CN116116575A - Process for improving slag magnetic iron grade and material adding equipment thereof - Google Patents
Process for improving slag magnetic iron grade and material adding equipment thereof Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
- B03C1/30—Combinations with other devices, not otherwise provided for
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/08—Separating or sorting of material, associated with crushing or disintegrating
- B02C23/10—Separating or sorting of material, associated with crushing or disintegrating with separator arranged in discharge path of crushing or disintegrating zone
- B02C23/12—Separating or sorting of material, associated with crushing or disintegrating with separator arranged in discharge path of crushing or disintegrating zone with return of oversize material to crushing or disintegrating zone
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/08—Separating or sorting of material, associated with crushing or disintegrating
- B02C23/14—Separating or sorting of material, associated with crushing or disintegrating with more than one separator
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/18—Drum screens
- B07B1/22—Revolving drums
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Abstract
本发明提供一种提高炉渣磁选铁品位的工艺及其物料添加设备,S1、物料加工:将石膏进行破碎并且进行烘干;S2、物料添加:将S1加工后的石膏与熔融状态炉渣添加至渣包内进行混合反应;S3、渣包缓冷:待S2物料添加完毕后,将第二步中渣包进行缓冷工序,进行通风降温,再进行喷水降温;S4、破碎磁选:将S3中缓冷结束的渣包进行倒包,对炉渣进行破碎并且进行磁选加工。该发明能够对炉渣进行处理,提高炉渣内选铁的含量,提高铁金属的品位,提高回收效益。
The invention provides a process for improving the grade of iron in slag magnetic separation and its material addition equipment, S1, material processing: crushing and drying gypsum; S2, material addition: adding gypsum and molten slag after S1 processing to Mixing reaction in the slag bag; S3, slow cooling of the slag bag: after the S2 material is added, the slag bag in the second step is subjected to a slow cooling process, ventilated and cooled, and then sprayed to cool down; S4, broken magnetic separation: the The slag ladle after slow cooling in S3 is poured, and the slag is crushed and processed by magnetic separation. The invention can process the slag, increase the iron content in the slag, improve the grade of iron metal, and improve the recovery efficiency.
Description
技术领域technical field
本发明涉及炉渣加工技术领域,尤其涉及一种提高炉渣磁选铁品位的工艺及其物料添加设备。The invention relates to the technical field of slag processing, in particular to a process for improving the grade of iron in slag magnetic separation and material adding equipment thereof.
背景技术Background technique
侧吹炉炉渣经渣缓冷和选矿工艺,得到铜精矿和选铜尾矿,选铜尾矿进行磁选,得到铁精矿和磁选尾矿,由于侧吹炉炉渣中磁性铁占比较低,磁性得到的铁精矿品位较低;国内某企业,2021年渣选厂的铜渣处理量约为62万吨/年,采用浮选选铜-磁选选铁工艺对铜渣进行综合回收利用,在低铁硅比生产情况下,渣选厂可保持约25%产率,产出48%-50%品位铁精矿,铁精矿含铁品位<50%市场有限,目前已堆积约7万吨,严重影响了企业的生产和经济效益。The side-blown furnace slag undergoes slow cooling and beneficiation process to obtain copper concentrate and copper tailings, and the copper tailings are subjected to magnetic separation to obtain iron concentrate and magnetic tailings. Low, the grade of iron ore concentrate obtained by magnetism is low; in a domestic company, the copper slag processing capacity of the slag concentrator in 2021 is about 620,000 tons/year, and the copper slag is comprehensively processed by flotation copper-magnetic separation iron separation process Recycling, in the case of low iron-silicon ratio production, the slag concentrator can maintain a production rate of about 25%, and produce iron concentrate with a grade of 48%-50%. The market for iron concentrate with an iron grade of <50% is limited and has been piled up at present About 70,000 tons have seriously affected the production and economic benefits of enterprises.
目前,针对侧吹炉炉渣中铁的回收,常用的方法为磨矿-磁选法。侧吹炉炉渣中主要含铁物相为铁橄榄石和磁铁矿;铁橄榄石和磁铁矿均为尖晶石矿物,但其磁性却有明显的差别,因此通过弱磁性可实现铁橄榄石与磁铁矿的有效分离,但是前提是使磁铁矿物最大限度的达到单体解离;在实际生产中,针对侧吹炉炉渣中铁磁选效果差的问题,多数企业是采用优化现有磁选工艺与参数和增加磨矿-磁选流程进行解决,其本质包括两个方面:第一,减小颗粒粒度,提高磁性氧化铁的单体解离程度,从而在磁选过程中达到较好的分离效果;第二,优化磁选工艺参数与流程,从磁选本身进行调整,减少目的矿物损失进入磁选尾矿,提高磁选效果。At present, for the recovery of iron in side-blowing furnace slag, the commonly used method is grinding-magnetic separation. The main iron-containing phases in side-blowing furnace slag are fayalite and magnetite; both fayalite and magnetite are spinel minerals, but their magnetic properties are significantly different, so fayalite and magnetite can be realized through weak magnetism. Effective separation of magnetite, but the premise is to maximize the dissociation of magnetite as a monomer; in actual production, in view of the poor effect of ferromagnetic separation in side-blowing furnace slag, most enterprises adopt the optimization of existing magnetic separation process Solve the problem with parameters and increase the grinding-magnetic separation process, which essentially includes two aspects: first, reduce the particle size and increase the degree of monomer dissociation of magnetic iron oxide, so as to achieve better separation in the magnetic separation process Effect; second, optimize the magnetic separation process parameters and process, adjust from the magnetic separation itself, reduce the loss of target minerals into the magnetic separation tailings, and improve the magnetic separation effect.
