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CN116035949B - A kind of oil-balanced low-turbidity high-compatibility cosmetic composition - Google Patents

A kind of oil-balanced low-turbidity high-compatibility cosmetic composition Download PDF

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CN116035949B
CN116035949B CN202211541096.3A CN202211541096A CN116035949B CN 116035949 B CN116035949 B CN 116035949B CN 202211541096 A CN202211541096 A CN 202211541096A CN 116035949 B CN116035949 B CN 116035949B
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oil
skin
alkyl
malate
cyclohexane
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CN116035949A (en
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喻竟
陈刚
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Guangzhou Kechuang Material Technology Co ltd
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Guangzhou Kechuang Material Technology Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/008Preparations for oily skin

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  • Life Sciences & Earth Sciences (AREA)
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  • General Health & Medical Sciences (AREA)
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  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

本发明公开了一种油脂平衡型的低浊度高兼容性化妆品组合物,包含:至少一种环己烷衍生物油脂;至少一种苹果酸酯;至少一种苯甲酸酯和至少一种烷基改性聚硅氧烷。本发明的有益效果为:通过环己烷乙基己酯作为桥梁、环己烷的部分兼容苯基硅油以及乙基己酯的部分兼容苹果酸酯,同时苯基硅油、环甲基硅油、苹果酸酯和皮肤分泌的油脂有比较好的兼容性,最终环甲基硅油、苯基硅油、苹果酸酯以及皮肤表面的油脂形成综合的平衡体系,该平衡体系通过每个成分量变化来适应不同的干皮、油皮、混合皮的底妆技术,可以在维持配方出色的初期涂布感水润感外,在中后期可以维持配方出色的使用感,该组合物增强了油相的稳定性,在配方中使用可以提高乳化稳定性。

The present invention discloses a grease-balanced low-turbidity high-compatibility cosmetic composition, comprising: at least one cyclohexane derivative grease; at least one malate; at least one benzoate and at least one alkyl-modified polysiloxane. The beneficial effects of the present invention are: by using cyclohexane ethylhexyl ester as a bridge, the cyclohexane part is compatible with phenyl silicone oil and the ethylhexyl part is compatible with malate, and at the same time, phenyl silicone oil, cyclomethicone oil, malate and the oil secreted by the skin have relatively good compatibility, and finally cyclomethicone oil, phenyl silicone oil, malate and the oil on the surface of the skin form a comprehensive balance system, and the balance system adapts to different base makeup technologies for dry skin, oily skin and mixed skin by changing the amount of each component, and can maintain the excellent initial coating feeling and moisturizing feeling of the formula, and can maintain the excellent use feeling of the formula in the middle and late stages, and the composition enhances the stability of the oil phase, and can improve the emulsification stability when used in the formula.

Description

Oil balance type low-turbidity high-compatibility cosmetic composition
Technical Field
The invention relates to a cosmetic composition and application and using method thereof, in particular to a grease balance type low-turbidity high-compatibility cosmetic composition.
