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CN115925051A - Hybrid system and method for treating produced water and seawater to be reinjected into subsea oil reservoirs - Google Patents

Hybrid system and method for treating produced water and seawater to be reinjected into subsea oil reservoirs Download PDF

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CN115925051A
CN115925051A CN202310031004.5A CN202310031004A CN115925051A CN 115925051 A CN115925051 A CN 115925051A CN 202310031004 A CN202310031004 A CN 202310031004A CN 115925051 A CN115925051 A CN 115925051A
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membranes
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G·卡瓦堪缇努涅斯
S·E·维申菲尔德
J·蒙特罗萨姆巴德
C·皮亚塞克伯格斯
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University Rio De Janeiro
Petroleo Brasileiro SA Petrobras
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/18Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis

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  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

本发明涉及用于生产和处理海水的水处理系统,其用于油井中的二次回收。本发明提供一种用于处理采出水和海水以重新注入离岸油储层中的混合型系统以及相关的一种混合型水处理方法。将要处理的水导入包含微滤/超滤膜的处理模块(20)或导入包含纳滤膜的水处理模块,取决于与油和固体的含量或硫酸根离子含量相关的水的品质。本发明的系统和方法允许重新注入采出水,而无需在平台上的另外的处理系统。本发明的其他优点包括减少离岸油处理和降低在离岸装置处的与另外的系统相关的安装、运行和维护成本。The present invention relates to a water treatment system for producing and treating seawater for secondary recovery in oil wells. The present invention provides a hybrid system for treating produced water and seawater for reinjection into an offshore oil reservoir and an associated hybrid water treatment method. The water to be treated is directed to a treatment module (20) comprising microfiltration/ultrafiltration membranes or to a water treatment module comprising nanofiltration membranes, depending on the quality of the water in relation to the content of oil and solids or the content of sulphate ions. The systems and methods of the present invention allow reinjection of produced water without the need for additional treatment systems on the platform. Other advantages of the present invention include reduced offshore oil handling and reduced installation, operation and maintenance costs associated with additional systems at the offshore installation.

Description

用于处理要重新注入海底油储层中的采出水和海水的混合型系统和方法Hybrid system and method for treating produced water and seawater to be reinjected into a subsea oil reservoir

本申请是申请日为2017年7月19日、申请号为201780057450.6、发明名称为“用于处理要重新注入海底油储层中的采出水和海水的混合型系统和方法”的中国专利申请的分案申请。This application is the result of a Chinese patent application with an application date of July 19, 2017, an application number of 201780057450.6, and an invention title of "Hybrid System and Method for Treating Produced Water and Seawater to be Reinjected into Subsea Oil Reservoirs" Divisional application.

技术领域technical field

本发明涉及离岸油生产装置中的水处理系统。更具体地,本发明涉及在油井次级回收所用的采出水和海水的处理系统。The present invention relates to water treatment systems in offshore oil production units. More specifically, the present invention relates to systems for the treatment of produced water and seawater for secondary recovery in oil wells.

背景技术Background technique

公知的是在离岸油装置中,次级油回收所用的技术之一是注入经处理的海水。在本文上下文中,已知的是海水包含大量的硫酸根离子(SO4 -2),大约2800mg/L。当海水注入到地层水(同源水)在溶液中包含足够的钡(Ba+2),锶(Sr+2)或者钙(Ca2+)离子的地域时,这二者前端的接触通常引起其硫酸盐:硫酸钡(BaSO4),硫酸锶(SrSO4)或者硫酸钙(CaSO4)发生沉淀。这些盐极难溶,并且沉淀的盐堵塞了井孔而导致地层损坏。它们也会在生产线和加工厂的装置中沉淀。It is known that in offshore oil installations, one of the techniques used for secondary oil recovery is the injection of treated seawater. In this context, it is known that seawater contains large amounts of sulfate ions (SO 4 −2 ), approximately 2800 mg/L. When seawater is injected into a region where formation water (homologous water) contains sufficient barium (Ba +2 ), strontium (Sr +2 ) or calcium (Ca 2+ ) ions in solution, contact between these two fronts usually causes Its sulfates: barium sulfate (BaSO 4 ), strontium sulfate (SrSO 4 ) or calcium sulfate (CaSO 4 ) precipitate. These salts are extremely insoluble, and the precipitated salts plug well bores causing formation damage. They also settle in production lines and equipment in processing plants.

取决于地岩层水中的钡和锶含量,可能必需要配置硫酸盐除去单元(URS),用于要注入到储层中的海水的处理,如图1所示。在URS中,使用纳滤膜(其可以是陶瓷的或者聚合物的)来从海水中除去硫酸根离子。因为海水具有固体粒子以及海洋植物和动物组分,因此必需在URS单元上游安装过滤器来改进它的性能。该过滤初始时用粗过滤器来进行,和随后用较小流动直径的筒式过滤器来进行。Depending on the barium and strontium content of the formation water, it may be necessary to deploy a sulfate removal unit (URS) for the treatment of seawater to be injected into the reservoir, as shown in Figure 1 . In URS, nanofiltration membranes (which can be ceramic or polymeric) are used to remove sulfate ions from seawater. Because seawater has solid particles and marine plant and animal components, it is necessary to install filters upstream of the URS unit to improve its performance. The filtration is performed initially with a coarse filter and subsequently with a cartridge filter of smaller flow diameter.

在URS中,水渗透过纳滤膜,并且一部分(典型的是25%)浓缩了硫酸根离子,并且分离至将来丢弃到海洋里。为了实现经处理的水中硫酸根离子的设计规格,并联使用了两组膜,随后是串联的第三组,根据图2的图示。In URS, water is permeated through nanofiltration membranes and a portion (typically 25%) is concentrated in sulfate ions and separated for future disposal into the ocean. To achieve the design specifications for sulfate ions in treated water, two sets of membranes were used in parallel, followed by a third set in series, according to the diagram in Figure 2.

一旦将水用URS处理,就获得了必要的规格,并且就能够注入到油储层中,来用于次级回收。Once the water has been treated with URS, the necessary specifications have been obtained and can be injected into oil reservoirs for secondary recovery.

此外,进一步已知的是将到达所述处理单元的采出水进行处理来除去油滴。用于这种类型的处理的常规技术具有图1所示的一般和简化形式的构造。Furthermore, it is further known to treat the produced water reaching the treatment unit to remove oil droplets. Conventional techniques for this type of processing have the general and simplified form shown in FIG. 1 .

具体地,采出水经历了处理方法来将含水相与油相分离,其包含重力分离,水力旋流器和浮法分离,然后根据现行的环境法规按规定在海洋中处置。未规定在一些平台上处置的水可以导向称作“不合格槽”的槽中,在这里用更长的时间来分离所述油相,和在一些情况中可以在处理设备中再加工。Specifically, produced water undergoes treatment methods to separate the aqueous phase from the oil phase, which include gravity separation, hydrocyclones, and floatation separation, before being regulated for disposal in the ocean according to current environmental regulations. Water not specified for disposal on some platforms can be directed to tanks called "bad tanks" where it takes longer to separate the oil phase and in some cases can be reprocessed in processing equipment.

但是,这种采出水处理装置具有降低的小于5.0μm的油滴和固体粒子除去效率。这样的条件限制了所述处理的整体效率,和因此获得这样的流出物流,其具有在悬浮的固体含量,油和油脂方面适于更大限制性储层的特性。所以在处理后,由于悬浮固体、油和油脂的含量,规定将采出水在海洋中处置,并且规定不重新注入。However, such produced water treatment devices have reduced removal efficiency of oil droplets and solid particles smaller than 5.0 μm. Such conditions limit the overall efficiency of the treatment, and thus obtain effluent streams with characteristics suitable for more restrictive reservoirs in terms of suspended solids content, oil and grease. So after treatment, it is stipulated that the produced water be disposed of in the sea due to the content of suspended solids, oil and grease, and it is stipulated not to reinject.

以此方式,目前在离岸油生产设施中采出水在处理后唯一的目的地就是处置掉。用于获得根据重新注入到更大限制性储层中所提出的要求的固体和油含量的常规产生水的处理设备的低效率以及其他因素导致了所述重新注入是不可行的。因此,在最近的次级回收方案中,这种选项仍然被忽略。In this way, currently the only destination of produced water after treatment in offshore oil production facilities is disposal. The inefficiency of conventionally produced water treatment equipment used to achieve the required solids and oil content according to the requirements imposed by re-injection into a more restrictive reservoir, among other factors, renders such re-injection impractical. Therefore, this option is still ignored in recent secondary recycling schemes.

但是,要注意的是开发允许重新注入采出水的处理系统对于生产油的领域来说是一个非常吸引人的选项,这主要归因于环境法规变得日益严格的趋势,以及趋向于增加这个作用领域中工业实践的可持续性。However, it is to be noted that the development of treatment systems that allow for the re-injection of produced water is a very attractive option for the oil producing sector, mainly due to the trend towards increasingly stringent environmental regulations and the tendency to increase this role Sustainability of industrial practices in the field.

在此意义上,微滤/超滤膜分离技术(使用陶瓷膜)已经被证实是用于这种挑战的一个令人关注的选项,因为当应用于处理采出水时,产生了具有低的油和固体含量的水。In this sense, microfiltration/ultrafiltration membrane separation technology (using ceramic membranes) has proven to be an interesting option for this challenge, because when applied to treat produced water, it produces oil with low and solids content of water.

在微滤/超滤膜分离方法中,如现有技术已知的,水渗透过所述膜,而一部分所供给的体积聚集了未渗透的油,并且以再循环形式返回所述系统。In microfiltration/ultrafiltration membrane separation methods, as known in the prior art, water permeates through the membrane, while a part of the supplied volume collects non-permeated oil and returns it to the system in recirculated form.

Ashaghi,K.Shams等人的标题为“Ceramic Ul tra-and Nanofi l trat ionMembranes for Oi lfield Produced Water Treatment:A Mini Review”公开了关于使用微滤/超滤陶瓷膜来处理采出水(除去固体和油粒子)的综述研究。在这篇科学论文中提出了使用微滤/超滤陶瓷膜的几个技术,因此它们的描述在此引入作为参考。Ashaghi, K. Shams et al., entitled "Ceramic Ultra-and Nanofi l trat ion Membranes for Oilfield Produced Water Treatment: A Mini Review" disclose information on the use of microfiltration/ultrafiltration ceramic membranes to treat produced water (removal of solids and A review of oil particles). Several techniques using microfiltration/ultrafiltration ceramic membranes are proposed in this scientific paper, so their descriptions are hereby incorporated by reference.

Weschenfelder,Si lvio E.等人(本发明的发明人之一)的标题为“Evaluat ionof membranes for the treatment of water from the oi lextract ion process”的论文公开了一个研究,其通过使用真实流出物的长期测试来评价了用于处理采出水的膜的性能,考虑了渗透流的形成和所产生的流出物的特性。结果表明通过使用孔尺寸等于0.1mm的膜,可以获得固体含量小于1mg L-1和油和油脂含量是1-3mg L-1的渗透物料流。此外,该文献公开了使用化学再生方法,恢复微滤/超滤陶瓷膜95%的初始透过性是可能的。该文献公开的内容也在此引入作为参考。The paper entitled "Evaluation of membranes for the treatment of water from the oi lextract ion process" by Weschenfelder, Silvio E. et al. (one of the inventors of the present invention) discloses a study by using real effluent Long-term tests evaluate the performance of membranes used to treat produced water, taking into account permeate flow formation and the characteristics of the resulting effluent. The results show that by using a membrane with a pore size equal to 0.1 mm, a permeate stream with a solids content of less than 1 mg L -1 and an oil and grease content of 1-3 mg L -1 can be obtained. Furthermore, this document discloses that it is possible to restore 95% of the initial permeability of microfiltration/ultrafiltration ceramic membranes using chemical regeneration methods. The disclosure of this document is also incorporated herein by reference.

在目前的方案中,如果确定了通过使用微滤/超滤膜分离方法来补充常规的采出水的处理能够实现重新注入,则例如在处理设备中将需要另外的系统,如上述现有技术文献中所述。这带来了明显更高的配置、运行和维护成本和更大的操作难度,以及更大的重量和平台上的占地面积。In the present scheme, if it is determined that re-injection can be achieved by supplementing conventional produced water treatment with microfiltration/ultrafiltration membrane separation methods, additional systems will be required, for example in the treatment plant, as described in the above-mentioned prior art documents described in . This brings significantly higher configuration, operating and maintenance costs and greater operational difficulty, as well as greater weight and footprint on the platform.

因此,显然,现有技术缺少这样的采出水的处理系统,其允许重新注入,而无需另外的如现有技术已知的处理系统。Thus, it is apparent that the prior art lacks a produced water treatment system that allows re-injection without the need for additional treatment systems as known in the prior art.

如下面将更好描述的,本发明寻求以实际的、有效的和成本有效的方式来解决上述现有技术的问题。As will be better described below, the present invention seeks to solve the above-mentioned problems of the prior art in a practical, efficient and cost-effective manner.

发明内容Contents of the invention

本发明的主要目标是提供一种混合型系统和方法,用于处理海水和生产,其允许重新注入采出水,而无需平台上另外的处理系统。The main objective of the present invention is to provide a hybrid system and method for seawater treatment and production that allows re-injection of produced water without the need for additional treatment systems on the platform.

为了实现上述目标,本发明提供一种混合型系统,用于处理采出水和海水,来重新注入离岸油储层中,其包含(i)至少一个要处理的水的入口,(i i)至少两个微滤/超滤水处理模块,每个模块包含(i i-a)至少一组微滤/超滤膜,其用于从要处理的水中除去油和固体,或者(i i-b)至少一组纳滤膜,其用于从要处理的水中除去硫酸根离子,(i i i)至少一个经处理的水的出口,其中将所述体积的要处理的水导向包含微滤/超滤膜的水处理模块或者导向包含纳滤膜的水处理模块,其取决于所述水的与油和固体含量或者硫酸根离子含量相关的品质。To achieve the above objects, the present invention provides a hybrid system for treating produced water and seawater for re-injection into an offshore oil reservoir comprising (i) at least one inlet for water to be treated, (ii) At least two microfiltration/ultrafiltration water treatment modules, each module comprising (ii-a) at least one set of microfiltration/ultrafiltration membranes for removing oil and solids from the water to be treated, or (ii-b) at least one A set of nanofiltration membranes for removing sulphate ions from the water to be treated, (iii) at least one outlet for treated water, wherein said volume of water to be treated is directed to comprise microfiltration/ultrafiltration membranes Depending on the quality of the water in relation to the oil and solids content or the sulfate ion content, the water treatment module is directed or directed to a water treatment module comprising nanofiltration membranes.

本发明进一步提供一种混合型方法,用于处理采出水和海水,来重新注入离岸油储层中,其基本包含步骤:(i)将要处理的水导向包含至少一组微滤/超滤膜的水处理模块,其用于从要处理的水中除去油和固体,或者(i i)将要处理的水导向包含至少一组纳滤膜的水处理模块,其用于从要处理的水中除去硫酸根离子,其中将所述体积的要处理的水导向包含微滤/超滤膜的水处理模块或者导向包含纳滤膜的水处理模块,其取决于所述水的与油和固体含量或者硫酸根离子含量相关的品质。The present invention further provides a hybrid method for treating produced water and seawater for re-injection into an offshore oil reservoir, essentially comprising the steps of: (i) directing the water to be treated to at least one set of microfiltration/ultrafiltration A water treatment module of membranes for removing oil and solids from the water to be treated, or (ii) directing the water to be treated to a water treatment module comprising at least one set of nanofiltration membranes for removing Sulfate ion, wherein the volume of water to be treated is directed to a water treatment module comprising microfiltration/ultrafiltration membranes or to a water treatment module comprising nanofiltration membranes, depending on the oil and solids content of the water or Quality related to sulfate ion content.

附图说明Description of drawings

下面给出的具体实施方式涉及附图和它们各自的附图标记。The detailed description given below refers to the drawings and their respective reference numerals.

图1显示了海水处理系统的示意图和分别用于注入和处置采出水,如现有技术已知的。Figure 1 shows a schematic diagram of a seawater treatment system and for injection and disposal of produced water respectively, as known in the prior art.

图2显示了通过硫酸盐除去单元(URS)用于注入油储层的海水处理的一个例子的示意图,如现有技术已知的。Figure 2 shows a schematic diagram of an example of seawater treatment for injection into an oil reservoir by means of a sulphate removal unit (URS), as known in the prior art.

图3显示了根据本发明的优选实施方案的包含纳滤或者微滤/超滤膜的处理模块的示意图。Figure 3 shows a schematic diagram of a processing module comprising nanofiltration or microfiltration/ultrafiltration membranes according to a preferred embodiment of the present invention.

图4显示了根据本发明的优选实施方案的混合型海水处理系统和用于重新注入采出水之一的示意图。Figure 4 shows a schematic diagram of a hybrid seawater treatment system and one for reinjection of produced water according to a preferred embodiment of the present invention.

图5显示了一种包含本发明的混合型系统的用于处理海水和用于重新注入采出水的完整系统的示意图。Figure 5 shows a schematic diagram of a complete system for treating seawater and for reinjection of produced water including the hybrid system of the present invention.

具体实施方式Detailed ways

在前面,将理解下面的说明书将脱离本发明优选的实施方案。但是,对本领域技术人员来说显而易见的,本发明不限于具体实施方案。In the foregoing, it is to be understood that the following description will depart from the preferred embodiments of the invention. However, it will be apparent to those skilled in the art that the present invention is not limited to specific embodiments.

图4显示了根据本发明优选的实施方案的一种混合型海水处理系统和用于进一步重新注入采出水的简化的示意图。该附图基本上包括要处理的水的两个入口,即,一个是采出水的入口2,具有高含量的油和固体,和一个是海水入口4,具有高含量的硫酸根离子。Figure 4 shows a simplified schematic diagram of a hybrid seawater treatment system and further re-injection of produced water according to a preferred embodiment of the present invention. The figure basically comprises two inlets for the water to be treated, namely one inlet 2 for produced water, with a high content of oil and solids, and one inlet 4 for seawater, with a high content of sulphate ions.

在导向处置或者通过本发明的混合型系统处理之前,采出水优选存储在至少一个槽10中。Produced water is preferably stored in at least one tank 10 prior to diversion for disposal or treatment by the hybrid system of the present invention.

优选收集来用于处理和随后注入的海水穿过一系列过滤器,第一过滤器提供有具有粗网的过滤元件,并且之后是提供有具有细网的过滤元件。优选第一过滤器12截留了到500μm的粒子,第二过滤器14截留了到25μm的粒子和第三过滤器截留了到5μm。Seawater collected for treatment and subsequent injection is preferably passed through a series of filters, the first filter being provided with a filter element with a coarse mesh and followed by a filter element with a fine mesh. Preferably the first filter 12 retains particles to 500 μm, the second filter 14 to 25 μm and the third filter to 5 μm.

优选采出水和所收集的海水二者分别到达至少一个由多个水控制阀门组成的集管18,其汇入每个处理模块20。Preferably both the produced water and the collected seawater respectively arrive at at least one header 18 consisting of a plurality of water control valves, which join each treatment module 20 .

每个处理模块20包含至少一个适用组的微滤/超滤膜(陶瓷膜)来从采出水中除去油和固体,或者至少一组所采用的纳滤膜(陶瓷或者聚合物膜),用于从海水中除去硫酸根离子。因此,至少一个集管18通过其控制阀门将采出水导入包含微滤/超滤膜的模块和将海水抽出到包含纳滤膜的模块中。优选所述至少一个集管细分为两个集管,一个用于控制在包含微滤/超滤膜的模块中采出水的入口,和另一个用于控制进入包含纳滤膜的模块的海水。Each treatment module 20 contains at least one suitable set of microfiltration/ultrafiltration membranes (ceramic membranes) to remove oil and solids from the produced water, or at least one set of nanofiltration membranes (ceramic or polymeric membranes) used for for the removal of sulfate ions from seawater. Thus, at least one header 18 directs produced water through its control valves to the modules containing the micro/ultrafiltration membranes and pumps seawater into the modules containing the nanofiltration membranes. Preferably said at least one header is subdivided into two headers, one for controlling the inlet of produced water in modules comprising microfiltration/ultrafiltration membranes, and the other for controlling the entry of seawater into modules comprising nanofiltration membranes .

优选至少一个集管18流体连接到两个要处理的水的入口管道上,即,一个用于采出水2和一个用于海水4。这些入口管道每个分别细分为多个并联的次级管道,用于每个处理模块的次级管道。在进入每个处理模块20之前,采出水和海水的次级管道流入处于每个控制阀门的下游从每个模块的单个入口管道。Preferably at least one header 18 is fluidly connected to two inlet conduits for the water to be treated, ie one for produced water 2 and one for seawater 4 . These inlet conduits are each subdivided into a plurality of parallel secondary conduits for the secondary conduits of each process module. Before entering each treatment module 20, secondary conduits of produced water and seawater flow into a single inlet conduit from each module downstream of each control valve.

所述控制阀门位于每个处理模块20的上游,以使得每个阀门控制一种类型的要处理的水的进入,即,来自于每个次级管道的采出水或者海水。The control valves are located upstream of each treatment module 20 such that each valve controls the entry of one type of water to be treated, ie produced water or seawater from each secondary pipeline.

优选,在进入处理模块20之前,在采出水和海水之间不存在混合。即,如果打开采出水入口控制阀门,则应当优选关闭海水入口控制阀门。Preferably, there is no mixing between produced water and seawater prior to entering the treatment module 20 . That is, if the produced water inlet control valve is opened, the seawater inlet control valve should preferably be closed.

优选,每个处理模块20包含仅仅一种类型的膜,即,纳滤或者微滤/超滤。因此优选如果具体的处理模块20仅仅包含纳滤膜,则仅仅将海水导向其中,关闭采出水的入口控制阀门。同样,采出水将导向仅仅包含微滤/超滤膜的处理模块20。Preferably, each treatment module 20 contains only one type of membrane, ie nanofiltration or micro/ultrafiltration. It is therefore preferred that if a specific treatment module 20 comprises only nanofiltration membranes, only seawater is directed therein, and the inlet control valve for produced water is closed. Likewise, produced water will be directed to a treatment module 20 containing only microfiltration/ultrafiltration membranes.

每个处理模块20设计来允许纳滤膜和微滤/超滤膜之间互换。换言之,每个模块可以将它的纳滤膜替换为微滤/超滤(反之亦然),这取决于每种水的处理要求。Each processing module 20 is designed to allow interchange between nanofiltration membranes and microfiltration/ultrafiltration membranes. In other words, each module can replace its nanofiltration membrane with microfiltration/ultrafiltration (and vice versa), depending on each water treatment requirement.

作为例子,将理解,在实施本发明的混合型系统之后不久,将仅仅需要通过纳滤膜来处理海水,因为将仍然没有采出水。因此,实际上全部的处理模块20可以仅仅装备有纳滤膜。由于产生采出水时,对处理海水的需求减少。在那种情况中,将处理模块20的纳滤膜用微滤/超滤膜替代。As an example, it will be appreciated that shortly after implementation of the hybrid system of the present invention, seawater will only need to be treated through nanofiltration membranes, since no water will still be produced. Thus, practically all treatment modules 20 can be equipped with nanofiltration membranes only. As produced water is produced, the need to treat seawater is reduced. In that case, the nanofiltration membranes of the treatment module 20 are replaced by microfiltration/ultrafiltration membranes.

图3显示了根据本发明的处理模块20的示意图细节。如所述的,处理模块20可以包含纳滤膜或者微滤/超滤膜,其取决于将通过具体模块的水的类型(采出水或者海水)。每个模块包含至少一组20微滤/超滤或者纳滤膜。优选如现有技术的URS那样,每个模块包含两组并联膜20a,20b,随后是第三组串联膜20c。Figure 3 shows a schematic detail of a processing module 20 according to the invention. As mentioned, the treatment module 20 may contain nanofiltration membranes or micro/ultrafiltration membranes, depending on the type of water (produced water or seawater) that will pass through the particular module. Each module contains at least one set of 20 microfiltration/ultrafiltration or nanofiltration membranes. Preferably as in the prior art URS, each module comprises two sets of membranes 20a, 20b connected in parallel, followed by a third set of membranes in series 20c.

优选,在处理模块20提供有纳滤膜的情况中,为了从海水中除去硫酸根离子,要处理的水通过第一的两组并联纳滤膜,以使得经处理体积的水的最大部分变成低硫酸根离子浓度,并且送去注入储层中。Preferably, in case the treatment module 20 is provided with nanofiltration membranes, in order to remove sulphate ions from seawater, the water to be treated passes through a first two sets of nanofiltration membranes connected in parallel, so that the largest part of the treated volume of water becomes to a low sulfate ion concentration and sent for injection into the reservoir.

通过第一组膜的硫酸根离子浓缩的其余的水导向与第一的两组串联的第三组膜20c。该第三组处理了这种更浓缩的水,并且也产生了具有较低浓度的硫酸根离子的较大部分(其将与通过第一的两组膜处理的水混合)和硫酸根离子极度浓缩的较小部分(其通常丢弃在海中)。The remainder of the water concentrated by sulfate ions passing through the first set of membranes is directed to a third set of membranes 20c in series with the first two sets. This third set treats this more concentrated water and also produces a larger fraction with a lower concentration of sulfate ions (which will mix with the water treated by the first two sets of membranes) and the sulfate ion extremes. A concentrated smaller fraction (which is usually discarded in the sea).

将来自于纳滤膜组处理的具有低硫酸根离子浓度的水用于注入储层中,但是可以经历另外的处理步骤。Water with low sulfate ion concentration from nanofiltration membrane stack treatment is used for injection into the reservoir, but may undergo additional treatment steps.

在提供有微滤/超滤膜的处理模块20的情况中,为了从采出水中除去油和固体,所述程序与上述非常类似。优选要处理的水通过第一的两组并联膜20a,20b,以使得所处理体积的水的最大部分包含低浓度的油和固体,并且导向来重新注入储层中。In the case of the treatment module 20 provided with microfiltration/ultrafiltration membranes, for the removal of oil and solids from the produced water, the procedure is very similar to that described above. The water to be treated is preferably passed through the first two sets of parallel membranes 20a, 20b so that the largest part of the treated volume contains low concentrations of oil and solids and is directed for reinjection into the reservoir.

送过第一组膜的油和固体被浓缩的其余的水导向与第一的两组串联的第三组膜20c。该第三组处理了这种更浓缩的水,并且也产生了具有较低油和固体的浓度的较大部分(其将与通过第一的两组膜处理的水混合)。将来自于全部三组微滤/超滤膜的具有低浓度的油和固体的水用于重新注入储层中。The oil and solids sent through the first set of membranes are concentrated and the remaining water is directed to a third set of membranes 20c in series with the first two sets. This third set processes this more concentrated water and also produces a larger fraction with a lower concentration of oil and solids (which will mix with the water processed by the first two sets of membranes). Water with low concentrations of oil and solids from all three sets of microfiltration/ultrafiltration membranes was used for reinjection into the reservoir.

取决于要处理的水的品质,每个处理模块20可以包含更多或者更少的串联和/或并联膜组。因此,要指出的是本发明不限于图3所示的膜组构造。Depending on the quality of water to be treated, each treatment module 20 may contain more or fewer series and/or parallel membrane stacks. Therefore, it is pointed out that the present invention is not limited to the membrane stack configuration shown in FIG. 3 .

仍然在提供有微滤/超滤膜的处理模块20的情况中,来自于第三组膜20c的油和固体浓缩的较小部分可以导向处理模块20的入口,如图3所示。Still in the case of a treatment module 20 provided with microfiltration/ultrafiltration membranes, a smaller fraction of the oil and solids concentration from the third set of membranes 20c can be directed to the inlet of the treatment module 20 as shown in FIG. 3 .

可选择地,如图5所示(离岸装置的全图),该油和固体浓缩的水(油性再循环)可以送到水处理系统来分离油相。优选该油和固体浓缩的水可以送到一些处理槽,如图5所示(处理槽24)。这个槽可以例如是不合规格槽,其通常已经用于采出水处理设备。可选择地,除了不合规格槽之外,可以提供另外的槽来进行这个步骤。Alternatively, as shown in Figure 5 (full view of the offshore unit), this oil and solids concentrated water (oily recycle) can be sent to a water treatment system to separate the oil phase. Preferably the oil and solids concentrated water can be sent to treatment tanks as shown in Figure 5 (treatment tank 24). This tank may for example be a substandard tank, which is normally already used in production water treatment plants. Optionally, additional slots other than the out-of-spec slots may be provided for this step.

任选地,至少一个水出口提供在处理槽24的下部,来抽出具有低浓度油的水,因为所述油密度低于水,在一段时间之后将浓缩在顶部。通过处理槽24下部中的水出口抽出的水(其具有相对低或者中等浓度的油)可以丢弃(如果规定的话),或者导向根据本发明的混合型处理系统,在这里它将送到包含微滤/超滤膜的处理模块20来进行除去油和固体的新的处理。在除去一些水之后,保留在处理槽24中的油性浓缩物优选导向油水分离系统23,来利用开采的油。这有利于排入海洋中的油最小化和有利于在井的总开采中采出水中所存在的油得到更好的利用。Optionally, at least one water outlet is provided in the lower part of the treatment tank 24 to draw water with a low concentration of oil, which will concentrate at the top after a period of time since the oil is less dense than water. Water drawn through the water outlet in the lower part of the treatment tank 24 (which has a relatively low or medium concentration of oil) can be discarded (if specified) or directed to a hybrid treatment system according to the invention where it will be sent to a A treatment module 20 of filtration/ultrafiltration membranes is used for new treatment to remove oil and solids. After removing some of the water, the oily concentrate remaining in the treatment tank 24 is preferably directed to an oil-water separation system 23 to utilize the recovered oil. This facilitates the minimization of oil discharge into the ocean and better utilization of the oil present in the produced water in the overall production of the well.

本发明进一步提供对处理模块中所用的膜进行反洗程序的可能性,特别是微滤/超滤膜。这样的程序可以例如通过泵(未示出)或者操控经处理的水管线和每组的供给线中的定时阀门来进行。这种程序允许定期反转所述膜中的流动,清洁和保持其性能。The invention further provides the possibility to perform a backwashing procedure on the membranes used in the treatment modules, in particular microfiltration/ultrafiltration membranes. Such a procedure can be performed, for example, by pumps (not shown) or by manipulating timed valves in the treated water lines and supply lines of each group. This procedure allows periodically reversing the flow in the membrane, cleaning and maintaining its performance.

任选地,如果需要,在重新注入储层之前,至少第一脱气器单元28提供在处理模块20的上游或者下游用于海水脱气。Optionally, at least a first degasser unit 28 is provided upstream or downstream of the treatment module 20 for seawater degassing, if desired, prior to reinjection into the reservoir.

本发明进一步提供一种混合型方法,用于处理采出水和海水,来重新注入离岸储层中,其基本包含步骤:The present invention further provides a hybrid method for treating produced water and seawater for re-injection into an offshore reservoir, essentially comprising the steps of:

a)将要处理的水导向包含至少一组微滤/超滤膜的水处理模块,其用于从要处理的水中除去油和固体;或者a) directing the water to be treated to a water treatment module comprising at least one set of microfiltration/ultrafiltration membranes for removing oil and solids from the water to be treated; or

b)将要处理的水导向包含至少一组纳滤膜的水处理模块,其用于从要处理的水中除去硫酸根离子,其中将所述体积的要处理的水导向包含微滤/超滤膜的水处理模块或者包含纳滤膜的水处理模块,这取决于所述水与油和固体含量或者硫酸根离子含量有关的品质。b) directing the water to be treated to a water treatment module comprising at least one set of nanofiltration membranes for removing sulfate ions from the water to be treated, wherein said volume of water to be treated is directed to comprise microfiltration/ultrafiltration membranes A water treatment module or a water treatment module comprising nanofiltration membranes, depending on the quality of the water in relation to oil and solids content or sulfate ion content.

进一步要强调的是本文详述的全部处理步骤可应用于本发明的系统和方法二者。It is further emphasized that all process steps detailed herein are applicable to both the system and method of the present invention.

因此,基于上述说明书,本发明提供一种系统和方法,用于处理海水和生产,其允许重新注入采出水,而无需在平台上另外的处理系统。通过本发明仍然实现了另外的优点,例如通过更有效的处理采出水而降低了离岸油处置,和降低了在离岸装置处与另外的系统相关的安装、运行和维护成本。Therefore, based on the above description, the present invention provides a system and method for treating seawater and production that allows re-injection of produced water without the need for additional treatment systems on the platform. Still further advantages are achieved by the present invention, such as reduced offshore oil disposal through more efficient treatment of produced water, and reduced installation, operation and maintenance costs associated with additional systems at offshore installations.

涉及本发明保护范围的众多改变是允许的。因此,要强调这样的事实,即,本发明不限于上述具体的设定/实施方案。Numerous variations within the scope of the invention are permissible. Accordingly, emphasis is placed on the fact that the present invention is not limited to the specific settings/embodiments described above.

特别地,本发明还涉及以下各项目:In particular, the present invention also relates to the following items:

项目1.一种用于处理要重新注入离岸油储层中的采出水和海水的混合型系统,特征在于包含:Item 1. A hybrid system for treating produced water and seawater to be reinjected into an offshore oil reservoir characterized by comprising:

至少一个要处理的水的入口;At least one inlet for water to be treated;

至少两个处理模块(20),每个模块包含:At least two processing modules (20), each containing:

至少一组微滤/超滤膜(20a,20b,20c),其用于从要处理的水中除去油和固体;或者At least one set of microfiltration/ultrafiltration membranes (20a, 20b, 20c) for removing oil and solids from the water to be treated; or

至少一组纳滤膜(20a,20b,20c),其用于从要处理的水中除去硫酸根离子;和at least one set of nanofiltration membranes (20a, 20b, 20c) for removing sulfate ions from the water to be treated; and

至少一个经处理的水的出口,其中将所述体积的要处理的水导向包含微滤/超滤膜的处理模块(20)或者导向包含纳滤膜的水处理模块,其取决于所述水含量与油和固体含量或者硫酸根离子含量有关的品质。At least one outlet for treated water, wherein the volume of water to be treated is directed to a treatment module (20) comprising microfiltration/ultrafiltration membranes or to a water treatment module comprising nanofiltration membranes, depending on the water Content Quality related to oil and solids content or sulfate ion content.

项目2.根据项目1的系统,特征在于每个处理模块(20)包含平行的至少两组膜(20a,20b)。Item 2. The system according to item 1, characterized in that each treatment module (20) comprises at least two sets of membranes (20a, 20b) in parallel.

项目3.根据项目1或者2的系统,特征在于每个处理模块(20)包含与其它组的膜(20a,20b)串联的至少一组膜(20c)。Item 3. The system according to item 1 or 2, characterized in that each treatment module (20) comprises at least one set of membranes (20c) in series with other sets of membranes (20a, 20b).

项目4.根据项目1-3任一项的系统,特征在于该至少一个要处理的水的入口包括两个水入口,即,一个是采出水的入口(2)和一个是海水的入口(4)。Item 4. The system according to any one of items 1-3, characterized in that the at least one inlet for water to be treated comprises two water inlets, i.e. one for produced water (2) and one for seawater (4 ).

项目5.根据项目4的系统,特征在于它进一步包含至少一个集管(18),其提供有多个阀门,用于控制进入每个水处理模块(20)的水的类型,即,采出水或者海水。Item 5. The system according to item 4, characterized in that it further comprises at least one header (18) provided with a plurality of valves for controlling the type of water entering each water treatment module (20), i.e. produced water Or sea water.

项目6.根据项目5的系统,特征在于所述入口管道(2,4)每个分别细分为多个平行的次级管道,用于每个处理模块(20)的次级管道。Item 6. The system according to item 5, characterized in that said inlet conduits (2, 4) are each subdivided into a plurality of parallel secondary conduits for the secondary conduits of each treatment module (20).

项目7.根据项目1-6任一项的系统,特征在于每个处理模块(20)包含仅仅一种类型的膜,即,纳滤或者微滤/超滤。Item 7. The system according to any one of items 1-6, characterized in that each treatment module (20) contains only one type of membrane, namely nanofiltration or micro/ultrafiltration.

项目8.根据项目1-7任一项的系统,特征在于每个处理模块(20)的膜是可与另一类型的膜互换的。Item 8. The system according to any one of items 1-7, characterized in that the membrane of each treatment module (20) is interchangeable with another type of membrane.

项目9.根据项目1-7任一项的系统,特征在于它另外包含至少一个水处理槽(24),其用于通过密度差来将水相与油相分离。Item 9. The system according to any one of items 1-7, characterized in that it additionally comprises at least one water treatment tank (24) for separating the water phase from the oil phase by density difference.

项目10.根据项目9的系统,特征在于水处理槽(24)与其下游和上游的至少两个处理模块(20)流体连通,完成一个循环。Item 10. The system according to item 9, characterized in that the water treatment tank (24) is in fluid communication with at least two treatment modules (20) downstream and upstream thereof, completing a cycle.

项目11.根据项目9或者10的系统,特征在于水处理槽(24)此外与至少一个用于海洋废物处理的出口和用于水和油的分离的水入口管道流体连通。Item 11. The system according to item 9 or 10, characterized in that the water treatment tank (24) is furthermore in fluid communication with at least one outlet for marine waste treatment and a water inlet conduit for separation of water and oil.

项目12.一种用于处理采出水和海水以重新注入离岸油储层中的混合型方法,特征在于它包含步骤:Item 12. A hybrid method for treating produced water and seawater for reinjection into an offshore oil reservoir, characterized in that it comprises the steps of:

将要处理的水导向包含至少一组的微滤/超滤膜的至少一个水处理模块(20),用于从要处理的水中除去油和固体;或者directing the water to be treated to at least one water treatment module (20) comprising at least one set of microfiltration/ultrafiltration membranes for removing oil and solids from the water to be treated; or

将要处理的水导向包含至少一组纳滤膜的至少一个处理模块(20),其用于从要处理的水中除去硫酸根离子,leading the water to be treated to at least one treatment module (20) comprising at least one set of nanofiltration membranes for removing sulfate ions from the water to be treated,

其中,取决于要处理的水的类型,即,采出水或者海水,将所述体积的要处理的水导向包含微滤/超滤膜的至少一个处理模块(20)或者导向包含纳滤膜的至少一个水处理模块。Therein, depending on the type of water to be treated, i.e. produced water or seawater, said volume of water to be treated is directed to at least one treatment module (20) comprising microfiltration/ultrafiltration membranes or to a treatment module (20) comprising nanofiltration membranes. At least one water treatment module.

项目13.根据项目12的方法,特征在于将要处理的水导向处理模块(20)的步骤进一步包含通过至少两组平行的膜(20a,20b)来处理水。Item 13. The method according to item 12, characterized in that the step of directing the water to be treated to the treatment module (20) further comprises treating the water through at least two sets of parallel membranes (20a, 20b).

项目14.根据项目12或者13的方法,特征在于将要处理的水导向处理模块(20)的步骤进一步包含通过与其它组的膜(20a,20b)串联的至少一组膜(20c)来处理水。Item 14. The method according to item 12 or 13, characterized in that the step of directing the water to be treated to the treatment module (20) further comprises treating the water through at least one set of membranes (20c) in series with other sets of membranes (20a, 20b) .

项目15.根据项目12-14任一项的方法,特征在于要处理的水是油和固体浓缩的采出水和硫酸根离子浓缩的海水。Item 15. The method according to any one of items 12-14, characterized in that the water to be treated is produced water concentrated in oil and solids and seawater concentrated in sulfate ions.

项目16.根据项目15的方法,特征在于它另外包含步骤:控制通过提供有多个阀门的至少一个集管(18)进入每个处理模块(20)的水的类型,即,采出水或者海水。Item 16. The method according to item 15, characterized in that it additionally comprises the step of: controlling the type of water entering each treatment module (20) through at least one header (18) provided with a plurality of valves, i.e. produced water or seawater .

项目17.根据项目12-16任一项的方法,特征在于它进一步包含步骤:将油和固体中浓缩的水部分从包含至少一组微膜/超过滤的至少一个处理模块(20)导向至少一个处理槽(24)。Item 17. The method according to any one of items 12-16, characterized in that it further comprises the step of directing the concentrated water portion of oil and solids from at least one treatment module (20) comprising at least one set of micromembranes/ultrafiltration to at least A treatment tank (24).

项目18.根据项目17的方法,特征在于它进一步包含步骤:在处理槽(24)内在给定的时间段通过密度差来分离不太稠的油相和较稠的含水相。Item 18. The method according to item 17, characterized in that it further comprises the step of: separating a less thick oily phase and a thicker aqueous phase by density difference within a given period of time in the treatment tank (24).

项目19.项目18的方法,特征在于它进一步包含步骤:通过处理槽(24)下部中所提供的至少一个水出口来排出所分离的含水相。Item 19. The method of item 18, characterized in that it further comprises the step of discharging the separated aqueous phase through at least one water outlet provided in the lower part of the treatment tank (24).

项目20.根据项目19的方法,特征在于它进一步包含步骤:将所排出的含水相导向海洋废物处理或者导向至少一个处理模块(20)。Item 20. The method according to item 19, characterized in that it further comprises the step of directing the discharged aqueous phase to marine waste treatment or to at least one treatment module (20).

项目21.根据项目18-20任一项的方法,特征在于它进一步包含步骤:在含水相排出步骤之后,将处理槽(24)中其余的油性浓缩物导向水和油分离系统(23)中。Item 21. The method according to any one of items 18-20, characterized in that it further comprises the step of directing the remaining oily concentrate in the treatment tank (24) to the water and oil separation system (23) after the aqueous phase discharge step .

项目22.根据项目14-24任一项的方法,特征在于它进一步包含至少一个步骤:通过至少一个脱气器单元(28)来将经处理的水脱气。Item 22. The method according to any one of items 14-24, characterized in that it further comprises at least one step of deaerating the treated water by means of at least one deaerator unit (28).

项目23.根据项目12-22任一项的方法,特征在于它进一步包含至少一个步骤:通过将其中的水的流动反转,来反洗至少一个处理模块(20)的膜。Item 23. The method according to any one of items 12-22, characterized in that it further comprises at least one step of backwashing the membranes of at least one treatment module (20) by reversing the flow of water therein.

Claims (17)

1. A hybrid system for treating produced water and seawater for reinjection into an offshore oil reservoir, characterized by comprising:
at least one inlet for water to be treated, having a produced water inlet (2) and a seawater inlet (4);
at least one header (18) provided with a plurality of valves;
at least two processing modules (20), each module comprising:
at least one set of microfiltration/ultrafiltration membranes (20a, 20b, 20c) adapted to remove oil and solids from the produced water to be treated; and
at least one set of nanofiltration membranes (20a, 20b, 20c) adapted to remove sulfate ions from the seawater to be treated,
wherein the microfiltration/ultrafiltration membrane assembly membrane (20a, 20b, 20c) and the nanofiltration membrane assembly membrane (20a, 20b, 20c) are interchangeable; and
at least one outlet for treated water,
wherein the water to be treated is directed through at least one header (18), the at least one header (18) directing the produced water stream to a treatment module (20) comprising a microfiltration/ultrafiltration membrane or directing the seawater stream to a treatment module (20) comprising a nanofiltration membrane,
the at least one header is subdivided into two headers, one for controlling the produced water to enter the module comprising the microfiltration/ultrafiltration membrane and the other for controlling the seawater to enter the module comprising the nanofiltration membrane, and
there is no mixing between the produced water and the seawater before entering the treatment module (20), an
Each treatment module (20) comprises only one type of membrane, i.e. nanofiltration or microfiltration/ultrafiltration, and
shortly after implementation of the hybrid system, the seawater will only need to be treated by nanofiltration membranes, and as produced water is produced, the nanofiltration membranes of the treatment module (20) are replaced with microfiltration/ultrafiltration membranes.
2. The system according to claim 1, characterized in that each processing module (20) comprises at least two sets of membranes (20a, 20b) in parallel.
3. The system according to claim 1 or 2, characterized in that each processing module (20) comprises at least one set of membranes (20 c) in series with the other sets of membranes (20a, 20b).
4. System according to claim 1, characterized in that each inlet duct (2, 4) is subdivided into a plurality of parallel secondary ducts, one for each processing module (20).
5. System according to claim 1, characterized in that it additionally comprises at least one water treatment tank (24) adapted to separate the aqueous phase from the oil phase by means of a density difference.
6. The system of claim 5, characterized in that the water treatment tank (24) is in fluid communication with at least two treatment modules (20) downstream and upstream thereof to complete a cycle.
7. System according to claim 5 or 6, characterized in that the water treatment tank (24) is furthermore in fluid communication with at least one outlet for offshore disposal and one inlet conduit for produced water separated between water and oil.
8. A hybrid method for treating produced water and seawater for re-injection into an offshore oil reservoir, the method using the system defined in claim 1, characterized in that the method comprises the steps of:
directing the water to be treated to at least one water treatment module (20) comprising at least one set of microfiltration/ultrafiltration membranes adapted to remove oil and solids from the produced water to be treated; or
Directing the water to be treated to at least one treatment module (20) comprising at least one set of nanofiltration membranes adapted to remove sulphate ions from the seawater to be treated; and
backwashing the membranes of at least one treatment module (20) by reversing the flow of water therein,
wherein the water to be treated is directed through at least one header (18), the at least one header (18) directing the produced water stream to a treatment module (20) comprising a microfiltration/ultrafiltration membrane or directing the seawater stream to a treatment module (20) comprising a nanofiltration membrane.
9. A method according to claim 8, characterized in that the step of directing the water to be treated to the treatment module (20) further comprises treating the water by at least two sets of membranes (20a, 20b) in parallel.
10. A method according to claim 8 or 9, characterised in that the step of directing the water to be treated to the treatment module (20) further comprises treating the water by at least one set of membranes (20 c) in series with the other sets of membranes (20a, 20b).
11. A method according to claim 8 or 9, characterized in that the water to be treated is produced water concentrated with oil and solids and seawater concentrated with sulphate ions.
12. Method according to claim 8 or 9, characterized in that it further comprises the step of: a portion of the oil and solids-enriched water is directed from at least one treatment module (20) containing at least one set of micro/ultrafiltration membranes to at least one treatment tank (24).
13. Method according to claim 12, characterized in that it further comprises the step of: the less thick oil phase is separated from the thicker water phase by a density difference in a given period of time in a treatment tank (24).
14. The method as recited in claim 13, characterized in that it further comprises the step of: the separated aqueous phase is discharged through at least one water outlet provided in the lower part of the treatment tank (24).
15. Method according to claim 14, characterized in that it further comprises the step of: the discharged aqueous phase is directed for offshore disposal or to at least one treatment module (20).
16. Method according to claim 13, characterized in that it further comprises the step of: after the aqueous phase discharge step, the remaining oily concentrate in the treatment tank (24) is directed to a water and oil separation system (23).
17. Method according to claim 13, characterized in that it further comprises at least one step of: the treated water is degassed by at least one degasser unit (28).
CN202310031004.5A 2016-07-20 2017-07-19 Hybrid system and method for treating produced water and seawater to be reinjected into subsea oil reservoirs Pending CN115925051A (en)

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PCT/BR2017/000076 WO2018014096A1 (en) 2016-07-20 2017-07-19 Hybrid system and method for treating produced water and sea water to be re-injected into a subsea oil reservoir
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