该方法在国内多数企业已经取得了一定的效果,但是也存在一些缺点,如磨矿-磁选进行再选后的精矿回收率较低,部分目的矿物进入磁选尾矿,造成经济损失;另外,磨矿本身属于高耗能处理单元,通过增加磨矿作业会导致生产成本大幅增加,从经济效益方面考虑该处理方法不具备优先选择性;除了以上方法以外,一些研究采用焙烧法或高温还原法回收侧吹炉炉渣中的铁,主要是通过氧化焙烧将铜渣中的铁富集为Fe3O4或还原焙烧富集为金属铁,再结合磁选或熔分等工艺进行回收;焙烧法或高温还原法结合磁选可以得到高品位的磁铁矿或金属铁,但是存在高耗能、产生二次废渣和烟气等缺点,不符合我国倡导的清洁生产、绿色节能的发展要求,该方法还未实现大规模工业化应用;因此如何提高炉渣内磁选铁的品位,提升磁选效果是需要解决的问题。This method has achieved certain results in most domestic enterprises, but there are also some disadvantages, such as the low recovery rate of concentrate after re-election by grinding-magnetic separation, and some target minerals enter the tailings of magnetic separation, resulting in economic losses; In addition, ore grinding itself is a high-energy-consuming processing unit. Increasing the grinding operation will lead to a substantial increase in production costs. From the perspective of economic benefits, this processing method is not preferred; in addition to the above methods, some studies use roasting or high temperature The reduction method recovers the iron in the side-blowing furnace slag, which mainly enriches the iron in the copper slag into Fe 3 O 4 through oxidation roasting or reduction roasting enrichment into metallic iron, and then combines magnetic separation or melting to recover; Roasting method or high temperature reduction method combined with magnetic separation can obtain high-grade magnetite or metallic iron, but there are disadvantages such as high energy consumption, secondary waste residue and flue gas generation, which do not meet the development requirements of clean production and green energy conservation advocated by China , this method has not yet achieved large-scale industrial application; therefore, how to improve the grade of magnetically separated iron in the slag and improve the effect of magnetic separation is a problem that needs to be solved.
发明内容Contents of the invention
针对上述问题,本发明提供一种提高炉渣磁选铁品位的工艺及其物料添加设备,该发明能够对炉渣进行处理,提高炉渣内磁选铁的含量,提高铁金属的品位,提高回收效益。In view of the above problems, the present invention provides a process for improving the grade of magnetically separated iron in slag and its material adding equipment. The invention can process the slag, increase the content of magnetically separated iron in the slag, improve the grade of iron metal, and improve the recovery efficiency.
为解决上述问题,本发明所采用的技术方案是:In order to solve the above problems, the technical solution adopted in the present invention is:
一种提高炉渣磁选铁品位的工艺,S1、物料加工:将石膏进行破碎并且进行烘干,控制石膏的含水量小于1%,控制石膏的粒度:1cm—2cm;A process for improving the grade of iron in slag magnetic separation, S1, material processing: crushing and drying the gypsum, controlling the water content of the gypsum to be less than 1%, and controlling the particle size of the gypsum: 1cm-2cm;
S2、物料添加:将S1加工后的石膏与熔融状态炉渣添加至渣包内进行混合反应,控制石膏与炉渣混合的比例为1:20-35;S2. Material addition: add the gypsum processed in S1 and molten slag into the slag bag for mixed reaction, and control the mixing ratio of gypsum and slag to 1:20-35;
S3、渣包缓冷:待S2物料添加完毕后,将第二步中渣包进行缓冷工序,进行通风降温,再进行喷水降温,控制缓冷时间为48h—72h;S3. Slow cooling of the slag bag: After the S2 material is added, the slag bag in the second step is subjected to a slow cooling process, ventilated and cooled, and then sprayed with water to cool down, and the slow cooling time is controlled to be 48h-72h;
S4、破碎磁选:将S3中缓冷结束的渣包进行倒包,对炉渣进行破碎并且进行磁选加工,其中控制破碎粒度:10cm—15cm,颚式破碎机在此破碎范围可有效节省电量,减少破碎时间,提高工作效率。S4. Crushing and magnetic separation: the slag bag that has been cooled slowly in S3 is reversed, and the slag is crushed and processed by magnetic separation. The crushing particle size is controlled: 10cm-15cm. The jaw crusher can effectively save electricity in this crushing range , reduce crushing time and improve work efficiency.
优选地,在S2中启动负压设备,控制炉渣烟气定向流动与石膏混合实现对烟气的吸附。Preferably, the negative pressure equipment is started in S2, and the directional flow of the slag flue gas is controlled to mix with the gypsum to achieve the adsorption of the flue gas.