Background
The basic skin texture of skin can be generally classified into dry skin, oily skin, mixed skin and neutral skin, and one of the differences between different skin textures in skin phenotype studies is the sebum secretion rate and the sebum secretion amount. In order to meet the demands of users with different skin types on makeup, foundation products are usually developed into a formula system based on the skin type, such as dry skin-applicable foundation liquid, oil skin-applicable foundation liquid and mixed skin-applicable foundation liquid. One of the main differences between these product types is that the set up of the grease system will vary from formulation to formulation. Although the oils conventionally used are mainly silicone oils and esters, and the light silicone oils are relatively high in weight, for example, most of cyclomethicone and dimethicone are used in the make-up technology, the chemical structure and glossiness of the oils are single, and the space for other esters is little in the water-in-silicone oil system. The grease system with the silicone oil as the main component and a small amount of esters as the auxiliary component is more or has the main component of balancing the early skin feel, and the esters with stronger relative residence capability are difficult to play a role in remarkably balancing sebum secretion due to lower use amount in the process of carrying make-up. Wherein, even in the process of attempting to improve the proportioning of esters, the low compatibility of silicone oil and esters can cause the risk of stability to the formulation, and in order to further improve the compatibility of silicone oil and esters, a compound system of emulsifying agent is additionally introduced to stabilize the formulation, and such change often further compromises the skin feel in the early stage. To solve this problem, we developed a set of grease balancing techniques with cyclohexane ethylhexyl ester, phenyl silicone oil and malate ester, with hexane ethylhexyl ester as the medium, by which the cyclohexane functional structure of cyclohexane ethylhexyl ester can be effectively compatible with phenyl silicone oil and the ethylhexyl ester functional structure of cyclohexane ethylhexyl ester can be effectively compatible with malate ester. Meanwhile, the malate has a compatible effect similar to sebum. Finally, the cyclomethicone, the phenyl silicone oil, the malate and the grease on the skin surface form a comprehensive balance system, and the balance system can improve the sebum deficiency of dry skin quality in the early stage through the change of the amount of each component, and can also improve the fusion of the sebum and the make-up grease in the later stage so as to facilitate the lasting skin pasting of the make-up. In addition, in practical application, the grease body can effectively reduce the turbidity of the formula and increase the transmission performance and diffuse transmission performance of the formula.
Disclosure of Invention
In view of the above-mentioned shortcomings in the prior art, it is an object of the present invention to provide a grease balanced, low turbidity, high compatibility cosmetic composition. The invention is realized by the following technical scheme.
A low turbidity, high compatibility cosmetic composition of the grease balance type, characterized by comprising:
a) At least one cyclohexane derivative oil, said cyclohexane derivative comprising at least one diethylhexyl cyclohexane;
b) At least one malate ester comprising at least one diethylhexyl malate;
c) At least one benzoate comprising at least one C12-15 alcohol benzoate;
d) At least one alkyl-modified polysiloxane comprising at least one phenyl silicone oil.
Preferably, the cyclohexane derivative comprises at least one cyclohexane, preferably diethylhexyl cyclohexane.
Preferably, the malate comprises at least one malic acid, preferably diethyl hexyl malate.
Preferably, the benzoate comprises at least one benzoic acid, preferably a C12-15 alcohol benzoate.
Preferably, the alkyl-modified polysiloxane comprises at least one polysiloxane, preferably phenyl silicone oil.
Preferably, the weight ratio of the diethylhexyl cyclohexane component and the malate is from 1:20 to 20:1, the sum of the weights being from 0.5% by weight to 30% by weight, based on 100% by weight of the composition.
Preferably, the weight ratio of the malate component to the alkyl-modified polysiloxane is from 10:1 to 1:10, the sum of the weights being from 1% by weight to 30% by weight, based on 100% by weight of the composition.
Preferably, the weight ratio of diethyl hexyl cyclohexane component plus malate to alkyl modified polysiloxane is from 5:1 to 1:5, preferably from 2:1 to 1:2, and from 0.5% to 60% by weight, based on 100% by weight of the composition.
Preferably, the weight ratio of diethyl hexyl cyclohexane component plus benzoate to alkyl modified polysiloxane is from 5:1 to 1:5, preferably from 2:1 to 1:2, and from 0.5% to 60% by weight, based on 100% by weight of the composition.
Preferably, the composition contains at least one additive of film forming polymers, thickeners, emulsifiers, oils, titanium dioxide, antioxidants, preservatives, fragrances, bactericides, emollients, humectants, and combinations thereof. The application of cosmetic compositions to the skin to permanently balance the application of oil control.
The invention has the beneficial effects that in the formula, the combination of cyclohexane derivatives, malate, benzoate and alkyl modified polysiloxane can maintain excellent soft feel of the formula in the middle and later stages besides maintaining excellent initial coating feel of the formula through the dissolution bridging effect of diethyl hexyl cyclohexane and alkyl modified polysiloxane, and has good dispersion effect on powder in the formula.
