CN116083815A - Wear-resistant stainless steel and preparation process thereof - Google Patents
Wear-resistant stainless steel and preparation process thereof Download PDFInfo
- Publication number
- CN116083815A CN116083815A CN202310050323.0A CN202310050323A CN116083815A CN 116083815 A CN116083815 A CN 116083815A CN 202310050323 A CN202310050323 A CN 202310050323A CN 116083815 A CN116083815 A CN 116083815A
- Authority
- CN
- China
- Prior art keywords
- content
- stainless steel
- workpiece
- wear
- resistant stainless
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 103
- 239000010935 stainless steel Substances 0.000 title claims abstract description 100
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 44
- 238000010438 heat treatment Methods 0.000 claims abstract description 41
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 35
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000000126 substance Substances 0.000 claims abstract description 21
- 239000011159 matrix material Substances 0.000 claims abstract description 20
- 238000001816 cooling Methods 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- 238000005266 casting Methods 0.000 claims abstract description 6
- 239000012535 impurity Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000002844 melting Methods 0.000 claims abstract description 3
- 238000007599 discharging Methods 0.000 claims abstract 4
- 230000008018 melting Effects 0.000 claims abstract 2
- 238000004881 precipitation hardening Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims 1
- 238000009740 moulding (composite fabrication) Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 47
- 238000005260 corrosion Methods 0.000 description 47
- 239000010949 copper Substances 0.000 description 46
- 239000011651 chromium Substances 0.000 description 35
- 239000000463 material Substances 0.000 description 26
- 230000000052 comparative effect Effects 0.000 description 21
- 229910052750 molybdenum Inorganic materials 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 229910001039 duplex stainless steel Inorganic materials 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000007550 Rockwell hardness test Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- UFGZSIPAQKLCGR-UHFFFAOYSA-N chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910003470 tongbaite Inorganic materials 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
技术领域technical field
本申请涉及不锈钢领域,尤其是涉及一种耐磨不锈钢及其制备工艺。The present application relates to the field of stainless steel, in particular to a wear-resistant stainless steel and a preparation process thereof.
背景技术Background technique
双相不锈钢指具有铁素体与奥氏体两种基体,一般较少相的含量最少也需要达到30%的不锈钢。在含C较低的情况下,Cr含量在18%-28%,Ni含量在3%-10%。有些钢还含有Mo、Cu、Nb、Ti、N等合金元素。该类钢兼有奥氏体和铁素体不锈钢的特点,与铁素体相比,塑性、韧性更高,无室温脆性,耐晶间腐蚀性能和焊接性能均显著提高,同时还保持有铁素体不锈钢的475℃脆性以及导热系数高,具有超塑性等特点。与奥氏体不锈钢相比,强度高且耐晶间腐蚀和耐氯化物应力腐蚀有明显提高。双相不锈钢具有优良的耐孔蚀性能,也是一种节镍不锈钢。Duplex stainless steel refers to stainless steel with ferrite and austenite matrix, and the content of less phase generally needs to reach at least 30%. In the case of low C content, the Cr content is 18%-28%, and the Ni content is 3%-10%. Some steels also contain alloying elements such as Mo, Cu, Nb, Ti, and N. This type of steel has the characteristics of both austenitic and ferritic stainless steels. Compared with ferrite, it has higher plasticity and toughness, no room temperature brittleness, significantly improved intergranular corrosion resistance and welding performance, while maintaining iron The body stainless steel is brittle at 475°C, has high thermal conductivity, and has the characteristics of superplasticity. Compared with austenitic stainless steel, it has high strength and significantly improved resistance to intergranular corrosion and chloride stress corrosion. Duplex stainless steel has excellent pitting corrosion resistance and is also a nickel-saving stainless steel.
由于两相组织的特点,通过正确控制化学成分和热处理工艺,使双相不锈钢兼有铁素体不锈钢和奥氏体不锈钢的优点,它将奥氏体不锈钢所具有的优良韧性和焊接性与铁素体不锈钢所具有的较高强度和耐氯化物应力腐蚀性能结合在一起。Due to the characteristics of the two-phase structure, through the correct control of the chemical composition and heat treatment process, the duplex stainless steel has the advantages of both ferritic stainless steel and austenitic stainless steel. It combines the excellent toughness and weldability of austenitic stainless steel with iron The higher strength and chloride stress corrosion resistance of ferritic stainless steels are combined.
但现有的不锈钢,通常比较重视耐腐蚀性能,为了保持其耐腐蚀性能处于较高值,通常会增加耐腐蚀的元素,从而导致不锈钢的耐磨性能会有所降低,当不锈钢在恶劣工况中使用时,不锈钢仅能耐住恶劣工况带来的腐蚀,而不能耐住恶劣工况对不锈钢的磨损,导致不锈钢损坏。However, the existing stainless steel usually pays more attention to corrosion resistance. In order to maintain its corrosion resistance at a high value, corrosion-resistant elements are usually added, resulting in a decrease in the wear resistance of stainless steel. When stainless steel is used in harsh working conditions When used in the environment, stainless steel can only withstand the corrosion caused by harsh working conditions, but cannot withstand the wear and tear on stainless steel caused by harsh working conditions, resulting in damage to stainless steel.
发明内容Contents of the invention
为了提高不锈钢的耐磨强度,本申请提供一种耐磨不锈钢及其制备工艺。In order to improve the wear-resistant strength of stainless steel, the application provides a wear-resistant stainless steel and a preparation process thereof.