一种物料添加设备,包括用于输送石膏的安装主体,所述安装主体第一端设置有进料装置,所述安装主体第二端设置有出料装置,所述安装主体内部设置有与安装主体内壁相对转动的筛分主体,所述筛分主体为中空筒状,所述筛分主体表面设置有筛分区域,所述出料装置包括物料输送箱,所述物料输送箱位置与筛分区域位置相对应,所述物料输送箱内部设置有螺旋输送叶片,所述安装主体外侧设置有用于驱动螺旋输送叶片以及筛分主体同步转动的驱动装置,所述安装主体内壁安装有位于筛分主体内部的破碎装置,所述筛分主体内壁固定连接有用于抬升石膏的抄料组件。A material adding device, comprising an installation main body for conveying gypsum, a feeding device is provided at the first end of the installation main body, a discharge device is provided at the second end of the installation main body, and an installation and The inner wall of the main body rotates relative to the screening body. The screening body is hollow and cylindrical. The surface of the screening body is provided with a screening area. Corresponding to the location of the area, the inside of the material conveying box is provided with a screw conveying blade, and the outside of the installation body is provided with a driving device for driving the screw conveying blade and the synchronous rotation of the screening body. The internal crushing device, the inner wall of the screening main body is fixedly connected with a copying assembly for lifting gypsum.
优选地,所述破碎装置包括两个并列设置的破碎安装轴,所述破碎安装轴表面安装有若干个并列设置的破碎主体,并列对应的两个破碎主体之间具有破碎间隙,多个破碎间隙按照物料移动方向逐渐减小,所述安装主体外壁设置有第一电控装置用以控制两个破碎安装轴同步转动。Preferably, the crushing device includes two crushing installation shafts arranged in parallel. Several crushing bodies arranged in parallel are installed on the surface of the crushing installation shafts. There is a crushing gap between the two crushing bodies corresponding to the paralleling. According to the gradual reduction of the moving direction of the material, the outer wall of the installation main body is provided with a first electric control device to control the synchronous rotation of the two crushing installation shafts.
优选地,所述驱动装置包括位于安装主体内部的第一驱动转轴,所述物料输送箱外壁转动连接有第二驱动转轴,所述物料输送箱外壁安装用控制第二驱动转轴转动的第二电控装置,所述第二驱动转轴与第一驱动转轴之间通过一级减速装置传动,所述第一驱动转轴与筛分主体之间通过二级减速装置传动。Preferably, the drive device includes a first drive shaft located inside the installation body, a second drive shaft is rotatably connected to the outer wall of the material delivery box, and a second electric drive for controlling the rotation of the second drive shaft is installed on the outer wall of the material delivery box. The transmission between the second drive shaft and the first drive shaft is through a first-stage reduction device, and the transmission between the first drive shaft and the screening main body is through a second-stage reduction device.
优选地,所述物料输送箱上端与安装主体外壁之间通过物料暂存斗连通,所述物料暂存斗内壁固定连接有倾斜的暂存挡板。Preferably, the upper end of the material delivery box communicates with the outer wall of the installation body through a material temporary storage bucket, and an inclined temporary storage baffle is fixedly connected to the inner wall of the material temporary storage bucket.
优选地,所述进料装置包括进料主体,所述进料主体上端固定连接有控制箱,所述控制箱上端固定连接有进料斗,所述控制箱侧壁连通有负压管道,所述控制箱内壁设置有阀组用以控制进料斗导通状态。Preferably, the feeding device includes a feeding body, the upper end of the feeding body is fixedly connected with a control box, the upper end of the control box is fixedly connected with a feeding hopper, and the side wall of the control box is connected with a negative pressure pipeline, so The inner wall of the control box is provided with a valve group to control the conduction state of the feed hopper.
优选地,所述抄料组件朝着第一方向倾斜设置,所述抄料组件与筛分主体之间形成存储区域,所述抄料组件为多个且沿着筛分主体内壁圆周分布。Preferably, the copying assembly is arranged inclined toward the first direction, a storage area is formed between the copying assembly and the screening body, and there are multiple copying assemblies distributed along the inner wall of the screening body.
优选地,所述抄料组件包括第一抄料板以及第二抄料板,所述第一抄料板与第二抄料板之间连接有扭力弹性部件,所述第一抄料板两端边缘部分固定连接有限位套筒,所述第二抄料板边缘部分固定连接有限位杆,所述限位杆两端贯穿限位套筒,所述限位杆表面开有控制凸块,所述限位套筒内壁开有弯曲的控制凹槽,所述安装主体内壁设置有用于控制限位杆移动的控制部件。Preferably, the copying assembly includes a first copying board and a second copying board, a torsional elastic member is connected between the first copying board and the second copying board, and the two parts of the first copying board The edge part of the end is fixedly connected with the limit sleeve, the edge part of the second copying plate is fixedly connected with the limit rod, the two ends of the limit rod pass through the limit sleeve, and the surface of the limit rod is provided with a control protrusion, The inner wall of the limiting sleeve is provided with a curved control groove, and the inner wall of the installation body is provided with a control component for controlling the movement of the limiting rod.
