[go: up one dir, main page]

CN116005212A - A kind of steel cord, monofilament and its production method and production device - Google Patents

A kind of steel cord, monofilament and its production method and production device Download PDF

Info

Publication number
CN116005212A
CN116005212A CN202310058709.6A CN202310058709A CN116005212A CN 116005212 A CN116005212 A CN 116005212A CN 202310058709 A CN202310058709 A CN 202310058709A CN 116005212 A CN116005212 A CN 116005212A
Authority
CN
China
Prior art keywords
monofilament
steel wire
brass
tank
wet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310058709.6A
Other languages
Chinese (zh)
Inventor
李呐
刘祥
寇首鹏
魏于博
刘湘慧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Xingda Steel Tyre Cord Co Ltd
Original Assignee
Jiangsu Xingda Steel Tyre Cord Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Xingda Steel Tyre Cord Co Ltd filed Critical Jiangsu Xingda Steel Tyre Cord Co Ltd
Priority to CN202310058709.6A priority Critical patent/CN116005212A/en
Priority to PCT/CN2023/076097 priority patent/WO2024152396A1/en
Publication of CN116005212A publication Critical patent/CN116005212A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/02Tanks; Installations therefor
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/22Electroplating: Baths therefor from solutions of zinc
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48After-treatment of electroplated surfaces
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/06Wires; Strips; Foils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Ropes Or Cables (AREA)

Abstract

The invention discloses a steel cord, a monofilament and a production method and a production device thereof, wherein the production method of the monofilament comprises the following steps: zinc plating is carried out on the surface of the brass steel wire, so that the brass steel wire with a zinc layer is obtained, and the gram weight of the zinc layer is 0.08-1 g/kg; washing, wet drawing and winding the brass steel wire with the zinc layer in sequence to obtain monofilaments; the production device of the monofilaments comprises a galvanizing tank, a rinsing tank, a wet drawing machine tool and a monofilament take-up pulley which are sequentially arranged. The invention maintains the zinc oxide on the surface of the monofilament at 0.05g/m after wet drawing by controlling the gram weight of the zinc layer 2 ~0.2g/m 2 Within the range, make a singleThe filaments and steel cords still have better aged adhesion retention without sacrificing initial adhesion.

Description

一种钢帘线、单丝及其生产方法和生产装置A kind of steel cord, monofilament and its production method and production device

技术领域technical field

本发明属于钢帘线技术领域,具体涉及一种钢帘线、单丝及其生产方法和生产装置。The invention belongs to the technical field of steel cords, and in particular relates to a steel cord, a monofilament, a production method and a production device thereof.

背景技术Background technique

黄铜钢丝帘线已广泛应用于各种橡胶制品,黄铜涂层作为中间媒介可以提供帘线和橡胶之间的粘附,黄铜可以与橡胶建立良好的初始粘合,但随着橡胶制品的使用,特别是在一些高湿、高热的特殊环境,帘线与橡胶的粘附保持率下降,加速二者的粘附降解,致使橡胶制品的耐久性能下降,即黄铜与橡胶的老化粘附性不能很好的维持,此种现象已广见报导,如Guy S J.J.Adhesion Sci.Technol,2005(6):445-465或Guy B,Wang BX etal.Rubber World,200:20-32等。因此在不降低现有黄铜涂层与橡胶粘附力的情况下,如何减少老化附着力的退化是延长轮胎等橡胶制品寿命的有效手段。Brass steel cord has been widely used in various rubber products, brass coating as an intermediate can provide the adhesion between the cord and rubber, brass can establish a good initial bond with rubber, but as rubber products Especially in some high-humidity and high-heat special environments, the adhesion retention rate between the cord and rubber decreases, which accelerates the adhesion degradation of the two, resulting in a decrease in the durability of rubber products, that is, the aging adhesion between brass and rubber. Adhesion cannot be well maintained, this phenomenon has been widely reported, such as Guy S J.J.Adhesion Sci.Technol, 2005(6):445-465 or Guy B, Wang BX et al.Rubber World, 200:20-32, etc. . Therefore, without reducing the adhesion between the existing brass coating and rubber, how to reduce the degradation of aging adhesion is an effective means to prolong the life of rubber products such as tires.

发明内容Contents of the invention

本发明的目的在于克服现有技术中的不足,提供一种钢帘线、单丝及其生产方法和生产装置,使单丝和钢帘线在不牺牲初始粘附力的条件下仍具有更佳的老化附着保持率。The object of the present invention is to overcome the deficiencies in the prior art, provide a kind of steel cord, monofilament and its production method and production device, make monofilament and steel cord still have better under the condition of not sacrificing the initial adhesion force Excellent aging adhesion retention.

本发明提供了如下的技术方案:The present invention provides following technical scheme:

第一方面,提供一种单丝的生产方法,包括以下步骤:In a first aspect, a method for producing a monofilament is provided, comprising the following steps:

在黄铜钢丝的表面镀锌,得到带有锌层的黄铜钢丝,所述锌层的克重为0.08~1g/kg;Galvanizing the surface of the brass steel wire to obtain a brass steel wire with a zinc layer, the grammage of the zinc layer is 0.08-1g/kg;

将带有锌层的黄铜钢丝依序进行水洗、湿拉和收线,得到单丝。The brass steel wire with zinc layer is washed with water, wet drawn and taken up in sequence to obtain monofilament.

进一步的,所述带有锌层的黄铜钢丝水洗后依序进行磷酸洗、再水洗和收线,得到酸洗后的钢丝;Further, after the brass steel wire with zinc layer is washed with water, it is washed with phosphoric acid, washed with water and taken up in sequence to obtain the steel wire after pickling;

对酸洗后的钢丝进行湿拉和收线,得到单丝。The pickled steel wire is wet-drawn and taken up to obtain a monofilament.

进一步的,所述黄铜钢丝的直径为0.5~4.0mm,所述黄铜钢丝表面黄铜涂层的厚度为0.4~2.5μm,黄铜涂层中铜的重量百分比为60~70%。Further, the diameter of the brass steel wire is 0.5-4.0 mm, the thickness of the brass coating on the surface of the brass steel wire is 0.4-2.5 μm, and the weight percentage of copper in the brass coating is 60-70%.

进一步的,所述湿拉步骤中钢丝的丝径压缩率>80%。Further, the wire diameter compression ratio of the steel wire in the wet drawing step is >80%.

第二方面,提供一种单丝,采用第一方面所述方法生产得到。The second aspect provides a monofilament produced by the method described in the first aspect.

第三方面,提供一种第二方面所述单丝的生产装置,包括依次设置的镀锌槽、水洗槽、湿拉机床和单丝收线轮。A third aspect provides a monofilament production device as described in the second aspect, comprising a galvanizing tank, a water washing tank, a wet drawing machine, and a monofilament take-up wheel arranged in sequence.