第一方面,本申请提供一种耐磨不锈钢,采用如下的技术方案:In the first aspect, the present application provides a kind of wear-resistant stainless steel, adopting the following technical scheme:
一种耐磨不锈钢,耐磨不锈钢按质量百分比包括以下物质:A wear-resistant stainless steel, the wear-resistant stainless steel includes the following substances by mass percentage:
C含量为0.08%以下;C content is less than 0.08%;
Si含量为1.0%以下;Si content is less than 1.0%;
Mn含量为1.0%-3.0%;Mn content is 1.0%-3.0%;
P含量为0.035%以下;P content is below 0.035%;
S含量为0.030%以下;The S content is below 0.030%;
Cu含量为1.5%-2.8%;Cu content is 1.5%-2.8%;
Cr含量为23.0%-27.0%;The Cr content is 23.0%-27.0%;
Mo含量为2.0%-4.0%;Mo content is 2.0%-4.0%;
Ni含量为4.0%-9.0%;Ni content is 4.0%-9.0%;
余量为Fe和不可避免的杂质;The balance is Fe and unavoidable impurities;
显微组织为铁素体和奥氏体为基体,经热处理后还含有析出硬化相。The microstructure is ferrite and austenite as the matrix, and it also contains precipitation hardening phase after heat treatment.
通过采用上述技术方案,Cr、Mo、Ni是不锈钢中影响耐腐蚀性能的关键元素,三种元素的含量不同时,对于双相不锈钢的耐腐蚀性能和耐磨性能均有不同的影响,当Cr和Mo元素的含量提高时,铁素体和奥氏体的耐腐蚀性能会逐渐提高,而Ni元素含量提高时,铁素体的耐腐蚀性能会逐渐提高,奥氏体的耐腐蚀性能会逐渐降低,所以Ni含量需要找到一个最佳点,使得铁素体和奥氏体的耐腐蚀性能较为平衡;在不降低腐蚀性能的情况下大大增强耐磨蚀能力,解决了既要耐腐又需高耐磨的恶劣工况中材料使用问题;C也是决定材料耐腐蚀性能的主要因素,C含量越高,材料的耐腐蚀性能越差,C含量越低,材料的成本就会高,因此取了性价比比较高的含量,不大于0.08%;Si加入,可以提高钢水浇铸的脱氧性能,但过高的Si含量,会影响材料的塑性以及耐腐蚀性能;P、S在不锈钢里面属于有害元素,对材料的塑性以及耐耐腐蚀性能都有明显的影响,为成本考虑把它们分别要求.不大于0.035%和0.030%。By adopting the above technical scheme, Cr, Mo, and Ni are the key elements affecting the corrosion resistance of stainless steel. When the contents of the three elements are different, they have different effects on the corrosion resistance and wear resistance of duplex stainless steel. When Cr When the content of Ni and Mo elements increases, the corrosion resistance of ferrite and austenite will gradually increase, and when the content of Ni element increases, the corrosion resistance of ferrite will gradually increase, and the corrosion resistance of austenite will gradually increase. Therefore, the Ni content needs to find an optimal point, so that the corrosion resistance of ferrite and austenite is relatively balanced; the corrosion resistance is greatly enhanced without reducing the corrosion performance, and it solves the problem of both corrosion resistance and corrosion resistance. The use of materials in harsh working conditions with high wear resistance; C is also the main factor determining the corrosion resistance of materials. The higher the C content, the worse the corrosion resistance of the material, and the lower the C content, the higher the cost of the material. The cost-effective content is not more than 0.08%. The addition of Si can improve the deoxidation performance of molten steel casting, but too high Si content will affect the plasticity and corrosion resistance of the material; P and S are harmful elements in stainless steel. It has a significant impact on the plasticity and corrosion resistance of the material, and they are required to be no more than 0.035% and 0.030% respectively for cost considerations.
优选的,所述耐磨不锈钢还包括RE,RE含量为0.10%以下。Preferably, the wear-resistant stainless steel also includes RE, and the RE content is less than 0.10%.
通过采用上述技术方案,RE主要的功能是增加奥氏体量,细化晶粒,提高不锈钢的综合力学性能,尤其是提高热处理后不锈钢的硬度,以及不锈钢硬度提高后的材料塑性。By adopting the above technical scheme, the main function of RE is to increase the amount of austenite, refine the grains, and improve the comprehensive mechanical properties of stainless steel, especially the hardness of stainless steel after heat treatment, and the plasticity of the material after the hardness of stainless steel is increased.
优选的,所述铁素体的含量为50%-70%,所述奥氏体的含量为30%-50%,经热处理后析出硬化相的含量为5%-10%。Preferably, the content of the ferrite is 50%-70%, the content of the austenite is 30%-50%, and the content of the precipitation hardened phase after heat treatment is 5%-10%.