优选地,所述控制部件包括第一磁体以及第二磁体,所述第一磁体与限位杆末端固定连接,所述第二磁体通过连接工件与安装主体内壁固定连接。Preferably, the control component includes a first magnet and a second magnet, the first magnet is fixedly connected to the end of the limit rod, and the second magnet is fixedly connected to the inner wall of the installation body through a connecting workpiece.
本发明的有益效果为:The beneficial effects of the present invention are:
1、本发明利用石膏对目标产物进行分解,能使渣中二价铁部分氧化为磁性铁,增加磁性铁含量,石膏分解产物中的CaO,在渣包中发生反应,使熔炼渣酸碱度发生改变,对浮选渣含铜有一定好处,提高了综合回收利用效益;并且能够实现自产废酸石膏综合利用;具有工艺流程简单、投资生产成本低、铁回收率高的优点;经过处理后的铁精矿品位增长3%—5%,对铜冶炼企业实现侧吹炉炉渣、废酸石膏资源化利用,具有重要的环境、经济效益,为同行业类似渣型提高磁性铁提供新的方法。1. The present invention uses gypsum to decompose the target product, which can partially oxidize the ferrous iron in the slag to magnetic iron, increase the content of magnetic iron, CaO in the gypsum decomposition product reacts in the slag bag, and changes the pH of the smelting slag , has certain benefits to the flotation slag containing copper, which improves the comprehensive recycling benefits; and can realize the comprehensive utilization of self-produced waste acid gypsum; has the advantages of simple process flow, low investment and production costs, and high iron recovery rate; after treatment The grade of iron concentrate increases by 3%-5%, which has important environmental and economic benefits for copper smelting enterprises to realize the resource utilization of side-blown furnace slag and waste acid gypsum, and provides a new method for similar slag types in the same industry to improve magnetic iron.
2、通过设置筛分主体、破碎装置等部件能够对废酸石膏进行一体化加工处理,实现对石膏的破损、筛分,最终通过螺旋输送叶片能够将破碎后的石膏进行定量输送,以满足石膏添加的质量以及数量要求;通过设置驱动装置能够控制筛分主体以及螺旋输送叶片同步转动,根据石膏添加的状态进行调整,二者同步强化或者减弱,简化了控制过程,满足了生产加工的需要;通过设置抄料组件能够对尺寸较大的石膏进行抬升输送,石膏能够自动掉落至破碎装置内完成破碎,破碎加工以及筛分加工均在筛分主体内进行,提高了加工的效率,满足了加工的需求。2. By setting the screening body, crushing device and other components, the waste acid gypsum can be processed in an integrated manner, and the damage and screening of the gypsum can be realized. Finally, the crushed gypsum can be quantitatively transported through the spiral conveying blades to meet the gypsum Added quality and quantity requirements; setting the driving device can control the synchronous rotation of the screening main body and the screw conveying blade, and adjust according to the state of gypsum addition. The two are synchronously strengthened or weakened, which simplifies the control process and meets the needs of production and processing; The gypsum with a large size can be lifted and transported by setting the copying component, and the gypsum can automatically fall into the crushing device to complete the crushing. The crushing process and the screening process are all carried out in the screening main body, which improves the processing efficiency and meets the requirements processing needs.
3、破碎间隙沿着石膏移动方向逐渐减小,能够对石膏进行阶段性破碎,提高破碎效率的同时降低对设备的影响,延长设备的使用时间;通过设置控制箱、阀组、负压管道等部件,通过关闭控制箱内的阀组让安装主体内部相对封闭,通过负压管道形成负压循环,能够让出料管道周围的烟气定向流动经过物料输送箱、螺旋输送叶片以及安装主体形成烟气循环通道实现对烟气的循环吸收,能够对部分氧化铁粉尘进行回收的同时降低了对作业环境的影响;烟气循环通道为U形,延长了吸收的距离,增强了对烟气吸收的效果;通过螺旋输送叶片对破碎后的石膏进行输送,破碎后的石膏在其内部形成海绵状的吸附滤芯,进一步增强了对烟气吸收的效果,具有一定温度的烟气能够对石膏进行干燥以及预热,降低了石膏内含水量的同时,能够降低能量损失,有利于铁、铜等金属的回收利用。3. The crushing gap gradually decreases along the moving direction of the gypsum, which can crush the gypsum in stages, improve the crushing efficiency while reducing the impact on the equipment, and prolong the service life of the equipment; by setting the control box, valve group, negative pressure pipeline, etc. Components, by closing the valve group in the control box, the interior of the installation body is relatively closed, and a negative pressure cycle is formed through the negative pressure pipe, which can allow the flue gas around the discharge pipe to flow directionally through the material conveying box, the screw conveying blade and the installation body to form smoke. The gas circulation channel realizes the circulation and absorption of flue gas, which can recover part of the iron oxide dust and reduce the impact on the working environment; the flue gas circulation channel is U-shaped, which prolongs the absorption distance and enhances the absorption of flue gas Effect: the crushed gypsum is conveyed by the spiral conveying blade, and the crushed gypsum forms a sponge-like adsorption filter element inside, which further enhances the effect of absorbing the flue gas, and the flue gas with a certain temperature can dry the gypsum and Preheating reduces the water content in the gypsum and at the same time reduces energy loss, which is beneficial to the recycling of iron, copper and other metals.
附图说明Description of drawings
图1为本发明的立体结构示意图;Fig. 1 is the three-dimensional structure schematic diagram of the present invention;
图2为本发明的主视结构示意图;Fig. 2 is the front view structure schematic diagram of the present invention;
图3为本发明的侧视结构示意图;Fig. 3 is the side view structural representation of the present invention;
图4为本发明的A-A线剖视结构示意图;Fig. 4 is the A-A line sectional structure schematic diagram of the present invention;
图5为本发明的筛分主体立体结构示意图;Fig. 5 is a schematic diagram of the three-dimensional structure of the screening main body of the present invention;
图6为本发明图5的侧视结构示意图;Fig. 6 is a side view structural schematic diagram of Fig. 5 of the present invention;
图7为本发明的化学反应示意图。Fig. 7 is a schematic diagram of the chemical reaction of the present invention.
图中:1、安装主体;2、进料装置;201、进料斗;202、负压管道;203、控制箱;2031、阀组;204、进料主体;3、出料装置;301、物料暂存斗;3011、暂存挡板;302、物料输送箱;3021、出料管道;303、螺旋输送叶片;4、驱动装置;401、二级减速装置;4011、外齿环;4012、减速齿轮;402、一级减速装置;4021、皮带轮一;4022、皮带轮二;403、第二驱动转轴;404、第二电控装置;5、破碎装置;501、破碎主体;502、破碎安装轴;503、第一电控装置;6、筛分主体;601、筛分区域;602、环形挡板;6021、通过开口;7、抄料组件;701、第一抄料板;702、限位套筒;703、限位杆;704、第二抄料板;801、第一磁体;802、第二磁体。In the figure: 1, installation main body; 2, feeding device; 201, feeding hopper; 202, negative pressure pipeline; 203, control box; 2031, valve group; 204, feeding main body; 3, discharging device; 301, Material temporary storage bucket; 3011, temporary storage baffle; 302, material conveying box; 3021, discharge pipe; 303, screw conveying blade; 4, driving device; 401, two-stage reduction device; 4011, external gear ring; 4012, Reduction gear; 402, primary reduction device; 4021, pulley one; 4022, pulley two; 403, second drive shaft; 404, second electric control device; 5, crushing device; 501, crushing main body; 502, crushing installation shaft ; 503, the first electric control device; 6, the screening main body; 601, the screening area; 602, the annular baffle; 6021, through the opening; Sleeve; 703, limit rod; 704, second copying plate; 801, first magnet; 802, second magnet.
具体实施方式Detailed ways
下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.
一种提高炉渣磁选铁品位的工艺,S1、物料加工:将石膏进行破碎并且进行烘干,控制石膏的含水量小于1%,控制石膏的粒度:1cm—2cm。A process for improving the grade of iron in slag magnetic separation, S1, material processing: crushing and drying the gypsum, controlling the moisture content of the gypsum to be less than 1%, and controlling the particle size of the gypsum: 1cm-2cm.
S2、物料添加:将S1加工后的石膏与熔融状态炉渣添加至渣包内进行混合反应,控制石膏与炉渣混合的比例为1:20-35;通过石膏与熔融状态的炉渣反应,能够将渣包内二价铁氧化为磁性铁,提高矿渣铁品位,提高后续磁选效果。S2. Material addition: add the gypsum processed in S1 and molten slag into the slag bag for mixed reaction, and control the mixing ratio of gypsum and slag to 1:20-35; through the reaction of gypsum and molten slag, the slag can be The divalent iron in the bag is oxidized to magnetic iron, which improves the grade of slag iron and improves the effect of subsequent magnetic separation.
S3、渣包缓冷:待S2物料添加完毕后,将第二步中渣包进行缓冷工序,进行通风降温,再进行喷水降温,控制缓冷时间为48h—72h;S3. Slow cooling of the slag bag: After the S2 material is added, the slag bag in the second step is subjected to a slow cooling process, ventilated and cooled, and then sprayed with water to cool down, and the slow cooling time is controlled to be 48h-72h;
S4、破碎磁选:将S3中缓冷结束的渣包进行倒包,对炉渣进行破碎并且进行磁选加工,其中控制破碎粒度:10cm—15cm。S4. Crushing and magnetic separation: the slag bag that has been slowly cooled in S3 is turned over, and the slag is crushed and subjected to magnetic separation processing, wherein the crushing particle size is controlled: 10cm-15cm.
在S2中启动负压设备,控制炉渣烟气定向流动与石膏混合实现对烟气的吸附,通过控制烟气与石膏混合,一方面能够通过石膏捕获烟气中的部分氧气铁,降低铁的损失;另外一方面能够对烟气进行定向吸收,改善作业环境。Start the negative pressure equipment in S2, control the directional flow of slag flue gas to mix with gypsum to realize the adsorption of flue gas, by controlling the mixing of flue gas and gypsum, on the one hand, part of the oxygen and iron in the flue gas can be captured by gypsum to reduce the loss of iron ; On the other hand, it can directional absorb the flue gas and improve the working environment.