进一步的,所述镀锌槽内盛有硫酸锌镀液,所述镀锌槽内设有阳极架,所述镀锌槽外设有阴极辊,所述阳极架和阴极辊分别连接同一电源的正极和负极;Further, the zinc sulfate bath is filled in the galvanizing tank, an anode frame is arranged in the galvanizing tank, and a cathode roll is arranged outside the galvanizing tank, and the anode frame and the cathode roll are respectively connected to the same power supply. Positive and negative poles;

所述水洗槽包括1个或多个不连通的分槽,所述分槽内盛有纯水,各分槽均设有第一提升泵以及与第一提升泵连接的第一水洗口;The water washing tank includes one or more disconnected sub-tanks filled with pure water, and each sub-tank is provided with a first lift pump and a first water washing port connected to the first lift pump;

所述湿拉机床内盛有润滑液,所述湿拉机床设有循环系统,所述湿拉机床的进口端和出口端均设有第一过线导轮。The lubricating fluid is filled in the wet drawing machine, and the wet drawing machine is provided with a circulation system, and the inlet end and the outlet end of the wet drawing machine are both provided with first wire passing guide wheels.

进一步的,包括依次设置的镀锌槽、水洗槽、磷酸槽、再水洗槽、酸洗后的钢丝收线轮、湿拉机床和单丝收线轮。Further, it includes a galvanizing tank, a washing tank, a phosphoric acid tank, a re-washing tank, a steel wire take-up reel after pickling, a wet drawing machine and a monofilament take-up reel arranged in sequence.

进一步的,所述磷酸槽内盛有磷酸液,所述磷酸槽通过隔板分隔为上槽体和下槽体,所述下槽体和上槽体间连接有第二提升泵;Further, the phosphoric acid tank is filled with phosphoric acid liquid, and the phosphoric acid tank is divided into an upper tank body and a lower tank body by a partition, and a second lift pump is connected between the lower tank body and the upper tank body;

所述再水洗槽设有第三提升泵以及与第三提升泵连接的第二水洗口;The rewash tank is provided with a third lift pump and a second water wash port connected to the third lift pump;

所述再水洗槽与酸洗后的钢丝收线轮之间设有第二过线导轮。A second wire passing guide wheel is provided between the re-washing tank and the pickled steel wire take-up wheel.

第四方面,提供一种钢帘线,由第二方面所述单丝捻制获得。In a fourth aspect, a steel cord is provided, which is obtained by twisting the monofilament described in the second aspect.

与现有技术相比,本发明的有益效果是:Compared with prior art, the beneficial effect of the present invention is:

(1)本发明提供的单丝生产方法,在黄铜钢丝的表面镀锌得到带有锌层的黄铜钢丝,将带有锌层的黄铜钢丝依序进行水洗、湿拉后在黄铜钢丝表面形成氧化锌,通过控制锌层的克重为0.08~1g/kg能够控制湿拉后单丝表面的氧化锌维持在0.05g/m2~0.2g/m2范围内,使单丝和钢帘线在不牺牲初始粘附力的条件下仍具有更佳的老化附着保持率,特别是湿老化和热老化条件下仍能维持良好的附着保持率;(1) In the monofilament production method provided by the present invention, the surface of the brass steel wire is galvanized to obtain a brass steel wire with a zinc layer, and the brass steel wire with a zinc layer is sequentially washed and wet-drawn on the brass wire Zinc oxide is formed on the surface of the steel wire. By controlling the gram weight of the zinc layer to 0.08-1g/kg, the zinc oxide on the surface of the monofilament after wet drawing can be controlled within the range of 0.05g/m 2 to 0.2g/m 2 , so that the monofilament and The steel cord still has a better aging adhesion retention rate without sacrificing the initial adhesion, especially under the conditions of wet aging and heat aging, it can still maintain a good adhesion retention rate;

(2)本发明的单丝与常规黄铜单丝相比,初始粘合波动范围仅为-2.5~+3.3%,但经过特殊湿热或蒸汽条件老化后其附着保持力高出常规黄铜单丝约5~18%。(2) Compared with the conventional brass monofilament, the monofilament of the present invention has an initial adhesion fluctuation range of only -2.5 to +3.3%, but its adhesion retention is higher than that of conventional brass monofilament after aging under special humid heat or steam conditions. Silk about 5 to 18%.

附图说明Description of drawings

图1是本发明实施例2中单丝生产装置的结构示意图;Fig. 1 is a schematic structural view of a monofilament production device in Example 2 of the present invention;

图2是本发明实施例4中单丝生产装置的结构示意图;Fig. 2 is a schematic structural view of a monofilament production device in Example 4 of the present invention;

图中标记为:1、黄铜钢丝;2、阴极辊;3、镀锌槽;4、阳极架;5、硫酸锌镀液;6、第一提升泵;7、第一水洗口;8、水洗槽;9、纯水;10、湿拉机床;11、润滑液;12、循环系统;13、带有氧化锌层的单丝;14、单丝收线轮;15、第一过线导轮;16、再水洗槽;17、酸洗后的钢丝;18、第二过线导轮;19、酸洗后的钢丝收线轮;20、第三提升泵;21、隔板;22、磷酸槽;23、磷酸液;24、第二提升泵;25、第二水洗口。The marks in the figure are: 1. Brass steel wire; 2. Cathode roller; 3. Galvanizing tank; 4. Anode rack; 5. Zinc sulfate plating solution; 6. The first lift pump; 7. The first water washing port; Washing tank; 9. Pure water; 10. Wet drawing machine; 11. Lubricating fluid; 12. Circulation system; 13. Monofilament with zinc oxide layer; 14. Monofilament take-up wheel; 15. First wire guide 16. Re-washing tank; 17. Steel wire after pickling; 18. Second wire guide wheel; 19. Steel wire take-up wheel after pickling; 20. Third lift pump; 21. Separator; 22. Phosphoric acid tank; 23, phosphoric acid solution; 24, the second lift pump; 25, the second water washing port.

具体实施方式Detailed ways

下面结合附图对本发明作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案,而不能以此来限制本发明的保护范围。The present invention will be further described below in conjunction with the accompanying drawings. The following examples are only used to illustrate the technical solutions of the present invention more clearly, but not to limit the protection scope of the present invention.

需要说明的是,在本发明的描述中,术语“前”、“后”、“左”、“右”、“上”、“下”、“内”、“外”等指示的方位或位置关系为基于附图中所示的方位或位置关系,仅是为了便于描述本发明而不是要求本发明必须以特定的方位构造和操作,因此不能理解为对本发明的限制。It should be noted that, in the description of the present invention, the terms "front", "rear", "left", "right", "upper", "lower", "inner", "outer" and the like indicate orientations or positions The relationship is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present invention and does not require that the present invention must be constructed and operated in a specific orientation, and thus should not be construed as a limitation of the present invention.

