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CN115835682A - Packaging material, packaging film layer, display panel and display device - Google Patents

Packaging material, packaging film layer, display panel and display device Download PDF

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Publication number
CN115835682A
CN115835682A CN202211497222.XA CN202211497222A CN115835682A CN 115835682 A CN115835682 A CN 115835682A CN 202211497222 A CN202211497222 A CN 202211497222A CN 115835682 A CN115835682 A CN 115835682A
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layer
film layer
display panel
encapsulation
encapsulating
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高昕伟
许程
赵康
张帅
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BOE Technology Group Co Ltd
Hefei BOE Zhuoyin Technology Co Ltd
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BOE Technology Group Co Ltd
Hefei BOE Zhuoyin Technology Co Ltd
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Abstract

The application provides an encapsulating material, encapsulation rete, display panel and display device, encapsulating material is in the Fourier infrared absorption spectrogram, and the wave number is 1500cm ‑1 To 3500cm ‑1 The integrated area of absorption peak in the range of 500cm in wavenumber ‑1 To 3500cm ‑1 The integral area ratio of all absorption peaks in the range is 3% or less. The application provides an encapsulating material, encapsulation rete, display panel and display device, through high temperature and high humidity storage test and Fourier infrared spectroscopy analysis, confirm when encapsulating material wave number 1500cm in Fourier infrared absorption spectrogram ‑1 To 3500cm ‑1 The integral area of the absorption peak of the position accounts for 500cm in the Fourier infrared absorption spectrogram ‑1 ~3500cm ‑1 When the ratio of the integral area of all absorption peaks in the range is 3% or less, the adverse effect of the encapsulating layer formed of the encapsulating material on the oxide TFT can be reduced, and the adverse effect on the oxide TFT can be reducedThe possibility of negative drift of the threshold voltage Vth of the TFT is reduced, and the problem of poor display of the display device is further avoided.

Description

封装材料、封装膜层、显示面板和显示装置Packaging material, packaging film layer, display panel and display device

技术领域technical field

本申请涉及显示技术领域,尤其涉及一种封装材料、封装膜层、显示面板和显示装置。The present application relates to the field of display technology, and in particular to an encapsulation material, an encapsulation film layer, a display panel and a display device.

背景技术Background technique

由于OLED显示装置具有自发光、亮度高、画质好和能耗低等优点,已经成为显示技术领域的主流发展方向。OLED显示装置需要使用TFT(Thin Film Transistor,薄膜晶体管)进行像素驱动,在相关技术中,大尺寸OLED显示装置主要使用氧化物TFT进行驱动,但是包括氧化物TFT的显示装置,其显示面板在使用过程中容易发生TFT阈值电压漂移导致的OLED显示装置显示白斑亮度不均问题。Since the OLED display device has the advantages of self-luminescence, high brightness, good image quality and low energy consumption, it has become the mainstream development direction in the field of display technology. OLED display devices need to use TFT (Thin Film Transistor, Thin Film Transistor) for pixel driving. In the related art, large-size OLED display devices mainly use oxide TFTs for driving, but the display devices including oxide TFTs, the display panel is using During the process, the problem of uneven brightness of white spots displayed on the OLED display device caused by the drift of the TFT threshold voltage is likely to occur.

发明内容Contents of the invention

有鉴于此,本申请的目的在于提出一种封装材料、封装膜层、显示面板和显示装置,以克服或者至少部分地解决包括氧化物TFT的显示装置,其显示面板在使用过程中容易产生OLED显示装置显示白斑亮度不均问题。In view of this, the purpose of this application is to propose a packaging material, packaging film layer, display panel and display device, to overcome or at least partially solve the problem of display devices including oxide TFTs, the display panel of which is easy to produce OLED during use. The display device shows the problem of uneven brightness of white spots.

基于上述目的,本申请第一方面提供了封装材料,所述封装材料在傅里叶红外吸收谱图中波数为1500cm-1至3500cm-1范围内的吸收峰积分面积占波数为500cm-1至3500cm-1范围内全部吸收峰积分面积的比例小于等于3%。Based on the above purpose, the first aspect of the present application provides a packaging material, the packaging material in the Fourier transform infrared absorption spectrum wavenumber is 1500cm -1 to 3500cm -1 The integral area of the absorption peak in the range of wavenumber is 500cm-1 to 500cm -1 The proportion of the integral area of all absorption peaks within the range of 3500cm -1 is less than or equal to 3%.

可选的,所述封装材料为硅氧化合物,且所述硅氧化合物中的硅氧键的数量占所述硅氧化合物中化学键总数量的比例大于等于97%。Optionally, the encapsulation material is a silicon-oxygen compound, and the number of silicon-oxygen bonds in the silicon-oxygen compound accounts for greater than or equal to 97% of the total number of chemical bonds in the silicon-oxygen compound.

基于同一发明构思,本申请第二方面提供了封装膜层,包括如第一方面所述的封装材料。Based on the same inventive concept, the second aspect of the present application provides an encapsulation film layer, including the encapsulation material as described in the first aspect.

基于同一发明构思,本申请第三方面提供了显示面板,包括发光层和至少覆盖所述发光层发光侧的封装层,所述封装层朝向所述发光层一侧为如第二方面所述的封装膜层。Based on the same inventive concept, the third aspect of the present application provides a display panel, including a light-emitting layer and an encapsulation layer covering at least the light-emitting side of the light-emitting layer, and the side of the encapsulation layer facing the light-emitting layer is as described in the second aspect Encapsulation film layer.

可选的,所述封装层包括第一封装膜层和第二封装膜层,所述第一封装膜层包覆所述发光层,所述第二封装膜层设置于所述第一封装膜层远离所述发光层的一侧,且所述第二封装膜层的水汽透过率小于所述第一封装膜层的水汽透过率。Optionally, the encapsulation layer includes a first encapsulation film layer and a second encapsulation film layer, the first encapsulation film layer covers the light-emitting layer, and the second encapsulation film layer is disposed on the first encapsulation film layer layer away from the light-emitting layer, and the water vapor transmission rate of the second packaging film layer is lower than the water vapor transmission rate of the first packaging film layer.

可选的,所述第二封装膜层的水汽透过率小于0.001克每平方米每天。Optionally, the water vapor transmission rate of the second packaging film layer is less than 0.001 grams per square meter per day.