石膏反应原理:Gypsum reaction principle:
石膏(CaS04·2H20)是有二个结晶水的硫酸钙晶体,在不同条件的加热处理中,其结晶水容易脱出,在800℃时,石膏开始分解为CaO和SO2加O2等;当向侧吹炉高温熔炼渣熔体添加石膏时,石膏发生分解反应,生成的CaO夺走铁橄榄石中的二氧化硅,而O2能使铁橄榄石中的二价铁氧化为磁性铁:Gypsum (CaS0 4 2H 2 0) is a calcium sulfate crystal with two crystal waters. During heat treatment under different conditions, its crystal water is easy to come out. At 800°C, gypsum begins to decompose into CaO and SO 2 plus O 2 etc.; when adding gypsum to the high-temperature smelting slag melt of the side-blowing furnace, the gypsum decomposes, and the generated CaO takes away the silicon dioxide in fayalite, and O2 can oxidize the ferrous iron in fayalite to Magnetic iron:
3(2FeO·SiO2)+3CaO+O2→3CaSiO3+2Fe3O4 3(2FeO·SiO 2 )+3CaO+O 2 →3CaSiO 3 +2Fe 3 O 4
参照图1-图6,一种物料添加设备,包括用于输送石膏的安装主体1,安装主体1第一端设置有进料装置2,安装主体1第二端设置有出料装置3,石膏原料从进料装置2处添加至安装主体1内完成破碎筛分,符合尺寸要求的石膏从出料装置3处排出,实现对石膏的添加;在安装主体1内部设置有与安装主体1内壁相对转动的筛分主体6,筛分主体6为中空筒状,筛分主体6表面设置有筛分区域601,通过筛分主体6实现对物料的筛分加工,其中筛分主体选择为多个圆周分布的筛分杆组成,相邻的两个筛分杆之间具有预定间隙,能够让尺寸小于2cm的石膏颗粒从该处排出,进入到出料装置3内实现出料过程。Referring to Fig. 1-Fig. 6, a material adding equipment includes an installation
其中出料装置3包括物料输送箱302,物料输送箱302位置与筛分区域601位置相对应,物料输送箱302内部设置有螺旋输送叶片303,在物料输送箱302的末端固定设置有出料管道3021,通过控制螺旋输送叶片303转动能够对破碎后的石膏颗粒进行输送,最终从出料管道3021处排出,实现石膏的定量添加;安装主体1外侧设置有用于驱动螺旋输送叶片303以及筛分主体6同步转动的驱动装置4,通过驱动装置4控制螺旋输送叶片303以及筛分主体6同步转动,能够根据物料输送的效率来同步提高筛分的效率,保证二者的同步一致,简化了控制过程,提高了加工效率;并且在安装主体1内壁安装有位于筛分主体6内部的破碎装置5,筛分主体6内壁固定连接有用于抬升石膏的抄料组件7,通过抄料组件7能够将筛分主体6内较大尺寸的石膏进行输送,将其抬升至上方实现石膏的破碎添加过程,物料能够掉落至破碎装置5内实现破碎加工过程。Wherein the discharge device 3 comprises a material delivery box 302, the position of the material delivery box 302 corresponds to the position of the screening area 601, the inside of the material delivery box 302 is provided with a spiral delivery blade 303, and the end of the material delivery box 302 is fixedly provided with a discharge pipeline 3021, the crushed gypsum particles can be transported by controlling the rotation of the screw conveying blade 303, and finally discharged from the discharge pipe 3021 to realize the quantitative addition of gypsum; the outside of the installation main body 1 is provided with a driving screw conveying blade 303 and a screening main body 6 Synchronously rotating driving device 4, through which the driving device 4 controls the synchronous rotation of the screw conveying blade 303 and the screening main body 6, which can synchronously improve the efficiency of screening according to the efficiency of material transportation, ensure the synchronization of the two, and simplify the control process , improving the processing efficiency; and the crushing device 5 positioned at the inside of the screening body 6 is installed on the inner wall of the installation body 1, and the inner wall of the screening main body 6 is fixedly connected with a copying assembly 7 for lifting gypsum, and the screening assembly 7 can be used for screening The larger-sized gypsum in the main body 6 is transported, and it is lifted to the top to realize the crushing and adding process of gypsum, and the material can fall into the crushing device 5 to realize the crushing process.