实施例1Example 1

本实施例提供一种单丝的生产方法,步骤如下:在黄铜钢丝的表面镀锌,得到带有锌层的黄铜钢丝,控制锌层的克重为0.08~1g/kg;将带有锌层的黄铜钢丝依序进行水洗、湿拉,经过湿拉后钢丝表面形成一层锌的氧化层,湿拉过程中钢丝的丝径压缩率>80%,最后收线,得到单丝。This embodiment provides a production method of monofilament, the steps are as follows: galvanize the surface of the brass steel wire to obtain a brass steel wire with a zinc layer, and control the grammage of the zinc layer to be 0.08 to 1 g/kg; The zinc-coated brass steel wire is washed with water and wet-drawn in sequence. After wet-drawing, a layer of zinc oxide layer is formed on the surface of the steel wire. During the wet-drawing process, the wire diameter compression rate of the steel wire is >80%. Finally, the wire is drawn up to obtain a monofilament.

其中,黄铜钢丝的直径为0.5~4.0mm,黄铜钢丝表面黄铜涂层的厚度为0.4~2.5μm,黄铜涂层中铜的重量百分比为60~70%,黄铜涂层可以为任意方式获得,例如电镀、喷涂或浸渍等方式。Wherein, the diameter of the brass steel wire is 0.5-4.0 mm, the thickness of the brass coating on the surface of the brass steel wire is 0.4-2.5 μm, the weight percentage of copper in the brass coating is 60-70%, and the brass coating can be Obtained in any way, such as electroplating, spraying or dipping.

传统帘线生产中,黄铜钢丝表面的黄铜涂层主要为α相黄铜,黄铜中铜锌含量比的差异,使得其在拉拔过程中表面难以生成0.05g/m2含量以上的氧化锌层。而当单丝表面氧化锌含量大于0.2g/m2时,会造成单丝表面氧化锌的过度偏高而影响单丝与橡胶之间的初始附着力。本实施例控制锌层的克重为0.08~1g/kg,湿拉过程中由于强烈机械摩擦会去除大部分表面锌层,并使锌部分氧化为氧化锌,湿拉后单丝表面的氧化锌最终维持在0.05g/m2~0.2g/m2范围内。湿拉后的单丝可以捻制为任意结构帘线,亦可以直接作为最终成品,由此,使单丝和帘线在不牺牲初始粘附力的条件下仍具有更佳的老化附着保持率,特别是湿和热老化。In the traditional cord production, the brass coating on the surface of the brass steel wire is mainly α-phase brass, and the difference in the content ratio of copper and zinc in the brass makes it difficult to generate more than 0.05g/ m2 content on the surface during the drawing process. Zinc oxide layer. And when the zinc oxide content on the surface of the monofilament is greater than 0.2g/ m2 , it will cause excessively high zinc oxide on the surface of the monofilament and affect the initial adhesion between the monofilament and the rubber. In this embodiment, the gram weight of the zinc layer is controlled to be 0.08-1g/kg. During the wet drawing process, due to strong mechanical friction, most of the surface zinc layer will be removed, and the zinc will be partially oxidized to zinc oxide. The zinc oxide on the surface of the monofilament after wet drawing Finally, it is maintained within the range of 0.05g/m 2 to 0.2g/m 2 . The monofilaments after wet drawing can be twisted into cords of any structure, and can also be directly used as the final product, so that the monofilaments and cords still have better aging adhesion retention without sacrificing the initial adhesion , especially humidity and heat aging.

实施例2Example 2

如图1所示,本实施例提供一种单丝的生产装置,用于生产实施例1中的单丝,结构包括依次设置的镀锌槽3、水洗槽8、湿拉机床10和单丝收线轮14。As shown in Figure 1, this embodiment provides a monofilament production device for producing the monofilament in Example 1. The structure includes a galvanizing tank 3, a water washing tank 8, a wet drawing machine 10 and a monofilament Take-up wheel 14.

镀锌槽3用于在黄铜钢丝1表面镀锌,其内盛有硫酸锌镀液5,镀锌槽3内设有阳极架4,镀锌槽3外设有阴极辊2,阳极架4和阴极辊2分别连接同一电源的正极和负极。The galvanizing tank 3 is used for galvanizing the surface of the brass steel wire 1, which contains zinc sulfate plating solution 5, and the anode frame 4 is arranged in the galvanizing tank 3, and the cathode roller 2 and the anode frame 4 are arranged outside the galvanizing tank 3 Connect the positive pole and the negative pole of the same power supply with the cathode roller 2 respectively.

水洗槽8包括1个或多个不连通的分槽,分槽内盛有纯水9,各分槽均设有第一提升泵6以及与第一提升泵6连接的第一水洗口7,第一提升泵6能够将分槽内的纯水9输送至第一水洗口7,对带有锌层的黄铜钢丝进行水洗。The washing tank 8 includes one or more disconnected sub-troughs, and pure water 9 is filled in the sub-troughs, and each sub-trough is provided with a first lifting pump 6 and a first washing port 7 connected with the first lifting pump 6, The first lift pump 6 can transport the pure water 9 in the sub-tank to the first water washing port 7 to wash the brass steel wire with zinc layer.

湿拉机床10内盛有润滑液11,湿拉机床10设有循环系统12,湿拉机床10的进口端和出口端均设有第一过线导轮15。带有锌层的黄铜钢丝水洗后通过湿拉机床10进口端的第一过线导轮15进入湿拉机床10进行湿拉工序,湿拉拉拔后得到的带有氧化锌层的单丝13经过出口端的第一过线导轮15传送至单丝收线轮14进行收线。The lubricating fluid 11 is filled in the wet drawing machine 10 , the wet drawing machine 10 is provided with a circulation system 12 , and the inlet and outlet ends of the wet drawing machine 10 are provided with first wire passing guide wheels 15 . After washing, the brass steel wire with zinc layer enters the wet drawing machine 10 through the first wire passing guide wheel 15 at the inlet end of the wet drawing machine 10 to carry out the wet drawing process, and the monofilament 13 with the zinc oxide layer obtained after wet drawing The first wire passing guide wheel 15 at the outlet end is sent to the monofilament take-up wheel 14 for take-up.

本实施例中,带有锌层的黄铜钢丝水洗后直接进行湿拉,进入湿拉前钢丝表面需保持清洁,因此水洗槽8通常设多个不连通的分槽进行清洗。本实施例适合单丝的小批量生产。In this embodiment, the brass steel wire with zinc layer is wet-drawn directly after washing, and the surface of the steel wire needs to be kept clean before wet-drawing. Therefore, the washing tank 8 is usually provided with a plurality of disconnected separate tanks for cleaning. This embodiment is suitable for small batch production of monofilaments.

实施例3Example 3

本实施例提供一种单丝的生产方法,步骤如下:在黄铜钢丝的表面镀锌,得到带有锌层的黄铜钢丝,控制锌层的克重为0.08~1g/kg;将带有锌层的黄铜钢丝依序进行水洗、磷酸洗、再水洗和收线,得到酸洗后的钢丝;对酸洗后的钢丝进行湿拉和收线,得到单丝。This embodiment provides a production method of monofilament, the steps are as follows: galvanize the surface of the brass steel wire to obtain a brass steel wire with a zinc layer, and control the grammage of the zinc layer to be 0.08 to 1 g/kg; The brass steel wire of the zinc layer is washed with water, phosphoric acid washed, washed with water and taken up in sequence to obtain the steel wire after pickling; the steel wire after pickling is wet-drawn and taken up to obtain a monofilament.

