 5 .

同时,在本发明中所述二次反应壳体上设有出气管,所述出气管内设有合成气出气口2;所述合成气出气口2与二次反应腔1相连通;出气管的设置,方便了合成气的外排。Simultaneously, in the present invention, the secondary reaction shell is provided with an air outlet pipe, and a synthesis gas outlet 2 is arranged in the air outlet pipe; the synthesis gas outlet 2 communicates with the secondary reaction chamber 1; the air outlet pipe The setting facilitates the discharge of synthesis gas.

同时,在本发明中所述一次反应壳体上设有进料口4;所述进料口4与一次反应腔6相连通;进料口4的设置,方便了物料的后续投放。At the same time, a feed port 4 is provided on the primary reaction shell in the present invention; the feed port 4 communicates with the primary reaction chamber 6; the setting of the feed port 4 facilitates the subsequent feeding of materials.

进一步的,在本发明中所述连接壳体8远离重整反应机构1-1一端设有连接套筒14;所述电极支杆12布置在连接套筒14内侧;连接套筒14的设置,方便了后续绝缘件15的布置,同时连接套筒14外部设有外螺纹,连接套筒14布置在连接壳体8下方,连接壳体8下方设有通孔,连接套筒14充当一个堵塞件,一个作用是有利于保证连接壳体8下端的密封性;同时连接套筒14还相当于充当一个连接件,方便了绝缘件15以及其他部件的布置。Further, in the present invention, the connecting sleeve 8 is provided with a connecting sleeve 14 at the end away from the reforming reaction mechanism 1-1; the electrode rod 12 is arranged inside the connecting sleeve 14; the setting of the connecting sleeve 14, It facilitates the arrangement of the follow-up insulator 15. At the same time, the outside of the connecting sleeve 14 is provided with external threads. The connecting sleeve 14 is arranged under the connecting shell 8, and a through hole is provided under the connecting shell 8. The connecting sleeve 14 acts as a blocking member , one role is to help ensure the tightness of the lower end of the connecting shell 8; at the same time, the connecting sleeve 14 is equivalent to serving as a connecting piece, which facilitates the arrangement of the insulating piece 15 and other components.

进一步的,在本发明中所述连接套筒14内设有绝缘件15;所述绝缘件15上设有穿接孔,所述电极支杆12通过穿接孔穿过绝缘件15布置;本发明通过绝缘件15的设置,起到很好的隔离防护作用,在具体实施时,在电极支杆12外侧裹覆有绝缘件15;在本发明中绝缘件15由氧化铝陶瓷材料制成。Further, in the present invention, the connecting sleeve 14 is provided with an insulator 15; the insulator 15 is provided with a piercing hole, and the electrode strut 12 is arranged through the insulator 15 through the piercing hole; The invention plays a very good isolation and protection role through the setting of the insulator 15. In practice, the outer side of the electrode support rod 12 is covered with the insulator 15; in the present invention, the insulator 15 is made of alumina ceramic material.

进一步的,在本发明中所述绝缘件15的穿接孔内设有固定套筒16,所述电极支杆12端部连接有接线柱17;固定套筒16的设置,起到很好的端部固定作用,方便对电极支杆的端部限位固定。Further, in the present invention, a fixing sleeve 16 is provided in the piercing hole of the insulator 15, and the end of the electrode pole 12 is connected with a terminal 17; the setting of the fixing sleeve 16 plays a very good role. The end fixing function is convenient to limit and fix the end of the electrode support rod.

进一步的,在本发明中所述绝缘件15外侧设有限位沉槽,所述连接套筒14嵌入在绝缘件15的限位沉槽内;这样的设置,方便了绝缘件15与连接套筒14之间的连接,同时在本发明中连接套筒14外侧设有外螺纹,方便了后续连接套筒14以及绝缘件15与壳体之间的连接。Further, in the present invention, the outer side of the insulator 15 is provided with a limit sink, and the connecting sleeve 14 is embedded in the limit sink of the insulator 15; such an arrangement facilitates the connection between the insulator 15 and the connection sleeve. 14, and in the present invention, external threads are provided on the outside of the connecting sleeve 14, which facilitates the connection between the subsequent connecting sleeve 14 and the insulating member 15 and the housing.