Drawings
FIG. 1 is a comparative sensory evaluation chart;
FIG. 2 is a diagram of a sensory evaluation of an example;
FIG. 3 is a diagram of the structure of diethylhexyl cyclohexane;
FIG. 4 is a diagram of a malate structure;
FIG. 5 is a diagram of the benzoate structure.
Detailed Description
In order that the objects, technical solutions and advantages of the present invention may be more readily understood, a technical solution of an embodiment of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiment of the present invention, and it is apparent that the described embodiment is a part of the embodiment of the present invention, but not all the embodiments. The components of the embodiments of the present invention generally described and illustrated in the figures herein may be arranged and designed in a wide variety of different configurations.
At least one cyclohexane derivative, so to speak, substituted with a cyclohexane branching.
The substitution may be alcohols or ethers such as trimethylol cyclohexanol, 2-methyl-5-cyclohexyl pentanol, 2-propyl-5-cyclohexyl pentanol, perfluorocyclohexyl methanol, methylcyclohexenyl butanol, dipentyloxy cyclohexane, cyclohexanedimethanol, dihexyloxy cyclohexane, cyclohexylglycerol, 2-t-butylcyclohexyloxy butanol, 4-t-butylcyclohexanol, camphene cyclohexanol and the like.
The substitution may be of carboxylic acids, such as cyclohexanediamine tetraacetic acid,
The substitution may be esters such as 2-t-butylcyclohexanol acetate, butylhydroxycyclohexyl formate, C1-8 alcohol tetrahydroxycyclohexanoate, cyclohexanediol bis-ethylhexanoate, 1, 4-cyclohexanediol bis-ethylhexanoate, cyclohexanediol bis-methylcrotonate, cyclohexylethanol acetate, 2-cyclohexylethanol acetate, cyclohexylethanol butyrate, cyclohexyl methacrylate, cyclohexyl phenyl carbamate, cyclohexanedipeptide-24 aminocyclohexane formate, dimethylcyclohexylethoxyisobutanol propionate, and the like.
The substitution may be alkyl groups such as dioctylcyclohexane, diethylhexylcyclohexane, etc., or alkyl groups may be haloalkyl groups such as perfluorobutylcyclohexane, perfluoro-t-butylcyclohexane, perfluoro-dimethylcyclohexane, perfluoro-methylcyclohexane, etc. In the present invention, diethylhexyl cyclohexane is preferred. Can effectively improve the compatibility of grease and hydrocarbon grease.
At least one malate has good biodegradability characteristics, thus being environmentally friendly. The present invention relates to the use of compounds having the structure wherein R1 and R2 are each a C3-C18 alkyl group, preferably r1=r2, for reducing equilibrium and dynamic surface tension in aqueous based compositions comprising organic compounds.
The malate may be prepared by esterification of malic acid with an alcohol. The reaction is expressed as follows, for the purposes of the present invention, all stereoisomers of malic acid are suitable, including L-malic acid, D-malic acid and DL-malic acid.
The dialkyl malates of the invention are prepared with all alcohols or mixtures of alcohols containing the requisite C3-C18 alkyl substituents, preferably alcohols containing 6 to 12 carbon atoms, and particularly preferably alcohols containing 8 carbon atoms. Suitable alkyl groups should have sufficient carbon atoms to allow the ability of the material to reduce surface tension.
The alkyl groups in the malates of the present invention may be the same or different. Symmetrical malates are preferred because of their ease of synthesis. The alkyl groups may be linear or branched, preferably with terminal branches. The point of attachment to oxygen may be on the middle or terminal carbon, preferably on the terminal carbon. The total number of carbon atoms on R1 and R2 should be greater than or equal to 12, and less than this minimum value would result in too high a polarity of the dialkyl malate. The total number of carbon atoms should be less than or equal to 36, and a larger number can cause the overall skin feel sticky and greasy, making it unusable in many formulations. Examples of suitable alkyl groups are n-hexyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, n-heptyl, 2-methylhexyl, 3-methylhexyl, 4-methylhexyl, 5-methylhexyl, 3-ethylpentyl, n-octyl, 2-methylheptyl, 3-methylheptyl, 4-methylheptyl, 5-methylheptyl, 6-methylheptyl, ethylhexyl, lauryl, myristyl, palmityl, stearyl, isostearyl and the like. Preferred derivatives are those wherein r1=r2 and the total number of alkyl carbons is 12-36. Among these derivatives, derivatives containing 12 to 24 alkyl carbons are preferable, and derivatives containing 12 to 20 alkyl carbons are particularly preferable, and derivatives containing 16 alkyl carbons are most preferable, particularly in the case of r1=r2=ethylhexyl. Furthermore, those alkyl groups containing terminal branches or attached at terminal oxygens are preferred.