通过采用上述技术方案,铁素体能够对S、P、Si元素进行溶解,防止元素的偏析和形成低熔点共晶,从而阻止凝固裂纹产生,铁素体的存在也可以打乱单一奥氏体组织的方向性,从而避免贫Cr层贯穿于晶粒之间构成腐蚀介质的集中通道;δ相铁素体富Cr,碳化铬可优先在δ相边缘沉淀,不会在奥氏体晶粒表面形成贫铬层,从而也有利于提高焊缝的抗晶间腐蚀性能;但是当铁素体的含量过多时,材料的强度、延展性等力学性能会降低,使得材料更脆且韧性较差,容易产生裂纹,且过多的铁素体会影响奥氏体的抗腐蚀性能,使得材料的抗腐蚀性能下降,本申请通过对各元素含量的控制,从而控制铁素体与奥氏体的含量,较好地平衡了铁素体和奥氏体之间的相比例,使不锈钢具有更佳的耐腐蚀性及更高的强度。By adopting the above technical scheme, ferrite can dissolve S, P, and Si elements, prevent element segregation and form low-melting eutectics, thereby preventing solidification cracks, and the existence of ferrite can also disrupt single austenite The directionality of the structure, so as to avoid the concentrated channel of the corrosive medium formed by the poor Cr layer running through the grains; the δ phase ferrite is rich in Cr, and chromium carbide can preferentially precipitate at the edge of the δ phase, and will not be on the surface of the austenite grains The formation of a chromium-poor layer is also beneficial to improve the intergranular corrosion resistance of the weld; but when the ferrite content is too much, the mechanical properties such as strength and ductility of the material will be reduced, making the material more brittle and less tough. Cracks are easy to occur, and too much ferrite will affect the corrosion resistance of austenite, which will reduce the corrosion resistance of the material. This application controls the content of ferrite and austenite by controlling the content of each element. The phase ratio between ferrite and austenite is better balanced, so that stainless steel has better corrosion resistance and higher strength.
优选的,所述Cr含量为24.0%-26.0%。Preferably, the Cr content is 24.0%-26.0%.
通过采用上述技术方案,Cr是形成主要的铁素体基体元素,为确保材料的铁素体基体不小于50%以及耐腐蚀性能的要求,因此进一步限定Cr的含量,把Cr的含量定于不小于24%,又因为如果Cr的含量超过27%,则铁素体基体会大于70%,所以为了保证铁素体基体小于70%,因此把Cr的含量进一步限定于不大于26%。By adopting the above technical scheme, Cr is the main ferrite matrix element, in order to ensure that the ferrite matrix of the material is not less than 50% and the requirements of corrosion resistance, the content of Cr is further limited, and the content of Cr is set at no It is less than 24%, and because if the content of Cr exceeds 27%, the ferrite matrix will be greater than 70%, so in order to ensure that the ferrite matrix is less than 70%, the content of Cr is further limited to not more than 26%.
优选的,所述Mo含量为2.5%-3.5%。Preferably, the Mo content is 2.5%-3.5%.
通过采用上述技术方案,Mo是形成铁素体基体次要元素,而加入Mo可以明显提高材料的耐腐蚀性能,尤其能提高在含有氯离子的酸性介质中腐蚀性能,为了考虑材料的性价比,因此把Mo含量控制在2.5%-3.5%。By adopting the above technical scheme, Mo is a secondary element to form the ferrite matrix, and the addition of Mo can significantly improve the corrosion resistance of the material, especially in the acidic medium containing chloride ions. In order to consider the cost performance of the material, therefore Control the Mo content at 2.5%-3.5%.
优选的,所述Ni含量为5.0%-8.0%。Preferably, the Ni content is 5.0%-8.0%.
通过采用上述技术方案,Ni是形成主要的奥素体基体元素,提高耐酸的腐蚀性能,且提高材料的塑性,从而提高材料的硬度,并且为确保奥素体基体在30%-50%之间,把Ni含量控制在5.0%-8.0%。By adopting the above technical scheme, Ni is the main element for forming the austenitic matrix, improving the corrosion resistance of acid, and improving the plasticity of the material, thereby improving the hardness of the material, and in order to ensure that the australoid matrix is between 30% and 50% , the Ni content is controlled at 5.0%-8.0%.
优选的,所述Mn含量为1.5%-2.5%。Preferably, the Mn content is 1.5%-2.5%.
通过采用上述技术方案,Mn是形成奥素体基体元素次要元素,加入1.5%-2.5%的Mn与Ni配合形成奥素体基体,提高材料的性价比。By adopting the above-mentioned technical scheme, Mn is a secondary element for forming the matrix element of the australite, and adding 1.5%-2.5% of Mn cooperates with Ni to form the matrix of the australite, thereby improving the cost performance of the material.
优选的,所述Cu含量为1.8%-2.5%。Preferably, the Cu content is 1.8%-2.5%.
通过采用上述技术方案,Cu提高不锈钢对酸的耐腐蚀性,尤其是耐硫酸的腐蚀,当Cu含量小于1.5%时,耐酸的腐蚀性能有明显的下降,而大于2.8%时,材料经过热处理后的塑性会明显变差,导致不锈钢的硬度降低,复杂的零件易开裂,因此综合考虑把Cu范围定在1.8%-2.5%,使得不锈钢的耐腐蚀性和硬度均较好。By adopting the above technical scheme, Cu improves the corrosion resistance of stainless steel to acid, especially the corrosion resistance to sulfuric acid. When the Cu content is less than 1.5%, the acid corrosion performance is significantly reduced, and when it is greater than 2.8%, the material after heat treatment The plasticity of copper will be significantly worse, resulting in a decrease in the hardness of stainless steel, and complex parts are easy to crack. Therefore, considering the range of Cu at 1.8%-2.5%, the corrosion resistance and hardness of stainless steel are both better.