进一步的,在本发明中所述壳体靠近重整反应机构1-1一端设有阳极盖10;所述阳极盖10上设有顶部通孔;本发明通过阳极盖10的设置,起到很好的端部限位作用,同时顶部通孔的设置,方便了高压电极11穿过阳极盖10与重整反应腔相连通。Further, in the present invention, the casing is provided with an anode cover 10 near the end of the reforming reaction mechanism 1-1; the anode cover 10 is provided with a top through hole; the present invention uses the setting of the anode cover 10 to play a very important role. The good position-limiting function of the end and the setting of the through hole at the top facilitate the communication between the high-voltage electrode 11 and the reforming reaction chamber through the anode cover 10 .

进一步的,在本发明中所述连接套筒14上设有固定螺母13,所述固定螺母13处于连接套筒14与壳体的连接处;本发明通过固定螺母13的设置,起到很好的锁止固定作用,保证了连接套筒14与壳体之间的连接。Further, in the present invention, the connecting sleeve 14 is provided with a fixing nut 13, and the fixing nut 13 is at the joint between the connecting sleeve 14 and the housing; The locking and fixing effect ensures the connection between the connecting sleeve 14 and the housing.

进一步的,在本发明中所述一次反应壳体与二次反应壳体通过上法兰组件相连接;所述一次反应壳体通过下法兰组件7与电弧等离子体炬1-2;本发明通过上法兰组件以及下法兰组件7的设置,方便了一次反应壳体与二次反应壳体之间的连接,也方便了一次反应壳体与连接壳体8之间的连接。Further, in the present invention, the primary reaction shell is connected to the secondary reaction shell through the upper flange assembly; the primary reaction shell is connected to the arc plasma torch 1-2 through the lower flange assembly 7; the present invention The arrangement of the upper flange assembly and the lower flange assembly 7 facilitates the connection between the primary reaction shell and the secondary reaction shell, and also facilitates the connection between the primary reaction shell and the connection shell 8 .

具体:specific:

本发明公开了一种滑动弧等离子体辅助柴油重整的重整装置主要包括滑动弧等离子体炬和与等离子体炬相连接的重整反应腔,等离子体炬用于产生辅助柴油裂解重整的旋转滑动弧等离子体,重整反应腔用于燃料等反应物的进料和重整。The invention discloses a reforming device for sliding arc plasma assisted reforming of diesel oil, mainly comprising a sliding arc plasma torch and a reforming reaction chamber connected with the plasma torch, the plasma torch is used to generate auxiliary diesel cracking and reforming The rotating sliding arc plasma, reforming reaction chamber is used for feeding and reforming reactants such as fuel.

所述等离子体炬包括连接壳体8、放电气管口9、阳极盖10、高压电极11、电极支杆12、固定螺母13、连接套筒14、绝缘件15、固定套筒16、接线柱17;其中,The plasma torch includes a connecting shell 8, a discharge gas pipe port 9, an anode cover 10, a high-voltage electrode 11, an electrode pole 12, a fixing nut 13, a connecting sleeve 14, an insulator 15, a fixing sleeve 16, and a terminal post 17 ;in,

外壳整体为两个不同内径的空心圆筒焊接在一起,小内径圆筒内部有螺纹,用于电极支杆12部件的调节与固定;高压电极11与电极支杆12头部通过螺纹旋紧;电极支杆12外部使用陶瓷材料包裹,即绝缘件15;阳极盖10置于高压电极11上端,与高压电极11保持一定间隙,并与外壳接触;固定套筒16以及连接套筒14外壁有螺纹;电极支杆12尾部与接线柱17连接,接线柱17连接高压电源。The whole shell is welded together by two hollow cylinders with different inner diameters. There are threads inside the cylinders with small inner diameters, which are used to adjust and fix the parts of the electrode rod 12; the high-voltage electrode 11 and the head of the electrode rod 12 are screwed tightly; The electrode support rod 12 is wrapped with ceramic material, that is, the insulator 15; the anode cover 10 is placed on the upper end of the high-voltage electrode 11, keeps a certain gap with the high-voltage electrode 11, and is in contact with the shell; the outer wall of the fixing sleeve 16 and the connecting sleeve 14 has threads ; The tail of the electrode pole 12 is connected to the terminal 17, and the terminal 17 is connected to a high voltage power supply.