At least one benzoate, the term "benzoate" includes esters of benzoic acid of the general formula (I) wherein R represents an aliphatic, aromatic, saturated, monounsaturated or polyunsaturated, straight or branched chain alkyl group having C4-C22 carbon atoms.
In a preferred embodiment R represents an aliphatic alkyl group.
Accordingly, "C12 alkyl benzoate" means a compound according to formula (I) wherein R represents a linear or branched, saturated or unsaturated alkyl group having 12 carbon atoms. The term "alkyl benzoate having a carbon chain length of 12" is used synonymously with such a compound. These two terms include both individual compounds such as dodecyl benzoate and mixtures of different alkyl benzoates at c=12, such as dodecyl benzoate and 2-ethyl-1-decyl benzoate, C12-15 alcohol benzoate, dipropylene glycol dibenzoate, diethylene glycol dibenzoate, tridecyl trimellitate, and the like.
The subject of the invention is an alkyl benzoate mixture, characterized in that R is a mixture, R being chosen in the range C6-C22, preferably in a total amount of C12-C15 >95%.
None of the alkyl benzoate mixtures known in the prior art have the distribution of the present invention. It has surprisingly been found that the mixtures with the carbon chain distribution according to the invention are not only highly spreadable (spreitend) oil bodies, but also have improved dissolution properties for UV light protection filters relative to the known alkyl benzoates.
The alkyl benzoates are prepared according to methods known to the expert. Alkyl benzoates can be obtained, for example, by reacting benzoic acid with the corresponding alcohol or alcohol mixture in the presence of a catalyst. Such a method is described, for example, in WO 2004/099117.
The alkyl benzoate mixtures of the present invention may also be obtained by using in the reaction an alcohol mixture having the carbon chain distribution of the present invention. The alkyl benzoate mixtures of the present invention can also be obtained by mixing the corresponding individual alkyl benzoates.
The odor of the product obtained by the esterification or transesterification reaction can be improved if desired by deodorization, and likewise, if necessary, can be treated by methods known to the expert to improve its color.
The total amount of C12-C15 fatty alcohols is >95% for the conventional alcohol mixtures suitable for preparing the alkyl benzoate mixtures of the present invention, with the preferred C12-15 alcohol benzoates of the present invention.
At least one alkyl-modified polysiloxane which promotes compatibility between the fatty acid ester and the silicone grease may be used alone or in combination of two or more. The modified alkyl group may be a C2-C45 alkyl group, and among them, ethyl, hexyl, octyl, lauryl, myristyl, palmityl, stearyl, cyclophenyl, phenylpropyl, phenyl, C4-24 alkyl, C20-24 alkyl, C24-28 alkyl, C26-28 alkyl, C30-45 alkyl, etc. are common. Preferred in the present invention is a polysiloxane containing a silicon atom having a phenyl group bonded to the inside of a polysiloxane chain as a silicon atom constituting the main chain of the polysiloxane. Is a compound denoted by the INCI name "polyphenylmethylsiloxane". Commercially available products include, for example, the trade name'PDM 20”、“PDM 20 "(manufactured by WACKER CHEMICAL Corporation), trade name" DOWSIL TM 556Cosmetic Grade Fluid "(manufactured by Dow co., ltd.) and trade name" NPC-3156 "(manufactured by NeChem co., ltd.) and the like. The content of the permeation system of the present invention is 5.0 to 50.0 mass%, preferably 7.0 to 40.0 mass%, more preferably 10.0 to 30.0 mass% relative to the mass% of the present invention.