第二方面,本申请提供一种耐磨不锈钢的制备工艺,采用如下的技术方案:In the second aspect, the present application provides a preparation process of wear-resistant stainless steel, which adopts the following technical scheme:
一种耐磨不锈钢的制备工艺,包括以下步骤:A preparation process of wear-resistant stainless steel, comprising the following steps:
步骤1:工件浇铸成型,将Fe高温融化成铁水,然后将计量准确的C、Si、Mn、P、S、Cu、Cr、Mo、Ni和RE各元素加入至融化的铁水中,混合均匀后浇铸至模具中,冷却成型后制得工件;Step 1: The workpiece is cast and molded, and Fe is melted into molten iron at high temperature, and then accurately measured elements such as C, Si, Mn, P, S, Cu, Cr, Mo, Ni and RE are added to the molten iron, and mixed evenly Casting into the mould, cooling and molding to obtain the workpiece;
步骤2:工件热处理,将箱式电炉预热,温度不高于200℃,然后将工件放入箱式电炉中,将箱式电炉温度升温至1000-1200℃后,保温2-3小时,然后直接将工件出炉下水冷却,时间控制在30秒以内,冷却后的工件再次进炉,直接升温至790-830℃后,保温1-2小时,最后工件出炉于空气中冷却至室温,制得耐磨不锈钢。Step 2: heat treatment of the workpiece, preheat the box-type electric furnace, the temperature is not higher than 200°C, then put the workpiece into the box-type electric furnace, raise the temperature of the box-type electric furnace to 1000-1200°C, keep it warm for 2-3 hours, and then Take the workpiece directly out of the furnace and cool it in water, and the time is controlled within 30 seconds. The cooled workpiece is put into the furnace again, and the temperature is directly raised to 790-830°C, and it is kept for 1-2 hours. Finally, the workpiece is cooled to room temperature in the air, and the resistant Grind stainless steel.
通过采用上述技术方案,本申请根据各元素的含量,制定了最适合本申请的热处理步骤,通过控制首次加热控制温度、回火温度、保温时间以及冷却的速率,从而提高成型后不锈钢的硬度,提高产品的塑性。By adopting the above-mentioned technical scheme, this application formulates the heat treatment steps most suitable for this application according to the content of each element, and by controlling the first heating control temperature, tempering temperature, holding time and cooling rate, thereby improving the hardness of the formed stainless steel, Improve the plasticity of the product.
综上所述,本申请具有如下有益效果:In summary, the application has the following beneficial effects:
1、由于本申请通过对元素C、Cr、Ni、Mo、Mn、Cu含量的控制,使得铁素体和奥氏体处于较为平衡的比例,使得在不锈钢既有较好的耐腐蚀性能,还提高了不锈钢的硬度,大大增强了不锈钢的耐磨蚀能力,解决了既要耐腐又需高耐磨的恶劣工况中材料使用问题。1. Because this application controls the content of elements C, Cr, Ni, Mo, Mn, and Cu, the ferrite and austenite are in a relatively balanced ratio, so that stainless steel has both good corrosion resistance and good corrosion resistance. The hardness of stainless steel is improved, the corrosion resistance of stainless steel is greatly enhanced, and the problem of using materials in harsh working conditions that require both corrosion resistance and high wear resistance is solved.
2、本申请中还加入元素RE,增加奥氏体量,细化晶粒,提高不锈钢的综合力学性能,尤其是提高热处理后不锈钢的硬度,以及不锈钢硬度提高后的材料塑性。2. In this application, element RE is also added to increase the amount of austenite, refine grains, and improve the comprehensive mechanical properties of stainless steel, especially the hardness of stainless steel after heat treatment, and the plasticity of the material after the hardness of stainless steel is improved.
3、本申请的方法,控制首次加热控制温度、回火温度、保温时间以及冷却的速率,从而提高成型后不锈钢的硬度,提高产品的塑性。3. The method of this application controls the first heating control temperature, tempering temperature, holding time and cooling rate, thereby increasing the hardness of the stainless steel after forming and improving the plasticity of the product.