外壳上部圆筒侧壁开设有放电气管口9,管口的圆截面与外壳的圆柱面垂直相切。The side wall of the cylinder on the upper part of the housing is provided with a gas discharge nozzle 9, and the circular section of the nozzle is vertically tangent to the cylindrical surface of the housing.

阳极盖10中心有内径不小于10mm的开孔,并且与等离子体炬外壳顶端相接触,且伸入重整腔体内;上述开孔就是顶部通孔。The center of the anode cover 10 has an opening with an inner diameter of not less than 10mm, which is in contact with the top of the plasma torch shell and extends into the reforming cavity; the above opening is the top through hole.

高压电极11的顶部为圆台形状,齿形结构用于散热;使用时高压电极11与阳极盖10不接触,且距离最近处,二者间隙不小于1mm。The top of the high-voltage electrode 11 is in the shape of a truncated cone, and the tooth-shaped structure is used for heat dissipation; when in use, the high-voltage electrode 11 is not in contact with the anode cover 10, and the gap between the two is not less than 1mm at the nearest point.

绝缘件15为氧化铝陶瓷材料,整体为两端外径大于中间的的圆筒状结构,且与高压电极11、阳极盖10、外壳同轴。The insulator 15 is made of alumina ceramic material, and has a cylindrical structure with outer diameters at both ends larger than that in the middle as a whole, and is coaxial with the high voltage electrode 11, the anode cover 10, and the casing.

绝缘件15中间凹陷部分与连接套筒14钎焊固定,内部通孔与电极支杆12直径一致;具有,本发明绝缘件15上设有限位沉槽,连接套筒14嵌入在限位沉槽内。The middle recessed part of the insulator 15 is brazed and fixed with the connecting sleeve 14, and the diameter of the internal through hole is consistent with that of the electrode pole 12; yes, the insulator 15 of the present invention is provided with a limit sinking groove, and the connecting sleeve 14 is embedded in the limit sinking groove Inside.

金属固定套筒16为截面是T型的圆筒,嵌入绝缘件15下部,与支杆接触,并通过螺帽压紧固定;接线柱17即电极支杆12尾部,通过螺母、垫片等与高压电源的导线压紧。The metal fixing sleeve 16 is a cylinder with a T-shaped cross section, which is embedded in the lower part of the insulator 15, contacts with the pole, and is fixed by nut compression; the terminal post 17 is the tail of the electrode pole 12, and is connected with The wires of the high voltage power supply are crimped.

固定螺母13为圆环结构,内壁设有螺纹,在等离子体炬整体装配完毕后,将固定螺母13旋转至连接套筒14与外壳接触的边缘并旋紧,用于固定高压电极11的位置。The fixing nut 13 is a ring structure with threads on the inner wall. After the plasma torch is assembled as a whole, the fixing nut 13 is rotated to the edge where the connecting sleeve 14 contacts the shell and tightened to fix the position of the high voltage electrode 11.

所述重整反应腔包括重整二次反应腔1、合成气出气口2、连接法兰、进料口4、内导管5、重整一次反应腔6;其中,所述重整一次反应腔6、重整二次反应腔1与等离子体炬均使用刀口法兰密封连接;所述内导管5一部分位于重整一次反应腔6内,一部分位于重整二次反应腔1内,固定在腔体上连接法兰3上。The reforming reaction chamber includes a reforming secondary reaction chamber 1, a synthesis gas outlet 2, a connecting flange, a feed port 4, an inner conduit 5, and a reforming primary reaction chamber 6; wherein, the reforming primary reaction chamber 6. Both the reforming secondary reaction chamber 1 and the plasma torch are sealed and connected by a knife-edge flange; a part of the inner conduit 5 is located in the reforming primary reaction chamber 6, and a part is located in the reforming secondary reaction chamber 1, and is fixed in the cavity The body is connected to the flange 3.