Additional conventional cosmetic ingredients:
the composition according to the invention may also comprise any conventional cosmetic ingredient, which may be chosen in particular from antioxidants, fragrances, preservatives, neutralising agents, surfactants, filters (solar filters), vitamins, moisturizers, self-tanning compounds (self-tanning compounds), anti-wrinkle active ingredients, emollients, hydrophilic or lipophilic active ingredients, anti-free radical agents, deodorants, sequestering agents and mixtures thereof.
Preferably, at least one of volatile silicone oil, volatile alkane, water-in-silicone emulsifier, polyol, surfactant, preservative, essence, humectant and active is also included. Physiologically acceptable medium the composition according to the invention comprises a physiologically acceptable and preferably cosmetically acceptable medium, that is to say the composition does not have any harmful side effects, in particular does not give the cosmetic user an unacceptable redness, temperature, pain or tingling sensation. In particular, the physiologically acceptable medium may comprise at least one oil.
W/O emulsifier
For the W/O emulsifier, hydrocarbon-based surfactants or silicone surfactants may be used.
According to one embodiment variant, hydrocarbon-based surfactants are preferred.
Examples of hydrocarbon-based surfactants that may be mentioned include polyester polyols such as PEG-30 dimerized hydroxystearate sold by Uniqema under the number Arlacel P135, and polyglyceryl-2 dimerized hydroxystearate sold by Cognis under the number Dehymuls PGPH.
Examples of silicone surfactants which may be mentioned include alkyl dimethicone copolyols such as lauryl dimethicone copolyol sold by Dow Corning under the name Dow Corning 5200Formulation Aid, cetyl dimethicone copolyol sold by Goldschmidt under the name Abil EM 90 or a mixture of polyglyceryl-4 isostearate/cetyl dimethicone copolyol/hexyl laurate sold by Goldschmidt under the name Abil WE 09. Still others are PEG-10 dimethicone, PEG/PPG-18/18 dimethicone, lauryl PEG-9 dimethicone ethyl dimethicone, cetyl PEG/PPE-10/1 dimethicone, cyclopentadimethicone, bis-PEG/PPG-14/14 dimethicone, and the like.
One or more co-emulsifiers may also be added thereto. The co-emulsifier may advantageously be selected from the group comprising polyol alkyl esters. Polyol alkyl esters which may be mentioned in particular include glycerol esters and/or sorbitan esters (for example polyglyceryl-3 diisostearate sold under the name L a m e f o r m T G I by Cognis, polyglyceryl-4 isostearate (for example the product sold under the name Isolan GI 34 by Goldschmidt), sorbitan isostearate (for example the product sold under the name Arlacel 987 by ICI), sorbitan isostearate (for example the product sold under the name Arlacel 986 by ICI), and mixtures thereof.
The compositions of the present invention are compatible in formulations comprising a mixture of polyols.
Advantageously, the polyol may be preferably selected from polyols of C2-C8, more preferably from polyols of C3-C6. The polyhydric alcohol may be selected from erythritol, glycerol, pentaerythritol, trimethylolpropane, ethylene glycol, propylene glycol, 1, 3-butanediol, 1, 3-propanediol pentanediol, hexanediol, isopentane diol, dipropylene glycol, diethylene glycol and diglycerol, ethylhexyl glycerol, octylglycol and mixtures thereof, glycerol and derivatives thereof, polyglycerols (such as glycerol oligomers, such as diglycerol), and polyethylene glycols, glycol ethers (especially containing 3 to 16 carbon atoms, such as monopropylene glycol (C1-C4) alkyl ethers, dipropylene glycol (C1-C4) alkyl ethers or tripropylene (C1-C4) alkyl ethers, monoethylene glycol (C1-C4) alkyl ethers, diethylene glycol (C1-C4) alkyl ethers or triethylene glycol (C1-C4) alkyl ethers), and mixtures thereof.