参照附图4;其中破碎装置5包括两个并列设置的破碎安装轴502,破碎安装轴502表面安装有若干个并列设置的破碎主体501,并列对应的两个破碎主体501之间具有破碎间隙,多个破碎间隙按照物料移动方向逐渐减小,安装主体1外壁设置有第一电控装置503用以控制两个破碎安装轴502同步转动,通过第一电控装置503控制两个破碎安装轴502朝着内侧转动,掉落至破碎主体501表面的石膏能够在挤压的作用下完成破碎加工;参照附图4,其中物料在筛分主体6内的石膏输送方向从左侧朝向右侧输送,位于左侧的破碎主体501之间的破碎间隙大于位于右侧破碎主体501之间的破碎间隙,通过设置破碎间隙逐渐增大能够对物料实现梯度破碎,逐渐降低石膏的力度,降低破碎的难度以及降低对零件的损耗;在破碎主体501表面可以固定有凸起的破碎齿以增强对石膏的破碎效果。Referring to accompanying drawing 4; wherein crushing device 5 comprises two crushing installation shafts 502 arranged side by side, and several crushing main bodies 501 arranged side by side are installed on the surface of the crushing installation shaft 502, and there is a crushing gap between the two crushing main bodies 501 corresponding in parallel, The multiple crushing gaps gradually decrease according to the moving direction of the material. The outer wall of the
参照附图4;其中驱动装置4包括位于安装主体1内部的第一驱动转轴,物料输送箱302外壁转动连接有第二驱动转轴403,物料输送箱302外壁安装用控制第二驱动转轴403转动的第二电控装置404,第二驱动转轴403与第一驱动转轴之间通过一级减速装置402传动,第一驱动转轴与筛分主体6之间通过二级减速装置401传动,通过设置一级减速装置402以及二级减速装置401能够对第二驱动转轴403的传动效力进行调整,实现筛分主体6以及螺旋输送叶片303按照比例传动,其中筛分主体6体积较大,转动速率低于螺旋输送叶片303转动速率;当所需的物料增多时,控制螺旋输送叶片303转动速度提高,此时石膏的出料速率增大,并且筛分主体6的筛分速率同步增大,二者协调配合,满足石膏添加需求。With reference to accompanying drawing 4; Wherein driving
其中一级减速装置402可以选择为皮带轮一4021以及皮带轮二4022的组合,二者配合能够实现一级减速,其中二级减速装置401可以选择为外齿环4011以及减速齿轮4012的组合,外齿环4011固定于筛分主体6的外壁,二者配合实现二级减速;这里需要说明的是,其中第一驱动转轴贯穿安装主体1并且部分延伸至外侧,一级减速装置402位于安装主体1内侧实现动力传动,二级减速装置401位于安装主体1的外侧实现动力传动,二级减速装置401以及一级减速装置402之间通过第一驱动转轴实现动力的传动,第一驱动转轴与安装主体1之间转动连接,并且在转动连接的位置设置有密封套,能保证相对的密封效果。Among them, the first-stage reduction device 402 can be selected as a combination of pulley one 4021 and pulley two 4022, and the cooperation of the two can realize a first-stage reduction. Among them, the second-
在物料输送箱302上端与安装主体1外壁之间通过物料暂存斗301连通,物料暂存斗301内壁固定连接有倾斜的暂存挡板3011,参照附图4,倾斜的暂存挡板3011从左上方朝着右下方延伸,并且右下方的边缘部分存在缺口供物料下料;暂存挡板3011与物料暂存斗301内壁形成暂存腔室能够对物料进行存储,能够根据筛分速率以及出料速率的不同进行调节,保证出料的数量,满足需求。Between the upper end of the
在进料装置2包括进料主体204,进料主体204上端固定连接有控制箱203,控制箱203上端固定连接有进料斗201,控制箱203侧壁连通有负压管道202,控制箱203内壁设置有阀组2031用以控制进料斗201导通状态,其中负压管道202外接负压设备,关闭阀组2031后,通过负压管道202能够产生负压带动安装主体1内的气体定向流动;具体为,出料管道3021周围的烟气从该处吸入,依次经过物料输送箱302、物料暂存斗301进入到筛分主体6内,最终流动至负压管道202处实现烟气循环通道;烟气在烟气循环通道内循环的过程当中,大部分烟气能够被破碎后的石膏混合被吸收,烟气中的部分氧化铁烟尘能够被吸附,最终排入渣包内,降低了铁的损失;并且烟气被吸收后能够降低烟气对周围环境的影响,改善作业环境;根据实际加工环境可以在出料管道3021末端安装有可调波纹管道,用于缩短间距,保证石膏投放的准确稳定;在波纹管道的末端安装有倒立设置的漏斗,能够增大末端吸附面积,增强对烟气的吸附效果。The feeding device 2 includes a feeding body 204, the upper end of the feeding body 204 is fixedly connected with a control box 203, the upper end of the control box 203 is fixedly connected with a feed hopper 201, the side wall of the control box 203 is connected with a negative pressure pipeline 202, and the control box 203 The inner wall is provided with a valve group 2031 to control the conduction state of the feed hopper 201, wherein the negative pressure pipeline 202 is externally connected with negative pressure equipment, after closing the valve group 2031, the negative pressure can be generated through the negative pressure pipeline 202 to drive the gas orientation in the installation body 1 Specifically, the flue gas around the discharge pipe 3021 is inhaled from there, passes through the material conveying box 302 and the material temporary storage bucket 301 in turn, enters the screening body 6, and finally flows to the negative pressure pipe 202 to realize the flue gas circulation channel; during the process of flue gas circulation in the flue gas circulation channel, most of the flue gas can be mixed and absorbed by the crushed gypsum, and part of the iron oxide dust in the flue gas can be absorbed and finally discharged into the slag bag, reducing the The loss of iron; and after the flue gas is absorbed, it can reduce the impact of the flue gas on the surrounding environment and improve the working environment; according to the actual processing environment, an adjustable corrugated pipe can be installed at the end of the discharge pipe 3021 to shorten the distance and ensure the delivery of gypsum Accurate and stable; an inverted funnel is installed at the end of the corrugated pipe, which can increase the adsorption area at the end and enhance the adsorption effect on smoke.