所述合成气出气口2位于重整二次反应腔1靠近上连接法兰3处;所述进料口4位于重整一次反应腔6上部,靠近与二次反应腔1上连接法兰3处,为一对中心对称的管口,口径6-10mm。The synthesis gas outlet 2 is located at the upper connecting flange 3 of the reforming secondary reaction chamber 1; the feed inlet 4 is located at the upper part of the reforming primary reaction chamber 6, close to the connecting flange 3 of the secondary reaction chamber 1 There are a pair of centrally symmetrical nozzles with a diameter of 6-10mm.

内导管5在重整二次反应腔1内的管口位置高于合成气出气口2,同时,在重整一次反应腔6内的位置低于进料口4;进料口4的内表面与重整一次反应腔6的外表面垂直相切,且内导管5、重整一次反应腔6、重整二次反应腔1、高压电极11同轴。The nozzle position of the inner conduit 5 in the reforming secondary reaction chamber 1 is higher than the synthesis gas outlet 2, and at the same time, the position in the reforming primary reaction chamber 6 is lower than the feed port 4; the inner surface of the feed port 4 It is vertical and tangent to the outer surface of the primary reforming reaction chamber 6, and the inner conduit 5, the primary reforming reaction chamber 6, the secondary reforming reaction chamber 1, and the high-voltage electrode 11 are coaxial.

本发明提供一种辅助柴油重整的装置,该装置包括滑动弧等离子体炬和与等离子体炬相连接的重整反应腔,等离子体炬用于产生辅助柴油裂解重整的旋转滑动弧等离子体,重整反应腔用于燃料、空气、水等反应物的进料,是发生反应的主要场所。The invention provides a device for assisting diesel oil reforming, which includes a sliding arc plasma torch and a reforming reaction chamber connected with the plasma torch, the plasma torch is used to generate rotating sliding arc plasma for auxiliary diesel cracking and reforming , The reforming reaction chamber is used for feeding fuel, air, water and other reactants, and is the main place where the reaction occurs.

将旋转滑动弧等离子体炬与重整反应腔相连接,利用产生的旋转滑动弧非热等离子体,在腔体内部进行柴油的进料与重整。这样,柴油在非平衡等离子体高温、高化学活性的环境中发生裂解,并进行部分氧化重整与水蒸气重整反应,同时释放热量,在重整反应腔中形成高温区域;裂解产物和重整产物经过内导管5在二次反应腔1内进一步停留,进行二次裂解和重整,从而实现柴油的高转化率重整制氢。The rotating sliding arc plasma torch is connected with the reforming reaction chamber, and the diesel fuel is fed and reformed inside the chamber by using the generated rotating sliding arc non-thermal plasma. In this way, diesel oil cracks in the environment of non-equilibrium plasma high temperature and high chemical activity, and undergoes partial oxidation reforming and steam reforming reactions, and releases heat at the same time, forming a high temperature area in the reforming reaction chamber; The whole product is further stayed in the secondary reaction chamber 1 through the inner conduit 5, and undergoes secondary cracking and reforming, so as to realize hydrogen production by reforming with a high conversion rate of diesel oil.

连接壳体8整体是将两个不同内径的空心圆筒焊接在一起,下部小内径圆筒内部有螺纹,用于电极支杆12部件的调节与固定;高压电极11与电极支杆12头部通过螺纹旋紧;电极支杆12外部使用陶瓷材料包裹,即绝缘件15,与外壳绝缘;阳极盖10置于高压电极11上端,与高压电极11保持一定间隙,并与外壳接触;连接套筒14外壁有螺纹,用于与外壳的配合固定;电极支杆12尾部与接线柱17连接,接线柱17连接高压电源,用于产生旋转滑动电弧。The connecting shell 8 is welded together with two hollow cylinders with different inner diameters, and the lower cylinder with a small inner diameter has threads for adjusting and fixing the parts of the electrode rod 12; the high-voltage electrode 11 and the head of the electrode rod 12 Tighten by thread; the electrode support rod 12 is wrapped with ceramic material, that is, the insulator 15, which is insulated from the shell; the anode cover 10 is placed on the upper end of the high-voltage electrode 11, keeps a certain gap with the high-voltage electrode 11, and is in contact with the shell; the connecting sleeve The outer wall of 14 is threaded for cooperating and fixing with the shell; the tail of the electrode support rod 12 is connected with the terminal 17, and the terminal 17 is connected with a high-voltage power supply for generating a rotating sliding arc.

高压电极11的顶部为圆台形状,下面齿形结构用于散热。The top of the high voltage electrode 11 is in the shape of a truncated cone, and the bottom tooth structure is used for heat dissipation.

在设计与安装过程中,高压电极11与阳极盖10不能接触,且距离最近处,二者间隙不小于1mm,以保证放电正常且产生的电弧在重整腔内旋转,具有一定的高度。During the design and installation process, the high-voltage electrode 11 and the anode cover 10 cannot be in contact, and the gap between the two is not less than 1mm at the nearest point, so as to ensure normal discharge and the generated arc rotates in the reforming chamber with a certain height.

绝缘件15中间凹陷部分与套筒钎焊固定,内部通孔与电极支杆12直径一致,用于电极支杆12穿出。The hollow part in the middle of the insulator 15 is fixed by brazing with the sleeve, and the inner through hole is consistent with the diameter of the electrode support rod 12 for the electrode support rod 12 to pass through.

接线柱17即电极支杆12尾部,通过螺母、垫片等与高压电源的导线压紧。The terminal 17 is the end of the electrode pole 12, which is pressed tightly with the wire of the high-voltage power supply through nuts, gaskets, etc.

合成气出气口2位于重整二次反应腔1靠近连接法兰处;进料口4位于重整一次反应腔61上部,靠近与二次腔连接法兰处,为一对中心对称的管口,口径6-10mm;The synthesis gas outlet 2 is located in the reforming secondary reaction chamber 1 close to the connecting flange; the feed port 4 is located in the upper part of the reforming primary reaction chamber 61, close to the connecting flange with the secondary chamber, and is a pair of centrally symmetrical nozzles , diameter 6-10mm;

内导管5在重整二次反应腔1内的管口位置需高于出气口,保证反应物在腔内具有足够的停留时间,以充分发生反应;同时,内导管5在重整一次反应腔6内的位置要低于进料口4,保证反应物通过等离子体区域。The nozzle position of the inner conduit 5 in the reforming secondary reaction chamber 1 needs to be higher than the gas outlet to ensure that the reactants have sufficient residence time in the chamber to fully react; at the same time, the inner conduit 5 is in the reforming primary reaction chamber The position in 6 is lower than the feed port 4 to ensure that the reactants pass through the plasma region.

进料口4的内表面与重整一次反应腔6的外表面垂直相切,且内导管5、重整一次反应腔6、重整二次反应腔1、高压电极11同轴。The inner surface of the feed port 4 is vertically tangent to the outer surface of the primary reforming reaction chamber 6, and the inner conduit 5, the primary reforming reaction chamber 6, the secondary reforming reaction chamber 1, and the high-voltage electrode 11 are coaxial.

在设计和安装过程中,为了获得更好的使用效果,并提高安装使用时的稳定性与操作便捷性,优选地,可根据腔内压力与合成气气流量的大小,增加合成气出气口2,优选地,将多个出气口设置为中心对称结构;同时,考虑到装置整体的小型化与安全性,将滑动弧等离子体辅助柴油重整装置的最大外径设置为76mm,长度为780mm,腔体壁厚不小于2mm;其中,重整反应腔设置为290mm。In the process of design and installation, in order to obtain a better use effect, and improve the stability and convenience of operation during installation and use, preferably, the syngas outlet 2 can be increased according to the pressure in the chamber and the flow rate of the syngas. , preferably, a plurality of gas outlets are arranged as a centrally symmetrical structure; at the same time, considering the overall miniaturization and safety of the device, the maximum outer diameter of the sliding arc plasma-assisted diesel reforming device is set to 76mm, and the length is 780mm, The wall thickness of the chamber is not less than 2mm; among them, the reforming reaction chamber is set to 290mm.

在实际使用过程中,将气源与放电气管口9相连,滑动弧等离子体炬的接线柱17与高压电源导线相连,柴油气、水蒸气、空气混合后通过进料口4通入腔内。In actual use, the gas source is connected to the discharge gas pipe port 9, the terminal post 17 of the sliding arc plasma torch is connected to the high-voltage power supply wire, and diesel gas, water vapor, and air are mixed and passed into the cavity through the feed port 4.

使用时,整体装置垂直放置,以使进入的反应物气流在重力作用下到达等离子体区域周围。In use, the monolith is positioned vertically so that the incoming reactant gas flow is gravitationally directed around the plasma region.

所需的反应物流量由柴油处理量和氧碳比、水碳比来确定,氧碳比通常为0.5-1.5之间,水碳比为1.6-2.6之间。为保障等离子体稳定运行,放电气流量应为15-30L/min之间,剩余的气体为载气,与柴油气、水蒸气混合进入腔内;柴油重整后的产物由出气口排出。The required reactant flow rate is determined by the diesel oil processing capacity, oxygen-carbon ratio, and water-carbon ratio. The oxygen-carbon ratio is usually between 0.5-1.5, and the water-carbon ratio is between 1.6-2.6. In order to ensure the stable operation of the plasma, the discharge gas flow rate should be between 15-30L/min, and the remaining gas is the carrier gas, which is mixed with diesel gas and water vapor into the cavity; the reformed diesel products are discharged from the gas outlet.

本发明重整装置可以实现应用滑动弧等离子体辅助柴油重整制取含氢混合气,避免催化重整器需经常更换催化剂、寿命短、反应不均匀等问题,实现无添加任何催化剂情况下较高的柴油转化率。提出的装置能够耐受重整反应产生的高温,安全性高,可处理柴油量大,能够实现长期稳定的运行。The reforming device of the present invention can realize the application of sliding arc plasma-assisted reforming of diesel oil to produce hydrogen-containing mixed gas, avoiding the problems of frequent replacement of catalysts, short service life, uneven reaction, etc. High diesel conversion rate. The proposed device can withstand the high temperature generated by the reforming reaction, has high safety, can handle a large amount of diesel oil, and can realize long-term stable operation.

本发明将旋转滑动弧等离子体炬与重整反应腔相连接,利用产生的旋转滑动弧非热等离子体,在腔体内部进行柴油的进料与重整。The invention connects the rotating sliding arc plasma torch with the reforming reaction chamber, and utilizes the generated rotating sliding arc non-thermal plasma to carry out feeding and reforming of diesel oil inside the chamber.

这样,柴油在非平衡等离子体高温、高化学活性的环境中发生裂解,并进行部分氧化重整与水蒸气重整反应,同时释放热量,在重整反应腔中形成高温区域;裂解产物和重整产物经过内导管5在二次反应腔1内进一步停留,进行二次裂解和重整,从而实现柴油的高转化率重整制氢。In this way, diesel oil cracks in the environment of non-equilibrium plasma high temperature and high chemical activity, and undergoes partial oxidation reforming and steam reforming reactions, and releases heat at the same time, forming a high temperature area in the reforming reaction chamber; The whole product is further stayed in the secondary reaction chamber 1 through the inner conduit 5, and undergoes secondary cracking and reforming, so as to realize hydrogen production by reforming with a high conversion rate of diesel oil.