本实施例与实施例1的不同之处在于,带有锌层的黄铜钢丝水洗后进行磷酸洗、再水洗和收线,磷酸洗使钢丝表面覆盖一层薄膜,避免钢丝镀层氧化,使得钢丝在湿拉前可以存放一定天数,无需及时流转,且钢丝可以多头同时电镀,适合单丝的大规模生产。The difference between this example and Example 1 is that the brass steel wire with zinc layer is washed with water, then phosphoric acid washed, then washed with water and taken up. Phosphoric acid washes the surface of the steel wire to cover a layer of film to avoid the oxidation of the steel wire coating, so that the steel wire It can be stored for a certain number of days before wet drawing, without timely circulation, and multiple wires can be electroplated at the same time, which is suitable for large-scale production of single wires.

实施例4Example 4

如图2所示,本实施例提供一种单丝的生产装置,用于生产实施例3中的单丝,结构包括依次设置的镀锌槽3、水洗槽8、磷酸槽22、再水洗槽16、酸洗后的钢丝收线轮19、湿拉机床和单丝收线轮。As shown in Figure 2, the present embodiment provides a monofilament production device, which is used to produce the monofilament in Example 3. The structure includes a galvanizing tank 3, a washing tank 8, a phosphoric acid tank 22, and a water washing tank arranged in sequence. 16. Steel wire take-up reel after pickling. 19. Wet drawing machine and monofilament take-up reel.

本实施例中镀锌槽3、湿拉机床和单丝收线轮的结构均与实施例2相同。The structures of the galvanizing tank 3, the wet drawing machine and the monofilament take-up wheel in this embodiment are all the same as those in Embodiment 2.

本实施例中由于带有锌层的黄铜钢丝在水洗槽8水洗后进行磷酸洗,所以水洗槽8设置的分槽数量可少于实施例2中水洗槽的分槽数量,如图2中只设1个分槽。In the present embodiment, due to the brass steel wire with the zinc layer is washed with phosphoric acid after washing in the washing tank 8, the number of sub-grooves provided by the washing tank 8 can be less than that of the washing tank in embodiment 2, as shown in Figure 2 There is only 1 sub-slot.

磷酸槽22内盛有磷酸液23,磷酸槽22通过隔板21分隔为上槽体和下槽体,下槽体和上槽体间连接有第二提升泵24,第二提升泵24可将下槽体内的磷酸液23输送至上槽体进行钢丝磷酸洗,形成上槽体和下槽体间的连通。Phosphoric acid liquid 23 is filled in the phosphoric acid tank 22, and the phosphoric acid tank 22 is separated into an upper tank body and a lower tank body by a partition 21, and a second lifting pump 24 is connected between the lower tank body and the upper tank body, and the second lifting pump 24 can The phosphoric acid solution 23 in the lower tank is transported to the upper tank for steel wire phosphoric acid washing to form a connection between the upper tank and the lower tank.

再水洗槽16设有第三提升泵20以及与第三提升泵20连接的第二水洗口25,第三提升泵20能够将再水洗槽16内的纯水输送至第二水洗口25对钢丝进行清洗。再水洗槽16与酸洗后的钢丝收线轮19之间设有第二过线导轮18,用于酸洗后的钢丝17的收线。The rewash tank 16 is provided with a third lift pump 20 and a second water wash port 25 connected with the third lift pump 20, and the third lift pump 20 can deliver the pure water in the rewash tank 16 to the second water wash port 25. Clean up. The second wire passing guide wheel 18 is arranged between the water washing tank 16 and the steel wire take-up wheel 19 after pickling, which is used for the take-up of the steel wire 17 after pickling.

实施例5Example 5

一包直径0.50mm的黄铜钢丝,黄铜涂层厚度0.4μm,黄铜涂层中铜含量60.21%,经过电镀锌、水洗、磷酸洗和再水洗之后收线,获得表面带有0.08g/kg的薄锌层黄铜钢丝,以87.75%的丝径压缩率经湿拉拉拔为0.175mm单丝,后捻制为A结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2,A结构帘线的初始硫化和老化数据见于表3。A package of brass steel wire with a diameter of 0.50mm, a brass coating thickness of 0.4μm, and a copper content of 60.21% in the brass coating. kg of thin zinc-coated brass steel wire is drawn into a 0.175mm monofilament by wet drawing at a wire diameter compression rate of 87.75%, and then twisted into an A-structure cord. The coating parameters of the brass steel wire are shown in Table 1. Monofilament, curtain The coating parameters of the cord and the surface zinc oxide layer data are shown in Table 2, and the initial vulcanization and aging data of the A-structure cord are shown in Table 3.

实施例6Example 6

一包直径1.52mm黄铜钢丝,黄铜涂层厚度1.5μm,黄铜涂层中铜含量63.04%,钢丝经过电镀锌、水洗之后进入湿拉机床,湿拉前电镀薄锌层的含量为0.24g/kg,以96.00%的丝径压缩率经湿拉拉拔为0.30mm单丝,后捻制为B结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2,B结构帘线的初始硫化和老化数据见于表3。A package of brass steel wire with a diameter of 1.52mm, the thickness of the brass coating is 1.5μm, and the copper content in the brass coating is 63.04%. After the steel wire is electro-galvanized and washed, it enters the wet drawing machine. g/kg, with a wire diameter compression ratio of 96.00%, it is wet-drawn into a 0.30mm monofilament, and then twisted into a B-structure cord. The coating parameters of the brass steel wire are shown in Table 1. The coating parameters of the monofilament and the cord The surface zinc oxide layer data is shown in Table 2, and the initial vulcanization and aging data of the B-structure cord are shown in Table 3.

实施例7Example 7

一包直径2.20mm黄铜钢丝,黄铜涂层厚度2.0μm,黄铜涂层中铜含量65.82%,过电镀锌、水洗、磷酸洗和再水洗之后收线,获得表面带有0.48g/kg的薄锌层黄铜钢丝,以97.02%的丝径压缩率经湿拉拉拔为0.38mm单丝,后捻制为C结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2,C结构帘线的初始硫化和老化数据见于表3。A package of brass steel wire with a diameter of 2.20mm, a brass coating thickness of 2.0μm, and a copper content of 65.82% in the brass coating. After electro-galvanizing, water washing, phosphoric acid washing and re-washing, the wire is taken up, and the surface has a surface concentration of 0.48g/kg. The thin zinc-coated brass steel wire is drawn into a 0.38mm monofilament by wet drawing at a wire diameter compression rate of 97.02%, and then twisted into a C-structure cord. The coating parameters of the brass steel wire are shown in Table 1. Monofilament, cord The coating parameters and surface zinc oxide layer data are shown in Table 2, and the initial vulcanization and aging data of the C-structure cord are shown in Table 3.