In particular, the polyhydric alcohol is selected from the group consisting of erythritol, glycerol, glycols, preferably propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol, ethylhexyl glycerol, octylene glycol, glycol ethers, preferably monopropylene glycol (C1-C4) alkyl ethers, dipropylene glycol (C1-C4) alkyl ethers or tripropylene glycol (C1-C4) alkyl ethers, or monoethylene glycol (C1-C4) alkyl ethers, diethylene glycol (C1-C4) alkyl ethers or triethylene glycol (C1-C4) alkyl ethers, and mixtures thereof.
According to a preferred embodiment of the present invention, the polyol is selected from the group consisting of ethylene glycol, pentaerythritol, trimethylolpropane, propylene glycol, butylene glycol, glycerol, polyglycerol and polyethylene glycol, and mixtures thereof.
In particular embodiments, the polyhydric alcohol is selected from the group consisting of erythritol, glycerol, propylene glycol, butylene glycol, ethylhexyl glycerol, octylethylene glycol, and mixtures thereof.
In a preferred embodiment, the composition comprises at least glycerol. Polyhydric alcohols, preferably C2-C8 polyhydric alcohols, more preferably C3-C6 polyhydric alcohols, preferably for example erythritol, glycerol, propylene glycol, 1, 3-butanediol, pentanediol, hexanediol, dipropylene glycol, diethylene glycol and diglycerol, and mixtures thereof, glycerol and derivatives thereof are known as humectants or moisturizers.
The composition according to the invention may also comprise an additional humectant or humectant.
These additional humectants or humectants that may be mentioned in particular include sorbitol; glycol ethers (containing in particular 3 to 16 carbon atoms), such as monopropylene glycol (C1-C4) alkyl ether, dipropylene glycol (C1-C4) alkyl ether or tripropylene glycol (C1-C4) alkyl ether, monoethylene glycol (C1-C4) alkyl ether, diethylene glycol (C1-C4) alkyl ether or triethylene glycol (C1-C4) alkyl ether, urea and derivatives thereof, in particular hydroxyethyl urea (Hydrovance) (2-hydroxyethyl urea) sold by National Starch, lactic acid, hyaluronic acid, fruit acid (AHA), salicylic acid (BHA), sodium picolinate, xylitol, serine, sodium lactate, alginase and derivatives thereof, chitosan and derivatives thereof, collagen, plankton, cogongrass (IMPERATA CYLINDRA) extract sold by Sedermafrican under the name Moist, acrylic acid homopolymers, such as beta-glucan from NOF, in particular sodium carboxymethyl beta-glucan from Mi belle-AG-Biochemistry, passion, oil, a mixture of C-30% by weight of water in a solution of a mixture of C-30% by weight of a water-soluble, such as that of a 3-30% of a 3-C60% by weight aqueous solution of a 3-C60% of a water-soluble glycoside, such as a mixture of a 3-C40% of a water-C60% of a material, a water-containing a mixture of a water-soluble glycoside, such as, in particular, a mixture of a water-30% of a water-soluble material, such as those manufactured by Chimex under the trade name Mexoryl, musk rose oil sold by Nestle, spheres of collagen and chondroitin sulfate of marine origin (Atelocollagen) sold by ENGELHARD LYON company under the name MARINE FILLING SPHERES, hyaluronic acid spheres, such as those sold by ENGELHARD LYON company, arginine, argan oil, and mixtures thereof.
As mentioned above, the cosmetically acceptable medium includes, inter alia, water and optionally a cosmetically suitable solvent. Wherein the water may be pure demineralized water or mineral water. Preferred solvents are aliphatic alcohols having from 2 to 4 carbon atoms, such as ethanol, isopropanol, polyols, such as propylene glycol, glycerol, ethylene glycol and polyol ethers, unbranched or branched hydrocarbons, such as pentane, hexane, isopentane and cyclic hydrocarbons, such as cyclopentane and cyclohexane, and mixtures thereof. In the sense of the present invention, "oil" means a compound that is liquid at room temperature (25 ℃) and that is completely insoluble in water or soluble in water at a rate of less than 10% by weight relative to the weight of the oil introduced into the water when introduced into the water at a concentration of at least 1% by weight at 25 ℃.