具体实施方式Detailed ways
实施例Example
实施例1Example 1
一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为24.2%;Mo含量为2.6%;Ni含量为5.5%;RE含量为0.1%;余量为Fe和不可避免的杂质;A wear-resistant stainless steel, which comprises the following substances in terms of mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; S content is 0.020%; Cu content is 2.0%; Cr content is 24.2%; Mo content is 2.6%; Ni content is 5.5%; RE content is 0.1%; the balance is Fe and unavoidable impurities;
一种耐磨不锈钢的制备工艺,包括以下步骤:A preparation process of wear-resistant stainless steel, comprising the following steps:
步骤1:工件浇铸成型,将Fe高温融化成铁水,然后将计量准确的C、Si、Mn、P、S、Cu、Cr、Mo、Ni和RE各元素加入至融化的铁水中,混合均匀后浇铸至模具中,冷却成型后制得工件;Step 1: The workpiece is cast and molded, and Fe is melted into molten iron at high temperature, and then accurately measured elements such as C, Si, Mn, P, S, Cu, Cr, Mo, Ni and RE are added to the molten iron, and mixed evenly Casting into the mould, cooling and molding to obtain the workpiece;
步骤2:工件热处理,将箱式电炉预热,温度不高于200℃,然后将工件放入箱式电炉中,将箱式电炉温度升温至1000-1200℃后,保温2-3小时,然后直接将工件出炉下水冷却,时间控制在30秒以内,冷却后的工件再次进炉,直接升温至790-830℃后,保温1-2小时,最后工件出炉于空气中冷却至室温,制得耐磨不锈钢Step 2: heat treatment of the workpiece, preheat the box-type electric furnace, the temperature is not higher than 200°C, then put the workpiece into the box-type electric furnace, raise the temperature of the box-type electric furnace to 1000-1200°C, keep it warm for 2-3 hours, and then Take the workpiece directly out of the furnace and cool it in water, and the time is controlled within 30 seconds. The cooled workpiece is put into the furnace again, and the temperature is directly raised to 790-830°C, and it is kept for 1-2 hours. Finally, the workpiece is cooled to room temperature in the air, and the resistant Grinding stainless steel
步骤2:工件热处理,将箱式电炉预热,温度150℃,然后将工件放入箱式电炉中,将温度升温至1080℃后,保温2.5小时,然后直接将工件出炉下水冷却,时间控制在30秒以内,冷却后的工件再次进炉,直接升温至810℃后,保温1.5小时,最后工件出炉于空气中冷却至室温,制得耐磨不锈钢;Step 2: Heat treatment of the workpiece, preheat the box-type electric furnace at a temperature of 150°C, then put the workpiece into the box-type electric furnace, raise the temperature to 1080°C, keep it warm for 2.5 hours, and then directly take the workpiece out of the furnace and put it in water to cool, the time is controlled at Within 30 seconds, the cooled workpiece is put into the furnace again, directly heated to 810°C, and kept for 1.5 hours, and finally the workpiece is released from the furnace and cooled to room temperature in the air to produce wear-resistant stainless steel;
所制得的耐磨不锈钢的铁素体的含量为54%,奥氏体的含量为46%,经热处理后析出硬化相的含量为7.9%。The prepared wear-resistant stainless steel has a ferrite content of 54%, an austenite content of 46%, and a precipitation hardening phase content of 7.9% after heat treatment.
实施例2Example 2
实施例2与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为25.8%;Mo含量为2.6%;Ni含量为5.5%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为67%,奥氏体的含量为33%,经热处理后析出硬化相的含量为8.2%。The difference between embodiment 2 and embodiment 1 is: a kind of wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 25.8%; the content of Mo is 2.6%; the content of Ni is 5.5%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 67%, the austenite content is 33%, and the precipitation hardening phase content after heat treatment is 8.2%.
实施例3Example 3
实施例3与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为25.0%;Mo含量为2.6%;Ni含量为5.5%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为62%,奥氏体的含量为38%,经热处理后析出硬化相的含量为7.9%。The difference between embodiment 3 and embodiment 1 is: a kind of wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 25.0%; the content of Mo is 2.6%; the content of Ni is 5.5%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 62%, the austenite content is 38%, and the precipitation hardening phase content after heat treatment is 7.9%.
实施例4Example 4
实施例4与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为25.0%;Mo含量为3.5%;Ni含量为5.5%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为64%,奥氏体的含量为36%,经热处理后析出硬化相的含量为8.0%。The difference between embodiment 4 and embodiment 1 is: a kind of wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 25.0%; the content of Mo is 3.5%; the content of Ni is 5.5%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 64%, the austenite content is 36%, and the precipitation hardening phase content after heat treatment is 8.0%.
实施例5Example 5
实施例5与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为25.0%;Mo含量为3.1%;Ni含量为5.5%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为63.4%,奥氏体的含量为36.6%,经热处理后析出硬化相的含量为7.9%。The difference between embodiment 5 and embodiment 1 is: a kind of wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 25.0%; the content of Mo is 3.1%; the content of Ni is 5.5%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 63.4%, the austenite content is 36.6%, and the precipitation hardening phase content after heat treatment is 7.9%.
实施例6Example 6
实施例6与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为25.0%;Mo含量为3.1%;Ni含量为7.8%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为56.1%,奥氏体的含量为43.9%,经热处理后析出硬化相的含量为8.2%。The difference between embodiment 6 and embodiment 1 is: a kind of wear-resistant stainless steel, which includes the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; S The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 25.0%; the content of Mo is 3.1%; the content of Ni is 7.8%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 56.1%, the austenite content is 43.9%, and the precipitation hardening phase content after heat treatment is 8.2%.
实施例7Example 7
实施例7与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为25.0%;Mo含量为3.1%;Ni含量为6.7%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为58.5%,奥氏体的含量为41.5%,经热处理后析出硬化相的含量为8.1%。The difference between embodiment 7 and embodiment 1 is: a kind of wear-resistant stainless steel, which includes the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 25.0%; the content of Mo is 3.1%; the content of Ni is 6.7%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 58.5%, the austenite content is 41.5%, and the precipitation hardening phase content after heat treatment is 8.1%.
实施例8Example 8
实施例8与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为2.45%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为25.0%;Mo含量为3.1%;Ni含量为6.7%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为59.2%,奥氏体的含量为40.8%,经热处理后析出硬化相的含量为8.2%。The difference between embodiment 8 and embodiment 1 is: a kind of wear-resistant stainless steel, which includes the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 2.45%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 25.0%; the content of Mo is 3.1%; the content of Ni is 6.7%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 59.2%, the austenite content is 40.8%, and the precipitation hardening phase content after heat treatment is 8.2%.