可选的,所述第一封装膜层的厚度大于等于0.3微米。Optionally, the thickness of the first packaging film layer is greater than or equal to 0.3 microns.

可选的,所述第二封装膜层的厚度小于等于1微米。Optionally, the thickness of the second packaging film layer is less than or equal to 1 micron.

可选的,所述显示面板还包括基板,所述发光层设置于所述基板的第一侧,所述第二封装层包覆所述第一封装层;所述基板的第一侧还设有围绕所述发光层的第一阻挡坝,所述第一阻挡坝的顶部设置有盖板,所述盖板、所述第一阻挡坝和所述基板围成的空间内设置有填充物封装层。Optionally, the display panel further includes a substrate, the luminescent layer is disposed on a first side of the substrate, and the second encapsulation layer covers the first encapsulation layer; There is a first barrier dam surrounding the light-emitting layer, a cover plate is provided on the top of the first barrier dam, and a filler package is provided in a space surrounded by the cover plate, the first barrier dam, and the substrate layer.

基于同一发明构思,本申请第四方面提供了显示装置,包括如第三方面所述的显示面板。Based on the same inventive concept, a fourth aspect of the present application provides a display device, including the display panel as described in the third aspect.

从上面所述可以看出,本申请提供的封装材料、封装膜层、显示面板和显示装置,通过高温高湿储存试验和傅里叶红外光谱分析,确定当封装材料在傅里叶红外吸收谱图中波数为1500cm-1至3500cm-1范围内的吸收峰积分面积占波数为500cm-1至3500cm-1范围内全部吸收峰积分面积的比例小于等于3%时,能够减少该封装材料所形成的封装层对氧化物TFT产生不良影响,从而降低TFT的阈值电压Vth发生负向漂移的可能,进而避免显示装置产生显示不良问题。As can be seen from the above, the packaging material, packaging film layer, display panel and display device provided by the application, through high-temperature and high-humidity storage tests and Fourier transform infrared spectrum analysis, determine that when the packaging material is in the Fourier transform infrared absorption spectrum In the figure, when the proportion of the integrated area of the absorption peak within the range of wavenumber 1500cm -1 to 3500cm -1 to the integral area of all absorption peaks within the range of wavenumber 500cm -1 to 3500cm - 1 is less than or equal to 3%, the formation of the encapsulation material can be reduced. The encapsulation layer has a bad influence on the oxide TFT, thereby reducing the possibility of negative drift of the threshold voltage Vth of the TFT, thereby avoiding the problem of poor display of the display device.

附图说明Description of drawings

为了更清楚地说明本申请或相关技术中的技术方案,下面将对实施例或相关技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本申请的实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the present application or related technologies, the following will briefly introduce the accompanying drawings that need to be used in the description of the embodiments or related technologies. Obviously, the accompanying drawings in the following description are only for this application Embodiments, for those of ordinary skill in the art, other drawings can also be obtained based on these drawings without any creative effort.

图1为氧化物TFT显示面板出现显示亮度不均的示意图;FIG. 1 is a schematic diagram of uneven display brightness of an oxide TFT display panel;

图2为亮度不均所在位置的氧化物TFT阈值电压Vth的数值曲线图示意图;FIG. 2 is a schematic diagram of a numerical curve diagram of an oxide TFT threshold voltage Vth at a position where brightness unevenness is located;

图3为氧化物TFT阈值电压Vth负漂移及显示面板出现白斑亮度不均而产生的像素收缩的不良示意图;Figure 3 is a bad schematic diagram of pixel shrinkage caused by negative drift of oxide TFT threshold voltage Vth and uneven brightness of white spots on the display panel;

图4为三种封装材料的傅里叶红外吸收谱图;Fig. 4 is the Fourier transform infrared absorption spectrum of three kinds of packaging materials;

图5为本申请实施例的显示面板的示意图。FIG. 5 is a schematic diagram of a display panel according to an embodiment of the present application.

附图标记说明:Explanation of reference signs:

1、封装层;101、第一封装膜层;102、第二封装膜层;2、发光层;3、填充物封装层;4、盖板;5、第一阻挡坝;6、基板;601、第一侧。1. Encapsulation layer; 101. First encapsulation film layer; 102. Second encapsulation film layer; 2. Luminescent layer; 3. Filler encapsulation layer; 4. Cover plate; 5. First barrier dam; 6. Substrate; 601 , the first side.

具体实施方式Detailed ways

为使本申请的目的、技术方案和优点更加清楚明白,以下结合具体实施例,并参照附图,对本申请进一步详细说明。In order to make the purpose, technical solutions and advantages of the present application clearer, the present application will be further described in detail below in conjunction with specific embodiments and with reference to the accompanying drawings.

应注意到:除非另外具体说明,否则在这些实施例中阐述的部件的相对布置、数字表达式和数值不限制本申请的范围。It should be noted that the relative arrangement of components, numerical expressions and numerical values set forth in these embodiments do not limit the scope of the present application unless specifically stated otherwise.

同时,应当明白,为了便于描述,附图中所示出的各个部分的尺寸并不是按照实际的比例关系绘制的。At the same time, it should be understood that, for the convenience of description, the sizes of the various parts shown in the drawings are not drawn according to the actual proportional relationship.

以下对至少一个示例性实施例的描述实际上仅仅是说明性的,绝不作为对本申请及其应用或使用的任何限制。The following description of at least one exemplary embodiment is merely illustrative in nature and is in no way intended to limit the application, its application or uses.

需要说明的是,除非另外定义,本申请实施例使用的技术术语或者科学术语应当为本申请所属领域内具有一般技能的人士所理解的通常意义。本申请实施例中使用的“第一”、“第二”以及类似的词语并不表示任何顺序、数量或者重要性,而只是用来区分不同的组成部分。“包括”或者“包含”等类似的词语意指出现该词前面的元件或者物件涵盖出现在该词后面列举的元件或者物件及其等同,而不排除其他元件或者物件。“连接”或者“相连”等类似的词语并非限定于物理的或者机械的连接,而是可以包括电性的连接,不管是直接的还是间接的。“上”、“下”、“左”、“右”等仅用于表示相对位置关系,当被描述对象的绝对位置改变后,则该相对位置关系也可能相应地改变。It should be noted that, unless otherwise defined, the technical terms or scientific terms used in the embodiments of the present application shall have the usual meanings understood by those skilled in the art to which the present application belongs. "First", "second" and similar words used in the embodiments of the present application do not indicate any order, quantity or importance, but are only used to distinguish different components. "Comprising" or "comprising" and similar words mean that the elements or items appearing before the word include the elements or items listed after the word and their equivalents, without excluding other elements or items. Words such as "connected" or "connected" are not limited to physical or mechanical connections, but may include electrical connections, whether direct or indirect. "Up", "Down", "Left", "Right" and so on are only used to indicate the relative positional relationship. When the absolute position of the described object changes, the relative positional relationship may also change accordingly.

显示面板之所以会出现亮度不均白斑,是由于氧化物TFT的阈值电压Vth发生负向漂移,导致电流增加,从而使得显示面板局部变亮。申请人经过研究发现,氧化物TFT的阈值电压Vth发生负向漂移的原因是由于氧化物TFT中的沟道层与显示面板的封装层之间产生反应,使得沟道的迁移率增加。The reason why the display panel has uneven brightness and white spots is that the threshold voltage Vth of the oxide TFT drifts negatively, which causes the current to increase, thereby making the display panel brighter locally. The applicant found through research that the negative shift of the threshold voltage Vth of the oxide TFT is due to the reaction between the channel layer in the oxide TFT and the packaging layer of the display panel, which increases the mobility of the channel.

如图1示出了氧化物TFT显示面板出现白斑的示意图。图2示出了白斑所在位置的氧化物TFT阈值电压Vth的数值曲线示意图,由该曲线可以看出氧化物TFT白斑处的阈值电压Vth相比于非白斑处(即白斑外圈以外的部分)的阈值电压Vth较低,且越靠近白斑中心位置,阈值电压Vth就越低,即白斑内圈的阈值电压Vth小于白斑中圈的阈值电压Vth小于白斑外圈的阈值电压Vth。图3示出了由于氧化物TFT阈值电压Vth负漂移及显示面板出现白斑而产生的像素收缩的不良示意图,像素收缩位置如图中虚线圆框所示。FIG. 1 shows a schematic diagram of white spots appearing on an oxide TFT display panel. Figure 2 shows a schematic diagram of the numerical curve of the threshold voltage Vth of the oxide TFT at the location of the white spot, from which it can be seen that the threshold voltage Vth of the oxide TFT white spot is compared with that of the non-white spot (that is, the part outside the outer circle of the white spot) The threshold voltage Vth of the white spot is lower, and the closer to the center of the white spot, the lower the threshold voltage Vth, that is, the threshold voltage Vth of the inner circle of the white spot is smaller than the threshold voltage Vth of the middle circle of the white spot is smaller than the threshold voltage Vth of the outer circle of the white spot. FIG. 3 shows a bad schematic diagram of pixel shrinkage due to the negative drift of the oxide TFT threshold voltage Vth and white spots on the display panel. The position of the pixel shrinkage is shown in the dotted circle box in the figure.

为了防止发生上述不良,需要对封装层所采用封装材料进行限定。In order to prevent the above defects, it is necessary to limit the encapsulation material used in the encapsulation layer.

有鉴于此,本申请实施例提供了一种封装材料,所述封装材料在傅里叶红外吸收谱图中波数为1500cm-1至3500cm-1范围内的吸收峰积分面积占波数为500cm-1至3500cm-1范围内全部吸收峰积分面积的比例小于等于3%。In view of this, an embodiment of the present application provides an encapsulation material, the integral area of the absorption peak in the Fourier transform infrared absorption spectrum ranges from 1500 cm -1 to 3500 cm -1 and the wave number is 500 cm -1 The ratio of the integral area of all absorption peaks within the range from 3500 cm -1 to 3500 cm -1 is less than or equal to 3%.

为了研究封装材料与产生白斑问题的对应关系,申请人选取三块OLED显示面板,三块OLED显示面板中的封装层的材料分别为SiON、SiNx和SiOx。对三块OLED显示面板进行高温高湿储存试验,示例性的,试验环境为温度范围在85±2℃,湿度范围在85±2%RH的稳定环境。在经过500小时的试验后,发现仅封装层为SiOx材料的OLED显示面板未出现白斑问题。In order to study the corresponding relationship between packaging materials and white spots, the applicant selected three OLED display panels, and the materials of the packaging layers in the three OLED display panels were SiON, SiNx and SiOx respectively. A high-temperature and high-humidity storage test is carried out on three OLED display panels. Exemplarily, the test environment is a stable environment with a temperature range of 85±2° C. and a humidity range of 85±2% RH. After 500 hours of testing, it was found that only the encapsulation layer of the OLED display panel made of SiOx material did not have the problem of white spots.

为了进一步探究上述三种封装材料与产生白斑之间的对应关系,对三块OLED显示面板中三种材料的封装层进行傅里叶红外光谱分析,获得傅里叶红外吸收谱图(以下简称吸收谱图)如图4所示,图中横坐标为波数(Wavernumber),单位为cm-1;纵坐标为吸收度(Absorbance)。由图中可以看出,在波数为500cm-1至1500cm-1位置范围内三种材料均有吸收峰,而在波数为1500cm-1至3500cm-1位置范围内三种材料的吸收峰出现较大区别,因此推测在波数为1500cm-1至3500cm-1位置范围内的吸收峰是对造成封装层与氧化物TFT中的沟道层产生反应从而使显示面板出现白斑问题的主要影响因素。In order to further explore the correspondence between the above three encapsulation materials and the generation of white spots, Fourier transform infrared spectroscopy was carried out on the encapsulation layers of the three materials in the three OLED display panels to obtain the Fourier transform infrared absorption spectrum (hereinafter referred to as absorption Spectrum) as shown in Figure 4, the abscissa in the figure is the wave number (Wavernumber), the unit is cm −1 ; the ordinate is the absorbance (Absorbance). It can be seen from the figure that all three materials have absorption peaks in the range of wavenumbers from 500cm -1 to 1500cm -1 , and the absorption peaks of the three materials appear relatively relatively in the range of wavenumbers from 1500cm -1 to 3500cm -1 Therefore, it is speculated that the absorption peak in the range of wavenumbers from 1500cm -1 to 3500cm -1 is the main factor that causes the reaction between the packaging layer and the channel layer in the oxide TFT, resulting in white spots on the display panel.

为了表征上述对应关系,通过现有软件对每种材料在波数为1500cm-1至3500cm-1位置范围内的吸收峰的积分面积分别进行求解,以及对每种材料在吸收谱图中全部吸收峰(即波数为500cm-1至3500cm-1位置范围内)的积分面积总和分别进行求解,在得到上述求解结果后,再分别计算每种材料在波数为1500cm-1至3500cm-1位置范围内的吸收峰的积分面积占其吸收谱图中全部吸收峰积分面积的比例,示例性的,对于SiON材料,该比例为7%;对于SiOx材料,该比例为3%。通过上述求得的比例结果结合结合高温高湿储存试验的实验结果可知,封装材料的该比例越大越容易造成由该封装材料所形成的封装层与氧化物TFT中的沟道层发生反应,进而使显示面板产生白斑问题。因此,能够确定当封装材料的上述比例小于等于3%时,能够防止其所形成的封装层与氧化物TFT中的沟道层发生反应,进而能够避免显示面板产生白斑。In order to characterize the above corresponding relationship, the integrated area of the absorption peaks of each material in the range of wavenumbers from 1500cm -1 to 3500cm -1 is solved by existing software, and all the absorption peaks of each material in the absorption spectrum (that is, the wavenumber is within the range of 500cm -1 to 3500cm -1 ), the sum of the integral areas is solved separately, and after the above solution results are obtained, the area of each material in the range of wavenumber from 1500cm -1 to 3500cm -1 is calculated separately. The proportion of the integral area of the absorption peak to the integral area of all absorption peaks in the absorption spectrum, for example, for SiON material, this proportion is 7%; for SiOx material, this proportion is 3%. According to the ratio results obtained above combined with the experimental results of the high-temperature and high-humidity storage test, it can be known that the larger the ratio of the packaging material, the easier it is to cause the packaging layer formed by the packaging material to react with the channel layer in the oxide TFT, and then Cause white spots on the display panel. Therefore, it can be determined that when the above-mentioned proportion of the encapsulation material is less than or equal to 3%, the encapsulation layer formed therein can be prevented from reacting with the channel layer in the oxide TFT, and thus white spots can be avoided on the display panel.

本实施例提供的封装材料,通过高温高湿储存试验和傅里叶红外光谱分析,确定当封装材料在傅里叶红外吸收谱图中波数为1500cm-1至3500cm-1范围内的吸收峰积分面积占波数为500cm-1至3500cm-1范围内全部吸收峰积分面积的比例小于等于3%时,能够减少该封装材料所形成的封装层对氧化物TFT产生不良影响,从而降低TFT的阈值电压Vth发生负向漂移的可能,进而避免显示装置产生显示不良问题。For the packaging material provided in this embodiment, through high-temperature and high-humidity storage tests and Fourier transform infrared spectrum analysis, it is determined that when the packaging material has a wave number in the Fourier transform infrared absorption spectrum, the absorption peak integral within the range of 1500cm -1 to 3500cm -1 When the area accounts for less than or equal to 3% of the integrated area of all absorption peaks within the range of wavenumbers from 500cm -1 to 3500cm -1 , it can reduce the adverse effect of the packaging layer formed by the packaging material on the oxide TFT, thereby reducing the threshold voltage of the TFT The possibility of negative drift of Vth occurs, thereby avoiding the problem of poor display of the display device.

在相关技术中,沟道层的材料可以为包括In、Ga、Zn、Sn、Pr(镧系元素)中的至少一种或几种元素的金属氧化物或者金属氮氧化物,例如IGZO、IGTO、IGO、ITO、IGZTO、IZO、ZTO、InO、ZnON、Pr-IGZO等材料中的至少一种或几种。例如,沟道层为包括In、Ga、Zn、Sn、Pr(镧系元素)中的至少一种或几种元素的金属氧化物半导体层或者金属氮氧化物半导体层,例如包括IGZO层、IGTO层、IGO层、ITO层、IGZTO层、IZO层、ZTO层、InO层、ZnON层、Pr-IGZO层中的至少一种或几种。In the related art, the material of the channel layer can be metal oxide or metal oxynitride including at least one or several elements of In, Ga, Zn, Sn, Pr (lanthanides), such as IGZO, IGTO , IGO, ITO, IGZTO, IZO, ZTO, InO, ZnON, Pr-IGZO and other materials at least one or more. For example, the channel layer is a metal oxide semiconductor layer or a metal oxynitride semiconductor layer including at least one or several elements of In, Ga, Zn, Sn, Pr (lanthanides), such as IGZO layer, IGTO layer, IGO layer, ITO layer, IGZTO layer, IZO layer, ZTO layer, InO layer, ZnON layer, Pr-IGZO layer at least one or more.

以采用IGZO(氧化铟镓锌)等氧化物半导体作为沟道层为例进行说明,申请人经研究发现,沟道层材料氧化铟镓锌即IGZO能够与氢发生反应,生成OH-离子,OH-离子的产生使得沟道的迁移率增加使得部分氧化物TFT的阈值电压Vth发生负向漂移。Taking the use of oxide semiconductors such as IGZO (indium gallium zinc oxide) as an example to illustrate the channel layer, the applicant has found through research that the material of the channel layer, indium gallium zinc oxide (IGZO), can react with hydrogen to generate OH- ions, OH - The generation of ions increases the mobility of the channel so that the threshold voltage Vth of the partial oxide TFT shifts negatively.

而相关技术中,封装层通常是通过化学气相沉积法制备形成的薄膜,示例性的,如采用常压化学气相沉积法制备氮氧化硅的薄膜,所用原料为NH3和SiH2,所形成的氮氧化硅的薄膜中会含有由于氨气裂解而引入的杂质氢。封装层中的杂质氢能够通过粒子(particle)等路径渗透后和沟道层发生反应,进而造成氧化物TFT的阈值电压Vth发生负向漂移。In related technologies, the encapsulation layer is usually a thin film prepared by chemical vapor deposition. For example, a silicon nitride oxide thin film is prepared by atmospheric pressure chemical vapor deposition, and the raw materials used are NH 3 and SiH 2 . The thin film of silicon oxynitride may contain impurity hydrogen introduced by the cracking of ammonia gas. Impurity hydrogen in the encapsulation layer can permeate through paths such as particles and react with the channel layer, thereby causing the threshold voltage Vth of the oxide TFT to shift negatively.

结合前述的实验结果,为了减小封装材料中的杂质氢含量,一些实施例中,所述封装材料为硅氧化合物,且所述硅氧化合物中的硅氧键的数量占所述硅氧化合物中化学键总数量的比例大于等于97%。In combination with the foregoing experimental results, in order to reduce the impurity hydrogen content in the packaging material, in some embodiments, the packaging material is a silicon-oxygen compound, and the number of silicon-oxygen bonds in the silicon-oxygen compound accounts for The proportion of the total number of chemical bonds is greater than or equal to 97%.

结合图4,吸收谱图中每个材料的吸收峰对应一个化学键,而每个吸收峰的积分面积则代表吸收波数在这一范围内的化学键数量。Combined with Figure 4, the absorption peak of each material in the absorption spectrum corresponds to a chemical bond, and the integrated area of each absorption peak represents the number of chemical bonds whose absorption wavenumber is within this range.

通过吸收谱图,可确定SiOx在波数为1000cm-1至1500cm-1位置范围内的该吸收峰对应Si-O化学键,其积分面积占吸收谱图中SiOx全部吸收峰的总积分面积的97%,即Si-O化学键的数量占SiOx中所包含的化学键的总数量的97%。而SiOx中的杂质氢通常会以X-H化学键的形式存在,当确定Si-O化学键的数量占总化学键数量的97%后,即可认为X-H化学键数量占比是小于等于3%的。因此,结合前述的高温高湿储存试验,可确定当封装材料为SiOx,且其中Si-O化学键的数量与SiOx中化学键总数量的比例大于等于97%时,能够减少该封装材料所形成的封装层对氧化物TFT产生不良影响,从而降低TFT的阈值电压Vth发生负向漂移的可能,进而避免显示装置产生白斑。Through the absorption spectrum, it can be determined that the absorption peak of SiOx in the range of wavenumbers from 1000cm -1 to 1500cm -1 corresponds to the Si-O chemical bond, and its integrated area accounts for 97% of the total integrated area of all SiOx absorption peaks in the absorption spectrum , that is, the number of Si-O chemical bonds accounts for 97% of the total number of chemical bonds contained in SiOx. The impurity hydrogen in SiOx usually exists in the form of XH chemical bonds. When it is determined that the number of Si-O chemical bonds accounts for 97% of the total number of chemical bonds, it can be considered that the proportion of XH chemical bonds is less than or equal to 3%. Therefore, in combination with the aforementioned high-temperature and high-humidity storage test, it can be determined that when the packaging material is SiOx, and the ratio of the number of Si-O chemical bonds to the total number of chemical bonds in SiOx is greater than or equal to 97%, the package formed by the packaging material can be reduced. The layer has an adverse effect on the oxide TFT, thereby reducing the possibility of a negative drift of the threshold voltage Vth of the TFT, thereby avoiding white spots on the display device.

基于同一个发明构思,结合上述各个实施例的封装材料的描述,本实施例提供一种封装膜层,该封装膜层具有上述各个实施例的封装材料相应的技术效果,在此不再赘述。Based on the same inventive concept, combined with the descriptions of the packaging materials in the above embodiments, this embodiment provides a packaging film layer, which has the corresponding technical effects of the packaging materials in the above embodiments, which will not be repeated here.

一种封装膜层,包括如上述各个实施例的封装材料。An encapsulation film layer, comprising the encapsulation material of each of the above embodiments.

需要说明的是,封装膜层可包括一种或多种硅氧化合物,但封装膜层整体材料特性需符合上述各个实施例中封装材料的特性,以减少该封装材料所形成的封装层对氧化物TFT产生不良影响。It should be noted that the encapsulation film layer may include one or more silicon oxide compounds, but the overall material characteristics of the encapsulation film layer must conform to the characteristics of the encapsulation material in each of the above embodiments, so as to reduce the oxidation resistance of the encapsulation layer formed by the encapsulation material. The material TFT has adverse effects.

基于同一个发明构思,结合上述各个实施例的封装膜层的描述,本实施例提供一种显示面板,该显示面板具有上述各个实施例的封装膜层相应的技术效果,在此不再赘述。Based on the same inventive concept, combined with the descriptions of the packaging film layers in the above embodiments, the present embodiment provides a display panel, which has the corresponding technical effects of the packaging film layers in the above embodiments, which will not be repeated here.

如图5所示,一种显示面板,包括发光层2和至少覆盖所述发光层2发光侧的封装层1,所述封装层1朝向所述发光层2一侧为如上述实施例所述的封装膜层。As shown in FIG. 5 , a display panel includes a light-emitting layer 2 and an encapsulation layer 1 covering at least the light-emitting side of the light-emitting layer 2. The side of the encapsulation layer 1 facing the light-emitting layer 2 is as described in the above-mentioned embodiments. packaging film layer.

示例性的,发光层2可以为有机发光二极管器件或电致发光器件(EL)。Exemplarily, the light emitting layer 2 may be an organic light emitting diode device or an electroluminescent device (EL).

示例性的,发光层2可以为顶发射结构或底发射结构,在本实施例中,以顶发射结构为例进行说明。Exemplarily, the light emitting layer 2 may be a top emission structure or a bottom emission structure, and in this embodiment, a top emission structure is used as an example for illustration.

示例性的,封装层1可为一层或多层,为了通过上述实施例的封装膜层对发光层2进行保护,当封装层1为多层时,需要使上述封装膜层为与发光层2距离最近的结构层,以防止含氢量较高的其他结构层对氧化物TFT造成不良影响。Exemplarily, the encapsulation layer 1 can be one or more layers. In order to protect the light-emitting layer 2 through the encapsulation film layer of the above embodiment, when the encapsulation layer 1 is multi-layered, it is necessary to make the above-mentioned encapsulation film layer be the same as the light-emitting layer. 2 The closest structural layer to prevent adverse effects on the oxide TFT caused by other structural layers with higher hydrogen content.

对于SiOx材料所形成的封装膜层,虽然其含氢量较小,能够避免对氧化物TFT产生不良影响,但是其阻水性较差,若封装层1仅为SiOx材料所形成的封装膜层,在温度和湿度较大的使用环境下,可能会发生封装层1的有效性降低,甚至失效。一旦SiOx材料所形成的封装膜层失效,空气中的氧气O2、氢气H2和水H2O等气体就会进入到封装层1内,与IGZO沟道层进行反应,进而导致氧化物TFT的阈值电压Vth发生负向漂移,显示装置产生白斑。For the encapsulation film layer formed by SiOx material, although its hydrogen content is small, it can avoid adverse effects on the oxide TFT, but its water resistance is poor. If the encapsulation layer 1 is only an encapsulation film layer formed by SiOx material, In a use environment with high temperature and humidity, the effectiveness of the encapsulation layer 1 may decrease or even fail. Once the encapsulation film layer formed by SiOx material fails, gases such as oxygen O2, hydrogen H2 and water H2O in the air will enter the encapsulation layer 1 and react with the IGZO channel layer, resulting in the threshold voltage Vth of the oxide TFT Negative drift occurs, and the display device produces white spots.

因此,为了对SiOx材料所形成的封装膜层进行保护,保证其封装效果,需要避免SiOx材料所形成的封装膜层受到空气中水的影响。如图5所示,一些实施例中,所述封装层1包括第一封装膜层101和第二封装膜层102,所述第一封装膜层101包覆所述发光层2,所述第二封装膜层102设置于所述第一封装膜层101远离所述发光层2的一侧,且所述第二封装膜层102的水汽透过率小于所述第一封装膜层101的水汽透过率。Therefore, in order to protect the encapsulation film layer formed by the SiOx material and ensure its encapsulation effect, it is necessary to prevent the encapsulation film layer formed by the SiOx material from being affected by water in the air. As shown in FIG. 5 , in some embodiments, the encapsulation layer 1 includes a first encapsulation film layer 101 and a second encapsulation film layer 102, the first encapsulation film layer 101 covers the light-emitting layer 2, and the first encapsulation film layer 102 The second encapsulation film layer 102 is arranged on the side of the first encapsulation film layer 101 away from the light-emitting layer 2 , and the water vapor transmission rate of the second encapsulation film layer 102 is lower than the water vapor of the first encapsulation film layer 101 transmittance.

示例性的,第一封装膜层101包覆发光层2,即第一封装膜层101在发光层2所在结构层表面的正投影至少能够完全覆盖发光层2在该结构层表面的正投影。例如,发光层2设置于基板6表面,发光层2在基板6表面的正投影形状为圆形,第一封装膜层101在基板6表面的正投影形状也为圆形,两个正投影的中心重合,且对应于发光层2的正投影的直径小于对应于第一封装膜层101的正投影的直径。需要说明的是,在本实施例中并不限定发光层2和第一封装膜层101的形状。Exemplarily, the first encapsulation film layer 101 covers the light-emitting layer 2, that is, the orthographic projection of the first encapsulation film layer 101 on the surface of the structural layer where the light-emitting layer 2 is located can at least completely cover the orthographic projection of the light-emitting layer 2 on the surface of the structural layer. For example, the luminescent layer 2 is arranged on the surface of the substrate 6, the shape of the orthographic projection of the luminescent layer 2 on the surface of the substrate 6 is circular, and the shape of the orthographic projection of the first packaging film layer 101 on the surface of the substrate 6 is also circular, and the two orthographic projections The centers coincide, and the diameter corresponding to the orthographic projection of the light-emitting layer 2 is smaller than the diameter corresponding to the orthographic projection of the first packaging film layer 101 . It should be noted that, in this embodiment, the shapes of the light emitting layer 2 and the first packaging film layer 101 are not limited.

通过在第一封装膜层101上设置水汽透过率较小的第二封装膜层102,可在一定程度上对空气中的水汽进行阻隔,防止空气中的水汽透过第二封装膜层102而与SiOx材料所形成的第一封装膜层101进行接触,避免空气中的水汽对第一封装膜层101产生不良影响,有助于保证第一封装膜层101的有效性,延长其使用寿命,从而进一步避免显示面板产生白斑。By arranging the second packaging film layer 102 with a lower water vapor transmission rate on the first packaging film layer 101, the water vapor in the air can be blocked to a certain extent, preventing the water vapor in the air from passing through the second packaging film layer 102. And contact with the first encapsulation film layer 101 formed by SiOx material, avoid the water vapor in the air from having adverse effects on the first encapsulation film layer 101, help to ensure the effectiveness of the first encapsulation film layer 101, prolong its service life , so as to further avoid white spots on the display panel.

一些实施例中,所述第二封装膜层102的水汽透过率小于0.001克每平方米每天。In some embodiments, the water vapor transmission rate of the second packaging film layer 102 is less than 0.001 grams per square meter per day.

结合前述三种封装材料的选择,申请人对不同封装材料分别进行了水汽透过试验。通过对厚度为1μm的SiOx材料进行水汽透过试验,可得SiOx材料的水汽透过率WVTR为7.2×10-2g/m2.day,即0.072克每平方米每天。而通过对厚度为1μm的SiON材料进行水汽透过试验,可得SiON材料的水汽透过率WVTR为1.7×10-4g/m2.day,即0.00017克每平方米每天。可以看出,水汽透过SiON材料的透过量远小于水汽透过SiOx材料的透过量。因此,为了满足第二封装膜层102的水汽透过率较高的要求,示例性的,可采用SiON材料所形成的膜层作为第二封装膜层102。Combining with the selection of the aforementioned three packaging materials, the applicant conducted water vapor transmission tests on different packaging materials. Through the water vapor transmission test on the SiOx material with a thickness of 1 μm, the water vapor transmission rate WVTR of the SiOx material is 7.2×10 -2 g/m 2 .day, that is, 0.072 grams per square meter per day. By performing a water vapor transmission test on a SiON material with a thickness of 1 μm, the water vapor transmission rate WVTR of the SiON material is 1.7×10 -4 g/m 2 .day, that is, 0.00017 grams per square meter per day. It can be seen that the amount of water vapor passing through the SiON material is much smaller than the amount of water vapor passing through the SiOx material. Therefore, in order to meet the requirement of high water vapor transmission rate of the second packaging film layer 102 , for example, a film layer formed of SiON material may be used as the second packaging film layer 102 .

结合上述实验结果可知,当显示面板采用SiON材料所形成的第二封装膜层102时,其含氢量大于SiOx材料所形成的第一封装膜层101的含氢量,若第一封装膜层101的厚度较薄,第二封装膜层102中的杂质氢有可能透过第一封装膜层101从而与氧化物TFT中的沟道层发生反应,进而造成显示面板产生白斑。因此,需要将第一封装膜层101的厚度进行合理化限定。一些实施例中,所述第一封装膜层101的厚度大于等于0.3微米。申请人经研究发现,当第一封装膜层101的厚度大于等于0.3微米时,其能够对第二封装膜层102进行阻断,有限避免第二封装膜层102所含的杂质氢透过第一封装膜层101与氧化物TFT的沟道层发生反应。In combination with the above experimental results, it can be seen that when the display panel adopts the second encapsulation film layer 102 formed of SiON material, its hydrogen content is greater than that of the first encapsulation film layer 101 formed of SiOx material, if the first encapsulation film layer The thickness of 101 is relatively thin, and impurity hydrogen in the second packaging film layer 102 may pass through the first packaging film layer 101 to react with the channel layer in the oxide TFT, thereby causing white spots on the display panel. Therefore, it is necessary to rationally limit the thickness of the first packaging film layer 101 . In some embodiments, the thickness of the first packaging film layer 101 is greater than or equal to 0.3 microns. The applicant has found through research that when the thickness of the first packaging film layer 101 is greater than or equal to 0.3 microns, it can block the second packaging film layer 102, and limitedly prevent the impurity hydrogen contained in the second packaging film layer 102 from passing through the first packaging film layer 102. An encapsulation film layer 101 reacts with the channel layer of the oxide TFT.

为了进一步防止第二封装膜层102所含的杂质氢透过第一封装膜层101与氧化物TFT的沟道层发生反应,还可通过降低第二封装膜层102的含氢量实现。申请人经研究发现,第二封装膜层102的含氢量与第二封装膜层102的厚度成正比,即第二封装膜层102的厚度越厚,其含氢量就越大,第二封装膜层102所含的氢透过第一封装膜层101的可能性也就越大。因此可通过消减第二封装膜层102的厚度实现降低第二封装膜层102的含氢量。In order to further prevent impurity hydrogen contained in the second packaging film layer 102 from passing through the first packaging film layer 101 and reacting with the channel layer of the oxide TFT, it can also be achieved by reducing the hydrogen content of the second packaging film layer 102 . The applicant has found through research that the hydrogen content of the second packaging film layer 102 is proportional to the thickness of the second packaging film layer 102, that is, the thicker the second packaging film layer 102, the greater its hydrogen content, and the second The hydrogen contained in the packaging film layer 102 is more likely to permeate through the first packaging film layer 101 . Therefore, the hydrogen content of the second packaging film layer 102 can be reduced by reducing the thickness of the second packaging film layer 102 .

综上,需要对第二封装膜层102的厚度进行合理化限定,以使其在满足对第一封装膜层101保护需求的同时,尽可能的降低其含氢量。有鉴于此,一些实施例中,所述第二封装膜层102的厚度小于等于1微米。To sum up, it is necessary to reasonably limit the thickness of the second packaging film layer 102 so as to reduce its hydrogen content as much as possible while meeting the protection requirements for the first packaging film layer 101 . In view of this, in some embodiments, the thickness of the second packaging film layer 102 is less than or equal to 1 micron.

如图5所示,一些实施例中,显示面板还包括基板6,所述发光层2设置于所述基板6的第一侧601,所述第二封装膜层102包覆所述第一封装膜层101;所述基板6的第一侧601还设有围绕所述发光层2的第一阻挡坝5,所述第一阻挡坝5的顶部设置有盖板4,所述盖板4、所述第一阻挡坝5和所述基板6围成的空间内设置有填充物封装层31。As shown in FIG. 5, in some embodiments, the display panel further includes a substrate 6, the light-emitting layer 2 is disposed on the first side 601 of the substrate 6, and the second packaging film layer 102 covers the first packaging The film layer 101; the first side 601 of the substrate 6 is also provided with a first barrier dam 5 surrounding the light-emitting layer 2, and the top of the first barrier dam 5 is provided with a cover plate 4, and the cover plate 4, A filler encapsulation layer 31 is disposed in the space enclosed by the first barrier dam 5 and the substrate 6 .

示例性的,基板6和盖板4均为透明玻璃材料或透明有机材料形成。Exemplarily, both the substrate 6 and the cover plate 4 are made of transparent glass material or transparent organic material.

示例性的,第一阻挡坝5围绕发光层2设置,以沿平行于基板6的第一侧601形成闭合的环形结构。在本实施例中,不对第一阻挡坝5所围成环形结构的形状进行限定,其可为长方形、正方形、圆形或多边形等。在第一阻挡坝5与发光层2之间预留有一定的空间。Exemplarily, the first barrier dam 5 is disposed around the light emitting layer 2 to form a closed ring structure along the first side 601 parallel to the substrate 6 . In this embodiment, the shape of the ring structure surrounded by the first barrier dam 5 is not limited, and it may be a rectangle, a square, a circle, or a polygon. A certain space is reserved between the first barrier dam 5 and the light emitting layer 2 .

示例性的,以下以顶发射的OLED显示面板为例对显示面板的形成过程进行说明。Exemplarily, the formation process of the display panel will be described below by taking a top-emitting OLED display panel as an example.

首先,在基板6的第一侧601上形成发光层2。之后,通过化学气相沉积方式在发光层2的发光侧(即远离基板6的一侧)沉积厚度为1μm的SiOx材料以形成包覆发光层2的第一封装膜层101。在第一封装膜层101形成完成后,再通过化学气相沉积方式在第一封装膜层101远离发光层2的一侧沉积厚度为0.5μm的SiON材料以形成包覆第一封装膜层101的第二封装膜层102。在第二封装膜层102形成完成后,向第一阻挡坝5和包覆有第一封装膜层101和第二封装膜层102的发光层2之间注入流体填充物,在流体填充物固化后能够形成填充物封装层31。最后,将盖板4与上述形成的结构层通过光学胶粘剂进行贴合,形成OLED显示面板。First, the light emitting layer 2 is formed on the first side 601 of the substrate 6 . Afterwards, SiOx material with a thickness of 1 μm is deposited on the light-emitting side of the light-emitting layer 2 (ie, the side away from the substrate 6 ) by chemical vapor deposition to form the first packaging film layer 101 covering the light-emitting layer 2 . After the formation of the first encapsulation film layer 101 is completed, SiON material with a thickness of 0.5 μm is deposited on the side of the first encapsulation film layer 101 away from the light-emitting layer 2 by chemical vapor deposition to form a coating covering the first encapsulation film layer 101. The second packaging film layer 102 . After the second encapsulation film layer 102 is formed, a fluid filler is injected between the first barrier dam 5 and the light-emitting layer 2 coated with the first encapsulation film layer 101 and the second encapsulation film layer 102, and the fluid filler solidifies Afterwards, the filler encapsulation layer 31 can be formed. Finally, the cover plate 4 and the above-formed structural layer are laminated with an optical adhesive to form an OLED display panel.

基于同一个发明构思,结合上述各个实施例的显示面板的描述,本实施例提供一种显示装置,该显示装置具有上述各个实施例的显示面板相应的技术效果,在此不再赘述。Based on the same inventive concept, combined with the descriptions of the display panels in the above embodiments, the present embodiment provides a display device that has the corresponding technical effects of the display panels in the above embodiments, which will not be repeated here.

一种显示装置,包括如上述各个实施例所述的显示面板。A display device includes the display panel as described in the above embodiments.

需要说明的是,上述对本申请的一些实施例进行了描述。其它实施例在所附权利要求书的范围内。在一些情况下,在权利要求书中记载的动作或步骤可以按照不同于上述实施例中的顺序来执行并且仍然可以实现期望的结果。另外,在附图中描绘的过程不一定要求示出的特定顺序或者连续顺序才能实现期望的结果。在某些实施方式中,多任务处理和并行处理也是可以的或者可能是有利的。It should be noted that some embodiments of the present application are described above. Other implementations are within the scope of the following claims. In some cases, the actions or steps recited in the claims can be performed in an order different from those in the above-described embodiments and still achieve desirable results. In addition, the processes depicted in the accompanying figures do not necessarily require the particular order shown, or sequential order, to achieve desirable results. Multitasking and parallel processing are also possible or may be advantageous in certain embodiments.

本申请中各个实施例均采用递进的方式描述,每个实施例重点说明的都是与其它实施例的不同之处,各个实施例之间相同或相似的部分相互参见即可。Each embodiment in the present application is described in a progressive manner, each embodiment focuses on the differences from other embodiments, and the same or similar parts between the various embodiments can be referred to each other.

本申请的描述是为了示例和描述起见而给出的,而并不是无遗漏的或者将本申请限于所公开的形式。很多修改和变化对于本领域的普通技术人员而言是显然的。选择和描述实施例是为了更好说明本申请的原理和实际应用,并且使本领域的普通技术人员能够理解本申请从而设计适于特定用途的带有各种修改的各种实施例。The description of the present application has been presented for purposes of illustration and description, but is not intended to be exhaustive or to limit the application to the form disclosed. Many modifications and changes will be apparent to those of ordinary skill in the art. The embodiment was chosen and described in order to better explain the principles of the application and the practical application, and to enable others of ordinary skill in the art to understand the application and design various embodiments with various modifications as are suited to the particular use.

所属领域的普通技术人员应当理解:以上任何实施例的讨论仅为示例性的,并非旨在暗示本申请的范围(包括权利要求)被限于这些例子;在本申请的思路下,以上实施例或者不同实施例中的技术特征之间也可以进行组合,步骤可以以任意顺序实现,并存在如上所述的本申请实施例的不同方面的许多其它变化,为了简明它们没有在细节中提供。Those of ordinary skill in the art should understand that: the discussion of any of the above embodiments is exemplary only, and is not intended to imply that the scope of the application (including claims) is limited to these examples; under the thinking of the application, the above embodiments or Combinations of technical features in different embodiments are also possible, steps may be implemented in any order, and there are many other variations of the different aspects of the embodiments of the application as described above, which are not provided in details for the sake of brevity.

尽管已经结合了本申请的具体实施例对本申请进行了描述,但是根据前面的描述,这些实施例的很多替换、修改和变型对本领域普通技术人员来说将是显而易见的。Although the application has been described in conjunction with specific embodiments thereof, many alternatives, modifications and variations of those embodiments will be apparent to those of ordinary skill in the art from the foregoing description.

本申请实施例旨在涵盖落入所附权利要求的宽泛范围之内的所有这样的替换、修改和变型。因此,凡在本申请实施例的精神和原则之内,所做的任何省略、修改、等同替换、改进等,均应包含在本申请的保护范围之内。The embodiments of the present application are intended to embrace all such alternatives, modifications and variations that fall within the broad scope of the appended claims. Therefore, any omissions, modifications, equivalent replacements, improvements, etc. within the spirit and principles of the embodiments of the present application shall be included within the protection scope of the present application.

Claims (10)

1. An encapsulating material, wherein the encapsulating material has a wave number of 1500cm in a Fourier infrared absorption spectrum -1 To 3500cm -1 The integrated area of absorption peak in the range of 500cm in wavenumber -1 To 3500cm -1 The integral area ratio of all absorption peaks in the range is 3% or less.
2. The packaging material of claim 1, wherein the packaging material is a silicon oxygen compound, and the proportion of the number of silicon oxygen bonds in the silicon oxygen compound to the total number of chemical bonds in the silicon oxygen compound is 97% or more.
3. An encapsulating film comprising the encapsulating material according to any one of claims 1 to 2.
4. A display panel comprising a light-emitting layer and an encapsulating layer covering at least a light-emitting side of the light-emitting layer, wherein the encapsulating layer is the encapsulating film layer according to claim 3 on a side facing the light-emitting layer.
5. The display panel of claim 4, wherein the encapsulation layer comprises a first encapsulation film layer and a second encapsulation film layer, the first encapsulation film layer covers the light emitting layer, the second encapsulation film layer is disposed on a side of the first encapsulation film layer away from the light emitting layer, and a water vapor transmittance of the second encapsulation film layer is smaller than that of the first encapsulation film layer.
6. The display panel of claim 5 wherein the second encapsulating film layer has a moisture vapor transmission rate of less than 0.001 grams per square meter per day.
7. The display panel according to claim 5, wherein the first encapsulation film layer has a thickness of 0.3 μm or more.
8. The display panel according to claim 5, wherein the thickness of the second encapsulation film layer is 1 μm or less.
9. The display panel according to claim 5, wherein the display panel further comprises a substrate, the light emitting layer is disposed on a first side of the substrate, and the second encapsulating layer encapsulates the first encapsulating layer; the first side of base plate still is equipped with around the first blocking dam of luminescent layer, the top of first blocking dam is provided with the apron, the apron first blocking dam with be provided with the filler encapsulated layer in the space that the base plate encloses.
10. A display device characterized by comprising the display panel according to any one of claims 4 to 9.
CN202211497222.XA 2022-11-25 2022-11-25 Packaging material, packaging film layer, display panel and display device Pending CN115835682A (en)

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