Very particularly preferred solvent is ethanol;
Examples
All percentages in the present invention are by weight and are based on 100% by weight of the cosmetic composition of the present invention, unless otherwise indicated.
The weight referred to in the present invention is the weight of the active substance. For substances in the form of dispersions, the invention is described in
The weight referred to is the actual weight of the substance and does not include the weight of the carrier, that is to say the weight of the substance referred to in the present invention in the form of a dispersion = weight of the dispersion x solids content of the dispersion. For solid materials containing water of crystallization, the weight of the material referred to in the present invention is the weight of the removed water of crystallization.
Examples
Raw materials and reagents
Both the examples and the comparative examples according to the invention can be prepared in that the polyurethane B) LATMOISO according to the invention is added with stirring to the oil phase at a stirring speed of 500-600rpm in order to take part in the emulsion addition of the formulation.
The examples or comparative examples in the present invention all have the components listed in the following table
Wherein wt% refers to the weight percent of the solid component in the ingredient based on the total weight of the formulation sample. And the sum of the percentages by weight of the solid components in polyurethane A) and in the amphoteric copolymer B) is kept at 2% by weight.
The skin used in the following experiments was asian skin. All the skins were healthy and undamaged.
Evaluation experiment 1 sensory evaluation
The testing method comprises applying the test product to skin of 6 subjects according to standard dosage and usage by 2 organoleptic experts, scientifically evaluating organoleptic properties of the product, and averaging, wherein the higher the value is, the better the corresponding evaluation dimension is represented
FIGS. 1 and 2 can be obtained
From FIG. 1, it can be seen that the system containing phenyl silicone oil has a reduced sticky feel and a later heavy feel compared to cyclosilicon, but a slower drying rate. In terms of the gradient of use of the single grease, 6840 increases the maintenance of the system with increasing amounts of use, and reduces the immediate sensation of hydration. And as 6840 increases, the heavy feel and push-away properties of the formulation decrease. The 6850 embodiment can be seen that the pushing-away performance of the formulation is improved along with the improvement of the dosage, which is better than that of the blank sample, and the heavy feel of the formulation can be reduced along with the improvement of the dosage. As can be seen from the formulation of the different total amounts used, the higher total amounts (comparative examples 13-16) perform better than the lower groups (comparative examples 17-20).
The group of examples can obtain better comprehensive performance when the total amount of the combined grease is higher (examples 6-10) while the phenyl silicone oil has lower greasy feel, and better comprehensive performance when the combination ratio of the grease is 6850:6840=2.5:1.5.
Evaluation experiment 2 optical test
The test method comprises uniformly coating test product with thickness of 25 μm with quartz glass as base material, and testing regular transmittance, diffuse transmittance and turbidity of the product 10min after coating
The average of the optical properties for the formulation is as follows:
Turbidity% Regular transmission% Diffuse transmission%
Comparative example 1 63.23 74.32 47.28
Comparative example 2 94.94 45.22 42.93
Comparative example 3 94.58 45.32 42.86
Comparative example 4 95.48 44.13 42.14
Comparative example 5 94.49 45.93 43.4
Comparative example 6 95.55 44.31 42.34
Comparative example 7 95.83 43.71 41.89
Comparative example 8 93.62 47.92 44.86
Comparative example 9 95.68 44.91 42.97
Comparative example 10 92.52 49.22 45.54
Comparative example 11 93.95 46.53 43.71
Comparative example 12 96.9 40.12 38.88
Comparative example 13 95.74 42.61 40.8
Comparative example 14 96.02 41.98 40.31
Comparative example 15 96.53 41.1 39.68
Comparative example 16 93.7 47.24 44.26
Comparative example 17 92.58 49.29 45.64
Comparative example 18 93.39 47.86 44.7
Comparative example 19 93.5 49.22 46.02
Comparative example 20 94.72 45.46 43.06
Example 1 65.74 72.59 47.23
Example 2 66.18 72.27 47.83
Example 3 68.69 71.17 48.88
Example 4 66.94 71.57 47.91
Example 5 73.07 67.96 49.66
Example 6 65.58 72.59 47.61
Example 7 73.44 67.14 49.31
Example 8 77.22 64.37 49.71
Example 9 71.26 68.75 48.99
Example 10 71.36 68.27 48.72
From optical comparison, it can be seen that the examples effectively reduce the turbidity of the formulation and increase the transmittance and diffuse transmittance of the formulation. The retention of the formulation is enhanced in the sense of use.