实施例8Example 8

一包直径3.14mm黄铜钢丝,黄铜涂层厚度2.2μm,黄铜涂层中铜含量67.91%,钢丝经过电镀锌、水洗之后进入湿拉机床,湿拉前电镀薄锌层的含量为0.70g/kg,以97.66%的丝径压缩率经湿拉拉拔为0.48mm单丝,单丝直接作为成品,黄铜钢丝镀层参数见表1,单丝的镀层参数及表面氧化锌层数据见于表2,其硫化数据见于表3。A pack of brass steel wire with a diameter of 3.14mm, the thickness of the brass coating is 2.2μm, and the copper content in the brass coating is 67.91%. g/kg, with a wire diameter compression rate of 97.66%, it is wet drawn into a 0.48mm monofilament, and the monofilament is directly used as a finished product. The coating parameters of the brass steel wire are shown in Table 1. The coating parameters of the monofilament and the surface zinc oxide layer data are found in Table 2, and its vulcanization data are found in Table 3.

实施例9Example 9

一包直径4.00mm黄铜钢丝,黄铜涂层厚度2.5μm,黄铜涂层中铜含量69.80%,钢丝经过电镀锌、水洗之后进入湿拉机床,湿拉前电镀薄锌层的含量为1.0g/kg,以96.00%的丝径压缩率经湿拉拉拔为0.8mm单丝,单丝直接作为成品,黄铜钢丝镀层参数见表1,单丝的镀层参数及表面氧化锌层数据见于表2,其硫化数据见于表3。A package of brass steel wire with a diameter of 4.00mm, the thickness of the brass coating is 2.5μm, and the copper content in the brass coating is 69.80%. g/kg, with 96.00% wire diameter compression rate, it is drawn into 0.8mm monofilament by wet drawing, and the monofilament is directly used as a finished product. The coating parameters of brass steel wire are shown in Table 1. The coating parameters of monofilament and the surface zinc oxide layer data are found in Table 2, and its vulcanization data are found in Table 3.

实施例10Example 10

一包直径1.52mm黄铜钢丝,黄铜涂层厚度1.5μm,黄铜涂层中铜含量63.06%,钢丝经过电镀锌、水洗之后进入湿拉机床,湿拉前电镀薄锌层的含量为0.09g/kg,以96.00%的丝径压缩率经湿拉拉拔为0.30mm单丝,后捻制为B结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2。A pack of brass steel wire with a diameter of 1.52mm, the thickness of the brass coating is 1.5μm, and the copper content in the brass coating is 63.06%. g/kg, with a wire diameter compression ratio of 96.00%, it is wet-drawn into a 0.30mm monofilament, and then twisted into a B-structure cord. The coating parameters of the brass steel wire are shown in Table 1. The coating parameters of the monofilament and the cord The surface zinc oxide layer data are shown in Table 2.

实施例11Example 11

一包直径1.52mm黄铜钢丝,黄铜涂层厚度1.5μm,黄铜涂层中铜含量63.06%,钢丝经过电镀锌、水洗之后进入湿拉机床,湿拉前电镀薄锌层的含量为0.50g/kg,以96.00%的丝径压缩率经湿拉拉拔为0.30mm单丝,后捻制为B结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2。A pack of brass steel wire with a diameter of 1.52mm, the thickness of the brass coating is 1.5μm, and the copper content in the brass coating is 63.06%. g/kg, with a wire diameter compression ratio of 96.00%, it is wet-drawn into a 0.30mm monofilament, and then twisted into a B-structure cord. The coating parameters of the brass steel wire are shown in Table 1. The coating parameters of the monofilament and the cord The surface zinc oxide layer data are shown in Table 2.

实施例12Example 12

一包直径1.52mm黄铜钢丝,黄铜涂层厚度1.5μm,黄铜涂层中铜含量63.06%,钢丝经过电镀锌、水洗之后进入湿拉机床,湿拉前电镀薄锌层的含量为0.73g/kg,以96.00%的丝径压缩率经湿拉拉拔为0.30mm单丝,后捻制为B结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2。A package of brass steel wire with a diameter of 1.52mm, the thickness of the brass coating is 1.5μm, and the copper content in the brass coating is 63.06%. g/kg, with a wire diameter compression ratio of 96.00%, it is wet-drawn into a 0.30mm monofilament, and then twisted into a B-structure cord. The coating parameters of the brass steel wire are shown in Table 1. The coating parameters of the monofilament and the cord The surface zinc oxide layer data are shown in Table 2.

实施例13Example 13

一包直径1.52mm黄铜钢丝,黄铜涂层厚度1.5μm,黄铜涂层中铜含量63.06%,钢丝经过电镀锌、水洗之后进入湿拉机床,湿拉前电镀薄锌层的含量为0.98g/kg,以96.00%的丝径压缩率经湿拉拉拔为0.30mm单丝,后捻制为B结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2。A pack of brass steel wire with a diameter of 1.52mm, the thickness of the brass coating is 1.5μm, and the copper content in the brass coating is 63.06%. g/kg, with a wire diameter compression ratio of 96.00%, it is wet-drawn into a 0.30mm monofilament, and then twisted into a B-structure cord. The coating parameters of the brass steel wire are shown in Table 1. The coating parameters of the monofilament and the cord The surface zinc oxide layer data are shown in Table 2.

对比例1Comparative example 1

一包直径0.50mm黄铜钢丝,黄铜涂层厚度0.4μm,黄铜涂层中铜含量60.21%,直接以87.75%的丝径压缩率经湿拉拉拔为0.175mm单丝,后捻制为A结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2,A结构帘线的初始硫化和老化数据见于表3。A package of brass steel wire with a diameter of 0.50mm, the thickness of the brass coating is 0.4μm, and the copper content in the brass coating is 60.21%. It is directly drawn into a 0.175mm monofilament by wet drawing at a wire diameter compression rate of 87.75%, and then twisted It is A structure cord, and the coating parameters of brass steel wire are shown in Table 1. The coating parameters of monofilament and cord and the surface zinc oxide layer data are shown in Table 2. The initial vulcanization and aging data of A structure cord are shown in Table 3.

对比例2Comparative example 2

一包直径1.52mm黄铜钢丝,黄铜涂层厚度1.5μm,黄铜涂层中铜含量62.43%,以96.00%的丝径压缩率经湿拉拉拔为0.30mm单丝,后捻制为B结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2,B结构帘线的初始硫化和老化数据见于表3。A pack of brass steel wire with a diameter of 1.52mm, the thickness of the brass coating is 1.5μm, the copper content in the brass coating is 62.43%, and the wire diameter compression rate is 96.00%. For structure B cords, see Table 1 for coating parameters of brass steel wires, Table 2 for coating parameters and surface zinc oxide layer data for monofilaments and cords, and Table 3 for initial vulcanization and aging data for structure B cords.

对比例3Comparative example 3

一包直径2.20mm黄铜钢丝,黄铜涂层厚度2.0μm,黄铜涂层中铜含量64.32%,以97.02%的丝径压缩率经湿拉拉拔为0.38mm单丝,后捻制为C结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2,C结构帘线的初始硫化和老化数据见于表3。A pack of brass steel wire with a diameter of 2.20mm, the thickness of the brass coating is 2.0μm, the copper content in the brass coating is 64.32%, and the wire diameter compression ratio is 97.02% After wet drawing, it is drawn into a 0.38mm monofilament, and then twisted into The coating parameters of the C structure cord and brass steel wire are shown in Table 1, the coating parameters of the monofilament and the cord and the surface zinc oxide layer data are shown in Table 2, and the initial vulcanization and aging data of the C structure cord are shown in Table 3.

对比例4Comparative example 4

一包直径3.14mm黄铜钢丝,黄铜涂层厚度2.2μm,黄铜涂层中铜含量66.36%,钢以97.66%的丝径压缩率经湿拉拉拔为0.48mm单丝,单丝直接作为成品,黄铜钢丝镀层参数见表1,单丝的镀层参数及表面氧化锌层数据见于表2,其硫化数据见于表3。A package of brass steel wire with a diameter of 3.14mm, the thickness of the brass coating is 2.2μm, and the copper content in the brass coating is 66.36%. As a finished product, the coating parameters of the brass steel wire are shown in Table 1, the coating parameters of the single wire and the surface zinc oxide layer data are shown in Table 2, and the vulcanization data are shown in Table 3.

对比例5Comparative example 5

一包直径4.00mm黄铜钢丝,黄铜涂层厚度2.5μm,黄铜涂层中铜含量67.24%,以96.00%的丝径压缩率经湿拉拉拔为0.8mm单丝,单丝直接作为成品,黄铜钢丝镀层参数见表1,单丝的镀层参数及表面氧化锌层数据见于表2,其硫化数据见于表3。A pack of brass steel wire with a diameter of 4.00mm, the thickness of the brass coating is 2.5μm, the copper content in the brass coating is 67.24%, and it is drawn into a 0.8mm monofilament by wet drawing at a wire diameter compression rate of 96.00%. The coating parameters of the finished product and brass steel wire are shown in Table 1, the coating parameters of the single wire and the surface zinc oxide layer data are shown in Table 2, and the vulcanization data are shown in Table 3.

对比例6Comparative example 6

一包直径1.52mm黄铜钢丝,黄铜涂层厚度1.5μm,黄铜涂层中铜含量65.07%,钢丝经过电镀锌、水洗之后进入湿拉机床,湿拉前电镀薄锌层的含量为1.18g/kg,以96.00%的丝径压缩率经湿拉拉拔为0.30mm单丝,后捻制为B结构帘线,黄铜钢丝镀层参数见表1,单丝、帘线的镀层参数及表面氧化锌层数据见于表2,B结构帘线的初始硫化数据见于表3。A package of brass steel wire with a diameter of 1.52mm, the thickness of the brass coating is 1.5μm, and the copper content in the brass coating is 65.07%. g/kg, with a wire diameter compression ratio of 96.00%, it is wet-drawn into a 0.30mm monofilament, and then twisted into a B-structure cord. The coating parameters of the brass steel wire are shown in Table 1. The coating parameters of the monofilament and the cord The surface zinc oxide layer data is shown in Table 2, and the initial vulcanization data of the B-structure cord is shown in Table 3.

对比例7Comparative example 7

一包直径3.14mm黄铜钢丝,黄铜涂层厚度2.2μm,黄铜涂层中铜含量69.24%,钢丝经过电镀锌、水洗之后进入湿拉机床,湿拉前电镀薄锌层的含量为1.20g/kg,以97.66%的丝径压缩率经湿拉拉拔为0.48mm单丝,单丝直接作为成品,黄铜钢丝镀层参数见表1,单丝的镀层参数及表面氧化锌层数据见于表2,其初始硫化数据见于表3。A pack of brass steel wire with a diameter of 3.14mm, the thickness of the brass coating is 2.2μm, and the copper content in the brass coating is 69.24%. g/kg, with a wire diameter compression rate of 97.66%, it is wet drawn into a 0.48mm monofilament, and the monofilament is directly used as a finished product. The coating parameters of the brass steel wire are shown in Table 1. The coating parameters of the monofilament and the surface zinc oxide layer data are found in Table 2 with initial vulcanization data in Table 3.

前述实施例5~13和对比例1~7中相同规格帘线初始硫化和老化均采用同种胶料,A、B、C规格帘线分别采用胶料R1、R2和R3胶料,实施例8、对比例4、对比例7的成品丝使用R4胶料,实施例9、对比例5的成品丝使用R5胶料。其中R1、R2、R3为同类型钢丝产品胶料,R4、R5为同类型钢丝产品胶料。The cords of the same specifications in the aforementioned Examples 5-13 and Comparative Examples 1-7 all adopt the same rubber material for initial vulcanization and aging, and the cords of A, B, and C specifications use rubber materials R1, R2, and R3 respectively. 8. The finished yarns of Comparative Example 4 and Comparative Example 7 used R4 sizing material, and the finished yarns of Example 9 and Comparative Example 5 used R5 sizing material. Among them, R1, R2, and R3 are rubber materials for steel wire products of the same type, and R4 and R5 are rubber materials for steel wire products of the same type.

表1各实施例或对比例黄铜钢丝镀层参数Each embodiment of table 1 or comparative example brass steel wire coating parameter

Figure BDA0004060902360000121
Figure BDA0004060902360000121

表2各实施例或对比例单丝、帘线的镀层参数和表面氧化锌数据Each embodiment of table 2 or comparative example monofilament, the coating parameter of cord and surface zinc oxide data

Figure BDA0004060902360000122
Figure BDA0004060902360000122

表3各实施例或对比实施例单丝、帘线初始硫化和老化粘合数据Table 3 Initial vulcanization and aging adhesion data of each embodiment or comparative example monofilament, cord

Figure BDA0004060902360000131
Figure BDA0004060902360000131

由表2数据可知:实施例6、10~13和对比例2随着黄铜钢丝上镀薄锌层的量增多,其对应单丝或帘线表面氧化锌含量增加,其中单丝表面氧化锌含量自0.022g/m2增至0.179g/m2,帘线表面氧化锌含量自0.030g/m2增至0.189g/m2;当薄锌层含量>1g/kg时,单丝、帘线表面氧化锌含量>0.2g/m2,单丝、帘线涂层中铜含量下降明显,下降幅度>2%,对比例6黄铜钢丝上镀薄锌层量为1.18g/kg,其对应单丝和帘线表面氧化锌含量分别为0.220g/m2、0.228g/m2,帘线与拉拔前钢丝镀层铜含量相比下降2.29%,对比例7黄铜钢丝上镀薄锌层量为1.20g/kg,其对应单丝表面氧化锌含量为0.235g/m2,单丝与拉拔前钢丝镀层铜含量相比下降2.80%。From the data in Table 2, it can be seen that in Examples 6, 10-13 and Comparative Example 2, as the amount of thin zinc coating on the brass steel wire increases, the zinc oxide content on the surface of the corresponding monofilament or cord increases, and the zinc oxide content on the surface of the monofilament increases. content increased from 0.022g/m 2 to 0.179g/m 2 , and the content of zinc oxide on the cord surface increased from 0.030g/m 2 to 0.189g/m 2 ; The zinc oxide content on the surface of the wire is more than 0.2g/m 2 , and the copper content in the monofilament and cord coating drops significantly, and the rate of decline is more than 2%. The zinc oxide content on the surface of the corresponding monofilament and the cord is 0.220g/m 2 and 0.228g/m 2 respectively, and the copper content of the cord coating is 2.29% lower than that of the steel wire before drawing. Comparative Example 7 The brass steel wire is coated with thin zinc The layer weight is 1.20g/kg, which corresponds to a zinc oxide content of 0.235g/m 2 on the surface of the monofilament, and the copper content of the monofilament is 2.80% lower than that of the steel wire coating before drawing.

表3中为各实施例或对比例中单丝或帘线的初始硫化和老化粘合数据,其中老化主要包括湿和热老化,分别为72h的93℃/95%RH湿热老化,48h的120℃蒸汽老化。由表3数据可知:实施例5~9黄铜钢丝表面上镀≤1g/kg的薄锌层后,无论是对应单丝或帘线其初始粘合力与对比例1~5黄铜钢丝相比初始粘合均相近,波动范围为-2.5~+3.3%;经过特殊湿热或蒸汽老化条件后钢丝粘合均下降,实施例5~7带有薄锌层的黄铜钢丝下降范围分别为15%、15%、10%和30%、22%、12%,对比例1~3黄铜钢丝下降范围分别为25%、23%、15%和36%、27%、30%,可见带有≤1g/kg薄锌层的钢丝经拉拔或捻制后单丝或帘线初始粘合与黄铜丝相近,但湿和热老化保持率高出约5~18%。Table 3 shows the initial vulcanization and aging adhesion data of monofilaments or cords in various examples or comparative examples, wherein the aging mainly includes wet and heat aging, which are 93°C/95%RH wet heat aging for 72h, 120% for 48h °C steam aging. From the data in Table 3, it can be seen that: after the thin zinc layer of ≤ 1g/kg is plated on the surface of the brass steel wire of Examples 5-9, the initial adhesion of the corresponding monofilament or cord is comparable to that of the brass steel wire of Comparative Examples 1-5. Compared with the initial adhesion, the fluctuation range is -2.5~+3.3%; the adhesion of steel wires decreases after special humid heat or steam aging conditions, and the reduction range of the brass steel wires with thin zinc layer in Examples 5 to 7 is 15% respectively. %, 15%, 10%, and 30%, 22%, 12%, the ranges of the brass steel wires in comparative examples 1 to 3 are 25%, 23%, 15%, and 36%, 27%, and 30%, respectively. It can be seen that there are Steel wires with a thin zinc layer of ≤1g/kg after drawing or twisting have similar initial adhesion to brass wires, but the wet and heat aging retention rates are about 5-18% higher.

以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和变形,这些改进和变形也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention, it should be pointed out that for those of ordinary skill in the art, without departing from the technical principle of the present invention, some improvements and modifications can also be made. It should also be regarded as the protection scope of the present invention.

Claims (10)

1.一种单丝的生产方法,其特征在于,包括以下步骤:1. a production method of monofilament, is characterized in that, comprises the following steps: 在黄铜钢丝的表面镀锌,得到带有锌层的黄铜钢丝,所述锌层的克重为0.08~1g/kg;Galvanizing the surface of the brass steel wire to obtain a brass steel wire with a zinc layer, the grammage of the zinc layer is 0.08-1g/kg; 将带有锌层的黄铜钢丝依序进行水洗、湿拉和收线,得到单丝。The brass steel wire with zinc layer is washed with water, wet drawn and taken up in sequence to obtain monofilament. 2.根据权利要求1所述的单丝的生产方法,其特征在于,所述带有锌层的黄铜钢丝水洗后依序进行磷酸洗、再水洗和收线,得到酸洗后的钢丝;对酸洗后的钢丝进行湿拉和收线,得到单丝。2. The production method of monofilament according to claim 1, characterized in that, after the brass steel wire with zinc layer is washed, phosphoric acid wash, rewash and take-up are carried out in sequence to obtain the steel wire after pickling; The pickled steel wire is wet-drawn and taken up to obtain a monofilament. 3.根据权利要求1所述的单丝的生产方法,其特征在于,所述黄铜钢丝的直径为0.5~4.0mm,所述黄铜钢丝表面黄铜涂层的厚度为0.4~2.5μm,黄铜涂层中铜的重量百分比为60~70%。3. The production method of monofilament according to claim 1, characterized in that, the diameter of the brass steel wire is 0.5-4.0 mm, and the thickness of the brass coating on the surface of the brass steel wire is 0.4-2.5 μm, The weight percentage of copper in the brass coating is 60-70%. 4.根据权利要求1所述的单丝的生产方法,其特征在于,所述湿拉步骤中钢丝的丝径压缩率>80%。4 . The production method of monofilament according to claim 1 , characterized in that, in the step of wet drawing, the wire diameter compression rate of the steel wire is >80%. 5.一种单丝,其特征在于,采用权利要求1~4任一项所述方法生产得到。5. A monofilament, characterized in that it is produced by the method according to any one of claims 1-4. 6.一种权利要求5所述单丝的生产装置,其特征在于,包括依次设置的镀锌槽、水洗槽、湿拉机床和单丝收线轮。6. A production device for monofilament according to claim 5, characterized in that it comprises a galvanizing tank, a washing tank, a wet drawing machine and a monofilament take-up wheel arranged in sequence. 7.根据权利要求6所述的单丝的生产装置,其特征在于,所述镀锌槽内盛有硫酸锌镀液,所述镀锌槽内设有阳极架,所述镀锌槽外设有阴极辊,所述阳极架和阴极辊分别连接同一电源的正极和负极;7. The production device of monofilament according to claim 6, characterized in that, zinc sulfate plating solution is filled in the described galvanizing tank, an anode rack is arranged in the described galvanizing tank, and the peripheral equipment of the galvanizing tank There is a cathode roller, and the anode frame and the cathode roller are respectively connected to the positive pole and the negative pole of the same power supply; 所述水洗槽包括1个或多个不连通的分槽,所述分槽内盛有纯水,各分槽均设有第一提升泵以及与第一提升泵连接的第一水洗口;The water washing tank includes one or more disconnected sub-tanks filled with pure water, and each sub-tank is provided with a first lift pump and a first water washing port connected to the first lift pump; 所述湿拉机床内盛有润滑液,所述湿拉机床设有循环系统,所述湿拉机床的进口端和出口端均设有第一过线导轮。The lubricating fluid is filled in the wet drawing machine, and the wet drawing machine is provided with a circulation system, and the inlet end and the outlet end of the wet drawing machine are both provided with first wire passing guide wheels. 8.根据权利要求6所述的单丝的生产装置,其特征在于,包括依次设置的镀锌槽、水洗槽、磷酸槽、再水洗槽、酸洗后的钢丝收线轮、湿拉机床和单丝收线轮。8. the production device of monofilament according to claim 6, is characterized in that, comprises the galvanizing tank that arranges successively, washing tank, phosphoric acid tank, rewashing tank, steel wire take-up wheel after pickling, wet drawing machine and Monofilament take-up reels. 9.根据权利要求8所述的单丝的生产装置,其特征在于,所述磷酸槽内盛有磷酸液,所述磷酸槽通过隔板分隔为上槽体和下槽体,所述下槽体和上槽体间连接有第二提升泵;9. The production device of monofilament according to claim 8, characterized in that, phosphoric acid liquid is filled in the phosphoric acid tank, and the phosphoric acid tank is divided into an upper tank body and a lower tank body by a partition, and the lower tank body A second lift pump is connected between the body and the upper tank; 所述再水洗槽设有第三提升泵以及与第三提升泵连接的第二水洗口;The rewash tank is provided with a third lift pump and a second water wash port connected to the third lift pump; 所述再水洗槽与酸洗后的钢丝收线轮之间设有第二过线导轮。A second wire passing guide wheel is provided between the re-washing tank and the pickled steel wire take-up wheel. 10.一种钢帘线,其特征在于,由权利要求5所述单丝捻制获得。10. A steel cord, characterized in that it is obtained by twisting the monofilament according to claim 5.
CN202310058709.6A 2023-01-19 2023-01-19 A kind of steel cord, monofilament and its production method and production device Pending CN116005212A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202310058709.6A CN116005212A (en) 2023-01-19 2023-01-19 A kind of steel cord, monofilament and its production method and production device
PCT/CN2023/076097 WO2024152396A1 (en) 2023-01-19 2023-02-15 Steel cord, and monofilament and production method and production device therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310058709.6A CN116005212A (en) 2023-01-19 2023-01-19 A kind of steel cord, monofilament and its production method and production device

Publications (1)

Publication Number Publication Date
CN116005212A true CN116005212A (en) 2023-04-25

Family

ID=86024756

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310058709.6A Pending CN116005212A (en) 2023-01-19 2023-01-19 A kind of steel cord, monofilament and its production method and production device

Country Status (2)

Country Link
CN (1) CN116005212A (en)
WO (1) WO2024152396A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2063725A (en) * 1979-11-23 1981-06-10 Sodetal Manufacture of wires for reinforcing rubber articles
CN101942686A (en) * 2009-07-07 2011-01-12 襄樊宇虹金属制品有限公司 Production process of coppered steel wire for enhancing rubber hose
JP2012036543A (en) * 2010-08-11 2012-02-23 Bridgestone Corp Method for manufacturing rubber-reinforcing steel wire and rubber-reinforcing steel wire
CN106191894A (en) * 2016-08-22 2016-12-07 江苏兴达钢帘线股份有限公司 Steel Wire Heat Treatment descaling bath anti-leak protection device

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4143209A (en) * 1977-06-07 1979-03-06 The Goodyear Tire & Rubber Company Process for making zinc coated steel wire and product made thereby
AT362666B (en) * 1977-06-07 1981-06-10 Goodyear Tire & Rubber STEEL REINFORCEMENT WIRE CONNECTABLE WITH RUBBER
GB8615746D0 (en) * 1986-06-27 1986-08-06 Bekaert Sa Nv Brass-coated steel elements
JP5907597B2 (en) * 2011-11-15 2016-04-26 株式会社ブリヂストン Brass-plated steel wire manufacturing method and brass-plated steel wire
CN103643572B (en) * 2013-11-21 2016-01-06 江苏天舜金属材料集团有限公司 A kind of manufacture method of heat treatment prestress wire
CN113000618B (en) * 2021-02-25 2023-01-17 江苏兴达钢帘线股份有限公司 Manufacturing method of monofilament steel cord and steel wire stress relieving device
CN113668027A (en) * 2021-07-29 2021-11-19 江苏兴达钢帘线股份有限公司 Method for manufacturing brass plating layer steel wire, tire bead steel wire, rubber tube steel wire and steel cord

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2063725A (en) * 1979-11-23 1981-06-10 Sodetal Manufacture of wires for reinforcing rubber articles
CN101942686A (en) * 2009-07-07 2011-01-12 襄樊宇虹金属制品有限公司 Production process of coppered steel wire for enhancing rubber hose
JP2012036543A (en) * 2010-08-11 2012-02-23 Bridgestone Corp Method for manufacturing rubber-reinforcing steel wire and rubber-reinforcing steel wire
CN106191894A (en) * 2016-08-22 2016-12-07 江苏兴达钢帘线股份有限公司 Steel Wire Heat Treatment descaling bath anti-leak protection device

Also Published As

Publication number Publication date
WO2024152396A1 (en) 2024-07-25

Similar Documents

Publication Publication Date Title
US5100517A (en) Process for applying a copper layer to steel wire
CN107824630A (en) A kind of metal wire, its manufacture method and tire
CN107442596B (en) A kind of steel cord production method
US9951469B2 (en) Steel cord for rubber reinforcement
CN214991962U (en) Water electroplating equipment for electroplating processing of surface of flexible film substrate
KR101293275B1 (en) Two-layered Metal Fibers and Manufacturing Method thereof, Ply Yarn and Ply Method, and the Fabric using the Ply Yarn
CN109518131A (en) A kind of ultrathin copper foil with carrier, ultrathin copper foil production method and device
CN116005212A (en) A kind of steel cord, monofilament and its production method and production device
WO2023202267A1 (en) Multi-metal compounding method for polymeric fiber material, and multi-metal composite fiber
CN111321442A (en) Production process of tire bead steel wire with high-tin bronze coating
US6892667B2 (en) Continuous plating method of filament bundle and apparatus therefor
JP2020126720A (en) Conductive fiber, cable and method for producing conductive fiber
CN114934308B (en) High-temperature superconducting strip copper electroplating device and method based on insoluble anode
CN107460528A (en) A kind of tinning stack
CN218932399U (en) Spinning equipment with automatic water supply and drainage function
CN212919013U (en) Double-line transformation equipment for electroplating production of diamond wires
CN205711019U (en) A kind of electrolytic tinning device
JP2015021184A (en) Method of manufacturing metal wire for reinforcement of rubber article, metal wire for reinforcement of rubber article, pneumatic tire using the same and apparatus for manufacturing metal wire for reinforcement of rubber article
CN222499380U (en) Aluminum alloy wire surface modification processing line
CN210846960U (en) Production equipment of environment-friendly metal color nylon rubber-coated wire
KR100353161B1 (en) Method for making a plated steel wire for steel cord
CN113186611A (en) PBO filament continuous washing device and method
CN220155194U (en) Durable double-layer multi-strand guide wire for intubation
CN112725872B (en) Device and method for high-speed electrodeposition of metal on continuous carbon fiber surface
CN213781640U (en) Tinned monofilament with improved toughness and strength

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination