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CN115939238B - Heterogeneous infrared SAM-APD material, heterogeneous infrared SAM-APD and preparation method thereof - Google Patents

Heterogeneous infrared SAM-APD material, heterogeneous infrared SAM-APD and preparation method thereof Download PDF

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CN115939238B
CN115939238B CN202211467066.2A CN202211467066A CN115939238B CN 115939238 B CN115939238 B CN 115939238B CN 202211467066 A CN202211467066 A CN 202211467066A CN 115939238 B CN115939238 B CN 115939238B
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apd
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CN115939238A (en
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王登魁
方铉
项超
房丹
牛守柱
楚学影
翟英娇
李金华
王晓华
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Changchun University of Science and Technology
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Abstract

本申请提供一种异质红外SAM‑APD材料、异质红外SAM‑APD及其制备方法。异质红外SAM‑APD材料,包括III‑V族吸收层、Si倍增结构层以及设置在III‑V族吸收层和Si倍增结构层之间的III‑V族垂直超晶格缓冲层。异质红外SAM‑APD的制备方法:通过离子注入技术对Si进行掺杂得到Si倍增结构层;在Si倍增结构层的表面依次外延生长III‑V族垂直超晶格缓冲层和III‑V族吸收层;采用紫外光刻技术制作刻蚀图形,利用电感耦合等离子体设备刻蚀APD台面结构,得到异质红外SAM‑APD。本申请提供的异质红外SAM‑APD材料,实现APD工作波长的拓展和增益性能的提升,易于实现硅基片上集成。

The present application provides a heterogeneous infrared SAM‑APD material, a heterogeneous infrared SAM‑APD and a preparation method thereof. The heterogeneous infrared SAM‑APD material comprises a III‑V absorption layer, a Si multiplication structure layer and a III‑V vertical superlattice buffer layer arranged between the III‑V absorption layer and the Si multiplication structure layer. The preparation method of the heterogeneous infrared SAM‑APD: Si is doped by ion implantation technology to obtain a Si multiplication structure layer; a III‑V vertical superlattice buffer layer and a III‑V absorption layer are sequentially epitaxially grown on the surface of the Si multiplication structure layer; an etching pattern is prepared by ultraviolet lithography technology, and an APD mesa structure is etched using an inductively coupled plasma device to obtain a heterogeneous infrared SAM‑APD. The heterogeneous infrared SAM‑APD material provided in the present application realizes the expansion of the APD operating wavelength and the improvement of the gain performance, and is easy to realize integration on a silicon substrate.

Description

异质红外SAM-APD材料、异质红外SAM-APD及其制备方法Heterogeneous infrared SAM-APD material, heterogeneous infrared SAM-APD and preparation method thereof

技术领域Technical Field

本申请涉及半导体材料领域,尤其涉及一种异质红外SAM-APD材料、异质红外SAM-APD及其制备方法。The present application relates to the field of semiconductor materials, and in particular to a heterogeneous infrared SAM-APD material, a heterogeneous infrared SAM-APD and a preparation method thereof.

背景技术Background Art

雪崩光电二极管(APD)作为快速、高增益探测器的典型代表,特别是红外波段的APD,在军用及民用光电子器件中都占有重要的地位,与此同时,硅基光电子集成是当今信息技术中最具发展前途的方向,被认为是解决当前电子器件瓶颈问题的关键,在激光通信、光互联及5G等技术方向具有广阔的应用前景,目前,硅基红外激光及波导器件性能已经基本达到商用标准,而红外探测器件的研究尚不充分,成为限制硅基光电子技术发展的重要因素。因此,开展与硅基技术兼容的红外APD器件研究,对硅基集成系统的发展和光电子器件的革新都具有重要意义。Avalanche photodiodes (APDs) are typical representatives of fast, high-gain detectors, especially infrared APDs, which play an important role in both military and civilian optoelectronic devices. At the same time, silicon-based optoelectronic integration is the most promising direction in today's information technology. It is considered to be the key to solving the current bottleneck problem of electronic devices and has broad application prospects in laser communications, optical interconnection, and 5G. At present, the performance of silicon-based infrared lasers and waveguide devices has basically reached commercial standards, while the research on infrared detection devices is still insufficient, which has become an important factor restricting the development of silicon-based optoelectronic technology. Therefore, research on infrared APD devices compatible with silicon-based technology is of great significance to the development of silicon-based integrated systems and the innovation of optoelectronic devices.

现阶段,硅APD具有高增益、低噪声等优点,是重要的可见光探测器,但由于Si禁带宽度的限制,其工作波长仅为400-1000nm,无法实现红外波段的覆盖,严重限制了其应用范围,尤其是在1.3μm和1.55μm波段的激光通讯领域。而InGaAs/InP基APD其噪声和带宽等性能都与Si APD存在差距,尤其还存在难以与硅基电子器件集成的问题。At present, silicon APD has the advantages of high gain and low noise, and is an important visible light detector. However, due to the limitation of Si bandgap width, its operating wavelength is only 400-1000nm, which cannot cover the infrared band, severely limiting its application range, especially in the field of laser communication in the 1.3μm and 1.55μm bands. InGaAs/InP-based APD has performance gaps in noise and bandwidth compared with Si APD, and is particularly difficult to integrate with silicon-based electronic devices.

发明内容Summary of the invention

本申请的目的在于提供一种异质红外SAM-APD(吸收倍增分离型雪崩光电二极管)材料、异质红外SAM-APD及其制备方法,以解决上述问题。The purpose of the present application is to provide a heterogeneous infrared SAM-APD (absorption multiplication separation avalanche photodiode) material, a heterogeneous infrared SAM-APD and a preparation method thereof to solve the above-mentioned problems.

为实现以上目的,本申请采用以下技术方案:To achieve the above objectives, this application adopts the following technical solutions:

一种异质红外SAM-APD材料,包括III-V族吸收层、Si倍增结构层以及设置在所述III-V族吸收层和所述Si倍增结构层之间的III-V族垂直超晶格缓冲层。A heterogeneous infrared SAM-APD material comprises a III-V group absorption layer, a Si multiplication structure layer and a III-V group vertical superlattice buffer layer arranged between the III-V group absorption layer and the Si multiplication structure layer.

优选地,所述III-V族吸收层包括InGaAs吸收层和InGaAs接触层,所述InGaAs吸收层与所述III-V族垂直超晶格缓冲层邻接;Preferably, the III-V group absorption layer comprises an InGaAs absorption layer and an InGaAs contact layer, and the InGaAs absorption layer is adjacent to the III-V group vertical superlattice buffer layer;

所述Si倍增结构层包括依次层叠设置的Si接触层、Si倍增层和Si电荷层,所述Si电荷层与所述III-V族垂直超晶格缓冲层邻接。The Si multiplication structure layer includes a Si contact layer, a Si multiplication layer and a Si charge layer which are stacked in sequence, and the Si charge layer is adjacent to the III-V group vertical superlattice buffer layer.

优选地,所述Si接触层为重掺杂的n型Si,所述Si倍增层为本征掺杂的Si,所述Si电荷层为重掺杂的p型Si。Preferably, the Si contact layer is heavily doped n-type Si, the Si multiplication layer is intrinsically doped Si, and the Si charge layer is heavily doped p-type Si.

优选地,所述III-V族垂直超晶格缓冲层为InAs/GaSb II型垂直超晶格缓冲层或InAs/InAsSb II型垂直超晶格缓冲层,所述InAs/GaSb II型垂直超晶格缓冲层包括依次层叠设置的GaSb缓冲层、GaSb层和InAs层,所述InAs/InAsSb II型垂直超晶格缓冲层包括依次层叠设置的GaAs缓冲层、InAs层和InAsSb层。Preferably, the III-V group vertical superlattice buffer layer is an InAs/GaSb II type vertical superlattice buffer layer or an InAs/InAsSb II type vertical superlattice buffer layer, the InAs/GaSb II type vertical superlattice buffer layer comprises a GaSb buffer layer, a GaSb layer and an InAs layer stacked in sequence, and the InAs/InAsSb II type vertical superlattice buffer layer comprises a GaAs buffer layer, an InAs layer and an InAsSb layer stacked in sequence.

优选地,所述III-V族垂直超晶格缓冲层为InAs/GaInSbⅡ型垂直超晶格缓冲层,所述InAs/GaInSbⅡ型垂直超晶格缓冲层包括依次层叠设置的GaAs层、GaSb缓冲层、InAs层和GaInSb层。Preferably, the III-V group vertical superlattice buffer layer is an InAs/GaInSbⅡ type vertical superlattice buffer layer, and the InAs/GaInSbⅡ type vertical superlattice buffer layer comprises a GaAs layer, a GaSb buffer layer, an InAs layer and a GaInSb layer which are stacked in sequence.

本申请还提供一种异质红外SAM-APD,其原料包括所述的异质红外SAM-APD材料。The present application also provides a heterogeneous infrared SAM-APD, the raw materials of which include the heterogeneous infrared SAM-APD material.

本申请还提供一种所述的异质红外SAM-APD的制备方法,包括:The present application also provides a method for preparing the heterogeneous infrared SAM-APD, comprising:

通过离子注入技术对Si进行掺杂得到所述Si倍增结构层;Doping Si by ion implantation technology to obtain the Si multiplication structure layer;

在所述Si倍增结构层的表面依次外延生长III-V族垂直超晶格缓冲层和III-V族吸收层;Epitaxially growing a III-V vertical superlattice buffer layer and a III-V absorption layer in sequence on the surface of the Si multiplication structure layer;

采用紫外光刻技术制作刻蚀图形,利用电感耦合等离子体设备刻蚀APD台面结构,得到所述异质红外SAM-APD。The etching pattern is made by using ultraviolet photolithography technology, and the APD table structure is etched by using inductively coupled plasma equipment to obtain the heterogeneous infrared SAM-APD.

与现有技术相比,本申请的有益效果包括:Compared with the prior art, the beneficial effects of this application include:

本申请提供的异质红外SAM-APD材料,将InGaAs红外吸收的特性和Si高增益、低噪声的优点有机结合,采用InGaAs作为吸收层,拓展探测器的工作波长;采用Si作为倍增层,保障探测器的雪崩及噪声特性,同时具有Si优异的倍增特性和InGaAs红外波段的吸收能力,更重要的还易于实现硅基片上集成,具有鲜明的特色。利用III-V族垂直超晶格缓冲层结构,抑制缺陷产生和传播,用周期性的横向应变降低缺陷穿透深度,达到降低异质结外延结构层中缺陷密度的目的,提升载流子分离传输效率;APD各层中的缺陷作为复合中心降低光生载流子的分离效率,同时吸收-倍增层的界面能带也降低了载流子的传输特性。常规的插入组分渐变层的方法仅能解决载流子传输问题,无法提高载流子分离效率,而III-V族垂直超晶格缓冲层结构,具有II型能带电子空穴波函数空间分离特性,并提供独立的电子空穴传输通道,可达到提高载流子分离效率并提升传输性能的目的。The heterogeneous infrared SAM-APD material provided by this application organically combines the infrared absorption characteristics of InGaAs and the advantages of high gain and low noise of Si. InGaAs is used as the absorption layer to expand the working wavelength of the detector; Si is used as the multiplication layer to ensure the avalanche and noise characteristics of the detector. At the same time, it has the excellent multiplication characteristics of Si and the absorption capacity of the infrared band of InGaAs. More importantly, it is easy to realize integration on a silicon substrate and has distinctive characteristics. The III-V vertical superlattice buffer layer structure is used to suppress the generation and propagation of defects, and the periodic lateral strain is used to reduce the penetration depth of defects, so as to achieve the purpose of reducing the defect density in the heterojunction epitaxial structure layer and improve the carrier separation and transmission efficiency; the defects in each layer of the APD act as recombination centers to reduce the separation efficiency of photogenerated carriers, and at the same time, the interface energy band of the absorption-multiplication layer also reduces the transmission characteristics of carriers. The conventional method of inserting a component gradient layer can only solve the problem of carrier transport but cannot improve the carrier separation efficiency. The III-V vertical superlattice buffer layer structure has the spatial separation characteristics of type II band electron-hole wave functions and provides an independent electron-hole transport channel, which can achieve the purpose of improving carrier separation efficiency and enhancing transport performance.

本申请提供的异质红外SAM-APD,大大拓展了光谱范围(1.1μm-10μm)和响应谱范围。The heterogeneous infrared SAM-APD provided in this application greatly expands the spectral range (1.1 μm-10 μm) and the response spectrum range.

本申请提供的异质红外SAM-APD的制备方法,工艺简单,可规模化生产应用。The preparation method of the heterogeneous infrared SAM-APD provided in the present application has a simple process and can be applied in large-scale production.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

为了更清楚地说明本申请实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本申请的某些实施例,因此不应被看作是对本申请范围的限定。In order to more clearly illustrate the technical solutions of the embodiments of the present application, the drawings required for use in the embodiments will be briefly introduced below. It should be understood that the following drawings only show certain embodiments of the present application and therefore should not be regarded as limiting the scope of the present application.

图1为本申请提供的异质红外SAM-APD材料的结构示意图;FIG1 is a schematic diagram of the structure of a heterogeneous infrared SAM-APD material provided in the present application;

图2为异质红外SAM-APD能带结构示意图;FIG2 is a schematic diagram of the energy band structure of a heterogeneous infrared SAM-APD;

图3为实施例提供的异质红外SAM-APD材料的结构示意图;FIG3 is a schematic diagram of the structure of a heterogeneous infrared SAM-APD material provided in an embodiment;

图4为实施例1提供的InAs/GaSb II型垂直超晶格缓冲层的TEM图;FIG4 is a TEM image of the InAs/GaSb II-type vertical superlattice buffer layer provided in Example 1;

图5为实施例1提供的InAs/GaSb II型垂直超晶格缓冲层的另外一张TEM图;FIG5 is another TEM image of the InAs/GaSb II-type vertical superlattice buffer layer provided in Example 1;

图6为实施例1提供的InAs/GaSb II型垂直超晶格缓冲层的XRD图;FIG6 is an XRD diagram of the InAs/GaSb II-type vertical superlattice buffer layer provided in Example 1;

图7为实施例1提供的InAs/GaSb II型垂直超晶格缓冲层的PL图;图8为实施例2提供的InAs/GaInSbⅡ型垂直超晶格缓冲层的PL图;FIG. 7 is a PL image of an InAs/GaSb II-type vertical superlattice buffer layer provided in Example 1; FIG. 8 is a PL image of an InAs/GaInSb II-type vertical superlattice buffer layer provided in Example 2;

图9为实施例3提供的InAs/InAsSbⅡ型垂直超晶格缓冲层的PL图;FIG9 is a PL image of the InAs/InAsSbⅡ type vertical superlattice buffer layer provided in Example 3;

图10为对比例1提供的传统的超晶格缓冲层结构示意图。FIG. 10 is a schematic diagram of a conventional superlattice buffer layer structure provided in Comparative Example 1.

附图标记:Reference numerals:

100-Si接触层;200-Si倍增层;300-Si电荷层;400-III-V族垂直超晶格缓冲层;500-InGaAs吸收层;600-InGaAs接触层。100-Si contact layer; 200-Si multiplication layer; 300-Si charge layer; 400-III-V vertical superlattice buffer layer; 500-InGaAs absorption layer; 600-InGaAs contact layer.

具体实施方式DETAILED DESCRIPTION

如本文所用之术语:As used herein:

“由……制备”与“包含”同义。本文中所用的术语“包含”、“包括”、“具有”、“含有”或其任何其它变形,意在覆盖非排它性的包括。例如,包含所列要素的组合物、步骤、方法、制品或装置不必仅限于那些要素,而是可以包括未明确列出的其它要素或此种组合物、步骤、方法、制品或装置所固有的要素。"Prepared from" is synonymous with "comprising." As used herein, the terms "comprising," "including," "having," "containing," or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a composition, process, method, article, or apparatus that comprises the listed elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, process, method, article, or apparatus.

连接词“由……组成”排除任何未指出的要素、步骤或组分。如果用于权利要求中,此短语将使权利要求为封闭式,使其不包含除那些描述的材料以外的材料,但与其相关的常规杂质除外。当短语“由……组成”出现在权利要求主体的子句中而不是紧接在主题之后时,其仅限定在该子句中描述的要素;其它要素并不被排除在作为整体的所述权利要求之外。The conjunction "consisting of excludes any unspecified element, step, or component. If used in a claim, this phrase renders the claim closed-ended so that it does not include materials other than those described, except for conventional impurities associated therewith. When the phrase "consisting of" appears in a clause of the body of a claim rather than immediately following the subject matter, it limits only the elements described in that clause; other elements are not excluded from the claim as a whole.

当量、浓度、或者其它值或参数以范围、优选范围、或一系列上限优选值和下限优选值限定的范围表示时,这应当被理解为具体公开了由任何范围上限或优选值与任何范围下限或优选值的任一配对所形成的所有范围,而不论该范围是否单独公开了。例如,当公开了范围“1~5”时,所描述的范围应被解释为包括范围“1~4”、“1~3”、“1~2”、“1~2和4~5”、“1~3和5”等。当数值范围在本文中被描述时,除非另外说明,否则该范围意图包括其端值和在该范围内的所有整数和分数。When an amount, concentration, or other value or parameter is expressed as a range, a preferred range, or a range defined by a series of upper preferred values and lower preferred values, this should be understood as specifically disclosing all ranges formed by any pairing of any range upper limit or preferred value with any range lower limit or preferred value, regardless of whether the range is disclosed separately. For example, when a range of "1 to 5" is disclosed, the described range should be interpreted as including ranges "1 to 4", "1 to 3", "1 to 2", "1 to 2 and 4 to 5", "1 to 3 and 5", etc. When a numerical range is described in this article, unless otherwise stated, the range is intended to include its end values and all integers and fractions within the range.

在这些实施例中,除非另有指明,所述的份和百分比均按质量计。In these examples, parts and percentages are by mass unless otherwise indicated.

“质量份”指表示多个组分的质量比例关系的基本计量单位,1份可表示任意的单位质量,如可以表示为1g,也可表示2.689g等。假如我们说A组分的质量份为a份,B组分的质量份为b份,则表示A组分的质量和B组分的质量之比a:b。或者,表示A组分的质量为aK,B组分的质量为bK(K为任意数,表示倍数因子)。不可误解的是,与质量份数不同的是,所有组分的质量份之和并不受限于100份之限制。"Parts by mass" refers to the basic unit of measurement for expressing the mass ratio of multiple components. 1 part can represent any unit mass, such as 1g or 2.689g. If we say that the mass of component A is a parts and the mass of component B is b parts, it means the ratio of the mass of component A to the mass of component B is a:b. Alternatively, it means that the mass of component A is aK and the mass of component B is bK (K is an arbitrary number, indicating a multiple factor). It should not be misunderstood that, unlike the mass parts, the sum of the mass of all components is not limited to 100 parts.

“和/或”用于表示所说明的情况的一者或两者均可能发生,例如,A和/或B包括(A和B)和(A或B)。"And/or" is used to indicate that one or both of the stated situations may occur, for example, A and/or B includes (A and B) and (A or B).

一种异质红外SAM-APD材料,包括III-V族吸收层、Si倍增结构层以及设置在所述III-V族吸收层和所述Si倍增结构层之间的III-V族垂直超晶格缓冲层。A heterogeneous infrared SAM-APD material comprises a III-V group absorption layer, a Si multiplication structure layer and a III-V group vertical superlattice buffer layer arranged between the III-V group absorption layer and the Si multiplication structure layer.

InGaAs/Si红外APD研究的难点在于高质量异质材料的制备,本申请提出硅基外延III-V族红外光半导体材料与硅结合,通过对化学键与Si结合,可以保障载流子在异质材料之间的高效传输,这也是实现InGaAs/Si异质红外APD的基础。Si倍增层上吸收层的高质量异质外延和吸收层-倍增层之间载流子的高效传输成为研究的重点。因此,降低外延层缺陷密度、抑制缺陷的传播与降低光生载流子复合效率、提高电子空穴的传输效率成为InGaAs/Si异质红外APD研究需要解决的关键问题。The difficulty in the study of InGaAs/Si infrared APD lies in the preparation of high-quality heterogeneous materials. This application proposes to combine silicon-based epitaxial III-V infrared semiconductor materials with silicon. By combining with Si through chemical bonds, the efficient transmission of carriers between heterogeneous materials can be guaranteed, which is also the basis for realizing InGaAs/Si heterogeneous infrared APD. The high-quality heteroepitaxiality of the absorption layer on the Si multiplication layer and the efficient transmission of carriers between the absorption layer and the multiplication layer have become the focus of research. Therefore, reducing the defect density of the epitaxial layer, inhibiting the propagation of defects, reducing the recombination efficiency of photogenerated carriers, and improving the transmission efficiency of electrons and holes have become the key issues that need to be solved in the study of InGaAs/Si heterogeneous infrared APD.

本申请针对上述的重点及难点,根据SAM-APD的工作原理,结合倍增层与吸收层分别采用Si和InGaAs材料的思想,设计了一种新型InGaAs/Si异质红外SAM-APD结构。在InGaAs与Si之间插入垂直分布的III-V族超晶格层,利用垂直分布超晶格结构中的横向应变抑制外延过程中缺陷的传播,有效降低缺陷密度,降低光生载流子散射效率;同时利用超晶格II型能带中电子和空穴波函数空间分离的特性,降低载流子复合效率,并形成独立的电子空穴高速传输通道,提升载流子的分离和传输效率,最终获得高性能的InGaAs/Si异质红外APD。其基本结构如图1所示,异质红外SAM-APD能带结构示意图如图2所示。In view of the above-mentioned key points and difficulties, this application designs a new type of InGaAs/Si heterogeneous infrared SAM-APD structure based on the working principle of SAM-APD and the idea of using Si and InGaAs materials for the multiplication layer and the absorption layer respectively. A vertically distributed III-V superlattice layer is inserted between InGaAs and Si, and the lateral strain in the vertically distributed superlattice structure is used to suppress the propagation of defects in the epitaxial process, effectively reducing the defect density and the efficiency of photogenerated carrier scattering; at the same time, the characteristics of the spatial separation of electron and hole wave functions in the superlattice type II energy band are used to reduce the carrier recombination efficiency, and an independent electron-hole high-speed transmission channel is formed to improve the separation and transmission efficiency of carriers, and finally obtain a high-performance InGaAs/Si heterogeneous infrared APD. Its basic structure is shown in Figure 1, and the schematic diagram of the heterogeneous infrared SAM-APD energy band structure is shown in Figure 2.

在一个可选的实施方式中,所述III-V族吸收层包括InGaAs吸收层和InGaAs接触层,所述InGaAs吸收层与所述III-V族垂直超晶格缓冲层邻接;In an optional embodiment, the III-V group absorption layer includes an InGaAs absorption layer and an InGaAs contact layer, and the InGaAs absorption layer is adjacent to the III-V group vertical superlattice buffer layer;

所述Si倍增结构层包括依次层叠设置的Si接触层、Si倍增层和Si电荷层,所述Si电荷层与所述III-V族垂直超晶格缓冲层邻接。The Si multiplication structure layer includes a Si contact layer, a Si multiplication layer and a Si charge layer which are stacked in sequence, and the Si charge layer is adjacent to the III-V group vertical superlattice buffer layer.

在一个可选的实施方式中,所述Si接触层为重掺杂的n型Si,所述Si倍增层为本征掺杂的Si,所述Si电荷层为重掺杂的p型Si。In an optional embodiment, the Si contact layer is heavily doped n-type Si, the Si multiplication layer is intrinsically doped Si, and the Si charge layer is heavily doped p-type Si.

在一个可选的实施方式中,所述III-V族垂直超晶格缓冲层为InAs/GaSb II型垂直超晶格缓冲层或InAs/InAsSb II型垂直超晶格缓冲层,所述InAs/GaSb II型垂直超晶格缓冲层包括依次层叠设置的GaSb缓冲层、GaSb层和InAs层,所述InAs/InAsSb II型垂直超晶格缓冲层包括依次层叠设置的GaAs缓冲层、InAs层和InAsSb层。In an optional embodiment, the III-V group vertical superlattice buffer layer is an InAs/GaSb II type vertical superlattice buffer layer or an InAs/InAsSb II type vertical superlattice buffer layer, the InAs/GaSb II type vertical superlattice buffer layer includes a GaSb buffer layer, a GaSb layer and an InAs layer stacked in sequence, and the InAs/InAsSb II type vertical superlattice buffer layer includes a GaAs buffer layer, an InAs layer and an InAsSb layer stacked in sequence.

InAs/GaSb II型垂直超晶格缓冲层或InAs/InAsSb II型垂直超晶格缓冲层,与所采用的InGaAs吸收层是晶格匹配的,不存在应力,具有较低的俄歇复合速率、带隙调节的灵活性和较高的材料均匀性,实现了电子与空穴的分离。The InAs/GaSb II vertical superlattice buffer layer or the InAs/InAsSb II vertical superlattice buffer layer is lattice-matched with the adopted InGaAs absorption layer, has no stress, has a lower Auger recombination rate, flexibility in bandgap adjustment and higher material uniformity, and realizes the separation of electrons and holes.

在一个可选的实施方式中,所述III-V族垂直超晶格缓冲层为InAs/GaInSbⅡ型垂直超晶格缓冲层,所述InAs/GaInSbⅡ型垂直超晶格缓冲层包括依次层叠设置的GaAs层、GaSb缓冲层、InAs层和GaInSb层。In an optional embodiment, the III-V group vertical superlattice buffer layer is an InAs/GaInSbⅡ type vertical superlattice buffer layer, and the InAs/GaInSbⅡ type vertical superlattice buffer layer includes a GaAs layer, a GaSb buffer layer, an InAs layer and a GaInSb layer stacked in sequence.

Sb基应变层超晶格(SLS)材料具有可调直接带隙的优点,InSb、InAsSb与InGaAs晶格匹配,基于InAs的II型结构,如InAs/InAsSb超晶格(SLs),为设计能带结构提供了显著的灵活性,能够抑制俄歇复合。Sb-based strained layer superlattice (SLS) materials have the advantage of tunable direct band gap, InSb, InAsSb and InGaAs lattice matching, and InAs-based type-II structures, such as InAs/InAsSb superlattices (SLs), provide significant flexibility in designing the band structure and can suppress Auger recombination.

本申请还提供一种异质红外SAM-APD,其原料包括所述的异质红外SAM-APD材料。The present application also provides a heterogeneous infrared SAM-APD, the raw materials of which include the heterogeneous infrared SAM-APD material.

本申请还提供一种所述的异质红外SAM-APD的制备方法,包括:The present application also provides a method for preparing the heterogeneous infrared SAM-APD, comprising:

通过离子注入技术对Si进行掺杂得到所述Si倍增结构层;Doping Si by ion implantation technology to obtain the Si multiplication structure layer;

在所述Si倍增结构层的表面依次外延生长III-V族垂直超晶格缓冲层和III-V族吸收层;Epitaxially growing a III-V vertical superlattice buffer layer and a III-V absorption layer in sequence on the surface of the Si multiplication structure layer;

采用紫外光刻技术制作刻蚀图形,利用电感耦合等离子体设备刻蚀APD台面结构,得到所述异质红外SAM-APD。The etching pattern is made by using ultraviolet photolithography technology, and the APD table structure is etched by using inductively coupled plasma equipment to obtain the heterogeneous infrared SAM-APD.

下面将结合具体实施例对本申请的实施方案进行详细描述,但是本领域技术人员将会理解,下列实施例仅用于说明本申请,而不应视为限制本申请的范围。实施例中未注明具体条件者,按照常规条件或制造商建议的条件进行。所用试剂或仪器未注明生产厂商者,均为可以通过市售购买获得的常规产品。The embodiments of the present application will be described in detail below in conjunction with specific examples, but it will be appreciated by those skilled in the art that the following examples are only used to illustrate the present application and should not be considered as limiting the scope of the present application. If specific conditions are not specified in the examples, they are carried out according to normal conditions or the conditions recommended by the manufacturer. If the manufacturer is not specified in the reagents or instruments used, they are all conventional products that can be purchased commercially.

实施例1Example 1

如图3所示,本实施例提供一种异质红外SAM-APD材料,由下至上依次包括Si接触层100、Si倍增层200、Si电荷层300、III-V族垂直超晶格缓冲层400、InGaAs吸收层500和InGaAs接触层600。As shown in FIG. 3 , this embodiment provides a heterogeneous infrared SAM-APD material, which includes, from bottom to top, a Si contact layer 100 , a Si multiplication layer 200 , a Si charge layer 300 , a III-V vertical superlattice buffer layer 400 , an InGaAs absorption layer 500 and an InGaAs contact layer 600 .

其中,Si接触层100为重掺杂的n型Si,Si倍增层200为本征掺杂的Si,Si电荷层300为重掺杂的p型Si。The Si contact layer 100 is heavily doped n-type Si, the Si multiplication layer 200 is intrinsically doped Si, and the Si charge layer 300 is heavily doped p-type Si.

III-V族垂直超晶格缓冲层400为InAs/GaSb II型垂直超晶格缓冲层,InAs/GaSbII型垂直超晶格缓冲层包括依次层叠设置的GaSb层和InAs层。The III-V group vertical superlattice buffer layer 400 is an InAs/GaSb II type vertical superlattice buffer layer. The InAs/GaSb II type vertical superlattice buffer layer includes a GaSb layer and an InAs layer stacked in sequence.

上述异质红外SAM-APD材料用于制备异质红外SAM-APD。The above heterogeneous infrared SAM-APD material is used to prepare heterogeneous infrared SAM-APD.

该异质红外SAM-APD的制备方法具体如下:The preparation method of the heterogeneous infrared SAM-APD is as follows:

1.通过离子注入技术对Si进行掺杂,离子注入对不同晶相的Si衬底进行处理,调节B和P的注入功率和时间等参数,分别得到重掺杂的n型Si作为Si接触层100,重掺杂的p型Si作为Si电荷层300,本征掺杂的Si作为Si倍增层200。1. Si is doped by ion implantation technology. Si substrates of different crystal phases are treated by ion implantation. Parameters such as the injection power and time of B and P are adjusted to obtain heavily doped n-type Si as Si contact layer 100, heavily doped p-type Si as Si charge layer 300, and intrinsically doped Si as Si multiplication layer 200.

2.在Si倍增层200上面外延生长InAs/GaSb II型垂直超晶格缓冲层:2. Epitaxially grow an InAs/GaSb II type vertical superlattice buffer layer on the Si multiplication layer 200:

首先生长250nm的GaSb缓冲层,生长缓冲层的目的是想要获得较好的表面。First, a 250nm GaSb buffer layer is grown. The purpose of growing the buffer layer is to obtain a better surface.

接着在GaSb缓冲层上进行异质外延生长InAs/GaSb超晶格结构材料,生长室温度大约在500℃,GaSb层的生长速率我们控制在0.5ML/s,InAs层的生长速度约为0.1ML/s。三五族元素束流比在3:1。Then, InAs/GaSb superlattice structure material is grown heteroepitaxially on the GaSb buffer layer. The growth chamber temperature is about 500℃, the growth rate of GaSb layer is controlled at 0.5ML/s, and the growth rate of InAs layer is about 0.1ML/s. The beam ratio of III-V elements is 3:1.

交替生长获得所需厚度的InAs/GaSb超晶格。该InAs/GaSb II型垂直超晶格缓冲层的TEM图如图4和图5所示,XRD图如图6所示,PL图如图7所示。The InAs/GaSb superlattice with the required thickness is obtained by alternating growth. The TEM images of the InAs/GaSb II type vertical superlattice buffer layer are shown in FIGS. 4 and 5 , the XRD image is shown in FIG. 6 , and the PL image is shown in FIG. 7 .

3.在InAs/GaSb II型垂直超晶格缓冲层上面使用分子束外延技术依次生长InGaAs吸收层500和InGaAs接触层600。3. The InGaAs absorption layer 500 and the InGaAs contact layer 600 are grown sequentially on the InAs/GaSb II type vertical superlattice buffer layer using molecular beam epitaxy technology.

4.最后采用紫外光刻技术制作刻蚀图形,利用电感耦合等离子体(ICP)设备刻蚀APD台面结构。4. Finally, ultraviolet lithography is used to make the etching pattern, and the APD mesa structure is etched using inductively coupled plasma (ICP) equipment.

实施例2Example 2

与实施例1不同的是,III-V族垂直超晶格缓冲层400为InAs/GaInSbⅡ型垂直超晶格缓冲层。InAs/GaInSbⅡ型垂直超晶格缓冲层包括层叠设置的GaAs层、GaSb缓冲层、InAs层和GaInSb层。Different from the embodiment 1, the III-V vertical superlattice buffer layer 400 is an InAs/GaInSbⅡ type vertical superlattice buffer layer. The InAs/GaInSbⅡ type vertical superlattice buffer layer includes a stacked GaAs layer, a GaSb buffer layer, an InAs layer and a GaInSb layer.

该InAs/GaInSbⅡ型垂直超晶格缓冲层的制备方法如下:采用分子束外延系统生长,砷源和锑源分别由带阀的裂解炉提供,阀门由气动开关控制,响应时间为0.1s。生长条件如下:生长温度在385~395℃,Ⅴ/Ⅲ束流比为5.7∶1~8.7∶1,层厚比为1~2.5。The preparation method of the InAs/GaInSbⅡ type vertical superlattice buffer layer is as follows: the arsenic source and the antimony source are respectively provided by a cracking furnace with a valve, and the valve is controlled by a pneumatic switch with a response time of 0.1s. The growth conditions are as follows: the growth temperature is 385-395℃, the V/III beam ratio is 5.7:1-8.7:1, and the layer thickness ratio is 1-2.5.

先外延生长一定厚度的GaAs层,然后再生长GaSb缓冲层,最后交替生长InAs/GaInSb超晶格。所得InAs/GaInSbⅡ型垂直超晶格缓冲层的PL图如图8所示。First, a GaAs layer of a certain thickness is epitaxially grown, then a GaSb buffer layer is grown, and finally an InAs/GaInSb superlattice is alternately grown. The PL image of the resulting InAs/GaInSb type II vertical superlattice buffer layer is shown in FIG8 .

实施例3Example 3

与实施例1不同的是,III-V族垂直超晶格缓冲层400为InAs/InAsSbⅡ型垂直超晶格缓冲层。InAs/InAsSbⅡ型垂直超晶格缓冲层包括层叠设置的GaAs缓冲层、InAs层和InAsSb层。Different from the embodiment 1, the III-V group vertical superlattice buffer layer 400 is an InAs/InAsSb type II vertical superlattice buffer layer. The InAs/InAsSb type II vertical superlattice buffer layer includes a stacked GaAs buffer layer, an InAs layer and an InAsSb layer.

该InAs/InAsSbⅡ型垂直超晶格缓冲层的制备方法如下:The preparation method of the InAs/InAsSbⅡ type vertical superlattice buffer layer is as follows:

采用分子束外延设备,生长参数包括:在衬底温度为460℃,III/V束流比为1:5时候,先生长GaAs缓冲层然后进行InAs层生长:首先开启In源和As源,开启30S后,关闭In源和As源。再进行InAsSb层生长:首先开启In源和As源,控制InAs在衬底上的迁移时间为0~1S,迁移速度0.5ML/S,当InAs在衬底覆盖度为70%时,关闭In源和As源,同时抽取反应腔内残余的As气氛;开启In源和Sb源,控制InSb在衬底上的迁移时间为0~1S,迁移速度0.5ML/S,当InSb在衬底覆盖度为30%时,关闭In源和Sb源,同时抽取反应腔内残余的Sb气氛,实现一个单分子层的InAsSb层的生长停止。The molecular beam epitaxy equipment is used, and the growth parameters include: when the substrate temperature is 460°C and the III/V beam ratio is 1:5, the GaAs buffer layer is grown first and then the InAs layer is grown: first turn on the In source and As source, turn on the In source and As source for 30 seconds, and then turn off the In source and As source. Then grow the InAsSb layer: first turn on the In source and As source, control the migration time of InAs on the substrate to 0-1S, and the migration speed to 0.5ML/S. When the coverage of InAs on the substrate is 70%, turn off the In source and As source, and extract the residual As atmosphere in the reaction chamber at the same time; turn on the In source and Sb source, control the migration time of InSb on the substrate to 0-1S, and the migration speed to 0.5ML/S. When the coverage of InSb on the substrate is 30%, turn off the In source and Sb source, and extract the residual Sb atmosphere in the reaction chamber at the same time, so as to stop the growth of a single-molecule layer of InAsSb layer.

(3)反正重复上述过程,直至所需厚度为止。由此完成InAs/InAsSbⅡ型超晶格的生长。(3) Repeat the above process until the desired thickness is reached. This completes the growth of the InAs/InAsSb II superlattice.

所得InAs/InAsSbⅡ型垂直超晶格缓冲层的PL图如图9所示。The PL image of the obtained InAs/InAsSbⅡ type vertical superlattice buffer layer is shown in Figure 9.

对比例1Comparative Example 1

本对比例,生长常规的横向排列而非本申请提供的创新型垂直排列的Ⅲ-Ⅴ族超晶格缓冲层。In this comparative example, a conventional lateral arrangement rather than the innovative vertical arrangement of III-V group superlattice buffer layer provided in the present application is grown.

其主要特征及步骤如下:采用分子束外延方法先在衬底的台阶上依次生长第一材料单分子层和第二材料单分子层,第一材料单分子层和第二材料单分子层共同铺满每个台阶,再重复生长第一材料单分子层和第二材料单分子层,直至所需厚度为止。然而这种传统的超晶格缓冲层会产生应变,由此产生的晶格失配将导致载流子传播过程中的位错缺陷。显然,如果在传统的结构中不加入超晶格缓冲层,将显著影响载流子的传输,由此影响探测器的灵敏性,从而降低探测器性能。其结构图如图10所示。Its main features and steps are as follows: molecular beam epitaxy is used to sequentially grow a monolayer of the first material and a monolayer of the second material on the steps of the substrate, the monolayer of the first material and the monolayer of the second material together cover each step, and then the monolayer of the first material and the monolayer of the second material are repeatedly grown until the required thickness is reached. However, this traditional superlattice buffer layer will produce strain, and the resulting lattice mismatch will lead to dislocation defects in the process of carrier propagation. Obviously, if the superlattice buffer layer is not added to the traditional structure, it will significantly affect the transmission of carriers, thereby affecting the sensitivity of the detector and reducing the performance of the detector. Its structural diagram is shown in Figure 10.

InGaAs作为一种典型的III-V族直接带隙半导体材料,具有高量子效率和高电子迁移率等特性且带隙可调,稳定性较好,因此使用InGaAs作为吸收层可以提升所述探测器的响应波长范围,如果更换为其他吸收层,会导致探测范围变小,稳定性变差等后果。As a typical III-V group direct bandgap semiconductor material, InGaAs has the characteristics of high quantum efficiency and high electron mobility, and has an adjustable bandgap and good stability. Therefore, using InGaAs as an absorption layer can improve the response wavelength range of the detector. If it is replaced with other absorption layers, it will lead to consequences such as a smaller detection range and worse stability.

硅(Si)在红外范围(1310nm~1550nm)是透明的,有效的方法是将Si倍增层与InGaAs吸收层结合,这将可以把InGaAs红外吸收的特性和Si高增益、低噪声的优点有机结合,如果缺少了Si倍增层将不能保障倍增特性从而影响探测器的效率。Silicon (Si) is transparent in the infrared range (1310nm~1550nm). An effective method is to combine the Si multiplication layer with the InGaAs absorption layer, which will organically combine the infrared absorption characteristics of InGaAs with the advantages of high gain and low noise of Si. If the Si multiplication layer is missing, the multiplication characteristics cannot be guaranteed, thus affecting the efficiency of the detector.

在本申请中,将InGaAs红外吸收的特性和Si高增益、低噪声的优点有机结合将是实现高性能红外APD的理想方案,该方案不仅可以满足硅基光电子集成的要求,还可以实现APD工作波长的拓展和增益性能的提升。根据APD的工作原理可知,吸收倍增分离型雪崩光电二极管(SAM-APD)是实现该方案的理想器件结构,即采用InGaAs作为吸收层,拓展探测器的工作波长;采用Si作为倍增层,保障探测器的雪崩及噪声特性。我们设计的InGaAs/Si异质红外APD结构,同时具有Si优异的倍增特性和InGaAs红外波段的吸收能力,更重要的还易于实现硅基片上集成,具有鲜明的特色。In this application, the organic combination of the infrared absorption characteristics of InGaAs and the advantages of high gain and low noise of Si will be an ideal solution for realizing high-performance infrared APD. This solution can not only meet the requirements of silicon-based optoelectronic integration, but also achieve the expansion of APD working wavelength and improvement of gain performance. According to the working principle of APD, the absorption multiplication separation avalanche photodiode (SAM-APD) is an ideal device structure for realizing this solution, that is, InGaAs is used as the absorption layer to expand the working wavelength of the detector; Si is used as the multiplication layer to ensure the avalanche and noise characteristics of the detector. The InGaAs/Si heterogeneous infrared APD structure we designed has both the excellent multiplication characteristics of Si and the absorption capacity of InGaAs in the infrared band. More importantly, it is easy to realize on-chip integration of silicon substrates and has distinctive characteristics.

最后应说明的是:以上各实施例仅用以说明本申请的技术方案,而非对其限制;尽管参照前述各实施例对本申请进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本申请各实施例技术方案的范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present application, rather than to limit it. Although the present application has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or replace some or all of the technical features therein with equivalents. However, these modifications or replacements do not cause the essence of the corresponding technical solutions to deviate from the scope of the technical solutions of the embodiments of the present application.

此外,本领域的技术人员能够理解,尽管在此的一些实施例包括其它实施例中所包括的某些特征而不是其它特征,但是不同实施例的特征的组合意味着处于本申请的范围之内并且形成不同的实施例。例如,在上面的权利要求书中,所要求保护的实施例的任意之一都可以以任意的组合方式来使用。公开于该背景技术部分的信息仅仅旨在加深对本申请的总体背景技术的理解,而不应当被视为承认或以任何形式暗示该信息构成已为本领域技术人员所公知的现有技术。In addition, those skilled in the art will appreciate that, although some embodiments herein include certain features included in other embodiments but not other features, the combination of features of different embodiments is meant to be within the scope of the present application and form different embodiments. For example, in the above claims, any one of the claimed embodiments may be used in any combination. The information disclosed in this background technology section is intended only to deepen the understanding of the overall background technology of the present application and should not be regarded as an admission or in any form of implication that the information constitutes prior art known to those skilled in the art.

Claims (3)

1. The heterogeneous infrared SAM-APD material is characterized by comprising a III-V absorption layer, a Si multiplication structure layer and a III-V vertical superlattice buffer layer arranged between the III-V absorption layer and the Si multiplication structure layer;
The III-V group absorption layer consists of an InGaAs absorption layer and an InGaAs contact layer, and the InGaAs absorption layer is adjacent to the III-V group vertical superlattice buffer layer;
The Si multiplication structure layer consists of an Si contact layer, an Si multiplication layer and an Si charge layer which are sequentially stacked, and the Si charge layer is adjacent to the III-V group vertical superlattice buffer layer;
the Si contact layer is heavily doped n-type Si, the Si multiplication layer is intrinsically doped Si, and the Si charge layer is heavily doped p-type Si;
the III-V group vertical superlattice buffer layer is an InAs/GaSb II type vertical superlattice buffer layer or an InAs/InAsSb II type vertical superlattice buffer layer, the InAs/GaSb II type vertical superlattice buffer layer comprises a GaSb buffer layer, a GaSb layer and an InAs layer which are sequentially stacked, and the InAs/InAsSb II type vertical superlattice buffer layer comprises a GaAs buffer layer, an InAs layer and an InAsSb layer which are sequentially stacked; or alternatively
The III-V group vertical superlattice buffer layer is an InAs/GaInSb II type vertical superlattice buffer layer, and the InAs/GaInSb II type vertical superlattice buffer layer comprises a GaAs layer, a GaSb buffer layer, an InAs layer and a GaInSb layer which are sequentially stacked.
2. A heterogeneous infrared SAM-APD, characterized in that its starting material comprises the heterogeneous infrared SAM-APD material of claim 1.
3. A method of making a heterogeneous infrared SAM-APD of claim 2, comprising:
Doping Si by an ion implantation technology to obtain the Si multiplication structure layer;
Sequentially epitaxially growing a III-V group vertical superlattice buffer layer and a III-V group absorption layer on the surface of the Si multiplication structure layer;
and manufacturing an etching pattern by adopting an ultraviolet lithography technology, and etching an APD mesa structure by utilizing inductive coupling plasma equipment to obtain the heterogeneous infrared SAM-APD.
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