6850 Obtained from data statistical analysis greatly contributes to the moisture feeling of the formula, and 6840 can remarkably enhance the push-off tendency of the formula and the residual feeling at the rear end of the formula. The skin feel balance of the formula is obviously enhanced by the mutual matching.
It will be evident to those skilled in the art that the invention is not limited to the precise details set forth, and that the invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The described embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and any changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (2)

1.一种油脂平衡型的低浊度高兼容性化妆品组合物,其特征在于,其质量组成为:1. A fat-balanced, low-turbidity, high-compatibility cosmetic composition, characterized in that its mass composition is: 氯化钠 1%Sodium chloride 1% 乙基己基甘油 0.1%Ethylhexylglycerin 0.1% 1,2-己二醇 0.5%1,2-Hexanediol 0.5% 丙三醇 8%Glycerol 8% Lipfilm 6850,中文名称为二乙基己基环己烷&丁羟甲苯,3%Lipfilm 6850, Chinese name is diethylhexylcyclohexane & butylated hydroxytoluene, 3% Lipfilm 6840,中文名称为苹果酸二乙基己酯&丁羟甲苯,1%Lipfilm 6840, Chinese name is diethylhexyl malate & butylated hydroxytoluene, 1% C12-15醇苯甲酸酯 2%C12-15 Alkyl Benzoate 2% 氧化铁红 0.18%Iron oxide red 0.18% 氧化铁黄 0.6%Iron oxide yellow 0.6% 氧化铁黑0.03%Iron oxide black 0.03% UT91AS 6.8%UT91AS 6.8% EM90 2.5%EM90 2.5% KF6017 1.5 %KF6017 1.5 % 膨润土3%Bentonite 3% DC556 15%DC556 15% F995 14.5%F995 14.5% 加水至100%。Add water to 100%. 2.一种油脂平衡型的低浊度高兼容性化妆品组合物,其特征在于,其质量组成为:2. A fat-balanced, low-turbidity, high-compatibility cosmetic composition, characterized in that its mass composition is: 氯化钠 1%Sodium chloride 1% 乙基己基甘油 0.1%Ethylhexylglycerin 0.1% 1,2-己二醇 0.5%1,2-Hexanediol 0.5% 丙三醇 8%Glycerol 8% Lipfilm 6850,中文名称为二乙基己基环己烷&丁羟甲苯,2.5%Lipfilm 6850, Chinese name is diethylhexylcyclohexane & butylated hydroxytoluene, 2.5% Lipfilm 6840,中文名称为苹果酸二乙基己酯&丁羟甲苯,1.5%Lipfilm 6840, Chinese name is diethylhexyl malate & butylated hydroxytoluene, 1.5% C12-15醇苯甲酸酯 2%C12-15 Alkyl Benzoate 2% 氧化铁红 0.18%Iron oxide red 0.18% 氧化铁黄 0.6%Iron oxide yellow 0.6% 氧化铁黑0.03%Iron oxide black 0.03% UT91AS 6.8%UT91AS 6.8% EM90 2.5%EM90 2.5% KF6017 1.5%KF6017 1.5% 膨润土3%Bentonite 3% DC556 15%DC556 15% F995 14.5%F995 14.5% 加水至100%。Add water to 100%.
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016173927A1 (en) * 2015-04-29 2016-11-03 Dsm Ip Assets B.V. Topical sunscreen emulsions

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016173927A1 (en) * 2015-04-29 2016-11-03 Dsm Ip Assets B.V. Topical sunscreen emulsions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
宝拉·培冈.《带着我去化妆品柜台》.新世界出版社,2009,894. *

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