显然本发明具体实现并不受上述方式的限制,只要采用了本发明的方法构思和技术方案进行的各种非实质性的改进,均在本发明的保护范围之内。Apparently, the specific implementation of the present invention is not limited by the above methods, as long as various insubstantial improvements are made by adopting the method concept and technical solutions of the present invention, they all fall within the protection scope of the present invention.

Claims (10)

1. The reforming device is characterized by comprising an arc plasma torch and a reforming reaction mechanism connected with the arc plasma torch, wherein the reforming reaction mechanism comprises a reforming reaction cavity; the upper end of the arc plasma torch stretches into the reforming reaction cavity; the arc plasma torch is used for generating non-thermal arc plasma for treating diesel oil, and the reforming reaction cavity is used for feeding and reforming the diesel oil.
2. The sliding arc plasma assisted diesel reforming apparatus of claim 1 wherein the arc plasma torch comprises a housing assembly having an electrode assembly disposed therein;
the housing assembly includes a connection housing; the connection shell is provided with a discharge pipe orifice;
the electrode assembly comprises a high-voltage electrode, and the high-voltage electrode is connected with an electrode support rod.
3. The reforming device for sliding arc plasma assisted diesel reforming according to claim 2, wherein a connecting sleeve is arranged at one end of the connecting shell away from the reforming reaction mechanism; the electrode struts are arranged inside the connecting sleeve.
4. A reformer for slip arc plasma assisted diesel reforming according to claim 3 wherein an insulator is provided within the connecting sleeve; and the insulating piece is provided with a through hole, and the electrode support rod is arranged through the insulating piece by the through hole.
5. The reformer of claim 4, wherein a fixing sleeve is disposed in the through hole of the insulating member, and the electrode strut is connected to a terminal post at an end thereof.
6. A reformer for slip arc plasma assisted diesel reforming according to claim 3, wherein the insulator has a limiting sink formed on the outside thereof, and the coupling sleeve is embedded in the limiting sink of the insulator.
7. The reformer of claim 2, wherein the housing has an anode cap disposed at an end thereof adjacent to the reforming reaction mechanism; the anode cover is provided with a top through hole.
8. A reformer for slip arc plasma assisted diesel reforming according to claim 3, wherein the coupling sleeve is provided with a retaining nut, the retaining nut being located at the junction of the coupling sleeve and the housing.
9. A reformer for slip arc plasma assisted diesel reforming according to claim 2, wherein the reforming reaction means comprises a primary reaction means and a secondary reaction means;
the arc plasma torch is connected with the secondary reaction mechanism through the primary reaction mechanism;
the primary reaction mechanism comprises a primary reaction shell, and a primary reaction cavity is formed by the hollow inside of the primary reaction shell;
the secondary reaction mechanism comprises a secondary reaction shell, and a secondary reaction cavity is formed in the secondary reaction shell in a hollow mode;
the primary reaction cavity is communicated with the second reaction cavity through an inner conduit;
an air outlet pipe is arranged on the secondary reaction shell, and a synthetic gas outlet is arranged in the air outlet pipe; the synthesis gas outlet is communicated with the secondary reaction cavity;
a feed inlet is formed in the primary reaction shell; the feed inlet is communicated with the primary reaction cavity.
10. The reformer of claim 9, wherein the primary reaction housing is connected to the secondary reaction housing by an upper flange assembly; the primary reaction housing is connected to the arc plasma torch through a lower flange assembly.
CN202211711112.9A 2022-12-29 2022-12-29 Device for reforming diesel oil assisted by sliding arc plasma Active CN116143073B (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070259228A1 (en) * 2006-05-08 2007-11-08 Hartvigsen Joseph J Plasma-Catalyzed, Thermally-Integrated Reformer For Fuel Cell Systems

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070259228A1 (en) * 2006-05-08 2007-11-08 Hartvigsen Joseph J Plasma-Catalyzed, Thermally-Integrated Reformer For Fuel Cell Systems

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