实施例9Example 9
实施例9与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为2.05%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为25.0%;Mo含量为3.1%;Ni含量为6.7%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为60.8%,奥氏体的含量为39.2%,经热处理后析出硬化相的含量为8.3%。The difference between embodiment 9 and embodiment 1 is: a wear-resistant stainless steel, which includes the following substances in terms of mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 2.05%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 25.0%; the content of Mo is 3.1%; the content of Ni is 6.7%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 60.8%, the austenite content is 39.2%, and the precipitation hardening phase content after heat treatment is 8.3%.
实施例10Example 10
实施例10与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为2.05%;P含量为0.030%;S含量为0.020%;Cu含量为2.4%;Cr含量为25.0%;Mo含量为3.1%;Ni含量为6.7%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为63.1%,奥氏体的含量为36.9%,经热处理后析出硬化相的含量为8.3%。The difference between Example 10 and Example 1 is: a wear-resistant stainless steel, which includes the following substances in terms of mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 2.05%; P content is 0.030%; S The content of Cu is 0.020%; the content of Cu is 2.4%; the content of Cr is 25.0%; the content of Mo is 3.1%; the content of Ni is 6.7%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 63.1%, the austenite content is 36.9%, and the precipitation hardening phase content after heat treatment is 8.3%.
实施例11Example 11
实施例11与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为2.05%;P含量为0.030%;S含量为0.020%;Cu含量为2.2%;Cr含量为25.0%;Mo含量为3.1%;Ni含量为6.7%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为61.1%,奥氏体的含量为38.9%,经热处理后析出硬化相的含量为8.2%。The difference between Example 11 and Example 1 is: a wear-resistant stainless steel, which includes the following substances in terms of mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 2.05%; P content is 0.030%; S The content of Cu is 0.020%; the content of Cu is 2.2%; the content of Cr is 25.0%; the content of Mo is 3.1%; the content of Ni is 6.7%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 61.1%, the austenite content is 38.9%, and the precipitation hardening phase content after heat treatment is 8.2%.
对比例comparative example
对比例1Comparative example 1
对比例1与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为22.0%;Mo含量为2.6%;Ni含量为5.5%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为46%,奥氏体的含量为54%,经热处理后析出硬化相的含量为7.2%。The difference between Comparative Example 1 and Example 1 is: a wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 22.0%; the content of Mo is 2.6%; the content of Ni is 5.5%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 46%, the austenite content is 54%, and the precipitation hardening phase content after heat treatment is 7.2%.
对比例2Comparative example 2
对比例2与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为28%;Mo含量为2.6%;Ni含量为5.5%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为72%,奥氏体的含量为28%,经热处理后析出硬化相的含量为8.6%。The difference between Comparative Example 2 and Example 1 is: a wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 28%; the content of Mo is 2.6%; the content of Ni is 5.5%; the content of RE is 0.1%; the balance is Fe and unavoidable impurities; The ferrite content of ground stainless steel is 72%, the austenite content is 28%, and the precipitation hardening phase content after heat treatment is 8.6%.
对比例3Comparative example 3
对比例3与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为24.2%;Mo含量为2.6%;Ni含量为3.0%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为74%,奥氏体的含量为26%,经热处理后析出硬化相的含量为8.3%。The difference between Comparative Example 3 and Example 1 is: a wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; S The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 24.2%; the content of Mo is 2.6%; the content of Ni is 3.0%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 74%, the austenite content is 26%, and the precipitation hardening phase content after heat treatment is 8.3%.
对比例4Comparative example 4
对比例4与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为2.0%;Cr含量为24.2%;Mo含量为2.6%;Ni含量为10.0%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为43%,奥氏体的含量为57%,经热处理后析出硬化相的含量为8.5%。The difference between Comparative Example 4 and Example 1 is: a wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; S The content of Cu is 0.020%; the content of Cu is 2.0%; the content of Cr is 24.2%; the content of Mo is 2.6%; the content of Ni is 10.0%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 43%, the austenite content is 57%, and the precipitation hardening phase content after heat treatment is 8.5%.
对比例5Comparative example 5
对比例5与实施例1的区别在于:未添加元素RE。The difference between Comparative Example 5 and Example 1 is that no element RE is added.
对比例6Comparative example 6
对比例6与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为1.0%;Cr含量为24.2%;Mo含量为2.6%;Ni含量为5.5%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为54%,奥氏体的含量为46%,经热处理后析出硬化相的含量为7.9%。The difference between Comparative Example 6 and Example 1 is: a wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; S The content of Cu is 0.020%; the content of Cu is 1.0%; the content of Cr is 24.2%; the content of Mo is 2.6%; the content of Ni is 5.5%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 54%, the austenite content is 46%, and the precipitation hardening phase content after heat treatment is 7.9%.
对比例7Comparative example 7
对比例7与实施例1的区别在于:一种耐磨不锈钢,其按质量百分比包括以下物质:C含量为0.06%;Si含量为0.8%;Mn含量为1.65%;P含量为0.030%;S含量为0.020%;Cu含量为3.0%;Cr含量为24.2%;Mo含量为2.6%;Ni含量为10.0%;RE含量为0.1%;余量为Fe和不可避免的杂质;所制得的耐磨不锈钢的铁素体的含量为54%,奥氏体的含量为46%,经热处理后析出硬化相的含量为7.9%。The difference between comparative example 7 and embodiment 1 is: a kind of wear-resistant stainless steel, which comprises the following substances by mass percentage: C content is 0.06%; Si content is 0.8%; Mn content is 1.65%; P content is 0.030%; The content of Cu is 0.020%; the content of Cu is 3.0%; the content of Cr is 24.2%; the content of Mo is 2.6%; the content of Ni is 10.0%; the content of RE is 0.1%; The ferrite content of ground stainless steel is 54%, the austenite content is 46%, and the precipitation hardening phase content after heat treatment is 7.9%.