这里需要说明的是,其中烟气通道为折弯的U形走向形成U形的烟气循环通道,U形走向的烟气通道能够延长烟气与石膏的接触时间,增大接触面积,提高吸收效果,此时破碎后的石膏颗粒还能够起到吸附剂的作用,用以降低氧化铁烟尘的损失;并且通过螺旋输送叶片303对破碎后的石膏颗粒进行输送,石膏颗粒在螺旋输送叶片303内处于相对填充满的状态,螺旋输送叶片303内石膏在输送的过程当中填充效果好,密度高,进一步提高对烟气吸收的效果。What needs to be explained here is that the flue gas channel is bent U-shaped to form a U-shaped flue gas circulation channel. The U-shaped flue gas channel can prolong the contact time between the flue gas and the gypsum, increase the contact area, and improve the absorption. As a result, the crushed gypsum particles can also act as an adsorbent to reduce the loss of iron oxide fumes; In a relatively full state, the gypsum in the
具体参照附图6;其中抄料组件7朝着第一方向倾斜设置,抄料组件7与筛分主体6之间形成存储区域,抄料组件7为多个且沿着筛分主体6内壁圆周分布,图6中的筛分主体6顺时针转动,抄料组件7倾斜方向与筛分主体6内壁之前形成锐角区域实现对物料的存储,筛分主体6在转动的过程当中大尺寸颗粒的石膏能够位于形成的存储区域内暂存,能够实现石膏的抬升输送,当抄料组件7移动至预定角度位置后,此时石膏能够在重力的作用下自由掉落至破碎装置5之间,实现破碎的上料加工。Specifically refer to accompanying drawing 6; Wherein copying
其中抄料组件7包括第一抄料板701以及第二抄料板704,第一抄料板701与第二抄料板704之间连接有扭力弹性部件,可以选择为扭力弹簧,在第一抄料板701两端边缘部分固定连接有限位套筒702,在第二抄料板704边缘部分固定连接有限位杆703,限位杆703两端贯穿限位套筒702,第二抄料板704与第一抄料板701之间存在间隙,其中第二抄料板704不仅可以围绕着第一抄料板701末端转动,还能够沿着筛分主体6轴线方向线性移动;在限位杆703表面开有控制凸块,限位套筒702内壁开有弯曲的控制凹槽,控制凸起能够在弯曲的控制凹槽内滑动,其中第二抄料板704沿着筛分主体6轴线方向线性移动的过程当中,在控制凸起以及控制凹槽的配合下其能够同步发生转动,通过控制其转动实现石膏的快速下料;在安装主体1内壁设置有用于控制限位杆703移动的控制部件,通过控制部件控制制限位杆703在预定的位置发生移动;制限位杆703在移动前,第二抄料板704处于附图6所示的状态,能够对石膏进行容纳,让其能够抬升至预定的高度;制限位杆703在移动后,能够克服扭力弹性部件力的作用,让第二抄料板704朝着第二方向转动,对石膏的限制消失,石膏滑落至破碎装置5内完成破碎加工。Wherein the copying
作为优选的控制方式;其中控制部件包括第一磁体801以及第二磁体802,根据控制凸起以及控制凹槽的状态决定第一磁体801以及第二磁体802处于吸引或者排斥的状态;其中第一磁体801与限位杆703末端固定连接,第二磁体802通过连接工件与安装主体1内壁固定连接,通过第二磁体802控制第一磁体801的状态以控制限位杆703线性移动,实现控制过程;同样上述控制方式可以选择楔形块等机械方式实现控制过程。As a preferred control method; wherein the control component includes a
最后需要说明的是,筛分主体6根据进料的方向分为第一端以及第二端,第一端为靠近进料装置2的一端,安装主体1内壁具有存储腔室用于容纳筛分主体6的第一端,以形成下降的台阶,保证物料的输送;筛分主体6的第二端固定有倾斜的环形挡板602,环形挡板602中间位置形成通过开口6021用于供破碎装置5通过,通过设置环形挡板602能够对第二端的石膏进行阻挡,限制其移动,以实现循环破碎,并且二者不会发生干涉;筛分主体6整体倾斜设置,靠近进料装置2一侧位置相对较高,以实现物料在转动筛选的过程当中定向输送,提高筛选以及输送的效率。Finally, it should be noted that the
工作原理:将石膏通过进料装置2添加至筛分主体6内,筛分主体6在转动的过程当中能够对石膏进行筛分,符合尺寸要求的石膏掉落至出料装置3内,最终从出料管道3021处排出;尺寸不符合要求的石膏在抄料组件7的作用下能够被抬升至高位,并且在转动的过程当中掉落至破碎装置5内,通过破碎装置5完成对大尺寸石膏的破碎加工。Working principle: Add gypsum to the screening
石膏第一次添加完毕后,调节控制箱203内的阀组2031封闭,此时通过负压管道202能够产生负压带动气体定向流动,在出料管道3021开口周围的烟气能够与物料输送的相反方向进行流动,让烟气能够与内部的石膏进行混合,通过石膏对烟气进行吸收,降低渣包内铁损失的同时降低对周围环境的影响。After the gypsum is added for the first time, the
以上所述仅为本发明的较佳实施例,并不用以限制本发明,凡在本发明的精神和原则之内,所做的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included in the scope of the present invention. within the scope of protection.
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