CN115895473A - A kind of waterproof point-resistant impact-absorbing acrylic foam tape and its preparation method - Google Patents
A kind of waterproof point-resistant impact-absorbing acrylic foam tape and its preparation method Download PDFInfo
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Abstract
本发明公开了一种防水型耐点冲击吸收丙烯酸泡棉胶带及其制备方法,包括保护层、粘接层及泡棉层,所述保护层为离型纸,数量为1层,所述粘接层具有粘性,数量为3层,所述泡棉层采用丙烯酸树脂制成,数量为2层,分别为第一泡棉层和第二泡棉层,所述第一泡棉层的一侧与其中一个所述粘接层连接,所述第二泡棉层的两侧均与所述粘接层连接,与所述第一泡棉层和所述第二泡棉层连接的两层所述粘接层通过所述离型纸连接。本发明中的第一泡棉层与第二泡棉层能够分离开来,可以将第一泡棉层或者第二泡棉层原先与离型纸接触的一侧贴附在正确的区域上,在不需要返厂贴附的情况下,解决了泡棉胶带贴附错误,降低了返厂带来的运输成本。
The invention discloses a waterproof point impact-resistant acrylic foam tape and a preparation method thereof, comprising a protective layer, an adhesive layer and a foam layer. The bonding layer is viscous, and the number is 3 layers. The foam layer is made of acrylic resin, and the number is 2 layers, which are respectively the first foam layer and the second foam layer. One side of the first foam layer connected to one of the adhesive layers, both sides of the second foam layer are connected to the adhesive layer, and the two layers connected to the first foam layer and the second foam layer are The adhesive layer is connected through the release paper. The first foam layer in the present invention can be separated from the second foam layer, and the side of the first foam layer or the second foam layer that was originally in contact with the release paper can be attached to the correct area, In the case that there is no need to return to the factory for attachment, it solves the error of attaching the foam tape and reduces the transportation cost caused by returning to the factory.
Description
技术领域technical field
本发明涉及泡棉胶带技术领域,尤其涉及一种防水型耐点冲击吸收丙烯酸泡棉胶带及其制备方法。The invention relates to the technical field of foam tapes, in particular to a waterproof type impact-resistant acrylic foam tape and a preparation method thereof.
背景技术Background technique
泡棉胶带具有出色的密封性、阻燃性等功能,广泛应用于电子电器产品等相关领域。Foam tape has excellent sealing performance, flame retardancy and other functions, and is widely used in related fields such as electronic and electrical products.
一般地,在对电子电器产品加工过程中将泡棉胶带贴附在相应区域上,之后,当发现贴附的区域错误时,只能将贴错泡棉胶带的电子电器产品返回工厂流水线重新贴附,但贴附这类行为较为简单,只是贴附错误的泡棉胶带无法再次使用,而缺少泡棉胶带,返厂重新贴附使得运输成本增加,发明人根据上述缺陷作出改进,提出一种防水型耐点冲击吸收丙烯酸泡棉胶带及其制备方法。Generally, during the processing of electronic and electrical products, the foam tape is attached to the corresponding area. Afterwards, when it is found that the attached area is wrong, the electronic and electrical products with the wrong foam tape can only be returned to the factory assembly line for re-attachment. Attached, but the behavior of attaching is relatively simple, but the wrongly attached foam tape cannot be used again, and the lack of foam tape, returning to the factory for re-attachment will increase the transportation cost. The inventor made improvements based on the above defects and proposed a Waterproof point-resistant impact-absorbing acrylic foam adhesive tape and its preparation method.
发明内容Contents of the invention
本发明的目的是为了解决泡棉胶带贴附错误,需返厂重新贴附而增加运输成本,而提出的一种防水型耐点冲击吸收丙烯酸泡棉胶带及其制备方法。The purpose of the present invention is to solve the problem of foam tape being attached incorrectly, which needs to be returned to the factory for re-attachment to increase transportation costs, and proposes a waterproof point-resistant impact-absorbing acrylic foam tape and a preparation method thereof.
为了实现上述目的,本发明采用了如下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:
一种防水型耐点冲击吸收丙烯酸泡棉胶带及其制备方法,包括保护层、粘接层及泡棉层,其特征在于,所述保护层为离型纸,数量为1层,所述粘接层具有粘性,数量为3层,所述泡棉层采用丙烯酸树脂制成,数量为2层,分别为第一泡棉层和第二泡棉层,所述第一泡棉层的一侧与其中一个所述粘接层连接,所述第二泡棉层的两侧均与所述粘接层连接,与所述第一泡棉层和所述第二泡棉层连接的两层所述粘接层通过所述离型纸连接。A waterproof point-resistant impact-absorbing acrylic foam tape and a preparation method thereof, comprising a protective layer, an adhesive layer and a foam layer, characterized in that the protective layer is a release paper, the number of which is one layer, and the adhesive The bonding layer is viscous, and the number is 3 layers. The foam layer is made of acrylic resin, and the number is 2 layers, which are respectively the first foam layer and the second foam layer. One side of the first foam layer connected to one of the adhesive layers, both sides of the second foam layer are connected to the adhesive layer, and the two layers connected to the first foam layer and the second foam layer are The adhesive layer is connected through the release paper.
优选地,粘接层为压敏胶涂布形成,压敏胶为丙烯酸酯压敏胶粘剂。Preferably, the adhesive layer is formed by coating a pressure-sensitive adhesive, and the pressure-sensitive adhesive is an acrylate pressure-sensitive adhesive.
优选地,所述粘接层包括如下重量份数的组分:100份丙烯酸树脂、10-15份丙烯酸橡胶、2-5份二异氰酸酯固化剂、0.5-1份偶联剂、0.2-1份分散剂、1-3份黑色颜料、0.5-1.5份未膨胀发泡粉。Preferably, the adhesive layer includes the following components in parts by weight: 100 parts of acrylic resin, 10-15 parts of acrylic rubber, 2-5 parts of diisocyanate curing agent, 0.5-1 part of coupling agent, 0.2-1 part Dispersant, 1-3 parts of black pigment, 0.5-1.5 parts of unexpanded foaming powder.
优选地,所述丙烯酸树脂包括如下重量份数的组分:26-30份丙烯酸丁酯、36-38份丙烯酸乙酯、0.5-1.5份丙烯酸、3-6份乙酸乙烯酯、28-32份甲基丙烯酸甲酯、0.1-0.5份过氧化二苯甲酰、100份乙酸乙酯。Preferably, the acrylic resin includes the following components in parts by weight: 26-30 parts of butyl acrylate, 36-38 parts of ethyl acrylate, 0.5-1.5 parts of acrylic acid, 3-6 parts of vinyl acetate, 28-32 parts Methyl methacrylate, 0.1-0.5 parts of dibenzoyl peroxide, 100 parts of ethyl acetate.
优选地,所述离型纸具有底纸层、淋膜层和硅油层,所述底纸层的数量为1层,所述淋膜层和所述硅油层的数量均为2层。Preferably, the release paper has a backing paper layer, a coating layer and a silicone oil layer, the number of the backing paper layer is 1, and the number of the coating layer and the silicone oil layer are 2 layers.
优选地,所述底纸层的两侧与所述淋膜层连接,所述淋膜层远离所述底纸层的一侧与所述硅油层连接,所述硅油层与所述粘接层连接。Preferably, both sides of the backing paper layer are connected to the coating layer, the side of the coating layer away from the backing paper layer is connected to the silicone oil layer, and the silicone oil layer is connected to the adhesive layer. connect.
优选地,所述第一泡棉层和所述第二泡棉层与所述粘接层连接的一侧上开设有多个凹孔,所述凹孔的深度小于所述第一泡棉层和所述第二泡棉层的厚度。Preferably, a plurality of concave holes are opened on the side where the first foam layer and the second foam layer are connected to the adhesive layer, and the depth of the concave holes is smaller than that of the first foam layer. and the thickness of the second foam layer.
优选地,多个所述凹孔在所述第一泡棉层和所述第二泡棉层上呈阵列排布。Preferably, a plurality of the concave holes are arranged in an array on the first foam layer and the second foam layer.
防水型耐点冲击吸收丙烯酸泡棉胶带的制备方法,其特征在于,包括如下步骤:The preparation method of waterproof point-resistant impact-absorbing acrylic foam tape is characterized in that it comprises the following steps:
第一步:先加入丙烯酸树脂与丙烯酸橡胶,搅拌均匀后,依次加入分散剂、偶联剂、黑色颜料、二异氰酸酯固化剂、未膨胀发泡粉后搅拌均匀过滤后,得到粘弹性体组合泡棉;The first step: first add acrylic resin and acrylic rubber, stir evenly, then add dispersant, coupling agent, black pigment, diisocyanate curing agent, unexpanded foaming powder, stir evenly and filter to obtain viscoelastic composite foam cotton;
第二步:将粘弹性体组合泡棉置于相应的模具中,该模具内具有多个呈阵列排布的凸点,随后进行发泡,在烤箱中发泡至110-140um后,取出后收卷放置;Step 2: Put the viscoelastic composite foam into the corresponding mold, which has multiple bumps arranged in an array, and then foam it. After foaming in the oven to 110-140um, take it out Rewind and place;
第三步:在温度为40℃-60℃的环境下熟化72h,得到防水型耐点冲击吸收丙烯酸泡棉胶带。Step 3: Curing for 72 hours at a temperature of 40°C-60°C to obtain a waterproof type impact-resistant acrylic foam tape.
优选地,所述烤箱的发泡温度为65-75℃。Preferably, the foaming temperature of the oven is 65-75°C.
相比现有技术,本发明的有益效果为:Compared with the prior art, the beneficial effects of the present invention are:
1、本发明中的第一泡棉层与第二泡棉层能够分离开来,可以将第一泡棉层或者第二泡棉层原先与离型纸接触的一侧贴附在正确的区域上,在不需要返厂贴附的情况下,解决了泡棉胶带贴附错误,降低了返厂带来的运输成本。1. The first foam layer and the second foam layer in the present invention can be separated, and the side of the first foam layer or the second foam layer that was originally in contact with the release paper can be attached to the correct area In addition, in the case of no need to return to the factory for attachment, it solves the error of attaching the foam tape and reduces the transportation cost caused by returning to the factory.
2、本发明中凹孔的设置,能够容纳部分粘接层的压敏胶,在相同压敏胶重量的情况下,能够使得粘接层的厚度减小,便于压敏胶在第一泡棉层和在第二泡棉层上的涂布操作,同时也减小了泡棉胶带的总厚度,有助于人工贴附操作。2. The setting of the concave hole in the present invention can accommodate part of the pressure-sensitive adhesive of the adhesive layer. Under the same pressure-sensitive adhesive weight, the thickness of the adhesive layer can be reduced, which is convenient for the pressure-sensitive adhesive to be placed in the first foam. layer and the coating operation on the second foam layer also reduces the overall thickness of the foam tape and facilitates the manual application operation.
附图说明Description of drawings
图1为本发明提出的一种防水型耐点冲击吸收丙烯酸泡棉胶带实施例一的结构示意图;Fig. 1 is the structure schematic diagram of embodiment one of a kind of waterproof point impact-resistant absorbing acrylic foam adhesive tape proposed by the present invention;
图2为图1中离型纸的结构示意图;Fig. 2 is the structural representation of release paper in Fig. 1;
图3为图2中A处的放大结构示意图;Fig. 3 is the schematic diagram of the enlarged structure of place A in Fig. 2;
图4为本发明提出的一种防水型耐点冲击吸收丙烯酸泡棉胶带实施例二的结构示意图。Fig. 4 is a structural schematic diagram of
图中:10、离型纸;11、底纸层;12、淋膜层;13、硅油层;20、粘接层;30、第一泡棉层;31、第二泡棉层;32、凹孔。In the figure: 10, release paper; 11, bottom paper layer; 12, coating layer; 13, silicone oil layer; 20, adhesive layer; 30, first foam layer; 31, second foam layer; 32, concave hole.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例,基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the present invention, not all of them. Based on The embodiments of the present invention and all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
在本发明的描述中,需要说明的是,术语“上”、“下”、“内”、“外”、“顶/底端”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of the present invention, it should be noted that the orientations or positional relationships indicated by the terms "upper", "lower", "inner", "outer", "top/bottom" etc. are based on the orientations shown in the drawings Or positional relationship is only for the convenience of describing the present invention and simplifying the description, but does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be construed as limiting the present invention. In addition, the terms "first" and "second" are used for descriptive purposes only, and should not be understood as indicating or implying relative importance.
在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“设置有”、“套设/接”、“连接”等,应做广义理解,例如“连接”,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that, unless otherwise specified and limited, the terms "installed", "set with", "sleeved/connected", "connected", etc. should be understood in a broad sense, such as " Connection" can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediary, and it can be an internal connection between two components. connectivity. Those of ordinary skill in the art can understand the specific meanings of the above terms in the present invention in specific situations.
参照图1-图4,Referring to Figure 1-Figure 4,
实施例一:Embodiment one:
一种防水型耐点冲击吸收丙烯酸泡棉胶带,包括保护层、粘接层及泡棉层,保护层为离型纸10,数量为1层,粘接层20具有粘性,数量为3层,泡棉层采用丙烯酸树脂制成,数量为2层,分别为第一泡棉层30和第二泡棉层31,第一泡棉层30的一侧与其中一个粘接层20连接,第二泡棉层31的两侧均与粘接层20连接,与第一泡棉层30和第二泡棉层31连接的两层粘接层20通过离型纸10连接。A waterproof point-resistant impact-absorbing acrylic foam tape, including a protective layer, an adhesive layer and a foam layer, the protective layer is a
进一步地,粘接层20为压敏胶涂布形成,压敏胶为丙烯酸酯压敏胶粘剂;Further, the
胶黏剂的制备方法为:The preparation method of adhesive is:
第一步:先称取丙烯酸酯聚合物溶液于配胶桶内,开启搅拌器;The first step: first weigh the acrylate polymer solution in the glue mixing bucket, and start the agitator;
第二步:再称取增粘树脂溶液加入搅拌的胶桶中,直至搅拌均匀;Step 2: Weigh the tackifying resin solution and add it to the mixing bucket until it is evenly stirred;
第三步:最后加入交联剂,继续搅拌40分钟,加入交联剂后所得胶液,务必于搅拌结束后两个小时内使用完毕。Step 3: Finally, add the cross-linking agent and continue to stir for 40 minutes. The glue obtained after adding the cross-linking agent must be used up within two hours after the end of stirring.
进一步地,粘接层20包括如下重量份数的组分:100份丙烯酸树脂、10-15份丙烯酸橡胶、2-5份二异氰酸酯固化剂、0.5-1份偶联剂、0.2-1份分散剂、1-3份黑色颜料、0.5-1.5份未膨胀发泡粉。Further, the
进一步地,丙烯酸树脂包括如下重量份数的组分:26-30份丙烯酸丁酯、36-38份丙烯酸乙酯、0.5-1.5份丙烯酸、3-6份乙酸乙烯酯、28-32份甲基丙烯酸甲酯、0.1-0.5份过氧化二苯甲酰、100份乙酸乙酯。Further, the acrylic resin includes the following components in parts by weight: 26-30 parts of butyl acrylate, 36-38 parts of ethyl acrylate, 0.5-1.5 parts of acrylic acid, 3-6 parts of vinyl acetate, 28-32 parts of methyl Methyl acrylate, 0.1-0.5 parts of dibenzoyl peroxide, 100 parts of ethyl acetate.
其中,所述丙烯酸树脂的制备方法包括如下步骤:Wherein, the preparation method of described acrylic resin comprises the steps:
称取上述组分的相应重量份数,在80℃条件下反应5h,得到混合物,然后保温3h后,混合物达到一定粘度后卸下,得到丙烯酸树脂。Weigh the corresponding parts by weight of the above components, react at 80° C. for 5 hours to obtain a mixture, and keep warm for 3 hours, and unload the mixture after reaching a certain viscosity to obtain an acrylic resin.
进一步地,离型纸10具有底纸层11、淋膜层12和硅油层13,底纸层11的数量为1层,淋膜层12和硅油层13的数量均为2层。Further, the
进一步地,底纸层11的两侧与淋膜层12连接,淋膜层12远离底纸层11的一侧与硅油层13连接,硅油层13与粘接层20连接。Further, both sides of the
实施例二:Embodiment two:
实施例二是对实施例一的改进,具体地:
第一泡棉层30和第二泡棉层31与粘接层20连接的一侧上开设有多个凹孔32,凹孔32的深度小于第一泡棉层30和第二泡棉层31的厚度。A plurality of
凹孔32的设置,目的在于容纳部分粘接层20的压敏胶,在相同压敏胶重量的情况下,能够使得粘接层20的厚度减小,便于压敏胶在第一泡棉层30和在第二泡棉层31上的涂布操作,同时也减小了本申请泡棉胶带的总厚度,有助于人工贴附操作。The purpose of setting the
进一步地,多个凹孔32在第一泡棉层30和第二泡棉层31上呈阵列排布。Further, a plurality of
防水型耐点冲击吸收丙烯酸泡棉胶带的制备方法,包括如下步骤:The preparation method of the waterproof point-resistant impact-absorbing acrylic foam tape comprises the following steps:
第一步:先加入丙烯酸树脂与丙烯酸橡胶,搅拌均匀后,依次加入分散剂、偶联剂、黑色颜料、二异氰酸酯固化剂、未膨胀发泡粉后搅拌均匀过滤后,得到粘弹性体组合泡棉;The first step: first add acrylic resin and acrylic rubber, stir evenly, then add dispersant, coupling agent, black pigment, diisocyanate curing agent, unexpanded foaming powder, stir evenly and filter to obtain viscoelastic composite foam cotton;
第二步:将粘弹性体组合泡棉置于相应的模具中,该模具内具有多个呈阵列排布的凸点,随后进行发泡,在烤箱中发泡至110-140um后,取出后收卷放置;Step 2: Put the viscoelastic composite foam into the corresponding mold, which has multiple bumps arranged in an array, and then foam it. After foaming in the oven to 110-140um, take it out Rewind and place;
第三步:在温度为40℃-60℃的环境下熟化72h,得到防水型耐点冲击吸收丙烯酸泡棉胶带。Step 3: Curing for 72 hours at a temperature of 40°C-60°C to obtain a waterproof type impact-resistant acrylic foam tape.
其中,模具有两种,一种为只能够对粘弹性体组合泡棉一侧形成凹孔32,制作出的为第一泡面层30;Wherein, there are two kinds of moulds, one is that the
另一种能够对粘弹性体组合泡棉两侧形成凹孔32,制作出的为第一泡面层31。Another kind can form
进一步地,所述烤箱的发泡温度为65-75℃。Further, the foaming temperature of the oven is 65-75°C.
本发明的工作原理:Working principle of the present invention:
先制备第一泡棉层30和第二泡棉层31,并在第一泡棉层30和第二泡棉层31具有凹孔32的侧面上涂布压敏胶,之后将离型纸10置于第一泡棉层30和第二泡棉层31之间,起到隔离作用;First prepare the
泡棉胶带第一次贴附时,是第二泡棉层31远离离型纸10的一侧贴附在相应区域,之后,若发现泡棉胶带贴附位置错误,则直接整体撕扯下,之后找出其中的离型纸10,将第一泡棉层30和第二泡棉层31与离型纸10撕开,分离开来,可以将第一泡棉层30或者第二泡棉层31原先与离型纸10接触的一侧贴附在正确的区域上,在不需要返厂贴附的情况下,解决了泡棉胶带贴附错误,降低了返厂带来的运输成本。When the foam tape is attached for the first time, the side of the
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above is only a preferred embodiment of the present invention, but the scope of protection of the present invention is not limited thereto, any person familiar with the technical field within the technical scope disclosed in the present invention, according to the technical solution of the present invention Any equivalent replacement or change of the inventive concepts thereof shall fall within the protection scope of the present invention.
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