性能检测试验performance test
试验1:Test 1:
1、热处理后硬度:根据GB/T230.1-2018《金属材料.洛氏硬度试验第1部分:试验方法》对实施例1-11和对比例1-5所制得的产品进行热处理后硬度的测试,从而检测产品的耐磨性能。1. Hardness after heat treatment: according to GB/T230.1-2018 "Metallic Materials. Rockwell Hardness Test Part 1: Test Method", the hardness after heat treatment of the products prepared in Examples 1-11 and Comparative Examples 1-5 The test, so as to detect the wear resistance of the product.
2、耐腐蚀性能:根据JB/T7901-1999《金属材料实验室均匀腐蚀全浸试方法》,以浓度为10%的硫酸,试验温度为80℃,对实施例1-11和对比例1-5所制得的产品进行耐腐蚀性能的测试。2. Corrosion resistance: According to JB/T7901-1999 "Metal Material Laboratory Uniform Corrosion Full Immersion Test Method", with a concentration of 10% sulfuric acid, the test temperature is 80 ° C, for examples 1-11 and comparative examples 1- 5 The prepared product is tested for corrosion resistance.
结合实施例1-5和对比例1-2并结合表1可以看出,Cr是形成主要的铁素体基体元素,为确保材料的铁素体基体处于50%-70%,使得不锈钢的耐腐蚀性能和硬度更好,并且当实施例3中Cr的含量,使铁素体处于最佳的比例,而Mo是形成铁素体基体次要元素,加入Mo可以明显提高材料的耐腐蚀性能,结合综合考虑,实施例5中的元素Cr和Mo的含量最佳。Combining Examples 1-5 and Comparative Examples 1-2 and Table 1, it can be seen that Cr is the main ferrite matrix element, in order to ensure that the ferrite matrix of the material is at 50%-70%, so that the resistance of stainless steel The corrosion performance and hardness are better, and when the content of Cr in Example 3 makes the ferrite in the best ratio, and Mo is a secondary element to form the ferrite matrix, adding Mo can obviously improve the corrosion resistance of the material, Taking into account the overall consideration, the content of elements Cr and Mo in Example 5 is the best.
结合实施例6-9和对比例3-5并结合表1可以看出,Ni是形成主要的奥素体基体元素,为确保奥素体基体在30%-50%之间,提高耐酸的腐蚀性能,且提高材料的塑性,从而提高材料的硬度,实施例7中Ni的含量最佳,而Mn是形成奥素体基体元素次要元素,Mn与Ni配合形成奥素体基体,提高材料的性价比,结合综合考虑,实施例9中的元素Mn与Ni的含量最佳;根据对比例5可看出,RE主要的功能是增加奥氏体量,细化晶粒,提高不锈钢的综合力学性能,尤其是提高热处理后不锈钢的硬度,以及不锈钢硬度提高后的材料塑性。。In combination with Examples 6-9 and Comparative Examples 3-5 and in conjunction with Table 1, it can be seen that Ni is the main austenitic matrix element to form, and in order to ensure that the australite matrix is between 30%-50%, it is necessary to improve the corrosion resistance of acid performance, and improve the plasticity of the material, thereby improving the hardness of the material, the content of Ni is the best in Example 7, and Mn is a secondary element that forms the austenitic matrix element, and Mn cooperates with Ni to form the australoid matrix to improve the hardness of the material Cost performance, combined with comprehensive consideration, the content of elements Mn and Ni in Example 9 is the best; according to Comparative Example 5, it can be seen that the main function of RE is to increase the amount of austenite, refine the grain, and improve the comprehensive mechanical properties of stainless steel , especially to improve the hardness of stainless steel after heat treatment, and the plasticity of the material after the hardness of stainless steel is improved. .
结合实施例10-11和对比例6-7并结合表1可以看出,Cu可有效提高不锈钢的耐腐蚀性,当Cu含量小于1.8%时,耐酸的腐蚀性能有明显的下降,而大于2.5%时,材料经过热处理后的塑性会明显变差,导致不锈钢的硬度降低,并且实施例11中的Cu含量,可使得不锈钢的耐腐蚀性和硬度均较好。In combination with Examples 10-11 and Comparative Examples 6-7 and in combination with Table 1, it can be seen that Cu can effectively improve the corrosion resistance of stainless steel. When the Cu content is less than 1.8%, the acid-resistant corrosion performance has a significant decline, while it is greater than 2.5%. %, the plasticity of the material after heat treatment will obviously deteriorate, resulting in a decrease in the hardness of the stainless steel, and the Cu content in Example 11 can make the corrosion resistance and hardness of the stainless steel better.
本具体实施例仅仅是对本申请的解释,其并不是对本申请的限制,本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改,但只要在本申请的77权利要求范围内都受到专利法的保护。This specific embodiment is only an explanation of this application, and it is not a limitation of this application. Those skilled in the art can make modifications to this embodiment without creative contribution according to needs after reading this specification, but as long as the 77th paragraph of this application All claims are protected by patent law.
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202310050323.0A CN116083815A (en) | 2023-02-01 | 2023-02-01 | Wear-resistant stainless steel and preparation process thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202310050323.0A CN116083815A (en) | 2023-02-01 | 2023-02-01 | Wear-resistant stainless steel and preparation process thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN116083815A true CN116083815A (en) | 2023-05-09 |
Family
ID=86207895
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202310050323.0A Pending CN116083815A (en) | 2023-02-01 | 2023-02-01 | Wear-resistant stainless steel and preparation process thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN116083815A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN119340568A (en) * | 2024-12-18 | 2025-01-21 | 深圳市豪鹏科技股份有限公司 | A wound button battery and an electroacoustic device |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4390367A (en) * | 1980-06-25 | 1983-06-28 | Mannesmann Aktiengesellschaft | High-alloyed steel being resistive to corrosion by natural gas |
CN1571861A (en) * | 2001-09-02 | 2005-01-26 | 山特维克公司 | Use of a duplex steel alloy |
CN105839024A (en) * | 2016-05-06 | 2016-08-10 | 泰州金东方特钢制造有限公司 | Heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material for garbage power station fire grate and preparing method of heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material |
CN108220813A (en) * | 2018-03-29 | 2018-06-29 | 东北大学 | A kind of spy's super-duplex stainless steel and its alloying component optimum design method |
CN109642282A (en) * | 2016-09-02 | 2019-04-16 | 杰富意钢铁株式会社 | Two phase stainless steel and its manufacturing method |
CN116652170A (en) * | 2023-07-10 | 2023-08-29 | 太原理工大学 | Duplex stainless steel and additive manufacturing method thereof |
-
2023
- 2023-02-01 CN CN202310050323.0A patent/CN116083815A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4390367A (en) * | 1980-06-25 | 1983-06-28 | Mannesmann Aktiengesellschaft | High-alloyed steel being resistive to corrosion by natural gas |
CN1571861A (en) * | 2001-09-02 | 2005-01-26 | 山特维克公司 | Use of a duplex steel alloy |
CN105839024A (en) * | 2016-05-06 | 2016-08-10 | 泰州金东方特钢制造有限公司 | Heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material for garbage power station fire grate and preparing method of heat-resistant, abrasion-resistant and corrosion-resistant duplex stainless steel casting alloy material |
CN109642282A (en) * | 2016-09-02 | 2019-04-16 | 杰富意钢铁株式会社 | Two phase stainless steel and its manufacturing method |
CN108220813A (en) * | 2018-03-29 | 2018-06-29 | 东北大学 | A kind of spy's super-duplex stainless steel and its alloying component optimum design method |
CN116652170A (en) * | 2023-07-10 | 2023-08-29 | 太原理工大学 | Duplex stainless steel and additive manufacturing method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN119340568A (en) * | 2024-12-18 | 2025-01-21 | 深圳市豪鹏科技股份有限公司 | A wound button battery and an electroacoustic device |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6415453B2 (en) | High corrosion resistance high strength Al-containing weathering steel sheet and method for producing the same | |
WO2020020034A1 (en) | High-strength and high-corrosion-resistance nickel-saving austenitic stainless steel and manufacturing method therefor | |
WO2021036271A1 (en) | High-temperature-resistant 400hb wear-resistant steel plate and method for production thereof | |
CN102560258A (en) | Low-carbon high-boron cast wear-resistant alloy steel and preparation method thereof | |
CN114318159B (en) | A 345MPa container steel plate with hydrogen-induced cracking resistance and its preparation method | |
JP7217353B2 (en) | Seawater corrosion resistant steel and its manufacturing method | |
CN101880833A (en) | A kind of stainless bearing steel adopting rare earth microalloying and its preparation method | |
CN111809115A (en) | Extra-thick plastic mold steel with excellent impact corrosion and wear resistance and preparation method thereof | |
CN107130175A (en) | A kind of high-strength corrosion-resisting magnetism-free stainless steel and preparation method thereof | |
CN105039861A (en) | Medium-manganese and boracic low-alloy abrasion-resistant steel plate and preparing method thereof | |
WO2019001587A1 (en) | Low-nickel copper-containing type t/p92 steel weld material for combating high temperature creep | |
CN113637889B (en) | A kind of preparation method of boron-containing high chromium wear-resistant steel ball | |
CN111809114A (en) | Plastic mold steel with excellent high temperature strength and preparation method thereof | |
CN109182673B (en) | A kind of low-cost high-strength wear-resistant stainless steel and production method thereof | |
CN116083815A (en) | Wear-resistant stainless steel and preparation process thereof | |
CN104946996A (en) | Alkali corrosion resistance high strength steel and production method thereof | |
CN101942606A (en) | Nitrogen alloyed austenitic hot work die steel and preparation method thereof | |
CN104611640B (en) | A kind of high boron iron-based sherardizing steel alloy and preparation method thereof | |
CN108866419A (en) | A kind of high intensity high corrosion resistance austenitic stainless steel and preparation method thereof | |
KR101243129B1 (en) | Precipitation hardening typed die steel with excellent hardness and toughness, and manufacturing method thereof | |
CN102154592A (en) | Micro-alloying martensite stainless steel for blades of water turbine and manufacturing method thereof | |
CN112048659A (en) | High-strength high-ductility steel plate and preparation method thereof | |
CN101555573A (en) | Alloy steel and heat treatment method thereof | |
CN116219270A (en) | High-strength precipitation hardening stainless steel for sensor elastomer and preparation method thereof | |
CN106119680B (en) | A kind of rare earth alloy cast iron of seawater corrosion resistance |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |